Abstract: Residual fractions from distillation of petroleum are rendered suitable for charge to catalytic cracking by high temperature, short time contact in a decarbonizing zone with fluidizable solid particles of essentially inert character and low surface area to deposit high boiling components of the crude and metals on the fluidizable solid particles whereby Conradson Carbon values and metal content of the hydrocarbon feedstock are reduced to levels tolerable in catalytic cracking and carbon laid down on the inert fluidizable particles is burned in a burning zone separate from the decarbonizing zone. Heated inert particles are recycled at least in part to the decarbonizing zone and then to the burning zone.

Abstract: The specification discloses a desulfurization, demetalation and denitrogenation process for coal and coal liquid charge stocks. The process comprises contacting the charge stock in the absence of externally added hydrogen with a hydrogen donor solvent in the presence of a catalytic amount of naturally occurring porous metal ores such as manganese nodules, bog iron, bog manganese, nickel laterites, bauxite or spent bauxite.

Abstract: A solid product resulting from the nucleated growth of the product on solid material of either the same or different composition and having a density higher than the reaction medium is formed from one or more liquid phase reactants by a method which comprises tangentially introducing the liquid phase reaction medium into the lower, smaller end of an inverted, frusto-conical reactor-separator, thereby imparting an upward swirling motion to the reaction medium in the reactor-separator, the horizontal velocity at the bottom of the reactor-separator being sufficiently large to cause fluidization of larger, solid product particles and concentration of them in the central lower portion of the reactor-separator and the vertical velocity at the top of the reactor-separator being sufficiently small to avoid carry-over of the smaller solid particles but sufficiently large to concentrate them in the upper portion of the reactor-separator; at least periodically recovering the larger, solid product particles in spherical

Abstract: In accordance with the present invention, a process is provided for removing impurities from heavy and light lube oil fractions that have been obtained from waste lubricating oil. The impurities in the light lube oil fraction are removed utilizing tetrahydrofurfuryl alcohol in an extraction column (10). An oil-rich raffinate has the solvent removed therefrom by steam distillation and stripping at reduced pressure in a distillation tower (20). The heavy lube oil fraction is purified in a manner similar to the purification of the light lube oil fraction. The finished heavy and light lube oil may then be subjected to further treatment, such as polishing steps or additives may be blended into the lube oil product depending on the desired use.

Abstract: A process is disclosed for the production of high octane gasoline and/or other valuable lower molecular weight products from carbo-metallic oils. Examples include crude oil, topped crude, reduced crude, residua, the extract from solvent de-asphalting and other heavy hydrocarbon fractions. These carbo-metallic oils contain quantities of coke precursors and heavy metal catalyst poisons substantially in excess of what is normally considered acceptable for FCC processing (fluid catalytic cracking) and substantial amounts of sulfur, nitrogen, and other troublesome components may also be present. Such carbo-metallic oils are converted to the desired products in a catalytic conversion process. Named "RCC" (Reduced Crude Conversion) after a particularly common or useful carbo-metallic feed, the present process is by no means restricted to reduced crude or to oils of petroleum origin, having utility in the processing of oils from coal, shale and other sources.

Abstract: Demetallized hydrocarbon feedstock is obtained from heavy oils by first solvent extracting the heavy oils and then demetallizing the extract in a magneto-filtration step. In another embodiment, diamagnetic nickel complexes in hydrocarbon oils are first converted to a paramagnetic product and the oil stream thereafter is passed through a magneto-filtration operation.

Abstract: A hydrocarbon conversion catalyst suitable for conversion of heavy hydrocarbon oils containing large amounts of metallic contaminants, such as petroleum residua, to lower boiling products comprises a porous inorganic oxide such as bulk alumina composited with an inorganic oxide gel matrix such as silica-alumina, and a crystalline aluminosilicate zeolite.

Abstract: A method of removing metal alkaryl sulfonates from a hydrocarbon solution is disclosed. Briefly, the method comprises (a) contacting the hydrocarbon solution containing metal alkaryl sulfonates with an aqueous basic solution containing a "recovery" surfactant, (b) forming a hydrocarbon phase and an aqueous phase containing metal alkaryl sulfonates and (c) separating the hydrocarbon phase and the aqueous phase.

Abstract: Whole crude and bottoms fractions from distillation of petroleum are upgraded by high temperature, short time contact with a fluidizable solid of essentially inert character to deposit high boiling components of the charge on the solid whereby Conradson Carbon values, salt content and metal content are reduced. The upgraded hydrocarbon fraction may be supplied to fractionator, in which case the high temperatue contactor serves as a heater, e.g. crude heater for crude distillation, in addition to improving quality of the fractions derived by distillation. For charge stocks boiling above about 500.degree.-650.degree. F., the upgrading process yields a product suitable for charge to catalytic cracking in that Conradson Carbon, salts and metals are reduced to levels tolerable in catalytic cracking.

Abstract: Process for removing metal(s) and water from used hydrocarbon lubricating oil characterized in that the said used oil is treated with an aqueous solution containing a surfactant and anions which form an insoluble salt or insoluble salts with at least one metal present in the said used oil followed by separation of an oil layer of reduced metal and water content.The oil so treated is suitable for refinery feedstock, and also as fuel oil or as blendstock for other hydrocarbon products, or as rerefining feedstock.

Abstract: A process for the production of an essentially ash-free oil stock from a lubricating oil containing ash-forming components comprising(a) contacting said lubricating oil with an aqueous ammonium salt treating agent;(b) removing a major portion of the water from the mixture resulting from combining said aqueous solution and said lubricating oil;(c) heating at least a portion of the product resulting from step (b) at a temperature in the range of about 320.degree. to about 420.degree. C. for a period of time sufficient to decompose at least a portion of any ammonium salts of sulfonic acid and dialkyldithiophosphoric acid that are contained therein;(d) cooling the product from step (c) to a temperature in the range of about 150.degree. to about 180.degree. C.; and(e) separating the solids from the product of step (d), optionally with subsequent hydrotreating and stripping of the oil thus obtained.

Abstract: Residual fractions from distillation of petroleum are rendered suitable for charge to catalytic cracking by high temperature, short time contact in a decarbonizing zone with a fluidizable solid particles of essentially inert character and low surface area to deposit high boiling components of the crude and metals on the fluidizable solid particles whereby Conradson Carbon values and metal content of the hydrocarbon feedstock are reduced to levels tolerable in catalytic cracking and carbon laid down on the inert fluidizable particles is burned in a burning zone separate from the decarbonizing zone. Heated inert particles are recycled at least in part to the decarbonizing zone and then to the burning zone.

Abstract: A method for increasing the sedimentation of mineral particles in feed liquids containing the same, particularly coal-derived liquids, by the use of an anti-solvent gas pressure technique. The mixture is held under a pressurized carbon dioxide atmosphere which causes an increase in the initial settling rate for sedimentation of the mineral particles from such liquids so that they may be used as fuels.

Abstract: Ammonium sulfate-bisulfate solution contaminated with metal and other ash producing contaminants is treated by adjusting the pH of the solution to the range that produces a precipitate of the contaminant by the addition of ammonia or ammonium hydroxide; cooled to at least the temperature at which a precipitate is produced; removing the precipitate from the solution; the pH of the solution from which the precipitate has been removed is adjusted to the range at which precipitation is substantially completed by the addition of sulfuric acid; and the SO.sub.4.sup.= ion concentration and the NH.sub.4.sup.+ ion concentration of the solution are adjusted to the range of the solution before initial circulation to produce a solution in which the metal concentration has been sufficiently reduced to permit recycle for use in reclaiming used motor oils.

Abstract: A thermal demetalation and desulfurization process comprising the addition of ammonia and water to heavy crude oils and residuums with minimal coke formation and with decreased viscosity.

Abstract: A process for separating petroleum distillation residues into a lower boiling fraction and a higher boiling fraction. The separation is effected with the aid of a process gas under super-critical conditions of temperature and pressure such that the gas selectively takes up the lower boiling fraction. By suitable selection of the gas, the process can be carried out at relatively low temperature, and with low input energy requirements when performed with recycling of the process gas.

Abstract: The octane number of a cracked naphtha can be significantly improved in a catalytic cracking unit, without significant decrease in naphtha yield, by maintaining certain critical concentrations of metals on the catalyst, suitably by blending or adding a heavy metals-containing component to the gas oil feed.

Abstract: Hydrocarbon oils such as residual petroleum oils are efficiently deasphalted and demetallized with recovery of high quality asphalt by contact with a liquid mixture of at least two of the components selected from hydrogen sulfide, carbon dioxide and propane. The recovered deasphalted oil, which is characterized by reduced metal and sulfur content, may be used as charge stock to the fluid catalytic cracking process or to the hydrocracking process.

Abstract: Oil shale retort effluent having a temperature of at least 650.degree. F. (343.degree. C.) is cooled, if necessary, to within the range from 600.degree.-800.degree. F. (316.degree.-427.degree. C.), separated into a liquid phase and a vapor phase, and the liquid phase is maintained within that range for 1 to 120 minutes to form a liquid product having a pour point less than 40.degree. F. (4.4.degree. C.). When the effluent contains at least one contaminant selected from soluble iron and soluble arsenic and is withdrawn from the retort at a temperature of at least 300.degree. F. (149.degree. C.), maintaining the liquid phase at a temperature from 300.degree.-800.degree. F. (149.degree.-427.degree. C.) will cause formation of (1) a precipitate containing iron, arsenic or both and (2) a liquid product having a reduced contaminant content.

Abstract: A method for the simultaneous use of a metals passivation agent and an oxidation promoter in a catalytic cracking system. The oxidation promoter charge is increased an effective amount upon charging the passivation agent at an excessive rate to thereby allow the benefits of both agents to be realized.

Abstract: In a process for hydrocracking heavy polynuclear carbonaceous feedstocks to produce lighter hydrocarbon fuels by contacting the heavy feedstocks with hydrogen in the presence of a molten metal halide catalyst in a hydrocracking zone, thereafter separating at least a major portion of the lighter hydrocarbon fuels from the spent molten metal halide and thereafter regenerating the spent molten metal halide by incinerating the spent molten metal halide by combustion of carbon and sulfur compounds in the spent molten metal halide in an incineration zone, the improvement comprising: (a) contacting the heavy feedstocks and hydrogen in the presence of the molten metal halide in the hydrocracking zone at reaction conditions effective to convert from about 60 to about 90 weight percent of the feedstock to lighter hydrocarbon fuels; (b) separating at least a major portion of the lighter hydrocarbon fuels from the spent molten metal halide; (c) contacting the spent molten metal halide with oxygen in a liquid phase gasifi

Abstract: A process for cracking gasoline feedstock with greater selectivity of gasoline production and greater metals tolerance wherein, said gasoline feedstock is brought into contact with a catalyst comprising a zeolite dispersed in an alumina-aluminum phosphate-silica matrix, said matrix having outstanding thermal stability.

Abstract: An integrated process universally applicable for the reclaiming of used lubricating oils, regardless of the contaminants or previous additive systems contained therein, is provided to produce an intermediate low-ash oil or a high-grade lube oil stock which comprises (a) contacting the used oil with an aqueous ammonium salt treating agent, (b) removing a major portion of water, (c) separating the oil phase from the resulting residual product, (d) subjecting the resulting separated oil to hydrotreating and thereafter (e) stripping the resulting hydrotreated lube oil stock. Optionally the low-ash product of step (c) can be recovered for use as a fuel oil, in grease formulations, or in the preparation of some types of lubricating oil formulations.

Abstract: Used cracking catalyst fines from a cracking process wherein antimony or a compound thereof is used as a metals passivation agent are used as an efficient passivation agent in a cracking process.

Abstract: Used cracking catalyst fines from a cracking process wherein antimony or a compound thereof is used as a metals passivation agent are used as an efficient passivation agent in a cracking process.

Abstract: A hydrocarbon conversion process suitable for the conversion of heavy hydrocarbon oils containing large amounts of metallic contaminants, such as petroleum residua, utilizes a catalyst comprising an inroganic oxide gel matrix comprising a major amount of silica, and minor amounts of zirconia and alumina, from about 15 to about 40 weight percent of an adsorbent such as bulk alumina, and a crystalline aluminosilicate zeolite.

Abstract: The fluid catalytic cracking of a residual oil fraction comprising metal contaminants and/or asphaltene type coke formers is processed by injecting the oil into the upper portion of a riser cracking operation under conditions to effect partial conversion thereof over a catalyst inactivated by carbonaceous deposits. A 650.degree.0 F. plus product of the low severity cracking is passed in contact with freshly regenerated catalyst under conditions of high conversion severity in the lower portion of the riser.

Abstract: A cross-linked polystyrene resin modified by the presence therein of chemically bound sulfur provides a highly selective sorbent for removal of heavy metal contaminants from liquids containing the same.

Abstract: A stream of wax-containing crude oil is passed through a heating zone which heats it sufficiently to melt the wax and is then passed through a rapid cooling zone where it is cooled to a temperature below the freezing point of the wax but sufficiently rapdily to prevent solidification of the wax. The cooled oil is then subjected promptly to further treatment while the wax is still in liquid condition in the oil at a temperature below said freezing point. The further treatment preferably includes passing a mixture of the cooled oil and wash water through a centrifuge and there separating the wash water from the oil while retaining the wax in the washed oil discharged from the centrifuge.

Abstract: A process is disclosed for demetallizing heavy hydrocarbon oils, by contacting the oil at elevated temperature with acidified active carbon. The process is particularly useful as a pretreatment of the heavy hydrocarbons for subsequent catalytic processes which are impared by metals such as nickel and vanadium.

Abstract: A catalyst composition, a method for its preparation and a hydrotreating process using same. The catalyst comprises a rigidly interconnected pack of irregularly shaped particles having an average diameter below 0.15 mm. Among the particles and throughout the pack are access channels comprising interconnected macropores having diameters in the 0.1 to 15 micron range which contribute at least 5 percent of the pore volume. The particles comprise materials selected from the group consisting of at least one refractory oxide component and one hydrogenation component. For each 100 parts of the oxide component the composition contains, in parts by weight, an amount of the hydrogenating component, calculated as metal, in the range from 0.1 to 50 parts.

Abstract: A process for the separation of a low metals content organic material from an easily calcinable solid material, effected by treating a low-melting solid material, resulting from the refining of a hydrocarbon crude oil, with naphtha at an elevated temperature and pressure whereby the resulting solid material, after separation of the liquid organic material, is in condition to be readily calcinable.

Abstract: A process for removing polonium from hydrocarbons which process comprises contacting fluid polonium containing hydrocarbons with an ion exchange resin, having a dry surface area of at least 1 m.sup.2 /g and containing exchange groups selected from the group consisting of acidic and strongly basic exchange groups.The ion exchange resins are preferably macroreticular resins. Suitable hydrocarbons for treatment are natural gas condensates.

Abstract: A method of negating the effects of metals poisoning on zeolite-containing cracking catalysts which comprises compositing tin with such catalysts.

Abstract: Solids are separated from a tar sands extract by gravity settling or centrifugation in the presence of a liquid promoter which promotes and enhances the separation of the solid material. The liquid promoter has a characterization factor of at least 9.75, a 5 volume percent distillation temperature of at least 250.degree. F and a 95 volume percent distillation temperature of at least 350.degree. F and no greater than 750.degree. F. As a result, liquid product is obtained without the necessity of preliminary coking of the entire extract.

Abstract: A process is provided for removing unfilterable suspended solids from an oil wherein these solids are agglomerated to separable conglomerated solids by adding to the oil an agglomerating agent comprising a mixture of acetone and 2-butanone.

Abstract: Disclosed is a process for the removal of solids and the fluid catalytic cracking of a synthetic hydrocarbon stream having a 90% boiling point above 800.degree. F. and containing finely divided solids. The stream is cracked under low-severity cracking conditions, and a first portion of the solids is removed along with the spent catalyst and separated from the spent catalyst in a catalyst regeneration zone. A second portion of the solids is removed by conventional means from the catalytically cracked product to form a product synthetic crude essentially free of solids.

Abstract: The amount of heat input required for the sequential fractionation of a crude oil in a crude column and a vacuum column is reduced by an improved heat exchange method wherein the desalted crude oil is flashed and the flash zone liquid is split into two streams. One of the streams is first heat exchanged against an atmospheric gas oil stream from the crude column and then against a first asphalt stream from the vacuum column. The other stream is first heat exchanged against a heavy vacuum gas oil stream from the vacuum column and then against a second asphalt stream from the vacuum column. The two streams are then recombined, heated and passed into the crude column.

Abstract: Heated hydrocarbon crude oil is passed into a first flash zone wherein it is separated into a first flash vapor and a first flash liquid. First flash vapor is water washed to remove soluble contaminants, and the resulting wash water and the first flash liquid are passed to a desalter. First flash liquid having substantial freedom from water soluble contaminants is passed from the desalter into a second flash zone wherein it is separated into a second flash vapor and a second flash liquid. The second flash liquid is passed into a conventional fractionation zone comprising a crude column and a vacuum column.

Abstract: A topped crude oil is admixed with a hydrocarbon solvent and centrifuged in the presence of a brine carrier to produce a hydrocarbon solvent-fuel oil mixture and a brine-asphalt-fuel oil mixture, the latter mixture being recovered and admixed with a ketone solvent which effects emulsion breaking and extracts residual fuel oil, a ketone solvent rich phase being subsequently recovered and subjected to fractionation to separate the fuel oil from the ketone solvent, the latter being recycled for further usage.

Abstract: A process is disclosed for reducing the level of compounds of certain metals from hydrocarbon liquids by contacting said metal compound-bearing hydrocarbon with acidified active carbon. The process is particularly useful for preferentially removing organo lead compounds from gasolines at mild conditions, with only small removal of organo manganese antiknock compounds such as methyl cyclopentadienyl manganese tricarbonyl which may be present.

Abstract: A method for reclaiming used, petroleum base, aircraft operational hydraulic fluids by a method which includes the sequential steps of settling, aerating, foam inhibiting, adding of only supplemental amounts of additive agents and fine particle filtering.

Abstract: A method of removing arsenic and selenium contaminants from a hydrocarbonaceous fluid, such as a synthetic crude oil and fractions thereof, is disclosed. In the disclosed method, the hydrocarbonaceous fluid, containing the contaminant is subjected to a heat treating step for a period of time sufficient to form a precipitate. The thus treated hydrocarbonaceous fluid can then be separated from the precipitate to recover a hydrocarbonaceous fluid having a reduced contaminant content.

Abstract: This invention relates to an improved process for the production of deashed coal which includes contacting coal with coal dissolving solvent at elevated temperature and pressure in a hydrogen atmosphere and thereafter passing the resulting mixture to a vacuum tower to remove coal dissolving solvent for recirculation and leave vacuum tower still bottoms, which are substantially free of coal dissolving solvent. Said still bottoms then are contacted with a solubilizing solvent to dissolve a substantial quantity of said still bottoms after which said dissolved still bottoms are separated from undissolved still bottoms. The separation procedure may be effected by settling, countercurrent decantation, or filtration using pressure precoated rotary and plate filters and the like.

Abstract: A method for removing ash, asphaltenic, metallic and sulfurous contaminants from a black oil by contacting said oil with a liquid paraffinic solvent in the presence of water.

Abstract: This invention relates to a process for catalytically cracking hydrocarbon feedstocks containing a contaminant deleterious to the process and catalyst and to a method for removing the contaminant from a crystalline aluminosilicate cracking catalyst used in the process, where the contaminant is vanadium, or vanadium and nickel, and optionally iron.

Abstract: Methods of treating an oil derived by liquefaction of coal particles to separate unreacted solid matter therefrom and collect it in water or other aqueous medium, which comprise controlling the specific gravity of the oil to provide an oleaginous fluid having a substantially lower specific gravity than the aqueous medium, as by mixing the oil with a liquid that is miscible therewith and has a lower specific gravity, or by controlling the temperature of the oil, or both; contacting the fluid with the aqueous medium; moving the fluid in such a manner as to provide a substantial acceleration thereto in a direction to drive most of the solid matter away from the fluid and into the aqueous medium as by moving the fluid in a swirling path around an axis while maintaining a portion of the aqueous medium around at least a portion of the periphery of the path; and separating the aqueous medium with the solid matter contained therein from the fluid.

Abstract: A method for treatment of the heavy hydrocarbonaceous fraction resulting from thermal cracking of high molecular-weight hydrocarbonaceous materials, which method comprises removing light hydrocarbons contained in said fraction by bringing it into contact with a bed packed with refractory inorganic particles at an elevated temperature so as to evaporate said light hydrocarbons and regenerating said refractory inorganic particles-packed bed by incinerating heavy hydrocarbonaceous materials remaining on and/or among said particles in the bed by supplying oxygen to the bed.

Abstract: Metals are removed from metal- and asphaltene-containing petroleum oils by contacting the oil with pellets of sorptive type attapulgus clay which has been extruded and then dried at a temperature between about 100.degree. and 650.degree. C. to a volatile content of less than 20 weight %.

Abstract: The conversion of high metals containing feed stock is accomplished in the presence of a low molecular weight carbon-hydrogen fragment contributing material and an acid function crystalline zeolite catalyst to produce gasoline of high quality and yields superior to that obtained heretofore.