First Stage Is An Hydrogenation (saturation) Patents (Class 208/57)
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Publication number: 20150001129Abstract: A process and apparatus is disclosed for pretreating a hydrocarbon stream in a hydrotreating reactor and separating the diesel materials from the pretreated effluent before the heavier liquid materials are fed to a hydrocracking unit. Thus diesel materials are preserved but recovered along with the hydrocracked effluent. A recovered diesel stream can be sent to a hydrotreating unit to improve its cetane rating.Type: ApplicationFiled: June 28, 2013Publication date: January 1, 2015Inventors: Peter Kokayeff, Clayton C. Sadler, Vasant P. Thakkar
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Patent number: 8900443Abstract: Methods for processing a hydrocarbonaceous feedstock flows are provided. In one embodiment, the method includes providing two or more hydroprocessing stages disposed in sequence, each hydroprocessing stage having a hydroprocessing reaction zone with a hydrogen requirement and each stage in fluid communication with the preceding stage. The hydrocarbonaceous feedstock flow may be separated into portions of fresh feed for each hydroprocessing stage, and the first portion of fresh feed to the first hydroprocessing stage is heated. The heated first portion of fresh feed may be supplied with hydrogen from the hydrogen source in an amount satisfying substantially all of the hydrogen requirements of the hydroprocessing stages to a first hydroprocessing zone. The unheated second portion of fresh feed is injected counter current to the process flow as quench at one or more locations in one or more of the reaction zones.Type: GrantFiled: April 6, 2012Date of Patent: December 2, 2014Assignee: UOP LLCInventors: Paul A. Sechrist, Robert L. Bunting, Nicholas W. Bridge
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Patent number: 8882991Abstract: In one aspect, the invention includes in a process for cracking a hydrocarbon feedstock comprising: a) feeding a hydrocarbon feedstock containing at least 1 wt % of resid components having boiling points of at least 500° C. to a furnace convection section to heat the feedstock; b) flashing the heated feedstock in a first flash separation vessel to create a first overhead stream and a first bottoms liquid stream; c) hydrogenating at least a portion of the first bottoms liquid stream to create a hydrogenated bottoms stream; d) flashing the hydrogenated bottoms stream in a second flash separation vessel to create a second overhead stream and a second bottoms liquid stream; e) cracking the first overhead stream and the second overhead stream in a cracking furnace to produce a pyrolysis effluent stream. In other embodiments, the process further comprises heating the hydrocarbon feedstock in step a) to a temperature within a range of from 315° C. to 705° C.Type: GrantFiled: August 21, 2009Date of Patent: November 11, 2014Assignee: ExxonMobil Chemical Patents Inc.Inventors: Keith H. Kuechler, Jennifer L. Bancroft, Paul F. Keusenkothen, Robert D. Strack
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Patent number: 8852426Abstract: Deep desulfurization of hydrocarbon feeds containing undesired organosulfur compounds to produce a hydrocarbon product having low levels of sulfur, i.e., 15 ppmw or less of sulfur, is achieved by hydrotreating the feed under mild conditions, and separating the hydrotreated effluent into an aromatic-rich fraction which contains a substantial amount of the aromatic refractory and sterically hindered sulfur-containing compounds, and an aromatic-lean fraction. The aromatic-rich fraction is contacted with isomerization catalyst, and the isomerized aromatic-rich fraction is recycled to the mild hydrotreating process.Type: GrantFiled: July 27, 2012Date of Patent: October 7, 2014Assignee: Saudi Arabian Oil CompanyInventor: Omer Refa Koseoglu
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Publication number: 20140291202Abstract: Methods are provided for dewaxing a distillate fuel boiling range feed to improve one or more cold flow properties of the distillate fuel feed, such as cloud point, with reduced consumption of hydrogen during the dewaxing process. The reduced hydrogen consumption is achieved by using a dewaxing catalyst with a reduced content of hydrogenation metals, such as a content of Pt or Pd of from about 0.03 wt % to about 0.35 wt %. A distillate fuel feed can be dewaxed to achieve a desired cloud point differential using a reduced metals content dewaxing catalyst under the same or similar conditions to those required for a dewaxing catalyst with higher metals content.Type: ApplicationFiled: February 28, 2014Publication date: October 2, 2014Applicant: EXXONMOBIL RESEARCH AND ENGINEERING COMPANYInventors: Xiaochun Xu, William J. Novak, Timothy L. Hilbert, Stephen J. McCarthy
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Publication number: 20140291201Abstract: One exemplary embodiment can be a process for hydroprocessing. The process can include providing a hydroprocessing zone having at least two beds, and quenching downstream of a first bed of the at least two beds with a first vacuum gas oil that may be lighter than another vacuum gas oil fed to the first bed.Type: ApplicationFiled: March 26, 2013Publication date: October 2, 2014Applicant: UOP, LLCInventors: Soumendra Mohan Banerjee, Mani Krishna, Avnish Kumar
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Publication number: 20140291203Abstract: A catalytic system characterized in that it comprises: a first catalyst, having a hydrogenating function, consisting of solid particles of which at least 95% by volume having an equivalent diameter smaller than 20 ?m, containing one or more sulfides of metals of group VI and/or VIII B, possibly prepared starting from an oil-soluble precursor of the same; and a second catalyst, having a cracking function, consisting of solid particles of which at least 90% by volume having an equivalent diameter larger than 5 ?m and smaller than 5 mm, containing an amorphous silico-aluminate and/or a crystalline silico-aluminate and/or an alumina, the equivalent average diameter of the solid particles of the second catalyst being greater than the equivalent average diameter of the solid particles of the first catalyst.Type: ApplicationFiled: September 6, 2012Publication date: October 2, 2014Applicant: Eni, S.P.A.Inventors: Daniele Molinari, Giuseppe Bellussi, Alberto Landoni, Paolo Pollesel
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Publication number: 20140262940Abstract: A process for upgrading residuum hydrocarbons is disclosed. The process may include: contacting a residuum hydrocarbon fraction and hydrogen with a first hydroconversion catalyst in a first ebullated bed hydroconversion reactor system; recovering a first effluent from the first ebullated bed hydroconversion reactor system; solvent deasphalting a vacuum residuum fraction to produce a deasphalted oil fraction and an asphalt fraction; contacting the deasphalted oil fraction and hydrogen with a second hydroconversion catalyst in a second hydroconversion reactor system; recovering a second effluent from the second hydroconversion reactor system; and fractionating the first effluent from the first ebullated bed hydroconversion reactor system and the second effluent from the second hydroconversion reactor system to recover one or more hydrocarbon fractions and the vacuum residuum fraction in a common fractionation system.Type: ApplicationFiled: March 5, 2014Publication date: September 18, 2014Applicant: LUMMUS TECHNOLOGY INC.Inventors: Mario C. Baldassari, Ujjal K. Mukherjee, Ann-Marie Olsen, Marvin I. Greene
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Patent number: 8834706Abstract: The present invention relates to a method for preparing lubricating base oils by using vacuum distilled deasphalted oil, and more specifically, to a method for preparing various kinds of lubricating base oils by distilling a distillate obtained from a solvent deasphalting (SDA) process under reduced pressure to obtain heavy deasphalted oil (H-DAO) and light deasphalted (Lt-DAO) and then treating the H-DAO and the Lt-DAO by catalytic reactions, respectively. According to the present invention, it is possible to obtain heavy lubricating base oil (150BS) of a high viscosity grade which can not be obtained by a known catalytic reaction and a lubricating base oil of group III by hydrogenation, in a high yield, and thus economical efficiency is excellent.Type: GrantFiled: June 3, 2011Date of Patent: September 16, 2014Assignee: SK Innovation Co., Ltd.Inventors: Kyung Seok Noh, Jae Wook Ryu, Do Hyoun Kim, Gyung Rok Kim, Seung Woo Lee, Do Woan Kim, Sun Choi, Seung Hoon Oh, Byung Won Yoon, Bum Suk Chun
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Patent number: 8828217Abstract: Diesel fuel is produced from a feedstock that is at least partially biocomponent in origin. A feedstock is treated in a reactor including one or more hydrotreating zones having a continuous gas phase. The liquid effluent from the hydrotreating zones is then hydroprocessed in a hydroprocessing zone having a continuous liquid phase, such as a hydroprocessing zone in the same reactor. The hydroprocessing zone can be operated under effective catalytic dewaxing conditions.Type: GrantFiled: June 24, 2011Date of Patent: September 9, 2014Assignee: ExxonMobil Research and Engineering CompanyInventors: Patrick L. Hanks, William E. Lewis
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Patent number: 8828218Abstract: This invention provides methods for multi-stage hydroprocessing treatment of FCC naphthas for improving the overall production quantity of naphtha boiling-range materials during naphtha production for low sulfur gasolines. Of particular benefit of the present processes is the selective treating of cat naphthas to remove gums instead of undercutting the overall naphtha pool by lowering the end cutpoints of the cat naphtha fraction. This maximizes the amount of refinery cat naphtha that can be directed to the gasoline blending pool while eliminating existing processing problems in hydrodesulfurization units. The processes disclosed herein have the additional benefit of minimizing octane losses in the increased naphtha pool volume.Type: GrantFiled: October 19, 2012Date of Patent: September 9, 2014Assignee: ExxonMobil Research and Engineering CompanyInventors: John Peter Greeley, Timothy Lee Hilbert, William Joseph Novak, Rohit Garg
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Patent number: 8821714Abstract: The invention describes a catalyst comprising at least one material with a hierarchical porosity comprising silicon and at least one hydrodehydrogenating element from group VIB and/or group VIII of the periodic table of the elements. Said material with a hierarchical porosity comprising silicon is constituted by at least two elementary spherical particles, each of said spherical particles comprising zeolitic nanocrystals having a pore size in the range 0.2 to 2 nm and a matrix based on silicon oxide, which is mesostructured, having a pore size in the range 1.5 to 30 nm and having amorphous walls with a thickness in the range 1 to 30 nm, said elementary spherical particles having a maximum diameter of 100 ?m. The matrix based on silicon oxide may contain aluminum.Type: GrantFiled: October 29, 2007Date of Patent: September 2, 2014Assignee: IFP Energies NouvellesInventors: Alexandra Chaumonnot, Patrick Bourges
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Patent number: 8808533Abstract: Process for treatment of a feedstock, such as hydrocarbons that comprise at least 4 carbon atoms per molecule and that comprise at least one unsaturated compound including benzene, such that said feedstock is treated in a distillation zone, associated with a hydrogenation reaction zone, at least in part outside of the distillation zone, and an isomerization zone, so as to discharge—at the top of the distillation zone and at the bottom of the distillation zone—an effluent that is low in unsaturated compounds, whereby said process comprises the treatment of at least a second feedstock, comprising at least one unsaturated compound including benzene, at least partially directly injected into the hydrogenation zone that is outside of the distillation zone.Type: GrantFiled: April 23, 2010Date of Patent: August 19, 2014Assignee: IFP Energies NouvellesInventors: Jean Luc Nocca, Quentin Debuisschert
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Publication number: 20140221712Abstract: Integrated processes for upgrading crude shale-derived oils, such as those produced by oil shale retorting or by in situ extraction or combinations thereof. Processes disclosed provide for a split-flow processing scheme to upgrade whole shale oil. The split flow concepts described herein, i.e., naphtha and kerosene hydrotreating in one or more stages and gas oil hydrotreating in one or more stages, requires additional equipment as compared to the alternative approach of whole oil hydrotreating. While contrary to conventional wisdom as requiring more capital equipment to achieve the same final product specifications, the operating efficiency vis a vis on-stream time efficiency and product quality resulting from the split flow concept far exceed in value the somewhat incrementally higher capital expenditure costs.Type: ApplicationFiled: February 1, 2013Publication date: August 7, 2014Applicant: LUMMUS TECHNOLOGY INC.Inventors: Marvin I. Greene, Ujjal K. Mukherjee, Arun Arora
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Publication number: 20140221709Abstract: A process for upgrading residuum hydrocarbons is disclosed. The process may include: contacting a residuum hydrocarbon fraction and hydrogen with a first hydroconversion catalyst in a first ebullated bed hydroconversion reactor system; recovering a first effluent from the first ebullated bed hydroconversion reactor system; solvent deasphalting a vacuum residuum fraction to produce a deasphalted oil fraction and an asphalt fraction; contacting the deasphalted oil fraction and hydrogen with a second hydroconversion catalyst in a second hydroconversion reactor system; recovering a second effluent from the second hydroconversion reactor system; and fractionating the first effluent from the first ebullated bed hydroconversion reactor system and the second effluent from the second hydroconversion reactor system to recover one or more hydrocarbon fractions and the vacuum residuum fraction in a common fractionation system.Type: ApplicationFiled: February 4, 2013Publication date: August 7, 2014Applicant: LUMMUS TECHNOLOGY INC.Inventors: Mario C. Baldassari, Ujjal K. Mukherjee, Ann-Marie Olsen, Marvin I. Greene
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Publication number: 20140221713Abstract: A process for upgrading residuum hydrocarbons and decreasing tendency of the resulting products toward asphaltenic sediment formation in downstream processes is disclosed. The process may include: contacting a residuum hydrocarbon fraction and hydrogen with a hydroconversion catalyst in a hydrocracking reaction zone to convert at least a portion of the residuum hydrocarbon fraction to lighter hydrocarbons; recovering an effluent from the hydrocracking reaction zone; contacting hydrogen and at least a portion of the effluent with a resid hydrotreating catalyst; and separating the effluent to recover two or more hydrocarbon fractions.Type: ApplicationFiled: February 4, 2013Publication date: August 7, 2014Applicant: LUMMUS TECHNOLOGY INC.Inventors: Mario C. Baldassari, Ujjal K. Mukherjee, Ann-Marie Olsen, Marvin I. Greene
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Patent number: 8784645Abstract: The method for manufacturing a hydrocarbon oil of the present invention comprises a first step wherein a plurality of reaction zones filled with a specific catalyst is disposed in series and a feedstock oil containing an oxygen-containing hydrocarbon compound derived from an animal or vegetable oil is supplied and hydrotreated under the conditions of a hydrogen pressure of 1 MPa or more and 10 MPa or less in each of the reaction zones; and a second step wherein hydrogen, hydrogen sulfide, carbon dioxide and water are removed from a product to be treated obtained in the first step to obtain a hydrocarbon oil. Among the plurality of reaction zones, the inlet temperature of the reaction zone disposed on the most upstream side is 150° C. or more and 250° C. or less, the inlet temperature of the second most upstream reaction zone or below is equal to or higher than the condensation temperature of water, and the outlet temperature of the reaction zone disposed on the most downstream side is 260° C.Type: GrantFiled: September 16, 2009Date of Patent: July 22, 2014Assignee: JX Nippon Oil & Energy CorporationInventors: Yasutoshi Iguchi, Tatsuo Hamamatsu, Hideki Ono, Akira Koyama, Hideshi Iki
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Patent number: 8784647Abstract: In a process for producing a hydroprocessing catalyst, a particulate metal oxide composition comprising an oxide of at least one first metal selected from Group 6 of the Periodic Table of the Elements can be mixed with particles of a sulfide of at least one second metal selected from Groups 8 to 10 of the Periodic Table of the Elements to produce a particulate catalyst precursor. The particulate catalyst precursor can then be sulfided under conditions sufficient to at least partially convert the particulate catalyst precursor into a layered metal sulfide having defect sites associated with the second metal sulfide.Type: GrantFiled: December 14, 2010Date of Patent: July 22, 2014Assignee: ExxonMobil Research and Egineering CompanyInventors: Chris E. Kliewer, Stuart L. Soled, Sabato Miseo, Jeffrey S. Beck
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Patent number: 8764970Abstract: The present invention relates to quenching, during hydroprocessing of a hydrocarbon feed stream. More particularly, the present invention provides for quenching in hydroprocessing of a hydrocarbon feed stream through a hydroprocessing vessel. Liquid quenches (from high pressure hot separator) were installed to assist in cooling the reactor inter-bed, and to maintain good liquid irrigation of the catalyst. The soluble hydrogen in the stream, kinetically active and available for immediate reaction, is the final piece of the puzzle for why this unit runs so well.Type: GrantFiled: September 10, 2008Date of Patent: July 1, 2014Assignee: Marathon Petroleum Company LPInventor: Howard F. Moore
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Patent number: 8747652Abstract: The present invention concerns a catalyst comprising at least one crystalline material comprising silicon with a hierarchical and organized porosity and at least one hydrodehydrogenating element selected from the group formed by elements from group VIB and/or group VIII of the periodic table of the elements. Said crystalline material comprising silicon with a hierarchical and organized porosity is constituted by at least two spherical elementary particles, each of said particles comprising a matrix based on oxide of silicon, which is mesostructured, with a mesopore diameter in the range 1.5 to 30 nm and having microporous and crystalline walls with a thickness in the range 1.5 to 60 nm, said elementary spherical particles having a maximum diameter of 200 microns. The invention also concerns hydrocracking/hydroconversion and hydrotreatment processes employing said catalyst.Type: GrantFiled: May 13, 2009Date of Patent: June 10, 2014Assignee: IFP Energies NouvellesInventors: Audrey Bonduelle, Alexandra Chaumonnot
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Patent number: 8741128Abstract: Deep desulfurization of hydrocarbon feeds containing undesired organosulfur and organonitrogen compounds to produce a hydrocarbon product having low levels of sulfur-containing and nitrogen-containing compounds, is achieved by first subjecting the entire feed to an extraction zone to separate an aromatic-rich fraction containing a substantial amount of the refractory organosulfur and organonitrogen compounds and an aromatic-lean fraction containing a substantial amount of the labile organosulfur and organonitrogen compounds. The aromatic-lean fraction is contacted with a hydrotreating catalyst in a hydrotreating reaction zone operating under mild conditions to convert the labile organosulfur and organonitrogen compounds. The aromatic-rich fraction is oxidized to convert the refractory organosulfur and organonitrogen compounds to oxidized organosulfur and organonitrogen compounds.Type: GrantFiled: December 15, 2010Date of Patent: June 3, 2014Assignee: Saudi Arabian Oil CompanyInventors: Omer Refa Koseoglu, Abdennour Bourane, Farhan M. Al-Shahrani, Emad Al-Shafi
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Patent number: 8741127Abstract: Reduction of sulfur-containing and nitrogen-containing compounds from hydrocarbon feeds is achieved by first contacting the entire feed with a hydrotreating catalyst in a hydrotreating reaction zone operating under mild conditions to convert the labile organosulfur and organonitrogen compounds. An extraction zone downstream of the hydrotreating reaction zone separates an aromatic-rich fraction that contains a substantial amount of the remaining refractory organosulfur and organonitrogen compounds. The aromatic-lean fraction is substantially free of organosulfur and organonitrogen compounds, since the non-aromatic organosulfur and organonitrogen compounds were the labile organosulfur and organonitrogen compounds which were initially removed by mild hydrotreating. The aromatic-rich fraction is oxidized to convert the refractory organosulfur and organonitrogen compounds to oxidized sulfur-containing and nitrogen-containing hydrocarbon compounds.Type: GrantFiled: December 14, 2010Date of Patent: June 3, 2014Assignee: Saudi Arabian Oil CompanyInventors: Omer Refa Koseoglu, Abdennour Bourane, Farhan M. Al-Shahrani, Emad Al-Shafi
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Publication number: 20140144809Abstract: A process is disclosed for hydrocracking a primary hydrocarbon feed and a diesel co-feed in a hydrocracking unit and hydrotreating a diesel product from the hydrocracking unit in a hydrotreating unit. The diesel stream fed through the hydrocracking unit is pretreated to reduce sulfur and ammonia and can be upgraded with noble metal catalyst.Type: ApplicationFiled: November 28, 2012Publication date: May 29, 2014Applicant: UOP LLCInventors: Peter Kokayeff, Paul R. Zimmerman
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Patent number: 8729322Abstract: Conversion of renewable hydrocarbons to transportation fuels is required to reduce carbon emission, limit the use of fossil fuels, and develop renewable energy sources. Sorbitol, xylitol and trehelose are polyalcohols generated from the liquefaction of various sugars and carbohydrates in biomass from algae, corn, sugarcane, switchgrasses, and biological wastes. Mixtures of aqueous polyols and fuel feedstocks are catalyzed over metal catalysts to produce hexanes, pentanes, and lighter hydrocarbons. By managing the catalyst, reaction conditions and sulfur content, the octane value of the product fuel is dramatically increased.Type: GrantFiled: August 3, 2010Date of Patent: May 20, 2014Assignee: Phillips 66 CompanyInventors: Edward L. Sughrue, Jianhua Yao
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Publication number: 20140124408Abstract: The present invention relates to a wet start-up method for hydrogenation unit, an energy-saving hydrogenation process, and a hydrogenation apparatus. The method involves heating a start-up activating oil to a specific temperature and flowing the heated oil through a bed of hydrogenation catalyst bed, so that the temperature at the catalyst bed layer is increased to 180±10° C. or above by means of heat exchange and the reaction heat generated from activation in the start-up method.Type: ApplicationFiled: October 31, 2013Publication date: May 8, 2014Applicants: Fushun Research Institute of Petroleum and Petrochemicals, SINOPEC, CHINA PETROLEUM & CHEMICAL CORPORATIONInventors: Ronghui ZENG, Tao LIU, Xiangchen FANG, Zhaoming HAN, Xuehui ZHANG, Shike SUN, Chong PENG, Rong GUO, Jihua LIU, Benzhe LI
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Publication number: 20140124407Abstract: A process for the hydroprocessing of a low value light cycle oil (LCO) hydrocarbon feed to provide a high-value diesel-range product. The process comprises a hydrotreatment stage followed by a hydrocracking stage, each of which is conducted under liquid-full reaction conditions wherein substantially all the hydrogen supplied to the hydrotreating and hydrocracking reactions is dissolved in the liquid-phase hydrocarbon feed. Ammonia and other gases formed during hydrotreatment are removed in a separation step prior to hydrocracking. The LCO feed is advantageously converted to diesel in high yield with little loss of hydrocarbon to naphtha.Type: ApplicationFiled: November 6, 2012Publication date: May 8, 2014Applicant: E I DU PONT DE NEMOURS AND COMPANYInventors: Hasan Dindi, Alan Howard Pulley, Vincent Adam Kuperavage, JR., Thanh Gia Ta
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Patent number: 8715485Abstract: The present invention concerns a catalyst comprising at least one amorphous material comprising silicon with a hierarchical and organized porosity and at least one hydrodehydrogenating element selected from the group formed by elements from group VIB and/or group VIII of the periodic table of the elements. Said amorphous material comprising silicon with a hierarchical and organized porosity is constituted by at least two spherical elementary particles, each of said spherical particles comprising a matrix based on oxide of silicon, which is mesostructured, with a mesopore diameter in the range 1.5 to 30 nm and having amorphous and microporous walls with a thickness in the range 1.5 to 50 nm, said elementary spherical particles having a maximum diameter of 200 microns. The invention also concerns hydrocracking/hydroconversion and hydrotreatment processes employing said catalyst.Type: GrantFiled: May 13, 2009Date of Patent: May 6, 2014Assignee: IFP Energies NouvellesInventors: Audrey Bonduelle, Alexandra Chaumonnot
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Patent number: 8696888Abstract: The invention concerns integration of hydroprocessing and steam cracking. A feed comprising crude or resid-containing fraction thereof is severely hydrotreated and passed to a steam cracker to obtain an olefins product.Type: GrantFiled: October 17, 2006Date of Patent: April 15, 2014Assignee: ExxonMobil Chemical Patents Inc.Inventors: Paul F. Keusenkothen, Megan L. Renstrom, Julian A. Wolfenbarger, Stephen H. Brown, John S. Buchanan
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Patent number: 8691082Abstract: Two-stage hydroprocessing uses a common dividing wall fractionator. Hydroprocessed effluents from both stages of hydroprocessing are fed to opposite sides of the dividing wall.Type: GrantFiled: September 30, 2010Date of Patent: April 8, 2014Assignee: UOP LLCInventors: John A. Petri, Vedula K. Murty, Peter Kokayeff
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Patent number: 8691076Abstract: Disclosed is a method of manufacturing high-quality naphthenic base oil by subjecting, as a feedstock, light cycle oil (LCO) and slurry oil (SLO) obtained through fluidized catalytic cracking (FCC) to hydrotreating and dewaxing.Type: GrantFiled: November 21, 2007Date of Patent: April 8, 2014Assignee: SK Lubricants Co., Ltd.Inventors: Chang Kuk Kim, Jee Sun Shin, Ju Hyun Lee, Sam Ryong Park, Gyung Rok Kim, Yoon Mang Hwang
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Publication number: 20140054198Abstract: A process for reducing the sulfur content of a hydrocarbon stream is disclosed. A full range cracked naphtha is contacted with a hydrogenation catalyst to convert at least a portion of the dienes and mercaptans to thioethers and to hydrogenate at least a portion of the dienes. The full range cracked naphtha is fractionated into a light naphtha fraction, a medium naphtha fraction, and a heavy naphtha fraction. The heavy naphtha fraction is hydrodesulfurized. The medium naphtha fraction is mixed with hydrogen and gas oil to form a mixture, which is contacted with a hydrodesulfurization catalyst to produce a medium naphtha fraction having a reduced sulfur concentration. The light, heavy, and medium naphtha fractions may then be recombined to form a hydrodesulfurized product having a sulfur content of less than 10 ppm in some embodiments.Type: ApplicationFiled: August 16, 2013Publication date: February 27, 2014Applicant: CATALYTIC DISTILLATION TECHNOLOGIESInventor: Gary G. Podrebarac
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Patent number: 8658020Abstract: A process is disclosed for converting distillate to gasoline-range hydrocarbons using a two-stage catalyst system including a first catalyst containing a Group VIII metal and a zeolite, and a second catalyst containing a Group VIII metal, tin and an inorganic oxide support.Type: GrantFiled: December 19, 2007Date of Patent: February 25, 2014Assignee: Phillips 66 CompanyInventors: Walter E. Alvarez, Edward L. Sughrue, II, Paul F. Meier, Tushar V. Choudhary
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Patent number: 8652321Abstract: Production of gasolines with low sulfur contents from a starting gasoline containing sulfur-containing compounds comprising a stage a) for selective hydrogenation of non-aromatic polyunsaturated compounds present in the starting gasoline, a stage b) for increasing the molecular weight of the light sulfur-containing products that are initially present in the gasoline that enters this stage, a stage c) for alkylation of at least a portion of the sulfur-containing compounds present in the product that originates from stage b), a stage d) for fractionation of the gasoline that originates from stage c) into at least two fractions, one fraction virtually lacking in sulfur-containing compounds, whereby the other contains a larger proportion of sulfur-containing compounds (heavy gasoline), a stage e) for catalytic treatment of the heavy gasoline for transformation of sulfur-containing compounds under conditions for the at least partial decomposition of hydrogenation of these sulfur-containing compounds.Type: GrantFiled: June 1, 2010Date of Patent: February 18, 2014Assignee: IFP Energies nouvellesInventors: Quentin Debuisschert, Denis Uzio, Jean-Luc Nocca, Florent Picard
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Publication number: 20140001088Abstract: A process for removing a nitrogen compound and a sulfur compound from a hydroprocessed vacuum gas oil feed includes contacting the hydroprocessed vacuum gas oil feed comprising the nitrogen compound and the sulfur compound with a VGO-immiscible phosphonium ionic liquid to produce a hydroprocessed vacuum gas oil and VGO-immiscible phosphonium ionic liquid mixture, and separating the mixture to produce a hydroprocessed vacuum gas oil effluent having a reduced nitrogen compound and sulfur compound content relative to the vacuum gas oil feed. It was found that the amount of the sulfur compound being removed was significantly improved by first removing the nitrogen compounds, especially polar nitrogen compounds.Type: ApplicationFiled: March 12, 2013Publication date: January 2, 2014Applicant: UOP LLCInventors: Beckay J. Mezza, Alakananda Bhattacharyya, Christopher P. Nicholas, Haiyan Wang
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Publication number: 20140001089Abstract: Process for hydrotreating a heavy hydrocarbon fraction using a system of switchable fixed bed guard zones each containing at least two catalyst beds and in which whenever the catalyst bed that is brought initially into contact with the feed is deactivated and/or clogged during the steps in which the feed passes successively through all the guard zones, the point of introduction of the feed is shifted downstream. The present invention also relates to an installation for implementing this process.Type: ApplicationFiled: December 20, 2011Publication date: January 2, 2014Applicant: IFP Energies nouvellesInventors: Frederic Bazer-Bachi, Christophe Boyer, Isabelle Guibard, Nicolas Marchal, Cecile Plain
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Patent number: 8617383Abstract: An integrated process for producing naphtha fuel, diesel fuel and/or lubricant base oils from feedstocks under sour conditions is provided. The ability to process feedstocks under higher sulfur and/or nitrogen conditions allows for reduced cost processing and increases the flexibility in selecting a suitable feedstock. The sour feed can be delivered to a catalytic dewaxing step without any separation of sulfur and nitrogen contaminants, or with only a high pressure separation so that the dewaxing still occurs under sour conditions. Various combinations of hydrotreating, catalytic dewaxing, hydrocracking, and hydrofinishing can be used to produce fuel products and lubricant base oil products.Type: GrantFiled: June 27, 2011Date of Patent: December 31, 2013Assignee: ExxonMobil Research and Engineering CompanyInventors: Krista Marie Prentice, Michel Daage, Ajit Bhaskar Dandekar, Christopher Gordon Oliveri, Rohit Vijay, Stephen J. McCarthy, Wenyih F. Lai, Bradley R. Fingland
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Patent number: 8608947Abstract: A process is provided to produce an ultra low sulfur diesel using a two stage hydrotreating reaction zone. The first stage hydrotreater may operate with a continuous liquid phase.Type: GrantFiled: September 30, 2010Date of Patent: December 17, 2013Assignee: UOP LLCInventors: John A. Petri, Vedula K. Murty, Peter Kokayeff
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Publication number: 20130313161Abstract: A process of hydroprocessing a hydrocarbon in a down flow reactor comprising one or more hydroprocessing-catalyst beds. The hydrocarbon feed is mixed with hydrogen and optionally diluent to form a liquid feed mixture wherein hydrogen is dissolved in the mixture, and the liquid feed mixture is introduced into the down flow reactor under hydroprocessing conditions. The hydroprocessing-catalyst bed(s) are liquid-full and the feed reacts by contact with the catalyst. Hydrogen gas is injected into at least one of the hydroprocessing-catalyst beds such that at least part of the hydrogen consumed in that bed is replenished and the liquid-full condition is maintained. In a multi-bed reactor, hydrogen gas may be injected into more than one or all of the hydroprocessing-catalyst beds.Type: ApplicationFiled: May 25, 2012Publication date: November 28, 2013Applicant: E I DU PONT DE NEMOURS AND COMPANYInventor: Hasan Dindi
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Patent number: 8574427Abstract: A process for removing a refractory nitrogen compound from a hydroprocessed vacuum gas oil feed includes contacting the hydroprocessed vacuum gas oil feed comprising the nitrogen compound with a VGO-immiscible phosphonium ionic liquid to produce a hydroprocessed vacuum gas oil and VGO-immiscible phosphonium ionic liquid mixture, and separating the mixture to produce a hydroprocessed vacuum gas oil effluent having a reduced refractory nitrogen compound content relative to the vacuum gas oil feed.Type: GrantFiled: July 23, 2012Date of Patent: November 5, 2013Assignee: UOP LLCInventors: Beckay J. Mezza, Haiyan Wang, Alakananda Bhattacharyya, Christopher P. Nicholas
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Patent number: 8551323Abstract: Systems and methods for hydroprocessing a heavy oil feedstock are disclosed. The system employs a plurality of contacting zones and at least one separation zone, wherein a solvating hydrocarbon having a normal boiling point less than 538° C. (1000° F.) is employed. In the system, a mixture of heavy oil feedstock and solvating hydrocarbon is provided to a contact zone along with a slurry catalyst feed in a hydrocarbon diluent. The contacting zone operates at a temperature and pressure near the critical temperature and pressure of the heavy oil and solvating hydrocarbon mixture to convert at least a portion of the heavy oil feedstock to lower boiling hydrocarbons, forming upgraded products.Type: GrantFiled: August 31, 2009Date of Patent: October 8, 2013Assignee: Chevron U.S.A. Inc.Inventors: Tayseer A Abdel-Halim, Axel Brait
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Patent number: 8545694Abstract: An improved aromatics saturation process for use with lube oil boiling range feedstreams utilizing a catalyst comprising a hydrogenation-dehydrogenation component selected from the Group VIII noble metals and mixtures thereof on a mesoporous support having aluminum incorporated into its framework and an average pore diameter of about 15 to less than about 40 ?.Type: GrantFiled: August 17, 2005Date of Patent: October 1, 2013Assignee: ExxonMobil Research and Engineering CompanyInventors: Stephen J. McCarthy, Wenyih F. Lai, Sylvain S. Hantzer, Ian A. Cody
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Publication number: 20130253238Abstract: The present invention relates to a method for producing lubricating base oil with a low cloud point and a high viscosity index. In the method, a lubricating base oil with a low pour point, a low cloud point and a high viscosity index is produced by a hydrorefining-isomerization/asymmetrical cracking-hydrofinishing in the presence of hydrogen, wherein a highly waxy heavy fraction oil having an initial boiling point of 300° C. to 460° C., a wax content of 5% or more, a pour point of ?20° C. or more and a cloud point of ?5° C. or more is used as a raw material, and naphtha and middle fraction oil being co-produced. The method is characterized mainly in the high yield of heavy base oil, a low pour point and cloud point, a high viscosity and viscosity index of the base oil.Type: ApplicationFiled: June 3, 2011Publication date: September 26, 2013Applicants: Dalian Institute of Chemical Physics (DICP), Chinese Academy of Sciences (CAS), PetroChina Company LimitedInventors: Sheng Hu, Zhijian Tian, Lijun Yan, Wenle Li, Yunpeng Xu, Kebin Chi, Xiangbin Meng, Bingchun Wang, Mingwei Tan, Lei Wang, Yanfeng Liu, Jinling Zhu, Shanbin Gao
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Publication number: 20130248418Abstract: An integrated slurry hydroprocessing and steam pyrolosyis process for the production of olefins and aromatic petrochemicals from a crude oil feedstock is provided. Crude oil, a steam pyrolysis residual liquid fraction and slurry reside are combined and treated in a hydroprocessing zone in the presence of hydrogen under conditions effective to produce an effluent having an increased hydrogen content. The effluent is thermally cracked with steam under conditions effective to produce a mixed product stream and steam pyrolysis residual liquid fraction. The mixed product stream is separated and olefins and aromatics are recovered and hydrogen is purified and recycled.Type: ApplicationFiled: March 20, 2013Publication date: September 26, 2013Applicant: Saudi Arabian Oil CompanyInventors: Esam SAYED, Raheel SHAFI, Abdul Rahman Zafer AKHRAS, Abdennour BOURANE, Ibrahim A. ABBA
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Publication number: 20130248416Abstract: An integrated hydrotreating, steam pyrolysis and coker process for the direct processing of a crude oil is provided to produce olefinic and aromatic petrochemicals, and petroleum coke. Crude oil and recycled coker liquid product are charged to a hydroprocessing zone operating under conditions effective to produce a hydroprocessed effluent which is thermally cracked in the presence of steam to produce a mixed product stream. The residual liquid fraction recovered upstream of the thermal cracking unit or within the thermal cracking unit is thermally cracked under conditions effective to produce coke and coker liquid product. The coker liquid product is recycled to the step of hydroprocessing while the petroleum coke is recovered. Hydrogen from the mixed product stream is purified and recycled to the hydroprocessing zone, and olefins, aromatics and pyrolysis fuel oil are recovered from the separated mixed product stream.Type: ApplicationFiled: March 20, 2013Publication date: September 26, 2013Applicant: SAUDI ARABIAN OIL COMPANYInventors: Raheel SHAFI, Abdennour BOURANE, Abdul Rahman Zafer AKHRAS, Essam SAYED, Ibrahim A. ABBA
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Publication number: 20130248417Abstract: Crude oil is charged to a hydroprocessing zone in the presence of hydrogen operating under conditions effective to produce a hydroprocessed effluent, which is thermally cracked in the presence of steam in a steam pyrolysis zone to produce a mixed product stream. Heavy components, which are derived from one or more of the hydroprocessed effluent, a heated stream within the steam pyrolysis zone, or the mixed product stream catalytically cracking are charged to a slurry hydroprocessing zone to produce a slurry intermediate product which is then thermally cracked. Olefins and aromatics are recovered from the separated mixed product stream as product.Type: ApplicationFiled: March 20, 2013Publication date: September 26, 2013Applicant: Saudi Arabian Oil CompanyInventors: Esam SAYED, Raheel SHAFI, Abdul Rahman Zafer AKHRAS, Abdennour BOURANE, Ibrahim A. ABBA
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Patent number: 8541636Abstract: The invention relates to a method for the catalytic hydrotreatment of a load based on a diesel fuel oil and a biological load based on plant oils and/or animal fats in a hydrotreatment unit. The invention is characterized in that the hydrotreatment unit comprises at least one hydrotreatment reactor operating on a countercurrent. The invention also relates to a hydrotreatment unit for implementing said method, and a corresponding hydrorefining unit.Type: GrantFiled: February 12, 2008Date of Patent: September 24, 2013Assignee: Total Raffinage MarketingInventor: César Vergel
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Publication number: 20130240405Abstract: The present invention provides a process for deep desulphurization of cracked gasoline with minimum octane loss of about 1-2 units. In this process full range cracked gasoline from FCC, Coker, Visbreaker etc is sent to Diolefin Saturation Reactor for selective saturation of diolefins. After saturation of diolefins, the stream is sent to Splitter for splitting into three cuts i.e Light Cut (IBP-70° C.), Intermediate Cut (70-90° C.) and Heavy Cut (90-210° C.). The Light Cut which contains majority of the high octane olefins and mercaptan sulfur is desulfurized with caustic treatment using Continuous Film Contactor (CFC). The sulfur in the Intermediate Cut is also predominantly mercaptans and the cut can be desulfurised by caustic treatment using CFC along with Light cut or separately desulfurised before being sent for isomerization. The Heavy Cut containing mainly thiophinic sulfur compounds is treated either by using conventional HDS process or reactive adsorption process.Type: ApplicationFiled: November 16, 2011Publication date: September 19, 2013Applicant: INDIAN OIL CORPORATION LIMITEDInventors: Sarvesh Kumar, Alok Sharma, Brijesh Kumar, Anju Chopra, Santanam Rajagopal, Kumar Ravinder Malhotra
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Patent number: 8529753Abstract: Disclosed is a combined process for hydrotreating and catalytic cracking of residue, wherein the residue, catalytic cracking heavy cycle oil with acidic solid impurity being removed, optional distillate oil and adistillate of catalytic cracking slurry oil from which the acidic solid impurity is removed are fed into residue hydrotreating unit, the hydrogenated residue obtained and optional vacuum gas oil are fed into catalytic cracking unit to obtain various products; the catalytic cracking heavy cycle oil from which the acidic solid impurity is removed is circulated to the residue hydrotreating unit; the catalytic cracking slurry oil is separated by distilling, the distillate of the catalytic cracking slurry oil after removing off the acidic solid impurity is circulated to the residue hydrotreating unit.Type: GrantFiled: December 27, 2007Date of Patent: September 10, 2013Assignees: Research Institute of Petroleum Processing, Sinopec, China Petroleum & Chemical CorporationInventors: Chuanfeng Niu, Lishun Dai, Yongcan Gao, Dadong Li, Yahua Shi, Hong Nie, Qinghe Yang
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Publication number: 20130220884Abstract: A process is provided that is directed to a steam pyrolysis zone integrated with a hydrotreating zone and a solvent deasphalting zone to permit direct processing of crude oil feedstocks to produce petrochemicals including olefins and aromatics.Type: ApplicationFiled: April 17, 2013Publication date: August 29, 2013Applicant: SAUDI ARABIAN OIL COMPANYInventors: Abdennour BOURANE, Raheel SHAFI, Essam SAYED, Ibrahim A. ABBA, Abdul Rahman Zafer AKHRAS
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Publication number: 20130197285Abstract: An integrated hydrotreating and steam pyrolysis process for the direct processing of a crude oil is provided to produce olefinic and aromatic petrochemicals. Crude oil and hydrogen are charged to a hydroprocessing zone operating under conditions effective to produce a hydroprocessed effluent reduced having a reduced content of contaminants, an increased paraffinicity, reduced Bureau of Mines Correlation Index, and an increased American Petroleum Institute gravity. Hydroprocessed effluent is thermally cracked in the presence of steam to produce a mixed product stream, which is separated. Hydrogen from the mixed product stream is purified and recycled to the hydroprocessing zone, and olefins and aromatics are recovered from the separated mixed product stream.Type: ApplicationFiled: January 28, 2013Publication date: August 1, 2013Applicant: Saudi Arabian Oil CompanyInventors: Raheel SHAFI, Julio HASSELMEYER, Abdennour BOURANE, Ibrahim A. ABBA, Abdul Rahman Zafer AKHRAS