With Subsequent Reforming Patents (Class 208/69)
  • Publication number: 20150060333
    Abstract: A process for treating heavy oil to provide a treated heavy oil having a reduced density and viscosity, as well as an olefin content that does not exceed 1.0 wt. %. The process comprises separating the initial heavy oil into a first fraction, which in general contains lower-boiling components, and a second fraction. The second fraction comprises a heavy oil having a p-value of at least 5% greater than the p-value of the initial heavy oil prior to separating the initial heavy oil into the first fraction and the second fraction, and the second fraction has an aromaticity that is no more than 5% less than the aromaticity of the initial heavy oil prior to separating the initial heavy oil into the first fraction and the second fraction. The second fraction then is upgraded to reduce the density and viscosity of the heavy oil. After the second fraction is upgraded, it is recombined with at least a portion of the first fraction to provide a treated heavy oil having an olefin content that does not exceed 1.0 wt. %.
    Type: Application
    Filed: August 7, 2014
    Publication date: March 5, 2015
    Inventors: Michel Chornet, Christos Chronopoulos, Soumaine Dehkissia
  • Patent number: 8940950
    Abstract: The process relates to the use of any naphtha-range stream containing a portion of C8+ aromatics combined with benzene, toluene, and other non-aromatics in the same boiling range to produce toluene. By feeding the A8+ containing stream to a dealkylation/transalkylation/cracking reactor to increase the concentration of toluene in the stream, a more suitable feedstock for the methylation reaction can be produced. This stream can be obtained from a variety of sources, including the pygas stream from a steam cracker, “cat naphtha” from a fluid catalytic cracker, or the heavier portion of reformate.
    Type: Grant
    Filed: November 23, 2011
    Date of Patent: January 27, 2015
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Justin M. Ellrich, Robert D. Strack, John W. Rebeck, Allen S. Gawlik, Larry L. Iaccino, Glenn C. Wood, Stephen H. Brown, Timothy Paul Bender
  • Patent number: 8911613
    Abstract: Disclosed is a method of simultaneously manufacturing high quality naphthenic base oil and heavy base oil using a single catalyst system, by subjecting an oil fraction (slurry oil or light cycle oil) produced by fluid catalytic cracking and an oil fraction (deasphalted oil) produced by solvent deasphalting to hydrotreating, catalytic dewaxing and hydrofinishing of the single catalyst system, thereby obtaining not only products having low viscosity but also heavy base oil products (150BS) having high viscosity which was impossible to obtain using a conventional catalytic reaction process, and also thereby producing base oil products having different properties using the single catalyst system, thus generating economic benefits and exhibiting superior efficiency.
    Type: Grant
    Filed: November 2, 2010
    Date of Patent: December 16, 2014
    Assignee: SK Innovation Co., Ltd.
    Inventors: Kyung Seok Noh, Jae Wook Ryu, Do Hyoun Kim, Gyung Rok Kim, Seung Woo Lee, Do Woan Kim, Sun Choi, Seung Hoon Oh, Byung Won Yoon, Bum Suk Chun
  • Patent number: 8888991
    Abstract: Heavy gas oil components, coking process recycle, and heavier hydrocarbons in the delayed coking process are cracked in the coking vessel by injecting a catalytic additive into the vapors above the gas/liquid-solid interface in the coke drum during the coking cycle. The additive comprises cracking catalyst(s) and quenching agent(s), alone or in combination with seeding agent(s), excess reactant(s), carrier fluid(s), or any combination thereof to modify reaction kinetics to preferentially crack these components. The quenching effect of the additive can be effectively used to condense the highest boiling point compounds of the traditional recycle onto the catalyst(s), thereby focusing the catalyst exposure to these target reactants. Exemplary embodiments of the present invention can also provide methods to (1) reduce coke production, (2) reduce fuel gas production, and (3) increase liquids production.
    Type: Grant
    Filed: February 12, 2013
    Date of Patent: November 18, 2014
    Inventor: Roger G. Etter
  • Publication number: 20140114097
    Abstract: A method and apparatus is provided for the continuous microwave depolymerization of high molecular weight organic feedstock material, such as waste plastics and includes intermittent or continuous feeding of the processing material on the surface or into the bulk of the sensitized hot bed located under microwave irradiation. As a result of the interaction of electromagnetic field with processed materials, sensitizer is heated by microwave energy and feedstock material undergoes the depolymerization reactions. The reaction zone can be localized on the surface of the hot bed or distributed in the bulk of the reaction mass depending on the agitation conditions of the reaction mass, such as stirring, or other agitation means, for example by re-circulated gas. Products of the reactions are vaporized and transported to the collection system, which may include a combination of a scrubber, a condenser and a settler.
    Type: Application
    Filed: May 16, 2013
    Publication date: April 24, 2014
    Applicant: CLIMAX GLOBAL ENERGY
    Inventors: John Hemmings, Thomas Pinto, Viktor Sharivker
  • Patent number: 8617384
    Abstract: A process for maximizing p-xylene production begins by producing a naphtha fraction and a light cycle oil fraction from a fluid catalytic cracking zone. The gasoline and light cycle oil fractions are combined and hydrotreated to produce a hydrotreated product. Fractionation of the hydrotreated product in a fractionation zone makes a light ends cut, a naphtha cut, a hydrocracker feed and an unconverted oil fraction. The hydrocracker feed is sent to a hydrocracking zone to make a hydrocracker product, which is then recycled back to the fractionation zone, feeding the hydrocracker product above an outlet for the hydrocracker feed, but below an outlet for the naphtha cut. The naphtha cut goes to a dehydrogenation zone where hydrogen is removed to make aromatics from naphthenes to make a dehydrogenated naphtha. The dehydrogenated naphtha is fed to an aromatics recovery unit to recover p-xylene and other aromatics.
    Type: Grant
    Filed: October 7, 2011
    Date of Patent: December 31, 2013
    Assignee: UOP LLC
    Inventors: Robert Haizmann, Laura E. Leonard
  • Patent number: 8608941
    Abstract: A reforming process includes integrating catalytic cracking product naphtha dehydrogenation and naphtha from a hydrocracking zone and feeding them to a dehydrogenation zone. The dehydrogenation zone includes a first portion of reforming catalyst from a catalyst regenerator that moves downward through the dehydrogenation zone. A product stream from the dehydrogenation zone flows to an aromatics unit and is separated into an aromatic-rich extract and a raffinate. Straight run naphtha and the raffinate are introduced to a first reforming zone that includes a second portion of reforming catalyst. The reforming catalyst moves through the first reforming zone then is removed from the bottom of each of the first reforming zone and the dehydrogenation zone and is fed to a second reforming zone. An effluent from the first reforming zone is fed to a plurality of reforming zones. The reforming catalyst moves downward through the multiple reforming zones then to a regenerator.
    Type: Grant
    Filed: October 7, 2011
    Date of Patent: December 17, 2013
    Assignee: UOP LLC
    Inventors: Robert Haizmann, Laura E. Leonard
  • Patent number: 8524961
    Abstract: A process for maximizing p-xylene production includes producing a naphtha fraction and a light cycle oil fraction from a fluid catalytic cracking zone. These fractions are combined and hydrotreated. Fractionation of the hydrotreated product makes a hydrocracker feed that is sent to a hydrocracking zone to make a naphtha cut and a hydrocracker product. The hydrocracker product is recycled back to the fractionation zone, and the naphtha cut is dehydrogenated in a dehydrogenation zone to make aromatics. Reforming catalyst from a catalyst regenerator moves downward through the dehydrogenation zone. Straight run naphtha and raffinate from the aromatics unit are introduced to an additional series of reforming zones. The reforming catalyst moves in parallel through the first reforming zone and the dehydrogenation zones, then is combined for entry to the second and subsequent reforming zones prior to regeneration.
    Type: Grant
    Filed: October 7, 2011
    Date of Patent: September 3, 2013
    Assignee: UOP LLC
    Inventors: Robert Haizmann, Laura E. Leonard
  • Patent number: 8440070
    Abstract: A process and apparatus process for preparing a resid-containing hydrocarbon feedstock for use in a regenerative pyrolysis reactor, comprising (a) feeding a resid-containing hydrocarbon feedstock to a thermal cracking unit; (b) thermally cracking at least about 60 wt. % of said resid having a boiling point of at least 565° C. in said hydrocarbon feedstock to form a vapor phase containing cracked hydrocarbons; (c) separating said vapor phase from remaining non-volatiles; and (d) converting the separated vapor phase in a regenerative pyrolysis reactor system.
    Type: Grant
    Filed: June 11, 2010
    Date of Patent: May 14, 2013
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventor: Paul F. Keusenkothen
  • Publication number: 20130087484
    Abstract: A process for maximizing p-xylene production begins by producing a naphtha fraction and a light cycle oil fraction from a fluid catalytic cracking zone. The gasoline and light cycle oil fractions are combined and hydrotreated to produce a hydrotreated product. Fractionation of the hydrotreated product in a fractionation zone makes a light ends cut, a naphtha cut, a hydrocracker feed and an unconverted oil fraction. The hydrocracker feed is sent to a hydrocracking zone to make a hydrocracker product, which is then recycled back to the fractionation zone, feeding the hydrocracker product above an outlet for the hydrocracker feed, but below an outlet for the naphtha cut. The naphtha cut goes to a dehydrogenation zone where hydrogen is removed to make aromatics from naphthenes to make a dehydrogenated naphtha. The dehydrogenated naphtha is fed to an aromatics recovery unit to recover p-xylene and other aromatics.
    Type: Application
    Filed: October 7, 2011
    Publication date: April 11, 2013
    Applicant: UOP LLC
    Inventors: Robert Haizmann, Laura E. Leonard
  • Patent number: 8372265
    Abstract: Undesirable gas oil components are selectively cracked or coked in a coking vessel by injecting an additive into the vapors of traditional coking processes in the coking vessel prior to fractionation. The additive contains catalyst(s), seeding agent(s), excess reactant(s), quenching agent(s), carrier(s), or any combination thereof to modify reaction kinetics to preferentially crack or coke these undesirable components that typically have a high propensity to coke. Exemplary embodiments of the present invention also provide methods to control the (1) coke crystalline structure and (2) the quantity and quality of volatile combustible materials (VCMs) in the resulting coke. That is, by varying the quantity and quality of the catalyst, seeding agent, and/or excess reactant the process may affect the quality and quantity of the coke produced, particularly with respect to the crystalline structure (or morphology) of the coke and the quantity & quality of the VCMs in the coke.
    Type: Grant
    Filed: November 19, 2007
    Date of Patent: February 12, 2013
    Inventor: Roger G. Etter
  • Patent number: 8206574
    Abstract: A reactor process added to a coking process to modify the quantity or yield of a coking process product and/or modify certain characteristics or properties of coking process products.
    Type: Grant
    Filed: February 11, 2009
    Date of Patent: June 26, 2012
    Inventor: Roger G. Etter
  • Publication number: 20110240519
    Abstract: One exemplary embodiment can be a process for alkylating and hydrogenating a light cycle oil. The process can include passing the light cycle oil, one or more C2-C6 alkenes, and hydrogen through a reaction vessel containing an alkylation zone and a hydrogenation zone. Generally, the hydrogen is at least partially comprised from a hydrocarbon product stream from a fluid catalytic cracking zone.
    Type: Application
    Filed: March 31, 2010
    Publication date: October 6, 2011
    Applicant: UOP, LLC
    Inventors: Deng-Yang Jan, Vasant P. Thakkar, Christopher P. Nicholas
  • Patent number: 7892500
    Abstract: A system and method for recycling plastics. The system and method recover materials such as hydrocarbon gases, liquid hydrocarbon distillates, various polymers and/or monomers used to produce the original plastics. The system and method allow about one unit of input of energy input to the plastic recycler to be used to create one or more gaseous components and one or more liquid distillate components from a plastic that is being recycled. The one or more gaseous components and one or more liquid distillate components produce about one corresponding unit of useable output energy recovered from the recycling of the plastic.
    Type: Grant
    Filed: November 18, 2009
    Date of Patent: February 22, 2011
    Inventor: William E. Carner
  • Publication number: 20110011768
    Abstract: A process and apparatus process for preparing a resid-containing hydrocarbon feedstock for use in a regenerative pyrolysis reactor, comprising (a) feeding a resid-containing hydrocarbon feedstock to a thermal cracking unit; (b) thermally cracking at least about 60 wt. % of said resid having a boiling point of at least 565° C. in said hydrocarbon feedstock to form a vapor phase containing cracked hydrocarbons; (c) separating said vapor phase from remaining non-volatiles; and (d) converting the separated vapor phase in a regenerative pyrolysis reactor system.
    Type: Application
    Filed: June 11, 2010
    Publication date: January 20, 2011
    Inventor: Paul F. Keusenkothen
  • Patent number: 7846323
    Abstract: The present invention generally relates to a method for producing an isoparaffinic product useful as jet fuel from a renewable feedstock. The method may also include co-producing a jet fuel and a liquefied petroleum gas (LPG) fraction from a renewable feedstock. The method includes hydrotreating the renewable feedstock to produce a hydrotreating unit heavy fraction that includes n-paraffins and hydroisomerizing the hydrotreating unit heavy fraction to produce a hydroizomerizing unit heavy fraction that includes isoparaffins. The method also includes recycling the hydroisomerizing unit heavy fraction through the hydroisomerization unit to produce an isoparaffinic product that may be fractionated into a jet fuel and an LPG fraction. The present invention also relates to a jet fuel produced from a renewable feedstock having improved cold flow properties.
    Type: Grant
    Filed: April 4, 2008
    Date of Patent: December 7, 2010
    Assignee: Syntroleum Corporation
    Inventors: Ramin Abhari, Lynn Tomlinson, Peter Havlik, Nathan Jannasch
  • Publication number: 20100213102
    Abstract: A catalytic conversion process which comprises catalytic cracking reaction of a hydrocarbon feedstock contacting with a medium pore size zeolite enriched catalyst in a reactor, characterized in that reaction temperature, weight hourly space velocity and catalyst/feedstock ratio by weight are sufficient to achieve a yield of fluid catalytic cracking gas oil between 12% and 60% by weight of said feedstock, wherein said weight hourly space velocity is between 25 h?1 and 100 h?1, said reaction temperature is between 450° C. and 600° C., and said catalyst/feedstock ratio by weight is between 1 and 30. This invention relates to a catalytic conversion process, especially for heavy feedstock oil to produce higher octane gasoline and an enhanced yield of propylene. More particularly, the invention relates to a process to utilize petroleum oil resources efficiently for decreasing the yield of dry gas and coke significantly.
    Type: Application
    Filed: August 7, 2008
    Publication date: August 26, 2010
    Inventors: Youhao Xu, Lishun Dai, Longsheng Tian, Shouye Cui, Jianhong Gong, Chaogang Xie, Jiushun Zhang, Jun Long, Zhijian Da, Hong Nie, Jinbiao Guo, Zhigang Zhang
  • Patent number: 7727376
    Abstract: A process to prepare base oils from a Fischer-Tropsch synthesis product by (a) separating the Fischer-Tropsch synthesis product into a fraction (i) boiling in the middle distillate range and below, a heavy ends fraction (iii) and an intermediate base oil precursor fraction (ii) boiling between fraction (i) and fraction (iii), (b) subjecting the base oil precursor fraction (ii) to a catalytic hydroisomerisation and catalytic dewaxing process to yield one or more base oil grades, (c) subjecting the heavy ends fraction (iii) to a conversion step to yield a fraction (iv) boiling below the heavy ends fraction (iii) and (d) subjecting the high boiling fraction (v) of fraction (iv) to a catalytic hydroisomerisation and catalytic dewaxing process to yield one or more base oil grades.
    Type: Grant
    Filed: July 2, 2004
    Date of Patent: June 1, 2010
    Assignee: Shell Oil Company
    Inventors: Nicholas James Adams, Michiel Cramwinckel, Jan Lodewijk Maria Dierickx
  • Publication number: 20090294329
    Abstract: The invention provides a low aromatic producing process for catalytical conversion of Fisher-Tropsch derived olefins to distillates (COD), which process includes the step of contacting Fisher-Tropsch derived olefins with a zeolyte type catalyst at pressures of more than 50 barg.
    Type: Application
    Filed: August 6, 2009
    Publication date: December 3, 2009
    Applicant: The Petroleum Oil and Gas Corporation of South Africa (PTY) Ltd.
    Inventors: Cyril David Knottenbelt, Carl Dunlop, Kholekile Zono, Maxwell Thomas
  • Patent number: 7626062
    Abstract: A system and method for recycling plastics. The system and method recover materials such as hydrocarbon gases, liquid hydrocarbon distillates, various polymers and/or monomers used to produce the original plastics. The system and method allow about one unit of input of energy input to the plastic recycler to be used to create one or more gaseous components and one or more liquid distillate components from a plastic that is being recycled. The one or more gaseous components and one or more liquid distillate components produce about one corresponding unit of useable output energy recovered from the recycling of the plastic.
    Type: Grant
    Filed: July 31, 2007
    Date of Patent: December 1, 2009
    Inventor: William E. Carner
  • Patent number: 7582201
    Abstract: In a system for thermal cracking gaseous feedstocks, the system including a gas cracker for producing an effluent comprising olefins, at least one transfer line exchanger for the recovery of process energy from the effluent and a water quench tower system, a process for extending the range of system feedstocks to include liquid feedstocks that yield tar is provided. The process includes the steps of injecting a first quench fluid downstream of a primary transfer line exchanger to quench the process effluent comprising olefins, separating in a first separation vessel a cracked product and a first byproduct stream comprising tar from the quenched effluent, directing the separated cracked product to a water quench tower system and quenching the separated cracked product with a second quench fluid to produce a cracked gas effluent for recovery and a second byproduct stream comprising tar. An apparatus for carrying out such process is also provided.
    Type: Grant
    Filed: December 5, 2006
    Date of Patent: September 1, 2009
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: James N. McCoy, Barrington M. Hammond, David J. Duhon, Mark A. Rooney, Robert D. Strack, John R. Messinger
  • Patent number: 7560019
    Abstract: In a system for thermal cracking gaseous feedstocks, the system including a gas cracker for producing an effluent comprising olefins, at least one transfer line exchanger for the recovery of process energy from the effluent and a water quench tower system, a process for extending the range of system feedstocks to include liquid feedstocks that yield tar is provided. The process includes the steps of injecting a first quench fluid downstream of the at least one transfer line exchanger to quench the process effluent comprising olefins, separating in a separation vessel a cracked product and a first byproduct stream comprising tar from the quenched effluent, directing the separated cracked product to the water quench tower system and quenching the separated cracked product with a second quench fluid to produce a cracked gas effluent for recovery and a second byproduct stream comprising tar. An apparatus for cracking a liquid hydrocarbon feedstock that yield tar is also provided.
    Type: Grant
    Filed: December 5, 2006
    Date of Patent: July 14, 2009
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: James N. McCoy, Walter F. Filupeit, Barrington M. Hammond, David J. Duhon, Mark A. Rooney, Robert A. Strack, John R. Messinger
  • Publication number: 20080128323
    Abstract: In a system for thermal cracking gaseous feedstocks, the system including a gas cracker for producing an effluent comprising olefins, at least one transfer line exchanger for the recovery of process energy from the effluent and a water quench tower system, a process for extending the range of system feedstocks to include liquid feedstocks that yield tar is provided. The process includes the steps of injecting a first quench fluid downstream of a primary transfer line exchanger to quench the process effluent comprising olefins, separating in a first separation vessel a cracked product and a first byproduct stream comprising tar from the quenched effluent, directing the separated cracked product to a water quench tower system and quenching the separated cracked product with a second quench fluid to produce a cracked gas effluent for recovery and a second byproduct stream comprising tar. An apparatus for carrying out such process is also provided.
    Type: Application
    Filed: December 5, 2006
    Publication date: June 5, 2008
    Inventors: James N. McCoy, Barrington M. Hammond, David J. Duhon, Mark A. Rooney, Robert D. Strack, John R. Messinger
  • Publication number: 20080128326
    Abstract: In a system for thermal cracking gaseous feedstocks, the system including a gas cracker for producing an effluent comprising olefins, at least one transfer line exchanger for the recovery of process energy from the effluent and a water quench tower system, a process for extending the range of system feedstocks to include liquid feedstocks that yield tar is provided. The process includes the steps of injecting a first quench fluid downstream of the at least one transfer line exchanger to quench the process effluent comprising olefins, separating in a separation vessel a cracked product and a first byproduct stream comprising tar from the quenched effluent, directing the separated cracked product to the water quench tower system and quenching the separated cracked product with a second quench fluid to produce a cracked gas effluent for recovery and a second byproduct stream comprising tar. An apparatus for cracking a liquid hydrocarbon feedstock that yield tar is also provided.
    Type: Application
    Filed: December 5, 2006
    Publication date: June 5, 2008
    Inventors: James N. McCoy, Walter F. Filupeit, Barrington M. Hammond, David J. Duhon, Mark A. Rooney, Robert A. D. Strack, John R. Messinger
  • Patent number: 7364650
    Abstract: The present invention provides an upgraded synthetic gasoline having a true boiling point (TBP) range of between 50° C.-300° C., a sulphur content of less than 1 ppm, a nitrogen content of less than 1 ppm, an aromatics content of between 0.01%-35% by weight, an olefins content of between 0.01%-45%, a benzene content of less than 1.00% by weight, an oxygen content of between 0.5-3.0% by weight, a RON of greater than 80, and a MON of greater than 80. The invention also provides processes for the production of the upgraded synthetic gasoline wherein the synthetic products derived from a Fischer-Tropsch reaction are passed to a cracking reactor to produce a synthetic gasoline stream which is subsequently fractionated and upgraded using an oxygenating reactor, and optionally a combination of an MTBE reactor, a dehydrocyclodimerisation reactor and C5 isomerisation reactor. The upgraded synthetic gasoline is useful as a fuel.
    Type: Grant
    Filed: November 5, 2002
    Date of Patent: April 29, 2008
    Assignee: BP Exploration Operating Company Limited
    Inventor: Josephus Johannes Helena Maria Font Freide
  • Patent number: 7318845
    Abstract: A distillate fuel steam reformer system in which a fuel feed stream is first separated into two process streams: an aliphatics-rich, sulfur-depleted gas stream, and an aromatics- and sulfur-rich liquid residue stream. The aliphatics-rich gas stream is desulfurized, mixed with steam, and converted in a reforming reactor to a hydrogen-rich product stream. The aromatics-rich residue stream is mixed with air and combusted to provide heat necessary for endothermic process operations. Reducing the amounts of sulfur and aromatic hydrocarbons directed to desulfurzation and reforming operations minimizes the size and weight of the overall apparatus. The process of the invention is well suited to the use of microchannel apparatuses for heat exchangers, reactors, and other system components, which may be assembled in slab configuration, further reducing system size and weight.
    Type: Grant
    Filed: June 23, 2003
    Date of Patent: January 15, 2008
    Assignee: Applied Research Associates, Inc.
    Inventors: Aly H. Shaaban, Timothy J. Campbell
  • Publication number: 20040256288
    Abstract: The present invention provides an upgraded synthetic gasoline having a true boiling point (TBP) range of between 50° C.-300° C., a sulphur content of less than 1 ppm, a nitrogen content of less than 1 ppm, an aromatics content of between 0.01%-35% by weight, an olefins content of between 0.01%-45%, a benzene content of less than 1.00% by weight, an oxygen content of between 0.5-3.0% by weight, a RON of greater than 80, and a MON of greater than 80. The invention also provides processes for the production of the upgraded synthetic gasoline wherein the synthetic products derived from a Fischer-Tropsch reaction are passed to a cracking reactor to produce a synthetic gasoline stream which is subsequently fractionated and upgraded using an oxygenating reactor, and optionally a combination of an MTBE reactor, a dehydrocyclodimerisation reactor and C5 isomerisation reactor. The upgraded synthetic gasoline is useful as a fuel.
    Type: Application
    Filed: May 4, 2004
    Publication date: December 23, 2004
    Inventor: Josephus Johannes Helena Maria Font Freide
  • Publication number: 20040140246
    Abstract: A process is disclosed for taking a cut from an FCC reactor product and reacting it in a separate reactor to upgrade the product quality Cracking or reformulating reactions in the separate reactor give reductions in olefins and reformulating hydrogen-transfer reactions convert undesirable olefins to isoparaffins and aromatics without reducing octane value Catalyst particles from the FCC reactor may be cycled to the separate reactor This process has also been found to substantially diminish concentrations of nitrogen and sulfur compounds fed to the separate reactor.
    Type: Application
    Filed: August 31, 2001
    Publication date: July 22, 2004
    Inventor: David A. Lomas
  • Patent number: 6677496
    Abstract: A process for the coproduction of purified benzene and ethylene is provided. The method comprises providing a first mixture comprising benzene, toluene, and one or more C6 to C7 non-aromatics and separating the majority of the benzene and the one or more C6 to C7 non-aromatics from the majority of the toluene to form a second mixture containing benzene and at least a portion of the one or more C6 to C7 non-aromatics. Thereafter at least about 80% of the C6 to C7 non-aromatics in the second mixture are cracked while maintaining essentially no cracking of benzene to produce a cracked product containing ethylene, propylene and pyrolysis gasoline comprising olefins, di-olefins and benzene. The pyrolysis gasoline is preferably hydrotreated and then fractionated to form a purified benzene product comprising at least about 80 wt % benzene. The purified benzene can be used as a feed to a liquid phase or mixed phase alkylation and/or to produce ethylbenzene or cumene.
    Type: Grant
    Filed: October 23, 2001
    Date of Patent: January 13, 2004
    Inventor: David Netzer
  • Patent number: 6495028
    Abstract: A process for catalytic conversion of hydrocarbon feedstock to produce isobutane and isoparaffin-enriched gasoline which comprises two different reactions, the preheated feedstock is contacted with hot regenerated catalyst in the lower part of a reactor with the result that catalytic cracking reaction takes place, and the mixture of vapors and the coke deposited catalyst are up-flowed and enter into a suitable reaction environment with the result that isomerization and hydrogen transfer reaction take place. The produced LPG has an isobutane content of about 20 wt % to about 40 wt % and the produced gasoline contains isoparaffin content of about 30 wt % to about 45 wt % and olefin content of less than 30 wt %. RON and MON of the gasoline are 90˜93 and 80˜84 respectively.
    Type: Grant
    Filed: April 21, 2000
    Date of Patent: December 17, 2002
    Assignees: China Petroleum Corporation, Research Institute of Petroleum Processing
    Inventors: Youhao Xu, Jiushun Zhang, Yinan Yang, Jun Long, Xieqing Wang, Zaiting Li, Raichi Zhang
  • Patent number: 6433235
    Abstract: An improved process for the conversion of normally gaseous methane-containing hydrocarbon mixtures, such as natural gas, to a normally liquid hydrocarbon product comprises separating the methane component of the gaseous mixture from the heavier hydrocarbon component, cracking the separated heavier: hydrocarbon component at a relatively low temperature and optionally cracking the methane component at a relatively high temperature. The low temperature cracking product and any high temperature cracking product are separated into a light product of principally hydrogen and a heavy product comprising unsaturated hydrocarbons. This heavy product is reacted with methane in the presence of an acidic alkalization catalyst. The resulting product mixture is separated into a light product, a portion of which is recycled, and the normally liquid hydrocarbon product.
    Type: Grant
    Filed: June 9, 2000
    Date of Patent: August 13, 2002
    Assignee: Bryan Research & Engineering, Inc.
    Inventor: Joel G. Cantrell
  • Patent number: 6288296
    Abstract: The invention includes a process of making a lubricating oil composition including: a process for making a high VI lubricating oil composition including the steps of (1) contacting a waste plastics feed including mainly polyethylene in a pyrolysis zone at pyrolysis conditions, whereby at least a portion of the waste plastics feed is cracked, thereby forming a pyrolysis zone effluent including 1-olefins and n-paraffins; (2) passing the pyrolysis zone effluent, including a heavy fraction and a middle fraction, the pyrolysis effluent middle fraction including 1-olefins, to a separations zone; where the pyrolysis effluent heavy fraction portion is separated from the pyrolysis effluent middle fraction; (3) passing the pyrolysis effluent middle fraction to a dimerization zone, where at least a portion of the pyrolysis effluent middle fraction is converted to a lube oil range material; and (4) passing at least a portion of the lube oil range material to a catalytic isomerization dewaxing zone, where at least a porti
    Type: Grant
    Filed: February 4, 2000
    Date of Patent: September 11, 2001
    Assignees: Chevron U.S.A. Inc., University of Kentucky Research Foundation
    Inventors: Stephen J. Miller, Gerald P. Huffman, Naresh Shah
  • Patent number: 6238548
    Abstract: An FCC process converts a secondary feed comprising a heart cut of a gasoline product stream with spent catalyst at mild conditions to obtain a surprising increase in the octane number of the resulting gasoline product. More surprisingly, the increase in gasoline stream octane number occurs with very low production of dry gas. Limiting the presence of heavy gasoline components was found to significantly raise the octane number produced by the process.
    Type: Grant
    Filed: September 2, 1999
    Date of Patent: May 29, 2001
    Assignee: UOP LLC
    Inventors: Lawrence L. Upson, Julie E. Wesling
  • Patent number: 6187982
    Abstract: A process useful in steam cracking is disclosed for selectively converting a feed comprising C4+ dienes and oxygenate to a product comprising increased C2+ monoolefins and para-xylene levels by contacting said feed under diolefin conversion conditions with a catalyst comprising a porous crystalline material having a Diffusion Parameter for 2,2-dimethylbutane of about 0.1-100 sec−1 when measured at a temperature of 120° C. and a 2,2-dimethylbutane pressure of 60 torr (8 kPa), a temperature of 430° C. and 0.5 WHSV.
    Type: Grant
    Filed: October 15, 1999
    Date of Patent: February 13, 2001
    Assignee: Mobil Oil Corporation
    Inventors: Jeffrey S. Beck, Stephen H. Brown, William A. Weber
  • Patent number: 6150577
    Abstract: The invention includes a process of making a lubricating oil composition including: a process for making a high VI lubricating oil composition including the steps of (1) contacting a waste plastics feed including mainly polyethylene in a pyrolysis zone at pyrolysis conditions, whereby at least a portion of the waste plastics feed is cracked, thereby forming a pyrolysis zone effluent including 1-olefins and n-paraffins; (2) passing the pyrolysis zone effluent, including a heavy fraction and a middle fraction, the pyrolysis effluent middle fraction including 1-olefins, to a separations zone; where the pyrolysis effluent heavy fraction portion is separated from the pyrolysis effluent middle fraction; (3) passing the pyrolysis effluent heavy fraction to a hydrogenation zone; and (4) passing at least a portion of the hydrogenation zone effluent to a catalytic isomerization dewaxing zone, where at least a portion of the hydrogenation zone effluent is contacted with a isomerization dewaxing catalyst at isomerization
    Type: Grant
    Filed: December 30, 1998
    Date of Patent: November 21, 2000
    Assignee: Chevron U.S.A., Inc.
    Inventors: Stephen J. Miller, Gerald P. Huffman, Naresh Shah
  • Patent number: 6143940
    Abstract: The invention includes a process of making a wax composition including: a process for making a heavy wax composition including the steps of (1) contacting a waste plastics feed containing primarily polyethylene in a pyrolysis zone at sub-atmospheric pressure, whereby at least a portion of the waste plastics feed is cracked, thereby forming a pyrolysis zone effluent including 1-olefins and n-paraffins; and (2) passing the pyrolysis zone effluent to a hydrotreating zone, for contacting with a hydrotreating catalyst at catalytic conditions.
    Type: Grant
    Filed: December 30, 1998
    Date of Patent: November 7, 2000
    Assignees: Chevron U.S.A. Inc., University of Kentucky Research Foundation
    Inventors: Stephen J. Miller, Gerald P. Huffman, Naresh Shah
  • Patent number: 5481052
    Abstract: This invention relates to a process for cracking waste polymers in a fluidized bed reactor to produce vaporous products comprising primary products which can be further processed, eg in a steam cracker to produce olefins, characterized in that the vaporous products are treated to generate a primary product substantially free of a high molecular weight tail having molecular weights >700 prior to further processing. The removal of the high molecular weight tail minimizes fouling and prolongs the lifetime of the reactors used for further processing.
    Type: Grant
    Filed: April 8, 1993
    Date of Patent: January 2, 1996
    Assignee: BP Chemicals Limited
    Inventors: Stephen Hardman, Stephen A. Leng, David C. Wilson
  • Patent number: 5152883
    Abstract: Process for producing gasolines having improved RON and MON which consists in subjecting the LCO, HCO and CLO obtained by catalytic cracking of a heavy hydrocarbon feedstock, to a hydrogenation treatment and subjecting the obtained products to a new catalytic cracking and then recovering hydrocarbons boiling in the range of gasolines.
    Type: Grant
    Filed: March 22, 1991
    Date of Patent: October 6, 1992
    Assignee: Fina Research S.A.
    Inventors: Michel Melin, Jacques F. Grootjans
  • Patent number: 4990239
    Abstract: High octane gasoline and high quality distillate are co-produced by a hydrocracking light cycle oil from a catalytic cracking process under conditions of low to moderate hydrogen pressure and severity to produce a high octane, hydrocracked gasoline. The distillate fraction from the hydrocracker is separated to form a first fraction which boils immediately above the gasoline fraction and a second, higher boiling fraction which is withdrawn as product. The first distillate fraction is recycled, preferably to extinction, to the cracker to increase the paraffinic content of the higher boiling distillate product by removal of the hydroaromatic components in the recycled fraction. The recycled fraction may be mixed with fresh feed to the cracker or may be injected at a higher level in the cracking riser as a secondary feed injection. The paraffinic distillate product has a low sulfur content and a high cetane index and is useful as a road diesel fuel.
    Type: Grant
    Filed: December 13, 1989
    Date of Patent: February 5, 1991
    Assignee: Mobil Oil Corporation
    Inventors: W. Rodman Derr, Jr., Peter J. Owens, Michael S. Sarli
  • Patent number: 4985134
    Abstract: High octane gasoline and high quality distillate are co-produced by a hydrocracking process in which a catalytic cracking light cycle oil is hydrocracked under conditions of low to moderate hydrogen pressure and severity to produce a high octane, hydrocracked gasoline. The distillate fraction which boils immediately above the gasoline fraction is recycled to the hydrocracker to increase the paraffinic content of this fraction by partial saturation and cracking of the aromatics contained in it so as to form a paraffinic distillate of low sulfur and high cetane index which is useful as a road diesel fuel. A higher boiling distillate fraction of relatively lower aromaticity may also be produced for use as a low sulfur fuel oil. The recycled fraction may be cooled to provide quench for the hydrocracker.
    Type: Grant
    Filed: November 8, 1989
    Date of Patent: January 15, 1991
    Assignee: Mobil Oil Corporation
    Inventors: W. Rodman Derr, Jr., Peter J. Owens, Michael S. Sarli
  • Patent number: 4789457
    Abstract: A moderate pressure hydrocracking process in which a highly aromatic, substantially dealkylated feedstock is processed directly to high octane gasoline by hydrocracking over a catalyst, preferably comprising a large pore size, crystalline alumino-silicate zeolite hydrocracking catalyst such as zeolite Y together with a hydrogenation-dehydrogenation component. The feedstock which is preferably a light cycle oil has an aromatic content of at least 50, usually at least 60 percent and an API gravity not more than 25. The hydrocracking typically operates at 600-1000 psig at moderate to high conversion leavels to maximize the production of monocyclic aromatics which provide the requisite octane value to the product gasoline. The unconverted products from the hydrocracker are recyclied to the catalytic cracking unit to obtain further improvements in gasoline yield and octane.
    Type: Grant
    Filed: June 22, 1987
    Date of Patent: December 6, 1988
    Assignee: Mobil Oil Corporation
    Inventors: Ronald H. Fischer, Yun-Yang Huang, Rene B. LaPierre, Philip Varghese
  • Patent number: 4738766
    Abstract: A moderate pressure hydrocracking process in which a highly aromatic, substantially dealkylated feedstock having a boiling point in the range between 300.degree. and 650.degree. F. is processed directly to high octane gasoline by hydrocracking over a catalyst, preferably comprising a large pore size, crystalline alumino-silicate zeolite hydrocracking catalyst such as zeolite Y together with a hydrogenation-dehydrogenation component. The feedstock which is preferably a light cut light cycle oil has an aromatic content of at least 50, usually at least 60 percent and an API gravity not more than 25. The hydrocracking typically operates at 600-1000 psig at moderate to high conversion levels to maximize the production of monocyclic aromatics which provide the requisite octane value to the product gasoline.
    Type: Grant
    Filed: December 10, 1986
    Date of Patent: April 19, 1988
    Assignee: Mobil Oil Corporation
    Inventors: Ronald H. Fischer, Rene B. LaPierre, Peter J. Owens, Philip Varghese