Catalyst In Multiple Stages Patents (Class 208/74)
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Patent number: 11332680Abstract: According to one more embodiments, presently disclosed are processes for producing petrochemical products from a hydrocarbon material. The process may include separating the hydrocarbon material into at least a lesser boiling point fraction and a greater boiling point fraction, combining steam with the greater boiling point fraction upstream of the cracking of the greater boiling point fraction, cracking at least a portion of the greater boiling point fraction in the presence of a first catalyst to produce a first cracking reaction product, combining steam with the lesser boiling point fraction upstream of the cracking of the lesser boiling point fraction, cracking at least a portion of the lesser boiling point fraction in the presence of a second catalyst to produce a second cracking reaction product, and separating the petrochemical products from one or both of the first cracking reaction product or the second cracking reaction product.Type: GrantFiled: September 1, 2020Date of Patent: May 17, 2022Assignee: Saudi Arabian Oil CompanyInventors: Musaed Salem Al-Ghrami, Aaron Chi Akah, Abdennour Bourane
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Patent number: 11286431Abstract: Apparatus and processes herein provide for converting hydrocarbon feeds to light olefins and other hydrocarbons. The processes and apparatus include a conventional riser reactor in combination with a mixed flow (e.g., including both counter-current and co-current catalyst flows) fluidized bed reactor designed for maximizing light olefins production. The effluents from the riser reactor and mixed flow reactor are processed in a catalyst disengagement vessel, and the catalysts used in each reactor may be regenerated in a common catalyst regeneration vessel. Further, integration of the two-reactor scheme with a catalyst cooler provides a refinery the flexibility of switching the operation between the two-reactor flow scheme, a catalyst cooler only flow scheme, or using both simultaneously.Type: GrantFiled: July 1, 2020Date of Patent: March 29, 2022Assignee: LUMMUS TECHNOLOGY LLCInventors: Liang Chen, Peter Loezos, Bryan Tomsula, Rama Rao Marri, Zan Liu
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Patent number: 11230673Abstract: According to one or more embodiments, presently disclosed are processes for producing petrochemical products from a hydrocarbon material. The process may include separating the hydrocarbon material into at least a lesser boiling point fraction and a greater boiling point fraction, cracking at least a portion of the greater boiling point fraction in the presence of a first catalyst in an environment comprising less than 0.1 mol. % water to produce a first cracking reaction product, combining steam with the lesser boiling point fraction upstream of the cracking of the lesser boiling point fraction, cracking at least a portion of the lesser boiling point fraction in the presence of a second catalyst to produce a second cracking reaction product, and separating the petrochemical products from one or both of the first cracking reaction product or the second cracking reaction product.Type: GrantFiled: September 1, 2020Date of Patent: January 25, 2022Assignee: Saudi Arabian Oil CompanyInventors: Musaed Salem Al-Ghrami, Aaron Chi Akah, Abdennour Bourane
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Patent number: 10792636Abstract: The invention relates to a cover system (5) for a solid particle lining (3) comprising an articulated structure (11) and an annular casing (13) covering the articulated structure (11), the casing (13) being formed by metal plates (16, 17) sealingly mounted so as to be movable relative to each other, the articulated structure (11) having metal skirts (31) forming articulated concentric circles (33) for supporting the plates (16, 17) of the casing (13) and adapting to the deformations of the lining (3), and metal elements (35) forming articulated spacers (37) making it possible to maintain a spacing between the articulated concentric circles (33) and to adapt to the deformations of the lining (3).Type: GrantFiled: February 16, 2018Date of Patent: October 6, 2020Assignee: CREALYST-GROUPInventor: Bernard Poussin
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Patent number: 10646862Abstract: Systems and methods are provided for catalyst regeneration using a stoichiometric amount or less air for coke combustion.Type: GrantFiled: November 29, 2017Date of Patent: May 12, 2020Assignee: EXXONMOBIL RESEARCH AND ENGINEERING COMPANYInventors: Suriyanarayanan Rajagopalan, Mohsen N. Harandi
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Patent number: 10633606Abstract: The present application generally relates to the introduction of a renewable fuel oil as a feedstock into refinery systems or field upgrading equipment. For example, the present application is directed to methods of introducing a liquid thermally produced from biomass into a petroleum conversion unit; for example, a refinery fluid catalytic cracker (FCC), a coker, a field upgrader system, a hydrocracker, and/or hydrotreating unit; for co-processing with petroleum fractions, petroleum fraction reactants, and/or petroleum fraction feedstocks and the products, e.g., fuels, and uses and value of the products resulting therefrom.Type: GrantFiled: June 25, 2014Date of Patent: April 28, 2020Assignee: Ensyn Renewables, Inc.Inventors: Barry A. Freel, Robert G. Graham
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Patent number: 10344238Abstract: An oil-coal co-hydrotreating processing includes the following steps: pulverized coal, vacuum residue and recycle oil are mixed to prepare coal slurry. After mixed with hydrogen, catalyst and additive, oil-coal slurry is preheated into a slurry bed reactor with high reacting pressure for thermal cracking and hydrogenation reaction. After reaction, all the products go into the hot high pressure separator for separation of solid from the bottom and gas from the top. The gas obtained goes into the fixed bed reactor for further hydrocracking or refining, and the distillate obtained enter the fractionating tower. The vacuum gas oil from the bottom of fractionating tower is taken as recycle oil piped to the oil-coal slurry mixing device as solvent.Type: GrantFiled: February 4, 2016Date of Patent: July 9, 2019Assignee: CATECH TECHNOLOGY CO., LTD.Inventor: Suan Li
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Patent number: 9650312Abstract: A process for upgrading residuum hydrocarbons is disclosed. The process may include: contacting a residuum hydrocarbon fraction and hydrogen with a first hydroconversion catalyst in a first ebullated bed hydroconversion reactor system; recovering a first effluent from the first ebullated bed hydroconversion reactor system; solvent deasphalting a vacuum residuum fraction to produce a deasphalted oil fraction and an asphalt fraction; contacting the deasphalted oil fraction and hydrogen with a second hydroconversion catalyst in a second hydroconversion reactor system; recovering a second effluent from the second hydroconversion reactor system; and fractionating the first effluent from the first ebullated bed hydroconversion reactor system and the second effluent from the second hydroconversion reactor system to recover one or more hydrocarbon fractions and the vacuum residuum fraction in a common fractionation system.Type: GrantFiled: February 20, 2014Date of Patent: May 16, 2017Assignee: Lummus Technology Inc.Inventors: Mario C. Baldassari, Ujjal K. Mukherjee, Ann-Marie Olsen, Marvin I. Greene
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Patent number: 9446997Abstract: Provided is a method for producing aromatic hydrocarbons, by which a feedstock containing a hydrogenation-treated oil of a thermally cracked heavy oil obtainable from an ethylene production apparatus is brought into contact with a catalyst for monocyclic aromatic hydrocarbon production containing a crystalline aluminosilicate, and thereby aromatic hydrocarbons are produced. A raw material having an end point of the distillation characteristics of 400° C. or lower is used as the feedstock. The contact between the feedstock and the catalyst for monocyclic aromatic hydrocarbon production is carried out at a pressure of 0.1 MPaG to 1.5 MPaG.Type: GrantFiled: September 14, 2011Date of Patent: September 20, 2016Assignee: JX Nippon Oil & Energy CorporationInventors: Shinichiro Yanagawa, Ryoji Ida, Masahide Kobayashi
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Patent number: 9440894Abstract: A process for upgrading residuum hydrocarbons is disclosed. The process may include: contacting a residuum hydrocarbon fraction and hydrogen with a first hydroconversion catalyst in a first ebullated bed hydroconversion reactor system; recovering a first effluent from the first ebullated bed hydroconversion reactor system; solvent deasphalting a vacuum residuum fraction to produce a deasphalted oil fraction and an asphalt fraction; contacting the deasphalted oil fraction and hydrogen with a second hydroconversion catalyst in a second hydroconversion reactor system; recovering a second effluent from the second hydroconversion reactor system; and fractionating the first effluent from the first ebullated bed hydroconversion reactor system and the second effluent from the second hydroconversion reactor system to recover one or more hydrocarbon fractions and the vacuum residuum fraction in a common fractionation system.Type: GrantFiled: March 5, 2014Date of Patent: September 13, 2016Assignee: Lummus Technology Inc.Inventors: Mario C. Baldassari, Ujjal K. Mukherjee, Ann-Marie Olsen, Marvin I. Greene
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Patent number: 9434892Abstract: A two stage Fluid Catalytic Cracking process and an apparatus for simultaneous production of light olefins such as ethylene and propylene and middle distillate range hydrocarbons, wherein a first flow reactor, preferably a downer and a second flow reactor, preferably a riser are operating at varying reaction severities using different catalyst systems with the regenerated catalyst entering the reactors inlet through independent regenerators. Mild cracking of the fresh feedstock is carried out in the first flow reactor of short residence time and the effluent of first flow reactor is separated in an intermediate separator/fractionator followed by re-cracking of the C4 hydrocarbons and naphtha range hydrocarbons, preferably C5-150° C. from the second product separation section and unconverted hydrocarbons (370° C.+) of first flow reactor, in the second flow reactor at higher severity employing different catalyst system.Type: GrantFiled: July 4, 2011Date of Patent: September 6, 2016Assignee: INDIAN OIL CORPORATION LTD.Inventors: Ponoly Ramachandran Pradeep, Sadhullah Mukthiyar, Gadari Saidulu, Debasis Bhattacharyya, Vetterkunnel Kumaran Satheesh
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Patent number: 9234143Abstract: The present invention discloses catalytic cracking apparatus and process, which are useful for catalytic cracking of heavy oils with a high heavy oil conversion, a high propylene yield and low dry gas and coke yields.Type: GrantFiled: October 29, 2010Date of Patent: January 12, 2016Assignee: CHINA PETROLEUM & CHEMICAL CORPORATIONInventors: Chaogang Xie, Yongcan Gao, Weimin Lu, Jun Long, Yan Cui, Jiushun Zhang, Yinan Yang, Jianguo Ma, Zheng Li, Nan Jiang
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Patent number: 9228138Abstract: A process and apparatus for recovering cycle oil from FCC CSO is described. By feeding the additional cycle oil to a hydrocracking unit additional diesel, naphtha and petrochemical feedstock may be obtained. The additional cycle oil is obtained by vacuum separation of the CSO. The described process and apparatus can provide additional recovery for a refiner.Type: GrantFiled: April 9, 2014Date of Patent: January 5, 2016Assignee: UOP LLCInventors: Jibreel A. Qafisheh, Jill A. Bonucci, Xin X. Zhu, Boyd E. Cabanaw
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Patent number: 9144780Abstract: A reactor design and configuration and a process for the catalytic dehydration of propanol to propylene where the reactor train is comprised of a multi-stage single reactor vessel or multiple reactor vessels wherein each stage and/or vessel has different length, internal diameter, and volume than the other stages and/or vessels and in addition the stages and/or reactor vessels are connected in series or in parallel arrangement, preferably used with an improved means of introducing the propanol feedstock and a heat carrying inert gas to the improved reactor train.Type: GrantFiled: December 26, 2012Date of Patent: September 29, 2015Assignee: Petron Scientech, IncInventors: Hassan Taheri, Yogendra Sarin, Brian Ozero
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Patent number: 9147901Abstract: A fuel cell system (1) with a fuel cell unit (2) including at least one fuel cell (3), as well as an anode gas feed (11) including a reformer (12). A reduced deposit of hydrocarbons on an anode (5) of the fuel cell (3), especially in case of a cold start of the fuel cell system (1), is achieved when the anode gas feed (11) has a reduction device (14), which is arranged between the reformer (12) and the anode (5).Type: GrantFiled: July 16, 2012Date of Patent: September 29, 2015Assignee: Eberspächer Climate Control Systems GmbH & Co. KGInventors: Karsten Reiners, Christian Weiss, Andreas Kaupert
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Patent number: 9132415Abstract: A method of upgrading heavy oil in which the heavy oil is preheated to above a boiling point of water to remove water as steam and lighter fractions as vapors. The heavy oil passes downwardly through a series of sequential horizontal heat gradients in a temperature gradient reactor. A temperature of each sequential heat gradient progressively increases so that lighter fractions of the heavy oil vaporize with minimal cracking and heavier heavy oil fractions continue to fall by force of gravity downwards. As they pass through further sequential heat gradients of progressively increasing temperature, they tend to crack into lighter fractions in the presence of nascent hydrogen. Coke, formed from heavier heavy oil fractions generated and deposited on a fluidized catalytic bed a bottom of the temperature gradient reactor, is fluidized with superheated steam. The superheated steam generates the nascent hydrogen required to promote hydrogen reactions by indirect heated steam reforming and water-gas shift reactions.Type: GrantFiled: June 30, 2011Date of Patent: September 15, 2015Assignees: 1304338 Alberta Ltd., 1304342 Alberta Ltd.Inventors: Jose Lourenco, MacKenzie Millar
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Publication number: 20150136647Abstract: Methods and systems. For producing diesel arc provided. The method for producing diesel can include cracking a first hydrocarbon feed in a first riser under first cracking conditions to provide a first effluent containing a first light cycle oil, a heavy cycle oil, and a first bottoms and Fractionating at least a portion of the first effluent to separate the first bottoms and the heavy cycle oil from the first light cycle oil. The method can include cracking the separated first bottoms in a second riser under second cracking conditions to produce a second effluent containing a second light cycle oil and a second bottoms. The method can also include cracking the separated heavy cycle oil in the first riser under third cracking conditions to provide a third effluent and mixing the third effluent with the first hydrocarbon feed to provide the first cracking conditions.Type: ApplicationFiled: November 21, 2013Publication date: May 21, 2015Applicant: KELLOGG BROWN & ROOT LLCInventors: Gautham KRISHNAIAH, Yongchao Li, Yonglin Yang, Jesse Henry Williams, IV
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Patent number: 8920630Abstract: A system comprising a riser reactor comprising a gas oil feedstock and a first catalyst under catalytic cracking conditions to yield a riser reactor product comprising a cracked gas oil product and a first used catalyst; a intermediate reactor comprising at least a portion of the cracked gas oil product and a second catalyst under high severity conditions to yield a cracked intermediate reactor product and a second used catalyst; wherein the intermediate reactor feedstock comprises at least one of a fatty acid and a fatty acid ester.Type: GrantFiled: April 10, 2008Date of Patent: December 30, 2014Assignee: Shell Oil CompanyInventors: George A. Hadjigeorge, Weijian Mo, Colin John Schaverien
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Patent number: 8888991Abstract: Heavy gas oil components, coking process recycle, and heavier hydrocarbons in the delayed coking process are cracked in the coking vessel by injecting a catalytic additive into the vapors above the gas/liquid-solid interface in the coke drum during the coking cycle. The additive comprises cracking catalyst(s) and quenching agent(s), alone or in combination with seeding agent(s), excess reactant(s), carrier fluid(s), or any combination thereof to modify reaction kinetics to preferentially crack these components. The quenching effect of the additive can be effectively used to condense the highest boiling point compounds of the traditional recycle onto the catalyst(s), thereby focusing the catalyst exposure to these target reactants. Exemplary embodiments of the present invention can also provide methods to (1) reduce coke production, (2) reduce fuel gas production, and (3) increase liquids production.Type: GrantFiled: February 12, 2013Date of Patent: November 18, 2014Inventor: Roger G. Etter
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Patent number: 8778170Abstract: A process for producing light olefins and aromatics, which comprises reacting a feedstock with a catalytic cracking catalyst in at least two reaction zones, wherein the reaction temperature of at least one reaction zone downstream of the first reaction zone is higher than that of the first reaction zone and its weight hourly space velocity is lower than that of the first reaction zone. The spent catalyst is separated, from the reaction product vapor, regenerated, and then returned to the reactor. The reaction product vapor is separated to obtain the desired products, light olefins and aromatics. This process efficiently produces light olefins such as propylene, ethylene, etc from heavy feedstocks, wherein the yield of propylene exceeds 20% by weight, and produces aromatics such as toluene, xylene, etc at the same time.Type: GrantFiled: March 8, 2005Date of Patent: July 15, 2014Assignees: China Petroleum Chemical Corporation, Research Institute of Petroleum Processing SinopecInventors: Jun Long, Zhijian Da, Dadong Li, Xieqing Wang, Xingtian Shu, Jiushun Zhang, Hong Nie, Chaogang Xie, Zhigang Zhang, Wei Wang
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Publication number: 20140034551Abstract: A process is described for maximizing the FCC middle distillates comprising the use of two different converters, operating in a coordinated manner that seeks to maximize the production of LCO for diesel, generating a specified gasoline and reducing fuel oil production. Converter “A” operates with a low contact time in the riser, of 0.2 to 1.5 sec. (preferably from 0.5 to 1.0 sec.) making a higher reaction temperature possible even at low severity, from 510° C. to 560° C. (preferably from 530° C. to 550° C.) and with a catalyst suitable to the maximization of LCO. Converter “B” possesses a high activity catalytic system, suited to cracking naphtha and DO generated in the first converter. Preferably, converter “B” has two separate risers, allowing the reaction temperatures of each to be adjusted independently according to the range most recommended for maximizing the cracking of each of the streams: 530° C. to 560° C. for the DO riser and 540° C. to 600° C. for the naphtha riser.Type: ApplicationFiled: April 15, 2011Publication date: February 6, 2014Applicant: PETROLEO BRASILEIRO S.A. - PETROBRASInventors: Emanuel Freire Sandes, Leandro Morais Silva, William Richard Gilbert, Jose Geraldo Furtado Ramos
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Patent number: 8551324Abstract: The present invention describes a process for the production of gasoline in a fluid catalytic cracking unit having at least one principal reactor operating using feeds with a low Conradson Carbon and a high hydrogen content, said process comprising recycling a coking cut either to a side chamber branching off the stripper or within the stripper itself by means of a tubular vessel within said stripper.Type: GrantFiled: October 13, 2011Date of Patent: October 8, 2013Assignee: IFP Energies nouvellesInventors: Frederic Feugnet, Romain Roux
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Publication number: 20130248420Abstract: One exemplary embodiment can be a process for fluid catalytic cracking. The process can include sending a first catalyst from a first riser reactor and a second catalyst from a second riser reactor to a regeneration vessel having a first stage and a second stage. The first catalyst may be sent to the first stage and the second catalyst may be sent to the second stage of the regeneration vessel. Generally, the first stage is positioned above the second stage.Type: ApplicationFiled: March 21, 2012Publication date: September 26, 2013Applicant: UOP, LLCInventor: Paolo Palmas
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Patent number: 8394259Abstract: One exemplary embodiment can be a fluid catalytic cracking unit. The fluid catalytic cracking unit can include a first riser, a second riser, and a disengagement zone. The first riser can be adapted to receive a first feed terminating at a first reaction vessel having a first volume. The second riser may be adapted to receive a second feed terminating at a second reaction vessel having a second volume. Generally, the first volume is greater than the second volume. What is more, the disengagement zone can be for receiving a first mixture including at least one catalyst and one or more products from the first reaction vessel, and a second mixture including at least one catalyst and one or more products from the second reaction vessel. Typically, the first mixture is isolated from the second mixture.Type: GrantFiled: February 8, 2012Date of Patent: March 12, 2013Assignee: UOP LLCInventors: Paolo Palmas, Robert L. Mehlberg
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Publication number: 20130056393Abstract: The invention provides for a process and apparatus for simultaneous conversion of lighter and heavier hydrocarbon feedstocks into improved yields of light olefins in the range of C2 to C4, liquid aromatics in the range C6 to C8 mainly benzene, toluene, xylene and ethyl benzene and other useful products employing at least two different reactors operated in series with respect to catalyst flow and parallel with respect to feed flow under different regimes and process conditions with same catalyst system.Type: ApplicationFiled: March 30, 2011Publication date: March 7, 2013Applicant: INDIAN OIL CORPORATION LIMITEDInventors: Saravanan Subramani, Debasis Bhattacharyya, Reshmi Manna, Satyen Kumar Das, Tridib Sarkar, Santanam Rajagopal
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Patent number: 8372265Abstract: Undesirable gas oil components are selectively cracked or coked in a coking vessel by injecting an additive into the vapors of traditional coking processes in the coking vessel prior to fractionation. The additive contains catalyst(s), seeding agent(s), excess reactant(s), quenching agent(s), carrier(s), or any combination thereof to modify reaction kinetics to preferentially crack or coke these undesirable components that typically have a high propensity to coke. Exemplary embodiments of the present invention also provide methods to control the (1) coke crystalline structure and (2) the quantity and quality of volatile combustible materials (VCMs) in the resulting coke. That is, by varying the quantity and quality of the catalyst, seeding agent, and/or excess reactant the process may affect the quality and quantity of the coke produced, particularly with respect to the crystalline structure (or morphology) of the coke and the quantity & quality of the VCMs in the coke.Type: GrantFiled: November 19, 2007Date of Patent: February 12, 2013Inventor: Roger G. Etter
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Patent number: 8354018Abstract: A process is disclosed for catalytically converting two feed streams. The feed to a first catalytic reactor may be contacted with product from a second catalytic reactor to effect heat exchange between the two streams and to transfer catalyst from the product stream to the feed stream. The feed to the second catalytic reactor may be a portion of the product from the first catalytic reactor.Type: GrantFiled: November 9, 2009Date of Patent: January 15, 2013Assignee: UOP LLCInventors: Laura E. Leonard, Jibreel A. Qafisheh, Robert L. Mehlberg
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Publication number: 20130001129Abstract: A catalytic conversion process for increasing the cetane number barrel of diesel, in which contacting the feedstock oil with a catalytic cracking catalyst having a relatively homogeneous activity containing mainly the large pore zeolites in a catalytic conversion reactor, wherein the reaction temperature, residence time of oil vapors and weight ratio of the catalyst/feedstock oil are sufficient to obtain a reaction product containing from about 12 to about 60% by weight of a fluid catalytic cracking gas oil relative to the weight of the feedstock oil and containing a diesel; the reaction temperature ranges from about 420° C. to about 550° C.; the residence time of oil vapors ranges from about 0.1 to about 5 seconds; the weight ratio of the catalytic cracking catalyst/feedstock oil is about 1-about 10. The fluid catalytic cracking gas oil is fed into other unit for further treatment or is fed back to the initial catalytic conversion reactor.Type: ApplicationFiled: October 20, 2010Publication date: January 3, 2013Applicants: Research Institute of Petroleum Processing, Sinopec, CHINA PETROLEUM & CHEMICAL CORPORATIONInventors: Youhao Xu, Jianhong Gong, Congli Cheng, Shouye Cui, Zhihai Hu, Yun Chen
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Publication number: 20120222991Abstract: Novel catalytic compositions for cracking of crude oil fractions are disclosed. The catalytic compositions comprise a basic material. When used in a cracking process, preferably a FCC process, the resulting LCO and HCO fractions have desirably low aromatics levels. Further disclosed is a one-stage FCC process using the catalytic composition of the invention. Also disclosed is a two-stage FCC process for maximizing the LCO yield.Type: ApplicationFiled: April 2, 2012Publication date: September 6, 2012Applicant: ALBEMARLE NETHERLANDS B.V.Inventors: PAUL O'CONNOR, KING YEN YUNG, AVELINO CORMA CANOS, ELBERT ARJAN DE GRAAF, ERJA PÄIVI HELENA RAUTIAINEN
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Patent number: 8206574Abstract: A reactor process added to a coking process to modify the quantity or yield of a coking process product and/or modify certain characteristics or properties of coking process products.Type: GrantFiled: February 11, 2009Date of Patent: June 26, 2012Inventor: Roger G. Etter
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Patent number: 8137631Abstract: One exemplary embodiment can be a fluid catalytic cracking unit. The fluid catalytic cracking unit can include a first riser, a second riser, and a disengagement zone. The first riser can be adapted to receive a first feed terminating at a first reaction vessel having a first volume. The second riser may be adapted to receive a second feed terminating at a second reaction vessel having a second volume. Generally, the first volume is greater than the second volume. What is more, the disengagement zone can be for receiving a first mixture including at least one catalyst and one or more products from the first reaction vessel, and a second mixture including at least one catalyst and one or more products from the second reaction vessel. Typically, the first mixture is isolated from the second mixture.Type: GrantFiled: December 11, 2008Date of Patent: March 20, 2012Assignee: UOP LLCInventors: Paolo Palmas, Robert L. Mehlberg
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Patent number: 8076525Abstract: Process for the preparation of C3 and C4 olefins and gasoline by: (a) contacting in a fluidised bed reactor a light hydrocarbon feedstock with a first catalyst inventory comprising a medium pore size zeolite catalyst, wherein the first catalyst inventory is a fresh catalyst inventory; (b) combining at least part of the catalyst inventory as used in step (a) with one or more catalyst streams to form a second catalyst inventory comprising a medium pore size zeolite catalyst and a large pore size zeolite catalyst; (c) contacting a hydrocarbon feedstock with the second catalyst inventory in a reactor riser to form cracked products.Type: GrantFiled: December 19, 2005Date of Patent: December 13, 2011Assignee: Shell Oil CompanyInventors: George A. Hadjigeorge, Colin John Schaverien, Nicolaas Wilhelmus Joseph Waij
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Publication number: 20110108458Abstract: A process is disclosed for catalytically converting two feed streams. The feed to a first catalytic reactor may be contacted with product from a second catalytic reactor to effect heat exchange between the two streams and to transfer catalyst from the product stream to the feed stream. The feed to the second catalytic reactor may be a portion of the product from the first catalytic reactor.Type: ApplicationFiled: November 9, 2009Publication date: May 12, 2011Applicant: UOP LLCInventors: Laura E. Leonard, Jibreel A. Qafisheh, Robert L. Mehlberg
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Publication number: 20100324232Abstract: A system comprising a riser reactor comprising a gas oil feedstock and a first catalyst under catalytic cracking conditions to yield a riser reactor product comprising a cracked gas oil product and a first used catalyst, a intermediate reactor comprising at least a portion of the cracked gas oil product and a second catalyst under high severity conditions to yield a cracked gasoline product and a second used catalyst, and a recycle conduit to send at least a portion of the cracked gas oil product to the riser reactor.Type: ApplicationFiled: October 8, 2008Publication date: December 23, 2010Inventors: Weijian Mo, William Cross Glenn, George A. Hadjigeorge, Wallace Phelps Wilkins
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Patent number: 7803265Abstract: A process is disclosed for converting distillate to gasoline-range hydrocarbons using a two-stage catalyst system including a first catalyst containing platinum, palladium, or platinum and palladium, and an acidic support, and a second catalyst containing iridium and an inorganic oxide support, and optionally nickel.Type: GrantFiled: February 4, 2009Date of Patent: September 28, 2010Assignee: ConocoPhillips CompanyInventors: Tushar V. Choudhary, Paul F. Meier, Edward L. Sughrue, II, Walter E. Alvarez
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Publication number: 20100236980Abstract: One exemplary embodiment can be a process for fluid catalytic cracking. The process can include withdrawing a catalyst from a reaction vessel to replace a catalyst inventory over a period of about 10- about 35 days for maximizing propylene yield.Type: ApplicationFiled: March 20, 2009Publication date: September 23, 2010Inventors: Lawrence L. Upson, Brian W. Hedrick, Keith Allen Couch
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Publication number: 20100163455Abstract: A system comprising a riser reactor comprising a gas oil feedstock and a first catalyst under catalytic cracking conditions to yield a riser reactor product comprising a cracked gas oil product and a first used catalyst; a intermediate reactor comprising at least a portion of the cracked gas oil product and a second catalyst under high severity conditions to yield a cracked intermediate reactor product and a second used catalyst; wherein the intermediate reactor feedstock comprises at least one of a fatty acid and a fatty acid ester.Type: ApplicationFiled: April 10, 2008Publication date: July 1, 2010Inventors: George A. Hadjigeorge, Weijian Mo, Colin John Schaverien
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Patent number: 7736491Abstract: A process for the fluid catalytic cracking of mixed hydrocarbon feeds from different sources is described, such as feeds A and B of different crackability, the process being especially directed to obtaining light fractions such as LPG and comprising injecting feed A in the base of the riser reactive section and feed B, of lower crackability, at a height between 10% and 80% of the riser, with feed B comprising between 5% and 50% of the total processed feed. The process requires that the feeds present differences in the contaminant content, improved dispersion of feeds A and B and feed B injection temperature same or higher than that of feed A.Type: GrantFiled: May 19, 2004Date of Patent: June 15, 2010Assignee: Petroleo Brasileiro S.A. - PetrobrasInventors: Claudia Maria de Lacerda Alvarenga Baptista, Henrique Soares Cerqueira, Emanuel Freire Sandes
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Patent number: 7692057Abstract: The present invention provides a process for producing lower olefins by catalytic cracking a feedstock comprising an olefins-enriched mixture containing C4 or higher olefins and optionally an organic oxygenate compound. The technical problem mainly addressed in the present invention is to overcome the defects presented in the prior art including low yield and selectivity of lower olefins as the target products, and short regeneration period of catalyst.Type: GrantFiled: August 11, 2006Date of Patent: April 6, 2010Assignees: China Petroleum & Chemical Corporation, Shanghai Research Institute of Petrochemical Technology SinopecInventors: Zaiku Xie, Juntao Liu, Weimin Yang, Siqing Zhong, Yanhui Yuan, Huiming Zhang
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Patent number: 7584789Abstract: A method for producing a crude product is disclosed. Formation fluid is produced from a subsurface in situ heat treatment process. The formation fluid is separated to produce a liquid stream and a first gas stream. The first gas stream includes olefins. The liquid stream is fractionated to produce one or more crude products. At least one of the crude products has a boiling range distribution from 38° C. and 343° C. as determined by ASTM Method D5307. The crude product having the boiling range distribution from 38° C. and 343° C. is catalytically cracked to produce one or more additional crude products. At least one of the additional crude products is a second gas stream. The second gas stream has a boiling point of at most 38° C. at 0.101 MPa.Type: GrantFiled: October 20, 2006Date of Patent: September 8, 2009Assignee: Shell Oil CompanyInventors: Weijian Mo, Augustinus Wilhelmus Maria Roes, Vijay Nair
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Patent number: 7544333Abstract: A device for the fluidized bed cracking of a hydrocarbon charge using two reaction chambers linked together by a cooling particles transferrer, a fractionating column and conduits to supply the hydrocarbonated effluents from each of the two chambers to the fractionating column. The fractionating column has, internally, at least two different areas: a first partitioned fractionating area in the form of two compartments, each of which communicates with a second common fractionating area. The conduits for the supply of effluents from the first and the second reaction chamber terminate, respectively, in the first and second compartment of the partitioned fractionating area. A recycler and an injector are provided for recycling and injecting into one of the reaction chambers of at least one cut drawn off from the partitioned fractionating compartment of the effluents of the other reaction chamber.Type: GrantFiled: May 18, 2004Date of Patent: June 9, 2009Assignee: Total Raffinage Distribution S.A.Inventors: Marcellin Espeillac, Pierre Crespin
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Publication number: 20090107881Abstract: Methods and systems for hydrocracking a heavy oil feedstock using, a colloidally or molecularly dispersed catalyst (e.g., molybdenum sulfide) which provide for concentration of the colloidally dispersed catalyst within the lower quality materials requiring additional hydrocracking. In addition to increased catalyst concentration, the inventive systems and methods provide increased reactor throughput, increased reaction rate, and of course higher conversion of asphaltenes and lower quality materials. Increased conversion levels of asphaltenes and lower quality materials also reduces equipment fouling, enables the reactor to process a wider range of lower quality feedstocks, and can lead to more efficient use of a supported catalyst if used in combination with the colloidal or molecular catalyst.Type: ApplicationFiled: October 31, 2007Publication date: April 30, 2009Applicant: HEADWATERS TECHNOLOGY INNOVATION, LLCInventors: Robert K. Lott, Yu-Hwa Chang
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Patent number: 7517500Abstract: A process and apparatus are disclosed contacting hydrocarbon feed with catalyst in a reactor vessel under conditions more vigorous than bubbling bed conditions and preferably fast fluidized flow conditions. The vigorous conditions assure thorough mixing of catalyst and feed to suppress formation of dry gas and the promotion of hydrogen transfer reactions.Type: GrantFiled: December 8, 2004Date of Patent: April 14, 2009Assignee: UOP LLCInventor: David A. Lomas
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Publication number: 20090000984Abstract: Processes for maximizing low aromatics LCO yield and/or propylene yield in fluid catalytic cracking are disclosed. The processes employ catalytic compositions that comprise a predominantly basic material and little to no large pore zeolite.Type: ApplicationFiled: June 9, 2008Publication date: January 1, 2009Applicant: ALBEMARLE NETHERLANDS B.V.Inventors: Elbert Arjan De Graaf, Raymond Paul Fletcher, King Yen Yung, Erja Paivi Helena Rautiainen
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Patent number: 7462275Abstract: The present invention relates to a process for the conversion of hydrocarbon streams with 95% true boiling point less than 400° C. to very high yield of liquefied petroleum gas in the range of 45-65 wt % of feed and high octane gasoline, the said process comprises catalytic cracking of the hydrocarbons using a solid fluidizable catalyst comprising a medium pore crystalline alumino-silicates with or without Y-zeolite, non crystalline acidic materials or combinations thereof in a fluidized dense bed reactor operating at a temperature range of 400 to 550° C., pressure range of 2 to 20 kg/cm2 (g) and weight hourly space velocity in range of 0.1 to 20 hour?1, wherein the said dense bed reactor is in flow communication to a catalyst stripper and a regenerator for continuous regeneration of the coked catalyst in presence of air and or oxygen containing gases, the catalyst being continuously circulated between the reactor-regenerator system.Type: GrantFiled: July 20, 2004Date of Patent: December 9, 2008Assignee: Indian Oil Corporation LimitedInventors: Asit Kumar Das, Debasis Bhattacharyya, Gadari Saidulu, Satayen Kumar Das, Bandaru Venkata Hari P. Gupta, Ramakrishnan Ramanarayanan, Latoor Lal Saroya, Konduri Lakshminarayana, Marri Rama Rao, Vinod Ramchandra Upadhyay, Sukumar Mandal, Deepa Meghavathu, Arumugam Velayutham Karthikeyani, Wadharwa Ram Kalsi, Arvind Pratap Singh, Veena Bansal, Ashok Kumar Tiwari, Venkatachalam Krishnan, Satish Makhija, Sobhan Ghosh, Niranjan Raghunath Raje
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Patent number: 7427349Abstract: The present invention relates to the field of hydroprocessing, and more particularly relates to a process directed to fuels hydrocracking and distillate feed hydrofining. This process has at least two stages. A relatively unconverted hydrofined product may be removed prior to the second stage, providing flexibility. In another embodiment, fresh feed may be added prior to the second stage. In both embodiments, fuels production is maintained at a constant level.Type: GrantFiled: December 16, 2004Date of Patent: September 23, 2008Assignee: Chevron U.S.A. Inc.Inventors: Ujjal K. Mukherjee, Kevin L. Hofer, Darush Farshid
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Patent number: 7393992Abstract: Sudstituted the abstract with a new abstract as follows: The invention relates to a continuous process for separation a mixture of hydrocarbons which has beenobtained by extractive distillation of C4 fraction useing a selective solvent and the hydrocarbons from the fraction C4 which are more readily soluble in the selective solvent than are the butanes and the butenes. The mixture is fed into a first distillation column in which it is separated into a steam which is taken off at the top and comprises 1,3-butadiene, propyne, possibly further low boilers and possibly water and a bottom stream comprising 1,3-butadiene, 1,2-butadiene, acetylenes and possibly further high boilers, with the proportion of 1,3-butadiene in the bottom stream from the distillatin column being regulated in such a way that it is at least sufficiently high to dilute the acetylenes to outside the range in which there is a risk of spontaneous decomposition.Type: GrantFiled: July 23, 2003Date of Patent: July 1, 2008Assignee: BASF AktiengesellschaftInventors: Thomas Hill, Klaus Kindler, Bernd Heida
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Patent number: 7323099Abstract: A process for selectively producing C2 to C4 olefins from feedstock such as a gas oil or resid. The feedstock is reacted in a first stage comprising a fluid catalytic cracking unit wherein it is converted in the presence of a mixture of conventional large pore zeolitic catalyst and a medium pore zeolitic catalyst to reaction products, including a naphtha boiling range stream. The naphtha boiling range stream is introduced into a second stage where it is contacted with a catalyst containing from about 10 to about 50 wt. % of a crystalline zeolite having an average pore diameter less than about 0.7 nanometers at reaction conditions which include temperatures ranging from about 500 to about 650° C. and a hydrocarbon partial pressure from about 10 to about 40 psia (about 70 to about 280 kPa).Type: GrantFiled: November 19, 2004Date of Patent: January 29, 2008Assignee: ExxonMobil Chemical Patents Inc.Inventor: Brian Erik Henry
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Patent number: 7316773Abstract: The present invention relates to a catalytic cracking process and a device used in the process in particular, the present invention provides a catalytic cracking process, which comprises which comprises: 1) catalytic cracking a feedstock in the first riser for less than about 1.5 second and sending the resultant stream into the first separating device,; 2) catalytic cracking the recycle oil obtained from the first separating device in the second riser for less than about 1.Type: GrantFiled: March 15, 2004Date of Patent: January 8, 2008Assignees: Petrochina Company Limited, University of Petroleum ChinaInventors: Jianfang Zhang, An Ma, Honghong Shan, Chaohe Yang, Genlin Niu, Yongshan Tu, Feng Du, Yudong Sun, Zheng Li, Chunyi Li, Zhongxiang Han
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Patent number: 7300565Abstract: The invention relates to a process to prepare a microcrystalline wax and a middle distillate fuel by (a) hydrocracking/hydroisomerizing a Fischer-Tropsch product, wherein the weight ratio of compounds having at least 60 or more carbon atoms and compounds having at least 30 carbon atoms in the Fischer-Tropsch product is at least 0.2 and wherein at least 30 wt % of compounds in the Fischer-Tropsch product have at least 30 carbon atoms, (b) performing one or more distillate separations on the effluent of step (a) to obtain a middle distillate fuel fraction and a microcrystalline wax having an initial boiling point of between 500 and 600° C.Type: GrantFiled: July 17, 2003Date of Patent: November 27, 2007Assignee: Shell Oil CompanyInventor: Arend Hoek