Abstract: Systems and methods for the catalytic cracking of light hydrocarbons, such as naphtha, to form light olefins and aromatics is disclosed. The systems and methods may include a catalytic cracking process that involves mixing catalyst with a gas and then this mixture is used to contact a hydrocarbon feed, e.g., light straight run naphtha or heavy straight run naphtha. The hydrocarbon feed may be mixed with dry gas such as methane and/or hydrogen to dilute the hydrocarbon feed, before the hydrocarbon feed is contacted with the catalyst/gas mixture.

Abstract: A method for upgrading a hydrocarbon feed is disclosed. The method may be carried out in a pyrolysis furnace that may have at least two coils and at least two thermal zones. The method may include two operating or run modes that may be repeated in a cycle. In one run, upgrading may be carried out in one coil while decoking may be carried out in the other coil. After a predetermined amount of time, the streams of the two coils may be switched for a second run, such that decoking may be carried out in the coil in which upgrading was done in the first run and upgrading may be carried out in the coil in which decoking was done in the first run. The first and the second run are cyclically repeated one after the other.

Abstract: Methods and apparatus for fluid catalytic cracking (FCC) of a hydrocarbon feedstock includes a first reactor (1), a second reactor (2), and a regenerator assembly (3) shared and connected with the two reactors. The regenerator assembly (3) includes a regenerator vessel which has a partition (17) dividing the regenerator vessel into a first subunit (18) and a second subunit (19); a plurality of regenerator inlets for receiving a first spent catalyst and second spent catalyst by the first subunit (18) and the second subunit (19); a plurality of regenerator inlet for receiving a first spent catalyst and a second spent catalyst by the first subunit (18) and the second subunit (10) respectively; an air controller (15) to allow for has flow to an air distributor (16) for supply of the gas to the first subunit (18) and the second subunit (19) to combust coke deposited on the first and the second spent catalyst, separately, to a desired degree to generate a fully and a partially regenerated catalyst.

Abstract: A system is provided for the production of heavy crude oil from an undersea reservoir, and for the treatment of the crude oil to facilitate its transport. A floating body (12) which produces the heavy crude oil, carries a hydrocarbon cracking station (32) that cracks the heavy crude into light liquid and gaseous hydrocarbons, and that uses heat resulting from the cracking to produce pressured steam. The pressured steam is used to drive a steam-powered engine (72) (with pistons or a turbine) that drives an electrical generator (74) whose electricity powers the system.

Abstract: Heavy gas oil components, coking process recycle, and heavier hydrocarbons in the delayed coking process are cracked in the coking vessel by injecting a catalytic additive into the vapors above the gas/liquid-solid interface in the coke drum during the coking cycle. The additive comprises cracking catalyst(s) and quenching agent(s), alone or in combination with seeding agent(s), excess reactant(s), carrier fluid(s), or any combination thereof to modify reaction kinetics to preferentially crack these components. The quenching effect of the additive can be effectively used to condense the highest boiling point compounds of the traditional recycle onto the catalyst(s), thereby focusing the catalyst exposure to these target reactants. Exemplary embodiments of the present invention can also provide methods to (1) reduce coke production, (2) reduce fuel gas production, and (3) increase liquids production.

Abstract: Processes for production of olefins from hydrocarbon feedstocks are provided. In one aspect, the processes of the present invention utilize coils passing through a pyrolysis furnace to partially convert a hydrocarbon feedstock to olefins, followed by further conversion of the hydrocarbon feedstock in an adiabatic reactor. A portion of the coils in the pyrolysis furnace carry the hydrocarbon feedstock and the remainder carry steam only. After a selected period of time, the material flowing through the coils is switched. By flowing steam through the coils that had previously contained the hydrocarbon feedstock, on-line decoking can occur. In another aspect, a high temperature reactor is used to convert methane or natural gas to olefins.

Abstract: A process for producing light olefins and aromatics, which comprises reacting a feedstock with a catalytic cracking catalyst in at least two reaction zones, wherein the reaction temperature of at least one reaction zone downstream of the first reaction zone is higher than that of the first reaction zone and its weight hourly space velocity is lower than that of the first reaction zone. The spent catalyst is separated, from the reaction product vapor, regenerated, and then returned to the reactor. The reaction product vapor is separated to obtain the desired products, light olefins and aromatics. This process efficiently produces light olefins such as propylene, ethylene, etc from heavy feedstocks, wherein the yield of propylene exceeds 20% by weight, and produces aromatics such as toluene, xylene, etc at the same time.

Abstract: Biomass (e.g., plant biomass, animal biomass, and municipal waste biomass) is processed to produce useful products, such as fuels. For example, systems can use feedstock materials, such as cellulosic and/or lignocellulosic materials and/or starchy materials, to produce ethanol and/or butanol, e.g., by fermentation.

Abstract: The present invention is directed to the upgrading of heavy petroleum oils of high viscosity and low API gravity that are typically not suitable for pipelining without the use of diluents. The method comprises introducing a particulate heat carrier into an up-flow reactor, introducing the feedstock at a location above the entry of the particulate heat carrier, allowing the heavy hydrocarbon feedstock to interact with the heat carrier for a short time, separating the vapors of the product stream from the particulate heat carrier and liquid and byproduct solid matter, collecting a gaseous and liquid product mixture comprising a mixture of a light fraction and a heavy fraction from the product stream, and using a vacuum tower to separate the light fraction as a substantially bottomless product and the heavy fraction from the product mixture.

Abstract: Undesirable gas oil components are selectively cracked or coked in a coking vessel by injecting an additive into the vapors of traditional coking processes in the coking vessel prior to fractionation. The additive contains catalyst(s), seeding agent(s), excess reactant(s), quenching agent(s), carrier(s), or any combination thereof to modify reaction kinetics to preferentially crack or coke these undesirable components that typically have a high propensity to coke. Exemplary embodiments of the present invention also provide methods to control the (1) coke crystalline structure and (2) the quantity and quality of volatile combustible materials (VCMs) in the resulting coke. That is, by varying the quantity and quality of the catalyst, seeding agent, and/or excess reactant the process may affect the quality and quantity of the coke produced, particularly with respect to the crystalline structure (or morphology) of the coke and the quantity & quality of the VCMs in the coke.

Abstract: A reactor process added to a coking process to modify the quantity or yield of a coking process product and/or modify certain characteristics or properties of coking process products.

Abstract: A process is disclosed for contacting feed with mixed catalyst in a secondary reactor that is incorporated into an FCC reactor. The mixed catalyst used in the secondary reactor is regenerated catalyst from a regenerator that regenerates spent catalyst from an FCC reactor that is mixed with spent catalyst from either the FCC reactor or the secondary reactor. The mixing of spent and regenerated catalyst reduces the catalyst temperature and tempers catalyst activity to inhibit both thermal and catalytic cracking reactions.

Abstract: A system and process for upgrading hydrocarbons such as heavy oils includes a high temperature plasma reactor apparatus, in one or more vessels, into which the oils are introduced along with water, such as steam, to produce lighter hydrocarbon fractions, along with carbon monoxide and hydrogen, that flows to an additional stage where more hydrocarbons and water are introduced for further fractionating reactions facilitated by reaction of carbon monoxide and water to produce carbon dioxide and nascent, or prompt, free radicals of hydrogen. Heavy hydrocarbons upgraded can include heavy oils in the form of tar sands, oil shale, and oil residuals. The vessel or vessels can each contain a carbonaceous bed facilitating the described reactions and example embodiments include one vessel with the reactions performed in a single bed and, also, two vessels with the reactions performed in a carbonaceous bed portion in each vessel.

Abstract: A process is disclosed for converting distillate to gasoline-range hydrocarbons using a two-stage catalyst system including a first catalyst containing platinum, palladium, or platinum and palladium, and an acidic support, and a second catalyst containing iridium and an inorganic oxide support, and optionally nickel.

Abstract: A process for the fluid catalytic cracking of mixed hydrocarbon feeds from different sources is described, such as feeds A and B of different crackability, the process being especially directed to obtaining light fractions such as LPG and comprising injecting feed A in the base of the riser reactive section and feed B, of lower crackability, at a height between 10% and 80% of the riser, with feed B comprising between 5% and 50% of the total processed feed. The process requires that the feeds present differences in the contaminant content, improved dispersion of feeds A and B and feed B injection temperature same or higher than that of feed A.

Abstract: A process for independently and concurrently cracking at least two different hydrocarbon feedstocks to olefins. The process is carried out in a furnace for cracking hydrocarbon feed which has at least a first and second independent radiant cracking zone to produce a first cracked product and second cracked product that are separately withdrawn from the furnace.

Abstract: The present invention provides a process for producing lower olefins by catalytic cracking a feedstock comprising an olefins-enriched mixture containing C4 or higher olefins and optionally an organic oxygenate compound. The technical problem mainly addressed in the present invention is to overcome the defects presented in the prior art including low yield and selectivity of lower olefins as the target products, and short regeneration period of catalyst.

Abstract: A system and process for upgrading hydrocarbons such as heavy oils includes high temperature plasma reactor apparatus, in one or more vessels, into which the oils are introduced along with water, such as steam, to produce lighter hydrocarbon fractions, along with carbon monoxide and hydrogen, that flows to an additional stage where more hydrocarbons and water are introduced for further fractionating reactions facilitated by reaction of carbon monoxide and water to produce carbon dioxide and nascent, or prompt, free radicals of hydrogen. Heavy hydrocarbons upgraded can include heavy oils in the form of tar sands, oil shale, and oil residuals. The vessel or vessels can each contain a carbonaceous bed facilitating the described reactions and example embodiments include one vessel with the reactions performed in a single bed and, also, two vessels with the reactions performed in a carbonaceous bed portion in each vessel.

Abstract: The present invention is directed to the upgrading of heavy petroleum oils of high viscosity and low API gravity that are typically not suitable for pipelining without the use of diluents. It utilizes a short residence-time pyrolytic reactor operating under conditions that result in a rapid pyrolytic distillation with coke formation. Both physical and chemical changes taking place lead to an overall molecular weight reduction in the liquid product and rejection of certain components with the byproduct coke. The liquid product is upgraded primarily because of its substantially reduced viscosity, increased API gravity, and the content of middle and light distillate fractions. While maximizing the overall liquid yield, the improvements in viscosity and API gravity can render the liquid product suitable for pipelining without the use of diluents.

Abstract: The present invention is directed to the upgrading of heavy petroleum oils of high viscosity and low API gravity that are typically not suitable for pipelining without the use of diluents. It utilizes a short residence-time pyrolytic reactor operating under conditions that result in a rapid pyrolytic distillation with coke formation. Both physical and chemical changes taking place lead to an overall molecular weight reduction in the liquid product and rejection of certain components with the byproduct coke. The liquid product is upgraded primarily because of its substantially reduced viscosity, increased API gravity, and the content of middle and light distillate fractions. While maximizing the overall liquid yield, the improvements in viscosity and API gravity can render the liquid product suitable for pipelining without the use of diluents.

Abstract: The present invention relates to a process for the conversion of hydrocarbon streams with 95% true boiling point less than 400° C. to very high yield of liquefied petroleum gas in the range of 45-65 wt % of feed and high octane gasoline, the said process comprises catalytic cracking of the hydrocarbons using a solid fluidizable catalyst comprising a medium pore crystalline alumino-silicates with or without Y-zeolite, non crystalline acidic materials or combinations thereof in a fluidized dense bed reactor operating at a temperature range of 400 to 550° C., pressure range of 2 to 20 kg/cm2 (g) and weight hourly space velocity in range of 0.1 to 20 hour?1, wherein the said dense bed reactor is in flow communication to a catalyst stripper and a regenerator for continuous regeneration of the coked catalyst in presence of air and or oxygen containing gases, the catalyst being continuously circulated between the reactor-regenerator system.

Abstract: The present invention relates to a catalytic cracking process and a device used in the process in particular, the present invention provides a catalytic cracking process, which comprises which comprises: 1) catalytic cracking a feedstock in the first riser for less than about 1.5 second and sending the resultant stream into the first separating device,; 2) catalytic cracking the recycle oil obtained from the first separating device in the second riser for less than about 1.

Abstract: The present invention relates to a process for selectively producing C3 olefins from a catalytically cracked or thermally cracked naphtha stream by fractionating the naphtha feed to obtain at least a C6 rich fraction and feeding the C6 rich fraction into a reaction stage at a point wherein the residence time of the C6 rich fraction is minimized.

Abstract: The present invention relates to a process for selectively producing C3 olefins from a catalytically cracked or thermally cracked naphtha stream by fractionating the naphtha feed to obtain a C6 fraction and feeding the C6 fraction either in the riser downstream of the injection point for the reminder of the naphtha feed, in the stripper, and/or in the dilute phase immediately downstream or above the stripper of a process unit.

Abstract: According to this invention, there is provided a process and apparatus for catalytic cracking of various petroleum based heavy feed stocks in the presence of solid zeolite catalyst and high pore size acidic components for selective bottom cracking and mixtures thereof, in multiple riser type continuously circulating fluidized bed reactors operated at different severities to produce high yield of middle distillates, in the range of 50–65 wt % of fresh feed.

Abstract: The present invention provides a catalytic cracking reactor system and process in which a riser reactor is configured to have two sections of different radii in order to produced improved selectivity to propene and butenes as products.

Abstract: A process and apparatus are disclosed contacting hydrocarbon feed with catalyst in a reactor vessel under conditions more vigorous than bubbling bed conditions and preferably fast fluidized flow conditions. The vigorous conditions assure thorough mixing of catalyst and feed to suppress formation of dry gas and the promotion of hydrogen transfer reactions.

Abstract: A process and apparatus is disclosed for contacting feed with mixed catalyst in a secondary reactor that is incorporated into an FCC reactor. The mixed catalyst used in the secondary reactor is regenerated catalyst from a regenerator that regenerates spent catalyst from an FCC reactor that is mixed with spent catalyst from either the FCC reactor or the secondary reactor. The mixing of spent and regenerated catalyst reduces the catalyst temperature and tempers catalyst activity to inhibit both thermal and catalytic cracking reactions.

Abstract: The invention relates to a process for converting cycle oils produced in catalytic cracking reactions into olefin and naphtha. More particularly, the invention relates to a process for hydroprocessing a catalytically cracked light cycle oil, and then re-cracking it in an upstream zone of the primary FCC riser reactor.

Abstract: The invention relates to a process for converting cycle oils produced in catalytic cracking reactions into light olefin and naphtha. More particularly, the invention relates to a process for hydroprocessing a catalytically cracked light cycle oil in order to form a hydroprocessed cycle oil containing a significant amount of tetralins. The hydroprocessed cycle oil is then re-cracked in an upstream zone of the primary FCC riser reactor.

Abstract: The present invention relates to a catalytic cracking process and a device used in the process in particular, the present invention provides a catalytic cracking process, which comprises which comprises:

Abstract: A process for cracking, in a fluidized bed, a hydrocarbon charge wherein the cooling particles, which may optionally also be catalytic particles, circulate in two successive reaction chambers (1; 16), in each of which they are brought into contact with at least one cut of hydrocarbons, and the reaction effluents from each of the chambers are directed towards one and the same fractionating unit. The effluents from each of the reaction chambers (1; 16) are fractionated in part separately in one and the same partially partitioned fractionating unit, and at least one cut (12) obtained by separately fractionating the effluents from one of the two reaction chambers (1; 16) is, as a whole or in part, reinjected into the other chamber.

Abstract: An entrained bed or fluidised bed process for catalytic cracking of a hydrocarbon feed in two reaction zones is described, one zone (1) being in catalyst dropper mode, the other (2) being in catalyst riser mode. A feed (102) and catalyst from at least one regeneration zone (302) are introduced into the upper portion of the dropper zone, the feed and catalyst are circulated in accordance with a catalyst to feed weight ratio, C/O, of 5 to 20, the cracked gases are separated from the coked catalyst in a first separation zone (105), the cracked gases are recovered (107), the coked catalyst is introduced (110) into the lower portion of the riser zone (2), the coked catalyst and said feed are circulated in a C/O weight ratio of 4 to 8, the used catalyst is separated from the effluent produced in a second separation zone (203), the catalyst is stripped in a stripping zone (212), the effluent and stripping gases are recovered (206) and the used catalyst is recycled (7) to the regeneration zone.

Abstract: The present invention provides a catalytic cracking reactor system and process in which a riser reactor is configured to have two sections of different radii in order to produced improved selectivity to propene and butenes as products.

Abstract: A two-stage process for converting petroleum residua and other low value oils to high valued gasoline blendstocks and light olefins. The first stage is comprised of a thermal process unit containing a reaction zone comprised of a horizontal moving bed of fluidized hot particles operated at temperatures from about 500 to 600° C. and having a short vapor residence time, and the second stage is comprised of a catalytic conversion zone operated at a temperature of about 525° C. to about 650° C., and also having a short vapor residence time, preferably shorter than that of the first stage reaction zone.

Abstract: This invention relates to a process to produce propylene from a hydrocarbon feed stream, preferably a naphtha feed stream, comprising C5 and C6 components wherein a light portion having a boiling point range of 120° C. or less is introduced into a reactor separately from the other components of the feed stream.

Abstract: The present invention is a fluidized catalytic cracking process that incorporates a zoned riser reactor. The process provides an in-situ method for feed upgrading in a riser reactor. The process assists in the removal of undesirable contaminants, such as nitrogen, from FCC feedstocks.

Abstract: A two-stage process for converting petroleum residua and other low value oils to high valued gasoline blendstocks and light olefins. The first stage is comprised of a thermal process unit containing a reaction zone comprised of a horizontal moving bed of fluidized hot particles operated at temperatures from about 500 to 600° C. and having a short vapor residence time, and the second stage is comprised of a catalytic conversion zone operated at a temperature of about 525° C. to about 650° C., and also having a short vapor residence time, preferably shorter than that of the first stage reaction zone.

Abstract: A high efficiency FCC process obtains the necessary regenerated catalyst temperature for a principally thermal cracking stage by cracking a light feedstock such as naphtha or a middle distillate in a first riser that principally performs thermal cracking and then cracks a heavy FCC feed in a second riser with a blend of catalyst from the principally thermal cracking step and recycle catalyst from the heavy feed to provide the necessary coke content on the catalyst that will produce high regenerated catalyst temperatures. The high temperature of the regenerated catalyst in the first riser provides a convenient means of cracking naphtha under high severity conditions and then using the remaining activity of the contacted catalyst for the principally catalytic reaction of the heavier feed. A separate thermal cracked product may be recovered from an intermediate blending vessel downstream of the first riser.

Abstract: A continuous pyrolysis and decoking process and apparatus is described for the production of acetylenic compounds, in which hydrocarbons and steam are circulated in at least one tube (31) of a steam cracking reactor (30) and steam is circulated in at least one tube (32) of that reactor. The hydrocarbon effluent and steam then circulate in at least one row (1) of a pyrolysis reactor (40) and the decoking effluent comprising steam circulate in at least one other row (2) of that reactor (4) to effect decoking. A set of valves V1, V2, V11, V12 is used to alternate the pyrolysis step path and the decoking step path. The temperature in the steam cracking furnaces is lower than that in the pyrolysis reactor.

Abstract: In a process and apparatus for visbreaking a heavy hydrocarbon feedstock in the liquid state, whereby the feedstock is brought to an appropriate temperature to cause cracking of at least part of the hydrocarbons present, and is then introduced into the bottom of a soaker (3) wherein it travels from bottom to top, and is then discharged from the top of said soaker (3) and directed to a fractionation unit, the improvement wherein a preferably inert gas is injected into the hydrocarbon feedstock inside the soaker (3), in the vicinity of the soaker side walls, at least at the bottom of the soaker (3) and the gas is injected upward along the side walls of the soaker (3) and flows from bottom to top along said walls co-currently with the hydrocarbon feedstock.

Abstract: A process for increasing the yield of C.sub.3 and C.sub.4 olefins by injecting light cat naphtha together with steam into an upstream reaction zone of a FCC riser reactor. The products of the upstream reaction zone are conducted to a downstream reaction zone and combined with fresh feed in the downstream reaction zone.

Abstract: There is provided a process and a device with a convection zone (A) and a radiation zone (B) in a furnace (10), whereby the process includes: a first stage of precracking a feedstock of light hydrocarbons (1) and a second stage of final co-cracking of the mixture that is composed of this precracked light feedstock (7) and a feedstock of heavy hydrocarbons (2). The process further includes: separate heating of the two feedstock streams (1 and 2) in the convection zone (A), in which the preheating temperature of each feedstock stream remains below the initial cracking temperature in each case; precracking (5) of the preheated light hydrocarbons; mixing of precracked light hydrocarbon stream (8) while a mixed stream (9) is formed; intense heating of mixed stream (9) to a temperature that is higher than the initial cracking temperature by virtue of the fact that the mixture is introduced into the radiation zone (B) of the furnace (10); and cooling (15) of cracked gases outside the furnace (10).

Abstract: The invention relates to a process for catalytic cracking and the associated apparatus in which the cracking reaction takes place in two substantially vertical and successive reaction zones, the loads being introduced into the first zone where it circulates from the top downwards, then at least a part of the product obtained is introduced into a second reaction zone in which it circulates in an ascending fashion. A supplementary hydrocarbonated phase is advantageously introduced into the product entering the second zone. The invention applies particularly to heavy loads, with a U-shaped apparatus.

Abstract: A process and apparatus for low cracking or recracking of liquid hydrocarbons with FCC catalyst containing 0.2 to 1.5 wt % coke is disclosed. FCC naphtha, or a thermally or hydrocracked naphtha, contacts spent FCC catalyst in a naphtha recracking reactor for limited conversion to lighter products and an increase in octane number. Spent catalyst from the recracking reactor can be recycled to the FCC reactor without stripping or regeneration. Naphtha recracking products are preferably cooled, then used as an absorbent to recover gasoline boiling range products from the FCC main column overhead vapor. Use of spent catalyst and controlled conversion conditions minimizes overcracking of the light liquid and minimizes formation of heavy ends.

Abstract: Methods for the fluidized catalytic cracking of plural hydrocarbon feedstocks in a riser reactor are disclosed. The processes generally comprises contacting a relatively light hydrocarbon feedstock in a first reaction zone with a first catalyst stream comprising spent catalyst, contacting a relatively heavy hydrocarbon feedstock in a second reaction zone with a second catalyst stream comprising freshly regenerated catalyst, and introducing at least a portion of the effluent from the first reaction zone into the second reaction zone. The first reaction zone and the second reaction zone preferably comprise first and second riser reaction zones, respectively.

Abstract: Process for producing gasolines having improved RON and MON which consists in subjecting the LCO, HCO and CLO obtained by catalytic cracking of a heavy hydrocarbon feedstock, to a hydrogenation treatment and subjecting the obtained products to a new catalytic cracking and then recovering hydrocarbons boiling in the range of gasolines.

Abstract: A fluid catalytic cracking (FCC) process and apparatus which employs relatively more elutriatable catalyst particles comprising intermediate pore zeolite, particularly ZSM-5, and relatively less elutriatable catalyst particles comprising large pore zeolite, preferably zeolite Y. The process and apparatus employ a first stripping vessel which also separates a more elutriatable first portion of catalyst from a less elutriatable second portion of catalyst. The more elutriatable first portion passes to a second stripping vessel, and subsequently recycles to a fluid catalytic cracking reactor riser. The second portion of less elutriatable catalyst passes from the first stripping vessel to a fluid catalytic cracking regenerator vessel and, after being regenerated, recycles to the reactor riser. The more elutriatable first portion contains a higher ratio of intermediate pore catalyst particles to large pore catalyst particles than does the second portion.

Abstract: An improved process for stripping, or desorbing, entrained hydrocarbon material and, where present, sulfur-containing material, from a catalyst mixture recovered from a catalytic cracking reaction zone is described which comprises:(a) providing a quantity of catalyst mixture containing entrained hydrocarbon material and, optionally, sulfur-containing material, in at least one stripping zone in which a stripping gas removes said entrained hydrocarbon material and, where present, sulfur-containing material, the catalyst mixture comprising, as a first catalyst component, an amorphous and/or large pore crystalline cracking catalyst and, as a second catalyst component, a shape selective medium pore crystalline silicate zeolite catalyst, said first and second catalyst components being present in admixture within a common stripping zone or segregated into separate stripping zones; and,(b) conducting an exothermic reaction within the common stripping zone or within the separate stripping zone containing segregated se

Abstract: The present invention discloses a catalytic cracking process featuring at least one riser reactor, at least one stripping unit and at least one regenerator, which comprises:(a) cracking a C.sub.