With Blending Of Products Of Distillation With Each Other Or With Converted Products Patents (Class 208/93)
  • Patent number: 11965134
    Abstract: A process for the production of sustainable aviation fuel (SAF) with low carbon intensity. The jet fuel is produced from the reaction of hydrogen from the electrolysis of water with captured carbon dioxide. The hydrogen and carbon dioxide are reacted to product a stream comprising carbon monoxide. Hydrogen and carbon monoxide are reacted to produce n-alkanes. Alkanes are hydroisomerized to produce sustainable aviation fuel with low carbon intensity.
    Type: Grant
    Filed: February 2, 2022
    Date of Patent: April 23, 2024
    Assignee: Infinium Technology, LLC
    Inventors: Dennis Schuetzle, Robert Schuetzle, James Bucher, Matthew Caldwell, Anja Rumplecker Galloway, Orion Hanbury, Glenn McGinnis
  • Patent number: 11866654
    Abstract: A method for producing a diesel having improved cold flow properties, the method comprising the steps of introducing a crude oil to a distillation column, separating the crude oil in the distillation unit to produce a light gas oil, and a light vacuum gas oil, where the light gas oil has a T95% cut point in the range between 300 deg C. and 340 deg C., where the light vacuum gas oil has a T95% cut point in the range between 400 deg C. and 430 deg C., processing the light vacuum gas oil in the supercritical water unit to produce an upgraded vacuum gas oil, separating the upgraded vacuum gas oil in the fractionator to produce an upgraded light fraction, an upgraded light gas oil, and upgraded heavy fraction, introducing the upgraded light gas oil into a diesel pool, and blending the light gas oil into the diesel pool.
    Type: Grant
    Filed: April 8, 2021
    Date of Patent: January 9, 2024
    Assignee: Saudi Arabian Oil Company
    Inventors: Ki-Hyouk Choi, Vinod Ramaseshan, Mohnnad H. Alabsi
  • Patent number: 11708537
    Abstract: A process for producing light olefins comprising thermal cracking. Hydrocracked streams are thermally cracked to produce light olefins. A pyrolysis gas stream is separated into a light pyrolysis gas stream and a heavy pyrolysis gas stream. A light pyrolysis gas stream is separated into a normal paraffins stream and a non-normal paraffins stream. A normal paraffins stream is thermally cracked. The integrated process may be employed to obtain olefin products of high value from a crude stream.
    Type: Grant
    Filed: September 15, 2022
    Date of Patent: July 25, 2023
    Assignee: UOP LLC
    Inventors: Stanley S. Carp, Alan K. Bedell, David M. Banks, Keith Allen Couch, Gregory Funk, Cora Wang Ploentham, Stanley Joseph Frey
  • Patent number: 10407628
    Abstract: A process for the refining of crude oil with at least one atmospheric distillation unit for separating the various fractions, a sub-atmospheric distillation unit, a conversion unit of the heavy fractions obtained, a unit for enhancing the quality of some of the fractions obtained by actions on the chemical composition of their constituents and a unit for the removal of undesired components, where the sub-atmospheric distillation residue is sent to one of the conversion units, the conversion unit includes at least one hydroconversion reactor in slurry phase, into which hydrogen or a mixture of hydrogen and H2S, is fed, in the presence of a suitable dispersed hydrogenation catalyst with dimensions ranging from 1 nanometer to 30 microns.
    Type: Grant
    Filed: July 4, 2014
    Date of Patent: September 10, 2019
    Assignee: ENI S.p.A.
    Inventors: Giuseppe Bellussi, Vincenzo Piccolo, Alberto Maria Antonio Malandrino, Valentina Fabio, Giacomo Fernando Rispoli
  • Patent number: 9670427
    Abstract: Methods and oil refinery apparatuses are provided for producing hydrocarbons. A method includes fractionating a crude oil feedstock to produce a crude saturated stream and a residual stream. The residual stream is cracked in a cracking device to produce an unsaturated stream, and the unsaturated stream and the crude saturated stream are combined to produce a combined stream. The combined stream is fractionated to produce a refinery fuel gas stream.
    Type: Grant
    Filed: November 18, 2014
    Date of Patent: June 6, 2017
    Assignee: UOP LLC
    Inventors: Sathit Kulprathipanja, Christopher McCormick, Joseph M. Ritchie
  • Patent number: 9644889
    Abstract: A liquefied natural gas (LNG) facility that employs a system to remove incondensable material from one or more refrigeration cycles within the facility. One or more embodiments of the present invention can be advantageously employed in an open-loop refrigeration cycle to remove at least a portion of one or more high vapor pressure components that have accumulated in the refrigerant cycle over time. In addition, several embodiments can be advantageously employed to stabilize facility operation in the event of drastic changes to the concentration of the natural gas feed stream introduced into the facility.
    Type: Grant
    Filed: September 4, 2009
    Date of Patent: May 9, 2017
    Assignee: ConocoPhillips Company
    Inventors: Weldon L. Ransbarger, Megan V. Evans, Attilio J. Praderio, David B. Messersmith
  • Patent number: 9352297
    Abstract: Activated carbon\nickel oxide\zinc oxide (AC\NiO\ZnO) and activated carbon\zinc oxide (AC\ZnO) were prepared and used as adsorbents for removal of thiophene, benzothiophene (BT) and dibenzothiophene (DBT) as sulfur compounds from hydrocarbon materials such as diesel fuel. The materials exhibited an efficient and economical way for removing sulfur compounds due to its low-energy consumption, ambient operation temperature and atmospheric pressure. A simple regeneration method of the spent adsorbents.
    Type: Grant
    Filed: November 27, 2013
    Date of Patent: May 31, 2016
    Assignees: King Fahd University of Petroleum and Minerals, King Abdulaziz City for Science and Technology
    Inventors: Khalid R. Alhooshani, Abdullah A. Al Swat, Tawfik A. Saleh, Mohammad N. Siddiqui
  • Patent number: 9284856
    Abstract: The present invention is a gas turbine combined cycle power plant which generates electricity by fueling a gas turbine with crude oil or heavy oil and which is provided with a vacuum distillation unit which distills and extracts a light oil fraction from crude oil or heavy oil by keeping the interior thereof in an environment which lowers a boiling point of crude oil or heavy oil, and the vacuum distillation unit is provided with heaters which heat distillation materials by using low pressure steam and medium pressure steam generated in a gas turbine combined cycle.
    Type: Grant
    Filed: December 18, 2009
    Date of Patent: March 15, 2016
    Assignee: MITSUBISHI HITACHI POWER SYSTEMS, LTD.
    Inventors: Masaki Iijima, Toyoaki Komori, Ryotaro Kanai, Takeo Araki
  • Patent number: 9193646
    Abstract: A process for providing aromatics from a coal tar stream. A coal tar stream is provided, and the coal tar stream is fractionated into at least a naphtha range stream. The naphtha range stream is hydrotreated, and the hydrotreated naphtha range stream is separated to provide at least a naphthene rich stream. The naphthene rich stream is reformed or dehydrogenated to convert the naphthene. The dehydrogenated naphthene rich stream may be combined with a portion of a reformed crude oil hydrocarbon stream.
    Type: Grant
    Filed: May 21, 2015
    Date of Patent: November 24, 2015
    Assignee: UOP LLC
    Inventors: Matthew Lippmann, Paul T. Barger, Maureen L. Bricker, Joseph A. Kocal, Kurt M. Vanden Bussche
  • Patent number: 9023193
    Abstract: An improved delayed coking process utilizing a coking unit and a coking unit product fractionating column which includes the steps of: heating a mixture of a fresh whole crude oil feedstream and the bottoms from the coking unit product fractionator in a furnace to a coking temperature in the range of 480° C. to 530° C./896° F. to 986° F.
    Type: Grant
    Filed: May 23, 2011
    Date of Patent: May 5, 2015
    Assignee: Saudi Arabian Oil Company
    Inventor: Omer Refa Koseoglu
  • Publication number: 20150060333
    Abstract: A process for treating heavy oil to provide a treated heavy oil having a reduced density and viscosity, as well as an olefin content that does not exceed 1.0 wt. %. The process comprises separating the initial heavy oil into a first fraction, which in general contains lower-boiling components, and a second fraction. The second fraction comprises a heavy oil having a p-value of at least 5% greater than the p-value of the initial heavy oil prior to separating the initial heavy oil into the first fraction and the second fraction, and the second fraction has an aromaticity that is no more than 5% less than the aromaticity of the initial heavy oil prior to separating the initial heavy oil into the first fraction and the second fraction. The second fraction then is upgraded to reduce the density and viscosity of the heavy oil. After the second fraction is upgraded, it is recombined with at least a portion of the first fraction to provide a treated heavy oil having an olefin content that does not exceed 1.0 wt. %.
    Type: Application
    Filed: August 7, 2014
    Publication date: March 5, 2015
    Inventors: Michel Chornet, Christos Chronopoulos, Soumaine Dehkissia
  • Publication number: 20140367309
    Abstract: The present invention provides a process for upgrading a heavy hydrocarbon mixture, said process comprising: i) dividing said heavy hydrocarbon mixture into at least a first portion and a second portion, wherein said first portion comprises 10-45% wt of the heavy hydrocarbon mixture and said second portion comprises 90-55% wt of the heavy hydrocarbon mixture; ii) thermally upgrading said first portion of heavy hydrocarbon mixture in an upgrader to produce a lighter hydrocarbon mixture; and iii) mixing said lighter hydrocarbon mixture with a heavy hydrocarbon mixture to produce an upgraded hydrocarbon mixture, wherein, on entry to said upgrader, the composition of said first portion of heavy hydrocarbon mixture is identical to that of said second portion of heavy hydrocarbon mixture.
    Type: Application
    Filed: January 3, 2013
    Publication date: December 18, 2014
    Inventors: Harald Vindspoll, Knut Vebjørn Grande, Carsten Frithjof Sørlie, Marianne Haugan
  • Publication number: 20140353210
    Abstract: The present invention is directed to the upgrading of heavy petroleum oils of high viscosity and low API gravity that are typically not suitable for pipelining without the use of diluents.
    Type: Application
    Filed: August 13, 2014
    Publication date: December 4, 2014
    Inventors: Robert Graham, Barry Freel
  • Patent number: 8882991
    Abstract: In one aspect, the invention includes in a process for cracking a hydrocarbon feedstock comprising: a) feeding a hydrocarbon feedstock containing at least 1 wt % of resid components having boiling points of at least 500° C. to a furnace convection section to heat the feedstock; b) flashing the heated feedstock in a first flash separation vessel to create a first overhead stream and a first bottoms liquid stream; c) hydrogenating at least a portion of the first bottoms liquid stream to create a hydrogenated bottoms stream; d) flashing the hydrogenated bottoms stream in a second flash separation vessel to create a second overhead stream and a second bottoms liquid stream; e) cracking the first overhead stream and the second overhead stream in a cracking furnace to produce a pyrolysis effluent stream. In other embodiments, the process further comprises heating the hydrocarbon feedstock in step a) to a temperature within a range of from 315° C. to 705° C.
    Type: Grant
    Filed: August 21, 2009
    Date of Patent: November 11, 2014
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Keith H. Kuechler, Jennifer L. Bancroft, Paul F. Keusenkothen, Robert D. Strack
  • Patent number: 8597495
    Abstract: The described invention discloses an innovative solvent deasphalter and hydroconversion-processing configuration for converting bitumen or heavy oils to produce a transportable synthetic crude oil (SCO). The innovative processing scheme disclosed herein maximizes the synthetic crude oil yield at a minimal investment compared to currently known methods.
    Type: Grant
    Filed: February 12, 2010
    Date of Patent: December 3, 2013
    Assignee: IFP Energies Nouvelles
    Inventor: James J. Colyar
  • Patent number: 8431013
    Abstract: A process for refining or pre-refining a crude oil P is described in which P is fractionated into several fractions, wherein partial oxidation of an asphaltenic residue R1 derived from P is carried out to produce a synthesis gas SG1 with an H2/CO ratio of less than 1, steam cracking is carried out of an external light hydrocarbon fraction to produce a synthesis gas SG2 with a H2/CO ratio of more than 3; SG1 and SG2 are mixed to produce a synthesis gas SG with a H2/CO ratio in the range 1.2 to 2.5, and SG is converted by Fischer-Tropsch synthesis, then the waxes produced are converted into middle distillates. Preferably, a vacuum distillate VGO and/or a deasphalted oil DAO derived from P are hydrocracked mixed with the waxes. The invention also pertains to a facility for carrying out the process.
    Type: Grant
    Filed: July 6, 2007
    Date of Patent: April 30, 2013
    Assignee: IFP
    Inventors: Alexandre Rojey, Eric Lenglet
  • Publication number: 20130068661
    Abstract: The invention relates to a method for removing sulfur from crude oils using a catalytic hydrotreating process operating at moderate temperature and pressure and reduced hydrogen consumption. The process produces sweet crude oil having a sulfur content of between about 0.1 and 1.0 wt % in addition to reduced crude density. The method employs least two reactors in series, wherein the first reactor includes a hydroconversion catalyst and the second reactor includes a desulfurization catalyst.
    Type: Application
    Filed: November 8, 2012
    Publication date: March 21, 2013
    Applicant: SAUDI ARABIAN OIL COMPANY
    Inventor: SAUDI ARABIAN OIL COMPANY
  • Publication number: 20130062257
    Abstract: Deep desulfurization of hydrocarbon feeds containing undesired organosulfur compounds to produce a hydrocarbon product having low levels of sulfur, i.e., 15 ppmw or less of sulfur, is achieved by flashing the feed at a target cut point temperature to obtain two fractions. A low boiling temperature fraction contains refractory, sterically hindered sulfur-containing compounds, which have a boiling point at or above the target cut point temperature. A high boiling temperature fraction, having a boiling point below the target cut point temperature, is substantially free of refractory sulfur-containing compounds. The high boiling temperature fraction is contacted with isomerization catalyst, and the isomerized effluent and the low boiling temperature fraction are combined and contacted with a hydrotreating catalyst in a hydrodesulfurization reaction zone operating under mild conditions to reduce the quantity of organosulfur compounds to an ultra-low level.
    Type: Application
    Filed: July 27, 2012
    Publication date: March 14, 2013
    Inventor: Omer Refa Koseoglu
  • Publication number: 20130062255
    Abstract: Deep desulfurization of hydrocarbon feeds containing undesired organosulfur compounds to produce a hydrocarbon product having low levels of sulfur, i.e., 15 ppmw or less of sulfur, is achieved by first subjecting the entire feed to an extraction zone to separate an aromatic-rich fraction containing a substantial amount of the aromatic refractory and sterically hindered sulfur-containing compounds and an aromatic-lean fraction containing a substantial amount of the labile sulfur-containing compounds. The aromatic-rich fraction is contacted with isomerization catalyst, and the isomerized aromatic-rich fraction and the aromatic-lean fraction are combined and contacted with a hydrotreating catalyst in a hydrodesulfurization reaction zone operating under mild conditions to reduce the quantity of organosulfur compounds to an ultra-low level.
    Type: Application
    Filed: July 27, 2012
    Publication date: March 14, 2013
    Inventor: Omer Refa Koseoglu
  • Patent number: 8366912
    Abstract: A method for recovering base oil from waste lubricating oil by separating base oil range constituents from a waste lubricating oil mixture, thereafter separating higher quality base oil constituents and lower quality base oil constituents from the base oil recovered from the waste lubricating oil mixture and thereafter treating the lower quality base oil constituents to produce marketable base oil. The total base oil produced from a waste lubricating oil mixture by this process is greater than the quantity producible by previous processes using only base oil separation from the waste lubricating oil mixture or processes which use only treatment of the base oil recovered from the waste lubricating oil mixture to produce the product base oil.
    Type: Grant
    Filed: March 8, 2005
    Date of Patent: February 5, 2013
    Assignee: ARI Technologies, LLC
    Inventor: Martin R. MacDonald
  • Publication number: 20130015100
    Abstract: This invention relates to systems and methods for catalytic steam cracking of non-asphaltene containing heavy hydrocarbon fractions. The method enables upgrading heavy hydrocarbons to hydrocarbons capable of being transported through pipelines and/or a pretreated step before further treatment in an upgrading refinery, including the steps of separating the heavy hydrocarbon mixture into a light fraction, a full gasoil fraction and a vacuum residue fraction with or without at least partial reduction or asphaltenes; adding a catalyst to the full gasoil and/or to the blend of this with a reduced asphaltenes fraction and subjecting the catalyst-full gasoil and/or deasphalted oil fraction to catalytic steam cracking to form an effluent stream; separating the effluent stream into a gas stream and a liquid stream; and mixing the liquid stream with the light fraction and the vacuum residue fraction to form an upgraded oil. The system includes hardware capable of performing the method.
    Type: Application
    Filed: June 28, 2012
    Publication date: January 17, 2013
    Applicant: Nexen Inc.
    Inventors: Pedro Pereira Almao, Gustavo Luis Trujillo, Enzo Peluso, Carmen Galarraga, Clementina Sosa, Carlos Scott Algara, Francisco Lopez-Linares, Lante Antonio Carbognani Ortega, Nestor Gregorio Zerpa Reques
  • Patent number: 8277637
    Abstract: Systems and methods for processing one or more hydrocarbons are provided. One or more hydrocarbons can be selectively separated to provide one or more heavy deasphalted oils. At least a portion of the heavy deasphalted oil can be cracked using a fluidized catalytic cracker to provide one or more lighter hydrocarbon products.
    Type: Grant
    Filed: December 27, 2007
    Date of Patent: October 2, 2012
    Assignee: Kellogg Brown & Root LLC
    Inventors: Anand Subramanian, Raymond Floyd
  • Patent number: 8177964
    Abstract: A process of delayed coking with modified feedstock is described maximising the volume of diesel oil and minimising the volume of coke produced by means of feedstock which comprises, in a first embodiment of the invention: the bottom product (8) of the vacuum distillation tower (6), known in the prior art as vacuum residuum, and a fraction (7?) of heavy vacuum gas oil (7) obtained in the aforesaid vacuum distillation. In a second embodiment of the present invention the bottom residuum (5) proceeding from the atmospheric distillation tower (2), known in the prior art as atmospheric residuum, is employed as feedstock of a Delayed Coking Unit (9).
    Type: Grant
    Filed: February 1, 2007
    Date of Patent: May 15, 2012
    Assignee: Petroleo Brasileiro S.A.—Petrobras
    Inventors: Gloria Maria Gomes Soares, Natalie Jorge Goncalves, Francisco Carlos Da Costa Barros, Sergio Cunha De Lucena, Aline Voigt Nadolni, Sergio Nunes Da Costa
  • Patent number: 8152870
    Abstract: A method for producing biofuels is provided. A method of making biofuels includes dewatering substantially intact algal cells to make an algal biomass, sequentially adding solvent sets to the algal biomass, and sequentially separating solid biomass fractions from liquid fractions to arrive at a liquid fraction comprising neutral lipids. The method also includes esterifying the neutral lipids, separating a water miscible fraction comprising glycerin from a water immiscible fraction comprising fuel esters, carotenoids, and omega-3 fatty acids. The method also includes obtaining a C16 or shorter fuel esters fraction, a C16 or longer fuel ester fraction, and a residue comprising carotenoids and omega-3 fatty acids. The method includes hydrogenating and deoxygenating at least one of (i) the C16 or shorter fuel esters to obtain a jet fuel blend stock and (ii) the C16 or longer fuel esters to obtain a diesel blend stock.
    Type: Grant
    Filed: April 6, 2011
    Date of Patent: April 10, 2012
    Assignee: Heliae Development, LLC
    Inventor: Aniket Kale
  • Patent number: 8152994
    Abstract: Systems and methods for processing one or more hydrocarbons are provided. One or more hydrocarbon feedstocks can be selectively separated to provide one or more light deasphalted oils. At least a portion of the light deasphalted oil can be hydrocracked to provide one or more hydrocarbon products.
    Type: Grant
    Filed: December 27, 2007
    Date of Patent: April 10, 2012
    Assignee: Kellogg Brown & Root LLC
    Inventors: Anand Subramanian, Raymond Floyd, Odette Eng
  • Patent number: 8002968
    Abstract: A process for treating a heavy hydrocarbon feedstock is disclosed. The process involves separating the feedstock into a residue component and a light component, the residue component having a lower API gravity than the light component and treating at least a portion of the light component to produce a synthetic transport diluent suitable for combining with at least a portion of the residue component to produce a product which meets applicable criteria for pipeline transport.
    Type: Grant
    Filed: November 14, 2005
    Date of Patent: August 23, 2011
    Assignee: Statoil Canada Ltd.
    Inventors: Leonard F. Flint, Patrick B. Carlson, Gareth R. Crandall
  • Patent number: 7820033
    Abstract: A process for increasing ethylene yield in a cracked hydrocarbon is provided. A hydrocarbon feed stream comprising at least 90% by weight of one or more C4-C10 hydrocarbons can be heated to provide an effluent stream comprising at least 10% by weight propylene. The effluent stream can be selectively separated to provide a first stream comprising heavy naphtha, light cycle oil, slurry oil, or any combination thereof and a second stream comprising one or more C4-C10 hydrocarbons. The second stream can be treated to remove oxygenates, acid gases, water, or any combination thereof to provide a third stream comprising the one or more C4-C10 hydrocarbons. The third stream can be selectively separated to provide a product stream comprising at least 30% by weight propylene. At least a portion of the product stream can be recycled to the hydrocarbon feed stream to increase ethylene yield in the effluent stream.
    Type: Grant
    Filed: April 30, 2007
    Date of Patent: October 26, 2010
    Assignee: Kellogg Brown & Root LLC
    Inventors: Curtis N. Eng, Yonglin Yang
  • Publication number: 20100243522
    Abstract: This invention relates to a system for the preparation of a high quality gasoline through the recombination of catalytic hydrocarbon and its process. The characteristics are as follows: the upper part of the fractionator is connected with light petrol hydrogenation unit through the light petrol pipeline. The lower part of the fractionator is connected with the extractor through the heavy petrol pipeline. The upper part of the extractor directly extracts the product through the pipeline and the lower part of the extractor is connected to the light petrol pipeline behind the light petrol hydrogenation unit. Compared with the prior art, this invention has the following advantages: the volume of used catalyst is greatly reduced. In addition, the sulfur reduction and olefin reduction effect are remarkable by using the hydrogenation units with special catalysts and parameters regarding different petrol fractions.
    Type: Application
    Filed: November 5, 2008
    Publication date: September 30, 2010
    Inventor: Ranfeng Ding
  • Patent number: 7737317
    Abstract: Processing schemes and arrangements are provided for the processing a heavy hydrocarbon feedstock via hydrocarbon cracking processing with selected hydrocarbon fractions being obtained via fractionation-based product recovery.
    Type: Grant
    Filed: September 28, 2006
    Date of Patent: June 15, 2010
    Assignee: UOP LLC.
    Inventors: Michael A. Schultz, Jason T. Corradi
  • Patent number: 7708878
    Abstract: A process for producing a product slate, which includes at least three base oil grades having kinematic viscosities at 100° C. within the range between about 1.8 cSt and 30 cSt, from a waxy feed having an initial boiling point of about 340° C. or less and a final boiling point of about 560° C. or higher, said process comprising (a) isomerizing at least a portion of the waxy feed, whereby the amount of isoparaffins present are increased; (b) distilling a first portion of the isomerized waxy feed in light block mode operation into at least three base oil fractions having different boiling ranges; (c) distilling a second portion of the isomerized waxy feed in medium block mode operation into at least three base oil fractions having different boiling ranges; and (d) blending at least one base oil fraction produced from light block mode with at least one base oil fraction produced from medium block mode to produce a lubricating base oil blend meeting a target value for at least one pre-selected property.
    Type: Grant
    Filed: March 10, 2005
    Date of Patent: May 4, 2010
    Assignee: Chevron U.S.A. Inc.
    Inventors: John M. Rosenbaum, Brent K. Lok, Philip E. Quinnett, Christopher Allen Simmons
  • Patent number: 7666294
    Abstract: A fuel composition useful for operating a jet engine or a diesel engine containing a petroleum derived kerosene fuel and a Fischer-Tropsch derived kerosene fuel is provided. The Fischer-Tropsch derived kerosene fuel contains normal and iso-paraffins in a weight ratio of greater than 1:1 and/or the freeze point of the composition is lower than the freeze points of both of the petroleum derived kerosene fuel and the Fischer-Tropsch derived kerosene fuel.
    Type: Grant
    Filed: September 16, 2004
    Date of Patent: February 23, 2010
    Assignee: Shell Oil Company
    Inventors: Joanna Margaret Bauldreay, Richard John Heins, Johanne Smith
  • Patent number: 7651605
    Abstract: When a heavy fuel oil with a sulfur content of 1 percent by mass or lower is produced from a feedstock consisting of a heavy hydrocarbon oil derived from a heavy crude oil having an API degree of 30 or less and containing sulfur and metal components in amounts larger than those of ordinary crude oil, the conventional processes requires higher reaction temperature and was accompanied with a remarkably enhanced deactivation rate of the catalyst which results in a remarkable shortened lifetime thereof. Therefore, it is regarded as substantially impossible to treat the feedstock.
    Type: Grant
    Filed: February 27, 2007
    Date of Patent: January 26, 2010
    Assignee: Nippon Oil Corporation
    Inventors: Wataru Sahara, Yoshiaki Fukui
  • Patent number: 7618530
    Abstract: A method for the efficient conversion of heavy oil to distillates using sequential hydrocracking in the presence of both supported and colloidal catalyst immediately followed by a high temperature-short residence time thermal treatment. The hydrocracker reaction products or a heavy oil and hydrogen donor diluent may be advantageously heated by direct contact with high velocity combustion products.
    Type: Grant
    Filed: September 21, 2006
    Date of Patent: November 17, 2009
    Assignee: The BOC Group, Inc.
    Inventor: Donald P. Satchell, Jr.
  • Patent number: 7553404
    Abstract: A process for preparing at least two compositions suitable for production of gasoline, which process comprises: fractionating an alkylation product to produce a first cut boiling in the range 90-106° C., a second cut boiling at temperature lower than said first cut, and a third cut boiling at a temperature above said first Cut, blending at least 2% by volume of said first cut with at least 5% of a component selected from at least one of a paraffin, an aromatic hydrocarbon and an olefinic hydrocarbon, said component having a boiling point of 60-160° C., wherein not more than 5% of the total composition of hydrocarbon has a boiling point of more than 160° C.
    Type: Grant
    Filed: October 31, 2007
    Date of Patent: June 30, 2009
    Assignee: BP Oil International Limited
    Inventors: Alisdair Quentin Clark, Philip Howard, Anthony George William Parker
  • Patent number: 7491314
    Abstract: A process for the production of a pipeline-transportable crude oil from a bitumen feed, the process comprising: (1) dividing the bitumen feed into two fractions, the first fraction comprising between 20 and 80 wt % of the feed, the second fraction comprising between 80 and 20 wt % of the total feed, (the two fraction together forming 100 wt % of the feed), (2) distillation of the first fraction obtained in step (1) (preferably under vacuum) into a light fraction boiling below 380° C. (preferably the 450° C. fraction, more preferably the 510° C. fraction) and a residual fraction; (3) thermal cracking (of at least part of, preferably all of,) the residual fraction obtained in the distillation process described in step (2); (4) distillation of the product obtained in step (3) into one or more light fractions (boiling below 350° C.), optionally one or more intermediate fractions (boiling between 350 and 510° C.) and a heavy fraction (boiling above at least 350° C.
    Type: Grant
    Filed: July 1, 2004
    Date of Patent: February 17, 2009
    Assignee: Shell Oil Company
    Inventors: Petrus Johannes Walterus Maria Van Den Bosch, Franciscus Antonius Maria Schrijvers
  • Publication number: 20080264829
    Abstract: A process for increasing ethylene yield in a cracked hydrocarbon is provided. A hydrocarbon feed stream comprising at least 90% by weight of one or more C4-C10 hydrocarbons can be heated to provide an effluent stream comprising at least 10% by weight propylene. The effluent stream can be selectively separated to provide a first stream comprising heavy naphtha, light cycle oil, slurry oil, or any combination thereof and a second stream comprising one or more C4-C10 hydrocarbons. The second stream can be treated to remove oxygenates, acid gases, water, or any combination thereof to provide a third stream comprising the one or more C4-C10 hydrocarbons. The third stream can be selectively separated to provide a product stream comprising at least 30% by weight propylene. At least a portion of the product stream can be recycled to the hydrocarbon feed stream to increase ethylene yield in the effluent stream.
    Type: Application
    Filed: April 30, 2007
    Publication date: October 30, 2008
    Inventors: Curtis N. Eng, Yonglin Yang
  • Patent number: 7250107
    Abstract: For producing basic oils and in particular very high quality oils, i.e. oils possessing a high viscosity index (VI), a low aromatics content, good UV stability and a low pour point, from oil cuts having an initial boiling point higher than 340° C., possibly with simultaneous production of middle distillates (in particular gasoils and kerosene) of very high quality, i.e. having a low aromatics content and a low pour point, the invention provides a flexible procedure for producing oils and middle distillates from a charge containing heteroatoms, i.e. containing more than 200 ppm by weight of nitrogen, and more than 500 ppm by weight of sulphur. The procedure comprises at least one hydrorefining stage, at least one stage of catalytic dewaxing on zeolite, and at least one hydrofinishing stage.
    Type: Grant
    Filed: July 23, 2001
    Date of Patent: July 31, 2007
    Assignee: Institut Francais du Petrole
    Inventors: Eric Benazzi, Christophe Gueret, Pierre Marion, Alain Billon
  • Patent number: 7161052
    Abstract: A process is described for the valorization of a charge of hydrocarbons and for reducing the vapour pressure of said charge, comprising three steps: a step a) consisting of separating said charge of hydrocarbons into a fraction (O1) comprising essentially compounds containing 5 carbon atoms, including at least 2% by weight of pentenes, a step b) consisting of placing said fraction (O1) in contact with a cut of hydrocarbons (O2) at least partly comprising hydrocarbons having a number of carbon atoms between 6 and 10, including at least 2% by weight of olefins, and a step c) consisting of separating the effluents originating from step b) into a gasoline cut (?) the upper distillation point of which is less than 100° C. and a kerosene cut (?) having a distillation range between 100° C. and 300° C.
    Type: Grant
    Filed: September 3, 2003
    Date of Patent: January 9, 2007
    Assignee: Institut Francais de Petrole
    Inventors: Patrick Briot, Vincent Coupard, Alain Forestiere, Eric Llido, Thierry Poussereau
  • Patent number: 6759438
    Abstract: Methods for producing a substantially paraffinic Fischer-Tropsch product or a blended Fischer Tropsch product comprising a selected oxygenate concentration, and if required, a selected oxygenate concentration of specific individual oxygenates, are disclosed. The methods of the present invention measure oxygenate concentration using GC-AED. The oxygenate measurements obtained using the GC-AED may be used to adjust and control various processes used to produce, upgrade, or finish Fischer Tropsch products to provide Fischer Tropsch products with a selected oxygenate concentration, and if required, a selected oxygenate concentration of specific individual oxygenates.
    Type: Grant
    Filed: January 15, 2002
    Date of Patent: July 6, 2004
    Assignee: Chevron U.S.A. Inc.
    Inventors: Andrew Rainis, D J O'Rear
  • Patent number: 6589415
    Abstract: The present invention is directed to a method for hydroprocessing Fischer-Tropsch products. The invention in particular relates to an integrated method for producing liquid fuels from a hydrocarbon stream provided by Fischer-Tropsch synthesis. The method involves separating the Fischer-Tropsch products into a light fraction with normal boiling points below 700° F. and including predominantly C5-20 components and a heavy fraction with normal boiling points above 650° F. and including predominantly C20+ components. The heavy fraction is subjected to hydrocracking conditions, preferably through multiple catalyst beds, to reduce the chain length. The light fraction is used as all or part of a quench fluid between each catalyst bed.
    Type: Grant
    Filed: April 4, 2001
    Date of Patent: July 8, 2003
    Assignee: Chevron U.S.A., Inc.
    Inventors: Ben D. Smith, Krishniah Parimi, Richard O. Moore, Jr.
  • Patent number: 6562230
    Abstract: A process for preparing hydrocarbons in the lube base oil range, lube base oils and lube oil compositions from a fraction with an average molecular weight above a target molecular weight and a fraction with an average molecular weight below a target molecular weight via molecular averaging is described. The fractions can be obtained, for example, from Fischer-Tropsch reactions, and/or obtained from the distillation of crude oil. Molecular averaging converts the fractions to a product with a desired molecular weight, for use in preparing a lube oil composition. The product can optionally be isomerized to lower the pour point, and also can be blended with suitable additives for use as a lube oil composition.
    Type: Grant
    Filed: December 22, 1999
    Date of Patent: May 13, 2003
    Inventors: Dennis O'Rear, Russell R. Krug
  • Patent number: 6531515
    Abstract: An integrated process for improved hydrocarbon recovery from a natural gas resource is disclosed. A methane-rich stream, an LPG stream and optionally a C5+ stream are isolated from a natural gas source in a first separation zone and desulfurized. The methane-rich stream is converted to syngas and subjected to hydrocarbon synthesis, for example, Fischer-Tropsch synthesis. The products from the hydrocarbon synthesis typically include a C4− fraction, a C5-C20 fraction, and a C20+ wax fraction. These fractions are isolated in a second separation zone. The C4− fraction is recycled through the first separation zone to provide methane for conversion to synthesis gas and an additional LPG fraction. The C4− fraction can be treated, for example, with hydrotreating or hydroisomerization catalysts and conditions before or after the separation.
    Type: Grant
    Filed: February 20, 2001
    Date of Patent: March 11, 2003
    Assignee: Chevron U.S.A. Inc.
    Inventors: Richard O. Moore, Jr., Roger D. Van Gelder, Grant C. Hilton, Clive Jones, Randall B. Pruet
  • Patent number: 6379534
    Abstract: A method for lowering the cloud/pour point of a waxy crude oil in locations where size and/or weight of the facility may need to be limited (i.e. arctic zones and offshore). The major components of the system comprise a fractionation/quench tower and a reaction furnace. The furnace has sufficient heat input to initiate thermal cracking of wax and the fractionation tower is operated at a temperature sufficient to flash off light hydrocarbons but also low enough to quench thermal cracking reaction. The feed to the furnace comprises a portion of the bottoms stream from the tower and the furnace output is fed back into the tower bottom to be quenched.
    Type: Grant
    Filed: February 19, 1999
    Date of Patent: April 30, 2002
    Assignee: Halliburton Energy Services, Inc.
    Inventors: Gee S. Fung, Philip E. DePalm, Puneet Sharma
  • Patent number: 6361683
    Abstract: A catalytic hydrocracking process wherein a hydrocarbonaceous feedstock and a liquid recycle stream having a temperature greater than about 500° F. and saturated with hydrogen is contacted with hydrogen in a hydrocracking reaction zone at elevated temperature and pressure to obtain conversion to lower boiling hydrocarbons. The resulting hot, uncooled effluent from the hydrocracking reaction zone is hot hydrogen stripped in a stripping zone maintained at essentially the same pressure as the hydrocracking zone to produce a first gaseous hydrocarbonaceous stream and a first liquid hydrocarbonaceous stream. The first gaseous hydrocarbonaceous stream is passed through a post-treat hydrogenation zone to saturate aromatic compounds and at least partially condensed to produce a second liquid hydrocarbonaceous stream and a second hydrogen-rich gaseous stream.
    Type: Grant
    Filed: February 22, 2000
    Date of Patent: March 26, 2002
    Assignee: UOP LLC
    Inventor: Tom N. Kalnes
  • Patent number: 6350351
    Abstract: A plant for the vacuum distillation of liquids has a vacuum rectification column and a vacuum-producing device based on a liquid-gas jet apparatus. The plant is furnished additionally with a jet pump. A nozzle of the jet pump is connected to a pipeline for bleeding a liquid fraction from the column, an evacuated medium inlet of the jet pump is connected to an outlet of the liquid-gas jet apparatus and an outlet of the jet pump is connected to a separator of the vacuum-producing device. The plant provides more effective vacuum distillation of liquids.
    Type: Grant
    Filed: October 12, 1999
    Date of Patent: February 26, 2002
    Inventors: Serguei A. Popov, Mikhail V. Akimov
  • Patent number: 6238549
    Abstract: The invention concerns a process for converting a hydrocarbon feed in which said feed is treated in a distillation zone producing an overhead vapor distillate and a bottom effluent, associated with an at least partially external reaction zone comprising at least one catalytic bed, in which at least one reaction for converting at least a portion of at least one hydrocarbon is carried out in the presence of a catalyst and a gas stream comprising hydrogen, the feed for the reaction zone being drawn off at the height of at least one draw-off level and representing at least a portion of the liquid flowing in the distillation zone, at least part of the effluent from the reaction zone being re-introduced into the distillation zone at the height of at least one re-introduction level, so as to ensure continuity of the distillation, said process being characterized in that at least a portion of the vapor distillate is re-contacted with at least a portion of the feed introduced into the distillation zone.
    Type: Grant
    Filed: December 14, 1999
    Date of Patent: May 29, 2001
    Assignee: Institut Francais du Petrole
    Inventors: Jean-Charles Viltard, Jean-Louis Ambrosino, Blaise Didillon
  • Patent number: 6190535
    Abstract: A catalytic hydrocracking process wherein a denitrification and desulfurization reaction zone effluent is heat-exchanged with a hydrogen-rich gaseous stream and introduced into a hydrocracking zone. The resulting effluent from the hydrocracking zone is passed directly without cooling into a hot, high-pressure stripper utilizing a hot, hydrogen-rich gaseous stream at least a portion of which is heated during the heat exchange with the denitrification and desulfurization reaction zone effluent. The stripper overhead is partially condensed to produce a hydrogen-rich gaseous stream and a liquid stream containing hydrocracked hydrocarbon compounds. At least a portion of the stripper bottoms is recycled to the denitrification and desulfurization reaction zone.
    Type: Grant
    Filed: August 20, 1999
    Date of Patent: February 20, 2001
    Assignee: UOP LLC
    Inventors: Tom N. Kalnes, Richard K. Hoehn
  • Patent number: 6103105
    Abstract: A process for the reduction of sulphur content in a FCC gasoline includes fractionation of the FCC gasoline into three fractions: a light fraction comprising 50-80% of the FCC gasoline, an intermediate boiling fraction comprising 10-30% of the FCC gasoline, and a heavy fraction comprising 5-20% of the FCC gasoline. The heaviest fraction is hydrotreated in the first bed of a hydrotreater at conditions that result in essentially total removal of the sulphur. The effluent from the first bed is quenched with the intermediate fraction. The combined oil stream is hydrotreated in a second and final bed in the hydrotreater at conditions that ensure the required overall sulphur reduction.
    Type: Grant
    Filed: March 4, 1999
    Date of Patent: August 15, 2000
    Assignee: Haldor Topsoe A/S
    Inventors: Barry Cooper, Kim Gr.o slashed.n Knudsen
  • Patent number: 6017441
    Abstract: A process for converting a heavy hydrocarbon fraction comprises treating the hydrocarbon feed in a hydroconversion section in the presence of hydrogen, the section comprising at least one three-phase reactor containing at least one ebullated bed hydroconversion catalyst, operating in liquid and gas riser mode, said reactor comprising at least one means for removing catalyst from said reactor and at least one means for adding fresh catalyst to said reactor.
    Type: Grant
    Filed: October 1, 1997
    Date of Patent: January 25, 2000
    Assignee: Institut Francais du Petrole
    Inventors: Frederic Morel, Gerard Heinrich, Stephane Kressmann, Alain Billon, Jean-Luc Duplan, Thierry Chapus
  • Patent number: 5980730
    Abstract: A process for converting a heavy hydrocarbon fraction comprises treating the hydrocarbon feed in a hydroconversion section in the presence of hydrogen, the section comprising at least one three-phase reactor containing at least one ebullated bed hydroconversion catalyst, operating in liquid and gas riser mode, said reactor comprising at least one means for removing catalyst from said reactor and at least one means for adding fresh catalyst to said reactor.
    Type: Grant
    Filed: October 1, 1997
    Date of Patent: November 9, 1999
    Assignee: Institut Francais du Petrole
    Inventors: Frederic Morel, Thierry Chapus, Stephane Kressman, Jean-Luc Duplan, Alain Billon, Gerard Heinrich