Distillation Patents (Class 208/92)
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Patent number: 11946000Abstract: A hydrocarbon cracker stream is combined with recycle content pyrolysis oil to form a combined cracker stream and the combined cracker stream is cracked in a cracker furnace to provide an olefin-containing effluent. The r-pyoil can be fed to the cracker feed. More specifically the-pyoil is present in said feedstock in an amount of not more than 20% by weight, based on the total weight of the feedstock.Type: GrantFiled: May 22, 2020Date of Patent: April 2, 2024Assignee: Eastman Chemical CompanyInventors: Daryl Bitting, Kenny Randolph Parker, Michael Gary Polasek, David Eugene Slivensky, Xianchun Wu, Jerome Leonard Stavinoha, Jr.
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Patent number: 11850565Abstract: A reactor and process for the production of bio-diesel. The reactor includes one or more coiled reaction lines. The lines are positioned within a tank containing a heat transfer media such as molten salt, maintained at about 750° F. A pump circulates the media within the tank. An emulsion of alcohol; refined feed stock, including glycerides and/or fatty acids; and preferably water is pumped through the reaction lines at temperatures and pressures sufficient to maintain the alcohol in a super-critical state. The curvature of the coils, pump pulsing, and the flow rate of the emulsion keep the emulsion in a turbulent state while in the reactor, ensuring thorough mixing of the alcohol and feed stock. The alcohol reacts with the glycerides and fatty acids to form bio-diesel. The reaction is fast, efficient with regard to energy input and waste generation, and requires minimal alcohol.Type: GrantFiled: May 6, 2022Date of Patent: December 26, 2023Assignee: LOUISIANA ECO GREEN, L.L.C.Inventors: Kemper J McSpadden, Gerard M Thomassie
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Patent number: 11807819Abstract: Systems and methods for processing full range naphtha to produce light olefins are disclosed. The systems and methods include separating the full range naphtha into a light naphtha stream and a heavy naphtha stream and integrating a catalytic cracking with a naphtha reforming to process the light naphtha and heavy naphtha streams.Type: GrantFiled: June 24, 2019Date of Patent: November 7, 2023Assignee: SABIC GLOBAL TECHNOLOGIES B.V.Inventors: Khalid A. Al-Majnouni, Naif A. Al-Dalaan, Ahmad M. Al-Shehri, Nabil Al-Yasser, Ahmed Al-Zenaidi
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Patent number: 11613713Abstract: Systems and methods for crude oil separation and upgrading, which include the ability to reduce aromatic complex bottoms content in gasoline and higher-quality aromatic compounds. In some embodiments, aromatic complex bottoms are recycled for further processing. In some embodiments, aromatic complex bottoms are separated for further processing.Type: GrantFiled: January 26, 2021Date of Patent: March 28, 2023Assignee: Saudi Arabian Oil CompanyInventors: Omer Refa Koseoglu, Robert Peter Hodgkins, Bruce Richard Beadle, Vinod Ramaseshan, Rakan Sulaiman Bilaus
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Patent number: 11406958Abstract: The present disclosure relates generally processes and systems for converting a C2-C7 light alkanes feed to liquid transportation fuels or value-added chemicals. The feed is contacted with an aromatization catalyst at a temperature and pressure that selectively converts C4 and larger alkanes to an intermediate product comprising monocyclic aromatics and olefins. Following separation of the aromatics and C5+ hydrocarbons from the intermediate product, unconverted C2-C3 alkanes are thermally-cracked to produce olefins that are subsequently oligomerized to produce a liquid transportation fuel blend stock or value-added chemicals.Type: GrantFiled: November 11, 2020Date of Patent: August 9, 2022Assignee: Phillips 66 CompanyInventors: Jianhua Yao, Neal D. McDaniel, Bruce B. Randolph, Robert M. Walston, Anthony O. Baldridge, James A. Suttil, Soumen Kundu, Hong Xie, Steven E. Lusk
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Patent number: 10981847Abstract: The present disclosure relates to processes that catalytically convert a hydrocarbon feed stream predominantly comprising both isopentane and n-pentane to yield upgraded hydrocarbon products that are suitable for use either as a blend component of liquid transportation fuels or as an intermediate in the production of other value-added chemicals. The hydrocarbon feed stream is isomerized in a first reaction zone to convert at least a portion of the n-pentane to isopentane, followed by catalytic-activation of the isomerization effluent in a second reaction zone with an activation catalyst to produce an activation effluent. The process increases the conversion of the hydrocarbon feed stream to olefins and aromatics, while minimizing the production of C1-C4 light paraffins. Certain embodiments provide for further upgrading of at least a portion of the activation effluent by either oligomerization or alkylation.Type: GrantFiled: October 4, 2019Date of Patent: April 20, 2021Assignee: Phillips 66 CompanyInventors: Anthony O. Baldridge, Neal D. McDaniel, James A. Suttil, Edward C. Weintrob, Jianhua Yao, Bruce B. Randolph, Maziar Sardashti, Robert M. Walston, Steven E. Lusk
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Patent number: 10870807Abstract: Process scheme configurations are disclosed that enable conversion of crude oil feeds with several processing units in an integrated manner into petrochemicals. The designs utilize minimum capital expenditures to prepare suitable feedstocks for the steam cracker complex. The integrated process for converting crude oil to petrochemical products including olefins and aromatics, and fuel products, includes mixed feed steam cracking, fluid catalytic cracking and conversion of naphtha to chemical rich reformate. Feeds to the mixed feed steam cracker include light products from hydroprocessing zones within the battery limits, recycle streams from the C3 and C4 olefins recovery steps, and raffinate from a pyrolysis gasoline and FCC naphtha aromatics extraction zone within the battery limits. Chemical reformate from straight run naphtha streams is used as an additional feed to the aromatics extraction zone and or the mixed feed steam cracker.Type: GrantFiled: November 17, 2017Date of Patent: December 22, 2020Assignee: Saudi Arabian Oil CompanyInventors: Mohammed Saeed Al-Ghamdi, Bader BaHammam, Naif Al Osaimi, Sami Barnawi
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Patent number: 10851315Abstract: Processes for the production of a gasoline blend. A C7 portion of a naphtha stream is first isomerized to increase the branched, iso-paraffins, and then, the isomerized effluent is passed to a dehydrogenation reaction zone. In the dehydrogenation zone, the C7 saturated hydrocarbons are convert to C7 olefins. The C7 olefins have a higher octane number than the C7 saturated hydrocarbons, and the branched olefins have a higher octane number than the normal olefins. The C7 olefins can be blended in a gasoline pool. C5 and C6 hydrocarbons can be isomerized and dehydrogenated as well, separately or with the C7 components.Type: GrantFiled: June 27, 2019Date of Patent: December 1, 2020Assignee: UOP LLCInventors: Mark P. Lapinski, Rajeswar Gattupalli, Bryan K. Glover, Mohamed Shakur, Keith A. Couch, Michael W. Penninger, Soumendra Mohan Banerjee, Deepak Bisht, Gautam Pandey, Amit Sharma, Priyesh Jayendrakumar Jani, Nishesh Garg
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Patent number: 10717941Abstract: Process scheme configurations are disclosed that enable conversion of crude oil feeds with several processing units in an integrated manner into petrochemicals. The designs utilize minimum capital expenditures to prepare suitable feedstocks for the steam cracker complex. The integrated process for converting crude oil to petrochemical products including olefins and aromatics, and fuel products, includes mixed feed steam cracking and fluid catalytic cracking. Feeds to the mixed feed steam cracker include light products and naphtha from hydroprocessing zones within the battery limits, recycle streams from the C3 and C4 olefins recovery steps, and raffinate from a pyrolysis gasoline and FCC naphtha aromatics extraction zone within the battery limits.Type: GrantFiled: November 17, 2017Date of Patent: July 21, 2020Assignee: Saudi Arabian Oil CompanyInventors: Mohammed Saeed Al-Ghamdi, Bader BaHammam, Naif Al Osaimi, Sami Barnawi
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Patent number: 10421914Abstract: A method comprising a combination and sequential methods to: a.-)Produce solid vacuum residue, b.-) Melt the solid vacuum residue, and c.-)Heat the melted Solid Vacuum residue. This invention applies to any single or mixture of hydrocarbons including one or more heavy crude oils, extra heavy crude oils, tar sands and/or bitumens, (named heavy feedstocks). The heavy feedstock is processed in the production field or a nearby location using atmospheric, vacuum distillation and a solid forming unit, to produce liquid distillates and a solid vacuum residue resulting from a deep cut point of the heavy vacuum gasoil. The Solid Vacuum Residue is melted and heated at the destination to be used as feedstocks in refineries deep conversion units to optimize operations and economics.This invention reduces the diluent imports at the heavy feedstocks production fields used for its production and/or its transportation.Type: GrantFiled: March 6, 2016Date of Patent: September 24, 2019Inventor: David Ledo Perez
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Patent number: 9809764Abstract: A process for producing high yields of higher quality (API Group II, Group III?) lubricating oil basestock fractions which allows the production of two or more types of high quality lubes in continuous mode (no blocked operation mode) without transition times and feed or intermediate product tankage segregation. Two consecutive hydroprocessing steps are used: the first step processes a wide cut feed at a severity needed to match heavy oil lube properties. The second step hydroprocesses a light oil after fractionation of the liquid product from the first step at a severity higher than for the heavy oil fraction. The two hydroprocessing steps will normally be carried out in separate reactors but they may be combined in a single reactor which allows for the two fractions to be processed with different degrees of severity.Type: GrantFiled: March 10, 2016Date of Patent: November 7, 2017Assignee: EXXONMOBIL RESEARCH AND ENGINEERING COMPANYInventors: Benjamin S. Umansky, Teck-Mui Hoo, Richard A. Demmin, Fengrong Chen, James W. Gleeson, Suisheng M. Dou, Tomas R. Melli, Michael C. Clark
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Patent number: 9783751Abstract: The invention relates to a process for the conversion of hydrogen and one or more oxides of carbon to hydrocarbons, which process comprises: contacting hydrogen and one or more oxides of carbon with a catalyst in a reaction zone; removing from the reaction zone an outlet stream comprising unreacted hydrogen, unreacted one or more oxides of carbon and one or more hydrocarbons and feeding the outlet stream to a separation zone in which the outlet stream is divided into at least three fractions, in which; a first fraction predominantly comprises unreacted hydrogen, unreacted one or more oxides of carbon and hydrocarbons having from 1 to 4 carbon atoms; a second fraction predominantly comprises hydrocarbons having 5 to 9 carbon atoms, at least a portion of which hydrocarbons having from 5 to 9 carbon atoms are olefinic; and a third fraction predominantly comprises hydrocarbons having 10 or more carbon atoms; characterized in that at least a portion of the second fraction is recycled to the reaction zone.Type: GrantFiled: April 5, 2013Date of Patent: October 10, 2017Assignee: IGTL TECHNOLOGY LTDInventor: Richard John Hyman
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Patent number: 9453169Abstract: A process for converting Fischer-Tropsch liquids and waxes into lubricant base stock and/or transportation fuels is disclosed. The process includes the steps of feeding a Fischer-Tropsch wax to a first isomerization unit to produce an isomerized Fischer-Tropsch wax product; combining a Fischer-Tropsch liquid with the isomerized Fischer-Tropsch wax product to create a mixture of the Fischer-Tropsch liquid and the Fischer-Tropsch wax product; and feeding the mixture to a fractionation column to separate the mixture into a lubricant base stock fraction and at least one transportation fuel fraction.Type: GrantFiled: September 13, 2013Date of Patent: September 27, 2016Assignee: UOP LLCInventors: Kenneth J. Stippich, Jr., Vasant P. Thakkar, John A. Petri
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Patent number: 9017545Abstract: Disclosed is a process for hydrotreating inferior naphtha fraction, comprising: (1) warming a recycle oil in a heating device; (2) mixing the inferior naphtha fraction with the recycle oil before and/or after the heating device; and (3) feeding the mixture of the inferior naphtha fraction and the recycle oil into a separating unit, wherein the gas-liquid separation is realized at least to obtain a gas phase and a liquid phase, wherein the gas phase comprises gasified inferior naphtha, wherein the gas phase enters a hydrotreating reactor to undergo hydrotreating, and wherein part of the liquid phase circulates to the heating device as the recycle oil; wherein warming of the recycle oil is controlled to ensure the temperature of gas phase from the separator at least reaches the inlet temperature of the hydrotreating reactor. Comparing with the prior art, the inventive process effectively solves the coking problem of the hydrogenating unit for inferior naphtha fraction.Type: GrantFiled: October 26, 2012Date of Patent: April 28, 2015Assignees: China Petroleum & Chemical Corporation, Fushun Research Institute of Petroleum and Petrochemicals, SinopecInventors: Ying Zhang, Baozhong Li, Ronghui Zeng, Youliang Shi
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Patent number: 8932451Abstract: Methods are provided for processing crude oil feeds with reduced or minimized energy usage, reduced or minimized numbers of processing steps, improved allocation of hydrogen, and reduced or minimized formation of low value products. The methods reduce or minimize the use of vacuum distillation, and in many aspects reduce or minimize the use of both atmospheric and vacuum distillation. The methods also reduce or minimize the use of coking and fluid catalytic cracking processes.Type: GrantFiled: August 29, 2012Date of Patent: January 13, 2015Assignee: ExxonMobil Research and Engineering CompanyInventors: Ramon A. Strauss, Stephen Harold Brown, Donald E. Stratton, Stefan Maria Willy Ceulemans
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Publication number: 20140353209Abstract: One exemplary embodiment can be a process for treating a naphtha stream. The process may include providing the naphtha stream to a fractionation zone. The fractionation zone may include a fractionation column producing a first stream having one or more C5? hydrocarbons and a second stream withdrawn at a lower elevation on the fractionation column than the first stream and having one or more C5+ hydrocarbons, and sending at least a portion of the second stream to an aromatics complex for producing at least one of benzene, toluene, and para-xylene.Type: ApplicationFiled: May 29, 2013Publication date: December 4, 2014Inventor: Steven F. Zink
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Patent number: 8888992Abstract: A process for improving flow properties of crude may include processing a first crude stream, which may in turn include cracking the first crude stream with fresh catalyst to form a cracked stream and spent catalyst, and then mixed with an unprocessed second stream. The spent catalyst may be regenerated to form fresh catalyst, which may then be recycled. At least part of the cracked stream may be mixed with a second crude stream. A ratio of the second crude stream to the first crude stream may be between about 0.5:1 and about 9:1. A ratio of part of the cracked stream to add to the second crude stream may be selected to achieve a API gravity of at least about 18. The first crude stream may be heated and stripped before being cracked.Type: GrantFiled: August 9, 2005Date of Patent: November 18, 2014Assignee: UOP LLCInventors: Brian W. Hedrick, James F. McGehee, Selman Z. Erisken, Jibreel A. Qafisheh
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Patent number: 8752623Abstract: In solvent-dominated recovery processes for recovering In situ oil, including bitumen, the produced fluid stream includes oil and solvent. The solvent is preferably recovered and reinjected into the reservoir. In previously described methods, solvent is removed from the oil/solvent mixture. In the present method, the oil/solvent mixture is first separated into a heavier stream and a lighter stream from which solvent is independently removed.Type: GrantFiled: January 10, 2011Date of Patent: June 17, 2014Assignee: ExxonMobil Upstream Research CompanyInventors: Eric B. Sirota, Owen J. Hehmeyer
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Patent number: 8721872Abstract: A method for thermally cracking an organic acid containing hydrocarbonaceous feed wherein the feed is first processed in a vaporization step, followed by thermal cracking.Type: GrantFiled: March 31, 2009Date of Patent: May 13, 2014Assignee: Equistar Chemicals, LPInventors: Donald H. Powers, Robert S. Bridges, Kenneth M. Webber
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Patent number: 8709234Abstract: A process in which the paraffinic effluent derived from a Fischer-Tropsch synthesis unit is separated to obtain a heavy C5+ fraction, said heavy fraction then being hydrogenated in the presence of a hydrogenation catalyst at a temperature in the range 80° C to 200° C, at a total pressure in the range 0.5 to 6 MPa, at an hourly space velocity in the range 1 to 10 h-1, and at a hydrogen flow rate corresponding to a hydrogen/hydrocarbons volume ratio in the range 5 to 80 NI/I/h, the liquid hydrogenated effluent then being brought into contact with a hydroisomerization/hydrocracking catalyst, with no prior separation step, the hydroisomerized/hydrocracked effluent then being distilled to obtain middle distillates and possibly oil bases.Type: GrantFiled: June 3, 2008Date of Patent: April 29, 2014Assignees: IFP Energies Nouvelles, ENI S.p.A.Inventors: Aurelie Dandeu, Nathalie Marchal-George, Vincent Coupard, Eric Caprani, Jean Cosyns, Damien Douziech, Stephane Fedou
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Patent number: 8696888Abstract: The invention concerns integration of hydroprocessing and steam cracking. A feed comprising crude or resid-containing fraction thereof is severely hydrotreated and passed to a steam cracker to obtain an olefins product.Type: GrantFiled: October 17, 2006Date of Patent: April 15, 2014Assignee: ExxonMobil Chemical Patents Inc.Inventors: Paul F. Keusenkothen, Megan L. Renstrom, Julian A. Wolfenbarger, Stephen H. Brown, John S. Buchanan
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Publication number: 20140083906Abstract: Provided is a process for cracking a hydrocarbon feedstock. The process having the steps of (a) continuously passing the feedstock through a vapor-liquid separator in which the feedstock is separated into a volatile stream and a non-volatile stream; (b) continuously passing the non-volatile stream to a cracker; and (c) continuously recycling a portion of the volatile stream to the feedstock. There is also an apparatus for cracking a hydrocarbon feedstock.Type: ApplicationFiled: September 27, 2012Publication date: March 27, 2014Applicant: EXXONMOBIL RESEARCH AND ENGINEERING COMPANYInventor: Eric B. Sirota
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Publication number: 20140053456Abstract: Methods and systems for the devolatilization of thermally produced liquids to raise the flash point are disclosed. Various methods and apparatus can be used to effectively reduce the volatile components, such as wiped film evaporator, falling film evaporator, flash column, packed column, devolatilization vessel or tank.Type: ApplicationFiled: August 26, 2013Publication date: February 27, 2014Applicant: Ensyn Renewables, Inc.Inventors: Geoffrey Hopkins, Barry A. Freel, Doug Clarke
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Publication number: 20140021094Abstract: Heavy hydrocarbons contained in FT off gas of a GTL process are removed by bringing the FT off gas into contact with absorption oil, by introducing the FT off gas into a distillation tower, by cooling the FT off gas or by driving the FT off gas into an adsorbent. A burner tip for heating a reformer tube, using FT off gas as fuel, is prevented from being plugged by the deposition of heavy hydrocarbons contained in the FT off gas.Type: ApplicationFiled: March 31, 2011Publication date: January 23, 2014Applicants: JAPAN OIL, GAS AND METALS NATIONAL CORPORATION, INPEX CORPORATION, JX NIPPON OIL & ENERGY CORPORATION, CHIYODA CORPORATION, COSMO OIL CO., LTD., NIPPON STEEL & SUMIKIN ENGINEERING CO., LTD., JAPAN PETROLEUM EXPLORATION CO., LTD.Inventors: Kenichi Kawazuishi, Fuyuki Yagi, Shuhei Wakamatsu, Tomoyuki Mikuriya
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Patent number: 8604262Abstract: A process for reforming a hydrocarbon stream is presented. The process involves splitting a naphtha feedstream to at least two feedstreams and passing each feedstream to separation reformers. The reformers are operated under different conditions to utilize the differences in the reaction properties of the different hydrocarbon components. The process utilizes a common catalyst, and common downstream processes for recovering the desired aromatic compounds generated.Type: GrantFiled: March 9, 2012Date of Patent: December 10, 2013Assignee: UOP LLCInventors: David A. Wegerer, Kurt M. Vanden Bussche, Mark D. Moser
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Publication number: 20130319662Abstract: Systems and methods for hydrotreating a liquid fraction of a shale oil stream using hydrogen gas that is concentrated from a gaseous fraction of the shale oil stream. The systems and methods include providing a portion of the gaseous fraction to a sorptive separation assembly and separating a concentrated hydrogen stream from the portion of the gaseous fraction within the sorptive separation assembly. The system and methods further include providing the concentrated hydrogen stream and the liquid fraction to a hydrotreater and reacting the concentrated hydrogen stream with the liquid fraction within the hydrotreater to produce the hydrotreated liquid stream. The systems and methods may include generating the shale oil stream within a subterranean formation using an in situ process, such as an in situ shale oil conversion process and/or providing a supplemental hydrogen stream to the hydrotreater.Type: ApplicationFiled: May 7, 2013Publication date: December 5, 2013Inventors: Emilio Alvarez, Harry W. Deckman, Frank Hershkowitz, William P. Meurer, Thomas R. Palmer
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Patent number: 8586812Abstract: Processes for upgrading condensate in a first hydrocarbon stream to provide distillate material may involve ionic liquid catalyzed olefin oligomerization of olefins in the first hydrocarbon stream to provide a first distillate enriched stream, dechlorination of the first distillate enriched stream, hydroprocessing at least one of a second and a third hydrocarbon stream to provide a second distillate enriched stream, and separation of a distillate product from the first and second distillate enriched streams.Type: GrantFiled: December 22, 2010Date of Patent: November 19, 2013Assignee: Chevron U.S.A. Inc.Inventors: Hye-Kyung C. Timken, Bi-Zeng Zhan
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Publication number: 20130277274Abstract: A process for the refining of crude oil, comprising a separation unit of the crude oil, consisting of at least one atmospheric distillation unit for separating the various fractions, a unit for the conversion of the heavy fractions obtained, a unit for improving the quality of some of the fractions obtained by actions on the chemical composition of their constituents, and units for the removal of undesired components, characterized in that the heaviest fraction, the atmospheric distillation residue, is sent to the conversion unit comprising a hydroconversion reactor in slurry phase or of the ebullated bed type, into which hydrogen or a mixture of hydrogen and ¾S is introduced in the presence of a suitable nanodispersed hydrogenation catalyst.Type: ApplicationFiled: October 27, 2011Publication date: October 24, 2013Applicant: Eni S.P.A.Inventors: Giacomo Fernando Rispoli, Giuseppe Bellussi
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Publication number: 20130161236Abstract: Methods are provided for processing crude oil feeds with reduced or minimized energy usage, reduced or minimized numbers of processing steps, improved allocation of hydrogen, and reduced or minimized formation of low value products. The methods reduce or minimize the use of vacuum distillation, and in many aspects reduce or minimize the use of both atmospheric and vacuum distillation. The methods also reduce or minimize the use of coking and fluid catalytic cracking processes.Type: ApplicationFiled: August 29, 2012Publication date: June 27, 2013Applicant: EXXONMOBIL RESEARCH AND ENGINEERING COMPANYInventors: Ramon A. Strauss, Stephen Harold Brown, Donald E. Stratton, Stefan Maria Willy Ceulemans
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Publication number: 20130118953Abstract: Disclosed is a process for hydrotreating inferior naphtha fraction, comprising: (1) warming a recycle oil in a heating device; (2) mixing the inferior naphtha fraction with the recycle oil before and/or after the heating device; and (3) feeding the mixture of the inferior naphtha fraction and the recycle oil into a separating unit, wherein the gas-liquid separation is realized at least to obtain a gas phase and a liquid phase, wherein the gas phase comprises gasified inferior naphtha, wherein the gas phase enters a hydrotreating reactor to undergo hydrotreating, and wherein part of the liquid phase circulates to the heating device as the recycle oil; wherein warming of the recycle oil is controlled to ensure the temperature of gas phase from the separator at least reaches the inlet temperature of the hydrotreating reactor. Comparing with the prior art, the inventive process effectively solves the coking problem of the hydrogenating unit for inferior naphtha fraction.Type: ApplicationFiled: October 26, 2012Publication date: May 16, 2013Applicants: FUSHUN RESEARCH INSTITUTE OF PETROLEUM AND PETROCHEMICALS, SINOPEC, CHINA PETROLEUM & CHEMICAL CORPORATIONInventors: CHINA PETROLEUM & CHEMICAL CORPORATI, FUSHUN RESEARCH INSTITUTE OF PETROLEU
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Publication number: 20130105356Abstract: Pyrolysis oil is upgraded by evaporating water from a mixture of the pyrolysis oil and a hydrocarbon having an atmospheric boiling point of at least 130° C. The method yields a de-watered pyrolysis oil mixture.Type: ApplicationFiled: October 31, 2012Publication date: May 2, 2013Applicant: SHELL OIL COMPANYInventor: Shell Oil Company
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Patent number: 8338495Abstract: In a GTL process of producing various kinds of hydrocarbon oils from natural gas, provided is improved heat efficiency in the case of using a steam reforming process or a carbon dioxide reforming process in the reforming. The process includes producing a synthesis gas by converting the natural gas and at least one of steam and carbon dioxide into a synthesis gas through a tubular reformer filled with a reforming catalyst, producing Fischer-Tropsch oil by subjecting the produced synthesis gas to a Fischer-Tropsch reaction, and upgrading in which the Fischer-Tropsch oil is subjected to hydrotreatment and distillation to produce various kinds of hydrocarbon oils, in which excess heat generated in the synthesis gas production is recovered, and the recovered heat is used as heat for at least one of hydrotreatment and distillation in the upgrading.Type: GrantFiled: September 18, 2008Date of Patent: December 25, 2012Assignees: Japan Oil, Gas and Metals National Corporation, Inpex Corporation, Nippon Oil Corporation, Japan Petroleum Exploration Co., Ltd., Cosmo Oil Co., Ltd., Nippon Steel Engineering Co., Ltd., Chiyoda CorporationInventors: Fuyuki Yagi, Kenichi Kawazuishi
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Publication number: 20120261308Abstract: Systems and methods for refining conventional crude and heavy, corrosive, contaminant-laden carbonaceous crude (Opportunity Crude) in partially or totally separated streams or trains.Type: ApplicationFiled: April 16, 2012Publication date: October 18, 2012Applicant: Bechtel Hydrocarbon Technology Solutions, Inc.Inventors: Benjamin Klein, Odette Eng
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Patent number: 8202480Abstract: An apparatus is disclosed for converting heavy hydrocarbon feed into lighter hydrocarbon products. The heavy hydrocarbon feed is slurried with a particulate solid material to form a heavy hydrocarbon slurry and hydrocracked in a slurry hydrocracking unit to produce vacuum gas oil (VGO) and pitch. A first vacuum column separates VGO from pitch, and a second vacuum column further separates VGO from pitch. As much as 15 wt-% of VGO can be recovered by the second vacuum column and recycled to the slurry hydrocracking unit. A pitch composition is obtained which can be made into particles and transported without sticking together.Type: GrantFiled: June 25, 2009Date of Patent: June 19, 2012Assignee: UOP LLCInventors: James F. McGehee, David N. Myers, Mark Van Wees, Paul R. Zimmerman, Ruth Buskus Kleinworth
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Patent number: 8182556Abstract: A method for producing biofuels is provided. A method of making biofuels includes dewatering substantially intact algal cells to make an algal biomass, sequentially adding solvent sets to the algal biomass, and sequentially separating solid biomass fractions from liquid fractions to arrive at a liquid fraction comprising neutral lipids. The method also includes esterifying the neutral lipids, separating a water miscible fraction comprising glycerin from a water immiscible fraction comprising fuel esters, carotenoids, and omega-3 fatty acids. The method also includes obtaining a C16 or shorter fuel esters fraction, a C16 or longer fuel ester fraction, and a residue comprising carotenoids and omega-3 fatty acids. The method includes hydrogenating and deoxygenating at least one of (i) the C16 or shorter fuel esters to obtain a jet fuel blend stock and (ii) the C16 or longer fuel esters to obtain a diesel blend stock.Type: GrantFiled: October 7, 2011Date of Patent: May 22, 2012Assignee: Haliae Development, LLCInventor: Aniket Kale
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Patent number: 8158840Abstract: A process and apparatus for steam cracking liquid hydrocarbon feedstocks utilizes a vapor/liquid separation apparatus to treat heated vapor/liquid mixtures to provide an overhead of reduced residue content and includes: i) indirectly heat exchanging liquid bottoms with boiler feed water to provide cooled liquid bottoms and preheated boiler feed water; ii) directing at least a portion of said preheated boiler feed water to a steam drum; and iii) recovering steam having a pressure of at least about 4100 kPa (600 psia) from said steam drum.Type: GrantFiled: June 3, 2008Date of Patent: April 17, 2012Assignee: ExxonMobil Chemical Patents Inc.Inventor: David B. Spicer
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Patent number: 8152994Abstract: Systems and methods for processing one or more hydrocarbons are provided. One or more hydrocarbon feedstocks can be selectively separated to provide one or more light deasphalted oils. At least a portion of the light deasphalted oil can be hydrocracked to provide one or more hydrocarbon products.Type: GrantFiled: December 27, 2007Date of Patent: April 10, 2012Assignee: Kellogg Brown & Root LLCInventors: Anand Subramanian, Raymond Floyd, Odette Eng
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Patent number: 8152870Abstract: A method for producing biofuels is provided. A method of making biofuels includes dewatering substantially intact algal cells to make an algal biomass, sequentially adding solvent sets to the algal biomass, and sequentially separating solid biomass fractions from liquid fractions to arrive at a liquid fraction comprising neutral lipids. The method also includes esterifying the neutral lipids, separating a water miscible fraction comprising glycerin from a water immiscible fraction comprising fuel esters, carotenoids, and omega-3 fatty acids. The method also includes obtaining a C16 or shorter fuel esters fraction, a C16 or longer fuel ester fraction, and a residue comprising carotenoids and omega-3 fatty acids. The method includes hydrogenating and deoxygenating at least one of (i) the C16 or shorter fuel esters to obtain a jet fuel blend stock and (ii) the C16 or longer fuel esters to obtain a diesel blend stock.Type: GrantFiled: April 6, 2011Date of Patent: April 10, 2012Assignee: Heliae Development, LLCInventor: Aniket Kale
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Patent number: 8137556Abstract: A method for producing biofuels is provided. A method of making biofuels includes dewatering substantially intact algal cells to make an algal biomass, extracting neutral lipids from the algal biomass, and esterifying the neutral lipids with a catalyst in the presence of an alcohol. The method also includes separating a water soluble fraction comprising glycerin from a water insoluble fraction comprising fuel esters and distilling the fuel esters under vacuum to obtain a C16 or shorter fuel esters fraction, a C16 or longer fuel ester fraction, and a residue comprising carotenoids and omega-3 fatty acids. The method further includes hydrogenating and deoxygenating at least one of (i) the C16 or shorter fuel esters to obtain a jet fuel blend stock and (ii) the C16 or longer fuel esters to obtain a diesel blend stock.Type: GrantFiled: October 7, 2011Date of Patent: March 20, 2012Assignee: Heliae Development, LLCInventor: Aniket Kale
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Patent number: 8137558Abstract: A method for producing biofuels is provided. A method of making biofuels includes dewatering substantially intact algal cells to make an algal biomass, extracting neutral lipids from the algal biomass, and esterifying the neutral lipids with a catalyst in the presence of an alcohol. The method also includes separating a water soluble fraction comprising glycerin from a water insoluble fraction comprising fuel esters and distilling the fuel esters under vacuum to obtain a C16 or shorter fuel esters fraction, a C16 or longer fuel ester fraction, and a residue comprising carotenoids and omega-3 fatty acids. The method further includes hydrogenating and deoxygenating at least one of (i) the C16 or shorter fuel esters to obtain a jet fuel blend stock and (ii) the C16 or longer fuel esters to obtain a diesel blend stock.Type: GrantFiled: September 30, 2011Date of Patent: March 20, 2012Assignee: Heliae Development, LLCInventor: Aniket Kale
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Patent number: 8083931Abstract: The invention is directed to a process wherein a feedstock or stream comprising steam cracker tar is passed to a vacuum pipestill. A deasphalted cut of tar is obtained as an overhead (or sidestream) and a heavy tar asphaltenic product is obtained as bottoms. In preferred embodiments, at least a portion of the bottoms product is sent to a partial oxidation unit (POX) wherein syn gas may be obtained as a product, and/or at least a portion of the bottoms product is used to produce a light product stream in a coker unit, such as coker naphtha and/or or coker gas oil. In another preferred embodiment at least a portion of the overheads product is added to refinery fuel oil pools and in yet another preferred embodiment at least a portion of the overheads product is mixed with locally combusted materials to lower soot make. Two or more of the aforementioned preferred embodiments may be combined.Type: GrantFiled: July 25, 2007Date of Patent: December 27, 2011Assignee: ExxonMobil Chemical Patents Inc.Inventors: James N. McCoy, Paul F. Keusenkothen, Alok Srivastava, James E Graham
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Patent number: 8052864Abstract: A process to prepare a sweet crude from an ash containing and heavy fraction of a tar sand oil comprising supplying an atmospheric distillation bottoms of a tar sands originated feed to a vacuum distillation to obtain a vacuum gas oil and a vacuum bottoms and contacting the vacuum gas oil with hydrogen to obtain a sweet synthetic crude. The vacuum bottoms obtained are separated into an asphalt fraction comprising between 0.1 and 4 wt % ash and a de-asphalted oil and the asphalt fraction is fed to a burner of a gasification reactor to obtain a mixture of hydrogen and carbon monoxide on which a water gas shift reaction is performed. Hydrogen sulphide and carbon dioxide are separated from the shifted gas in an acid removal unit thereby obtaining crude hydrogen which is purified and used to obtain the sweet synthetic crude.Type: GrantFiled: November 29, 2007Date of Patent: November 8, 2011Assignee: Shell Oil CompanyInventors: Jacobus Eilers, Johannes Cornelis De Jong, Franciscus Johanna Arnoldus Martens
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Patent number: 8002968Abstract: A process for treating a heavy hydrocarbon feedstock is disclosed. The process involves separating the feedstock into a residue component and a light component, the residue component having a lower API gravity than the light component and treating at least a portion of the light component to produce a synthetic transport diluent suitable for combining with at least a portion of the residue component to produce a product which meets applicable criteria for pipeline transport.Type: GrantFiled: November 14, 2005Date of Patent: August 23, 2011Assignee: Statoil Canada Ltd.Inventors: Leonard F. Flint, Patrick B. Carlson, Gareth R. Crandall
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Patent number: 7947860Abstract: Processing schemes and arrangements for application of a dividing wall separation column in the processing of an effluent resulting from FCC processing modified for increased light olefin production. The dividing wall separation column desirably splits a naphtha feedstock produced or resulting from such modified FCC processing to produce or form a light fraction containing C5-C6 compounds, an intermediate fraction containing C7-C8 compounds and a heavy fraction containing C9+ compounds.Type: GrantFiled: September 28, 2006Date of Patent: May 24, 2011Assignee: UOP LLCInventors: Michael A. Schultz, Keith A. Couch
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Patent number: 7857965Abstract: A process for upgrading hydrocarbonaceous oil containing heteroatom-containing compounds where the hydrocarbonaceous oil is contacted with a solvent system that is a mixture of a major portion of a polar solvent having a dipole moment greater than about 1 debye and a minor portion of water to selectively separate the constituents of the carbonaceous oil into a heteroatom-depleted raffinate fraction and heteroatom-enriched extract fraction. The polar solvent and the water-in-solvent system are formulated at a ratio where the water is an antisolvent in an amount to inhibit solubility of heteroatom-containing compounds and the polar solvent in the raffinate, and to inhibit solubility of non-heteroatom-containing compounds in the extract. The ratio of the hydrocarbonaceous oil to the solvent system is such that a coefficient of separation is at least 50%.Type: GrantFiled: April 4, 2005Date of Patent: December 28, 2010Assignee: James W. Bunger and Associates Inc.Inventors: James W. Bunger, Donald E. Cogswell
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Patent number: 7833409Abstract: A method for treating fuel containing vanadium including extracting vanadium from the fuel with an adsorption material and fractionating the fuel into a light oil fraction and a heavy fuel fraction. The light fuel fraction has a reduced amount of vanadium. Systems for fuel preparation are also provided.Type: GrantFiled: August 30, 2007Date of Patent: November 16, 2010Assignee: General Electric CompanyInventors: Parag Prakash Kulkarni, Gregg Anthony Deluga, Arnaldo Frydman, Gregory Ronald Gillette, Narendra Joshi, Ke Liu, Vladimir Zamansky
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Publication number: 20100243524Abstract: A method for thermally cracking an organic acid containing hydrocarbonaceous feed wherein the feed is first processed in a vaporization step operated under conditions designed to vaporize and transmit a significant amount of the acid species in the feed to a thermal cracking furnace.Type: ApplicationFiled: March 31, 2009Publication date: September 30, 2010Inventor: Donald H. Powers
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Publication number: 20100243525Abstract: A method for thermally cracking an organic acid containing hydrocarbonaceous feed wherein the feed is first processed in a vaporization step, followed by thermal cracking.Type: ApplicationFiled: March 31, 2009Publication date: September 30, 2010Inventors: Donald H. Powers, Robert S. Bridges, Kenneth M. Webber
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Publication number: 20100243523Abstract: A method for thermally cracking an organic acid containing hydrocarbonaceous feed wherein the feed is first processed in a vaporization step operated under conditions designed to disassociate acid species in the feed prior to passing the feed to a thermal cracking furnace.Type: ApplicationFiled: March 31, 2009Publication date: September 30, 2010Inventor: Donald H. Powers
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Patent number: 7737317Abstract: Processing schemes and arrangements are provided for the processing a heavy hydrocarbon feedstock via hydrocarbon cracking processing with selected hydrocarbon fractions being obtained via fractionation-based product recovery.Type: GrantFiled: September 28, 2006Date of Patent: June 15, 2010Assignee: UOP LLC.Inventors: Michael A. Schultz, Jason T. Corradi