Abstract: Froth flotation of oxidized coal in the presence of certain imidazoline or imidazolinium salts improves both the selectivity and recovery attained. Imidazolines found particularly efficacious are those bearing a fatty alkyl group in the 2- position and an N-aminoethyl or N-hydroxyethyl group. Preferred imidazolinium salts are those corresponding to the following formula: ##STR1## wherein R is a C.sub.6 to C.sub.22 alkyl or alkenyl group.

Abstract: A process for recovering metallic values by putting the values into solution and separating undesired mineral matter from the solution using countercurrent flotation is provided. The process involves leaching metallic values from host rock, conditioning the resultant ore pulp with the required reagents to achieve selective flotation of mineral matter in the metallic values solution, introducing the conditioned ore pulp into flotation cells, along with counterflow of solution from an immediately subsequent flotation step, wherein simultaneous washing and flotation is achieved, and the mineral matter is removed leaving a solution of the metallic values. The resultant mineral matter froth product is subjected to subsequent stages of flotation and simultaneous washing with counterflow of solution removed from each subsequent stage of flotation, water and/or barren solution being used for washing in the final flotation stage.

Abstract: A method is disclosed for improving the recovery of a conventional single or double stage flotation process for the benefication of phosphate ore. The method includes treating the discarded froth product of the conventional phosphate proces with waste slime from the flotation process. The slime and froth product is agitated to completely deactive the cationic reagent prior to the anionic treatment with new phosphate ore in a conventional flotation process.

Abstract: A blend of certain xanthates with mercaptan/glycol combinations produce collector compositions which yield improved results in ore flotation.

Abstract: An improved method in concentration of zirconium ores and minerals by froth flotation process which comprises subjecting a sufficiently fine sized ore of zirconium metal in the presence of phenethylglycolic acid or its sodium salt; or the like alkyl substituted phenylglycolic acid; the indicated compound provide selectivity and recovery of zirconium minerals over silica and silicate gangue.

Abstract: This invention provides a process for the beneficiation of phosphate ores having a magnesia-rich carbonate-containing gangue and a silica-containing gangue, which process comprises subjecting the phosphate ore particles to controlled attrition to remove at least a portion of the magnesia-rich carbonate-containing gangue; and subjecting the phosphate ore resulting from attrition to a plurality of flotations to remove the remaining magnesia-rich carbonate-containing gangue and the silica-containing gangue and to recover a concentrated phosphate product, the flotations including sequentially a phosphate flotation, a silica flotation and a carbonate flotation. Alternatively, the controlled attrition can be employed after the silica flotation and prior to the carbonate flotation.

Abstract: Finely-divided ore is beneficiated in a froth floation process carried out in a closed vessel containing a medium on which a froth is formed as a result of the injection into the bottom of the vessel of a gasified slurry which percolates upwardly and circulates in the medium. A lighter fraction of the ore froths on the surface of the medium and is conveyed hydraulically into a receiver wherein the gaseous component is separated from the froth and is recycled through a compressor for mixing with an ore slurry supplied to mixing nozzles which inject the slurry into the medium. A heavier fraction of the ore sinks into the medium and is collected by and exhausted from the vessel through an underflow siphon located between the surface of the medium and the mixing nozzles. A wet scrubber flows a series of fluid jets in a horizontal grid pattern underneath the surface of the medium for limiting the upward percolation of the heavier fraction to the surface.

Abstract: The invention relates to a process and apparatus for the separation of the isotopes of a body, and particularly of a heavy metal. The process comprises the preparation of a tension-active compound of said body, the solution of this compound in a liquid having a strong surface tension, the injection of a non-miscible body into this solution to form a plurality of separation surfaces, and the recovery of the fraction of the solution adjacent to said separation surfaces. The apparatus comprises a plurality of vats, means for injecting a gas into these vats to produce a foam, means to collect the foam and transfer it into a vat downstream, and means to transfer a portion of the liquid from one vat into another vat located upstream thereof. The process and apparatus are applied to the isotopic separation of uranium.

Abstract: Process for treating by reverse flotation phosphate ores of the carbonate or silico-carbonate gangue type. It includes the steps of:(1) conditioning of the ore in a manner known per se with a product acting to depress the phosphate compounds,(2) treatment of the conditioned ore step (1) with a collector essentially comprising a phosphoric ester,(3) flotation of the carbonates, this leading to a flotation residue which contains the phosphate compounds and, if so required, in the case where the starting compound is of the silico-carbonate gangue type,(4) conditioning of said flotation residue by a cationic collector, the possibly present silicates being thus separated by flotation.The process permits benification of the phosphate ores by a treatment wholly carried out in sea-water.

Abstract: A method for upgrading the bitumen content of tar sands, wherein a raw tar sand slurry admixture of tar sands, water, collectors, and dispersing/wetting agents is milled; conditioned and then separated by a series of froth flotations at ambient temperatures from about 2.degree. C. to about 25.degree. C. to recover a concentrated bitumen tar sand product which may be processed by conventional means to recover oil from the bitumen. Enhanced recovery of bitumen may be accomplished by moderate heating in one or more of the flotation zones to about 50.degree. C. The method permits recovery and recycle of various components used in processing of the tar sand.

Abstract: Dithiocarbonic acid, trithiocarbonic acid, water soluble salts of dithiocarbonic acid or trithiocarbonic acid or mixtures thereof when contacted with a mixed sulfide ore effectively depresses copper and iron sulfides thereby permitting molybdenite to be recovered by froth flotation. In copper concentrates produced by a flotation process, the organic collector reagents adhering to the surface of the copper and iron sulfides may be, and preferably are, stripped by conventional physical or chemical means prior to contacting the copper concentrate with the trithiocarbonate depressants of the invention. However, the trithiocarbonates of the invention have been found to be effective depressants of copper and iron sulfides in concentrates which are not stripped prior to treatment with the depressant.

Abstract: Fulvene and hydrocarbyl substituted fulvenes are disclosed as mineral collectors for ore flotation processes, particularly for molybdenum sulfide recovery.

Abstract: A composition comprising a mercaptan, an imidazoline and a frother has been found to synergistically increase gold recovery over the recovery achievable with mercaptan and imidazoline alone.

Abstract: This invention relates to the use of a primary-branched aliphatic ether monoamine, 3-nonyloxypropylmonoamine, its ethoxylated or propoxylated derivatives and partial acid salts thereof, as a major or minor constituent in the formulation of superior silica flotation collectors. Such collectors are employed in the separation of silica from iron ore, phosphate, and other valuable ores.

Abstract: The present invention relates to an enrichment process, by flotation, of sedimentary ores containing phosphate, and comprising a gangue of the carbonated type and in some cases a gangue of the siliceous type, wherein an amphoteric product of formula ##STR1## is at least used as collecting agent, in which formula: R is of form R.sub.1 or R.sub.1 O--, R.sub.1 being a saturated or unsaturated alkyl radical, either linear or branched, and comprising between 5 and 19 carbon atoms.R' and R" are H or --Aq--Z, bearing in mind that for R", when n is greater than 1, there can be in the molecule simultaneously radicals H and radicals --Aq--Z.Ap and Aq are polymethylene chains containing between 1 and 4 carbon atoms,n is a number equal to O or an integer between 1 and 5,Z is a radical selected from the carboxylic, the sulphonic and the phosphonic radicals, and in obtaining the flotation of the carbonated gangue by a reverse flotation in "basic medium .

Abstract: A method is disclosed for separating titaniferous and ferruginous discolorants from a crude kaolin clay. A dispersed aqueous slurry of the clay is formed containing a deflocculant and a fatty acid collecting agent, and the slurry is conditioned to coat the discolorants with the collecting agent to thereby render the discolorants hydrophobic. A system of sub-micron sized magnetic ferrite seeding particles, the surfaces of which have been rendered hydrophobic, is thereupon added to the slurry. The seeded slurry is mixed to coalesce the hydrophobic-surfaced discolorants with the hydrophobic-surfaced seeding particles, and the slurry is then subjected to a froth flotation, which removes substantial quantities of the discolorants and seeding partices coalesced therewith, and also removes excess seeding particles and excess collecting agent.

Abstract: Recovery of copper and iron from ores is enhanced by adding beta-mercaptoethanol as a depressant to a froth flotation process. Flotation of sulfides of zinc and lead is reduced.

Abstract: This invention relates to froth flotation of coal.According to the invention a predominantly paraffinic residual oil having a cut point of at least 190.degree. C. at atmospheric pressure is used as a "collector" for the froth flotation of minerals. A preferred oil is a coal spray oil used in coke oven technology. The "collector" is for use with a "frother" such as a polyglycol ether.

Abstract: Finely divided solids suspended in liquids (such as aqueous slurries of coal fines) are agglomerated by flowing those suspensions and a binding agent into a turbulent-flow agglomeration zone along with a slurry of seed pellets having sizes and proportions correlated with those of the finely divided solids and the agglomerates being formed to induce particle growth by layering rather than by coalescence.

Abstract: A process for the recovery of molybdenum and copper values from an ore comprising the same is provided which comprises employing an oxazine compound as a collection agent.

Abstract: Dialkyl xanthogen formates are known collectors, but the reaction that produces them, between an alkaline alkyl xanthate and an alkaline chloroformate, also causes side reactions which produce varying amounts of xanthic anhydride, carbonyl sulfide and dialkyl carbonate as by-products, and yield of formate may be as low as 30%. There are here disclosed processing schemes for controlling the amount and type of products and by-products produced in the reaction, and flotation tests show that certain product mixtures are significantly improved collectors for sulfide ores.

Abstract: An improved process for the beneficiation of coal and the separation of impurities therefrom comprising subjecting coal to surface treatment by contact with an aqueous medium comprising polymerizable monomer, polymerization catalyst and liquid organic carrier, thereby rendering said coal hydrophobic and oleophilic, the improvement comprising the high shear intermixing of the surface treated coal with at least one water wash medium thereby providing for the removal of further hydrophilic impurities, such as mineral ash from the coal. Apparatus for carrying out the process and the products prepared therefrom are also provided.

Abstract: A method is disclosed for treating dore slag resulting from smelting of a dore furnace charge, by grinding such slag and then subjecting the obtained pulp to froth flotation in the presence of a suitable frother and collector to produce a precious metals concentrate which is then filtered and returned to the dore furnace with the next charge. The tails from the froth flotation may then be finely ground and subjected to several additional flotation stages to improve recovery of the precious metals, and the entire operation is preferably carried out as a closed loop process so that only the tailings from the rougher flotation are removed and shipped to the smelter.

Abstract: A process for the recovery of mineral values by froth flotation in an aqueous medium employing a novel frother. Frothers prepared by Michael addition between alpha, beta-unsaturated ethylenic compounds and either alcohols, amines or mercaptans or by the condensation of HCN, aldehydes/ketones with either alcoholics, amines or mercaptans have been found to be effective in the froth flotation system and capable of reducing the required collector consumption.

Abstract: A method is disclosed for the production of metallurgical grade coal and low ash coal by the combination of froth flotation and selective agglomeration.

Abstract: A collector for use in concentrating metal values in ores by flotation, said collector comprising a synergistic mixture of O-isopropyl N-ethylthionocarbamate and O-isobutyl N-methylthionocarbamate. Ore dressing flotation methods wherein said mixture serves as collector are also provided.

Abstract: A process is disclosed for the recovery of lead, silver and gold from the iron-bearing residue of an electrolytic zinc process by froth-flotating a slurry of the iron-bearing residue in the presence of a sulfidic collector agent in order to froth-flotate the sulfides and to separate them from the iron-bearing residue. The iron-bearing residue is sulfidized selectively in order to convert the lead, silver and possibly gold substantially quantitatively to sulfides before the iron-bearing residue is froth-flotated.

Abstract: Use of reverse flotation for phosphate rock ore treatment, wherein starch is added first to depress phosphate rock particles, followed by addition of cationic reagent, e.g., amine to float the silica. Phosphate rock is recovered as sink concentrate and silica is recovered as float tailings.

Abstract: A method for separating the exinite group macerals from the total coal by froth flotation in the presence of at least one short chain alcohol frothing agent and at least one methyl polyglycol type frothing agent in a first froth flotation zone to produce an exinite and other coal maceral-rich stream which is thereafter subjected to froth flotation in a second froth flotation zone in the presence of a short chain alcohol frothing agent to produce an exinite group maceral-rich stream and a stream rich in other coal macerals with the exinite-rich stream thereafter being mixed with an additional quantity of a short chain alcohol frothing agent and passed to a third froth flotation zone to produce an exinite group maceral group concentrate stream which is thereafter processed to produce a particulate exinite maceral group concentrate.

Abstract: Zinc and lead are separated together out of dust derived from a gas-cleaning installation in iron or steel making by a flotation-separation treatment. In order economically to provide a good separation of these metals and to leave a residue which is re-usable in an ore-preparation process in the iron and steel industry, the flotation-separation treatment is at a pH of 7 to 9 and is effective to achieve a separation, according to size of the dust particles, of a floated component in which the zinc and lead are concentrated and a non-floated component which is suitable for re-use.

Abstract: A flotation composition for removing pigments from waste paper, which consists of a carboxylic acid ester and of from 0 to 10 weight %, referred to the ester of the above formulae, of a surfactant.

Abstract: A method of beneficiating a phosphate ore containing silica and an alkaline earth metal carbonate impurity, particularly dolomite or calcite. The steps include testing the ore for excessive levels of carbonate impurities, the use of conventional flotation steps to remove silica, grinding the ore to a particle size in which at least 90% of the ore particles are less than 0.355 mm and thereafter reagentizing the ground phosphate containing ore with water, a carbonate collector, a phosphate depressant and a pH regulator to obtain a flotation feed having a solids level of about 20-30% and a pH of about 5.6-6.0. The flotation feed is then subjected to a reverse flotation in a flotation cell to remove carbonate impurities as the cell overflow and to collect a phosphate concentration as the cell underflow.

Abstract: An extender oil characterized as having a viscosity at 100.degree. F. in a range of about 40 to about 250 SUS and an aromatic content in the range of about 60 to about 85 wt % of the total collector composition of which about 10 to about 20 wt % of the total collector composition is chosen from among benzothiophenes and dibenzothiophenes. The above-described extender oil blended with the tall oil in a ratio of tall oil to extender oil in a range of about 75 wt %: to about 25 wt % to about 25 wt %:about 75 wt %. The extender oil described above blended with a fatty amine in a ratio of fatty amine to extender oil in a range of about 50 wt %:50 wt % to about 10 wt %:90 wt %. The flotation process for recovering phosphates and/or potash employing the compositions described above.

Abstract: A reagent and a method for using the reagent for treating a solid material disposed in a liquid medium and having an oxygen-controlled surface condition. The reagent includes a liquid hydrocarbon, a reducing material and an activator material. The liquid hydrocarbon such as mineral oil has a specific gravity different from the specific gravity of the liquid medium. The reducing material such as phosphorous pentasulfide is present in an amount sufficient to establish a reducing environment around the solid material for breaking the oxygen control on the surface of the solid material. The activator material such as zinc thiophosphate is present in an amount sufficient to establish an electrostatic charge on the solid material after the oxygen-controlled surface condition has been broken. A more specific feature of the invention is directed to the method of flotation of extremely fine bituminous coal having an oxygen-controlled surface condition.

Abstract: Beneficiation of metallic oxide ores by froth flotation process using polyhydroxy fatty acids collector-frothers in the presence of silica, silicates, and the like gangue minerals to obtain pure concentrates of desired metal values; comprises, adding to a water suspension of finely divided ore material of polyhydroxy fatty acids to collect the metal value, leaving unaffected gangue minerals.

Abstract: The impure jarosite residue of an electrolytic zinc process is leached in a sulfuric-acid-bearing solution in order to produce a leach residue which contains lead, silver and gold and a ferrisulfate-bearing solution and to separate them from each other, whereafter the leach residue is sulfidized and froth-flotated in order to recover a combined concentrate which contains lead, silver and gold, and the ferrisulfate-bearing solution is fed to a ferritic treatment stage, in which ferrisulfate and ferrites react in the presence of ions of alkali and ammonium at 80.degree.-105.degree. C. and form pure jarosite and zinc sulfate.

Abstract: A scheelite concentrate is recovered from a scheelite ore containing silicate minerals and other calcareous minerals by froth flotation which process comprises grinding the ore sufficiently fine to liberate the scheelite grains, pulping the gound ore with water to form a slurry containing between about 20% and about 40% solids by weight, sequentially conditioning the slurry with at least one alkali metal carbonate in small but effective amounts to provide an alkaline pH adjustment and a source of carbonate ions, with small but effective amount of alkali metal silicates to depress siliceous and calcareous gangue minerals other than scheelite and with a fatty acid collector in small but effective amounts to coat the scheelite grains, the conditioning with the fatty acid collector being conducted with sufficient agitation to disintegrate floccules of scheelite, silicate mineral and other calcareous mineral grains and to preferentially reflocculate the scheelite grains for a period of time sufficient to produce u

Abstract: A method of beneficiating ore containing barite by a froth flotation process. C.sub.8-34 alpha olefin sulfonates and salts thereof are the active component in compositions which are effective barite collectors and frothers. Additionally, the alpha olefin sulfonates can be admixed with C.sub.8-34 alkyl sulfates, salts thereof, tall oil fatty acids, salts thereof, mahogany petroleum sulfonates, salts thereof, sulfosuccinamates, salts thereof, as well as with admixtures of these compounds to achieve compositions which are efficient barite collectors and frothers.

Abstract: Rutile is recovered from copper ore tailings by means of a froth flotation process comprising: (a) flotation of sulfides and carbonates at a pH of about 9 to 10, using sodium isopropyl xanthate and sodium oleate as collectors, and detrine as rutile depressant, and (b) flotation of rutile from the resulting tailings at a pH of about 2 to 3, using hydrofluoric acid as a rutile selectivity-assisting agent and water-soluble petroleum sulfonate as rutile collector.

Abstract: Beneficiation of metallic ores selected from the group of zinc, bismuth, cobalt, nickel, titanium, zirconium, thorium, chromium, molybdenum, wolfram, and uranium, by froth flotation process using commercial amines in conjunction with oxalic acid or alkali oxalates to obtain pure concentrates of said metal values comprises; adding to a water suspension of finely divided ore of amine type collectors and an adequate amount of oxalic acid or a soluble oxalate which acting in conjunction activate and levitate in the froth by usual froth flotation process the metal values of zinc, bismuth, cobalt, nickel, titanium, zirconium, chromium, and uranium minerals; and for molybdenum and wolfram recovering the pulp of mineral slurry are oxidized with hydrogen peroxide, or any strong oxidizing agent and proceed as described above.

Abstract: A procedure for the separation of arsenic from fluorite by means of magnetization and flotation of the pyrites present in the fluorite ore, and in which arsenic is associated, irrespectively of the chemical form in which said arsenic is present.

Abstract: This invention relates to the use of zirconium compounds and complexes thereof as flotation aids in a wide variety of systems.

Abstract: A method is disclosed for separating titaniferous and ferruginous discolorants from a crude kaolin clay. A dispersed aqueous slurry of the clay is formed containing a deflocculant and a fatty acid collecting agent, and the slurry is conditioned to coat the discolorants with the collecting agent to thereby render the discolorants hydrophobic. A system of sub-micron sized magnetic ferrite seeding particles, the surfaces of which have been rendered hydrophobic, is thereupon added to the slurry. The seeded slurry is mixed to coalesce the hydrophobic-surfaced discolorants with the hydrophobic-surfaced seeding particles, and the slurry is then subjected to a froth flotation, which removes substantial quantities of the discolorants and seeding particles coalesced therewith, and also removes excess seeding particles and excess collecting agent.

Abstract: Direct flotation of pyrochlore from its ore can be carried out at acidic pH using 1-amidoethyl-2-substituted imidazolines of the formula ##STR1## wherein R and R' are independently alkyl or alkenyl of 8 to 22 carbons, or their salts. In the presence of large amounts of carbonate in the ore, the pulp is acidified with hydrofluoric acid, fluosilicic acid, or their acid reacting compounds. Using this process, pyrochlore concentrates can be obtained by direct flotation from ore containing 0.1% or more of sulphide compounds calculated as FeS.sub.2.

Abstract: S-Allyl-S'-n-butyl-trithiocarbonate and S-benzyl-S'-n-butyl-trithiocarbonate, their use and flotation agents and a process to make these novel compositions are disclosed.

Abstract: Alkylaryl hydrocarbons having at least eleven carbon atoms, when used either alone or in combination with known sulfide collectors, result in enhanced recovery and selectivity when used as collectors for sulfide minerals. These alkylaryl hydrocarbons are generally derived from the alkylation of aromatic compounds with the appropriate olefin in synthetic processes. Isopropyl naphthalene appears foremost among these compound as an effective sulfide collector.

Abstract: Employment of a latex emulsion prepared from a hydrocarbon, animal or vegetable based oil with a hydrophobic water-in-oil emulsifier and a hydrophilic surfactant in the froth flotation of coal improves coal recovery without increasing the ash content. The emulsifier employed should have an HLB value of 5.0 or less while the surfactant should have an HLB value of 9.0 or higher.

Abstract: An improved froth flotation process wherein preselected particles are selectively separated under froth flotation conditions as a froth phase from remaining feed particles as an aqueous phase in the presence of an anionic collector. Such improvement is characterized by the addition of an effective proportion of a promoter. The promoter is characterized as an amine oxide promoter. Preferred feed particles are phosphate ore particles.

Abstract: A method is disclosed for beneficiating a kaolin clay pigment to improve the rheological properties of a high solids suspension subsequently formed therefrom. According to the method, a 10 to 20% solids aqueous suspension of a kaolin clay is subjected to a selective rheological separation, by mixing the suspension with from about 0.001% to 0.1% by weight of dry clay, of a high molecular weight anionic polymer, and allowing the thereby treated suspension to separate into a sedimented phase, and a supernatant phase which is substantially free of aggregates; and separating the supernatant phase containing the beneficiated kaolin pigment in suspension. The suspended product of the process can then be conventionally processed, as by reductive bleaching, floccing, filtering, washing, dispersing, and drying.

Abstract: Mine run coal is pulverized and the extended surfaces of the coal particles are rendered hydrophobic and oilophilic by a chemical bonding and graft polymerization reaction with a water insoluble organic polymerizable monomer under peroxidation influence in a predominantly water reaction medium.The mineral ash present in the coal and particularly the iron pyrites remains hydrophilic and is separated from the polymeric organic surface bonded coal product in a water washing step wherein the washed coal floats on and is recovered from the water phase and the ash is removed with the separated wash water in a critical wash step.Excess water is removed from the beneficiated hydrophobic surface-altered coal product mechanically. The hydrophobic and oilophilic organic polymeric surface bonded coating about the coal particles is fortified by inclusion of additional unbound free fatty acids by further small additions thereof.