Chemically Specified Precipitant, Coagulant, Or Flocculant Patents (Class 210/705)
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Patent number: 5552498Abstract: The invention comprise a composition for breaking oil-in-water emulsions comprising adding from about 1 part per million to about 500 parts per million of an amphoteric acrylic acid copolymer to the emulsion. Once the copolymer is added, the emulsion is subjected to agitation until the oil-in-water emulsion is resolved and the oil and water separates into two phases. The oil and water phases are then subjected to a separation technique to separate the phases. The invention further comprises a method of synthesizing the amphoteric polymers used in the emulsion breaking application.Type: GrantFiled: December 5, 1995Date of Patent: September 3, 1996Assignee: Nalco Chemical CompanyInventor: Michael L. Braden
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Patent number: 5543056Abstract: A method for treating water using natural polymers that provide an alternate and improved means to achieve enhanced coagulation is described. A method for removing particles, color, and color from drinking water, comprising adding a primary coagulant such as a natural, cationic polymer like chitosan or a cationic starch and a coagulant aid such as bentonite to drinking water to form a mixture. A preferred concentration weight ratio of natural polymer to clay mineral is between 1:5 and 1:20.A composition for removing particles and color from drinking water is described that includes a natural, cationic polymer coagulant and clay mineral in a total amount effective to coagulate suspended material in the drinking water. The composition includes a weight ratio natural polymer coagulant/clay mineral of between about 1:5 to about 1:20.Type: GrantFiled: June 29, 1994Date of Patent: August 6, 1996Assignee: Massachusetts Institute of TechnologyInventors: Susan E. Murcott, Donald R. F. Harleman
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Patent number: 5540836Abstract: A wastewater treatment system and method for substantially reducing or eliminating total suspended solids (TSS), biological organic discharge or biochemical oxygen demand (BOD), and fats, oils and greases (FOG) contaminants. The system includes at least one mixing chamber for mixing wastewater with at least one dewatering agent or chemical and air to form an aerated mixture and at least one tank having a plurality of compartments for facilitating flotation, settling and removal of contaminants from the aerated mixture as it flows through the tank. Preferably, the system includes first and second mixing chambers and first and second tanks arranged in series with each of the tanks including drag lines for removing floating and settled contaminants.Type: GrantFiled: June 16, 1994Date of Patent: July 30, 1996Inventor: Thomas J. Coyne
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Patent number: 5536644Abstract: A method is disclosed for separating a substance from a liquid medium. The method comprises combining the liquid medium containing the substance with magnetic particles under conditions for non-specific chemical binding of the magnetic particles. Thereafter, the medium is subjected to a magnetic field gradient to separate the particles from the medium. The preferred non-specific binding is achieved as the result of charge interactions between the particles usually by means of a polyionic reagent. The method of the invention has particular application to the separation of cells and microorganisms from aqueous suspensions and also to the determination of an analyte in a sample suspected of containing the analyte. The analyte is a member of a specific binding pair (sbp). The sample is combined in an assay medium with magnetic particles and a sbp member complementary to the analyte.Type: GrantFiled: December 9, 1994Date of Patent: July 16, 1996Assignee: Behringwerke AGInventors: Edwin F. Ullman, Vartan E. Ghazarossian, Nurith Kurn, Litai Weng
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Patent number: 5529696Abstract: A method of laundering oily items comprises laundering said items in a wash solution which includes a surfactant system and a source of alkalinity. The source of alkalinity is an alkali metal aluminate preferably sodium aluminate at a concentration effective to have at least about 25 ppm of the alkali aluminate present in the wash solution measured as alumina. The wash solution is then separated from the laundered items and its pH reduced to about 9 or less. A destabilizing polymer such as diallyldimethyl ammonium chloride can be added. This combination causes the oil and grease to separate from the wash solution and float to the surface along with the sodium aluminate. If the concentration of the sodium aluminate is above about 100 ppm preferably about 250 ppm, there is no need to add the destabilizing polymer. This does not affect the overall efficiency of the detergent, yet significantly improves the ability to separate the oil and grease from the waste wash solution.Type: GrantFiled: July 20, 1995Date of Patent: June 25, 1996Assignee: Diversey CorporationInventor: Dave Tibbitts
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Patent number: 5518632Abstract: A method for separating water soluble, polymerizable resin from rinse water containing such resin which comprises adjusting the specific gravity of the rinse water so that the resin floats on the surface of the rinse water. The resin is then removed and purified for reuse.Type: GrantFiled: March 25, 1994Date of Patent: May 21, 1996Inventor: Thomas W. Juday
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Patent number: 5514282Abstract: A system and related method for the treatment of dairy and other food processing plant wastewaters provides recoverable by-products from two separate stages and a final water effluent clean enough for direct discharge or process reuse. The system provides an effective alternate to conventional wastewater treatment and includes, as its operating steps which provide useful by-products, dissolved air flotation and membrane separation. The recoverable by-products from these two unit operations are high in amino acids and provide sufficient nutritional value to permit their use as animal feed or fertilizer products.Type: GrantFiled: April 1, 1994Date of Patent: May 7, 1996Inventors: David C. Hibbard, Bala Raghunath, Craig S. Guyse
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Patent number: 5512134Abstract: A process for removing printing inks from printed wastepaper in the presence of a deinking chemical is provided. In this process printed wastepaper is disintegrated to form a paper stock suspension and the detached printing ink particles are removed in known manner by flotation or washing in another stage. In this process, alkoxylates of blown oils are used as the deinking chemical. The deinking chemical is added during disintegration and/or before the flotation or washing step. Preferably, the printed wastepaper is disintegrated in the presence of 0.02 to 2% by weight and preferably 0.1 to 0.8% by weight, based on air-dry paper stock, of alkoxylates of blown oils. This deinking chemical also removed printing inks from paper circuit waters.Type: GrantFiled: July 29, 1994Date of Patent: April 30, 1996Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Peter Daute, Berthold Schreck, Klaus Hornfeck
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Patent number: 5510014Abstract: An aged tin or tin alloy plating bath is regenerated by adding a water-soluble polymer as a coagulant and a polymeric flocculant to remove sludge.Type: GrantFiled: September 1, 1995Date of Patent: April 23, 1996Assignee: Mac Dermid, IncorporatedInventor: Hiroyoshi Murayama
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Patent number: 5501798Abstract: Disclosed is an improved method for extending the useful life of a reverse osmosis membrane having a high pressure side and a low pressure side, the membrane used for separating soluble and sparingly soluble inorganic materials from an aqueous solution, the process comprising introducing an aqueous solution containing the soluble and sparingly soluble inorganic materials to the high pressure side of a reverse osmosis membrane and pressurizing the aqueous solution on said high pressure side to produce liquid on the low pressure side substantially free of said inorganic materials. Solution containing concentrated inorganic materials is transformed from the high pressure side of the reverse osmosis membrane to a high pressure side of a microfiltration membrane, and soluble inorganic materials transferred to the high pressure side of the microfiltration membrane was precipitated to provide solution containing particles of the inorganic materials.Type: GrantFiled: April 6, 1994Date of Patent: March 26, 1996Assignee: Zenon Environmental, Inc.Inventors: Riad A. Al-Samadi, Andrew Benedek
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Patent number: 5500131Abstract: Materials and methods relating to water treatment processes are described. More specifically, the process is non-toxic and is useful for the removal of algae, other suspended solids, or contaminants in surface waters or in potable water treatment. Coccolithic calcium carbonate can be used in combination with a flocculent such as aluminum chloride to obtain the desired results.Type: GrantFiled: April 5, 1994Date of Patent: March 19, 1996Inventor: Jean-Paul Metz
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Patent number: 5472619Abstract: A process for the separation and purification of fat-containing waste water including the step of adding an effective flocculating and oxidizing amount of a composition including:10-30% acetic acid5-20% peracetic acid15-25% hydrogen peroxide1-10% phosphoric acidbal. waterThe process may also include the addition of ferrous sulfate or other source of ionic iron to accelerate the action of the peracetic acid composition.Type: GrantFiled: September 3, 1993Date of Patent: December 5, 1995Assignee: Birko CorporationInventors: Frederick W. Holzhauer, Dana J. Johnson, Terry McAninch
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Patent number: 5454955Abstract: Hectorite is utilized in conjunction with a water soluble cationic coagulant to clarify waste water from the deinking of waste paper.Type: GrantFiled: March 25, 1994Date of Patent: October 3, 1995Assignee: Nalco Chemical CompanyInventors: William E. Albrecht, David W. Reed, James H. Smith
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Patent number: 5453203Abstract: Disclosed is a process and apparatus for purifying a low polluted water containing concurrently or selectively inadequate matters including heavy metals such as iron contents and manganese, and fine suspended matters, which comprises adding a reactant primarily containing a colloidal silica from a reactant charger to the polluted water stored in a primary tank to emulsify the inadequate matters; adding a coagulant primarily containing chitosan into the polluted water from a coagulant charger; feeding external air under high pressure by a pump into the polluted water, and separating the air from the polluted water, followed by dissolution of the air under pressure in the polluted water using a water separator; injecting the thus treated polluted water into a polluted water stored preliminarily in a secondary tank to generate very fine bubbles in polluted water stored in the secondary tank under releasing of the pressure; allowing the inadequate matters emulsified and flocculated to float up onto the water surfType: GrantFiled: October 22, 1993Date of Patent: September 26, 1995Assignees: Toyo Dynam Co., Ltd., Tokai Kosan Co., Ltd.Inventor: Tadao Higuchi
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Patent number: 5435808Abstract: A process for the curing of animal hides using a brine solution including the step of adding an effective bactericidal and flocculating amount of a composition comprising:10-30 wt. % acetic acid5-20 wt. % peracetic acid15-25 wt. % hydrogen peroxide1-10 wt. % phosphoric acidbalance waterOther peracids, such as, perlactic acid, percitric acid, perproprionic acid, perbenzoic acid, perpentenoic acid and perbutyric acid may be used.Type: GrantFiled: December 17, 1993Date of Patent: July 25, 1995Assignee: Birko CorporationInventors: Frederick W. Holzhauer, Dana J. Johnson, Terry McAninch
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Patent number: 5405743Abstract: Compounds and methods are disclosed for reversibly aggregating particles suspended in a liquid medium. The method comprises combining the liquid medium containing the particles with a polyionic polymer capable of aggregating the particles under conditions suitable for such aggregation. Thereafter, the particles are contacted with a chemical reagent capable of cleaving the polyionic polymer under conditions sufficient to reverse the aggregation. Optionally, magnetic particles are added to the liquid medium in the present method under conditions for non-specific binding and the medium including the aggregates is subjected to a magnetic field gradient to separate the aggregates from the medium. The compounds of the present invention are polyions. The aggregation of the particles is reversible upon contact with chemical agents which cleave at least some of the bonds within the polyionic polymer.Type: GrantFiled: June 29, 1994Date of Patent: April 11, 1995Assignee: Syntex (U.S.A.) Inc.Inventors: Thomas L. Tarnowski, Cheng-I Lin, Edwin F. Ullman
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Patent number: 5405541Abstract: The present invention comprises an improved method and apparatus for treating water in heat exchange systems. The present invention automatically and inexpensively provides an effective chemical to process water systems at times and in proportion to the need for water treatment in such systems. When used in evaporative cooling systems, the present invention adds the treatment chemical to the system via the make-up water. The make-up water acquires a substantially constant concentration of treatment chemical as it is passed through a device containing a treatment chemical. The constant concentration of chemical is achieved by dividing the make-up flow into two streams within the device, saturating the smaller of the two streams with chemical, and re-mixing the two streams. The biocide agent used in the preferred embodiment of the invention is prilled elemental iodine.Type: GrantFiled: June 17, 1992Date of Patent: April 11, 1995Assignee: Baltimore Aircoil Company, Inc.Inventors: Daniel H. Pope, Dennis R. Honchar, Wilbur L. Medairy
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Patent number: 5403567Abstract: Hydrogen sulfide or other gaseous component is removed from a gas stream containing the same by distribution of the gas stream in the form of fine bubbles by a rotary impeller and stationary shroud arrangement at a submerged location in an aqueous iron or other transition metal chelate solution, or other suitable catalyst, contained in an enclosed reaction vessel. Sulfur particles, or other insoluble phase product, of narrow particle size range formed in the reaction are floated off from the iron chelate solution. An oxygen-containing gas stream also is distributed in the form of fine bubbles by a separate rotary impeller and stationary shroud arrangement at a separate submerged location in the iron chelate solution. The second submerged location generally is separated from the first by a baffle extending downwardly in the reaction vessel from a top closure towards a bottom closure.Type: GrantFiled: April 6, 1994Date of Patent: April 4, 1995Inventors: James W. Smith, Nim Y. Lee
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Patent number: 5387405Abstract: A secondary polishing process for Bayer Process liquors suspension is described. The polishing process uses a combination of bio-polymers, particularly such bio-carbohydrates as dextran, with an inert insoluble solid, such as a filter aid, to treat the primary red mud settler overflow, then clarifying these treated overflow liquors in a secondary clarifier. Results provide for from 0-20 milligrams per liter suspended solids, often from 0-5 ppm suspended solids, and may make sand filter or Kelly filter operation an option in the Bayer Process.Type: GrantFiled: June 24, 1993Date of Patent: February 7, 1995Assignee: Nalco Chemical CompanyInventors: Lawrence J. Connelly, Robert P. Mahoney, Ralph W. Kaesler, Robert L. Wetegrove
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Patent number: 5382378Abstract: A stable blended product comprising a melamine aldehyde, urea aldehyde or melamine-urea aldehyde and colloidal silica is useful as a detackifier for solvent-borne paints and other resinous materials. This product is also useful as a conditioning agent prior to collection of water-borne paints, a treatment for water containing oils or greases, a color-remover in natural waters, and for enhanced removal of suspended solids.Type: GrantFiled: February 10, 1993Date of Patent: January 17, 1995Assignee: Calgon CorporationInventors: Robert J. Guerrini, Paul A. Rey
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Patent number: 5370993Abstract: Compounds and methods are disclosed for reversibly aggregating particles suspended in a liquid medium. The method comprises combining the liquid medium containing the particles with a polyionic polymer capable of aggregating the particles under conditions suitable for such aggregation. Thereafter, the particles are contacted with a chemical reagent capable of cleaving the polyionic polymer under conditions sufficient to reverse the aggregation. Optionally, magnetic particles are added to the liquid medium in the present method under conditions for non-specific binding and the medium including the aggregates is subjected to a magnetic field gradient to separate the aggregates from the medium. The compounds of the present invention are polyions. The aggregation of the particles is reversible upon contact with chemical agents which cleave at least some of the bonds within the polyionic polymer.Type: GrantFiled: May 12, 1992Date of Patent: December 6, 1994Assignee: Syntex (U.S.A.) Inc.Inventors: Thomas L. Tarnowski, Cheng-I Lin, Edwin F. Ullman
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Patent number: 5360169Abstract: Described are a process and device for recycling articles containing metals or metal vapors, in particular mercury-vapor lamps. The articles are fed into a container containing a liquid which converts the metal or metal vapor into harmless compounds, in particular sulphides. In the container, the articles are pushed into the liquid and then destroyed under the liquid, releasing the metal or metal vapor, the liquid acting as a protective layer and ensuring that the metal or metal vapor is trapped immediately is released. The container is emptied at intervals diately it is released. The container is emptied at intervals and the contents transferred to a central processing plant.Type: GrantFiled: November 19, 1992Date of Patent: November 1, 1994Assignee: Ubib Unternehmensberatungs GmbHInventor: Antonius Kohler
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Patent number: 5332506Abstract: The invention provides a method of recovering water from an acid workover, the water including dispersed solids and emulsified oil. According to the method, the water is treated with an effective amount of a dispersion of a water-soluble cationic polymer.Type: GrantFiled: December 13, 1993Date of Patent: July 26, 1994Assignee: Nalco Chemical CompanyInventors: Robert A. Marble, Timothy L. Sweeney
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Patent number: 5328677Abstract: An apparatus and process for the removal and recovery of sulfides from tannery waste water or liquor. The apparatus comprises a closed vessel, the sulfide-bearing liquor is introduced into a first or acidulation zone of the vessel and mixed with acid to decrease the pH, preferably to a value below 4.0, and generate hydrogen sulfide. The acidified liquor is then overflowed into a second or desorption zone of the vessel and slowly agitated and conveyed through the second zone by disc conveyors to release the hydrogen sulfide gas from the liquor. A slight vacuum is drawn on the vessel causing the released hydrogen sulfide gas to be drawn into a third reaction zone of the vessel, where the gas combines with sodium hydroxide solution to form sodium sulfhydrate. The effluent from the second zone can be filtered or dewatered and the filtrate discharged to a disposal site while the proteinaceous solids can be recovered for use as fertilizer.Type: GrantFiled: June 17, 1992Date of Patent: July 12, 1994Assignee: PVL Limited Partnership IInventors: Richard G. Waite, Paul R. Erickson
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Patent number: 5320759Abstract: A process for selectively recovering dissolved heavy metals from a solution is disclosed that involves selectively reacting a xanthate with such dissolved heavy metals. Selective reaction of a xanthate with selected dissolved heavy metals is accomplished by conducting the reaction under conditions such that only some of the heavy metals react with the xanthate, to the exclusion of reaction with other dissolved heavy metals. Selectivity of the reaction is particularly influenced by the pH at which the reaction occurs. Typically, the reaction should occur at a pH below about 4.0. Xanthates, once reacted, can be separated from the heavy metal xanthate reaction product and recycled for use within the process. Purified heavy metal product can be produced if desired.Type: GrantFiled: June 11, 1992Date of Patent: June 14, 1994Assignee: Hazen Research, Inc.Inventor: Enzo Coltrinari
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Patent number: 5308499Abstract: An effluent treatment process having the steps of: a) adding a coagulant to the effluent to concentrate the organic material therein; b) treating the thus concentrated organic material with a mixture of a cationic polymer of copolymer in the presence of an anionic surfactant, a nonionic surfactant or both; and c) separating the organic material from the effluent by flotation.Type: GrantFiled: January 7, 1992Date of Patent: May 3, 1994Assignee: Commonwealth Scientific and Industrial Research OrganisationInventors: David R. Dixon, Tiong C. Ha
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Patent number: 5302296Abstract: Materials such as amines, alcohols, aminoalcohols, ethers and mixtures thereof, including halogenated adducts thereof, have been found to be useful floc modifiers for water clarifiers to form an effective overall water clarifier composition. The water clarifier portion of the composition is a dithiocarbamate. The floc modifier of a particular water clarifier composition need not be the same compound that is reacted with carbon disulfide (CS.sub.2) to make the water clarifier portion of the novel compositions.Type: GrantFiled: February 22, 1993Date of Patent: April 12, 1994Assignee: Baker Hughes IncorporatedInventors: Eric J. Evain, Hartley H. Downs, Daniel K. Durham
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Patent number: 5281339Abstract: A method of recovering contaminants from suspension or solution in a liquor comprises the steps of forming a foam of the liquor, displacing said foam onto a drainage device to dry said foam and separate the liquor said contaminants being retained in the dried foam and the drained liquor being reduced in contaminant content.Type: GrantFiled: December 6, 1991Date of Patent: January 25, 1994Assignee: ICI Australia Operations Proprietary LimitedInventors: David E. Mainwaring, Ian H. Harding, Peter Sanciolo
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Patent number: 5269939Abstract: A waste stream such as from an animal or poultry processing plant is mixed with bentonite or Grafted Bentonite and then with liquid Chitosan as natural flocculents to form a rigid floc which removes fats, oils, greases, and/or proteins from the waste stream. The flocculated solids (sludge) is removed and dried, and either formed into granules or pellets. The recovered material may be used as animal feed, when appropriate. However, it is particularly useful when mixed with coal fines and pelletized to form fuel pellets or used in granule form as a fuel source.Type: GrantFiled: July 13, 1992Date of Patent: December 14, 1993Inventors: Edward L. Laurent, Patricia D. Laurent
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Patent number: 5246590Abstract: A system is disclosed for controlling the amount of treatment composition, e.g., cationic coagulant, to be introduced into an aqueous medium, e.g., a laundry waste water, having a content of non-solid fats, oils and/or grease (FOG) which is to be reduced. This system comprises a detector adapted to determine the electric charge value of a material comprising the aqueous medium having a FOG which is to be reduced and to provide a signal indicative of this electric charge value and an automatic processor provided with a relationship of the amount of treatment composition to be introduced into the aqueous medium to reduce the FOG of the aqueous medium to a given level as a function of the signal, and adapted to receive the signal and to provide a control signal to a source of treatment composition to control the amount of treatment composition introduced from the source of treatment composition into the aqueous medium.Type: GrantFiled: September 15, 1992Date of Patent: September 21, 1993Assignee: Dober Chemical CorporationInventors: John G. Dobrez, Michael A. Reeks
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Patent number: 5238663Abstract: The invention relates to a process for recovering nickel from industrial effluents, characterized in thata) the effluent loaded with nickel is allowed to settle in a corrugated-plate separator (1) for the removal of solid constituents contained therein,b) a flocculant is added and the mixture is neutralized with alkali or mineral acid,c) after flocculation, the mixture is again allowed to settle in a corrugated-plate separator (3) andd) filtered through a sand filter (4),e) the filtered effluent is passed through a sequestering cation exchanger system containing three exchanger columns, the first column (5) being loaded up to breakthrough of nickel, the second column (6) serving as a guard filter and the third column (7) being regenerated or standing by in the freshly regenerated state,f) the particular column loaded with nickel is regenerated with dilute mineral acid, andg) the regenerate is treated with sodium hypophosphite in the presence of catalytic quantities of sodium borohydride, and to equipment forType: GrantFiled: September 12, 1991Date of Patent: August 24, 1993Assignee: Merck Patent Gesellschaft mit beschrankter HaftungInventors: Werner Vikari, Ralf Steinstrasser, Heinrich Nikolaus, Gunther Feldmann-Schlohbohm, Klaus Behne
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Patent number: 5236598Abstract: A novel method of treating circulating water containing over-sprayed, water-borne paint, such as in a paint spray booth operation, comprises adjusting the alkalinity of the paint spray booth water to between about 20 and 600 ppm, on a calcium carbonate basis, by adding a designated alkalinity source thereto, adding a cationic potato starch to the water, contacting the over-sprayed, water-borne paint with the alkalinity-adjusted paint spray booth water after addition of the cationic potato starch, adding an effective amount of a polymer floccing agent to the paint spray booth water, and removing resulting sludge from the paint spray booth water.Type: GrantFiled: October 15, 1992Date of Patent: August 17, 1993Assignee: Calgon CorporationInventors: Wood E. Hunter, Lewis D. Morse
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Patent number: 5230808Abstract: A flocculating agent which comprises: a particulate ethylene oxide polymer present in an amount of between about 20 to about 35% by weight; an inert liquid vehicle comprising a mixture of a glycol which is present in an amount between about 25 to about 30% by weight, and glycerine which is present in an amount between about 45 to about 50% by weight, wherein the specific gravity of the ethylene oxide polymer is approximately the same as the specific gravity of the inert liquid vehicle; and a suspension agent which is present in an amount between about 0.4 to about 0.6% by weight, wherein the flocculating agent has a viscosity in the range between about 1800 to about 5900 cps.Type: GrantFiled: September 24, 1992Date of Patent: July 27, 1993Assignee: Nalco Canada Inc.Inventors: Daniel K. Chung, Stephen B. Warrick
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Apparatus and process for the separation and reclamation of selected components in grease trap waste
Patent number: 5225085Abstract: A process for separating the grease, solids and water components from grease such as grease traps and fry grease. The grease is collected and introduced into a primary holding tank to effect primary crude separation. The grease is removed to a second stage separator for further concentration. The water and solids are separately directed to a second stage to separate these components. The separated water is treated suitable for discharge into a sewer. The solids are dried and the solids and grease are then suitable for re-use. In the preferred embodiment, the separators are centrifuges. Heating of the grease may also be necessary to achieve proper viscosity for handling and to remove bacteria.Type: GrantFiled: November 7, 1991Date of Patent: July 6, 1993Inventors: Laksir P. Napier, Tommy L. Mortensen, Dawn F. Abbey -
Patent number: 5223147Abstract: Contaminated soils are treated in that an aqueous slurry of the soil is separated into a coarse fraction and a fine fraction, the fine fraction is subjected to flotation, the resulting froth is dewatered and then carried away as a pollutant concentrate, and the underflow from the flotation is dewatered and is then carried away as purified soil. An emulsified oily vegetable oil is used as a collector agent for the selective flotation or an emulsified light mineral oil is used as a collector agent for the selective flotation and a light mineral oil is stirred as a conditioning agent into the fine fraction before it is subjected to the selective flotation.Type: GrantFiled: December 6, 1991Date of Patent: June 29, 1993Assignee: Metallgesellschaft AktiengesellschaftInventors: Friedrich Rosenstock, Jochen Guntner, Elmar Haite, Horst Dittmann
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Patent number: 5204007Abstract: Method for removing suspended solids from a stream of waste water for subsequent use as an animal feed, wherein bentonite and an anionic polymer are added to the waste water which is maintained within a predetermined pH range. No metallic salts or other materials unacceptable as food additives are added to the waste water stream to facilitate flocculation of the bentonite and suspended solids. The pH range, maintained from 3.5 to 9.0 and optimally from 4.0 to 5.0, facilitates the coagulation of the suspended solids without the use of the metallic salts or other such additives. Microscopic air bubbles are used to float the flocculated bentonite and solids to the surface. In some cases the materials may be floated by gravity forces alone without the use of air bubbles. These floated materials are removed by skimmers or other top-floating solids removing apparatus commonly known in the industry and rendered into animal feed products.Type: GrantFiled: December 30, 1991Date of Patent: April 20, 1993Assignees: Kenneth L. Mosley, Hans E. LundgrenInventors: Kenneth L. Mosley, Hans E. Lundgren
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Patent number: 5178770Abstract: A method of treating BCTMP/CTMP wastewater to improve retention and purification of cellulose fiber suspension and clarification of the BCTMP/CTMP wastewater which comprises the addition of a cationic, water soluble coagulant having a molecular weight less than 15,000,000 in an amount of about 1 to about 300 ppm; and a high molecular weight flocculant selected from the group consisting of: nonionic polymers having a molecular weight in the range between about 500,000 to about 30,000,000, low charge cationic polymers having a molecular weight in the range between about 5,000,000 to about 30,000,000, and low charge anionic polymers having a molecular weight in the range between about 5,000,000 to about 30,000,000, in an amount of about 0.1 to about 100 ppm.Type: GrantFiled: July 12, 1991Date of Patent: January 12, 1993Assignee: Nalco Canada Inc.Inventor: Daniel K. Chung
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Patent number: 5151195Abstract: Copolymers of an acrylic compound and a polymerizable quaternary ammonium compound are useful as flotation-aids for removing oils and/or solid materials from aqueous systems. The polymerizable quaternary ammonium compounds are 1-alkoxy-2-hydroxy propyl quaternaries of N-(N'N'-dialkylaminoalkyl)acrylamides.Type: GrantFiled: August 11, 1988Date of Patent: September 29, 1992Assignee: Petrolite CorporationInventors: Rudolf S. Buriks, Allen R. Fauke
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Patent number: 5143623Abstract: A method and apparatus for capturing descending particle matter and chemical precipitate so that this material can be removed from a water body on a timely basis to remove offending nutrients. This method uses a plurality of funnel shaped collection chambers each attached at its apex to a collection conduit. Descending particle matter and precipitate concentrates at the apex of the chamber where a flow control valve closes upon activation of a suction on the receiving conduit so that external flow is restricted and flow velocity within the tube is maximized to aid suspension and removal of accumulated material. A tube selector is utilized to apply suction to only one collection conduit at a time, and a chemical feed apparatus is employed to produce the chemical precipitate above the receiving chambers. By this method, nutrients and particle matter can be removed from water bodies thus restoring their water quality.Type: GrantFiled: June 17, 1991Date of Patent: September 1, 1992Inventor: Brian L. Kroll
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Patent number: 5132025Abstract: A method of recycling or destroying the components of viscous oil well drilling mud and saltwater which includes reducing the mud to an aqueous slurry; separating and collecting the useable hydrocarbons from the slurry by evaporation or chemical action; injecting deleterious substances including saltwater into an environmentally approved injection well; and or forming fertilizer pellets from remaining dehydrated solids.Type: GrantFiled: December 3, 1990Date of Patent: July 21, 1992Inventor: Ricky A. Hays
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Patent number: 5128046Abstract: Improved water quality of overboard waters discharged from off-shore oil producing rigs is obtained by treating oily produced waters from a crude oil separator, and prior to exposure to air, with an effective coalescing amount of a combination of an iron chelating agent and various polymeric coagulating/coalescing agents. The preferred chelating agent is citric acid, or its salts, EDTA, HEDTA, or mixtures thereof. The polymeric coagulating/coalescing agents may be anionic, cationic, ampohoteric, but are most preferably copolymers of acrylamide with at least one of the monomers chosen from the group consisting of acrylic acid, methacrylic acid, DMAEA, DMAEM, or their acid of quaternary salts, DADMAC, MAPTAC, AMPS, and the like.Type: GrantFiled: April 16, 1990Date of Patent: July 7, 1992Assignee: Nalco Chemical CompanyInventors: Robert A. Marble, Michael L. Braden
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Patent number: 5104549Abstract: There is disclosed a waste treatment process for alkaline waste liquid in which substances to be removed exist in ionic and colloidal states. In the process, powdered tannin is added to the waste liquid to produce solid substance of the tannin and to capture the substances to be removed on the solid substance. Then, the waste liquid is subjected to filtration to thereby separate the solid substance including the substances to be removed.Type: GrantFiled: April 17, 1991Date of Patent: April 14, 1992Assignee: Mitsubishi Nuclear Fuel Co.Inventors: Yoshinobu Kamei, Wataru Shirato
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Patent number: 5076937Abstract: Method and apparatus for removing impurities from a laundry wash effluent including the steps and means therefor of acidifying the solution, infusing a gas into the solution and coalescing the released contaminant droplets by means of baffle plates into droplets sufficient to achieve buoyany with respect to the solution. The resulting top layer of buoyant droplets is skimmed from the solution and the remaining solution is adjusted to a neutral pH for discharge.Type: GrantFiled: July 26, 1990Date of Patent: December 31, 1991Assignee: Unitog Rental Services, Inc.Inventor: Stephen M. Montgomery
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Patent number: 5076939Abstract: A novel method of treating circulating water containing over-sprayed water-based or solvent-based paint, such as in a paint spray booth operation, comprises adjusting the alkalinity of the paint spray booth water by adding an alkalinity source thereto, contacting the oversprayed paint with the alkalinity-adjusted water and with an alumina coated silica sol added to the water, adding an effective amount of a polymer floccing agent to the water, and removing resulting sludge from the water.Type: GrantFiled: May 2, 1991Date of Patent: December 31, 1991Assignee: Calgon CorporationInventors: W. Eugene Hunter, Lewis D. Morse
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Patent number: 5030359Abstract: Fats and proteins in wastewater are commonly concentrated in a dissolved air flotation cell as a sludge ("skimmings") which has a very high water content, even after centrifuging or the like. A process is provided to reduce the water content of the sludge thereby reducing the cost of disposal of the sludge.Type: GrantFiled: November 8, 1990Date of Patent: July 9, 1991Assignee: FMC CorporationInventors: Harry M. Castrantas, Frank E. Caropreso
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Patent number: 5009792Abstract: The present invention relates to a method for clarifying aqueous salt solutions containing inorganic insolubles and possibly also organic components. Air is introduced into a recirculating system for the aqueous solution, pressurized and then released, thus forming microbubbles in the solution. Fluocculants are added and the presence of foam forming organic components is ensured. The foam formed is back-mixed into the solution while dissolved air flotation is interrupted, whereupon it may be restarted for flotation of possible remaining contaminants. The foam forming process can be performed in the presence of surfactants, wax and/or oil for forming a stable foam to be back-mixed into the solution for releasing entrapped microbubbles thereto. The method can be carried out by continuously supplying flocculant and solution to the flotation vessel. Dissolved air flotation and back-mixing are then carried out sequentially.Type: GrantFiled: October 24, 1989Date of Patent: April 23, 1991Assignee: Norsk Hydro a.s.Inventors: Jarl M. Pettersen, Arild Nilsson, Robert M. Millaway
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Patent number: 4971775Abstract: A method for removing iron(III), copper(II), zinc(I) and nickel(II) from an effluent containing chelant (EDTA, DEPA, HOEDTA) comprising treating the effluent with a soluble calcium compound (e.g., Ca(OH).sub.2) CaCl.sub.2, Ca(NO.sub.3).sub.2) in a molar equivalent to the chelant in combination with a monovalent hydroxide to a pH greater than 12.4 and then adding an effective amount of a dialkyldithiocarbamate (e.g.; sodium-N,N-diethyldithiocarbamate) to precipitate the metal hydroxides and nickel dialkyldithiocarbamate. Heating the solution to about 180 F. further speeds up the removal of the nickel(II). The nickel concentration of spent chelant cleaning solution can be reduced to less than 1 ppm.Type: GrantFiled: June 30, 1987Date of Patent: November 20, 1990Assignee: Dowell SchlumbergerInventors: Edgar F. Hoy, Stanley B. McConnell
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Patent number: 4966713Abstract: In a processing for treating waste containing effluent water from a food processing plant, the effluent water is contacted with a flocculant comprising a crude algal composition or a crude alkali processed algal composition obtained from algae selected from the classes Rhodophyceae, Cyanophyceae, Chlorophyceae and Phaeophyceae, at an acidic pH. A floc, which contains substantially all of the solid waste components of the effluent water, is formed as a result of the treatment process, and can be recovered for use in animal feedstocks or as other products such as fertilizers, or safely disposed of an in landfill operations. The clarified effluent water is sufficiently waste free that it can be forwarded to a secondary treatment facility or back into the food processing plant for reuse in certain plant operations.Type: GrantFiled: April 13, 1989Date of Patent: October 30, 1990Assignee: FMC CorporationInventors: Daniel W. Keys, Grady W. Burgin
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Patent number: 4966712Abstract: A flotation collector is formed on a copolymer comprising (A) 2 to 95 mol % of a structural unit represented by the general formula I: ##STR1## wherein R.sup.1 is H or methyl, Y is --O-- or --NH--, A is C.sub.1-4 alkylene, C.sub.2-4 hydroxyalkylene, or phenylene, and Z is ##STR2## wherein R.sup.2, R.sup.3, and R.sup.4 are independently H, C.sub.1-12 alkyl or C.sub.7-10 aralkyl and X.sup..crclbar. is anion pair, (B) 5 to 98 mol % of a structural unit represented by the general formula II: ##STR3## wherein R.sup.5 is H or methyl and W is C.sub.6-8 aryl, ##STR4## wherein n is 2 to 4 and m is 0 to 20, ##STR5## wherein R.sup.6 is C.sub.1-18 alkyl, C.sub.5-8 cycloalkyl, C.sub.7-10 aralkyl, or C.sub.6-18 aryl, and (C) 0 to 50 mol % of other structural unit. A method for the treatment of an inorganic substance-containing water system by the use of the flotation collector.Type: GrantFiled: January 19, 1989Date of Patent: October 30, 1990Assignee: Nippon Shokubai Kagaku Kogyo Kabushiki KaishaInventors: Hideyuki Nishibayashi, Yoshiaki Urano, Nobuhiro Matsuura, Yoshiyuki Hozumi, Fumio Watanabe
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Patent number: 4957633Abstract: The present invention concerns a floatation clarifying/flocculating procedure for purifying liquid, in which particles of impurities present in a liquid to be purified or impurities dissolved in the liquid which have been converted into particle form with the aid of flocculating chemicals, are separated from the liquid to be purified and carried to the surface of the liquid, to form thereon a sludge bed. The sludge bed is conducted out through a sludge trough to a sewer or equivalent, and flocculating chemicals are then added to the remaining liquid thus already at least partially purified, so that the chemicals form dirt particles with the impurities still present in a dissolved state but which have not yet been removed from the remaining liquid.Type: GrantFiled: February 7, 1989Date of Patent: September 18, 1990Inventor: Oiva Suutarinen