Chemically Specified Precipitant, Coagulant, Or Flocculant Patents (Class 210/705)
  • Patent number: 4454047
    Abstract: A process of treating an aqueous system which comprises adding to the system a stable emulsion of an aqueous internal phase in a non-aqueous external phase. The aqueous internal phase contains a homo- or a copolymer of an acrylamido alkylene quaternary ammonium salt.
    Type: Grant
    Filed: May 18, 1982
    Date of Patent: June 12, 1984
    Assignee: Petrolite Corporation
    Inventors: Harold L. Becker, Rudolf S. Buriks
  • Patent number: 4387034
    Abstract: A collector for use in concentrating metal values in ores by flotation, said collector comprising a synergistic mixture of O-isopropyl N-ethylthionocarbamate and O-isobutyl N-methylthionocarbamate. Ore dressing flotation methods wherein said mixture serves as collector are also provided.
    Type: Grant
    Filed: October 23, 1981
    Date of Patent: June 7, 1983
    Assignee: Thiotech, Inc.
    Inventors: Kim N. Unger, Dennis V. Smeltzer
  • Patent number: 4385995
    Abstract: Method of recovering and using heretofore lost or discarded coal fines which are a product of various coal washing processes comprising coating the fine coal with a oil/water mixture, separating excess oil/water mixture, forming into particles as by rolling or tumbling and drying to recover a strong pellet suitable for shipment.
    Type: Grant
    Filed: August 15, 1980
    Date of Patent: May 31, 1983
    Inventor: Michael A. Dondelewski
  • Patent number: 4382823
    Abstract: A process for removing color, turbidity, flavor, and odor from impure, high Brix, sugar syrup involves entrapping the sugar impurities in an insoluble, primary calcium phosphate or aluminum hydroxide floc at about neutral pH, dividing the sugar syrup into a small portion and a large portion, aerating the small portion of the syrup at a specific Brix, recombining the small portion and the large portion, adding a polyelectrolyte to convert the primary floc into a secondary floc to which the air bubbles easily adhere and to cause flotation of said secondary floc, thus forming a scum mat at the top of the vessel. The purified sugar syrup is then filtered with or without activated carbon and small amounts of a filter aid to produce a sugar syrup with substantially reduced color, turbidity, flavor, and odor. The sugar in the scum is recovered by mixing it with water and allowing a second flotation to take place without any further aeration or chemicals addition.
    Type: Grant
    Filed: September 24, 1981
    Date of Patent: May 10, 1983
    Assignee: The Coca Cola Company
    Inventor: Geir V. Gudnason
  • Patent number: 4377473
    Abstract: A method for separating the exinite group macerals from the total coal by froth flotation in the presence of at least one short chain alcohol frothing agent and at least one methyl polyglycol type frothing agent in a first froth flotation zone to produce an exinite and other coal maceral-rich stream which is thereafter subjected to froth flotation in a second froth flotation zone in the presence of a short chain alcohol frothing agent to produce an exinite group maceral-rich stream and a stream rich in other coal macerals with the exinite-rich stream thereafter being mixed with an additional quantity of a short chain alcohol frothing agent and passed to a third froth flotation zone to produce an exinite group maceral group concentrate stream which is thereafter processed to produce a particulate exinite maceral group concentrate.
    Type: Grant
    Filed: July 16, 1981
    Date of Patent: March 22, 1983
    Assignee: Atlantic Richfield Company
    Inventors: Timothy J. Laros, Richard D. Pick
  • Patent number: 4376708
    Abstract: This invention relates to ureylene prepared by reacting an oxyalkylated polyamine with urea and to uses of such ureylene for example in removing oils, solids, and combinations thereof from aqueous systems, etc.
    Type: Grant
    Filed: May 11, 1981
    Date of Patent: March 15, 1983
    Assignee: Petrolite Corporation
    Inventor: Thomas J. Bellos
  • Patent number: 4372844
    Abstract: An extender oil characterized as having a viscosity at 100.degree. F. in a range of about 40 to about 250 SUS and an aromatic content in the range of about 60 to about 85 wt % of the total collector composition of which about 10 to about 20 wt % of the total collector composition is chosen from among benzothiophenes and dibenzothiophenes. The above-described extender oil blended with the tall oil in a ratio of tall oil to extender oil in a range of about 75 wt %: to about 25 wt % to about 25 wt %:about 75 wt %. The extender oil described above blended with a fatty amine in a ratio of fatty amine to extender oil in a range of about 50 wt %:50 wt % to about 10 wt %:90 wt %. The flotation process for recovering phosphates and/or potash employing the compositions described above.
    Type: Grant
    Filed: June 29, 1981
    Date of Patent: February 8, 1983
    Assignee: Phillips Petroleum Company
    Inventors: Clarence R. Bresson, Robert M. Parlman
  • Patent number: 4372864
    Abstract: A reagent and a method for using the reagent for treating a solid material disposed in a liquid medium and having an oxygen-controlled surface condition. The reagent includes a liquid hydrocarbon, a reducing material and an activator material. The liquid hydrocarbon such as mineral oil has a specific gravity different from the specific gravity of the liquid medium. The reducing material such as phosphorous pentasulfide is present in an amount sufficient to establish a reducing environment around the solid material for breaking the oxygen control on the surface of the solid material. The activator material such as zinc thiophosphate is present in an amount sufficient to establish an electrostatic charge on the solid material after the oxygen-controlled surface condition has been broken. A more specific feature of the invention is directed to the method of flotation of extremely fine bituminous coal having an oxygen-controlled surface condition.
    Type: Grant
    Filed: December 15, 1977
    Date of Patent: February 8, 1983
    Inventor: James R. McCarthy
  • Patent number: 4348287
    Abstract: This invention relates to the use of zirconium compounds and complexes thereof as flotation aids in a wide variety of systems.
    Type: Grant
    Filed: May 26, 1981
    Date of Patent: September 7, 1982
    Assignee: Petrolite Corporation
    Inventor: Fred W. Jenkins
  • Patent number: 4340487
    Abstract: A process is provided for removing suspended solids from a waste water stream exiting from a wet rendering plant, a centrifugal rendering plant and/or a hide curing brine system before the stream enters a public sewer system. Such waste water typically has some oils, fats and/or protein particles in addition to easily settled solids previously removed therefrom. The waste water is delivered to a holding tank wherefrom the waste water is drawn and pH adjusted with sodium carbonate, sodium hydroxide, or the like. Air is injected into the pH adjusted waste water along with flocculating agent such as ferric sulfate. Thereafter, the waste water is injected at a relatively low velocity into a flotation tank wherein flocculated wet solids urged upwardly by the injected air are allowed to float to the top of the tank and water which is relatively low in suspended solids and biological oxygen demand is removed from the lower portion of the tank and is pH adjusted and sent to a sewer.
    Type: Grant
    Filed: December 24, 1980
    Date of Patent: July 20, 1982
    Inventor: Michael R. Lyon
  • Patent number: 4340488
    Abstract: The invention serves for conditioning and sterilization of sludges originating from sewage treatment plants, and from water preparing plants, respectively, in such a manner, that both the homogenization and the mixing with coagulating agent of the sludge as well as the flotation separation of solid phase are carried out by ultrasonic treatment, while the microorganisms, among them also the pathogene ones, are decomposed. The conditioning agent added in the final phase of the ultrasonic treatment of a few minutes is metallic salt in case of biological sludges, and polyeletrolyte in case of sludges containing chemicals.
    Type: Grant
    Filed: April 6, 1981
    Date of Patent: July 20, 1982
    Assignee: Vizgazdalkodasi Tudomanyos Kutatokozpont
    Inventors: Andras Toth, Emese Toth nee Palotai, Jozsef Olah, Jozsef Bitskey, Lajos Bulkai
  • Patent number: 4337123
    Abstract: A process for the production of fuel alcohol from fermented plant mashes, without vinasse. In this process alcohol is produced from fermented mashes obtained from diverse raw plant materials. The process introduces a treatment of the mash, after fermentation and before distillation, by which treatment several substances contained in the fermented mash are removed, so that the distillation is fed with a purified beer. Distillation of this beer produces alcohol and does not produce vinasse.
    Type: Grant
    Filed: August 29, 1980
    Date of Patent: June 29, 1982
    Assignee: Versa Consultoria Technica LTDA., CGC
    Inventors: Alvaro De Sa, Jacob M. Luksenberg
  • Patent number: 4320108
    Abstract: The invention relates to a process for the removal of metals, especially of iron and/or nickel and/or vanadium or their compounds, from carbon black. To this end, the invention provides for an aqueous carbon black suspension to be heated to a temperature of about 30.degree. to 90.degree. C., for chlorine to be passed therethrough with agitation. The chlorine gas is used in a stoichiometric excess, based on the metal content of the aqueous carbon black suspension. Next, the carbon black is separated from the aqueous suspension and dried.
    Type: Grant
    Filed: November 3, 1980
    Date of Patent: March 16, 1982
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Manfred Wolter, Gero Heymer
  • Patent number: 4311595
    Abstract: In a flotation method for purification of industrial or municipal waste water, in which the waste water comes in contact with electrodes having an electrical potential capable of electrolytically decomposing a portion of the waste water, thereby creating an ascending stream of gas bubbles, the waste water is mixed before or during the electrolytic decomposition with wettable particles of polymer material which are practically insoluble in water and have an absolute density of 1.3 g/cm.sup.3 at the most. Polymeric materials, especially polyalkane fibrids, are suitable for use as particles. This process makes it possible to purify oil-containing waste water by electroflotation without forming an oil film on the electrodes.
    Type: Grant
    Filed: August 25, 1980
    Date of Patent: January 19, 1982
    Assignee: BBC, Brown, Boveri & Company, Limited
    Inventor: Elias Julke
  • Patent number: 4308148
    Abstract: Water soluble polymeric flocculants are prepared by photopolymerizing olefinically unsaturated hydrophilic monomer(s), the photopolymerization recipe including a polyhydroxylated organic additive, such as gluconic acid. Such polyhydroxy compound facilitates solubilization of the resultant flocculants, without substantial decrease in the molecular weight thereof, and ensures against the by-production of water insoluble fractions.
    Type: Grant
    Filed: June 7, 1979
    Date of Patent: December 29, 1981
    Assignee: Rhone-Poulenc Industries
    Inventors: Jean Boutin, Jean Neel
  • Patent number: 4303780
    Abstract: This invention relates to ureylene prepared by reacting an oxyalkylated polyamine with urea and to uses of such ureylene for example in removing oils, solids, and combinations thereof from aqueous systems, etc.
    Type: Grant
    Filed: February 26, 1980
    Date of Patent: December 1, 1981
    Assignee: Petrolite Corporation
    Inventor: Thomas J. Bellos
  • Patent number: 4289628
    Abstract: The invention relates to a process for separating solids from liquid matter by means of gravity, using a three-dimensional filter element and an alluvial filter layer wherein a gas is fed into the medium to be treated prior to its introduction into the filter element in the form of fine or finest bubbles which accumulate on the solid particles. The particles loaded with air floated up rapidly to the upper level of the column of liquid in the filter element, forming a layer of sludge. Said layer built up continuously an alluvial filter layer at the internal surface of the water-permeable supporting filter element from the bottom upwards along the wall relative to the rising level of the liquid in the filter element. The process, realized in the presence or absence of flocculating agents, results in a higher separation degree with regard to the solids content as well as an increased elimination of the biological oxygen demand.
    Type: Grant
    Filed: May 28, 1980
    Date of Patent: September 15, 1981
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Dieter Disselbeck, Rudolf Richter
  • Patent number: 4282256
    Abstract: There is disclosed a method for the preparation of an animal feed supplement from fish cannery waste process water in which the water is maintained under aerobic conditions and is processed through a flotation cell to separate the oils and proteins contained in the water as a concentrated sludge. The sludge is dewatered, blended with a bulk, solid carrier preserved against oxidative spoilage of the lipids with an effective anti-oxidant, and dried in vacuum under low temperature conditions to obtain an animal feed supplement in dry particulate form. The processing of the waste water is done under aerobic conditions to promote the growth of yeast and non-toxic, aerobic, bacterial improve color and odor and texture, and enhance the feed value of the sludge recovered from the processing.
    Type: Grant
    Filed: October 22, 1979
    Date of Patent: August 4, 1981
    Assignee: Star-Kist Foods, Inc.
    Inventors: Vince J. Evich, Gerald C. Brown, Howard J. Dunn
  • Patent number: 4267059
    Abstract: An auxiliary for improving the retention of flushable solids, for accelerating the dewatering of suspensions and for more rapidly working up industrial waters, effluents and sludges by the addition of a basic water-soluble polymer being produced by reacting (a) an aliphatic polyethylene glycol ether amine and (b) a basic polyamino amide to form an intermediate product and (c) reacting said intermediate with an epihalohydrin, dihaloalkane, glyoxal-bis-acrylamide, bis-acrylamidoacetic acid, acrylamidoglycolic acid or tetraalkyloxyethane.
    Type: Grant
    Filed: October 15, 1979
    Date of Patent: May 12, 1981
    Assignee: Wolff Walsrode Aktiengesellschaft
    Inventors: Rudolf Behn, Lutz Hoppe, Branislav Bohmer
  • Patent number: 4263148
    Abstract: A process is disclosed for removing colloidal and non-colloidal humic matter from an aqueous solution of phosphoric acid, the process comprising (a) treating the phosphoric acid solution with a flocculant to flocculate the humic matter, (b) adding to the aqueous solution an effective amount of a phenol compound in order to destabilize the colloidal humic matter contained in the solution and to aid in the formation of froth, and (c) separating the humic matter from the solution by froth flotation.
    Type: Grant
    Filed: April 9, 1979
    Date of Patent: April 21, 1981
    Assignee: Earth Sciences, Inc.
    Inventors: Raymond D. Symens, Robert S. Rickard
  • Patent number: 4251362
    Abstract: The invention relates to a method of treating in particular polluting materials such as hydrocarbons. Said materials are processed with at least one basic product such as hydraulic, natural organic or synthetic binder and in particular the calcium sulphate semi-hydrates showing qualities required for a quick setting, hardening, sequestration and retention. More particularly, the basic products used are calcium sulphate semi-hydrates in the form ALPHA. Said basic products may be also used for the processing of residual sludges or waste waters.
    Type: Grant
    Filed: May 29, 1979
    Date of Patent: February 17, 1981
    Inventor: Etienne Tillie
  • Patent number: 4251363
    Abstract: Phosphate slimes are effectively settled by the sequential addition of effective amounts of a low molecular weight acrylamide: acrylic acid copolymer of high anionicity and a high molecular weight acrylamide: acrylic acid copolymer of low anionicity.
    Type: Grant
    Filed: September 11, 1979
    Date of Patent: February 17, 1981
    Assignee: American Cyanamid Company
    Inventors: Ralph J. Chamberlain, Richard E. Ellwanger
  • Patent number: 4224149
    Abstract: Use of an effective amount of a precipitant or sequestrant for calcium ions improves performance of anionic polymeric carboxylic acid flocculants in flocculating phosphate slimes.
    Type: Grant
    Filed: April 30, 1979
    Date of Patent: September 23, 1980
    Assignee: American Cyanamid Company
    Inventors: James S. Balcerski, Arthur M. Schiller, Arthur Snow
  • Patent number: 3933630
    Abstract: A process for the treatment of waste waters from the preparation of phthalic esters of alcohols to reduce the BOD and recover alcohols comprising treating the waste water with a strong acid and then extracting the acidified waste water with an alcohol, preferably the same as the alcohol used to form the phthalic ester.
    Type: Grant
    Filed: September 3, 1974
    Date of Patent: January 20, 1976
    Assignee: Rhone-Progil
    Inventors: Jacques Helgorsky, Michel Auroy