Abstract: A process of treating an aqueous system which comprises adding to the system a stable emulsion of an aqueous internal phase in a non-aqueous external phase. The aqueous internal phase contains a homo- or a copolymer of an acrylamido alkylene quaternary ammonium salt.
Abstract: A collector for use in concentrating metal values in ores by flotation, said collector comprising a synergistic mixture of O-isopropyl N-ethylthionocarbamate and O-isobutyl N-methylthionocarbamate. Ore dressing flotation methods wherein said mixture serves as collector are also provided.
Abstract: Method of recovering and using heretofore lost or discarded coal fines which are a product of various coal washing processes comprising coating the fine coal with a oil/water mixture, separating excess oil/water mixture, forming into particles as by rolling or tumbling and drying to recover a strong pellet suitable for shipment.
Abstract: A process for removing color, turbidity, flavor, and odor from impure, high Brix, sugar syrup involves entrapping the sugar impurities in an insoluble, primary calcium phosphate or aluminum hydroxide floc at about neutral pH, dividing the sugar syrup into a small portion and a large portion, aerating the small portion of the syrup at a specific Brix, recombining the small portion and the large portion, adding a polyelectrolyte to convert the primary floc into a secondary floc to which the air bubbles easily adhere and to cause flotation of said secondary floc, thus forming a scum mat at the top of the vessel. The purified sugar syrup is then filtered with or without activated carbon and small amounts of a filter aid to produce a sugar syrup with substantially reduced color, turbidity, flavor, and odor. The sugar in the scum is recovered by mixing it with water and allowing a second flotation to take place without any further aeration or chemicals addition.
Abstract: A method for separating the exinite group macerals from the total coal by froth flotation in the presence of at least one short chain alcohol frothing agent and at least one methyl polyglycol type frothing agent in a first froth flotation zone to produce an exinite and other coal maceral-rich stream which is thereafter subjected to froth flotation in a second froth flotation zone in the presence of a short chain alcohol frothing agent to produce an exinite group maceral-rich stream and a stream rich in other coal macerals with the exinite-rich stream thereafter being mixed with an additional quantity of a short chain alcohol frothing agent and passed to a third froth flotation zone to produce an exinite group maceral group concentrate stream which is thereafter processed to produce a particulate exinite maceral group concentrate.
Abstract: This invention relates to ureylene prepared by reacting an oxyalkylated polyamine with urea and to uses of such ureylene for example in removing oils, solids, and combinations thereof from aqueous systems, etc.
Abstract: An extender oil characterized as having a viscosity at 100.degree. F. in a range of about 40 to about 250 SUS and an aromatic content in the range of about 60 to about 85 wt % of the total collector composition of which about 10 to about 20 wt % of the total collector composition is chosen from among benzothiophenes and dibenzothiophenes. The above-described extender oil blended with the tall oil in a ratio of tall oil to extender oil in a range of about 75 wt %: to about 25 wt % to about 25 wt %:about 75 wt %. The extender oil described above blended with a fatty amine in a ratio of fatty amine to extender oil in a range of about 50 wt %:50 wt % to about 10 wt %:90 wt %. The flotation process for recovering phosphates and/or potash employing the compositions described above.
Abstract: A reagent and a method for using the reagent for treating a solid material disposed in a liquid medium and having an oxygen-controlled surface condition. The reagent includes a liquid hydrocarbon, a reducing material and an activator material. The liquid hydrocarbon such as mineral oil has a specific gravity different from the specific gravity of the liquid medium. The reducing material such as phosphorous pentasulfide is present in an amount sufficient to establish a reducing environment around the solid material for breaking the oxygen control on the surface of the solid material. The activator material such as zinc thiophosphate is present in an amount sufficient to establish an electrostatic charge on the solid material after the oxygen-controlled surface condition has been broken. A more specific feature of the invention is directed to the method of flotation of extremely fine bituminous coal having an oxygen-controlled surface condition.
Abstract: A process is provided for removing suspended solids from a waste water stream exiting from a wet rendering plant, a centrifugal rendering plant and/or a hide curing brine system before the stream enters a public sewer system. Such waste water typically has some oils, fats and/or protein particles in addition to easily settled solids previously removed therefrom. The waste water is delivered to a holding tank wherefrom the waste water is drawn and pH adjusted with sodium carbonate, sodium hydroxide, or the like. Air is injected into the pH adjusted waste water along with flocculating agent such as ferric sulfate. Thereafter, the waste water is injected at a relatively low velocity into a flotation tank wherein flocculated wet solids urged upwardly by the injected air are allowed to float to the top of the tank and water which is relatively low in suspended solids and biological oxygen demand is removed from the lower portion of the tank and is pH adjusted and sent to a sewer.
Abstract: The invention serves for conditioning and sterilization of sludges originating from sewage treatment plants, and from water preparing plants, respectively, in such a manner, that both the homogenization and the mixing with coagulating agent of the sludge as well as the flotation separation of solid phase are carried out by ultrasonic treatment, while the microorganisms, among them also the pathogene ones, are decomposed. The conditioning agent added in the final phase of the ultrasonic treatment of a few minutes is metallic salt in case of biological sludges, and polyeletrolyte in case of sludges containing chemicals.
Abstract: A process for the production of fuel alcohol from fermented plant mashes, without vinasse. In this process alcohol is produced from fermented mashes obtained from diverse raw plant materials. The process introduces a treatment of the mash, after fermentation and before distillation, by which treatment several substances contained in the fermented mash are removed, so that the distillation is fed with a purified beer. Distillation of this beer produces alcohol and does not produce vinasse.
Abstract: The invention relates to a process for the removal of metals, especially of iron and/or nickel and/or vanadium or their compounds, from carbon black. To this end, the invention provides for an aqueous carbon black suspension to be heated to a temperature of about 30.degree. to 90.degree. C., for chlorine to be passed therethrough with agitation. The chlorine gas is used in a stoichiometric excess, based on the metal content of the aqueous carbon black suspension. Next, the carbon black is separated from the aqueous suspension and dried.
Abstract: In a flotation method for purification of industrial or municipal waste water, in which the waste water comes in contact with electrodes having an electrical potential capable of electrolytically decomposing a portion of the waste water, thereby creating an ascending stream of gas bubbles, the waste water is mixed before or during the electrolytic decomposition with wettable particles of polymer material which are practically insoluble in water and have an absolute density of 1.3 g/cm.sup.3 at the most. Polymeric materials, especially polyalkane fibrids, are suitable for use as particles. This process makes it possible to purify oil-containing waste water by electroflotation without forming an oil film on the electrodes.
Abstract: Water soluble polymeric flocculants are prepared by photopolymerizing olefinically unsaturated hydrophilic monomer(s), the photopolymerization recipe including a polyhydroxylated organic additive, such as gluconic acid. Such polyhydroxy compound facilitates solubilization of the resultant flocculants, without substantial decrease in the molecular weight thereof, and ensures against the by-production of water insoluble fractions.
Abstract: This invention relates to ureylene prepared by reacting an oxyalkylated polyamine with urea and to uses of such ureylene for example in removing oils, solids, and combinations thereof from aqueous systems, etc.
Abstract: The invention relates to a process for separating solids from liquid matter by means of gravity, using a three-dimensional filter element and an alluvial filter layer wherein a gas is fed into the medium to be treated prior to its introduction into the filter element in the form of fine or finest bubbles which accumulate on the solid particles. The particles loaded with air floated up rapidly to the upper level of the column of liquid in the filter element, forming a layer of sludge. Said layer built up continuously an alluvial filter layer at the internal surface of the water-permeable supporting filter element from the bottom upwards along the wall relative to the rising level of the liquid in the filter element. The process, realized in the presence or absence of flocculating agents, results in a higher separation degree with regard to the solids content as well as an increased elimination of the biological oxygen demand.
Abstract: There is disclosed a method for the preparation of an animal feed supplement from fish cannery waste process water in which the water is maintained under aerobic conditions and is processed through a flotation cell to separate the oils and proteins contained in the water as a concentrated sludge. The sludge is dewatered, blended with a bulk, solid carrier preserved against oxidative spoilage of the lipids with an effective anti-oxidant, and dried in vacuum under low temperature conditions to obtain an animal feed supplement in dry particulate form. The processing of the waste water is done under aerobic conditions to promote the growth of yeast and non-toxic, aerobic, bacterial improve color and odor and texture, and enhance the feed value of the sludge recovered from the processing.
Type:
Grant
Filed:
October 22, 1979
Date of Patent:
August 4, 1981
Assignee:
Star-Kist Foods, Inc.
Inventors:
Vince J. Evich, Gerald C. Brown, Howard J. Dunn
Abstract: An auxiliary for improving the retention of flushable solids, for accelerating the dewatering of suspensions and for more rapidly working up industrial waters, effluents and sludges by the addition of a basic water-soluble polymer being produced by reacting (a) an aliphatic polyethylene glycol ether amine and (b) a basic polyamino amide to form an intermediate product and (c) reacting said intermediate with an epihalohydrin, dihaloalkane, glyoxal-bis-acrylamide, bis-acrylamidoacetic acid, acrylamidoglycolic acid or tetraalkyloxyethane.
Type:
Grant
Filed:
October 15, 1979
Date of Patent:
May 12, 1981
Assignee:
Wolff Walsrode Aktiengesellschaft
Inventors:
Rudolf Behn, Lutz Hoppe, Branislav Bohmer
Abstract: A process is disclosed for removing colloidal and non-colloidal humic matter from an aqueous solution of phosphoric acid, the process comprising (a) treating the phosphoric acid solution with a flocculant to flocculate the humic matter, (b) adding to the aqueous solution an effective amount of a phenol compound in order to destabilize the colloidal humic matter contained in the solution and to aid in the formation of froth, and (c) separating the humic matter from the solution by froth flotation.
Abstract: The invention relates to a method of treating in particular polluting materials such as hydrocarbons. Said materials are processed with at least one basic product such as hydraulic, natural organic or synthetic binder and in particular the calcium sulphate semi-hydrates showing qualities required for a quick setting, hardening, sequestration and retention. More particularly, the basic products used are calcium sulphate semi-hydrates in the form ALPHA. Said basic products may be also used for the processing of residual sludges or waste waters.
Abstract: Phosphate slimes are effectively settled by the sequential addition of effective amounts of a low molecular weight acrylamide: acrylic acid copolymer of high anionicity and a high molecular weight acrylamide: acrylic acid copolymer of low anionicity.
Type:
Grant
Filed:
September 11, 1979
Date of Patent:
February 17, 1981
Assignee:
American Cyanamid Company
Inventors:
Ralph J. Chamberlain, Richard E. Ellwanger
Abstract: Use of an effective amount of a precipitant or sequestrant for calcium ions improves performance of anionic polymeric carboxylic acid flocculants in flocculating phosphate slimes.
Type:
Grant
Filed:
April 30, 1979
Date of Patent:
September 23, 1980
Assignee:
American Cyanamid Company
Inventors:
James S. Balcerski, Arthur M. Schiller, Arthur Snow
Abstract: A process for the treatment of waste waters from the preparation of phthalic esters of alcohols to reduce the BOD and recover alcohols comprising treating the waste water with a strong acid and then extracting the acidified waste water with an alcohol, preferably the same as the alcohol used to form the phthalic ester.