Abstract: A method and apparatus are disclosed for separating a multiphase fluid stream that includes a heavier fluid component and a lighter fluid component. The fluid flows along a first helical flowpath with a first pitch. The first helical flowpath is sufficiently long to establish a stabilised rotating fluid flow pattern for the stream. The uniform rotating fluid also flows along a second helical flowpath, the second helical flowpath having a second pitch greater than the first pitch. The lighter fluid is removed from a radially inner region of the second helical flowpath. The method and apparatus are particularly suitable for the separation of oil droplets from water, especially from water for reinjection into a subterranean formation as part of an oil and gas production operation. The method and apparatus are conveniently applied on a modular basis.

Abstract: The present invention provides compositions, systems and methods for demulsifying an emulsion including an aqueous phase and an organic phase by adding an effective amount of a composition comprising at least one quaternary organopolysiloxane or salt thereof to the emulsion, the composition optionally including at least one of quaternary epihalohydrin/polyamine copolymers or salts, and/or (poly)diallyldimethylammonium halides.

Abstract: In a process and apparatus for treating produced water, for example for re-use in an oil or bitumen extraction operation of for treating frac water, the produced water flows through a series of treatment units. A portion of the produced water may by-pass one or more of the treatment units but the by-pass portion may be such that the treated water is still acceptable, for example for discharge or reuse. Concentrations of oil and grease, organic carbon, silica, pH or related parameters in the produced water may be monitored and used to control the process or apparatus. Control of the process may involve one or more of altering a by-pass portion, altering the addition of chemicals, and altering the operation of a unit process. The process may be controlled to respond to upset conditions, or such that the concentration of one or more limiting contaminants is near, but not over, a specified maximum for re-use or discharge.

Abstract: An apparatus for separating hydrophilic material from hydrophobic material, comprising: (a) a body having a first and second parallel walls defining an elongated cavity; (b) a water-absorbing material in the cavity along the first wall and having a surface essentially parallel to the second wall, thereby defining a channel between the surface and the second wall; (c) a first inlet having a first inlet end disposed in the channel, the first inlet being configured for injecting a mixture of hydrophilic and hydrophobic material; (d) a first outlet having a first outlet end disposed in the channel proximate the surface downstream of the first inlet end and configured for removing the hydrophilic material; and (e) a second outlet having a second outlet end disposed in the channel a distance from the surface downstream of the first inlet end and configured for removing the hydrophobic material.

Abstract: A method for removing contaminants such as oil and solids from water by feeding a mixture of water containing the contaminants and carbon dioxide to a cyclone; separating water from the mixture; separating a second mixture of oil, carbon dioxide and water from the mixture and feeding the second mixture to a separator wherein oil, carbon dioxide and water are recovered from the separator.

Abstract: A separation process for separating two or more immiscible liquids using contactors utilizing high surface area vertical hanging fibers is disclosed. This separation process is especially useful in the separation of disulfide oil formed during the oxidation of spent caustic solution that was used to remove sulfur contaminates from light hydrocarbons.

Abstract: An integrated unit operations for the treatment of a waste stream, such as spent caustic, is provided in a single vertical vessel having at least three separate zones: a mixing, a settling, and a mass transfer zone.

Abstract: The present invention provides compositions, systems and methods for demulsifying an emulsion including an aqueous phase and an organic phase by adding an effective amount of a composition comprising at least one quaternary organopolysiloxane or salt thereof to the emulsion, the composition optionally including at least one of quaternary epihalohydrin/polyamine copolymers or salts, and/or (poly)diallyldimethylammonium halides.

Abstract: Systems and methods for treating a stream comprising a hydrocarbon liquid and an aqueous-based liquid are provided. The systems and methods may utilize a media composite comprising a mixture of a cellulose-based material and a polymer. In certain systems and methods, the media composite is capable of being backwashed. The stream comprising the hydrocarbon liquid and aqueous-based liquid may be separated by contacting the stream with the media composite. In certain system and methods, the stream comprising the hydrocarbon liquid and aqueous-based liquid may be coalesced by contacting the stream with the media composite.

Abstract: A method of cleaning a wellbore drilled with a drilling fluid that forms a filter cake that includes emplacing a breaker fluid into the wellbore, the breaker fluid comprising: an aqueous fluid; a fragmentation agent; and an amphoteric chemotrope; and shutting in the well for a period of time sufficient to initiate breaking of the filter cake is disclosed.

Abstract: Methods are provided for separating solids containing oily/water of the type normally encountered in SAGD and hydraulic fracturing operations. The solids containing oily/water is subjected to ultrasound separation techniques and mechanical separation operations. The mechanical separation operation may, preferably, comprise centrifugal separation such as that in which the treated solids containing oily/water is separated into a solids fraction, an oil fraction, and a water fraction.

Abstract: An emulsion-breaking additive is combined with an emulsion concentrate to yield a reaction product and the emulsion concentrate is produced in a process stream and contains entrapped bio-oil. Subsequent phase separating can be accomplished with gravity separation and/or mechanical processing. The emulsion-breaking additive can be native to the process stream. Related systems and methods are also provided.

Abstract: The invention provides a method and apparatus for reducing the energy needed to process stillage in an ethanol refining operation. The method involves adding to stillage an effective amount of at least one processing aid. The flocculant induces the separation of insoluble material that would otherwise remain suspended in water but which impose a high shear energy cost on the refining processes. This allows for the removal of insoluble material that would otherwise be overlooked but which increase energy costs. This allows for more efficient and effective separation and recovery of insoluble fractions of the concentrated thin stillage that would otherwise be overlooked and lost in the process. Loss of these valued fractions as a result of traditional processing techniques and those requiring extensive additional energy input results in the loss of high value co-products to low revenue process streams.

Abstract: The present invention relates to methods for the separation of oil and water, in particular through the action of a polymeric material on oil/water emulsions (including oil-in-water and water-in-oil emulsions).

Abstract: A method of flocculating coal fines from produced water is provided. The method includes the steps of: (A) mixing at least: (i) produced water, wherein the produced water comprises suspended coal fines; (ii) one or more oil-soluble phosphate esters; and (iii) water-immiscible solvent; wherein the mixing is in proportions to obtain an oil-in-water emulsion; (B) allowing or mechanically causing the oil-in-water emulsion to substantially break into: (i) a first fluid having a continuous phase comprising at least some of the water from the produced water; and (ii) a second fluid having a continuous phase comprising at least some of the water-immiscible solvent; and (C) mechanically separating the first fluid and the second fluid. Optionally, the step of mixing further includes mixing with a crosslinker for the one or more phosphate esters to form a gel for suspending the separated coal fines.

Abstract: This invention reveals to the public the centralized sump oil and acid oil treatment process and system. The process consist of (1) the filter; (2) entry to reaction kettle, the sodium carbonate solution added at the time of air floatation till PH value keeps about 6.0-8.0; and emulsion splitter and flocculating agent added for further reaction; (3) suspension of air floatation and static settlement; (4) the international crude oil is collected after the detergent oil at the upper level of the reaction kettle is dehydrated under normal and reduced pressure; the wastewater is drained after filtering by the natural oil removal tank and the oil-water filter; the sludge is solidified by the cement and the quick lime and aluminium oxide are used as the coagulant aid for solidifying the sludge.

Abstract: This invention relates to devices and processes for removing asphaltenes and/or metals from crude oil to increase refinery processing of heavy materials. The desalters of this invention reduce and/or remove at least a portion of asphaltenes and/or metals form the crude oil. The separation occurs by mixing water with the crude oil to result in an aqueous phase having water and water soluble salts, an interface phase having asphaltenes and/or metals along with water, and a hydrocarbon phase having desalted, deasphalted and/or reduced metal crude oil.

Abstract: A method of treating tailings comprising a solids fraction and a hydrocarbon fraction is disclosed. A primary flow is supplied to a jet pump, the primary flow comprising water and less than 20% solids by mass. A secondary flow is supplied to a mixing chamber of the jet pump, the secondary flow comprising a slurry of water and tailings, the slurry comprising more solids by mass than the primary flow. The jet pump is operated using the primary flow such that the tailings are agitated to effect at least a partial phase separation of the hydrocarbon fraction from the tailings. The methods disclosed herein may also be applied to treat tailings ponds.

Abstract: Separation media, separation modules and methods are provided for separating water from a water and hydrocarbon emulsion and include a fibrous nonwoven coalescence layer for receiving the water and hydrocarbon emulsion and coalescing the water present therein as a discontinuous phase to achieve coalesced water droplets having a size of 1 mm or greater, and a fibrous nonwoven drop retention layer downstream of the coalescence layer having a high BET surface area of at least 90 m2/g or greater sufficient to retain the size of the coalesced water droplets to allow separation thereof from the hydrocarbon.

Abstract: A process for the separation of production fluids is provided. The production fluids comprise an oil/water emulsion stabilized with fine solids. The emulsion may further comprise asphaltenes and naphthenic acids and resins. The process includes subjecting the emulsion to a flocculating agent to flocculate solids within the emulsion, and separating water and solids from crude oil in a first separator. The process further includes subjecting the separated crude oil to a demulsifier after subjecting the emulsion to a flocculating agent, and further separating water from the crude oil in a second separator. A process for producing fluids from a hydrocarbon-bearing reservoir is also provided, using the separation processes herein.

Abstract: The present invention comprises a process and apparatus for separation of hydrocarbons from hydrocarbon-containing produced water, wherein in stage 1 the hydrocarbon-containing produced water is supplied with a gas-containing component, whereupon a gas- and hydrocarbon-containing produced water mixture is fed to an inlet tube (22, 27) in the center of a tank, whereupon the said mixture is tangentially distributed via at least one nozzle (7) and at least one baffle plate (8.1), whereupon separated hydrocarbons are conveyed to at least one outlet from the tank and cleaned water is conveyed to an outlet (12) from the tank.

Abstract: A system and method of separating grease from water in used cooking oil prior to collection and removal of the grease from the restaurant or other facility where the used cooking oil was created, collected or stored.

Abstract: A method including exposing a substance to a first type of electromagnetic waves generated by a first device. The frequency of the first type of electromagnetic waves is in the radio frequency range and the device preferably consumes no more than about 1,000 Watts of power. The exposure takes place for a period of time and at a frequency sufficient to detectably alter at least one physical property of the substance as it existed prior to the exposure. The substance is selected from the group consisting of a hydrate, a water and oil emulsion, clay, scale, cement, a completion fluid, tank sediment and iron sulfide.

Abstract: Oily and/or solids-containing water is clarified by chemical treatment to form flocculated and agglomerated solid phases and a clear water phase. In the clarification process, microbubbles of air or other gas are introduced at atmospheric pressure, via an eductor or other suitable device, together with a flocculant. During the subsequent formation of floes and their agglomeration into larger masses, microbubbles become entrained within and adhered to the solid flocculated materials. The resulting masses are very buoyant and easily separated from the water via a variety of approaches that include skimming, decanting, filtration, and screening. This process results in a solids phase that may be disposed of as waste, if desired, and a highly clarified water phase.

Abstract: A small-scale dynamic simulator for crude oil refinery desalters has a pressurized oil deviblis configured to hold a supply of crude oil and a water deviblis configured to hold a supply of wash water. At least one chemical feed pump selectively adds emulsion breaker chemicals to the desalter simulator and a low shear metering pump is configured to pump crude oil and wash water through the desalter simulator. An emulsion forming device forms a crude oil-wash water emulsion that is then received in a desalter vessel. The desalting vessel is fitted with electric grids which simulate those found in electric desalters. The emulsion is resolved within the desalter vessel with the assistance of the emulsion breaker chemicals so the wash water and crude oil form distinct phases, with substantially desalted crude oil removed from an upper portion of the desalter vessel and substantially oil-free wash water removed from a bottom portion of the desalter vessel.

Abstract: An electrostatic coalescer includes an outer wall defining a flow path for receiving a process fluid. A plurality of electrode plates is disposed within the flow path. A controller includes an inductor and a signal generator. The inductor is coupled in parallel with the plurality of electrode plates. The inductor and the plurality of electrode plates define a resonant circuit. The signal generator is coupled to the plurality of electrode plates and operable to apply an alternating current signal to the plurality of electrode plates at a frequency corresponding to a resonant frequency of the resonant circuit in the presence of the process fluid. The signal generator varies the frequency of the alternating current signal based on a positive feedback signal received from the resonant circuit to maintain resonance.

Abstract: The invention relates to a method for separating emulsions of oil and water, the method comprising incorporating a demulsifying-effective amount of a polyorganosiloxane demulsifier into an emulsion comprising an oil phase and an aqueous phase. The invention also relates to compositions containing polyorganosiloxane demulsifier and the water and oil phases of an emulsion.

Abstract: The present invention generally relates to a coalescer device and separation method employing the coalescer device for coalescing material comprising a dispersed liquid phase from an emulsion.

Abstract: Composition and method of use for tannin based environmentally benign polymeric coagulants are disclosed. Tannin based coagulants are copolymers of naturally occurring tannins and a cationic monomer. One embodiment of the present invention provides for a composition, of a tannin based polymeric coagulant which is comprised of N,N-(dimethylaminoethyl) methacrylate (MADAME) polymerized using t-butylhydroperoxide and sodium metabisulfite. The resulting polyMADAME is converted to hydrochloride and then blended/reacted in an aqueous medium with tannin to obtain a homogenous poly(MADAME)-tannin composition. The method of use comprises adding an amount of the composition effective for the purpose of clarifying oily wastewater from food and beverage, steel, automotive, transportation, refinery, pharmaceutical, metals, paper and pulp, chemical processing and hydrocarbon processing industries.

Abstract: A process for treating a recovered wellbore fluid, where the process includes contacting an aqueous wellbore fluid with ozone, wherein the aqueous wellbore fluid comprises organic contaminants; and separating the aqueous wellbore fluid into an organic phase and a clarified water phase is disclosed.

Abstract: A process and a device implementing the process, for separating fluids in emulsion and/or in solution, and/or for low pressure distillation, in particular of water and/or gaseous hydrocarbons dissolved in crude petroleum, and/or for separation of crude petroleum droplets emulsified in water, to obtain water with necessary characteristics for its injection without pollution of underground aquifers, and/or when the mixture is dominant in crude petroleum, acceleration of settling of the water in the lower part of the mixture, and/or for low pressure distillation of crude petroleum. The method creates a localized zone of reduced pressure on part of the free surface of a liquid to be processed, within a closed processing tank, without the overall pressure inside the closed processing tank being affected.

Abstract: An apparatus for separating a fluid mixture includes a uniaxial cyclonic separator (2) having a separation chamber (18) for separating the fluid mixture by cyclonic action into a first fluid and a second fluid. An inlet (16) is located at a first end of the separation chamber (18) for receiving a fluid mixture, while a first outlet (22) for the first fluid and a second outlet (26) for the second fluid are located at a second end of the separation chamber. A gas injection means (12) is provided for injecting a gas into the fluid mixture to aid separation within the separation chamber (18). The gas injection may also be through an annular chamber surrounding the separator chamber (18). The gas in this case is introduced through a porous medium 130 via a gas supply line 136.

Abstract: A composition comprising one or more siloxane cross-linked demulsifiers wherein said siloxane cross-linked demulsifiers are prepared by reacting one or more alkylphenol-formaldehyde resin alkoxylates, one or more polyalkylene glycols, or a mixture thereof, with up to about 1.0 molar equivalents of one or more silicon-based cross-linkers of formula R1R2R3R4Si wherein R1, R2, R3, R5, R6 and R7 are independently selected from H, Cl, C1-C4 alkyl and C1-C4 alkoxy; R4. is selected from H, Cl, C1-C4 alkyl, C1-C4 alkoxy and a group of formula L1SiR5R6R7; L1 is absent or is selected from —O—, arylene and C1-C12 alkylene, optionally interrupted by one or more —O— or —N(R8)—; and R8 is H or C1-C4 alkyl and a method of using the demulsifier composition to resolve water-in-oil emulsions.

Abstract: Methods for treating oily wastewater comprising adding to the wastewater a cationic coagulant and an acrylamide copolymer flocculant. The acrylamide copolymer flocculant may comprise either an anionic acrylamide copolymer flocculant or a cationic acrylamide copolymer flocculant or both. The acrylamide flocculants may be present in an emulsion or mixture along with activated starch or maleamate derivatized starch. The method may be employed, for example, to clarify SAGD and/or frac produce waters.

Abstract: Methods of deoiling oily water such as SAGD and frac produce water. The oily water is treated with a natural coagulant selected from tannins and chitosan. A cationic and/or anionic flocculant may also be added to the treated oily water. The thus treated oily water may be subjected to conventional mechanical oil separation techniques such as hydrocyclonic separation, dissolved air flotation, entrapped air flotation, induced gas flotation, gravity filters, reverse osmosis filters, API, or Voraxial® bulk separators and the like.

Abstract: A method for recovering tallow from food or animal processing wastewater includes adding a flocculant to the wastewater to agglomerate suspended fats, oil and grease particles in the wastewater, separating solid waste materials from the wastewater and processing the solid waste materials to recover tallow. The flocculant includes polyacrylamide or an acrylamide copolymer. A process for separating fats, oil and grease from food or animal processing wastewater is also provided.

Abstract: A method is provided of recycling and cleaning up oil-based waste drilling mud and cuttings contaminated with oil-based waste drilling mud. A facility for performing the method is also provided. The method includes removing the coarse solids from the mud, breaking the emulsion, separating the hydrophobic phase from the water phase and the solid phase, vaporizing all residual oil and water from the solids, and burning off the vaporized oil. The method produces a solid “soil” product that is free from oil contamination, an oil product that is fit for reuse, and clean air emissions. A thermal desorber can be used to efficiently vaporize the oil at low temperature. Optionally the water fraction of the mud can be vaporized, solutes and salts can be captured as evaporite and then be mixed with the soil product. The method has the unique advantage of producing no persistent hazardous waste.

Abstract: Separation media, separation modules and methods are provided for separating water from a water and hydrocarbon emulsion and include a fibrous nonwoven coalescence layer for receiving the water and hydrocarbon emulsion and coalescing the water present therein as a discontinuous phase to achieve coalesced water droplets having a size of 1 mm or greater, and a fibrous nonwoven drop retention layer downstream of the coalescence layer having a high BET surface area of at least 90 m2/g or greater sufficient to retain the size of the coalesced water droplets to allow separation thereof from the hydrocarbon.

Abstract: The disclosure describes a novel approach for treating water, such as oilfield production waste. The disclosure describes novel methods for chemically treating contaminated water, such as chemical processes for softening water, demulsifying hydrocarbons, destroying a sequestering effect on divalent cations, destroying any detectable amount or over 99% of aerobic and anaerobic bacteria, and breaking long chain polymers. The disclosure further describes novel methods for clarifying contaminated water to remove suspended solids.

Abstract: The use of alkoxylated polyalkanolamines as demulsifiers for splitting oil-water emulsions, especially for splitting crude oil emulsions.

Abstract: A method is provided of recycling and decontaminating oil-based waste drilling mud and cuttings contaminated with oil-based waste drilling mud. A facility for performing the method is also provided. The method includes removing the coarse solids from the mud, breaking the emulsion, and separating the hydrophobic phase from the water phase and the solid phase. The solids may then be treated by either or both of two approaches. One approach involves vaporizing all residual oil and water from the solids, and burning off the vaporized oil. Another approach involves at least partially vaporizing the residual oil from the solids and recondensing the oil. The method produces a solid “soil” product that is free from oil contamination (or is sufficiently decontaminated to allow reuse), an oil product that is fit for reuse, and clean air emissions. A thermal desorber or a soil dryer can be used to efficiently vaporize the oil at low temperature.

Abstract: A system for separating hydrocarbons from water, the system including an inlet for receiving a fluid, the fluid including a water phase and a hydrocarbon phase, and a separation tank having a first partition and a second partition, wherein the first partition is configured to receive the fluid from the inlet. Furthermore, the system includes a first outlet configured to receive the water phase from the first partition, a second outlet configured to receive the hydrocarbon phase from the second partition, and a support structure configured to receive the water phase from the first outlet and the hydrocarbon phase from the second outlet. Also, a method of separating a fluid into a water phase and a hydrocarbon phase, the method including injecting the fluid containing the water phase and the hydrocarbon phase into a separation tank.

Abstract: In one aspect, the present invention provides a subsea separation vessel for the separation of a mixture comprising oil and water comprising (a) at least one inlet for introducing a oil-water mixture; (b) a flow path for conducting the oil-water mixture; (c) at least one oil-water separation structure; and (d) at least one fluid outlet. The oil-water separation structure includes a multifunctional surface. The oil-water separation structure is located within the flow path and wherein the multifunctional surface is superhydrophobic with respect to water, and either oleophilic or superoleophilic with respect to oil. A method for separating oil from an oil-water mixture is also provided.

Abstract: A method of cleaning a wellbore drilled with a drilling fluid that forms a filter cake that includes emplacing a breaker fluid into the wellbore, the breaker fluid comprising: an aqueous fluid; a fragmentation agent; and an amphoteric chemotrope; and shutting in the well for a period of time sufficient to initiate breaking of the filter cake is disclosed.

Abstract: A separation process for separating two or more immiscible liquids using fiber-film technology is disclosed. This separation process is especially useful in the separation of disulfide oil formed during the oxidation of spent caustic solution that was used to remove sulfur contaminates from light hydrocarbons.

Abstract: A method for treating an interface rag includes the steps of removing a volume of rag at a controlled rate from an upstream rag source and passing the rag through a high pressure pump and a heater. The heater heats the rag to a temperature of at least 350° F. to thermally decomposing any chemicals that had been added to the interface rag to promote separation. Diluent is then mixed with the heated rag to cool the rag to a temperature less than 300° F. and produce a 30 API rag. The cooled diluted rag is then treated in an electrostatic treater or sent directly to a hydrocyclone cluster. The electrostatic treater is preferably a vertical electrostatic treater with a conical-shaped lower portion and a means for agitating the solid-laden water within the treater to prevent the solids from settling on the bottom of the treater.

Abstract: Method for treatment of oil on a solid or liquid surface to facilitate subsequent removal of the oil from the surface. A fat-soluble metal containing substance comprising an organic anion and a metallic cation is added to the oil. The metal containing substance may be prepared by allowing a metal salt to react with an acidic organic compound in a process in which a suitable oxidation agent ensures that all the metal in the end product is present at its highest stable oxidation state while at least one volatile compound is formed during the preparation. A polymeric material with a high specific surface area may optionally be added or a prepolymer for allowing subsequent formation of such a polymeric material.

Abstract: An emulsion treating unit and process. A subcooled boiling zone in the unit comprises a heat transfer surface to contact an emulsion at a temperature in excess of the saturation temperature of an aqueous phase in the emulsion, wherein the boiling zone is atmospherically vented. The unit also provides means for recovering an oil-rich layer from adjacent a vapor-liquid interface; and means for recovering an aqueous-rich layer from below the oil-rich layer. The process provides operation of the treating unit to heat an emulsion in the subcooled boiling zone, wherein the boiling zone is atmospherically vented, recovering an oil-rich layer and recovering an aqueous-rich layer from below the oil-rich layer. In one embodiment the boiling zone comprises a heat transfer surface having a temperature in excess of the saturation temperature of the aqueous-rich layer, wherein the vapor-liquid interface is subcooled with respect to the saturation temperature of the aqueous layer.

Abstract: The present invention relates to methods for the separation of oil and water, in particular through the action of a polymeric material on oil/water emulsions (including oil-in-water and water-in-oil emulsions).

Abstract: A system for soil, groundwater, or surface water remediation, comprises a water supply including a first fluid stream in fluid communication with a first injection point, and a second fluid stream in fluid communication with a second injection point. A first surfactant pump can be adapted to inject a surfactant into the first fluid stream, and a second surfactant pump can be adapted to inject a surfactant into the second fluid stream. A first oxidant pump can be adapted to inject an oxidant into the first fluid stream, and a second oxidant pump can be adapted to inject an oxidant into the second fluid stream.