Abstract: A water-soluble cationic (co)polymer dispersion prepared by the polymerization of a specified cationic quaternary monomer, which is obtained by quaternization by use of an alkyl halide, optionally with another cationic monomer and/or (meth)acrylamide, the polymerization being carried out in a salt solution which does not dissolve the resulting (co)polymer, and in the presence of a specific cationic polymer dispersant which is soluble in the salt solution, and its use as a flocculant or a paper chemical are provided.

Abstract: A method of treating a water-swellable clay after the clay has been mined and dried to improve its properties when in contact with contaminated water. After the common initial drying of the clay to a moisture content of 12% by weight or less, the clay is impregnated with an aqueous solution containing a dissolved, water-soluble polymer, in an amount of at least about 0.5% by weight based on the dry weight of the clay, and the clay is wetted to a moisture content of more than 12% by weight, preferably at least about 15% or more, based on the dry weight of the clay, and then redried to a moisture content of 12% by weight or less, based on the dry weight of the clay.

Abstract: Disclosed are methods for reducing turbidity of aqueous systems and clarifying wastewater systems utilizing a graft copolymer having the structure: ##STR1## whereby the cationic monomer (F) is represented by ##STR2## wherein R is hydrogen or a C.sub.1 to C.sub.3 alkyl group, R.sub.1 is the salt of an ammonium cation, and the molar percentage of a:b is from about 95:5 to about 5:95, with the proviso that the sum of a and b equals 100%.

Abstract: The invention relates to the clarification of deinking process waters which result from the recycling of paper. More specifically, the present invention relates to the use of containing vinylamine as water clarifying agents in said processes.

Abstract: A method of removing waste oil from industrial oily waste water is disclosed. The method comprises the steps of adding to the oily waste water which includes oil, dispersed solids and emulsified water, an effective amount of a demulsifier which comprises a copolymer of a cationic monomer and a vinyl alkoxysilane; allowing the oil, emulsified water and dispersed solids to flocculate and separate into layers; and then removing the water layer from the treated waste water. The cationic monomer is selected from the group consisting diallyldimethylammonium halide, dimethylaminoethyl acrylate quaternary salt and dimethylaminoethyl methacrylate quaternary salt.

Abstract: The invention comprises a method of preventing deposition of oil on steel mill scale particles comprising adding from about 1 part per million to about 500 parts per million of an amine acrylate/acrylic acid copolymer to mill flume water. Once the copolymer is added, deposition of oil onto scale particles is prevented. The recovered mill scale has less than 2% oil by weight on the scale, making it suitable for recycle to the steelmaking process. Oil and water are subsequently separated with a greater percentage of oil being recovered.

Abstract: The invention comprise a composition for breaking oil-in-water emulsions comprising adding from about 1 part per million to about 500 parts per million of an amphoteric acrylic acid copolymer to the emulsion. Once the copolymer is added, the emulsion is subjected to agitation until the oil-in-water emulsion is resolved and the oil and water separates into two phases. The oil and water phases are then subjected to a separation technique to separate the phases. The invention further comprises a method of synthesizing the amphoteric polymers used in the emulsion breaking application.

Abstract: A process and apparatus for the treatment and recovery of spent vehicle coolant that involves the following steps:a) removing the spent coolant from the engine;b) treating the spent coolant with sodium dimethyldithiocarbamate to cause dissolved metals therein to form insoluble particles;c) treating the spent coolant of step b) with an aqueous basic coagulating agent such as a polyquaternary ammonium compound in its hydroxide form;d) filtering the spent coolant from step c) through a set of filters and then through a bed of carbon particles, to produce a relatively cleaner liquid; ande) adding to the relatively clear liquid a combination of corrosion inhibitors, buffering agents and alkali, whereby the treated coolant can be recycled to the vehicle for effective coolant performance therein.

Abstract: The invention is an improved process for denaturing and coagulating paint in an aqueous medium in which denatured and coagulated paint must remain in a dispersion in the aqueous medium. The aqueous medium contains a coagulant and the aqueous medium is maintained at an alkaline earth metal ion equivalent of less than 1.0 mmole/liter.

Abstract: The present invention provides a method for purifying agricultural waste. The method includes the steps of adding effective amounts of at least one polymer flocculent, at least one coagulant, and at least one precipitant. The combined effect of the various components of the present invention not only purifies the agricultural waste but also yields a dewatered organic mass for composting to act as a peat replacement.

Abstract: A method of laundering oily items comprises laundering said items in a wash solution which includes a surfactant system and a source of alkalinity. The source of alkalinity is an alkali metal aluminate preferably sodium aluminate at a concentration effective to have at least about 25 ppm of the alkali aluminate present in the wash solution measured as alumina. The wash solution is then separated from the laundered items and its pH reduced to about 9 or less. A destabilizing polymer such as diallyldimethyl ammonium chloride can be added. This combination causes the oil and grease to separate from the wash solution and float to the surface along with the sodium aluminate. If the concentration of the sodium aluminate is above about 100 ppm preferably about 250 ppm, there is no need to add the destabilizing polymer. This does not affect the overall efficiency of the detergent, yet significantly improves the ability to separate the oil and grease from the waste wash solution.

Abstract: A method of flocculating coagulated and/or finely divided suspended matter in aqueous systems comprising adding to the system from 0.005 to 1 weight percent based on the dry weight of the coagulated and/or finely suspended matter of at least one water soluble cationic polymer selected from a water soluble cationic copolymer (I) composed of the polymerization reaction of an N-vinylamide with at least one cationic quaternary amine monomer.

Abstract: A contaminant precipitating composition and method are disclosed. The composition comprises a water soluble branched polymeric composition effective for the purpose of precipitating contaminants from an aqueous solution. The method comprises adding an amount of the composition, effective for the purpose, to the aqueous solution so as to complex, precipitate and remove contaminants from the aqueous solution.

Abstract: Process for removing unwanted material from wanted material containing water by bringing an isocyanate-containing prepolymer into contact with the materials, allowing the prepolymer to react with the water to form a flexible foam and removing the foam obtained from the wanted material.

Abstract: A contaminant precipitating composition and method are disclosed. The composition comprises a water soluble, branched, polydithiocarbamic acid salt effective for the purpose of precipitating contaminants from an aqueous solution. The method comprises adding an amount of the composition effective for the purpose to the aqueous solution so as to complex, precipitate and remove contaminants from the aqueous solution.

Abstract: A method, composition and filter for reducing the presence of sludge or varnish precursors in a lubricating oil circulating within an internal combustion engine. The lubricating oil containing sludge or varnish precursors is contacted with discrete particles of an oil insoluble, oil wettable compound having an antioxidant functional group and/or a dispersant functional group, which are capable of complexing with sludge or varnish precursors. Preferably the compounds comprises a crosslinked amine having ethylene amine functionality. The starting polyethylene amines have a number average molecular weight in the range of about 100 to about 60,000, preferably 200 to 250 and are crosslinked with a silicon oxide, silane, silicate, epoxide, quinone, or phenol-formaldehyde crosslinking agent. The particles are encaged within a one or two stage oil filter together with filtering media such as chemically active filter media, physically active filter media and inactive filter media.

Abstract: The invention comprises a process for removing true and apparent color from pulp and paper waste waters. It comprises treating these waste waters with a vinylamine polymer including from about 1 to about 100 mole percent vinylamine and from about 1 to about 99 mole percent of at least one monomer selected from the group consisting of amidine vinylformamide, vinyl alcohol, vinyl acetate, vinyl pyrrolidinone and the esters, amides, nitriles and salts of acrylic acid and methacrylic acid.

Abstract: A method for flocculating finely divided particles suspended in nonpolar liquids, thereby facilitating the removal of these particles by sedimentation or filtration, by treating the contaminated nonpolar liquids with from about 0.01% to about 5% by weight of a flocculant comprising a water soluble organic compound having a cationic quaternary nitrogen or ammonium group. The flocculants useful in the method of the invention are desirably miscible or dispersible in the nonpolar liquid, and a carrier solvent or surfactant may be used to improve dispersibility of the flocculant.

Abstract: The invention provides a method for dewatering coal tailing aqueous slurries. The method including the step of adding to the slurry a flocculant composition including a vinylamine polymer including from about 1 to about 100 mole percent vinylamine and from about 1 to about 99 mole percent of at least one monomer selected from the group consisting of vinylformamide, vinyl acetate, vinyl pyrrolidinone, vinyl alcohol and the esters, amides and salts of acrylic acid and methacrylic acid.

Abstract: The invention comprises a process for removing true and apparent color from pulp and paper waste waters. It comprises treating these waste waters with a coagulant and vinylamine polymer. The coagulant is selected from the group consisting of epichlorohydrin-dimethylamine, guanidine-formaldehyde condensation polymers, cyanoguanidine-formaldehyde condensation polymers, urea-formaldehyde condensation polymers, polyethyleneimines, polydiallyldimethylammonium chloride, copolymers of polydiallyldimethylammonium chloride and acrylamide, and ethylenedichloride-ammonia. The vinylamine polymer includes from about 1 to about 100 mole percent vinylamine and from about 1 to about 99 mole percent of at least one monomer selected from the group consisting of amidine vinylformamide, vinyl alcohol, vinyl acetate, vinyl pyrrolidinone and the esters, amides, nitriles and salts of acrylic acid and methacrylic acid.

Abstract: A method for conditioning food processing waste prior to chemical dewatering comprising the step of treating the food processing waste with an effective amount of at least one hydrophobic polymer coagulant.

Abstract: Organic impurities are removed from Bayer process liquors using a polymer which contains vinylamine and/or vinylformamide.

Abstract: A precipitating agent containing thioacetamide is described for the precipitating of heavy metals from flue gases and waste waters, it containing thioacetamide (C.sub.2 H.sub.5 SN) in a 1-20% aqueous solution, which, in addition, contains a buffer substance in order to prevent hydrolyric spontaneous decomposition, the solution having a pH of between 5.5 and 9.0.

Abstract: Siliceous materials produced by thermally treating spent Bayer process liquors are obtained in modified form when produced in the presence of polymeric quaternary ammonium compounds, polyamine polymers, copolymers of acrylic acid and acrylamide, and polyacrylamides. These modified siliceous materials possess morphologies which confer upon them a reduced tendency to deposit on surfaces throughout the process.

Abstract: A process for removing proteinaceous materials, fats and oils from food processing wastewater using a coagulant such as lignin or a halogen ion containing compound together with a flocculant such as a natural polymer such as a polysaccharide or synthetic polymer is described. The combination of lignin or halogen and polymer is effective for coagulating and flocculating proteinaceous materials, fats and oils in food processing wastewater at low pH.

Abstract: A method for optimizing the dosage of a polyelectrolyte treating agent in a water treatment process using a fluorescent material having the opposite electrical charge as a polyelectrolyte treating agent used to treat water in a water treatment process.

Abstract: A composition and method for separating red blood cells from whole blood including a rouleaux-forming aggregator and an enhancer for enhancing the settling rate. The enhancer is a material which alters directly or indirectly the properties of the red blood cell and may alter the structure and/or reactivity of the aggregator, without adversely affecting the morphology and function of white blood cells. In most instances, the red blood cell enhancers of the invention are osmotic agents. Such agents create a hypertonic solution while not entering the cells themselves. Preferably the enhancer is a salt of oxalic acid, a salt of malonic acid, mannitol or sucrose. Potassium oxalate is most preferred. High molecular weight substances which are large enough to form molecular bridges between red blood cells form the aggregators used in the invention.

Abstract: The present invention is intended to provide a metal scavenger that is free from the defects of metal scavengers formed by introducing dithioic acid groups to polyalkylenepolyamines or the like, is high in settling speed of flock when used in waste water treatment, and can carry out treatment of waste water efficiently and also to provide a process of producing the same efficiently. The present metal scavenger has a structure that is formed by replacing the hydrogen atoms linked to the nitrogen atoms of a polyamine having aminomethyl groups by dithioic acid groups or their salts and that is represented by the following general formula: ##STR1## wherein R represents a dithioic acid group, an alkali metal dithioate group, an alkaline earth metal dithioate group, or an ammonium dithioate group and R' represents a hydrogen atom, a dithioic acid group, an alkali metal dithioate group, an alkaline earth metal dithioate group, or an ammonium dithioate group.

Abstract: A process for removing carboxylic acids from aqueous solutions using a composition of a polyaluminum chlorohydrate and a cationic polyelectrolyte is described. After or during the initial contact of the aqueous solution with the composition, an organic liquid may optionally be added after which separation into an aqueous phase and an organic phase occurs whereby the organic acids are removed in the organic phase. The preferred polyaluminum chlorohydrate is aluminum chlorohydrate, and the preferred cationic polyelectrolyte is a high molecular weight poly(dimethyl diallyl) ammonium chloride.

Abstract: In the process described, esterification products of an oxyalkylated primary fatty amine and 0.5 to 1.5 mol per mole of fatty amine of a simple dicarboxylic acid or of a dicarboxylic acid from the group comprising dimeric fatty acids are employed as emulsion breakers.

Abstract: A wet paint spray booth treating agent comprising a melamine--aldehyde acid colloid solution, a nitrogen atom-containing organic compound and an anionic water soluble high molecular weight dispersant. A method for the treatment of a wet paint spray booth which comprises adding a melamine--aldehyde acid colloid solution, a nitrogen atom-containing organic compound and an anionic water soluble high molecular weight dispersant to a recirculating washing water in a wet paint spray booth.

Abstract: A process for flocculating, in a liquid other than Bayer process streams, suspended solids comprised primarily of minerals other than iron oxide and tin oxide. The solids are contacted with a hydroxamated polymer. The amount of hydroxamated polymer is sufficient to increase the settling rate of the solids and to decrease the turbidity of the solids.

Abstract: A method is described for improving the removal of toxic resin acids and fatty acids from pulp and paper effluent and from other streams containing resins and fatty acids. The addition of an anionic material, such as albumin, gelatin, alginate or alginic acid prior to clarification with conventional or state of the art cationic coagulation clarification or retention will improve the removal of resin acids and fatty acids.

Abstract: A highly colored dye wastewater is treated by a sequence of steps to obtain a color reduction of 90 percent or more. The method requires acidifying the wastewater and adding a cationic flocculant. A reducing agent is then, optionally, added to further reduce the color value of the wastewater and produce an oxidation-reduction potential of at least -200 and, generally, about -400 to -800. The reducing agent is, preferably, either a hydrosulfite or both a bisulfite and an alkali metal borohydride.

Abstract: The present invention provides a process for recovering alkali carbonates such as alkali sesquicarbonates from slurries of minerals such as Trona which contain those carbonates as well as clays and shales. The invention further provides a method for recovering alkaline earth carbonates from caustic slurries of those carbonates, as well as to clarifying the supernatant liquids which result from recovery of the alkaline earth carbonates.

Abstract: The dewatering of sludge is improved by utilizing a water-soluble cationic copolymer in the aqueous phase of a water-in-oil emulsion wherein the copolymer has been prepared by (i) preparing an aqueous solution of a non-ionic monomer and a portion of the cationic monomer, (ii) emulsifying the aqueous solution in a hydro-carbon oil to form a water-in-oil emulsion, (iii) adding the balance of the total intended cationic monomer to the emulsion while substantially no polymerization is occurring, and (iv) polymerizing the monomers.

Abstract: A method is provided for removing metals from a fluid stream containing these metals. The method involves treating the fluid stream with a water soluble ethylene dichloride ammonia polymer having a molecular weight of from 500 to 100,000 that contains at least 5 mole percent of dithiocarbamate salt groups to form a complex with the metals. Then, the fluid stream is passed through a filtering device to remove the complexes from the fluid stream.

Abstract: A method for treating waste pickle liquor solution comprising the steps of (a) adding a flocculating agent to the pickle liquor solution; (b) allowing at least some of the silica in the pickle liquor to begin to flocculate; (c) again adding a flocculating agent to the pickle liquor solution; (d) allowing the floccules containing silica formed in step (b) to increase in size; and (e) physically separating floccules formed in step (d) from the pickle liquor solution.

Abstract: The invention provides a method of recovering water from an acid workover, the water including dispersed solids and emulsified oil. According to the method, the water is treated with an effective amount of a dispersion of a water-soluble cationic polymer.

Abstract: A method for treating a waste system containing an oil phase dispersed on a water phase is disclosed that includes adding a polysalt having an anionic polymer component and a cationic polymer component wherein the weight ratio of the anionic polymer component to the cationic polymer component ranges from about 5:95 to 40:60, on an active basis.

Abstract: The invention relates to coagulating agents formulated in the form of two separate components A and B for coagulating paints, waxes and coating compositions, which agents contain one or more aluminosilicate(s), one or more wax(es) and/or wax analogues and one or more active ingredient(s) and/or auxiliary material(s) that are known per se for coagulating and/or formulating, as well as to the aqueous slurries of the two-component agents and to the use thereof in circulation waters of paint disposal units.

Abstract: A process capable of operation under hostile conditions for accelerating the sedimentation of suspended solids in an aqueous suspension using a flocculating agent comprising a water-soluble polymer composition produced from a monomer composition comprising at least one of a hydrophilic N-vinyl lactam or a hydrophilic vinyl-containing sulfonate.

Abstract: The invention describes the use of molybdenum compounds in circulating waters of wet precipitators of spray coating units for detackifying and coagulating paints and/ or varnishes, waxes and other organic coating compositions, and a process for detackifying and coagulating paints and/ or varnishes, waxes and other organic coating compositions by means of molybdenum-containing coagulants.

Abstract: A method of converting a toxic composition containing an aldehyde to a composition which is substantially non-toxic. The aldehyde is reacted with a compound having protic oxygen or nitrogen atoms and a polyimine or polyimine derivative to absorb or swell the aldehyde-containing composition and preferably to yield a substantially solid reaction product by way of a substantially irreversible reaction.

Abstract: Materials such as amines, alcohols, aminoalcohols, ethers and mixtures thereof, including halogenated adducts thereof, have been found to be useful floc modifiers for water clarifiers to form an effective overall water clarifier composition. The water clarifier portion of the composition is a dithiocarbamate. The floc modifier of a particular water clarifier composition need not be the same compound that is reacted with carbon disulfide (CS.sub.2) to make the water clarifier portion of the novel compositions.

Abstract: A method for improving the dispersibility of over-sprayed, solvent-based paints in aqueous systems which comprises adding an effective amount of a chelating agent to an aqueous system containing solvent-based paints, particularly in high-hardness waters.

Abstract: The use of quaternized polyvinylamines for use in water clarification is disclosed.

Abstract: A method for treating an ink-laden wastewater stream comprising adding an effective amount of a melamine-aldehyde polymer to the ink laden stream being treated and segregating at least some portion of the resulting ink-laden agglomerated solids from the treated water.

Abstract: Disclosed are methods for removing benzene from hydrocarbon process waters. These methods include adding aluminum chlorohydrate to the water and then separating the benzene by solvent extraction.

Abstract: Disclosed herein is a flocculating agent comprising a specified cationic polymer having an amidine structure. The cationic polymer flocculating agents according to the present invention have 20 to 90% by mole of a repeating amidine unit represented by the formula (1) and/or (2): ##STR1## The agents have a reduced viscosity of 0.1 to 10 dl/g as measured in a 1N saline solution of 0.1 g/dl at 25.degree. C.The agents have a remarkably excellent performance as flocculating agents, in particular for organic sludge.