Including Degassing Patents (Class 210/750)
  • Patent number: 11944919
    Abstract: An improved surface evaporation system where droplet size and spray configuration is controlled and modified based upon ambient conditions in order to prevent the spreading of salts and other contaminants outside of a treatment pit or specific area. Water droplet size can be controlled by adjustment of the spray nozzle side. Increasing the nozzle size to increase droplet size results in a reduction of mist travel direction (i.e., drift distance). Reducing the nozzle size decreases the droplet size, and increases drift distance. Similarly, changing the configuration of the spray will affect drift distance. For example, changing the spray direction and height from a vertical spray direction to a flatter, more horizontal direction (with resulting greater area) results in a substantially decreased drift distance. In addition, the system also takes into account the effects of wind speed and direction and humidity. Evaporation modules may use standard spray nozzles, or ultrasonic evaporators.
    Type: Grant
    Filed: August 2, 2022
    Date of Patent: April 2, 2024
    Assignee: HYDROZONIX, LLC
    Inventor: Mark Patton
  • Patent number: 11383994
    Abstract: A method for treating hydrogen sulfide in a solution includes providing the solution containing hydrogen sulfide. The method also includes adding sodium nitrite to the solution in an amount suitable to react with the hydrogen sulfide and treat the hydrogen sulfide.
    Type: Grant
    Filed: July 28, 2020
    Date of Patent: July 12, 2022
    Assignee: United Laboratories International, LLC
    Inventors: Jack G. Frost, Kenneth J. Snyder
  • Patent number: 11274574
    Abstract: A carbon-based fuel gasification power generation system is configured to remove ammonia from syngas using washing water, and effectively use the ammonia-containing washing water. The system includes a gasification facility provided with a water scrubber for removing ammonia in the syngas generated as gasified carbon-based fuel, and a power generation facility provided with a combustor for burning gas for combustion generated in the gasification facility and air for combustion humidified in the humidifying tower, and a gas turbine driven by combustion gas. The ammonia-containing water recovered in the water scrubber is supplied to the humidifying tower. Using the water, compressed air to be supplied to the combustor is humidified.
    Type: Grant
    Filed: August 14, 2020
    Date of Patent: March 15, 2022
    Assignee: Mitsubishi Power, Ltd.
    Inventor: Fumihiko Kiso
  • Patent number: 11077328
    Abstract: The present invention is for an improved vertical flow reactor utility that makes the technology more attractive for industrial development. The various embodiments of the invention improve various aspects of a vertical flow reactor utility. For example, in accordance with an embodiment of the invention, the design of the reactor is improved. Other embodiments provide improved systems and methods for, for example, insertion of oxygen, electrical production, and/or reactor geometry. These one or more various embodiments of the present invention lowers costs to construct, install, and/or operate a vertical flow reactor by improving economy of construction and/or operation of VFR systems.
    Type: Grant
    Filed: February 26, 2020
    Date of Patent: August 3, 2021
    Inventor: David Stanley Moulton
  • Patent number: 10913670
    Abstract: Processes of consolidating oil sands tailings which includes fines and process water are disclosed. The processes include mixing the oil sands tailings with a highly water soluble salt or an aqueous solution thereof to destabilize and consolidate solids in the tailings, e.g., to destabilize and consolidate fines in the tailings and separating the consolidated solids from the process water. A water soluble polymer flocculant and coarse particles, e.g., sand, can also be used in the treatment of oil sands tailings.
    Type: Grant
    Filed: November 5, 2018
    Date of Patent: February 9, 2021
    Assignee: EXTRAKT PROCESS SOLUTIONS, LLC
    Inventors: Paul C. Painter, Bruce G. Miller, Aron Lupinsky
  • Patent number: 10836658
    Abstract: A preparation including a) at least one N-formal and b) at least one dialkylhydroxylamine. The preparation is preferably formulated as a concentrate. The preparation can be used (in particular in the form of the concentrate) for the reduction of free oxygen and the preservation of water, and also correspondingly additivated water. The mixture of N-formals with dialkylhydroxylamine is not only outstandingly compatible, but considerably improves the activity of dialkylhydroxylamines as oxygen scavengers.
    Type: Grant
    Filed: August 8, 2018
    Date of Patent: November 17, 2020
    Assignee: VINK CHEMICALS GMBH & CO. KG
    Inventors: Ralf Gradtke, Wolfgang Beilfuss, Jennifer Knopf, Michael Streek
  • Patent number: 10710903
    Abstract: Processing contaminated water containing volatile or/and semi-volatile compounds via flash evaporation. Method and system include: superheating contaminated water (via a superheating unit), for forming superheated contaminated water having a temperature equal to or higher than a predetermined threshold temperature; flash evaporating the superheated contaminated water (via a flash evaporation unit), for forming superheated contaminated steam; and thermally oxidizing the superheated contaminated steam (via a thermal oxidation unit), so as to thermally oxidize the volatile compounds contained therein, and form thermal oxidation gas/vapor products. Optionally, further includes integrated configuration and operation of a process control/data-information processing unit, and a heat recycling unit. Results in obtaining high yields and high energy efficiencies for removal of volatile compounds from contaminated water.
    Type: Grant
    Filed: January 11, 2016
    Date of Patent: July 14, 2020
    Assignee: Elcon Recycling Center (2003) Ltd.
    Inventor: Zvi Elgat
  • Patent number: 10549268
    Abstract: Embodiments of the present invention include a filter element for decomposing contaminants including a substrate, and a photocatalytic composition comprising at least a photocatalyst. The embodiments of the present invention also includes a system for decomposing contaminants including a substrate, and a photocatalytic composition comprising at least a photocatalyst; and a method using the system.
    Type: Grant
    Filed: July 4, 2014
    Date of Patent: February 4, 2020
    Assignee: Nitto Denko Corporation
    Inventors: Takashi Ozaki, Takuya Fukumura, Keita Mine, Guang Pan, Ekambaram Sambandan, Rajesh Mukherjee
  • Patent number: 10527011
    Abstract: A fuel deoxygenation system has a deoxygenator, an ultrasound transducer, and a control. The ultrasonic transducer is operable to direct ultrasonic waves into a flow passage for a fuel connected to the deoxygenator. A gas turbine engine and a method are also disclosed.
    Type: Grant
    Filed: June 6, 2017
    Date of Patent: January 7, 2020
    Assignee: Hamilton Sundstrand Corporation
    Inventors: Alexander Staroselsky, Haralambos Cordatos
  • Patent number: 10377653
    Abstract: An economical method for recovering phosphate or phosphate and nitrogen from liquid streams. A liquid containing phosphate is introduced into a culture of autotrophic microorganisms in the presence of natural or artificial light, thereby producing a liquid effluent with elevated pH and reduced alkalinity. The alkalinity is reduced through the consumption of bicarbonate/carbonate by the autotrophic microorganisms. The effluent is then chemically treated with low-cost chemicals to provide Ca++ or Mg++ ions necessary to form a phosphate precipitate such as calcium phosphate or magnesium-ammonium-phosphate (MAP). The autotrophic microorganisms can be cultivated in ponds, lagoons, or photobioreactors. The pH of the culture is adjustable within a preferred range of 7.5 to 10.5 by adjusting the photobioreactor operation.
    Type: Grant
    Filed: September 29, 2017
    Date of Patent: August 13, 2019
    Inventor: Dennis A. Burke
  • Patent number: 10280103
    Abstract: The invention presents innovative methods to de-scale sulfate-rich saline streams such as seawater and the like in conjunction with desalination processes. The effective de-scaling of such streams by the inventive methods: (1) enhances the performance, efficiency and cost effectiveness of desalination processes; and (2) allows the viable use of the de-scaled reject brine from desalination processes, for example, as a suitable saline water for oil-gas field's water injection operations to improve hydrocarbons recovery and/or as a feed stock for chlor-alkali industries.
    Type: Grant
    Filed: February 13, 2016
    Date of Patent: May 7, 2019
    Inventor: Mansour S. Bader
  • Patent number: 10266432
    Abstract: The present invention relates to an apparatus and a method for treating ballast water, and an exemplary embodiment of the present invention provides a ballast water treatment apparatus including: a tank; a spray nozzle which supplies ballast water in the form of droplets into the tank; and a gas circulation unit which supplies inert gas to the spray nozzle, and sucks inert gas that is not dissolved in the ballast water in the tank.
    Type: Grant
    Filed: August 10, 2015
    Date of Patent: April 23, 2019
    Assignee: University-Industry Foundation, Yonsei University
    Inventors: Chang Ha Lee, Yongha Park, Jae-Hoon Hong, Tao Wei, Doo Wook Kim, Jae-Jeong Kim, Pil Rip Jeon
  • Patent number: 10258920
    Abstract: Oil wells at a certain stage of their production require Improved Oil Recovery (IOR) using a compatible and suitable saline fluid. To maintain production of such wells as they age further, IOR may advance to Enhanced Oil Recovery (EOR) using immiscible-CO2, miscible-CO2, and miscible CO2-based Water-Alternating-Gas (WAG). This invention provides innovative methods to satisfy the need for IOR and EOR fluids in oil-fields by effectively de-scaling saline streams, recovering waste heat from flue gas, and de-sulfurizing flue gas. The methods are also useful for any power plants or combined heat and power (CHP) co-generation plants (e.g., power-seawater desalination co-generation plants) at sea locations using seawater for cooling and/or for producing drinking water. The inventive methods obviate a variety of operating, economic and environmental problems not only in oil-fields but also in power plants and CHP co-generation plants.
    Type: Grant
    Filed: February 23, 2015
    Date of Patent: April 16, 2019
    Inventor: Mansour S. Bader
  • Patent number: 10214274
    Abstract: A ballast water treatment operating apparatus includes a ballast water treatment unit for performing a certain treatment of ballast water flowing in from the outside for a ballast operation or performing a certain treatment of ballast water discharged into the outside for a de-ballast operation; a positional information receiving unit for receiving positional information; a control unit for confirming a ship's position by using positional information received from the positional information receiving unit and then determining whether to operate the ballast water treatment unit during a ballast operation or during a de-ballast operation, thereby being capable of preventing an unnecessary energy consumption.
    Type: Grant
    Filed: April 5, 2016
    Date of Patent: February 26, 2019
    Assignee: TECHCROSS CO. LTD.
    Inventors: Kyu Won Park, Seong Tae Kim, Hai Don Lee, Yong Seok Park, Gwang Ho Lee, Eun Kyu Park
  • Patent number: 10124346
    Abstract: This invention relates to a process for recovering valuable metals from ore with significantly reduced water consumption through the discrete treatment and storage of coarse tailings. Ore is ground to produce a coarse particulate ore. The coarse particulate ore is treated in a coarse flotation stage to produce a low grade concentrate fraction and a coarse tailings fraction. The low grade concentrate fraction is treated to produce fine tailings and a saleable concentrate. The coarse tailings are treated separately from the fine tailings and water is recovered from the coarse tailings by hydraulically stacking; filtering or screening, whereafter the coarse tailings are dry stacked, without being recombined with the fine tailings.
    Type: Grant
    Filed: January 29, 2016
    Date of Patent: November 13, 2018
    Assignee: ANGLO AMERICAN SERVICES (UK) LTD.
    Inventors: Anthony Owen Filmer, Daniel John Alexander
  • Patent number: 10018605
    Abstract: A method for measuring an amount of dissolved oxygen contained in a liquid sample, including the steps of: (1) adding a deoxygenating amino compound to a liquid sample to prepare the liquid sample having a predetermined concentration of the deoxygenating amino compound; (2) after Step (1), heating the liquid sample containing the deoxygenating amino compound at a temperature of 80° C. or more; (3) after Step (2), measuring the concentration of the deoxygenating amino compound contained in the liquid sample; and (4) calculating the amount of the dissolved oxygen contained in the liquid sample in Step (1) from the amount of the reacted deoxygenating amino compound by comparing the concentration of the deoxygenating amino compound measured in Step (3) and the concentration of the deoxygenating amino compound measured in Step (1).
    Type: Grant
    Filed: August 10, 2015
    Date of Patent: July 10, 2018
    Assignees: MEDISCIENCE ESPOIR INC., SANYO KAKO CO., LTD.
    Inventors: Azuma Takase, Akira Sumiyoshi, Takaaki Matsumoto, Toshikatsu Hagiwara
  • Patent number: 9993826
    Abstract: A hydrate production apparatus according to the present invention comprises: a main body unit having a reaction space in which a hydrate is produced therein; an inlet pipe unit connected to one side of the main body unit so as to introduce, into the reaction space, a host material and a guest material for producing the hydrate; an outlet pipe unit connected to the other side of the main body unit so as to discharge the hydrate produced in the reaction space to the outside; and a pulverizing device unit provided inside the reaction space so as to increase a reaction area for producing the hydrate by pulverizing, into fine-sized particles, an object to be pulverized, which is at least one of the introduced host material and guest material.
    Type: Grant
    Filed: September 2, 2015
    Date of Patent: June 12, 2018
    Assignee: KOREA INSTITUTE OF INDUSTRIAL TECHNOLOGY
    Inventors: Ju Dong Lee, Kyung Chan Kang, Seong Jun Cho, Joung Ha Kim, Hyoung Chan Kim
  • Patent number: 9931355
    Abstract: The invention relates to a combination of compounds derived from gallic acid, with an antitumoral and antimetastatic activity via a mechanism that involves the induction of apoptosis and the immunogenic death of the tumor cells and the subsequent activation of the specific immune response. The invention also relates to a composition containing a combination of derivatives of gallic acid and pharmaceutically acceptable excipients for the production of useful medicaments in the treatment of cancer. The invention further relates to the use of said composition in a coadjuvant in conventional chemotherapy, reducing the doses of chemotherapeutic agents used in the treatment of cancer.
    Type: Grant
    Filed: September 11, 2012
    Date of Patent: April 3, 2018
    Assignees: PONTIFICLA UNIVERSIDAD JAVERIANA, FUNDACION UNIVERSITARIA JUAN N. CORPAS
    Inventors: Susana Fiorentino, John Fredy Hernandez, Claudia Uruena, Diana Castaneda, Luis Miguel Pombo, Tito Alejandro Sandoval
  • Patent number: 9828407
    Abstract: The invention relates to the preparation of phenolic derivatives by enzymatic condensation of phenolics selected among pyrocatechol or its derivatives with the glucose moiety of sucrose. The production of said phenolic derivatives is achieved with a glucosyltransferase (EC 2.4.1.5). These O-?-glucosides of selected phenolics are new, have a solubility in water higher than that of their parent polyphenol and have useful applications in cosmetic and pharmaceutical compositions, such as antioxidative, antiviral, antibacterial, immune-stimulating, antiallergic, antihypertensive, anti-ischemic, antiarrythmic, antithrombotic, hypocholesterolemic, antilipoperoxidant, hepatoprotective, anti-inflammatory, anticarcinogenic, antimutagenic, antineoplastic, anti-thrombotic and vasodilatory formulations, or in any other field of application.
    Type: Grant
    Filed: November 20, 2013
    Date of Patent: November 28, 2017
    Assignee: LIBRAGEN
    Inventors: Daniel Auriol, Renaud Nalin, Patrick Robe, Fabrice Lefevre
  • Patent number: 9611154
    Abstract: A method for the utilization of reaction water formed during the synthesis of hydrocarbons from synthesis gas in a GTL process includes the cleaning of oxygenates while quenching of the synthesis gas at a temperature of more than 500° C. while in contact with a catalyst for steam conversion of oxygenates, and the degasification of the cleaned up reaction water. Cleaned up and degasified water is utilized for cooling synthesis gas to a temperature of lower than 400° C. and for water steam production. The invention ensures efficient treatment of reaction water with removal of oxygenates, the use of obtained treated water as boiler feed water, and for the production of water steam.
    Type: Grant
    Filed: September 30, 2013
    Date of Patent: April 4, 2017
    Assignee: OBSHCHESTVO S ORGANICHENNOY OTVETSTVENNOST' YU “GAZOHIM TEKHNO”
    Inventors: Sergey Erikovich Dolinskiy, Alexander Alexandrovich Dergachev
  • Patent number: 9567146
    Abstract: A process for producing an oxygen absorbing agent includes treating an alloy with an aqueous solution of an acid or an alkali, the alloy including at least one transition metal selected from the group consisting of manganese, iron, platinum, and copper group metals and at least one metal selected from the group consisting of aluminum, zinc, tin, lead, magnesium, and silicon to elute and remove at least a part of the component; and subjecting the alloy obtained by removing at least a part of the component in the alloy to treatment with an aqueous solution of a salt of an inorganic acid or a salt of an organic acid that can form a salt with the transition metal as the component, to form a metal salt in at least a part of the surface of the alloy.
    Type: Grant
    Filed: August 1, 2013
    Date of Patent: February 14, 2017
    Assignee: MITSUBISHI GAS CHEMICAL COMPANY, INC.
    Inventors: Natsuko Matsushita, Emi Ishihara, Hirokazu Tanaka, Tatsuo Iwai
  • Patent number: 9487419
    Abstract: A method for treating acid mine drainage includes mixing acid mine drainage (20) and alkaline tailings from a gold recovery process (140). The acid mine drainage is thereby neutralized (12).
    Type: Grant
    Filed: March 12, 2013
    Date of Patent: November 8, 2016
    Assignee: MINTAILS MINING S A (PTY) LIMITED
    Inventors: Jan Hendrik Phillipus Jacobs, Robert George Freeman
  • Patent number: 9278860
    Abstract: A method and an apparatus for recycling waste sulfuric acid solution are provided. The method includes providing a reaction tank and introducing a waste sulfuric acid (H2SO4) solution into the reaction tank, and the waste sulfuric acid solution includes hydrogen peroxide (H2O2). The method also includes supplying a compound containing chlorine into the reaction tank. The method further includes mixing the compound containing chlorine with the waste sulfuric acid solution to promote a chemical reaction that decomposes the hydrogen peroxide (H2O2).
    Type: Grant
    Filed: July 22, 2014
    Date of Patent: March 8, 2016
    Assignee: Taiwan Semiconductor Manufacturing Co., Ltd.
    Inventors: Jin-Feng Shiu, Rouh-Jier Wang, Ching-Jung Hsu, Wan-Yu Chen, Han-Ru Hung
  • Patent number: 9212070
    Abstract: A water treatment system is provided including a tank having a top, a control valve, and an air inlet. The control valve is positioned on the top of the tank and in fluid communication with the tank. The control valve includes a plurality of orifices in fluid communication with a source of untreated water, a treated water outlet, a drain, and a source of sterilizing fluid. The air inlet is in fluid communication with the tank and with a first venturi. The control valve is operative to control the flow of untreated water through the first venturi to draw air through the air inlet and into the tank. The control valve includes a sterilizer valve that is operative to open and close at least one passage in fluid communication between the control valve and the source of sterilizing fluid.
    Type: Grant
    Filed: June 8, 2012
    Date of Patent: December 15, 2015
    Assignee: CHANDLER SYSTEMS, INC.
    Inventor: William D. Chandler, Jr.
  • Publication number: 20150136705
    Abstract: A method for treating drainage containing hydrogen peroxide that has been used for sterilizing and washing an inside of a water treatment system or washing and surface finishing of electronic components includes passing the drainage through the hydrogen peroxide decomposition reactor, injecting effluent water from the hydrogen peroxide decomposition reactor into a side part of the tubular container of the gas-liquid separator, and contacting the drainage with the hydrogen peroxide decomposition catalyst to decompose the hydrogen peroxide in the drainage into oxygen and water, thereby yielding the treated water.
    Type: Application
    Filed: January 16, 2015
    Publication date: May 21, 2015
    Inventors: Hiroto TOKOSHIMA, Norito IKEMIYA, Hideki KOBAYASHI
  • Patent number: 9034195
    Abstract: A method of treatment of water in an aquatic environment. Water is first pumped from a reservoir to a first mixing station. An inert gas is introduced into the pumped water at the first mixing station to provide inert gas saturated water, which inert gas saturated water will displace undesired gasses in the water in the reservoir. The inert gas saturated water is then pumped to a sparging column such that the inert gas and undesired gasses will be released from the inert gas saturated water to provide depleted water.
    Type: Grant
    Filed: November 16, 2012
    Date of Patent: May 19, 2015
    Assignee: Revalesio Corporation
    Inventor: Anthony B. Wood
  • Patent number: 9011701
    Abstract: The present invention relates to a method and arrangement for the treatment of liquid material based on organic waste products, in particular sludge from sewage disposal plants and the like, wherein the sludge material is added and mixed with chemicals, in particular sulphuric acid, nitric acid, and/or ammonia, during the vaporization and degasification of liquid from the material to increase the solids content thereof.
    Type: Grant
    Filed: August 21, 2007
    Date of Patent: April 21, 2015
    Assignee: Conterra Technology AS
    Inventor: Ove Blomkvist
  • Publication number: 20150068985
    Abstract: A method for removing chloride from samples containing volatile organic carbon, wherein a chloride containing sample is mixed with a difficultly volatile acid, wherein hydrochloric acid gas arises, which is present in dissolved form in a sample-acid mixture and then the hydrochloric acid gas is purged by a carrier gas from the sample-acid mixture, wherein the hydrochloric acid gas is removed from the carrier gas following the purging and the carrier gas is fed back to the sample-acid mixture. In order during the hydrochloric acid purging largely to suppress the driving out of easily volatile organic compounds, the sample-acid mixture has a temperature of approximately 3° C. to 30° C., wherein, following the purging from the sample-acid mixture, the hydrochloric acid gas is removed from the carrier gas by absorption with water.
    Type: Application
    Filed: November 12, 2014
    Publication date: March 12, 2015
    Inventors: Ulrich Kathe, Andrea Gross, Anja Gerlinger
  • Patent number: 8968574
    Abstract: A method and device for the wet oxidation treatment of liquid waste laden with mineral matter in suspension. The device comprises a reactor including a treatment column, first and second heat exchangers placed upstream and downstream, respectively, of the reactor. The solution to be treated, laden with mineral matter to which an oxidizing gas has been added, is injected into the reactor for treatment after being preheated in the first heat exchanger. When the solution exits the reactor, the hot treated mixture is divided into two hot stream fragments. The first hot treated mixture stream fragment, the flow rate of which is kept constant by a diaphragm column, is used for controlling the temperature of the first heat exchanger and then discharged after being used in the first heat exchanger. The second hot treated mixture stream fragment is directly cooled and discharged when the second hot treated mixture stream fragment leaves the reactor.
    Type: Grant
    Filed: March 15, 2010
    Date of Patent: March 3, 2015
    Assignee: Granit Technologies S.A.
    Inventor: Boris Correa
  • Publication number: 20150034567
    Abstract: A process for removing acid decomposable contaminants from a processing liquid wherein an acid is admixed with a processing liquid and the mixture of acid and processing liquid are introduced into a degassing vessel such that the gas formed by the reaction of the acids and the decomposable gases is released and a processing liquid freed of acid decomposable contaminants is removed from the degassing vessel.
    Type: Application
    Filed: February 19, 2013
    Publication date: February 5, 2015
    Inventors: Stephen W. Carlson, Raymond G.F. Abry
  • Patent number: 8946309
    Abstract: Process to generate synthesis gas and/or liquid raw materials and/or energy materials from waste and/or biomass by performing the following steps: a) solvolysis of the organic components of waste and/or biomass in an alkaline solution or hydrate smelter at a temperature range of 150° to 250° C. and pressure between 3 and 12 bar, whereby the organic components are converted into at least one liquid phase and the inorganic components are sedimented; b) elimination of the inorganic components from the liquid phase by physical separation methods; c) transfer of the vapors generated during the solvolysis into a rectification column, where the organic components are separated from water; and d) further separation of the organic components by rectification, extraction and sorption and/or conversion by thermal gasification into synthesis gas or burnable gas.
    Type: Grant
    Filed: November 20, 2009
    Date of Patent: February 3, 2015
    Inventors: Wenzel Bergmann, Thomas Müller
  • Publication number: 20150021278
    Abstract: An apparatus for continuous hydrolysis of sludge comprising material of biological origin, such as organic material, the apparatus comprising a reactor with: an inlet for feeding sludge into the reactor in a feeding zone thereof, an inlet for feeding steam into the reactor in a steam feeding zone thereof, an outlet for allowing processed sludge to exit the reactor, wherein at least a part of the reactor forms a first ascending zone in which the sludge during use flows in an upwards direction, and a first descending zone in which the sludge during use flows in a downwards direction. A first gas collecting zone is defined in the transition between the first ascending zone and the first descending zone, and a first gas outlet is arranged to allow a part of the gas collected in the first gas collecting zone to be removed, while a part of the gas remains in the gas collecting zone.
    Type: Application
    Filed: February 8, 2013
    Publication date: January 22, 2015
    Applicant: Veolia Water Solutions & Technologies Support
    Inventor: Soren Johannes Hojsgaard
  • Patent number: 8900444
    Abstract: A solvent that reversibly converts from a hydrophobic liquid form to hydrophilic liquid form upon contact with water and a selected trigger, e.g., contact with CO2, is described. The hydrophilic liquid form is readily converted back to the hydrophobic liquid form and water. The hydrophobic liquid is an amidine or amine. The hydrophilic liquid form comprises an amidinium salt or an ammonium salt.
    Type: Grant
    Filed: November 8, 2013
    Date of Patent: December 2, 2014
    Assignees: Queen's University at Kingston, GreenCentre Canada
    Inventors: Philip G. Jessop, Lam N. Phan, Andrew J. Carrier, Rui Resendes, Dominik Wechsler
  • Publication number: 20140332474
    Abstract: Process for reducing the Total Organic Carbon of a first aqueous composition (A) comprising submitting (A) to a treatment with active chlorine at a first pH value in order to obtain a second aqueous composition (B), submitting at least one part of (B) to a venting treatment at a second pH value lower than the first pH value in order to obtain a third aqueous composition (C) and submitting at least one part of (C) to a treatment with active chlorine at a third pH value lower than the second pH value in order to obtain a fourth aqueous composition (D) with a Total Organic Carbon lower than the Total Organic Carbon of (A).
    Type: Application
    Filed: December 12, 2012
    Publication date: November 13, 2014
    Inventor: Bruno Fouchet
  • Patent number: 8877069
    Abstract: A system is provided that substantially increases the efficiency of CO2 capture and removal by positioning a catalyst within an optimal distance from the air-liquid interface. The catalyst is positioned within the layer determined to be the highest concentration of carbon dioxide. A hydrophobic tether is attached to the catalyst and the hydrophobic tether modulates the position of the catalyst within the liquid layer containing the highest concentration of carbon dioxide.
    Type: Grant
    Filed: February 8, 2012
    Date of Patent: November 4, 2014
    Assignee: Lawrence Livermore National Security, LLC.
    Inventors: Carlos A. Valdez, Joe H. Satcher, Jr., Roger D. Aines, Sergio E. Wong, Sarah E. Baker, Felice C. Lightstone, Joshuah K. Stolaroff
  • Patent number: 8871098
    Abstract: The invention discloses an apparatus and method to uniformly disperse ozone gas bubbles into liquid phase water for the treatment thereof. The apparatus consists of a water inlet section connected with a section with structured packing or monolith having parallel flow channels. A portion of the influent water is withdrawn from the main water stream as a side stream, pressurized by a pump, mixed with ozone-containing gas, and then injected back into the main water flow. The side stream may be divided into multiple streams either before or after mixing with the ozone-containing gas, and then injected into the main flow section upstream of the packed section. In alternate embodiments, the ozone-containing gas can be injected directly through the gas diffusers just upstream of the packed section in order to achieve uniform concentration of gas and liquid in the fluid entering the monolith.
    Type: Grant
    Filed: September 22, 2011
    Date of Patent: October 28, 2014
    Assignee: Air Products and Chemicals, Inc.
    Inventors: Vipul P. Dholakia, Annemarie Ott Weist, David Lee Mitchell, Jr.
  • Publication number: 20140291258
    Abstract: The invention relates to a solution for enriching a liquid with oxygen. For this purpose, oxygen from the ambient air is introduced into the liquid by means of an injector and is partially dissolved in it. The liquid which leaves the injector, and which is laden with dissolved and undissolved gas components of the air, is then introduced into at least one degassing unit (2), which is connected downstream to the injector, for the removal of undissolved gas components that form bubbles in the liquid. According to the invention, the injector involves a multiple injector having at least two injector chambers (11, 12, 13, 14).
    Type: Application
    Filed: April 27, 2012
    Publication date: October 2, 2014
    Inventor: Uwe Wuerdig
  • Patent number: 8821728
    Abstract: A system of treating high nitrogen content waste water is disclosed, where the system includes a precipitation and conditioning subsystem, an ammonia stripper subsystem, and a denitrification subsystem. The system is adapted to reduce nitrogen contamination to level below about 10 ppm and in certain embodiments below 3 ppm.
    Type: Grant
    Filed: September 20, 2013
    Date of Patent: September 2, 2014
    Inventors: Randy A. Galgon, Allen Ray Stickney, Richard B. Steinberg
  • Publication number: 20140224747
    Abstract: Method and apparatus for treating potable water in municipal and similar tanks to reduce and remove undesirable disinfectant byproducts such as trihalomethanes from the water by providing a water circulation system to create circulation patterns in the tank water and an air flow system for creating an air flow pattern in the headspace region of the enclosed tank above the water surface. In operation, a portion of the tank water is drawn-up a draft tube from the tank floor to above the water surface and sprayed through a nozzle outwardly about a vertical axis and slightly downwardly toward the surface of remaining tank water. The air flow system creates and directs a high volume of air through the tank above the water surface to volatize undesirable trihalomethanes in the drawn-up water portion to gaseous state to enter the air flow pattern and exit the tank into ambient air.
    Type: Application
    Filed: February 8, 2013
    Publication date: August 14, 2014
    Applicant: Medora Environmental, Inc.
    Inventors: Corey M. Simnioniw, Jonathan L. Zent, Willard R. Tormaschy, Joel J. Bleth, Gary A. Kudrna, Douglas P. Walter
  • Publication number: 20140183142
    Abstract: A method for treating hydrogen sulfide in a solution includes providing the solution containing hydrogen sulfide. The method also includes adding sodium nitrite to the solution in an amount suitable to react with the hydrogen sulfide and treat the hydrogen sulfide.
    Type: Application
    Filed: March 4, 2014
    Publication date: July 3, 2014
    Applicant: United Laboratories International, LLC
    Inventors: Jack G. Frost, Kenneth J. Snyder
  • Publication number: 20140158638
    Abstract: Implementations of the present invention relate to systems, methods, and apparatus for filtering and treating water, such as tap water, well water, spring water, etc., and producing drinking, bathing, and swimming water. More specifically, such systems, methods, and apparatus can produce purified water by removing substantially all suspended as well as dissolved solids, undesirable acids, gasses and all and any contaminates from the water. Additionally, the systems, methods, and apparatus can produce reprogrammed high biophoton mineralized drinking water by chilling vortexing over proprietary lodestones, ingenious, sedimentary and metamorphic rocks and creating bicarbonate ions in the water introducing minerals and/or salts into the water.
    Type: Application
    Filed: December 12, 2012
    Publication date: June 12, 2014
    Applicant: PRISTINEHYDRO DEVELOPMENT, INC.
    Inventors: Glen B. Caulkins, Michael H. Colburn
  • Patent number: 8734653
    Abstract: A mercury remediation method and apparatus for reducing mercury levels in water to a nanogram per liter level that uses four treatment steps: (1) chelation; (2) oxidation; (3) reduction; and (4) air stripping, vapor/liquid separation. There is a fifth step in the process, which does not involve the wastewater. It is to scrub the stripper air of the volatile mercury in an off-gas adsorption unit or to condense volatile mercury in a cryogenic mercury trap.
    Type: Grant
    Filed: November 30, 2011
    Date of Patent: May 27, 2014
    Inventor: Terrence W. Aylesworth
  • Publication number: 20140120018
    Abstract: A process and apparatus to remove and breakdown volatile organic compounds from drinking water, groundwater, wastewater, frack water and air exhaust. The process entails filling a tank, chamber, pipe, or column with ozone-containing gas, introducing into this ozone-containing gas-filled tank, chamber, pipe or column, very small droplets of water, contaminated with volatile organic compounds which then volatilize out from the water and break down in the ozone gas thereby improving the water quality and associated air quality. The current invention has been shown to achieve more than 99% combined removal efficiency. The process can also be used to treat air streams containing volatile organic compounds. To increase efficiency, ozone is introduced where the atomized particles are smallest. Three configurations utilizing said process include upward and downward spray of contaminated water into ozone and pumping through openings in an enclosure to a reaction chamber filled with ozone-containing gas.
    Type: Application
    Filed: October 25, 2012
    Publication date: May 1, 2014
    Inventors: Marcia Jada Berger, Isaac Wayne Anderson
  • Patent number: 8702994
    Abstract: A method for treating hydrogen sulfide in a solution includes providing the solution containing hydrogen sulfide. The method also includes adding sodium nitrite to the solution in an amount suitable to react with the hydrogen sulfide and treat the hydrogen sulfide.
    Type: Grant
    Filed: March 31, 2009
    Date of Patent: April 22, 2014
    Assignee: United Laboratories International, LLC
    Inventors: Jack G. Frost, Kenneth J. Snyder, Jr.
  • Patent number: 8673956
    Abstract: Imido-acid salts and compositions containing imido-acid salts are described herein. Methods of their preparation and use are also described herein. The methods of using the imido-acid salts include the reduction of volatile compounds from gas and liquid streams and the delivery of pharmaceutical agents to subjects.
    Type: Grant
    Filed: November 29, 2012
    Date of Patent: March 18, 2014
    Assignee: Board of Trustees of The University of Alabama
    Inventor: Jason E. Bara
  • Patent number: 8632742
    Abstract: Disclosed are methods for controlling, mercury emissions, and more particularly, to methods for controlling mercury re-emissions from a wet flue gas desulfurizer used in a combustion process. A method of controlling mercury re-emission from a combustion process includes measuring either mercury concentration, oxidation-reduction, potential (ORP), and/or sulfide concentration within a scrubber liquor of a wet flue gas desulpherizer (wFGD); correlating the mercury concentration, ORP, and /or sulfide concentration with an amount of mercury re-emission additive required in the scrubber liquor to reduce and/or prevent mercury re-emission to a selected level; and adjusting the rate of addition of mercury re-emission additive into the scrubber liquor to attain the selected level of mercury re-emission.
    Type: Grant
    Filed: October 22, 2012
    Date of Patent: January 21, 2014
    Assignee: Nalco Company
    Inventors: Bruce A. Keiser, Jitendra Shah, John V. Meier, Robert W. Dorner, Jianwei Yuan, Rebecca L. Stiles, Wayne Carlson, Darlington Mlambo
  • Patent number: 8580124
    Abstract: A solvent that reversibly converts from a hydrophobic liquid form to hydrophilic liquid form upon contact with water and a selected trigger, e.g., contact with CO2, is described. The hydrophilic liquid form is readily converted back to the hydrophobic liquid form and water. The hydrophobic liquid is an amidine or amine. The hydrophilic liquid form comprises an amidinium salt or an ammonium salt.
    Type: Grant
    Filed: October 28, 2010
    Date of Patent: November 12, 2013
    Assignees: Queen's University at Kingston, GreenCentre Canada
    Inventors: Philip G. Jessop, Lam N. Phan, Andrew J. Carrier, Rui Resendes, Dominik Wechsler
  • Publication number: 20130292335
    Abstract: The present invention provides processes for removing nitrogen species from fresh water or high salinity water recirculated aquaculture systems. The processes are based on physico-chemical treatments which are performed at ambient temperatures and at low p H values thus keeping the total ammonia nitrogen concentrations below a value which is considered detrimental for the growth or survival rate of cultured fish/shrimp.
    Type: Application
    Filed: November 17, 2011
    Publication date: November 7, 2013
    Inventors: Ori Lahav, Youri Gendel, Noam Mozes, Ayana Benet Perlberg, Yuri Hanin
  • Patent number: 8574442
    Abstract: A method for treating effluent containing dissolved or suspended solids includes directing the effluent containing dissolved or suspended solids to a reactor and oxidizing at least a portion of the dissolved or suspended solids in the reactor with an oxidizing agent. Oxidation is carried out at a temperature ranging between approximately 20° C. and approximately 350° C. and at a pressure ranging between approximately 1 bar and approximately 160 bar. A gaseous phase and a liquid phase form within the reactor during oxidation. The method includes separating the gaseous phase from the liquid phase and heating the effluent in the reactor with the heat produced from the oxidation of the dissolved or suspended solids.
    Type: Grant
    Filed: April 13, 2007
    Date of Patent: November 5, 2013
    Assignee: Veolia Water Solutions & Technologies Support
    Inventors: Merzark Belkhodja, Didier Cretenot
  • Patent number: 8529771
    Abstract: A process for working up alkaline process wastewater from the nitration of aromatic compounds to mono-, di- and trinitroaromatics, said alkaline process wastewater having a pH of 7.5 to 13, comprising the steps of a) acidifying the alkaline process wastewater by adding concentrated sulfuric acid which originates from the workup of the aqueous, sulfuric acid-containing phase obtained in the nitration to a pH below 5, which forms a mixture A consisting of organic phase which separates out and acidic aqueous phase, b) contacting the mixture A with fresh sewage sludge, and c) removing the sewage sludge.
    Type: Grant
    Filed: December 13, 2010
    Date of Patent: September 10, 2013
    Assignee: BASF SE
    Inventors: Ruediger Fritz, Renate Hempel, Michael Zoellinger, Anne-Kathrin Merten, Doris Zschieschang, Ina Homann, Annett Gersdorf, Holger Allardt, Reiner Reetz, Elvira Flegel