Abstract: A method for cleaning process apparatus used for production of liquids, especially for cleaning filters, for example membrane filters. The apparatus is contacted with a solution of periodate. It is especially preferred that the cleaning process is carried out at a temperature between 15 and 95° C.

Abstract: A method for treating a sludge to be fed to a bioreactor for treating wastewater, or an anaerobic or aerobic sludge digester, the method comprising contacting the sludge with free nitrous acid.

Abstract: A method for decontaminating a liquid having sulfides includes preparing a stabilized sodium percarbonate solution. In an embodiment, the method includes decontaminating a liquid. The liquid comprises reactive sulfides. The method also includes preparing a stabilized sodium percarbonate solution, which includes adding sodium percarbonate to a liquid solution. The liquid solution comprises a peroxide stabilizer and an acid. The method further includes dosing the liquid into the stabilized sodium percarbonate solution to decontaminate the liquid by oxidizing at least a portion of the reactive sulfides.

Abstract: A method and system of providing ultrapure water for semiconductor fabrication operations is provided. The water is treated by utilizing a free radical scavenging system and a free radical removal system. The free radical scavenging system can utilize actinic radiation with a free radical precursor compound, such as ammonium persulfate. The free radical removal system can comprise use of a reducing agent. The ultrapure water may be further treated by utilizing ion exchange media and degasification apparatus. A control system can be utilized to regulate addition of the precursor compound, the intensity of the actinic radiation, and addition of the reducing agent to the water.

Abstract: Systems and methods for removing organic contaminants from water may be used, for example, to treat produced water from a steam assisted heavy oil recovery operation. The treated produced water may be re-used to create steam. Alternatively, the produced water may be a blowdown stream treated to facilitate further treatment in a thermal crystallizer. The treatments may include pH adjustment or separating de-solubilized organics or both. Other treatments may include one or more of oxidation, sorption and biological treatments. The treatments may be used alone or in various combinations. One exemplary combination includes reducing the pH of produced water, separating de-solubilized organics from the produced water, and oxidizing the produced water or contacting the produced water with activated carbon.

Abstract: A mercury remediation method and apparatus for reducing mercury levels in water to a nanogram per liter level that uses four treatment steps: (1) chelation; (2) oxidation; (3) reduction; and (4) air stripping, vapor/liquid separation. There is a fifth step in the process, which does not involve the wastewater. It is to scrub the stripper air of the volatile mercury in an off-gas adsorption unit or to condense volatile mercury in a cryogenic mercury trap.

Abstract: Advanced oxidation process namely ozonation and Fenton's (hydrogen peroxide/Fe:2+) were utilized to degrade kinetic hydrate inhibitor (KHI). The oxidized solution after scavenging oxygen can be successfully disposed to the injection well. This facilitates use of KHI more frequently and in higher concentrations for future projects oil & gas operations. It also offers an alternative that competes efficiently with thermodynamic hydrate inhibitor (THI) or complements THI.

Abstract: Various embodiments of contaminant removal systems, compositions, and methods are described herein. In one embodiment, a method for oxidizing a contaminant includes contacting the contaminant with a peroxygen compound and initializing, maintaining, or propagating degradation of the peroxygen compound with an oxygenated organic compound, thereby releasing oxidizing radicals. The method also includes oxidizing the contaminant with the released oxidizing radicals.

Abstract: A method of removing contaminants from slurry samples is set forth. The method includes the utilization of repeated pressurizing and depressurizing steps to disrupt solidified particles in solid-containing slurries thereby increasing decontamination efficiency. An expansion fluid is injected into the slurry sample sufficient to create microbubbles when the slurry sample is depressurized. The micro bubbles mechanically disrupt the solidified particles increasing contaminant exposure. The microbubbles also provide for increased interfacial regions where contaminants can accumulate at gas-liquid thin films that are in close proximity to and can be effectively removed using a suitable expansion fluid and optional decontamination agents.

Abstract: A method of treating water in order to minimize scaling and biomass buildup in water conduits or containers in which the treated water is used includes pressurizing and optionally filtering ambient air, processing the pressurized ambient air in a chamber including at least one ultraviolet light source operated to generate an output flow mixture of pressurized air and reactive oxygen species (ROS) gas, mixing the pressurized ROS/gas output mixture to realize a flow of water/pressurized ROS gas/air mixture and outputting the flow of water/pressurized ROS gas/air mixture as the treated water process product. The process includes generating reactive oxygen species (ROS) gas in the pressurized ROS/gas output mixture including at least one of Super Oxide (O2?), Peroxide (—O2—), Hydro peroxide (HO2?), Hydroxyl Radicals (OH.), Ozone (O3?) and Molecular Oxygen (O2).

Abstract: The present invention relates generally to stable percarboxylic acid compositions comprising, inter alia, at least two stabilizing agents, and various uses for water treatments, including water treatments in connection with oil- and gas-field operations. The present invention also relates to slick water compositions and gel based compositions that comprise stable percarboxylic acid compositions and the use thereof in oil- and gas-field operations.

Abstract: A water treatment method by catalyzing ozone with a persulfate comprises the following steps: introducing the ozone into an ozone contact reactor filled with water to be treated; at the same time putting the persulfate into the reactor, wherein a stirring state is kept in the water treatment process. The method solves the problems of difficulty in the ionization of hydrogen peroxide, low capability in inducing the decomposition of the ozone, high hydrogen peroxide residues and inconvenience of hydrogen peroxide transportation and storage existing in the conventional water treatment method for catalyzing the ozone by using the hydrogen peroxide.

Abstract: A method of removing color bodies from a fermentation broth includes precipitating a color-forming impurity (color body) by adjusting the fermentation broth to a pH greater than about 13; filtering our precipitated color-forming impurities from the broth; and bleaching a second color impurity by treating the broth with an oxidizing agent.

Abstract: Systems and methods for generating reactive oxygen species formulations useful in various oxidation applications. Exemplary formulations include singlet oxygen or superoxide and can also contain hydroxyl radicals or hydroperoxy radicals, among others. Formulations can contain other reactive species, including other radicals. Exemplary formulations containing peracids are activated to generate singlet oxygen. Exemplary formulations include those containing a mixture of superoxide and hydrogen peroxide. Exemplary formulations include those in which one or more components of the formulation are generated electrochemically. Formulations of the invention containing reactive oxygen species can be further activated to generate reactive oxygen species using activation chosen from a Fenton or Fenton-like catalyst, ultrasound, ultraviolet radiation or thermal activation.

Abstract: The invention relates to a method for treating water charged with colloidal impurities, either dissolved or suspended, in a treatment plant, wherein said method comprises: the step of contacting said water, in an advanced oxidation area, with hydrogen peroxide in the presence of at least one transition-metal salt; a flocculation step that comprises contacting said water, in a flocculation area, with at least one flocculation additive and with at least one ballast comprising at least one non-soluble granular material denser than water and used as a biomass carrier; the step of feeding the water and floc mixture thus obtained into a settling area; the step of separating the treated water at the upper portion of said settling area from a mixture of sludge and ballast resulting from the settling of said flocs; the step of extracting the sludge and ballast mixture at the lower portion of said settling area; and the step of recycling at least a portion of the sludge into said advanced oxidation area.

Abstract: A method of water treatment include mixing a hydrogen peroxide solution into a flow of water and subsequently mixing and dissolving ozone into the flow of water. The hydrogen peroxide solution may be conditioned with a water-soluble hydroxide salt. After the mixing and dissolving of the ozone into the flow of water, at least a portion of the hydrogen peroxide solution dissociates into hydroperoxide ions at a dissociation rate, the hydroperoxide ions react with the ozone to form hydroxyl radicals, and the hydroxyl radicals react with organic contaminants in the flow of water to remove the organic contaminants. The flow of water is then directed into a contact basin to facilitate the further decay of ozone.

Abstract: Waste household liquid containing solid fecal content so as to include potentially toxic bacterial content is collected in a septic tank and periodically discharged through a pipe where a quantity of hydrogen peroxide is injected into the pipe to be mixed with the waste liquid. The pipe carries the liquid to a centrifugal separator to separate the solid content from the liquid so that the solid content free from toxic bacterial content is collected and the waste liquid with the solid content removed is discharged for re-use or for disposal to the ground.

Abstract: Synergistic mixtures of haloamines and their use to control the growth of microorganisms in aqueous systems are disclosed. The method of using the synergistic mixtures entails adding an effective amount of a monohaloamine and an effective amount of a dihaloamine to an aqueous system. The ratio of monohaloamine to dihaloamine is selected to result in a synergistic biocidal effect.

Abstract: A hybrid chemical/mechanical water treatment plant and method employing rapid sulfur dioxide chemical disinfection and dewatering technology in conjunction with lime and oxidization/reduction agents to removal pharmaceuticals and personal care products from waters to meet operating constraints and environmental permitting restrictions and siting limitations for water treatment.

Abstract: A method for the combined chemical oxidation/assisted bioremediation of contaminated materials, comprising contacting a contaminated material with at least one metal chelate and at least one peroxide compound.

Abstract: The invention is directed to processes for treating biosolids that result in high-value, nitrogen-containing, slow-release, organically-augmented inorganic fertilizer that are competitive with less valuable or more costly conventional commercially manufactured fertilizers. The process involves conditioning traditional waste-water biosolids and processing the conditioned biosolids continuously in a high throughput manufacturing facility. The exothermic design and closed loop control of the primary reaction vessel decreases significantly the amount of power necessary to run a manufacturing facility. The process utilizes green technologies to facilitate decreased waste and enhanced air quality standards over traditional processing plants. The fertilizer produced from recovered biosolid waste is safe and meets or exceeds the United States Environment Protection Agency (USEPA) Class A and Exceptional Quality standards and is not subject to restrictions or regulations.

Abstract: A device and a method for treating liquids by ozone, including a pipe in which a main flow of the liquid is guided in a flow direction from an inlet to an outlet, an ozone feed point at which ozone can be introduced in gas form into the main flow, and at least two mixers which are located downstream of the ozone feed point, wherein the mixers are arranged at a distance from one another, and wherein at least one reaction zone is formed between the mixers, and wherein the mixers are designed in such a way that they each dissolve only a portion of the ozone in the main flow that has been introduced in gas form.

Abstract: A method for removing sulfide from an aqueous alkali solution in which hydrogen peroxide is introduced into a sulfide-containing aqueous alkali solution associated with an alkali mineral recovery operation. The method is particularly useful for the processing of sulfide-containing aqueous alkali solutions containing NaHCO3 and Na2CO3, where bicarbonate in the sulfide-depleted alkali solution is decomposed to form Na2CO3, with concurrent evolution of gaseous carbon dioxide byproduct but without formation of gaseous H2S as a pollutant, and where Na2CO3 values are subsequently recovered from the sulfide-depleted carbonate-rich alkali solution via a crystallization operation.

Abstract: A method of degrading halogenated organic compounds, to use of the method for decontaminating PFOS (perfluorooctanesulfonic acid) and PFOA (perfluorooctanoic acid) contaminated medium, and a composition such as that which is suitable to be applied in said method.

Abstract: The present invention provides systems and methods for in-situ remediation of soil and groundwater having contaminants such as but not limited to organic compounds perhaps providing adsorption, chemical oxidation, and even biodegradation of contaminants with novel treatments such as but not limited to mixtures of granular activated carbon, calcium peroxide, sodium persulfate, and nitrate perhaps in various concentrations.

Abstract: Certain exemplary embodiments provide methods for reducing a concentration of a contaminant associated with a medium, which can be any substance or material, such as soil, water, air, and/or fluid. In one exemplary method, the medium is treated with a ferric chelate and an oxidizing agent in amounts effective to oxidize at least a portion of the contaminant.

Abstract: Provided is an arsenic-containing solid comprising 100 parts by mass of a scorodite-type iron-arsenic compound and at least 1 part by mass of an iron oxide compound added thereto, in which the scorodite-type iron-arsenic compound is produced by adding an oxidizing agent to an aqueous acidic solution that contains a 5-valent arsenic (V) ion and a 2-valent iron (II) ion, then promoting the precipitation of an iron-arsenic compound with stirring the liquid, and finishing the precipitation thereof within a range where the pH of the liquid is at most 1.2. The iron oxide compound includes goethite, hematite and their mixture, preferably having a BET specific surface area of at least 3 m2/g, more preferably at least 20 m2/g.

Abstract: A method for removing sulfide from an aqueous alkali solution in which hydrogen peroxide is introduced into a sulfide-containing aqueous alkali solution associated with an alkali mineral recovery operation. The method is particularly useful for the processing of sulfide-containing aqueous alkali solutions containing NaHCO3 and Na2CO3, where bicarbonate in the sulfide-depleted alkali solution is decomposed to form Na2CO3, with concurrent evolution of gaseous carbon dioxide byproduct but without formation of gaseous H2S as a pollutant, and where Na2CO3 values are subsequently recovered from the sulfide-depleted carbonate-rich alkali solution via a crystallization operation.

Abstract: Embodiments of the invention provide a tetraamido macrocyclic ligand catalytic activator bound to a carbon containing support. When combined with an oxidant, such as a peroxy compound, the carbon supported catalytic activator is a long-lived, robust oxidizing agent useful for oxidizing oxidizable compounds, such as aromatic groups, conjugated pi systems, natural and synthetic hormones, pesticides, pathogens, and dyes.

Abstract: Disclosed is a method, apparatus and system for the remediation of contaminated soils, groundwater and water. A combination of reagents such as persulfate and ozone or persulfate, ozone and hydrogen peroxide may be used to enhance destruction of organic contaminants. Reagents may be injected into the smear zone to trap and destroy volatile compounds that may otherwise escape treatment.

Abstract: Methods for introducing a substantially uniform concentration of a functional agent into a flowing stream of water using a shaped composition. The composition may be shaped and sized to be inserted into a device configured to be attached over the end of a faucet. The shaped composition comprises a dissolvable region including a functional agent (e.g., an anti-microbial sanitizing agent). A non-dissolvable region disposed adjacent to the dissolvable region may optionally be provided. The substantially non-dissolvable region remains substantially intact as the dissolving region is progressively dissolved, introducing the functional agent into a flowing stream of water.

Abstract: Disclosed are reactive fibers having a polycationic exterior surface to which multivalent peroxy anions are bound. The use of such fibers, mats of such fibers, and filters of such fibers, as well as methods of treating fluid streams, and rejuvenating such fibers, mats and filters are also disclosed.

Abstract: The invention relates to a method and a device for purifying liquid effluents, in which water is separated from substances by performing, in a single vertical enclosure (3), a vertical bubbling in the effluents fed at a flow rate d. The enclosure has a free surface and includes at least two compartments (4, 5, 6, 7) communicating together for enabling a circulation between the compartments successively from the top to the bottom and from the bottom to the top between the lower portion thereof and a medium level at a flow rate D at least three times higher than the flow rate d. The supernatant phase is continuously discharged and a hydraulic or gaseous chemical oxidation of said effluents is simultaneously carried out in the same enclosure, the chemical oxidation rate and the bubble flow rate and size being selected in order to progressively obtain a separation of the solid/liquid and liquid/liquid phases at the surface of the enclosure for obtaining a COD below a predetermined threshold.

Abstract: An activated carbon having a high catalytic activity as an oxidation catalyst or a decomposition catalyst, and use therefor are provided. The activated carbon has (a) an oxygen content in a range from 1.40 to 4.30% by mass, (b) a nitrogen content in a range from 0.90 to 2.30% by mass, (c) a sulfur content in a range from 0.50 to 1.20% by mass, and (d) a hydrogen content in a range from 0.40 to 0.65% by mass. The activated carbon may have at least one characteristic of (e) an amount of an acidic surface functional group of 0.10 to 0.36 meq/g, (f) an amount of a basic surface functional group of 0.50 to 1.30 meq/g, and (g) a benzene adsorption capacity of 25 to 50%. The activated carbon catalyzes an oxidation reaction of N-(phosphonomethyl) iminodiacetic acid with a peroxide (e.g., hydrogen peroxide) and achieves an efficient production of N-(phosphonomethyl)glycine even after repetitive use. The activated carbon also efficiently decomposes a chloramine.

Abstract: A Fenton reaction catalyst including a reaction product as an active component, in which the reaction product is obtained by using roasted and ground coffee beans (in particular, coffee grounds) or tea leaves (in particular, tea dregs) as feedstocks for supplying a component having a reduction effect, and mixing the feedstocks for supplying the component having a reduction effect with an iron-supplying source containing divalent or trivalent iron in the presence of water. The Fenton reaction catalyst can be used to generate hydroxy radicals from hydrogen peroxide. The Fenton reaction catalyst can maintain iron in a divalent state for a long period of time.

Abstract: The object of the invention is to provide a method for cleaning circulation water, which reduces the cost of operation and maintenance as much as possible, without a cumbersome cleaning operation such as by detaching electrode plates from an electrolysis cleaning tank and removing scale from inside the tank, and to provide a device used in this method.

Abstract: A system and method for treating an aqueous effluent having organic material. The system comprises a single cell reactor having an injector for injecting an oxidizing gas into the reactor. Disposed downstream from the injector is an immersed membrane filtration device for filtering the effluent contained or passing through the reactor. Disposed between the membrane filtration device and the injector for directing an oxidizing gas into the reactor, is a bed of catalyst material. Preferably the oxidizing gas injector injects an oxidizing gas in a direction co-currently the direction of the effluent being treated. The bed of catalyst material is capable of catalyzing the oxidation of the organic material in the effluent or absorbing the organic material.

Abstract: Fenton and Fenton-like system enhancing agent and the usage thereof are provided. It relates to a water treatment enhancer (enhancing agent) and the usage thereof. It widens water pH range of Fenton and Fenton-like system reaction. It reduces amount of Fe2+ required for Fenton reaction. It increases rate of Fenton-like reaction. The enhancing agent is selected from sodium sulfite, lithium sulfite, potassium sulfite, magnesium sulfite, calcium sulfite, hydroxylamine hydrochloride, hydroxylamine perchlorate, hydroxylamine sulfate, hydrazine, N,N-diethylhydroxylamine, amino ethanolamine, hydroxylamine solution or N,N,N?,N?-tetrasubstituted p-phenylenediamine. The method of use of enhancing agent comprises the steps of: adding Fenton or Fenton-like system enhancing agent, an agent for enhancement and hydrogen peroxide into water subject to treatment; and mixing and allowing reaction. The enhancing agent can increase the rate of reaction for the water treatment and reduce the dosage of the agent for enhancement.

Abstract: This invention provides a process for the detoxification of chemical agents including chemical warfare agents such as sulfur mustards, nitrogen mustards, nerve agents of G and V type, lewisite and adamsite by reacting the chemical agents with hydroxyl radicals at a pH greater than 7.0 to detoxify the agents and to render them suitable for disposal. The process can be used on-site and can be easily scaled to fairly large sizes.

Abstract: A method for decontaminating a liquid having sulfides includes preparing a stabilized sodium percarbonate solution. In an embodiment, the method includes decontaminating a liquid. The liquid comprises reactive sulfides. The method also includes preparing a stabilized sodium percarbonate solution, which includes adding sodium percarbonate to a liquid solution. The liquid solution comprises a peroxide stabilizer and an acid. The method further includes dosing the liquid into the stabilized sodium percarbonate solution to decontaminate the liquid by oxidizing at least a portion of the reactive sulfides.

Abstract: The disclosure relates to a method for oxidising one or more organic compounds, including placing the organic compounds in contact with at least one oxidising agent as well as with a catalyst agent including at least one source of divalent or trivalent transition metal ions and at least one poly-?-hydroxyacrylic acid and/or a poly-?-hydroxyacrylate. The disclosure can be used for removing pollutants from soils.

Abstract: A method for cleaning process apparatus used for production of liquids, especially for cleaning filters, for example membrane filters. The apparatus is contacted with a solution of peroxydisulphate. It is especially preferred that the cleaning process is carried out at a temperature between 15 and 95° C.

Abstract: A method for removing undesired substances from liquid water may comprise the steps of: subjecting an oxygen-containing substance to an environment; increasing a temperature within said environment; ionizing said oxygen-containing substance; forming an electrostatically enhanced oxygen species; transferring at least some of said electrostatically enhanced oxygen species to said liquid water; processing said liquid water by action of said electrostatically enhanced oxygen species; creating a charged negatively electrostatically enhanced water species by the presence of said electrostatically enhanced oxygen species in said liquid water; and removing said undesired substances from said liquid water through action of said charged negatively electrostatically enhanced water species in said liquid water, perhaps with the goal of purifying water. Such water may be used in a variety of manners, including but not limited to reuse of the purified water in a closed loop system as a cleaning agent.

Abstract: Disclosed herein too is a method that includes dispersing nanotubes in media that comprises flavin moieties substituted with solubilizing side chains, and/or non-flavin containing molecular species; self-assembling the flavin moieties and other non-flavin containing molecular species in a pattern that is orderly wrapped around the nanotubes to form a composite; introducing desired amounts of an optional reagent that competes with self-assembly in order to disturb the wrapping around nanotubes with moderate order; and centrifuging the mass of the nanotubes and the composites to extract the composite from other nanotubes that are not in composite form.

Abstract: Method for SOx remediation in a manufacturing operation includes providing a process stream including an organic compound and an amount of a sulfur-containing compound, an oxidation stream including at least one chemical oxidant, and combining at least a portion of the oxidant stream with at least a portion of the process stream to obtain an organic stripper feed stream, in which the amount of the sulfur-containing compound is reduced upon reaction with the at least one chemical oxidant. The method can further include directing at least a portion of the organic stripper feed stream to a combustion operation, and emitting a SOx remediated off gas from the combustion operation. A system using the disclosed method also is provided.

Abstract: A process for treating wastewater containing nitro-hydroxy-aromatic compounds using oxidative sub-critical conditions. The wastewater to be treated is adjusted to contain excess hydroxide equivalent to greater than three moles of free hydroxide per mole of total nitro-hydroxy-aromatic compounds, and a sub-stoichiometric amount of an oxidant is supplied to the wastewater. The nitro-hydroxy-aromatic compounds may include nitro-phenol salts or nitro-cresol salts.

Abstract: A method for treating ship ballast water in which aquatic organisms in the ship ballast water are exterminated by adding hydrogen peroxide or a compound producing hydrogen peroxide in an amount such that a hydrogen peroxide concentration comes to be 10 to 500 mg/L to the ship ballast water, and then providing physical means for causing shear strength and/or cavitation to the ship ballast water.

Abstract: A process for oxidizing a chemical contaminant selected from the group consisting of (i) aromatic compounds, (ii) unsaturated compounds having one or more of the following bonds: C?C, C?C, C?O and C?N, and (iii) amines, which process comprises combining the chemical contaminant and cuprous (Cu+) ions in an aqueous solution in a reaction vessel in an essentially oxygen-free environment, and subsequently feeding an oxidizer to said solution.

Abstract: A method of reducing styrene emissions in aqueous cured-in-place pipe closed molding processes and other aqueous environments using a styrene reduction agent. The reduction agent generally comprises a calibrated mixture of salts including sodium chloride plus three persulfate salts: ammonium (APS), potassium (KPS), and sodium (NPS). These ingredients are combined in powder form and are compressed into soluble capsules containing calibrated amounts of the mixture. The capsule(s) may be prescribed through the use of software. Capsule(s) are added to the cure water prior to starting the boiler equipment for the Cured-In-Place Pipe process in order to reduce the residual monomer content in either process or waste streams.

Abstract: Embodiments are provided for removing a variety of contaminants using both rare earth and non-rare earth-containing treatment elements.