Nitrogenous Patents (Class 210/903)
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Patent number: 8486359Abstract: The processes are utilized to recover ammonium from waste water using CO2 acidified absorption water. The process is particularly suited for utilization of cellular matter and a CO2 rich tail gas from a syngas fermentation process and derives significant benefit from the recovery of ammonium bicarbonate and ammonium carbonate. Ammonia and ammonium are recovered from the treatment of the syngas as an ammonium rich solution, at least a portion of which is recycled to the fermentation zone to aid in the production of liquid products. A carbon dioxide rich gas produced by fermentation is used to capture the ammonia and ammonium, forming the ammonium rich solution.Type: GrantFiled: July 25, 2011Date of Patent: July 16, 2013Assignee: Coskata, Inc.Inventor: Robert Hickey
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Patent number: 8465646Abstract: To provide an apparatus for treating a nitrate waste liquid that includes a denitrification tank (12A) which accommodates active sludge that adsorbs or takes in the radioactive substance in a nitrate waste liquid (11) and in which an anaerobic microorganism that reduces the nitric acid to nitrogen gas grows, and a reaeration tank (14) in which a denitrification-treated liquid (24) treated in the denitrification tank (12A) is aerated and mixed with active sludge.Type: GrantFiled: February 6, 2009Date of Patent: June 18, 2013Assignee: Mitsubishi Heavy Industries, Ltd.Inventors: Naoki Ogawa, Katsushi Shibata, Kazuhiko Kuroda, Hiromitsu Nagayasu, Kuniaki Takahashi, Yoshimi Kawato, Yoshihiro Meguro
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Patent number: 8454830Abstract: Waste-treatment processes are enhanced through generation and introduction of specific biological populations customized to perform or favor specific tasks either during the main process, for the formation or precipitation of certain biological nutrients, or to accomplish solids formation reduction in a post-treatment process. These bacteria may be grown from specialized mixes of activated sludge and waste influent by exposing these materials to controlled environments (e.g., in an off-line treatment area). They may then be returned to the main process to perform certain tasks such as converting particulate cBOD into soluble cBOD for utilization, to reduce high solids yield organisms by supplementing the population characteristics with low yield organism characteristics, to provide biological nutrients or oxygenation assistance, to improve nitrification/denitrification efficiency, or to disfavor filamentous biology such as Norcardia sp.Type: GrantFiled: December 8, 2009Date of Patent: June 4, 2013Assignee: Siemens Industry, Inc.Inventor: Daniel R. Miklos
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Patent number: 8409438Abstract: To provide an apparatus for treating a radioactive nitrate waste liquid that includes a denitrification tank (12A) which accommodates active sludge that adsorbs or takes in the radioactive substance in a nitrate waste liquid (11) and in which an anaerobic microorganism that reduces the nitrate to nitrogen gas grows, and a reaeration tank (14) in which a denitrification-treated liquid (24) treated in the denitrification tank (12A) is aerated and mixed with active sludge. A pH adjuster (21), a carbon source (22), and nitrogen gas are supplied to the denitrification tank (12A) so as to separate a denitrified liquid into a solid content and the denitrification-treated liquid (24) by using a first solid-liquid separating film (25), and the denitrification-treated liquid (24) treated with the active sludge in the reaeration tank (14) is reaerated and separated into a solid content and a reaeration-treated liquid (27) by using a second solid-liquid separating film (28).Type: GrantFiled: February 6, 2009Date of Patent: April 2, 2013Assignee: Mitsubishi Heavy Industries, Ltd.Inventors: Naoki Ogawa, Katsushi Shibata, Osamu Kohanawa, Kazuhiko Kuroda, Hiromitsu Nagayasu
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Patent number: 8404210Abstract: An iron composition having a plurality of elemental components is disclosed. The major component is an iron component of at least about 68% to about 92% iron by weight. Other components by weight include manganese; cerium; carbon; phosphorous; sulfur; aluminum; silicon; chromium; copper; and zinc. Combined with layers of sand, brick chips and/or charcoal, the iron composition can be used to create a water filter for filtering inorganic arsenic species and soluble metal ions out of water. To enhance hydrous ferric oxide complexation and precipitation, the iron composition may be treated with food grade acids or a water mixture.Type: GrantFiled: January 29, 2008Date of Patent: March 26, 2013Assignee: George Mason Research Foundation, Inc.Inventor: Abul Hussam
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Patent number: 8398855Abstract: A waste treatment process comprised of an ammonification system to convert soluble organic nitrogen into ammonia nitrogen, followed by a physico-chemical process to remove a substantial amount of the ammonia as a recovered ammonium sulfate fertilizer or ammonium hydroxide (“aqua ammonia”), and followed by an ammonia oxidation process to oxidize the remaining ammonia from the physico-chemical process. The process reduces ammonia and carbonaceous organic matter to less than 10 mg/l and recovers ammonia in the form of either ammonium sulfate or ammonium hydroxide.Type: GrantFiled: September 30, 2010Date of Patent: March 19, 2013Inventors: Philip Bruno Pedros, Mark Mathew Simon, Stephen Howard Brown
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Patent number: 8394272Abstract: This invention relates to a method that uses heterothrophic ammonia oxidation bacteria (HAOB) to remove carbon and nitrogen pollutants in wastewater. The method includes the cultivation of the heterotropic bacteria in an activated sludge environment and the removal of carbon and nitrogen from the wastewater. According to the physiological characteristics of HAOB and the principles of combined oxidation of carbon and nitrogen, the method is able to achieve simultaneous removal of carbon and nitrogen under the condition that the cells do not grow. The process is able to be carried out in the temperature range of 6-40° C. No excess sludge is produced in the process. The invention is able to control the process and product composition of anaerobic ammonia oxidation through the control of organic carbon source, and is able to realize zero-accumulation of NO3?N in the nitrification process. The invention can fully utilize existing activated sludge systems to remove carbon and nitrogen.Type: GrantFiled: August 8, 2007Date of Patent: March 12, 2013Inventor: Guanghao Peng
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Patent number: 8382984Abstract: The invention relates to a method for biologically treating waste water, using a set of micro-organisms having different metabolic spectra, in order to eliminate carbon and nitrogen, even phosphorus. Some of the micro-organisms are fixed to mobile solid carriers (2) and form a fluidised fixed biomass. Some of the micro-organisms are free to be used in an activated mud treatment. To this end, a first non-aerated treatment zone (21a) is followed by a second aerated treatment zone (21b); the treated effluent is subjected to a solid/liquid separation by flotation (6) at a speed higher than 10 m/H; and part of the mud recovered by flotation is recirculated (8) towards the activated mud treatment, said recirculation being controlled (9, 10, 11) so that the MES concentration of the effluent subjected to the liquid/solid separation remains compatible with the retained flotation.Type: GrantFiled: July 25, 2008Date of Patent: February 26, 2013Assignee: DegremontInventor: Laure Graveleau
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Patent number: 8372284Abstract: Disclosed are a wastewater treatment plant and a wastewater treatment method. The wastewater treatment plant includes: a reactor including a gas outlet, a treated water outlet, and an inlet through which wastewater and gas are supplied, through which the wastewater is introduced, to perform aeration and denitrification; a sludge separation means including plural reaction unit bodies stacked inside the reactor to divide the interior of the reactor into upper and lower sides and separating sludge in a aeration process by forming a gas hold-up space for collecting the gas rising from a lower portion of the reactor; and a aeration unit introducing gas into the reactor.Type: GrantFiled: July 17, 2008Date of Patent: February 12, 2013Assignee: Ecodays Co., Ltd.Inventor: Hong Bok Choi
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Patent number: 8361319Abstract: A wastewater treatment system includes wastewater having nitrogen-containing compounds, an anoxic zone having denitrifying bacteria, and an aerobic zone having nitrifying bacteria. The anoxic zone is coupled to the aerobic zone, and wastewater flows from the anoxic to the aerobic zone or vice versa. A fluidized bed heat exchanger configured to accept heat from a heat engine and to transfer the heat from the heat engine to the wastewater is positioned in the aerobic zone or the anoxic zone. The fluidized bed heat exchanger includes particulate media, and fluidization of the particulate media scrubs bacterial growth from portions of the fluidized bed heat exchanger. Treating wastewater can include flowing wastewater having nitrogen-containing compounds into a biological reactor having an anoxic zone and an aerobic zone, and heating the wastewater with heat from a heat engine to facilitate denitrification reactions in the anoxic zone and nitrification reactions in the aerobic zone.Type: GrantFiled: June 6, 2012Date of Patent: January 29, 2013Inventor: Alexander Fassbender
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Patent number: 8303817Abstract: A nitrification carrier having made nitrifying bacteria dominant therein and a denitrification carrier having made anaerobic ammonium-oxidizing bacteria dominant therein are mixed in a treatment tank. Both of a nitrification reaction with the nitrification carrier and a denitrification reaction with denitrification carrier are allowed to proceed in the treatment tank to decompose ammonium nitrogen in wastewater to nitrogen gas. The ratio of the bacterial loads of the nitrifying bacteria and the anaerobic ammonium-oxidizing bacteria can be easily controlled by immobilizing the nitrifying bacteria and the anaerobic ammonium-oxidizing bacteria on different carriers from each other (nitrification carrier and denitrification carrier) and by controlling the volume ratio (ratio of the feeding amounts) of the nitrification carrier and the denitrification carrier.Type: GrantFiled: March 23, 2010Date of Patent: November 6, 2012Assignee: Hitachi Plant Technologies, Ltd.Inventors: Kazuichi Isaka, Yuya Kimura, Tatsuo Sumino
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Patent number: 8303811Abstract: An aquarium filter element having a removable insert. The removable insert may include a chemical agent or biological agent for treating aquarium water.Type: GrantFiled: January 27, 2010Date of Patent: November 6, 2012Assignee: Central Garden and Pet CompanyInventor: Brad L Mihlbauer
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Patent number: 8298422Abstract: A method for the treatment of effluents containing nitrogen in the form of ammonium, in which: a volume of effluent is introduced into the batch reactor in successive volume fractions, each volume fraction being treated during a subcycle, each subcycle including a phase of feeding with a volume fraction and, in an alternating manner, two treatment stages, i.e. an aerated first stage, during which complete or partial oxidation of the ammonium takes place to give nitrites, followed by a nonaerated second stage, during which the nitrites produced and the ammonium are converted to nitrogen gas. During the aerated first stage, the dissolved oxygen concentration in the batch reactor is maintained between 0.1 mgO2/l and 0.6 mgO2/l; the N—NO2:N—NH4 ratio is adjusted to be between 0.9 and 1.5 at the beginning of the nonaerated stage; and the nonaerated phase is carried out by deammonification, without the provision of carbon-based substrate.Type: GrantFiled: October 6, 2008Date of Patent: October 30, 2012Assignee: DegremontInventor: Adriana Gonzalez Ospina
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Patent number: 8293109Abstract: A wastewater treatment method for treating wastewater containing ammonium nitrogen, includes the steps of: charging an unacclimated denitrification carrier containing anaerobic ammonium-oxidizing bacteria into a treatment tank; charging an unacclimated nitrification carrier containing nitrifying bacteria into the treatment tank; acclimating the unacclimated denitrification carrier in the treatment tank under an anaerobic condition; acclimating the unacclimated nitrification carrier in the treatment tank under an aerobic condition, after having acclimated the denitrification carrier; nitriting the ammonium nitrogen in the wastewater to generate nitrite with the acclimated nitrification carrier; and denitrifying the nitrite generated by nitriting the ammonium nitrogen with the acclimated denitrification carrier, while using the ammonium nitrogen in the wastewater as a hydrogen donor.Type: GrantFiled: March 22, 2010Date of Patent: October 23, 2012Assignee: Hitachi Plant Technologies, Ltd.Inventors: Yuya Kimura, Kazuichi Isaka, Tatsuo Sumino
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Patent number: 8287734Abstract: The present invention is directed to a novel process and method for treating nitrogen that is contained in an organic waste stream using aeration at a preferred predetermined mass loading in an aerobic volume followed by treatment in an anoxic/anaerobic volume. The present invention also includes the solid humus material produced from the treatment of an organic waste stream aeration at a predetermined loading in an aerobic volume followed by treatment in an anoxic/anaerobic volume and the removal of said humus solids.Type: GrantFiled: February 25, 2010Date of Patent: October 16, 2012Assignee: Bion Technologies, Inc.Inventors: Jere Northrop, James W. Morris
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Patent number: 8252183Abstract: An exemplary method of treating nitrogen-contaminated wastewaters, especially those with high ammonia concentrations, according to the invention includes the steps of ammonia degassing and recapture, and of nutrient assimilation with microalgae. Organic nitrogen, organic carbon, phosphorus, heavy metals and other compounds may also be removed in different embodiments of the invention. Examples of applicable wastewaters include landfill leachate, municipal solid waste anaerobic digester effluent, agricultural anaerobic digester effluent, municipal wastewaters, agricultural wastewaters, and other similarly contaminated wastewaters.Type: GrantFiled: December 31, 2011Date of Patent: August 28, 2012Assignee: Kent BioEnergy CorporationInventors: Michael J. Massingill, Gregory Schwartz, Christian-Dominik Henrich, Timothy R. Wells, Wayne Sterud, James Carlberg, Jon C. Van Olst
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Patent number: 8246837Abstract: A method for removal of ammonia from a polluted medium avoids the disadvantages related to the chemical-physical properties of an ammonium-containing salt (MAP). The method has improved technical and economical operational parameters and produces a reusable and environmentally friendly nitrogen fertilizer. All chemical processes and mechanical steps of the method are carried out in one single container, with the different steps divided into time phases. The chemical products are prevented from transportation between compartments and contact with pumps and pipes. Only liquids without precipitates are in contact with these elements. The method is applicable to ammonia-containing water from leachate, wastewater, the food industry, and agriculture.Type: GrantFiled: October 17, 2007Date of Patent: August 21, 2012Assignee: Skap Holding ApSInventor: Poul Erik Bundgaard Jensen
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Patent number: 8236174Abstract: Disclosed is a system for treating wastewater. The system includes a microorganism clad structure positioned in a body of wastewater such that the microorganism clad structure is at least partially submerged in the body of wastewater. The apparatus also includes an aeration device, such as a propeller-type, surface mounted aeration device, supplying a horizontal flow of oxygenated water to the microorganisms attached to the microorganism clad structure such that the microorganisms may carry out a biological process.Type: GrantFiled: February 6, 2012Date of Patent: August 7, 2012Assignee: Aeration Industries International LLCInventors: Daniel Durda, G. Shawn Brown, Cory Mortenson
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Patent number: 8226828Abstract: A wastewater treatment system comprising one apparatus (1) for de-nitrification and effluent solids removal, another apparatus (2) for biological main treatment, and a further apparatus (3) for solids removal (5), each apparatus including a volume (40) in which each process is performed, a media-retaining sieve (6) at the volume (40) and arranged to retain buoyant media particles (4) in the volume (40), and a gas sparging device (8), (9) which is located in a lower end region of the volume (40) and which is controllable by way of valves (11) and (15). The three volumes (40) are substantially (10) identical to, or multiples of, each other, the three sieves (6) are substantially identical to each other, and the three sparging devices (8), (9) are substantially identical to each other. The gas is sparged into the main treatment bed at a lower flow rate for wastewater aeration but intermittently at a higher flow rate to disrupt and clean the bed.Type: GrantFiled: October 16, 2006Date of Patent: July 24, 2012Inventors: Alan David Cole Cantwell, Paul Antony Zuber
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Patent number: 8197689Abstract: A wastewater treatment system includes wastewater having nitrogen-containing compounds, an anoxic zone having denitrifying bacteria, and an aerobic zone having nitrifying bacteria. The anoxic zone is coupled to the aerobic zone, and wastewater flows from the anoxic zone to the aerobic zone or vice versa. The wastewater treatment system is configured to accept heat from a heat engine to heat the wastewater. Treating wastewater can include flowing wastewater having nitrogen-containing compounds into a biological reactor having an anoxic zone and an aerobic zone, and heating the wastewater with heat from a heat engine to facilitate denitrification reactions in the anoxic zone and to facilitate nitrification reactions in the aerobic zone. In some cases, the wastewater is heated with a three phase fluidized bed heat exchanger having porous particulates in contact with heat exchange tubes, with bacteria coupled to an interior of the porous particulates.Type: GrantFiled: June 22, 2011Date of Patent: June 12, 2012Inventor: Alexander Fassbender
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Patent number: 8157993Abstract: In a wastewater treatment plant using methane gas, a by-product of anaerobic sludge digestion, to generate energy in a combustor to run the plant, a system for collecting the gas stream from the plant biological process and feeding the gas stream, containing nitrous oxide emissions, into the combustor. The nitrous oxide is thermally reduced down to nitrogen (N2) and oxygen (O2).Type: GrantFiled: January 21, 2010Date of Patent: April 17, 2012Inventor: Philip B. Pedros
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Patent number: 8110108Abstract: Disclosed is a system for treating wastewater. The system includes a microorganism clad structure positioned in a body of wastewater such that the microorganism clad structure is at least partially submerged in the body of wastewater. The apparatus also includes an aeration device, such as a propeller-type, surface mounted aeration device, supplying a horizontal flow of oxygenated water to the microorganisms attached to the microorganism clad structure such that the microorganisms may carry out a biological process.Type: GrantFiled: January 18, 2011Date of Patent: February 7, 2012Assignee: Aeration Industries International LLCInventors: Daniel Durda, G. Shawn Brown, Cory Mortenson
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Patent number: 8110109Abstract: A method of biologically treating water and more particularly, a process for nitrifying and denitrifying water includes employing a continuous aeration mode and a sequential aeration mode. In the continuous aeration mode, nitrification and denitrification reactions occur simultaneously in the water. The continuous aeration mode occurs when the nitrate concentration of the water reaches a predetermined low threshold. The sequential aeration mode occurs when the nitrate concentration reaches a predetermined high threshold. When in the sequential aeration mode, aeration is ceased when the ammoniac concentration reaches a predetermined low threshold and aeration is activated when the ammoniac concentration reaches a predetermined high threshold.Type: GrantFiled: December 7, 2007Date of Patent: February 7, 2012Assignee: OTV SAInventors: Cyrille Lemoine, Patricia Grelier
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Patent number: 8083944Abstract: Described herein is a Submerged Attached Growth Reactor (SAGR) which provides nitrification (ammonia removal) from wastewater in cold to moderate climates. The system described herein is novel in that the SAGR reactor includes more than one influent distribution point. Specifically, in addition to the first influent distribution point at the front end of the reactor, there is provided at least one additional distribution point(s) downstream of this first distribution point for introduction of influent into the reactor. As a result of this arrangement, when a second low carbonaceous biochemical oxygen demand (CBOD), high nitrogen influent is distributed into the reactor at a location downstream of the initial influent entry point, a second (or more) population of bacteria (mainly nitrifying bacteria) is established and/or maintained in a physically discrete part of the overall treatment reactor.Type: GrantFiled: January 19, 2011Date of Patent: December 27, 2011Assignee: Nelson Environmental IncInventors: Martin Hildebrand, Merle Kroeker, Byron Heppner
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Patent number: 8052877Abstract: A process for the removal of azide ions from aqueous liquids at alkaline pH by alkali-soluble metals and catalyst or by hydrogen and catalyst.Type: GrantFiled: December 22, 2009Date of Patent: November 8, 2011Assignee: Sanofi-AventisInventors: Antal Tungler, Gabor Bajnoczy, Erzsebet Odor
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Patent number: 8048303Abstract: A bioretention system and method are provided for removing phosphorus, nitrogen and other materials from effluent such as wastewater and stormwater. The system and method can include a filtration media comprising water treatment residuals and other fill such as soil. Plants can be growing in the soil. The system can also include a drainage system to regulate outflow, to function during both low and high throughputs of water.Type: GrantFiled: July 1, 2010Date of Patent: November 1, 2011Inventor: William Lucas
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Patent number: 8029674Abstract: A process for treatment of water to convert ammonia to nitrate including: feeding water containing dissolved ammonia, as an influent introducing water to be treated, into a packed column containing filter media as packing; introducing air through a diffuser at the bottom of the packed column to maintain the water saturated with oxygen throughout the packed column; establishing colonies of bacteria converting ammonia to nitrate within the column; and removing an ammonia-free and nitrite-fee effluent from the column.Type: GrantFiled: June 1, 2009Date of Patent: October 4, 2011Assignee: The United States of America as represented by the Administrator of the Environmental Protection AgencyInventor: Darren Alan Lytle
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Patent number: 8029673Abstract: The present invention relates to a vertical-horizontal filter unit for the biological purification of polluted water, comprising an upper zone of a soil patch planted with plants, having inlets for the polluted water, and arranged underneath a sand layer with a lower filter zone made of gravel and at least one removal point for the purified water, wherein between the upper and lower filter zones a barrier layer with openings is arranged and the filter unit is sealed against the soil on the sides and at the bottom. The openings in the barrier layer are arranged along the edge and/or the barrier layer does not reach the edge of the patch completely. The invention is characterized in that the upper zone acts as an aerobically cleaning zone and the lower zone as an anaerobically cleaning zone.Type: GrantFiled: November 23, 2007Date of Patent: October 4, 2011Inventor: Joachim Böttcher
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Patent number: 8017019Abstract: Improved fluidized bed precipitators (20, 46, 62, 74, 108, 112, 134, 168) especially useful for the treatment of waste waters containing soluble phosphorus are provided, having upright, primary fluidized bed sections (22, 48, 64, 76, 110, 114, 136) and obliquely oriented solids settling sections (28, 54, 68, 120, 144) which enhance the settling of small particles (166) and return thereof to the fluidized bed sections (22, 48, 64, 76, 110, 114, 136). The precipitators (20, 46, 62, 74, 108, 112, 134, 168) may also be equipped with a solids detection/withdrawal assembly (178) made up of one or more pressure transducers (180, 182) operable to determine the pressures within the fluidized bed sections 22, 48, 64, 76, 110, 114, 136) as a measure of bed densities, along with a selectively operable valve (172) which may be opened to periodically remove solids without clogging.Type: GrantFiled: June 13, 2008Date of Patent: September 13, 2011Assignees: Kansas State University Research Foundation, Kansas Environmental Management Associates, LLCInventors: Gina Young Becker, Sigifredo Castro Diaz, Michael Hanson, Kylo Martin Heller, Dean Thompson
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Patent number: 8012353Abstract: A method for treatment of nitrified wastewater, the method including supplying wastewater to be treated to a tank having a layer of biomass supporting media near or at the top thereof, retaining biomass on and below the biomass supporting media for a sufficient time such that the biomass hydrolyses and supplies organic carbon to the wastewater in the tank; denitrifying and simultaneously clarifying the wastewater by providing an upward flow of the wastewater in the tank through the layer of biomass supporting media and discharging excess sludge from the bottom of the tank at a rate which is selected to maintain nitrate and ammonia concentrations below selected thresholds.Type: GrantFiled: August 9, 2007Date of Patent: September 6, 2011Assignee: Aqwise-Wise Water TechnologiesInventors: Ronen Itzhak Schechter, Nir Assulin
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Patent number: 8002986Abstract: Waste-treatment processes are enhanced through generation and introduction of specific biological populations customized to perform or favor specific tasks either during the main process, for the formation or precipitation of certain biological nutrients, or to accomplish solids formation reduction in a post-treatment process. These bacteria may be grown from specialized mixes of activated sludge and waste influent by exposing these materials to controlled environments (e.g., in an off-line treatment area). They may then be returned to the main process to perform certain tasks such as converting particulate cBOD into soluble cBOD for utilization, to reduce high solids yield organisms by supplementing the population characteristics with low yield organism characteristics, to provide biological nutrients or oxygenation assistance, to improve nitrification/denitrification efficiency, or to disfavor filamentous biology such as Norcardia sp.Type: GrantFiled: August 26, 2005Date of Patent: August 23, 2011Inventor: Daniel Robert Miklos
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Patent number: 7976703Abstract: The present invention provides a treating unit of activated sludge for wastewater treatment and a treating apparatus having the same. The treating unit is constructed by a cage-shaped supporting structure which defines an interior space for containing the microbial cell therein. The present invention provides a measure for simultaneous removal of organics and nitrogen compounds from the wastewater under a condition of controlled aeration, and makes the configuration of treating apparatus as well as the treating process more simplified. It is also an alternative to replace the traditional A2O process. According to the present invention, the design of sludge return, which is essential for the conventional activated sludge treatment, is not needed. Moreover, the present invention is compatible with the conventional activated sludge treatment process and is advantageous in its short start-up period during which a stable operation is achievable.Type: GrantFiled: May 5, 2009Date of Patent: July 12, 2011Inventors: Cheng-Fang Lin, Ping-Yi Yang, Karen Lin
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Patent number: 7972513Abstract: A process for treating nitrogenous wastewater contains an autotrophic denitrification reaction, a heterotrophic denitrification reaction and a COD removal reaction simultaneously and mixedly taking place in a single reactor. The nitrification reaction is caused by nitrifying bacteria, in which ammonium is oxidized into nitrite. The autotrophic denitrification reaction is caused by autotrophic denitrifying bacteria, in which ammonium used as electron donor and nitrite used as electron acceptor are converted into nitrogen gas and nitrate. The heterotrophic denitrification reaction is caused by heterotrophic denitrifying bacteria, in which nitrate and COD are consumed. It is not necessary to build two separate reactors for aerobic nitrification and anaerobic denitrification, thereby effectively reducing the fabrication and operation cost.Type: GrantFiled: October 9, 2009Date of Patent: July 5, 2011Assignees: Leaderman & Associates Co., Ltd., National Chiao Tung UniversityInventors: Der-Ming Lee, Ming-Kuei Chiang, Chin-Te Chen, Keng-Chuan Sung, Jih-Gaw Lin, Chih-Cheng Wang
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Patent number: 7972517Abstract: A method for treating a portion of liquid waste manure comprising adding a first reagent to the portion in a first vessel to cause the formation of waste manure flocs of a first size; adding a second reagent to liquid portion to cause growth of the waste manure flocs of the first size into separable waste manure flocs; adding optionally a third reagent to the portion of liquid containing waste manure flocs to cause further growth of the separable waste manure flocs; separating the liquid volume containing separable waste manure flocs into a waste manure sludge and a first filtrate; and dewatering the waste manure sludge in a filtration system comprising a first filter including a first housing, a first displaceable filter medium, and a first displacement actuator disposed between the first housing and the first displaceable filter medium.Type: GrantFiled: February 22, 2008Date of Patent: July 5, 2011Assignee: Innovative environmental Products, Inc.Inventor: Francis C. Miller
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Patent number: 7972502Abstract: An aeration-less water treatment apparatus including an anaerobic reactor which receives sewage to cause the sewage to flow as an upward stream, and an aerobic reactor which receives treated water from the anaerobic reactor to cause the water to flow as a downward stream so that the water contacts aerobic microorganisms and air to aerobically treat the polluted matter in the water, the apparatus further including a suspended sludge section located in a lower part of the anaerobic reactor and in which the anaerobic microorganisms are suspended in the sewage, and a carrier section located in an upper part of the anaerobic reactor and having carriers to which the anaerobic microorganisms are attached, the anaerobic microorganisms having flowed from the suspended sludge section being further attached to the carriers.Type: GrantFiled: July 2, 2008Date of Patent: July 5, 2011Assignee: Kabushiki Kaisha ToshibaInventors: Masahiko Tsutsumi, Takumi Obara, Nobuyuki Ashikaga, Katsuya Yamamoto, Hiroshi Tamura
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Publication number: 20110100908Abstract: In the treatment of domestic and municipal waste water environmental pollutants, such as ammonia, oxides of nitrogen, organic matter which gives rise to what is known as chemical oxygen demand (COD) [and biological oxygen demand (BOD)], and solid matter, should be removed from the waste water In a typical treatment process the waste water is treated to remove ammonia, firstly by nitrification—the biological oxidation of ammonia (NH3) to nitrite (NOD2?) and then to nitrate (NOD3?)—and, secondly, by de-nitrification—the conversion of the formed nitrite or nitrate to nitrogen gas (N2). Domestic and municipal waste water normally contains bacteria which will perform this treatment.Type: ApplicationFiled: May 20, 2005Publication date: May 5, 2011Inventor: Thomas Stephenson
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Patent number: 7927039Abstract: The invention relates to a method for improving vermiculite's intake of ammonium, in which method heating of the crude vermiculite is conducted to a temperature where vermiculite's third dehydration step takes place, the temperature being lower than the temperature where vermiculite's fourth dehydration/dehydroxylation step takes place. The invention relates also to use of the obtained vermiculite and to an absorption material, comprising vermiculite material and additives, where at least 50% of the vermiculite material comprises vermiculite, which has undergone the third dehydration step but not the fourth dehydration/dehydroxylation step. The invention relates also to use of thermally treated and ammonium doped vermiculite as fertilizer/soil conditioner.Type: GrantFiled: June 30, 2006Date of Patent: April 19, 2011Assignees: Turun Yliopisto, Svenska Osterbottens Forbund for utbildning och kulturInventors: Olav Eklund, Vesa Tokopainen, Alexey Shebanov, Nina Åkerback, Sten Engblom
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Patent number: 7927484Abstract: Methods, systems and compositions for a green sorption media for bioretention soil amendments in drainfields for on-site waste water systems filled with the green sorption media to foster an anaerobic or anoxic environment saturated. The green sorption media includes one or more recycled materials, including tire crumb, sawdust, orange peel, coconut husks, leaf compost, oyster shell, soy bean hulls and one or more naturally occurring materials including peat, sands, zeolites, and clay. The wastewater filtration system for a passive drainfield includes the green sorption material mixture, a cell including baffled compartments and a riser, the cell filled with green sorption material mixture to provide an alternating cycle of aerobic and anoxic environments, an influent distribution system to distribute the influent over the cell, and a piping system arranged for dosing the cell to sustain the functionality of the green sorption material mixture to remove nutrient content in wastewater.Type: GrantFiled: September 11, 2008Date of Patent: April 19, 2011Assignee: University of Central Florida Research Foundation, Inc.Inventors: Martin P. Wanielista, Ni-Bin Chang, Ammarin Makkeasorn
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Patent number: 7914678Abstract: A compact high efficiency combined biological and physical unsaturated wastewater treatment filter configured for periodic backwashing is disclosed. The filter utilizes packed media and removes pollutants and pathogens from wastewater and other dirty water sources. The filter comprises a periodic backwashing means to less the chance that biofilm growth will clog the media pores. However, such backwashing still leaves sufficient biofilm attached to the media to maintain a very high level of treatment. In the preferred embodiment, the filter utilizes high frequency dosing to cause pore saturation at or near the surface during dosing and shortly thereafter in order to maximize distribution uniformity and to induce downward airflow into the media. The system provides a number of unexpected benefits; including allowing a very low distribution pressure and providing high oxygen transfer at low energy utilization into the filter media for aerobic biodegradation of pollutants.Type: GrantFiled: February 27, 2009Date of Patent: March 29, 2011Inventor: Robert A. Beggs
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Patent number: 7909995Abstract: An economical, integrated system works in series with anaerobic digestion of animal waste to recover nitrogen and phosphorous, while also scrubbing the produced biogas.Type: GrantFiled: June 3, 2008Date of Patent: March 22, 2011Assignee: Washington State University Research FoundationInventors: Anping Jiang, Tianxi Zhang, Craig Frear, Shulin Chen
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Patent number: 7910001Abstract: The present invention relates to a novel arrangement of denitrification reactors for removal of nitrate compounds in a recirculating aquaculture system. The novel arrangement of an aquaculture system of the present invention includes positioning one or more anaerobic denitrification reactors upstream of aerobic nitrification and degassing processes. One aspect of the present invention includes a flow of aqueous medium from aquatic species rearing tanks towards one or more denitrification reactors. Another aspect of the present invention includes flow of aqueous medium from aquatic species rearing tanks to a solids removing filter or mechanical filtration means for removal of solid waste matter or biomass prior to flow of aqueous medium towards one or more denitrification reactors.Type: GrantFiled: December 12, 2008Date of Patent: March 22, 2011Assignee: Mote Marine LaboratoryInventors: James T. Michaels, II, Heather J. Hamlin, William H. Dutt, William Graham, Peter Steinbach, Brian Babbitt, Brian A. Richards, II
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Patent number: 7892433Abstract: Disclosed is a system for treating wastewater. The system includes a microorganism clad structure positioned in a body of wastewater such that the microorganism clad structure is at least partially submerged in the body of wastewater. The apparatus also includes an aeration device, such as a propeller-type, surface mounted aeration device, supplying a horizontal flow of oxygenated water to the microorganisms attached to the microorganism clad structure such that the microorganisms may carry out a biological process.Type: GrantFiled: March 15, 2010Date of Patent: February 22, 2011Assignee: Aeration Industries International, Inc.Inventors: Daniel Durda, G. Shawn Brown, Cory Mortenson
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Patent number: 7879236Abstract: A lagoon of effluent is established, comprising a set of sub-portions at different levels in the lagoon associated with a corresponding set of concentrations of dissolved oxygen, each sub-portion of the lagoon having a different concentration of dissolved oxygen. An incubator comprising a set of sub-portions associated with said set of concentrations of dissolved oxygen is established, each sub-portion of the incubator having a different concentration of dissolved oxygen. A volume of effluent from each sub-portion of the lagoon is transmitted to a corresponding sub-portion of an incubator having a substantially similar concentration of dissolved oxygen as said sub-portion of the lagoon. A first remediated volume of effluent is generated in said corresponding sub-portion of the incubator responsive to proliferating a first microorganism which uses a first compound in said volume of effluent as substrate for growth, the first microorganism enabling a first chemical reaction which alters the first compound.Type: GrantFiled: October 9, 2008Date of Patent: February 1, 2011Assignee: Verdure Technologies, Inc.Inventor: Mark Terry
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Patent number: 7854842Abstract: Waste-treatment processes are enhanced through generation and introduction of specific biological populations customized to perform or favor specific tasks either during the main process, for the formation or precipitation of certain biological nutrients, or to accomplish solids formation reduction in a post-treatment process. These bacteria may be grown from specialized mixes of activated sludge and waste influent by exposing these materials to controlled environments (e.g., in an off-line treatment area). They may then be returned to the main process to perform certain tasks such as converting particulate cBOD into soluble cBOD for utilization, to reduce high solids yield organisms by supplementing the population characteristics with low yield organism characteristics, to provide biological nutrients or oxygenation assistance, to improve nitrification/denitrification efficiency, or to disfavor filamentous biology such as Norcardia sp.Type: GrantFiled: August 29, 2005Date of Patent: December 21, 2010Inventor: Daniel Robert Miklos
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Patent number: 7850851Abstract: A process for treating waste water to remove phosphorous and nitrogen in a treatment system including an anaerobic zone (5) containing an anaerobic mixed liquor having organisms which release phosphorous into the anaerobic mixed liquor; an anoxic zone (7) containing an anoxic mixed liquor having organisms which uptake phosphorous and denitrify the anoxic mixed liquor and an aerobic zone (9) containing an aerobic mixed liquor having organisms which uptake phosphorous and nitrify the aerobic mixed liquor; the process including the steps of providing wastewater to be treated into the anaerobic zone (5) and communicating anaerobic mixed liquor from the anaerobic zone (5) to the anoxic zone (7). The anoxic mixed liquor is then communicated from the anoxic zone (7) to the anaerobic zone (5) and the anoxic mixed liquor from the anoxic zone (7) to the amble zone (9).Type: GrantFiled: August 14, 2006Date of Patent: December 14, 2010Assignee: Siemens Water Technologies Corp.Inventors: Fufang Zha, Edward John Jordan
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Patent number: 7842186Abstract: The present invention provides a method of treating wastewater containing phosphorus and/or nitrogen for removing phosphorus and/or nitrogen from the wastewater, including following steps of: (a) introducing wastewater containing phosphorus and/or nitrogen into a an anaerobic reactor, treating the introduced wastewater with anaerobic microorganisms, to produce biogas from organic matters in the wastewater, and then discharging the treated wastewater saturated with carbon dioxide under carbon dioxide partial pressure of 0.2 to 0.5 atm; and (b) injecting the treated wastewater of step (a) into a carbon dioxide stripping apparatus wherein the wastewater is free-fallen to expose the wastewater to ambient condition with carbon dioxide partial pressure of less than 0.001 atm so that carbon dioxide stripping takes place and increase in pH occurs without addition of alkaline substance, and then providing proper pH of 8.4 to 9.6 to form struvite.Type: GrantFiled: March 7, 2008Date of Patent: November 30, 2010Assignee: Entechs Co.Inventors: In Chung, Chi-Don Sung
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Patent number: 7811455Abstract: A method for the removal and sequestration of ammonia nitrogen from anaerobic fermentation effluent while producing a higher BTU biogas. The method includes the steps of removing the slurry from the digester, stripping the ammonia from the slurry or portion thereof with a high BTU biogas, blending the stripped ammonia with the digesters biogas to remove the carbon dioxide and precipitate ammonium bicarbonate/carbonate as a solid while producing a high Btu biogas, a portion of which is used to strip the ammonia and CO2 from the slurry. The process removes ammonia nitrogen from the digester effluent while producing a high Btu biogas and a solid ammonium bicarbonate/carbonate product. Ammonia stripping is accomplished with a recycled stripping gas deficient in CO2 and ammonia that is capable of removing the CO2 and ammonia from solution by virtue of the lower partial pressures of CO2 and ammonia in the stripping unit.Type: GrantFiled: June 5, 2008Date of Patent: October 12, 2010Inventor: Dennis A. Burke
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Patent number: 7776217Abstract: A bioretention system and method are provided for removing phosphorus, nitrogen and other materials from effluent such as wastewater and stormwater. The system and method can include a filtration media comprising water treatment residuals and other fill such as soil. Plants can be growing in the soil. The system can also include a drainage system to regulate outflow, to function during both low and high throughputs of water.Type: GrantFiled: April 16, 2009Date of Patent: August 17, 2010Inventor: William Lucas
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Patent number: 7749384Abstract: An apparatus is provided that includes: a containment system 208 having at least one sidewall and bottom that are substantially impermeable to a passage of water; a distribution system 124 to introduce an aqueous stream comprising nitrates into the containment system; a de-nitrification system 128 comprising a de-nitrification media, the media being contained within the containment system; a pump to pressurize the stream and cause the stream to pass through the de-nitrification media, thereby converting at least most of the nitrates into nitrogen gas and forming a treated stream; and a collection system 132 to remove the treated stream from the containment system.Type: GrantFiled: May 22, 2008Date of Patent: July 6, 2010Inventors: David W. Patton, Gerald Lee Lamb, Jamie Lee Miller
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Patent number: 7736513Abstract: Biological nutrient removal (BNR) in wastewater treatment to remove carbonaceous substrates, nutrients and phosphorus, has recently become increasingly popular worldwide due to increasingly stringent regulations. Biological fluidized bed (BFB) technology, which could be potentially used for BNR processes, can provide some advantages such as high efficiency and compact structure. This present invention incorporates the fixed-film biological fluidized bed technology with the biological nutrient removal in a twin liquid-solid fluidized bed, which has achieved the simultaneous elimination of organic carbon, nitrogen and phosphorus, in a very efficient manner and with very compact space requirements. The BNR-LSFB has two fluidized beds, running as anoxic/anaerobic and aerobic processes to accomplish simultaneous nitrification and denitrification and to remove carbonaceous substrates, nutrients and phosphorus, with continuous liquid and solids recirculation through the anoxic/anaerobic bed and the aerobic bed.Type: GrantFiled: August 28, 2007Date of Patent: June 15, 2010Assignee: The University of Western OntarioInventors: Jingxu Zhu, George Nakhla, Yubo Cui