Deoxidant Or Free-metal Containing Patents (Class 252/178)
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Patent number: 12042777Abstract: A deodorant composition may be suitable for use with an aldehyde gas or a ketone gas, and may include an aminoguanidine salt and a metal chelating agent. The aminoguanidine salt is preferably at least one of an aminoguanidine hydrochloride and an aminoguanidine sulfate. The chelating agent is preferably at least one of an inorganic phosphoric acid and salt thereof, and a carboxylic acid and salt thereof.Type: GrantFiled: November 19, 2019Date of Patent: July 23, 2024Assignee: TOAGOSEI CO., LTD.Inventors: Atsushi Takanohashi, Yuki Uesugi, Yoshinao Yamada
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Patent number: 11673814Abstract: Systems, devices, and techniques described herein relate to iron-based desalination of water. In some cases, an inflow of water including chlorine and sodium can be received. A plurality of iron nanoparticles may capture the chlorine and the sodium. The iron nanoparticles may at least partially include Zero Valent Iron (ZVI). An outflow of the water may be emitted. The chlorine and the sodium may be omitted from the outflow.Type: GrantFiled: February 12, 2021Date of Patent: June 13, 2023Assignee: Badwater Alchemy Holdings LLCInventor: William J. Walker
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Patent number: 10266424Abstract: The present invention pertains to a process for treating waste water from mining. The process involves contacting the mining waste water with an emulsion of a nano scale compound comprising iron, magnesium, or both. Mixing results in a substantially foam-like layer at the surface of the mixture which may be further oxidized to form treated water.Type: GrantFiled: April 18, 2017Date of Patent: April 23, 2019Assignee: Terra-Hydrochem, Inc.Inventor: Roger Kubala
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Patent number: 9221701Abstract: Disclosed are methods of operating steam generators, particularly evaporators, in hard water environments characterized by high Si and Mg content in which the pHcold of the feed water stream is maintained within a range of about 11 to 12 in order to reduce, eliminate or remove scale from internal evaporator surfaces. Additional components may be added to the feed water stream including surfactants, chelants, dispersants, sequestrants and mixtures thereof.Type: GrantFiled: November 21, 2011Date of Patent: December 29, 2015Assignee: CHEMTREAT, INC.Inventors: John Richardson, Rob Bedinger, James Wilkins
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Publication number: 20150129472Abstract: Cellulose acetate or polyvinylpyrrolidone is electrospun into fibers having diameters of nanometer scale to form a first mat that is capable of absorbing hydrocarbons. A second mat may be formed from a solution of cellulose acetate or polyvinylpyrrolidone further containing tungsten trioxide. The solution is electrospun onto a copper mesh and then thermally oxidized to create a nanostructure comprising a grid or network of tungsten trioxide crystals and copper oxide crystals. The nanogrid is capable of photocatalyzing the degradation of hydrocarbons to carbon dioxide and water. The grid may be combined with the first mat to degrade hydrocarbons that the first mat absorbs.Type: ApplicationFiled: June 27, 2012Publication date: May 14, 2015Inventors: Pelagia-Irene Gouma, Jusang Lee
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Publication number: 20150068980Abstract: The nanocomposite for removing selenium from water is multi-walled carbon nanotubes impregnated with iron. The nanocomposite is made by dissolving iron nitrate in ethanol, adding the carbon nanotubes, heating the mixture to evaporate the ethanol, and calcining the resulting nanocomposite. The carbon nanotubes preferably have a length and a diameter between 10 nm and 30 nm, and the iron is homogenously distributed in the nanotubes as nanoparticles of 1-2 nm diameter. The nanocomposite adsorbs selenium from aqueous solution. The pH of the aqueous solution may be adjusted to between 1 and 4, adsorption being most efficient at a pH of 1.Type: ApplicationFiled: September 12, 2013Publication date: March 12, 2015Applicant: KING FAHD UNIVERSITY OF PETROLEUM AND MINERALSInventors: OMER YAHYA BAKATHER, MUATAZ ALI ATIEH
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Patent number: 8894878Abstract: The present invention provides a nanopolymetallic reducing agent filler comprising 20%-70% iron powder, 10%-30% tourmaline power, 2%-15% copper power, 3%-10% bamboo charcoal powder, 2%-15% kaoline, 2%-15% magnesite powder, 2%-15% pyrolusite powder, and 10%-30% zeolite powder. All percentages described above are by weight. A process of forming the nanopolymetallic reducing agent filler is also provided, including grinding and ball milling raw materials of each component respectively into powder particles of 10 nm-100 ?m, which are then mixed uniformly by weight percentage and granulated to form a granular mixture, and sintering the granular mixture at high temperature or cold pressing it into a granular filler.Type: GrantFiled: September 7, 2011Date of Patent: November 25, 2014Assignee: T&H USA Group, Inc.Inventors: Liang Shuhong, Wang Meiling
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Publication number: 20140305870Abstract: Described herein is a liquid filtration device is disclosed comprising a fluid conduit fluidly connecting a fluid inlet to a fluid outlet; and a water filtration medium disposed in the fluid conduit; the water filter medium comprising a metal-containing particulate, wherein the metal-containing particulate comprises a thermolysis product of a metal salt wherein the salt is selected from nitrogen-containing oxyanions, sulfur-containing anions, chlorides, phosphates, and combinations thereof; and methods of removing chloramines from aqueous solutions.Type: ApplicationFiled: December 13, 2012Publication date: October 16, 2014Inventors: Mark R. Stouffer, Meredith McMurdo Doyle, Allen R. Siedle, Thomas E. Wood
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Publication number: 20140305882Abstract: Described herein is a liquid filtration device is disclosed comprising a fluid conduit fluidly connecting a fluid inlet to a fluid outlet; and a water filtration medium disposed in the fluid conduit; the water filter medium comprising a metal-containing particulate, wherein the metal-containing particulate comprises a thermolysis product of a metal carboxylate; and methods of removing chloramines from aqueous solutions.Type: ApplicationFiled: December 13, 2012Publication date: October 16, 2014Applicant: 3M INNOVATIVE PROPERTIES COMPANYInventors: Meredith McMurdo Doyle, Mark R. Stouffer, Thomas E. Wood
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Patent number: 8784679Abstract: Embodiments of a method of producing an aqueous powder composition for treating water comprise mixing sodium metabisulfite powder with amines, wherein the amines comprises liquid cyclohexylamine, and adding water to the mixture of sodium metabisulfite powder and liquid cyclohexylamine to catalyze the production of the aqueous powder composition.Type: GrantFiled: October 25, 2011Date of Patent: July 22, 2014Assignee: Dubois Chemicals, Inc.Inventors: Richard M. Moore, Lyle H. Steimel
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Publication number: 20140038266Abstract: The invention relates to a method of preparing an oil absorbent composition. The method comprises heating and then de-mineralising a precursor plant material under conditions suitable to produce an oil absorbent composition comprising charcoal. The invention extends to oil absorbent compositions per se, such as charcoal-based compositions, and to various uses of the compositions for efficiently and rapidly absorbing spilled oil, for example from water surfaces, or from bituminous sands.Type: ApplicationFiled: October 3, 2013Publication date: February 6, 2014Applicant: The Forestry CommissionInventors: Franciscus Antonius Anna Maria De Leij, James Stratford, Tony Hutchings
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Publication number: 20130320255Abstract: Amphiphilic copolymers formed from plant oil-derived vinyl ether monomers and polyethylene glycol alkyl vinyl ethers are provided. Nanoparticles coated with these amphiphilic polymers are well-suited for water remediation applications.Type: ApplicationFiled: May 17, 2013Publication date: December 5, 2013Applicant: NDSU Research FoundationInventors: Bret Ja Chisholm, AChintya Bezbaruah, Harjyoti Kalita
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Publication number: 20130240439Abstract: A nanocomposite is disclosed comprising reduced graphene oxide (RGO) and at least one of a metal and an oxide of the metal. Also disclosed is an adsorbent comprising the nanocomposite and an adsorbent comprising the nanocomposite bound to silica by using chitosan. A filtering device comprising the nanocomposite and/or the adsorbent is also disclosed. Also disclosed are methods for producing the nanocomposites, adsorbents, and filtering devices described herein.Type: ApplicationFiled: September 2, 2011Publication date: September 19, 2013Applicant: INDIAN INSTITUTE OF TECHNOLOGYInventors: Thalappil Pradeep, Shihabudheen Mundampra Maliyekkal, Sreeprasad Theruvakkattil Sreenivasan
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Publication number: 20130233802Abstract: Metal nanocomposites and methods of producing the same are disclosed. The nanocomposites have metal nanoparticles dispersed in a matrix carrier and can be produced by: treating a matrix material having a functional group with a quaternary amine compound to form a function site; treating the matrix material with a metal salt such that a metal ion of the metal salt is chelated with the functional site; treating the matrix material with an alkali; and microwaving the matrix material to form the metal nanocomposites.Type: ApplicationFiled: March 15, 2013Publication date: September 12, 2013Applicant: BOARD OF TRUSTEES OF THE UNIVERSITY OF ARKANSASInventor: Tito Viswanathan
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Publication number: 20130099158Abstract: Embodiments of a method of producing an aqueous powder composition for treating water comprise mixing sodium metabisulfite powder with amines, wherein the amines comprises liquid cyclohexylamine, and adding water to the mixture of sodium metabisulfite powder and liquid cyclohexylamine to catalyze the production of the aqueous powder composition.Type: ApplicationFiled: October 25, 2011Publication date: April 25, 2013Applicant: DUBOIS CHEMICALS, INC.Inventors: Richard Moore, Lyle H. Steimel
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Publication number: 20120285899Abstract: The present invention provides a nanopolymetallic reducing agent filler comprising 20%-70% iron powder, 10%-30% tourmaline power, 2%-15% copper power, 3%-10% bamboo charcoal powder, 2%-15% kaoline, 2%-15% magnesite powder, 2%-15% pyrolusite powder, and 10%-30% zeolite powder. All percentages described above are by weight. A process of forming the nanopolymetallic reducing agent filler is also provided, including grinding and ball milling raw materials of each component respectively into powder particles of 10 nm-100 ?m, which are then mixed uniformly by weight percentage and granulated to form a granular mixture, and sintering the granular mixture at high temperature or cold pressing it into a granular filler.Type: ApplicationFiled: September 7, 2011Publication date: November 15, 2012Inventors: Liang Shuhong, Wang Meiling
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Publication number: 20120273427Abstract: Provided herein are compositions and methods for removing a variety of pollutants from wastewater. Such compositions are obtained by immobilizing barium-based hybrid materials, such as BaSO4:APRB. Such compositions are easy to separate from the treated wastewater. After separation, the compositions, which include the pollutants, may be conveniently further separated from the pollutants and thus recovered for use again.Type: ApplicationFiled: January 20, 2011Publication date: November 1, 2012Inventors: Hongwen Gao, Yulin Shen, Shan Liu
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Publication number: 20120273431Abstract: The present inventors have discovered a novel composition, method of making the composition, system, process for treating a fluid containing a contaminant. The fluid may be aqueous. The contaminated fluid may be in the form of a suspension. The treatment reduces the concentration of the contaminant. The reduction in concentration of a contaminant may be sufficient so as to effect remediation of the fluid with respect to the contaminant. The treatment may reduce the concentration of a plurality of contaminants. The present composition, system, and process are robust and flexible. The composition includes zero valent iron, an iron oxide mineral, and ferrous iron. The ferrous iron promotes maintenance of the iron oxide mineral. The iron oxide mineral promotes the activity of the zero valent iron. The process and system may involve multiple stages. A stage may be optimized for treatment with respect to a particular contaminant.Type: ApplicationFiled: September 20, 2010Publication date: November 1, 2012Applicant: THE TEXAS A&M UNIVERSITY SYSTEMInventor: Yongheng Huang
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Publication number: 20120160775Abstract: A porous and permeable composite for treatment of contaminated fluids, said composite including a body of iron particles and 0.01-10% by weight of at least one functional ingredient distributed and locked in the pores and cavities of the iron body. Also, methods of making a permeable porous composite for water treatment. Also, use of a permeable porous composite for reducing the content of contaminants in a fluid, wherein said fluid is allowed to pass through the permeable composite.Type: ApplicationFiled: August 4, 2010Publication date: June 28, 2012Applicant: HOGANAS ABInventor: Bo Hu
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Publication number: 20120111802Abstract: An activated carbon cloth-supported bimetallic Pd—Cu nanocatalyst is disclosed comprising about 1 wt % Pd and about 0.35-0.45 wt % Cu and having a surface Cu/Pd metal ratio of about 8-10 m2/m2. The nanocatalyst is capable of removing nitrate and/or nitrite from wastewater with a high selectivity to nitrogen.Type: ApplicationFiled: May 4, 2010Publication date: May 10, 2012Applicant: TECHNION RESEARCH AND DEVELOPMENT FOUNDATION LTD.Inventors: Moshe Sheintuch, Uri Matatov-Meytal
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Publication number: 20120055873Abstract: The present invention relates to methods of making and using and compositions of metal nanoparticles formed by green chemistry synthetic techniques. For example, the present invention relates to metal nanoparticles formed with solutions of plant extracts and use of these metal nanoparticles in removing contaminants from soil and groundwater and other contaminated sites. In some embodiments, the invention comprises methods of making and using compositions of metal nanoparticles formed using green chemistry techniques.Type: ApplicationFiled: November 8, 2011Publication date: March 8, 2012Applicants: The U.S.A as represented by the Administrator of the U.S. Environmental Protection Agency, VeruTEK, Inc.Inventors: George E. Hoag, John B. Collins, Rajendar S. Varma, Mallikarjuna N. Nadagouda
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Publication number: 20120024799Abstract: Nanostructured manganese-containing compositions having reduced manganese dissolution and methods of making and using the same are provided. In one embodiment, a composition of matter comprises a nanostructured oxide or hydroxide doped with Mn4+. The composition of matter can be made by forming a nanostructured oxide or hydroxide material doped with Mn3+ and oxidizing the Mn3+ to Mn4+ to reduce dissolution of the manganese in the nanostructured oxide or hydroxide material. In another embodiment, a method of reducing dissolution of manganese present in a nanostructured MnO2 material comprises: doping a nanostructured MnO2 material with Fe3+ to reduce the dissolution of the manganese.Type: ApplicationFiled: April 30, 2008Publication date: February 2, 2012Applicant: Inframat CorporationInventors: Huimin Chen, Lei Jin
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Patent number: 8097559Abstract: The present invention provides a supported reactant for in situ remediation of soil and/or groundwater contaminated with a halogenated hydrocarbon consisting essentially of an adsorbent impregnated with zero valent iron, wherein the adsorbent is capable of adsorbing the halogenated hydrocarbon. In one embodiment, the adsorbent is activated carbon.Type: GrantFiled: August 11, 2004Date of Patent: January 17, 2012Assignee: Remediation Products, Inc.Inventors: Scott Noland, Bob Elliott
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Publication number: 20110001083Abstract: Scale inhibition compositions and methods for use are disclose, where the composition including one or a plurality chelating agents, one or a plurality dispersing agents, one or a plurality of oxygen scavenging agents including one sugar alcohol or a plurality of sugar alcohols, and pH adjusted to a pH greater than about 9.Type: ApplicationFiled: July 2, 2009Publication date: January 6, 2011Applicant: Clearwater International, LLCInventors: Olusegun Matthew Falana, Ali Shah
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Publication number: 20100096334Abstract: One aspect of the present invention includes a swellable sol-gel composition including a plurality of interconnected organosilica nanoparticles. Another aspect of the present invention includes a swellable composite including a plurality of interconnected organosilica nanoparticles and a particulate material capable of binding to or reacting with a non-polar or organic sorbate. When dried, the sol-gel composition and the swellable composite may be capable of swelling to at least twice their dried volume when placed in contact with a non-polar or organic sorbate.Type: ApplicationFiled: September 15, 2009Publication date: April 22, 2010Inventor: Paul L. Edmiston
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Patent number: 7482384Abstract: Iron composite particles for purifying soil or ground water, comprise ?-Fe and magnetite, and having a ratio of a diffraction intensity D110 of (110) plane of ?-Fe to a sum of a diffraction intensity D311 of (311) plane of magnetite and the diffraction intensity D110 (D110/(D311+D110)) of 0.30 to 0.95 as measured from X-ray diffraction spectrum of the iron composite particles, an Al content of 0.10 to 1.50% by weight and an S content of 3500 to 7000 ppm; a process for producing the iron composite particles; a purifying agent containing the iron composite particles; a process for producing the purifying agent; and a method for purifying soil or ground water.Type: GrantFiled: June 8, 2004Date of Patent: January 27, 2009Assignee: Toda Kogyo CorporationInventors: Masayuki Uegami, Junichi Kawano, Koji Kakuya, Tomoko Okita, Kenji Okinaka
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Publication number: 20080257834Abstract: The present invention relates to a harmful material remediating agent comprising a metal oxide and a reducing material, and it can remediate environmental. pollutants such as harmful organic compounds and nitrate or nitrite nitrogen-containing compounds efficiently and at low cost.Type: ApplicationFiled: May 28, 2008Publication date: October 23, 2008Inventors: Ken-Ichi Sasaki, Kaoru Sakurai
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Patent number: 7351355Abstract: A purifying agent for purifying soil or ground water which comprises a water suspension containing iron composite particles comprising ?-Fe and magnetite, and having an average particle diameter of 0.05 to 0.50 ?m, an S content of 3500 to 10000 ppm and an Al content of 0.10 to 1.50% by weight, and polyaspartic acid or a salt thereof. The purifying agent is capable of decomposing aliphatic organohalogen compounds or aromatic organohalogen compounds contained in the soil or ground water in an efficient, continuous and economical manner.Type: GrantFiled: November 29, 2004Date of Patent: April 1, 2008Assignee: Toda Kogyo CorporationInventors: Koji Kakuya, Masayuki Uegami, Junichi Kawano, Tomoko Okita, Kenji Okinaka, Andreas D. Jazdanian
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Publication number: 20080067468Abstract: Describes a composition comprising a mixture of (1) a major amount of calcium hypochlorite, e.g., hydrated calcium hypochlorite, and (2) a minor amount of calcium hypochlorite-compatible hydrophobic additive (other than discrete particulate Group IIA or IIIA metal stearates) in amounts sufficient to provide the composition with reduced hydrophilic properties. The composition has a solution rate in water at standard conditions that is less than the calcium hypochlorite used to prepare the composition, but sufficient for the intended application. Describes also calcium hypochlorite compositions in which the hydrophobic additive is an organo-silicon material, or a metal oxide, e.g., amorphous precipitated silica, treated with a hydrophobizing agent, such as an organo-silicon material, e.g., an organo-silane and/or organo-siloxane material.Type: ApplicationFiled: August 30, 2007Publication date: March 20, 2008Applicant: PPG INDUSTRIES OHIO, INC.Inventors: STANLEY R. PICKENS, TIMOTHY A. OKEL, ERIK A. SCHOENMAN, SHANTILAL M. MOHNOT, PATRICK RYAN
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Patent number: 7037946Abstract: A zero-valent metal emulsion is used to dehalogenate solvents, such as pooled dense non-aqueous phase liquids (DNAPLs), including trichloroethylene (TCE). The zero-valent metal emulsion contains zero-valent metal particles, a surfactant, oil and water. The preferred zero-valent metal particles are nanoscale and microscale zero-valent iron particles.Type: GrantFiled: October 31, 2003Date of Patent: May 2, 2006Assignee: The United States of America as represented by the Administrator of the National Aeronautics and Space AdministrationInventors: Debra R. Reinhart, Christian Clausen, Cherie L. Geiger, Jacqueline Quinn, Kathleen Brooks
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Patent number: 6926878Abstract: Arsenic and TOC are removed from drinking water or wastewaters by use of finely-divided metallic iron in the presence of powered elemental sulfur or other sulfur compounds such as manganese sulfide, followed by an oxidation step. A premix may be produced for this process, by adding the iron, sulfur and oxidizing agent to water in a predetermined pH range. The iron and sulfur are mixed for a period of time dependent upon the temperature and pH of the water and the presence of complexing or sequestering minerals and organic acids in the water. An oxidizing agent is added to the mixture and agitating is continued. In a preferred embodiment the oxidizing agent is hydrogen peroxide. Water is decanted from the mixture after a sufficient reaction time, to produce a concentrated premix. This premix can be added to water intended for drinking or to industrial effluents containing toxic materials.Type: GrantFiled: May 21, 2003Date of Patent: August 9, 2005Inventor: Peter F. Santina
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Patent number: 6669853Abstract: This invention relates to compositions, which are useful in removing dissolved oxygen from a fluid stream, preferably an aqueous stream. The compositions comprise blend of an oxime and a primary hydroxylamine. This invention also relates to a process for removing oxygen from an aqueous system, which comprises adding an oxime and a primary hydroxylamine to a fluid system.Type: GrantFiled: August 9, 2001Date of Patent: December 30, 2003Assignee: Ashland Inc.Inventors: Kostan B. Charkhutian, Bruce L. Libutti, Frank L. M. De Cordt, Martti Samuli Ahomäki
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Patent number: 6664298Abstract: A zero-valent metal emulsion is used to dehalogenate solvents, such as pooled dense non-aqueous phase liquids (DNAPLs), including trichloroethylene (TCE). The zero-valent metal emulsion contains zero-valent metal particles, a surfactant, oil and water.Type: GrantFiled: October 2, 2001Date of Patent: December 16, 2003Assignee: The United States of America as represented by the Administrator of the National Aeronautics & Space AdministrationInventors: Debra R. Reinhart, Christian Clausen, Cherie L. Geiger, Jacqueline Quinn, Kathleen Brooks
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Patent number: 6540923Abstract: An oxygen scavenger, containing a heterocyclic compound having a N-substituted amino group as an effective component, can adequately exhibit the oxygen scavenging effect in not only feed water lines for high temperature water, a boiler, and steam and condensate return lines, but also feed water lines for low temperature water. The oxygen scavenger contains: a heterocyclic compound having a N-substituted amino group or a salt thereof; a hydroxybenzene derivative and/or a naphthoquinone derivative; and neutral amine.Type: GrantFiled: December 5, 2000Date of Patent: April 1, 2003Assignee: Kurita Water Industries Ltd.Inventors: Masakazu Koizumi, Yukimasa Shimura, Shiro Taya, Takatoshi Sato
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Publication number: 20020100896Abstract: An oxygen scavenger, containing a heterocyclic compound having a N-substituted amino group as an effective component, can adequately exhibit the oxygen scavenging effect in not only feed water lines for high temperature water, a boiler, and steam and condensate return lines, but also feed water lines for low temperature water. The oxygen scavenger contains: a heterocyclic compound having a N-substituted amino group or a salt thereof; a hydroxybenzene derivative and/or a naphthoquinone derivative; and neutral amine.Type: ApplicationFiled: December 5, 2000Publication date: August 1, 2002Applicant: KURITA WATER INDUSTRIES LTD.Inventors: Masakazu Koizumi, Yukimasa Shimura, Shiro Taya, Takatoshi Sato
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Patent number: 6402984Abstract: The invention effectively prevents occurrence of corrosion in water tubes or the like of boilers. The invention provides a method for operating a boiler, including regulating a concentration of sulfate ions SO42− in boiler water to under 500 ppm, and a method for injecting a sulfite base oxygen scavenger, including setting a concentration of residual dissolved oxygen in boiler feed water to 2-4 ppm. The invention further provides a sulfite base oxygen scavenger composition comprising: 3-30 weight % of at least one selected from a group consisting of Na2SO3, K2SO3, NaHSO3 and KHSO3; 1-20 weight % of NaOH or KOH; 0.2-2 weight % of potassium sorbate; and 5-500 ppm of CoSO4.Type: GrantFiled: September 16, 1999Date of Patent: June 11, 2002Assignee: Miura Co., Ltd.Inventors: Junichi Nakajima, Masazumi Yamashita, Kenichi Kimura
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Patent number: 6391256Abstract: A dissolved oxygen removal method using an activated carbon fiber catalyst thereof which includes the steps of a reducing agent injection step for injecting a reducing agent into the water, a reactor entrance dissolved oxygen measuring step for measuring a concentration of a dissolved oxygen contained in a water, a water flow rate control step for controlling the supplied amount of the water, an activated carbon fiber catalyst reaction step for removing a dissolved oxygen contained in the water with the reaction between the reducing agent and the dissolved oxygen in an activated carbon fiber reactor in which an activated carbon fiber catalyst is packed, and a control step for controlling the feeding rate of the reducing agent in accordance with the water flow rate and the reactor entrance dissolved oxygen, for thereby extending the life time of the facility and decreasing the operational and maintenance costs by fully removing a dissolved oxygen in water used for an steam generator or cooling system.Type: GrantFiled: October 15, 1998Date of Patent: May 21, 2002Assignee: Korea Electric Power CorporationInventors: Jeon Soo Moon, Kwang Kyu Park, Gon Seo, Hae Ran Song
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Patent number: 6350410Abstract: The present invention provides a method and composition for inhibiting biological fouling in an irrigation system. According to the invention, an effective amount of active zinc is added to irrigation water passing through an irrigation system to inhibit biological fouling. In a preferred form of the invention, the active zinc is chelated with 1-hydroxyethane 1,1-diphosphonic acid (HEDPA). In addition to inhibiting the formation of biological fouling in the system, the active zinc provides nourishment to plants irrigated by the irrigation system.Type: GrantFiled: April 13, 1995Date of Patent: February 26, 2002Assignee: CH20 IncorporatedInventors: Carl E. Iverson, Joyce Prindle
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Publication number: 20010050350Abstract: A semiconductor wafer cleaning formulation, including 1-21% wt. fluoride source, 20-55% wt. organic amine(s), 0.5-40% wt. nitrogenous component, e.g., a nitrogen-containing carboxylic acid or an imine, 23-50% wt. water, and 0-21% wt. metal chelating agent(s). The formulations are useful to remove residue from wafers following a resist plasma ashing step, such as inorganic residue from semiconductor wafers containing delicate copper interconnecting structures.Type: ApplicationFiled: March 27, 2001Publication date: December 13, 2001Applicant: Advanced Technology Materials Inc.Inventors: William A. Wojtczak, Ma. Fatima Seijo, David Bernhard, Long Nguyen
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Patent number: 6221262Abstract: Method for reducing the number of viable organisms present in ship ballast water wherein the ballast water is treated so as to reduce the concentration of dissolved oxygen and/or carbon dioxide to a level(s) at which a substantial portion of the organisms present cease to remain viable. The treatment comprises adding to the ballast water a suitable amount of an antioxidant.Type: GrantFiled: November 18, 1998Date of Patent: April 24, 2001Inventors: Robert W. G. MacDonald, Robert Bull, Douglas F Porter, Peter Lansell
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Patent number: 6136219Abstract: The composition for clarifying a body of water comprises at least an anionic polyacrylamide, aluminum chloral hydrate or aluminum oxide and citric acid combined in amounts sufficient to produce a clarification of a body of water. If necessary, calcium carbonate or calcium sulfate may be included in the composition to neutralize pH in acidic environments for increased effectivity.Type: GrantFiled: July 1, 1999Date of Patent: October 24, 2000Inventor: Stephen W. Decker
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Patent number: 6080332Abstract: The invention comprises a novel process for producing an anti-scaler coating for monomer polymerization reactors comprising mixing hydroxymethansulphincal acid with 1-naphthol. The invention also comprises an anti-scaling product obtained by this novel process.Type: GrantFiled: March 6, 1998Date of Patent: June 27, 2000Assignee: C.I.R.S. S.p.A.Inventor: Mario Sattin
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Patent number: 6056875Abstract: A filtering material for filtering hot water in a shower utilizes ceramic-type calcium sulfite beads, made from a ceramic binder and calcium sulfite, and a copper-zinc media, with the ceramic-type calcium sulfite beads and the copper-zinc media being present in substantially equal volumetric portions.Type: GrantFiled: February 8, 1999Date of Patent: May 2, 2000Inventor: David K. Farley
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Patent number: 5965094Abstract: According to the invention, there are provided a novel process for preparing an anti-scaling coating on the walls of a polymerization vessel by using aromatic compounds reacted with sodium hydroxymethanesulphinate, and an anti-scaling coating obtained by this novel process.Type: GrantFiled: March 12, 1998Date of Patent: October 12, 1999Assignee: C.I.R.S. S.p.A.Inventor: Mario Sattin
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Patent number: 5866014Abstract: Arsenic and TOC are removed from drinking water or wastewaters by use of finely-divided metallic iron in the presence of powdered elemental sulfur or other sulfur compounds such as manganese sulfide, followed by an oxidation step. A premix may be produced for this process, by adding the iron, sulfur and oxidizing agent to water in a predetermined pH range. The iron and sulfur are mixed for a period of time dependent upon the temperature and pH of the water and the presence of complexing or sequestering minerals and organic acids in the water. An oxidizing agent is added to the mixture and agitating is continued. In a preferred embodiment the oxidizing agent is hydrogen peroxide. Water is decanted from the mixture after a sufficient reaction time, to produce a concentrated premix. This premix can be added to water intended for drinking or to industrial effluents containing toxic materials.Type: GrantFiled: November 4, 1996Date of Patent: February 2, 1999Inventor: Peter F. Santina
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Patent number: 5597510Abstract: Coagulant compositions, advantageously solvent (water) solution thereof, well suited for the treatment/purification of impure aqueous media, e.g., surface waters, wastewaters, effluents, etc., via sedimentation technique, comprise (i) at least one basic aluminum polychloride or polychlorosulfate, (ii) at least one iron(II) and/or iron(III) compound, and (iii) at least one alkali metal and/or alkaline earth metal halide.Type: GrantFiled: May 24, 1994Date of Patent: January 28, 1997Assignee: Kemrhone FranceInventors: Sylvain Danda, Magnus Kvant, Yvette Pescher
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Patent number: 5512200Abstract: Low pH acidic compositions for uses related generally to chemical, pharmaceutical and cosmetic agents and more particularly, but not limited to, used as bactericides, fungicides, germicides and virucides; all having pH values of less than about 2.0 in their final form. These low pH acidic compositions generally comprise two phases in solution. Phase I comprises from about 2 to about 98 weight percent of varying percentages of several chemical, pharmaceutical and cosmetic substances.Phase II comprises from about 2 to about 99 weight percent of an active aqueous acidic component having a pH value of less than about 1.Type: GrantFiled: April 18, 1994Date of Patent: April 30, 1996Assignee: Thomas G. BongardInventor: Silverio M. Garcia
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Patent number: 5397499Abstract: The present invention relates to a material for the purification of fluids. More particularly, the present invention relates to a material for flocculating and separating organic substances or surface active agents contained in waste water.Type: GrantFiled: July 7, 1993Date of Patent: March 14, 1995Inventor: Sanai Fujita
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Patent number: 5147604Abstract: A method is disclosed for reducing the oxygen content of water using a hydrazine-free dioxo aromatic compound or organically-substituted derivative thereof.Type: GrantFiled: September 6, 1988Date of Patent: September 15, 1992Assignee: Betz Laboratories, Inc.Inventors: Stanley J. Ciuba, John A. Muccitelli
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Patent number: 5082599Abstract: 2-Methyl- and 2-hydroxymethyl-serine-N,N-diacetic acid and derivatives thereof of the general formula I ##STR1## in which X denotes hydrogen, alkali metal or ammonium which may or may not be substituted by C.sub.1 -C.sub.4 -hydroxyalkyl groups and Z denotes hydrogen or hydroxyl.The compounds I serve as complexing agents for heavy metal ions or alkaline earth metal ions and as bleach stabilizers or builders in detergents and cleaning formulations.Type: GrantFiled: March 16, 1990Date of Patent: January 21, 1992Assignee: BASF AktiengesellschaftInventors: Alfred Oftring, Stefan Birnbach, Richard Baur, Charalampos Gousetis, Wolfgang Trieselt