Deoxidant Or Free-metal Containing Patents (Class 252/178)
  • Patent number: 4929364
    Abstract: An aqueous concentrate useful for treating boiler waters to scavenge oxygen therefrom which contains at least 0.3% by weight of either gallic acid or propyl gallate. This aqueous concentrate has a pH adjusted to at least 8.5 by a water-soluble neutralizing amine of the type used to treat boiler waters. Additionally, a method for treating boiler waters with an oxygen scavenger.
    Type: Grant
    Filed: November 4, 1988
    Date of Patent: May 29, 1990
    Assignee: Nalco Chemical Company
    Inventors: Patricia A. Reardon, David A. Grattan
  • Patent number: 4895703
    Abstract: A method for inhibiting corrosion due to dissolved oxygen wherein trihydroxybenzene compounds, alone or in combination with conventional oxygen scavengers, preferably hydroquinone, are added to boiler water to prevent corrosion by reducing dissolved oxygen levels in boiler feedwater.
    Type: Grant
    Filed: August 15, 1988
    Date of Patent: January 23, 1990
    Assignee: Calgon Corporation
    Inventors: John D. Zupanovich, Lois J. Neil, Dennis J. Sepelak
  • Patent number: 4891141
    Abstract: An oxygen scavenger for boiler water includes ascorbic acid neutralized with diethylaminoethanol. The diethylaminoethanol provides condensate treatment for the long and short steam lines and improves the scavenging of the ascorbic acid.
    Type: Grant
    Filed: December 11, 1987
    Date of Patent: January 2, 1990
    Assignee: DuBois Chemicals, Inc.
    Inventors: Ronald J. Christensen, Lyle H. Steimel
  • Patent number: 4874541
    Abstract: An all in one boiler water treatment composition includes an oxygen scavenging system, an alkalinity control agent such as sodium carbonate, diethylaminoethanol as a condensate treatment, a polymer system including polymethacrylate or polyacrylate and polymaleic acid along with an oxygen scavenging system. The oxygen scavenging system includes the diethylaminoethanol, a polyhydroxy acid and a sulfite.
    Type: Grant
    Filed: June 10, 1988
    Date of Patent: October 17, 1989
    Assignee: DuBois Chemicals, Inc.
    Inventors: Lyle H. Steimel, Ronald J. Christensen
  • Patent number: 4851130
    Abstract: When an aqueous system containing dissolved oxygen and erythorbate or ascorbate is passed through an activated carbon bed, the oxygen is removed at ambient temperatures. This method of oxygen removal finds practical application in the removal of oxygen from boiler condensate, low temperature boiler feedwater and oil well injection water or brine.
    Type: Grant
    Filed: November 30, 1988
    Date of Patent: July 25, 1989
    Assignee: Pfizer Inc.
    Inventor: Ralph D. May
  • Patent number: 4830766
    Abstract: The deposition of metal-containing scale, such as iron silicate scale, from a hot aqueous geothermal brine, or the like, is controlled by blending into the brine sufficient reducing agent effective for reducing trivalent iron and manganese cations in a high temperature brine solution to divalent ions to cause an overall decrease in scale deposition, especially of iron silicate scale. Preferably, from 2 to 7 times the stoichiometric amount of reducing agent is used to effect a 70 to 90 percent reduction in the formation of iron silicate scale.
    Type: Grant
    Filed: October 15, 1986
    Date of Patent: May 16, 1989
    Assignee: Union Oil Company of California
    Inventors: Darrell L. Gallup, John W. Jost
  • Patent number: 4765921
    Abstract: Acid compositions with high concentrations of active ingredients intended for the treatment of industrial or domestic waters and for cleaning the corresponding industrial or sanitary installations, comprising carboxylic polymer materials, a strong acid, possibly a salt of a divalent metal and possibly known specific agents, which comprise:(a) from 10 to 60% by weight expressed in anhydrous form of a water-soluble carboxylic polymer in its acid form containing at least 5% by weight and preferably at least 10% by weight of itaconic acid,(b) from 10 to 80% by weight expressed in anhydrous form of at least one strong acid,(c) from 0 to 15% by weight expressed in anhydrous form of zinc in the form of Zn.sup.2+ ions,(d) from 0.1 to 10% by weight expressed in anhydrous form of specific agents,(e) from 5 to 65% by weight of water.
    Type: Grant
    Filed: June 22, 1987
    Date of Patent: August 23, 1988
    Assignee: Coatex S.A.
    Inventors: Jacky Rousset, Jean Moro
  • Patent number: 4731124
    Abstract: A method of applying a descaling reagent comprising a one-electron reducing agent which is a low oxidation state transition metal ion in combination with a complexing agent to a surface to be treated to descale the surface which method comprises:(i) maintaining a low oxidation state transition metal ion either in solution under an inert atmosphere in a container made of or lined with an inert material or as a solid salt under an inert atmosphere;(ii) preparing a solution of the complexing agent and removing oxygen therefrom; and(iii) mixing the ingredients from steps (i) and (ii) either in situ in contact with the surface to be treated, or mixing the ingredients from steps (i) and (ii) prior to application to the surface to be treated under conditions whereby no substantial decomposition of the so-formed reagent occurs.
    Type: Grant
    Filed: August 31, 1984
    Date of Patent: March 15, 1988
    Assignee: Central Electricity Generating Board
    Inventors: David Bradbury, Timothy Swan, Michael G. Segal
  • Patent number: 4681697
    Abstract: A process for producing a solid, cold-water soluble, sulfate containing aluminum chloride composition suitable for use as a waste water clarifying agent comprising introducing alkali aluminate, sulfuric acid, hydrochloric acid and hydrated aluminum oxide into a spray drier and recovering the resulting solid product.
    Type: Grant
    Filed: April 22, 1986
    Date of Patent: July 21, 1987
    Assignee: Kali-Chemie Aktiengesellschaft
    Inventors: Werner Doetsch, Rudolf Siegel
  • Patent number: 4681737
    Abstract: A method of inhibiting corrosion due to dissolved oxygen is disclosed, whereby chelant-stabilized sodium erythorbate, alone or in combination with conventional corrosion inhibitors, is added to boiler water to prevent corrosion by reducing dissolved oxygen levels in boiler feedwater.
    Type: Grant
    Filed: September 17, 1985
    Date of Patent: July 21, 1987
    Assignee: Calgon Corporation
    Inventors: Jerry L. Walker, John D. Zupanovich
  • Patent number: 4626411
    Abstract: A composition containing a hydroxylamine compound; a quinone, a dihydroxybenzene, a diaminobenzene, or an aminohydroxybenzene compound; and a neutralizing amine is an excellent oxygen scavenger and corrosion inhibitor in boiler water and other aqueous systems.
    Type: Grant
    Filed: April 17, 1985
    Date of Patent: December 2, 1986
    Assignee: Dearborn Chemical Company, Limited
    Inventors: John J. Nemes, Harvey W. Thompson, John E. Waller
  • Patent number: 4549968
    Abstract: Stable oxygen scavenger compositions adapted for storage without resulting in substantial sludge formation and oxygen scavenging methods of using the compositions are disclosed. The compositions comprise hydroquinone, a compatible amine termed a mu-amine, and a member selected from the group consisting of isoascorbic acid and ascorbic acid and water soluble salt forms thereof. Methods comprise adding from about 0.05-200 ppm hydroquinone, 0.001-400 ppm mu-amine, and about 0.00025-500 ppm of isoascorbic or ascorbic acid to the desired aqueous medium.
    Type: Grant
    Filed: May 18, 1984
    Date of Patent: October 29, 1985
    Assignee: Betz Laboratories, Inc.
    Inventor: John A. Muccitelli
  • Patent number: 4487708
    Abstract: An improved oxygen scavenger for aqueous mediums is disclosed which comprises hydrazine-free solution of hydroquinone and mu-amine.
    Type: Grant
    Filed: March 12, 1981
    Date of Patent: December 11, 1984
    Assignee: Betz Laboratories, Inc.
    Inventor: John A. Muccitelli
  • Patent number: 4479917
    Abstract: An oxygen-scavenging and corrosion-inhibiting agent for fluidic systems comprising an aminoguanidine compound selected from the formula: ##STR1## or a salt thereof, wherein R is selected from H or a lower alkyl group having 1 to 4 carbon atoms; wherein X is selected from NH or NNH.sub.2 ; and Y is selected from --NH.sub.2 or --NHNH.sub.2.
    Type: Grant
    Filed: November 14, 1983
    Date of Patent: October 30, 1984
    Assignee: Olin Corporation
    Inventors: Eugene F. Rothgery, Steven A. Manke
  • Patent number: 4477364
    Abstract: An acidic glass cleaning composition for removal of residue, deposits and impurities from glassware is provided, the improved acidic glass cleaning composition comprising from about 1 to about 15 weight percent hydrofluoric acid and from about 85 to about 99 weight percent of an aqueous acidic composition having a pH value of less than about 1.
    Type: Grant
    Filed: November 7, 1983
    Date of Patent: October 16, 1984
    Assignee: Capetrol International, Inc.
    Inventor: Silverio M. Garcia
  • Patent number: 4477285
    Abstract: A composition for use in treating surfaces susceptible of oxidation is disclosed herein which comprises the combination of a particulate abrasive material and a particulate, ascorbic-type reducing compound. A variety of percentages of the abrasive and reducing compounds may be employed, and the consistency of the abrasive material may be varied in accordance with the application for which the composition is intended. Also disclosed herein is a kit which includes a container of the described composition. A method for treating an oxidizable surface by use of a composition as described is also disclosed herein.
    Type: Grant
    Filed: August 31, 1981
    Date of Patent: October 16, 1984
    Inventor: Frederick K. Ault
  • Patent number: 4439339
    Abstract: An aqueous acidizer composition and method of utilizing same in the removal of scale from fresh water production equipment such as desalinators or evaporators (watermakers) and distillation units as well as heat exchangers and boilers. The composition contains a blend of three acids of varying strengths carefully selected to provide a timed release effect. The acids which are employed include hydrochloric acid, dichloroacetic acid and acetic acid. The composition further contains a surfactant such as isopropyl alcohol which provides surfactant properties and also reacts with the acids, resulting in multiple equilibria in which the corresponding esters are formed. The composition also includes an acid-base indicator such as methyl orange to signify neutralization of the acidizer during use in scale removal. The present composition is particularly effective in removal of phosphate and carbonate scale as well as some sulfate scale. Other deposits containing basic anions are also removed.
    Type: Grant
    Filed: February 8, 1983
    Date of Patent: March 27, 1984
    Inventor: Carl J. Doumit
  • Patent number: 4435303
    Abstract: The present invention is directed to a composition which includes an anionic fatty alcohol metal sulfate surfactant, a nonionic substituted poly (ethylene oxide) surfactant, an ethanolamine, zinc and hydroxyacetic acid. A method for removing scale from a surface is taught.
    Type: Grant
    Filed: January 3, 1983
    Date of Patent: March 6, 1984
    Inventor: Khodabandeh Abadi
  • Patent number: 4311599
    Abstract: An improved method for scavenging dissolved oxygen from alkaline waters which comprises treating said waters with at least 10 ppm of methylene blue in its reduced or leuco base form.
    Type: Grant
    Filed: November 12, 1980
    Date of Patent: January 19, 1982
    Assignee: Nalco Chemical Company
    Inventor: Manuel Slovinsky
  • Patent number: 4289645
    Abstract: An improved oxygen scavenger for aqueous mediums is disclosed which comprises hydrazine-free solution of hydroquinone and mu-amine. Representative examples of mu-amines include: aminomethylpropanol, triethylenetetramine, diisopropanolamine, secbutylamine, monoisopropanolamine, ethylenediamine, dimethylaminopropylamine, monoethanolamine, dimethyl(iso)propanolamine, methoxypropylamine, and diethylaminoethanol.
    Type: Grant
    Filed: July 14, 1980
    Date of Patent: September 15, 1981
    Assignee: Betz Laboratories, Inc.
    Inventor: John A. Muccitelli
  • Patent number: 4282111
    Abstract: A method is disclosed for reducing the oxygen content of water using a hydrazine-free aqueous solution of hydroquinone.
    Type: Grant
    Filed: April 28, 1980
    Date of Patent: August 4, 1981
    Assignee: Betz Laboratories, Inc.
    Inventor: Stanley J. Ciuba
  • Patent number: 4279767
    Abstract: An improved oxygen scavenger for aqueous mediums is disclosed which comprises hydrazine-free solution of hydroquinone and mu-amine.
    Type: Grant
    Filed: July 14, 1980
    Date of Patent: July 21, 1981
    Assignee: Betz Laboratories, Inc.
    Inventor: John A. Muccitelli
  • Patent number: 4278635
    Abstract: A method for boiler water treatment to retard corrosion due to dissolved oxygen. Hydroquinone and certain related compounds are highly effective oxygen scavengers for use in boiler water and thereby effect reduction of corrosion resulting from dissolved oxygen.
    Type: Grant
    Filed: December 26, 1979
    Date of Patent: July 14, 1981
    Assignee: Chemed Corporation
    Inventor: Herman Kerst
  • Patent number: 4207201
    Abstract: The application is concerned with a process for the manufacture of an aqueous iron (III)-chloride-sulfate solution by the oxidation of iron (II) sulfate with chlorine in aqueous solution.
    Type: Grant
    Filed: March 8, 1978
    Date of Patent: June 10, 1980
    Assignee: Kronos Titan GmbH
    Inventors: Achim Hartmann, Achim Kulling, Dieter Schinkitz, Edgar Klein
  • Patent number: 4082683
    Abstract: An improved dithionite composition suitable for preparing stock solutions comprising a dithionite, e.g., sodium dithionite, and at least 5% by weight of a water-soluble sulphite, e.g., sodium sulphite. The composition may further contain a metal-complexing agent, an activator for the dithionite, a surface-active agent and a thickening agent. The composition is applicable for the removal of metal dust soiling and metal oxide stains, particularly rust stains, from surfaces.
    Type: Grant
    Filed: September 10, 1976
    Date of Patent: April 4, 1978
    Assignee: Lever Brothers Company
    Inventor: Wilhelmus Gerardus Galesloot
  • Patent number: 4019859
    Abstract: A method of stabilizing aqueous solutions containing alkali metal sulfite or bisulfite and a catalyst therefor by incorporating in said solutions a stabilizing amount of triethylene tetramine. The catalyzed sulfites which are of primary concern in the present instance are those which are used to inhibit or control oxygen corrosion in water treatment, particularly boiler water treatment.
    Type: Grant
    Filed: September 20, 1976
    Date of Patent: April 26, 1977
    Assignee: Betz Laboratories, Inc.
    Inventors: Walter M. Lavin, James I. McFarlane, Dennis L. Rose
  • Patent number: 3983048
    Abstract: The rapid removal of dissolved oxygen from aqueous solutions is accomplished by the use of a composition comprised of a mixture of an aqueous solution of hydrazine and a catalytic proportion of an aryl amine compound. The compositions of this invention are particularly useful in the removal of dissolved oxygen from aqueous solutions such as boiler water, thereby inhibiting corrosion of the metal surfaces of the boiler.
    Type: Grant
    Filed: December 10, 1973
    Date of Patent: September 28, 1976
    Assignee: Olin Corporation
    Inventors: Henry W. Schiessl, John D. Kaufman, David A. Csejka
  • Patent number: 3974039
    Abstract: A process of reclaiming drinking and industrial water from sea water, accing to which the sea water to be processed is subjected to a pretreatment, comprising filtering, acidifying and degassing said sea water. To the thus treated sea water there is then added in suspension finely divided barium sulphate to provide nuclei for the crystal growth of calcium sulphate on the barium sulphate. The thus obtained suspension is then in a continuous process heated and partly evaporated, during which process, temperatures of supersaturation, with respect to calcium sulphate are reached, the water which is evaporated being collected as condensate and distillate.
    Type: Grant
    Filed: November 4, 1974
    Date of Patent: August 10, 1976
    Assignee: Gesellschaft fur Kernenergieverwertung in Schiffbau und Schiffahrt mbH
    Inventors: Klaus Frohner, Hossein Panahandeh
  • Patent number: 3957673
    Abstract: A scale inhibitor composition comprising Cr.sub.2 O.sub.3, reducing agent, refractory or clay, SiO.sub.2 and water glass, and a method of inhibiting the formation of scale on the surfaces of metal substrates to be heated in high temperature atmosphere by application of a coating of the scale inhibitor composition either on the metal surface, or on a subbing layer of a parting agent previously applied on the metal surfaces are disclosed, wherein improvements are effected particularly in both yield and prevention of surface scars.
    Type: Grant
    Filed: July 16, 1973
    Date of Patent: May 18, 1976
    Assignee: Nippon Steel Corporation
    Inventors: Akimi Umezono, Minoru Kitayama, Susumu Yamaguchi, Hisao Odashima
  • Patent number: 3931038
    Abstract: A corrosion and scale inhibiting composition and process useful in recirculating cooling water systems consisting essentially of the following components calculated as weight percent:Alkoxylated polyol phosphate ester 30 to 50% ZnCl.sub.
    Type: Grant
    Filed: July 31, 1973
    Date of Patent: January 6, 1976
    Assignee: Nalco Chemical Company
    Inventors: Francesca Mochi-Bartolani, Mauro Minervini, Aurelio Mannini