Reactant Contains Ethylenic Group Patents (Class 252/182.18)
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Patent number: 11874563Abstract: The present invention relates to novel photoaligning polymer materials, to their use as orienting layer for liquid crystals, which are used for the production of non-structured and structured optical elements, electro-optical elements, multi-layer systems or in nanoelectronics.Type: GrantFiled: August 8, 2018Date of Patent: January 16, 2024Assignee: ROLIC TECHNOLOGIES AGInventors: Cedric Klein, Fabien Xavier Delbaere, Richard Frantz
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Patent number: 10894869Abstract: A polyisocyanurate foam insulation product includes polyisocyanurate foam produced from reacting an isocyanate and a polyol blend having a functionality of at least 2.2. The isocyanate and the polyol blend are reacted so that the polyisocyanurate foam has an isocyanate index equivalent with or greater than 300. The polyisocyanurate foam includes a fire retardant and includes between 0.02 and 0.45 weight percent of a zinc salt compound. The foam insulation board exhibits a flame spread of no greater than 25 and a smoke index of no greater than 50 when exposed to flame conditions in accordance with an ASTM E-84 test.Type: GrantFiled: November 25, 2019Date of Patent: January 19, 2021Assignee: Johns ManvilleInventors: Malay Nandi, Lance Wang, Jawed Asrar
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Patent number: 10597483Abstract: In a process for the production of pore-free polyurethane elastomer moldings with Shore D hardness of at least 60 in accordance with DIN 53505, (a) polyesterdiol with OH number from 20 to 100 mg KOH/g and (b) a chain extender composed of diol with molar mass below 300 g/mol, is mixed with (c) isocyanate prepolymers obtainable via reaction of diisocyanate with polyesterols with functionality from 1.95 to 2.2 and with OH number from 20 to 200 mg KOH/g to form a reaction mixture. The reaction mixture is charged to a mold and hardened to form the polyurethane elastomer. Polyurethane elastomer moldings are thus obtainable by this process, and these polyurethane moldings may be used as cladding component for commercial vehicles, bodywork component in vehicle construction, or a cladding component of a machine installation.Type: GrantFiled: May 22, 2015Date of Patent: March 24, 2020Assignee: BASF SEInventors: Julio Albuerne, Rolf Illguth, Franz Xaver Redl, Bernd Bremert, Hermann Voelker
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Patent number: 10563033Abstract: A polyisocyanurate foam insulation product includes polyisocyanurate foam produced from reacting an isocyanate and a polyol blend having a functionality of at least 2.2. The isocyanate and the polyol blend are reacted so that the polyisocyanurate foam has an isocyanate index equivalent with or greater than 300. The polyisocyanurate foam includes a fire retardant and includes between 0.02 and 0.45 weight percent of a zinc salt compound. The foam insulation board exhibits a flame spread of no greater than 25 and a smoke index of no greater than 50 when exposed to flame conditions in accordance with an ASTM E-84 test.Type: GrantFiled: September 28, 2017Date of Patent: February 18, 2020Assignee: Johns ManvilleInventors: Malay Nandi, Lance Wang, Jawed Asrar
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Patent number: 10544253Abstract: A curable composition for making polyisocyanurate comprising products obtained by combining and mixing at an isocyanate index of at least 100 at least a polyisocyanate composition, an isocyanate reactive composition comprising at least 50 mol % diols and a toughening agent comprising acrylic block copolymers.Type: GrantFiled: July 9, 2015Date of Patent: January 28, 2020Assignee: HUNTSMAN INTERNATIONAL LLCInventor: Steve Andre Woutters
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Patent number: 10047195Abstract: The present invention relates to the use of monomers bearing associative groups in order to manufacture a supramolecular polycondensate, to certain of these monomers, to a process for manufacturing a supramolecular polycondensate, to the polycondensate obtained, and also to an article or a composition incorporating same. The associative groups may be, for example, imidazolidone, urea or triazole groups.Type: GrantFiled: March 28, 2013Date of Patent: August 14, 2018Assignee: Arkema FranceInventors: Jean-Philippe Gillet, Jean-Pierre Disson, Bruno Van Hemelryck
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Patent number: 10035915Abstract: Disclosed herein is a composition comprising 65 to 95 weight percent of a fluorinated monofunctional monomer; 5 to 35 weight percent of a fluorinated multifunctional monomer; and 0.5 to 3 weight percent of a silane coupling agent; where all weight percents are based on the total weight of the composition; where the fluorinated monofunctional monomer and the fluorinated multifunctional monomer are devoid of any trifunctional fluorocarbon moieties when they have 6 or more fluorocarbon repeat units; where the fluorocarbon repeat units are CF2 or CF moieties; and where a crosslinked composition has a shore D hardness of 56 to 85 and has a refractive index (RI) that meets the limitation of the equation RI?1.368+10.8/X, where X denotes wavelength in nanometers.Type: GrantFiled: October 15, 2014Date of Patent: July 31, 2018Assignee: OFS FITEL, LLCInventors: Xiaoguang Sun, Debra A Simoff, Andrei A Stolov, Adam Hokansson, Natalia Reyngold
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Patent number: 9988485Abstract: The present invention provides a process for preparing radiation-curing allophanates having residual monomer contents of less than 0.5% by weight and an NCO content of less than 1% by weight, wherein (A) compounds containing isocyanate groups, (B) hydroxy-functional compounds which contain groups which react, with polymerization, with ethylenically unsaturated compounds on exposure to actinic radiation (radiation-curing groups) and (C) optionally further compounds containing NCO-reactive groups, also optionally in the presence of a catalyst, are used to form NCO-group-containing urethanes having radiation-curing groups, which are subsequently reacted, without further addition of compounds containing isocyanate groups, in the presence of an allophanatization catalyst, the ratio of NCO groups of the compounds from A) to the OH groups of the compounds from B) and, where used, C) being 1.45:1.0 to 1.1:1.0.Type: GrantFiled: December 23, 2015Date of Patent: June 5, 2018Assignee: ALLNEX NETHERLANDS B.V.Inventors: Michael Ludewig, Jan Weikard
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Patent number: 9783632Abstract: A urethane (meth)acrylate not comprising caprolactone is the product of reaction of A) a monoalcohol bearing from 1 to 5 (meth)acrylates, B) an allophanate-modified polyisocyanate, C) optionally, in the presence of a saturated polyol of functionality 2 to 3, D) optionally, in the presence of an unsaturated polyol with a hydroxyl functionality of 2 to 4, said polyol being C3 to C18, E) optionally, in the presence of a reactive diluent. A process for preparing the urethane (meth)acrylate includes reacting the monoalcohol A) and the polyisocyanate B) in the optional presence of C), D), and/or E). The urethane (meth)acrylate may be used in curable compositions for coatings, in particular for varnishes and inks, adhesives, adhesion primers, coatings for wood, metal or plastic and application by spray gun and provide a good compromise between reactivity, flexibility, adherence, hardness, and ease of use.Type: GrantFiled: October 13, 2014Date of Patent: October 10, 2017Assignee: Arkema FranceInventors: Charles Bourrousse, Philippe Ciceron
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Patent number: 9266797Abstract: Disclosed herein are systems and methods for monitoring and controlling a nitroxide-based polymerization inhibitor in vinyl-based monomers. A dosage of the nitroxide-based polymerization inhibitor is provided in the vinyl-based monomers. A residual concentration of the nitroxide-based polymerization inhibitor is measured substantially in real time, and an optimized dosage of the nitroxide-based polymerization inhibitor is provided in response to the measured residual concentration.Type: GrantFiled: February 12, 2013Date of Patent: February 23, 2016Assignee: Ecolab USA Inc.Inventors: Ramon Colorado, Jr., Vincent Lewis, Robert A. Geiger, Jessica Hancock, Andrew R. Neilson
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Patent number: 8980970Abstract: The invention relates to a process for preparing binders which contain 1) allophanate groups, 2) groups that react with ethylenically unsaturated compounds with polymerization on exposure to actinic radiation (radiation-curing groups) and 3) optionally NCO-reactive groups, by reacting at temperatures ?130° C. A) one or more NCO-functional compounds containing uretdione groups with B) one or more compounds that contain isocyanate-reactive groups and groups that react with ethylenically unsaturated compounds with polymerization on exposure to actinic radiation (radiation-curing groups), and then C) with one or more saturated, hydroxyl-containing compounds other than B), at least one of these compounds having an OH functionality of ?2, in the presence of D) a catalyst containing one or more zinc compounds, the reaction with compounds C) taking place at least proportionally with the formation of allophanate groups. The present invention also relates to the binders obtained by the process of the invention.Type: GrantFiled: September 1, 2005Date of Patent: March 17, 2015Assignee: ALLNEX IP S.a.r.L.Inventors: Jan Weikard, Dorota Greszta-Franz, Wolfgang Fischer, Jörg Schmitz, Holger Mundstock, Christophe Detrembleur
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Publication number: 20150060727Abstract: The invention provides a method for synthesizing 7-Acetyleno quinone methide compounds that is safe and inexpensive. The method avoids the need for extremely cold reaction temperatures and unlike the prior art does not require any highly explosive materials. The method comprises the steps of: a) performing a condensation reaction between 3,5-di-tert-butyl-4-hydroxybenzaldehyde and a secondary amine thereby forming a secondary amine quinone methide intermediate; b) removing water from the secondary amine quinone methide intermediate by azeotropic distillation; c) adding the dehydrated secondary amine quinone methide intermediate to an organic medium containing a metal acetylide to form a Mannich base intermediate; and d) adding a release agent to the Mannich base intermediate to yield a 7-Acetyleno quinone methide.Type: ApplicationFiled: October 29, 2014Publication date: March 5, 2015Applicant: NALCO COMPANYInventor: Jonathan Masere
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Publication number: 20150045499Abstract: The present invention provides a curable composition comprising an acrylate and a quantum dot, and a device using the same. Since the luminous efficiency and dispersion of a quantum dot are excellent and the curable composition has remarkable UV stability and heat resistance, the curable composition can be effectively applied to various forms of light emitting devices.Type: ApplicationFiled: December 1, 2012Publication date: February 12, 2015Inventors: Myeon Choeon Choi, Jeong Og Choi, Doo Hyo Kwon
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Patent number: 8895680Abstract: The present invention relates to redox-curing type nonaqueous curable compositions having: at least one liquid radical polymeric monomer (a); an organic peroxide (b); and a powdered water-soluble reducing compound (c), where the powdered water-soluble reducing compound (c) is dispersed in the liquid radical polymeric monomer (a).Type: GrantFiled: August 8, 2005Date of Patent: November 25, 2014Assignee: Kuraray Noritake Dental Inc.Inventors: Mitsunobu Kawashima, Aki Takase
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Patent number: 8853295Abstract: The present invention relates to a process for the preparation of particularly reactive and low-viscosity reaction products of polyisocyanates which contain activated ethylenically unsaturated groups which react by polymerization under the action of actinic radiation, and the use of these reaction products in coating compositions, and particularly scratch-resistant coatings obtainable therefrom.Type: GrantFiled: February 12, 2010Date of Patent: October 7, 2014Assignee: ALLNEX IP S.a.r.L.Inventors: Michael Ludewig, Wolfgang Fischer, Helmut Kuczewski
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Publication number: 20140264163Abstract: The present invention includes a process and apparatus for the production of methylene diphenyl diisocyanate (MDI) isomer mixtures with a low 2,2?-MDI isomer content and a high 2,4?-MDI isomer content. The resulting mixtures have an increased reactivity and are acceptable in food grade application due to the reduction in primary aromatic amines formed during the curing process. The process and apparatus also include controlling the amount of 4,4?-MDI, which is the most reactive isomer in the mixture allowing use in a wide variety of applications.Type: ApplicationFiled: November 19, 2012Publication date: September 18, 2014Applicant: Dow Global Technologies LLCInventors: Andrei S. Merenov, Gerard I. Jansma, Paul A. Gillis
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Publication number: 20140275400Abstract: The present invention provides methylene beta-diketone monomers, methods for producing the same, and compositions and products formed therefrom. In the method for producing the methylene beta-diketones of the invention, a beta-diketone is reacted with a source of formaldehyde in a modified Knoevenagel reaction optionally in the presence of an acidic or basic catalyst, and optionally in the presence of an acidic or non-acidic solvent, to form reaction complex. The reaction complex may be an oligomeric complex. The reaction complex is subjected to further processing, which may be vaporization by contact with an energy transfer means in order to isolate the beta-diketone monomer. The present invention further compositions and products formed from methylene beta-diketone monomers of the invention, including monomer-based products (e.g., inks, adhesives, coatings, sealants or reactive molding) and polymer-based products (e.g., fibers, films, sheets, medical polymers, composite polymers and surfactants).Type: ApplicationFiled: October 18, 2012Publication date: September 18, 2014Inventors: Yangbin Chen, Adam G. Malofsky, Jeffrey M. Sullivan, Stanley C. Wojciak, Tanmoy Dey, Bernard M. Malofsky
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Patent number: 8834970Abstract: Preliminary cure of an aqueous acrylic weatherproofing emulsion coating is accelerated by contacting the coating with urea hydrochloride dissolved in water or an organic solvent at least partially miscible with water.Type: GrantFiled: October 26, 2006Date of Patent: September 16, 2014Assignee: Tremco Barrier Solutions, Inc.Inventors: James R. Wells, Michael J. Mettille
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Publication number: 20140221518Abstract: The invention relates to a composition for producing a polyurethane system, especially a polyurethane foam. The composition comprising one or more compounds comprising at least one 5- or 6-membered ring comprising one or two oxygen atoms and carbon atoms The present invention also relates to a process for producing polyurethane systems by using this composition as well as polyurethane systems obtained from such a process. The present invention also relates to the use of the polyurethane system of the present invention.Type: ApplicationFiled: February 4, 2014Publication date: August 7, 2014Applicant: EVONIK INDUSTRIES AGInventors: Eva Emmrich-Smolczyk, Harald Modro, Patrick Kuhlmann
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Publication number: 20140179846Abstract: An additive composition comprises a wax and a nucleating agent. The nucleating agent can be dispersed in the wax. A process for producing a nucleated polymer comprises the steps of (a) providing a reactor; (b) providing an additive composition comprising a wax and a nucleating agent; (c) providing an extruder; (d) reacting in the reactor a reactant mixture comprising an olefin monomer and hydrogen to produce a polyolefin polymer; (e) collecting and recovering the polyolefin polymer produced by the reaction; (f) conveying the polyolefin polymer to the extruder; (g) conveying the additive composition to the extruder; and (g) extruding the polyolefin polymer and the additive composition to produce a nucleated polymer composition.Type: ApplicationFiled: November 1, 2013Publication date: June 26, 2014Applicant: MILLIKEN & COMPANYInventors: K. David Lake, Jr., John D. Price
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Publication number: 20140128506Abstract: The present invention concerns low-odor, low-viscosity hardeners for epoxy resins, including an amine with at least one amino group of formula (I) and an amine with at least one amino group of formula (II), wherein the amino groups of formulas (I) and (II) are present in a particular ratio. These hardeners harden quickly with epoxy resins and without blushing to form films of high hardness and good resistance. They are especially suitable for low-emission coatings.Type: ApplicationFiled: July 9, 2012Publication date: May 8, 2014Applicant: SIKA TECHNOLOGY AGInventors: Andreas Kramer, Edis Kasemi
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Publication number: 20140103254Abstract: A composition is provided that consists essentially of a first polymer system and a second polymer system. The first polymer system has a first modulus of about 180 ksi to about 335 ksi. The first polymer system consists essentially of a thermosetting acrylate. The second polymer system consists essentially of a thermosetting epoxy system and an epoxy curing agent. The thermosetting epoxy system comprises a first epoxy.Type: ApplicationFiled: December 16, 2013Publication date: April 17, 2014Applicant: THE BOEING COMPANYInventor: Gary Robert Weber
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Publication number: 20140048740Abstract: The present invention relates primarily to a mixture that is suitable for use in the no-bake process for producing cores and moulds for the foundry industry, and a reaction mixture comprising said mixture and an acid hardener (i.e. an acid catalyst). The present invention further relates to a method of producing a mixture according to the invention and a method of producing a mould or a core. The invention also relates to a mould or a core for producing metal objects and a kit comprising a mixture according to the invention and certain acid hardeners. The invention further relates to the use of a mixture according to the invention as cold-setting binder and the use of said mixtures or reaction mixtures in a no-bake process for producing metal objects.Type: ApplicationFiled: December 16, 2011Publication date: February 20, 2014Applicant: HUETTENES-ALBERTUS CHEMISCHE WERKE GMBHInventors: Christian Fourberg, Gérard Ladégourdie, Norbert Benz, Eckard Piech
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Publication number: 20140005338Abstract: A polymerizable composition which contains a cycloolefin monomer and a ruthenium carbene complex which is expressed by the following general formula (I): (in which general formula (I), R1 and R2 respectively independently represent a hydrogen atom, halogen atom, or cyclic or chain C1 to C20 hydrocarbon group which may contain a halogen atom, oxygen atom, nitrogen atom, sulfur atom, phosphorus atom, or silicon atom; X1 and X2 respectively independently represent an anionic ligand; L1 and L2 respectively independently represent a neutral electron donor ligand; L2 is a group with a higher three-dimensionally bulk than L1, where L1 and L2 are at cis positions with each other; R1 and R2 may bond with each other to form an aliphatic ring or aromatic ring which may contain a hetero atom; and R1, R2, X1, X2, L1, and L2 may bond with each other in any combination to form a multidentate chelating ligand).Type: ApplicationFiled: March 8, 2012Publication date: January 2, 2014Applicant: ZEON CORPORATIONInventors: Akihiko Yoshiwara, Yasuo Tsunogae
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Patent number: 8604097Abstract: The present invention relates to a process for preparing radiation-curing binders containing allophanate groups by reacting, at temperatures of ?130° C., A) one or more compounds containing uretdione groups with B) one or more OH-functional compounds which contain groups which react, with polymerization, with ethylenically unsaturated compounds on exposure to actinic radiation (radiation-curing groups), C) optionally NCO-reactive compounds other than B), in the presence of D) a catalyst containing at least one zinc compound, to form allophanate groups by opening the uretdione ring. The present invention also relates to the binders obtained by the process of the invention and to coating compositions containing these binders.Type: GrantFiled: January 27, 2011Date of Patent: December 10, 2013Assignee: Bayer MaterialScience AGInventors: Jan Weikard, Christophe Detrembleur, Dorota Greszta-Franz, Frank Richter, Wolfgang Fischer, Jörg Schmitz, Holger Mundstock
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Publication number: 20130310477Abstract: The present invention is a polyol composition (A) for the production of polyurethane resins which comprises a compound (a1) having a vinyl-polymerizable functional group represented by general formula (I) and a strength improver (a2) represented by general formula (II). In general formula (I), R is hydrogen, C1-15 alkyl, or C6-21 aryl. In general formula (II), R1 is a residue derived from an active-hydrogen-containing compound by removing one active hydrogen atom; Y is a residue derived from an at least divalent aromatic polycarboxylic acid (f) by removing the carboxyl groups; a is an integer satisfying the relationship: 1?a?(the number of substituents on the aromatic ring?1); Z is a residue derived from an at least m-valent active-hydrogen-containing compound by removing the m active hydrogen atoms; and m is an integer of 1 to 10.Type: ApplicationFiled: August 22, 2011Publication date: November 21, 2013Applicant: SANYO CHEMICAL INDUSTRIES, LTD.Inventors: Katsuya Uchida, Koji Kabu, Kei Sasaki, Tomohisa Hirano
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Patent number: 8586694Abstract: The polymerization catalyst for a polythiourethane-based optical material of the present invention includes a sulfonate represented by the following general formula (1). Furthermore, in the formula, R1, R2, R3 and R4 each independently represent an alkyl group having 1 to 18 carbon atoms, R1, R2, R3 and R4 may be bonded to each other to form a ring. R5 represents a hydrogen atom or an alkyl group having 1 to 18 carbon atoms, and X represents a nitrogen atom or a phosphorus atom.Type: GrantFiled: February 4, 2008Date of Patent: November 19, 2013Assignee: Mitsui Chemicals, Inc.Inventors: Masanori Iwazumi, Nobuo Kawato, Mamoru Tanaka, Hidetoshi Hayashi, Seiichi Kobayashi
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Publication number: 20130303719Abstract: The present invention provides improved methods for the chemical synthesis of methylene malonates using the Knovenagel synthesis reaction. The method of the invention provides for improved methylene malonates by significantly reducing or eliminating the formation of alternative and/or deleterious side products, significantly reducing or eliminating unwanted consumption of methylene malonates, and significantly reducing or eliminating the degradation of methylene malonates. These advantages result in methylene malonates, which upon recovery, are of higher quality, greater purity, improved yield and possess overall improved performance characteristics (e.g., improved cure speed, retention of cure speed, improved shelf-life and/or stability).Type: ApplicationFiled: October 19, 2011Publication date: November 14, 2013Applicant: BIOFORMIX, LLCInventors: Bernard Miles Malofsky, Tanmoy Dey, Jeffrey M. Sullivan, Yangbin Chen, Stanley C. Wojciak, Bernard M. Malofsky
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Patent number: 8569439Abstract: A hardener for silicone rubber materials comprising a silane compound which comprises a 2-hydroxy-propionic acid alkyl ester radical.Type: GrantFiled: August 29, 2008Date of Patent: October 29, 2013Assignee: Nitro-Chemie Aschau GmbHInventors: Theodor Ederer, Thomas Knott, Ulrich Pichl, Gerhard Schmidt, Ludwig Waldmann
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Publication number: 20130281564Abstract: The present invention relates to novel photoactive polymer materials their use as orienting layer for liquid crystals, which are used for the production of non-structured and structured optical elements or electro-optical elements and multi-layer systems.Type: ApplicationFiled: December 21, 2011Publication date: October 24, 2013Applicant: ROLIC AGInventor: Hubert Seiberle
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Publication number: 20130276653Abstract: The present invention relates to a curable jettable fluid for making a flexographic printing master characterized in that the jettable fluid has a viscosity measured at jetting temperature of less than 15 mPa·s and comprises at least 50 wt. % of a mixture of a cyclic monofunctional (meth)acrylate monomer, a monofunctional urethane acrylate oligomer and a difunctional (meth)acrylate monomer.Type: ApplicationFiled: December 19, 2011Publication date: October 24, 2013Applicant: AGFA GRAPHICS NVInventors: Eddie Daems, Luc Vanmaele
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Patent number: 8563664Abstract: A composition, prepolymer and method to produce a polymer based on biodegradable or essentially renewable crude materials, which can be crosslinked by free radicals. The composition is based on polyesters that are functionalized with unsaturated monomer units, in a way that unsaturated groups can be located along the polymer main chain as well as at the ends of the prepolymer. In connection to the product production, the prepolymer is exposed to free radicals that leads to network formation. The composition of the crosslinked biopolymer can be adjusted from a stiff engineering material to an elastic rubbery material. The new biopolymer can be used in composite materials, dispersions, barrier materials, rubbery materials, biomedical applications, and the like.Type: GrantFiled: November 3, 2005Date of Patent: October 22, 2013Assignee: JVS-Polymers OyInventor: Jukka Seppälä
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Publication number: 20130274416Abstract: Disclosed is a graft monomer composition for thermoplastic transparent resins, a composition for thermoplastic transparent resins using the same and a thermoplastic transparent resin that exhibits superior transparency and color at low rubber contents. According to the graft monomer composition, the composition for thermoplastic transparent resins and the thermoplastic transparent resin, although the content of rubber in final products increases or the content of rubber in graft copolymers in the preparation of final products increases, the copolymer surrounds the surface of rubber well, thus reducing haze, considerably improving transparency and exhibiting excellent natural color.Type: ApplicationFiled: December 23, 2011Publication date: October 17, 2013Applicant: LG Chem, Ltd.Inventors: Jeong-Su Choi, Keun-Hoon Yoo, Hyong-Min Bahn, Won-Seok Lee, Seok-Goo Jang
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Publication number: 20130235114Abstract: An inkjet printing method includes, in order, the steps of a) providing to an inkjet printer at least two or more colorless liquids having a different composition and at least one color inkjet ink; b) mixing the color inkjet ink in a controlled amount with the two or more colorless liquids; and c) printing the ink-mixture of the color inkjet ink and the two or more colorless liquids with the inkjet printer onto an ink-receiver.Type: ApplicationFiled: April 29, 2013Publication date: September 12, 2013Applicant: AGFA GRAPHICS NVInventors: Etienne VAN THILLO, Frank DE VOEGHT
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Patent number: 8524034Abstract: Provided is a complex of hydrogen peroxide and at least one compound represented by Formula I: wherein X is: —C(R3)3, —C?C(R3), —O(R3), —N(R3)2, or —S(R3); and R1, R2, and R3 are each independently selected from H, alkyl, alkenyl, alkynyl, aralkyl, aryl, heteroaryl heteroarylalkyl, heterocyclyl, and cycloalkyl, or R2 and an R3 are optionally taken together to form an alicyclic ring. Also provided are anaerobic cure systems and curable compositions employing the complexes described herein.Type: GrantFiled: July 7, 2011Date of Patent: September 3, 2013Assignees: Henkel Corporation, Henkel Ireland LimitedInventors: Philip T. Klemarczyk, David Birkett, David Farrell, Peter Wrobel, Ciaran McArdle, Greg Clarke
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Patent number: 8524807Abstract: Compounds VB of the formula (I) or (II), said compounds being particularly suitable as curing agents for epoxide resins. The compounds can be produced easily and rapidly. They can be used in the form of aqueous curing agents and form stabile aqueous emulsions in particular. This facilitates the formulation of ECC compounds for use primarily as coatings.Type: GrantFiled: June 12, 2009Date of Patent: September 3, 2013Assignee: Sika Technology AGInventor: Pierre-André Bütikofer
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Publication number: 20130225706Abstract: A reaction system comprising an organic polyisocyanate and an isocyanate reactive component for preparation of a viscoelastic polyurethane foam is provided. The isocyanate reactive component comprises (i) from 10 to 50% by weight of one or more low equivalent weight propylene oxide rich (PO-rich) polyols having a combined number average equivalent weight from 200 to 500, (ii) from 45 to 95% by weight of one or more ethylene oxide (EO-rich) polyols having a combined number average equivalent weight from 200 to 800 and an ethylene oxide content from 40% to 65% by weight of the total mass of the EO-rich polyol and at least one of (iii) from 10 to 30% by weight of one or more high equivalent weight PO-rich polyols having a number average equivalent weight from 800 to 2,000 or (iv) from 10 to 40% by weight of one or more propylene oxide co-polymer polyols containing styrene-acrylonitrile.Type: ApplicationFiled: August 30, 2011Publication date: August 29, 2013Applicant: DOW GLOBAL TECHNOLOGIES LLCInventors: Hongming Ma, Kaoru Aou, Rogelio R. Gamboa, Carola Rosenthal, Randal Autenrieth
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Patent number: 8507618Abstract: Composition comprising (A) 50-99.5 wt %, based on the total weight, of A, B and C of a reaction resin or reaction resin mixture that is processed into thermosetting materials, said resin or resin mixture being liquid at temperatures in the range of 15 to 100° C. and having an average molecular weight of 200 to 500,000 and with a sufficient number of suitable reactive groups for a curing process and (B) 0.5-50 wt %, relative to the total weight of A, B and C of one or more dispersed polyorganosiloxanes that are contained in the reaction resin or reaction resin mixture homogeneously in finely distributed form as polyorganosiloxane droplets with a diameter of 0.001 to 4 ?m, wherein the organopolysiloxane particle is a polymer of the general formula (R3SiO1/2)W(R2SiO2/2)X—(RSiO3/2)Y—(SiO4/2)Z, where w=0 to 20 Mol %, x=80 to 99.9 Mol %, y=0.5 to 10 Mol %, z=0 to 10 Mol %, (C) 0.Type: GrantFiled: November 20, 2009Date of Patent: August 13, 2013Assignee: Wacker Chemie AGInventors: Oliver Schäfer, Helmut Oswaldbauer
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Patent number: 8507632Abstract: An actinic energy ray curable composition useful as a paint or coating agent, especially for products where scratch resistance is desired, includes a particular composition that includes a urethane (meth)acrylate obtained by reacting to an organic isocyanate having a plurality of isocyanate groups in one molecule with a polycaprolactone-modified alkyl (meth)acrylate and a long-chain alcohol.Type: GrantFiled: September 11, 2006Date of Patent: August 13, 2013Assignee: Natoco Co., Ltd.Inventors: Masahiro Hara, Tomihisa Ohno, Susumu Kawakami
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Publication number: 20130197114Abstract: A composition and process useful to make flexible polyurethane foams and in particular flexible molded polyurethane foams is disclosed. The usage of dipolar aprotic liquids such as DMSO, DMI, sulfolane, N-methyl-acetoacetamide, N,N-dimethylacetoacetamide as well as glycols containing hydroxyl numbers OH#?1100 as cell opening aides for 2-cyanoacetamide or other similar molecules containing active methylene or methine groups to make a polyurethane foam is also disclosed. The advantage of using cell opener aids results in a) no foam shrinkage; b) lower use levels of cell opener; c) foam performance reproducibility d) optimum physical properties. In addition, combining the acid blocked amine catalyst together with the cell opener and the cell opener aid results in a less corrosive mixture as well as provides a method that does not require mechanical crushing for cell opening.Type: ApplicationFiled: June 27, 2012Publication date: August 1, 2013Applicant: Air Products and Chemicals, Inc.Inventors: Juan Jesus Burdeniuc, James Douglas Tobias, Renee Jo Keller
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Publication number: 20130197123Abstract: The claimed invention provides a novel compound not having been studied before, that is, a diene carboxylate anion that contains a specific structure, and a salt thereof. The claimed invention further provides a diene carboxylate anion and a salt thereof, especially a metal salt thereof, which are easily soluble in general organic solvents, reactive diluents, and resins, may be in a liquid state at normal temperature depending on the structure, and have high polymerizability. Polymerization/curing of these produces a resin to which many ionic bonds and a metal are introduced, providing various properties such as hardness, scratch resistance, anti-fingerprint property, gas-barrier property, water vapor barrier property, oxygen absorption property, ultraviolet protection, infrared protection, color development and coloring, high refractive index, adhesion, various catalytic abilities, fluorescence ability and light-emitting ability, optical amplification, dispersibility, and antistatic properties.Type: ApplicationFiled: October 5, 2011Publication date: August 1, 2013Applicant: NIPPON SHOKUBAI CO., LTD.Inventor: Tomomasa Kaneko
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Publication number: 20130190457Abstract: Controlled thermal crosslinking in a polyacrylate-based composition is accomplished by a crosslinker-accelerator system for the thermal crosslinking of polyacrylates having functional groups suitable for entering into linking reactions with epoxide groups, comprising at least one substance comprising at least one epoxide group (crosslinker) and at least one substance of the general formula (I) R1R2N—CR3R4—CR5R6—(CR7R8)n—NR9R10??(I) wherein the radicals R1, R2, R9 and R10 independently of one another are a hydrogen atom or a substituted or unsubstituted alkyl or cycloalkyl radical having 1 to 8 carbon atoms or an alkylene group bonded to the main chain and having 1 to 8 carbon atoms, where at least one of the radicals R1, R2, R9 and R10 is not a hydrogen atom; the radicals R3, R4, R5, R6, R7 and R8 independently of one another are a hydrogen atom or an alkyl group having 1 to 8 carbon atoms or form a 5-7-membered cycloalkylene group; and n is an integer from 0 to 4 (accelerator).Type: ApplicationFiled: January 18, 2013Publication date: July 25, 2013Applicant: tesa SEInventor: tesa SE
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Publication number: 20130184420Abstract: To provide a monomer composition containing an unsaturated polyalkylene glycol ether-based monomer and having excellent stability. Provided is a monomer composition containing an unsaturated polyalkylene glycol ether-based monomer represented by the following chemical formula (1): YO(R1O)nR2??(1) [in the formula, Y represents an alkenyl group having 2 to 7 carbon atoms; R1O represents one or two or more types of oxyalkylene groups having 2 to 18 carbon atoms; n represents an average addition mole number of oxyalkylene groups and is a number of 5 to 500; and R2 represents a hydrogen atom or a hydrocarbon group having 1 to 30 carbon atoms], an organic acid, and water, and having a pH of 4 to 13.Type: ApplicationFiled: September 22, 2011Publication date: July 18, 2013Applicant: NIPPON SHOKUBAI CO., LTD.Inventor: Hiroshi Kawabata
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Patent number: 8440278Abstract: The use of 3-pyridinol and 5-pyrimidinol derivatives for adjusting the reactivity and the gel time of resin mixtures and/or reactive resin mortars based on radically polymerizable compounds is described. Furthermore, a resin mixture and a reactive resin mortar containing the 3-pyridinol and 5-pyrimidinol derivatives for adjusting the reaction time and the gel time, and having improved storage stability and good low temperature hardening properties, are described.Type: GrantFiled: June 8, 2012Date of Patent: May 14, 2013Assignee: Hilti AktiengesellschaftInventor: Armin Pfeil
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Publication number: 20130032756Abstract: The present invention provides a thermoplastic polymer composition containing a particular phenol compound or organic phosphoric compound, compound (9) which is compound (9a) represented by CmH2mOm wherein m is an integer of not less than 3 and not more than 10, and having one aldehyde group or ketone group and m?1 hydroxy groups with at least one hydroxy group having been replaced by an alkoxy group represented by —OR26 wherein R26 is a C1-12 alkyl group, and a thermoplastic polymer, and a processing stabilizer containing a particular phenol compound or organic phosphoric compound, and compound (9). A combined use of a particular phenol compound or organic phosphoric compound and compound (9) can improve processing stability of a thermoplastic polymer composition.Type: ApplicationFiled: April 14, 2011Publication date: February 7, 2013Applicant: SUMITOMO CHEMICAL COMPANY, LIMITEDInventors: Yoshikazu Kimura, Hideaki Awa
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Publication number: 20130035426Abstract: The present invention provides a thermoplastic polymer composition containing a particular phenol compound or organic phosphorous compound, trehalose and a thermoplastic polymer, as well as a stabilizer composition containing a particular phenol compound or organic phosphorous compound and trehalose. A combined use of a particular phenol compound or organic phosphorous compound and trehalose can improve processing stability of a thermoplastic polymer composition.Type: ApplicationFiled: April 14, 2011Publication date: February 7, 2013Applicant: SUMITOMO CHEMICAL COMPANY, LIMITEDInventors: Yoshikazu Kimura, Hideaki Awa
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Publication number: 20120315417Abstract: The use of 3-pyridinol and 5-pyrimidinol derivatives for adjusting the reactivity and the gel time of resin mixtures and/or reactive resin mortars based on radically polymerizable compounds is described. Furthermore, a resin mixture and a reactive resin mortar containing the 3-pyridinol and 5-pyrimidinol derivatives for adjusting the reaction time and the gel time, and having improved storage stability and good low temperature hardening properties, are described.Type: ApplicationFiled: June 8, 2012Publication date: December 13, 2012Applicant: Hilti AktiengesellschaftInventor: Armin PFEIL
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Publication number: 20120283349Abstract: A radiation curable composition for UV LED curing includes at least one co-initiator selected from the group consisting of an aliphatic tertiary amine and a dialkyl aniline derivative; and at least one specific carbazole photoinitiator. The radiation curable composition can be advantageously used to prevent unstable yellowing behaviour in an image upon storage.Type: ApplicationFiled: December 6, 2010Publication date: November 8, 2012Applicant: AGFA-GEVAERT N.V.Inventor: Johan Loccufier
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Publication number: 20120261625Abstract: The present invention relates to a stabilized monomer dispersion containing inorganic oxide nanoparticles with high refractive index in which the refractive index of the inorganic oxide nanoparticles is greater than 1.65 and the average particle size of the high refractive inorganic oxide nanoparticles ranges from 1 to 100 nm and its content is in a range of from 1.0% by weight to 10.0% by weight based on the total weight of the monomer dispersion. The present invention also relates to a process for preparing the stabilized monomer dispersion containing high refractive inorganic oxide nanoparticles.Type: ApplicationFiled: January 25, 2012Publication date: October 18, 2012Inventors: Wen-Yen CHIU, I-Ann Lei, Dai-Fu Lai, Wen-Chang Chen, Yang-Yen Yu, Guey-Sheng Liou, Trong-Ming Don
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Publication number: 20120225832Abstract: The invention relates to amphiphilic C-glycoside derivatives, to methods of using them and to processes for synthesizing them. Specifically, the invention relates to novel cyclic and linear enone-glycolipids and cyclic ketone-glycolipids.Type: ApplicationFiled: November 8, 2010Publication date: September 6, 2012Applicant: Yale UniversityInventors: Patrick Foley, Paul Anastas, Toby Sommer