Reactant Contains Ethylenic Group Patents (Class 252/182.18)
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Patent number: 8119599Abstract: A method of treatment of native, non-denatured tissue to increase resistance to tearing, fissuring, rupturing, and/or delamination, comprising the step of: contacting at least a portion of the tissue with an effective amount of a reagent that increases crosslinks in the tissue.Type: GrantFiled: October 17, 2007Date of Patent: February 21, 2012Assignee: Orthopeutics, L.P.Inventors: Thomas P. Hedman, Paul Slusarewicz
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Patent number: 8106141Abstract: Reaction products prepared from reactants including: (a) at least one compound of structural Formula (I): wherein R1 is selected from aryl and heteroaryl; X is selected from a direct bond, —O—, —S—, —NH—, alkylene, cycloalkylene, heterocyclylene, arylene, alkarylene, and heteroarylene; Y is a substituted alkylene group having at least two contiguous carbon atoms and which can be interrupted by one or more —O—, —S—, or —NH— moieties as defined herein, wherein the alkylene group of Y has substituents independently selected from —OH, —NH2, —SH, cycloalkyl, heterocyclyl, aryl, and heteroaryl, or two hydrogen atoms on the same carbon atom of Y are replaced by carbonyl, and wherein at least two substituents of Y are each independently selected from —OH, —NH2, and —SH, as defined herein; and (b) at least one isocyanate functional material.Type: GrantFiled: May 7, 2008Date of Patent: January 31, 2012Assignee: Henkel CorporationInventors: Anthony F. Jacobine, Andrew Messana, David M. Glaser, Steven Thomas Nakos
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Patent number: 8071698Abstract: The present invention relates to cationically curable compositions for curing on a surface comprising a cationically curable component, an accelerator species comprising at least one vinyl ether functional group and an initiator component capable of initiating cure of the cationically curable component. The initiator comprises at least one metal salt, which is chosen so that it is reduced at the surface, and where the standard reduction potential of the initiator component is greater than the standard reduction potential of the surface, and where when the composition is placed in contact with the surface, the metal salt of the initiator component of the composition is reduced at the surface, thereby initiating cure of the cationically curable component of the composition. The accelerator species comprising at least one vinyl ether functional group greatly enhances the rate of cure. No catalytic component is required in the composition for efficient cure.Type: GrantFiled: May 22, 2009Date of Patent: December 6, 2011Assignee: Loctite (R&D) LimitedInventors: David Farrell, Ciaran B. McArdle, Michael Doherty
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Publication number: 20110290418Abstract: Provided is a complex of hydrogen peroxide and at least one compound represented by Formula I: wherein X is: —C(R3)3, —C?C(R3), —O(R3), —N(R3)2, or —S(R3); and R1, R2, and R3 are each independently selected from H, alkyl, alkenyl, alkynyl, aralkyl, aryl, heteroaryl heteroarylalkyl, heterocyclyl, and cycloalkyl, or R2 and an R3 are optionally taken together to form an alicyclic ring. Also provided are anaerobic cure systems and curable compositions employing the complexes described herein.Type: ApplicationFiled: July 7, 2011Publication date: December 1, 2011Applicants: Loctite ( R&D) Limited, Henkel CorporationInventors: Philip T. Klemarczyk, David Birkett, David Farrell, Peter Wrobel, Ciaran McArdle, Greg Clarke
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Patent number: 8057698Abstract: The invention relates to mixtures of methacrylamide and aqueous N-methylolmethacrylamide solution.Type: GrantFiled: October 31, 2006Date of Patent: November 15, 2011Assignee: Evonik Röhm GmbHInventors: Wolfgang Klesse, Joachim Knebel
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Patent number: 7947241Abstract: The present application relates to the use of a solution for the treatment of exhaust gases at the outlet of on-board or stationary diesel engines. It also relates to its use in any device for the treatment of these exhaust gases, regardless of whether the engines are engines of heavy goods vehicles or engines for light vehicles or also engines for stationary industrial engine applications.Type: GrantFiled: February 14, 2008Date of Patent: May 24, 2011Assignee: Total Raffinage MarketingInventors: Pierre Schmelzle, Leire Oro-Urrea, Stéphanie Escoffier, Françoise Douce
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Patent number: 7939578Abstract: Polymeric fibers and methods of making the polymeric fibers are described. The polymeric fibers are crosslinked hydrogels or dried hydrogels that are prepared from a precursor composition that contains polymerizable material having an average number of ethylenically unsaturated groups per monomer molecule greater than 1.0. The polymeric fibers can contain an optional active agent.Type: GrantFiled: August 30, 2007Date of Patent: May 10, 2011Assignee: 3M Innovative Properties CompanyInventors: Robin E. Wright, Mahfuza B. Ali, Jessica M. Buchholz, Louis C. Haddad, Linda K. M. Olson, Matthew T. Scholz, Narina Y. Stepanova, Michael J. Svarovsky, Richard L. Walter, Caroline M. Ylitalo, Diane R. Wolk, Yifan Zhang
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Publication number: 20110076502Abstract: The present disclosure is directed to a single phase acetylated castor component (SP-ACC). An acetylated castor component is purified to produce the SP-ACC which contains a reduced amount of, or no, insoluble component(s) therein. The SP-ACC enhances the performance and properties of plasticizers of which it is a component.Type: ApplicationFiled: June 23, 2010Publication date: March 31, 2011Inventors: Bharat I. Chaudhary, Beate Sczekalla, Abhijit Ghosh-Dastidar, Yang Cheng, Prashant Tatake, Raymond M. Collins
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Patent number: 7902315Abstract: The present invention relates to a process for preparing radiation-curing binders containing allophanate groups by reacting at temperatures of ?130° C. A) one or more compounds containing uretdione groups with B) one or more OH-functional compounds which contain groups which react, with polymerization, with ethylenically unsaturated compounds on exposure to actinic radiation (radiation-curing groups), C) optionally NCO-reactive compounds other than B), in the presence of D) a catalyst containing at least one zinc compound, to form allophanate groups by opening the uretdione ring.Type: GrantFiled: September 1, 2005Date of Patent: March 8, 2011Assignee: Bayer MaterialScience AGInventors: Jan Weikard, Christophe Detrembleur, Dorota Greszta-Franz, Frank Richter, Wolfgang Fischer, Jörg Schmitz, Holger Mundstock
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Publication number: 20110049423Abstract: The invention relates to special (methyl)acrylaic monomers and concerns more particularly an enhanced process for preparing solutions of alkylimiozolidone (meth)acrylates in water solutions of alkylimidazolidone (meth)acrylates in a light (meth)acrylate.Type: ApplicationFiled: April 8, 2009Publication date: March 3, 2011Applicant: Arkema FranceInventors: Alain Riondel, Jean-Michel Paul
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Patent number: 7897718Abstract: The present invention relates to an acrylated semi-crystalline hyperbranched polyurethane oligomer and a preparation method thereof, which is characterized in that on the basis of the synthesis of hyperbranched polyurethane oligomer, it adopts a two-step process to make modifications to form a methacrylic and/or acrylic double bond and a long carbon chain with a carbon atom number higher than 10 or a benzene ring or a naphthalene ring at the terminals. The obtained oligomer has a lower melting point and a higher glass transition temperature and can be cured by means of radiation, and the curing rate is high enough to effectively improve production efficiency and save energy to form a cured film having a higher hardness and excellent thermal stability. The raw materials used in the method of the invention are easily obtained, and the method is suitable for large-scale production in industry.Type: GrantFiled: May 18, 2006Date of Patent: March 1, 2011Assignee: Eternal Chemical Co., Ltd.Inventors: Chi-Kang Chang, Chin-Yuan Chen, Wen-Fang Shi, Hong-Bo Liang
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Patent number: 7887716Abstract: This invention relates to cationically curable sealants that provide low moisture permeability and good adhesive strength after cure. The composition consists essentially of an electrophoretic device containing an oxetane compound and a photoinitiating system comprising and photoinitiator and optionally a photosensitizer.Type: GrantFiled: July 25, 2008Date of Patent: February 15, 2011Assignee: Henkel AG & Co. KGaAInventors: Shengqian Kong, Stijn Gillissen
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Publication number: 20100297356Abstract: This invention is directed to a process for the preparation of a crosslinker composition, comprising the steps of providing a mixture of an aliphatic alcohol A having at least one hydroxyl group and from 1 to 10 carbon atoms, with at least one multifunctional aldehyde C having at least two aldehyde groups —CHO to form a mixture AC, heating the mixture AC to convert at least a part of the multifunctional aldehyde C to its hemiacetal or to its acetal to form a mixture (AC)?, adding to the mixture (AC)? least one cyclic urea U or the educts to produce the said cyclic urea U in situ, which cyclic urea U has at least one unsubstituted >NH group, and reacting the mixture thus obtained to form a chemical bond between the nitrogen atom of the at least one unsubstituted >NH group of the at least one cyclic urea U5 and the carbon atom of the least one aldehyde group —CHO of the multifunctional aldehyde C, and coating compositions comprising the said crosslinker composition.Type: ApplicationFiled: December 5, 2008Publication date: November 25, 2010Applicant: Cytec Technology CorpInventors: Lawrence A. Flood, Barry A. Lawless
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Patent number: 7803870Abstract: Disclosed are a cycloolefin resin molded product having excellent flame retardance and a polymerizable composition used for producing such a molded product. A polymerizable composition comprising the cycloolefin monomer, a flame retardant and a metathesis polymerization catalyst is characterized in that a monomer having a condensed ring formed of an aliphatic ring having one or more carbon-carbon double bonds and a ring with aromatic characteristics is used as the cycloolefin monomer. A molded product can be produced through bulk polymerization of this polymerizable composition.Type: GrantFiled: July 8, 2009Date of Patent: September 28, 2010Assignee: Zeon CorporationInventor: Tomoo Sugawara
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Publication number: 20100216903Abstract: An isocyanate-reactive composition containing a blowing agent that includes HFC 134a and water characterized by a vapor pressure which is lower than that of comparable compositions which do not include the stabilizing composition of the present invention. The stabilizing composition of the present invention includes an ethoxylated nonylphenol and propylene carbonate. This stabilizing composition is included in the isocyanate-reactive composition in an amount sufficient to promote the solubility of the blowing agent. The isocyanate-reactive composition may be stored at ambient conditions rather than under pressure and may be hand mixed with an isocyanate to produce a foam. The isocyanate-reactive composition containing blowing agent of the present invention may be used to produce foams having good physical properties after storage at ambient temperature and pressure for periods as long as 3 months.Type: ApplicationFiled: February 20, 2009Publication date: August 26, 2010Applicant: Bayer MaterialScience LLCInventor: Michael A. Dobransky
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Patent number: 7732646Abstract: An allyl type crosslinking agent for use in production of a super water-absorbent polymer comprising a polymerizable compound having a carbon-carbon double bond or a salt thereof. The crosslinking agent comprises a linear hydroxypolyallyl ether having at least one hydroxyl group and at least two allyl groups obtained by allyletherification of hydroxyl groups in a linear polyol compound selected from the group consisting of erythritol, xylitol and sorbitol. This allyl type crosslinking agent is highly soluble in an aqueous solvent, and can give an excellent super water-absorbent polymer, which cannot be obtained in the prior arts, having high levels of both of water absorptivity under atmospheric pressure and water absorptivity under pressurized conditions.Type: GrantFiled: January 3, 2005Date of Patent: June 8, 2010Assignee: Daiso Co., Ltd.Inventors: Shin-ichiro Nakamura, Yasumi Shimizu, Tohru Matsutomi, Thomas Daniel
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Patent number: 7714037Abstract: A photoinitiated cationically curable composition is provided, including at least one substantially saturated epoxy component comprising at least two glycidyl ether groups; at least one acrylonitrile/butadiene copolymer; and at least one cationic photoinitiator. The compositions exhibit excellent strength properties as well as reduced color formation upon curing, particularly after post-curing thermal treatments. Methods of bonding substrates with such compositions and articles prepared therefrom are also provided through the invention.Type: GrantFiled: December 15, 2006Date of Patent: May 11, 2010Assignee: Henkel CorporationInventor: Philip T. Klemarczyk
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Patent number: 7700662Abstract: The present invention relates to a process for preparing low-viscosity, allophanate-containing and NCO-free polyurethane prepolymers curable by actinic radiation, and to the products obtainable by this process. The prepolymers have residual monomer contents of less than 0.5% by weight and an NCO content of less than 1% by weight, and are prepared by a process in which A) diisocyanates, B) hydroxy-functional compounds containing groups which react with ethylenically unsaturated compounds on exposure to actinic radiation, and C) polyester, polyether or polycarbonate polyols having a functionality of at least 1.Type: GrantFiled: March 30, 2007Date of Patent: April 20, 2010Assignee: Bayer MaterialScience AGInventors: Michael Ludewig, Jan Weikard, Nicolas Stoeckel, Wolfgang Fischer
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Publication number: 20100093904Abstract: The present invention provides a granular stabilizer for a polymer which is low-dusting and thus is easy to be handled. The present invention relates to a granular stabilizer for a polymer, comprising a compound shown by the formula (1): wherein R1s and R2s each independently represents a hydrogen atom, an alkyl group having 1 to 8 carbon atoms, or a cycloalkyl group having 5 to 8 carbon atoms; R3s each independently represents a hydrogen atom or an alkyl group having 1 to 8 carbon atoms; and X represents a single bond, a sulfur atom, an oxygen atom, an alkylidene group having 1 to 8 carbon atoms or a cycloalkylidene group having 5 to 8 carbon atoms.Type: ApplicationFiled: October 5, 2009Publication date: April 15, 2010Applicant: SUMITOMO CHEMICAL COMPANY, LIMITEDInventors: Kazuhiro Kitamura, Natsuko Sato, Kenji Kimura
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Publication number: 20100084603Abstract: A process for the preparation of new polyols and polyesters from a natural oil or other unsaturated fatty acid esters is described. The process involves ozone cleavage of double bonds in the fatty acid chains of the oils along with coupling of a hydroxylated compound such as a mono-alcohol, a diol, or a polyol to the cleaved ends of the molecules resulting from the cleavage with a base. The resulting polyols and polyesters are as intermediates for polymers.Type: ApplicationFiled: September 15, 2009Publication date: April 8, 2010Applicants: Board of Trustees of Michigan State University, Bioplastic Polymers and Composites, LLCInventors: Ramani Narayan, Daniel Graiver, Kenneth W. Farminer, Phuong T. Tran, Tam Tran
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Publication number: 20100056739Abstract: The invention relates to a method for the transportation of a monomer composition in which a composition comprising an aqueous solution of partially or entirely neutralized acrylic acid or overneutralized acrylic acid is placed in a transport means or sent through a pipe. The method according to the invention is characterized in that it has an increased level of safety during the transportation of acrylic acid monomers, an improved quality of the resulting product, and a high degree of efficiency. The method ensures safe transport of the highly reactive acrylic acid. The amount of polymerization inhibitors added to said acrylic acid may be reduced. An additional advantage is the minimization of the formation of dimeric acrylic acid. Tempering of containers, pipes, and pipelines may be omitted.Type: ApplicationFiled: March 20, 2008Publication date: March 4, 2010Applicant: BASF SEInventors: Rüdiger Funk, Wilfried Heide, Matthias Weismantel, Ulrich Hammon, Andrea Karen Bennett
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Patent number: 7670499Abstract: Special amine compositions comprising a) 30-70% by weight of a polyetherdiamine of the general formula (I) in which n is from 10 to 70, b) 3-30% by weight of a monoamine of the general formula R1—NH2, in which R1 is the straight-chain or branched, saturated or preferably unsaturated radical of a hydrocarbon having 5 to 22 carbon atoms or of a monofunctional polyetheramine having a molecular weight of up to 400 g/mol and c) 3-30% by weight of a di- or triamine and d) 5-40% by weight of an alkylphenol of the general formula (II) in which R2 is the straight-chain, branched or cyclic, saturated or unsaturated radical of a hydrocarbon having 5 to 14 carbon atoms, and curable epoxy resin compositions comprising these special amine compositions, the use of which results in thermosets which have a low degree of crosslinking, are resilient even at low temperatures and are resistant to chemical compositions, and the production of shaped articles and coatings using these curable compositions.Type: GrantFiled: July 8, 2005Date of Patent: March 2, 2010Assignee: Huntsman Advanced Materials Americas LLCInventors: Jörg Volle, Michael Vogel
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Publication number: 20090324675Abstract: The present invention provides a biocompatible prepolymer comprising hydrophilic and hydrophobic segments, wherein the hydrophobic segments have at least one ethylenically unsaturated functional group and at least 5% of the segments have two or more ethylenically unsaturated functional groups and water. The invention further provides a biocompatible prepolymer composition comprising hydrophilic and hydrophobic prepolymers, wherein at least one of the hydrophobic prepolymers has at least one ethylenically unsaturated functional group and at least 5% of the prepolymers have two or more ethylenically unsaturated functional groups and water. The invention further provides use of the prepolymer or prepolymer compositions of the invention in biomedical applications such as tissue engineering, as bone substitutes or scaffolds, and in wound treatment.Type: ApplicationFiled: August 2, 2007Publication date: December 31, 2009Applicant: POLYNOVO BIOMATERIALS PTY LIMITEDInventors: Pathiraja Arachchillage Gunatillake, Roshan Tyrrel Anton Mayadunne, Raju Adhikari, Heng Chy Taing, Tam Phuong Thi Le, Jerome Anthony Werkmeister, John Alan Maurice Ramshaw, Jacinta Frances White, Tracy Ann Tebb
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Publication number: 20090288769Abstract: The present invention relates to cationically curable compositions for curing on a surface comprising a cationically curable component, an accelerator species comprising at least one vinyl ether functional group and an initiator component capable of initiating cure of the cationically curable component. The initiator comprises at least one metal salt, which is chosen so that it is reduced at the surface, and where the standard reduction potential of the initiator component is greater than the standard reduction potential of the surface, and where when the composition is placed in contact with the surface, the metal salt of the initiator component of the composition is reduced at the surface, thereby initiating cure of the cationically curable component of the composition. The accelerator species comprising at least one vinyl ether functional group greatly enhances the rate of cure.Type: ApplicationFiled: May 22, 2009Publication date: November 26, 2009Applicant: Loctite (R&D)LimitedInventors: David Farrell, Ciaran B. McArdle, Michael Doherty
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Publication number: 20090283719Abstract: A thermosetting composition containing an aluminosiloxane and an epoxy silicone. The thermosetting composition of the present invention is suitably used for, for example, photosemiconductor devices mounted with blue or white LED elements (backlights for liquid crystal displays, traffic lights, outdoor big displays, advertisement sign boards, and the like).Type: ApplicationFiled: April 7, 2009Publication date: November 19, 2009Applicant: NITTO DENKO CORPORATIONInventor: Hiroyuki KATAYAMA
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Publication number: 20090270549Abstract: In order to make available a crosslinking agent for ethylene acrylate (AEM) and polyacrylate (ACM) elastomers, which is equivalent to the crosslinking agents containing guanidine that have been used until now, but which does without the teratogenically acting guanidines which are toxologically hazardous, it is proposed that the crosslinking agent for diaminically crosslinkable AEM and ACM elastomers comprise a diamine crosslinker, an accelerator selected from 1,8-diazabicyclo-5,4,0-undec-7-ene (DBU), derivatives and salts thereof, and a moderator of the pyrrolidone type.Type: ApplicationFiled: April 14, 2009Publication date: October 29, 2009Inventor: Roy Horst Josef Hornig
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Publication number: 20090226749Abstract: Combination of additives suitable for use in production or preparation of thermoplastics comprising at least one metal comprising compound i) and at least one compound ii) chosen among compounds which wholly or partially can be manufactured by condensation of one or more alcohols and compounds which wholly or partially can be manufactured by ring-opening addition of heterocyclic organic compounds comprising at least one oxygen atom. Furthermore the invention concerns a method for changing properties of thermoplastics using such a combination as well as the resulting thermoplastics and products based on such thermoplastics.Type: ApplicationFiled: April 23, 2007Publication date: September 10, 2009Applicant: NOR-X INDUSTRY ASInventors: Ferdinand Mannle, Kaare Roger Rodseth, Emil Arne Kleppe, Roger Hauge, Bjorn Steinar Tanem
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Patent number: 7582355Abstract: The present invention provides an optical unit for high-resolution applications all lenses in which are made of plastics. The optical unit includes lens (1) and (2). The lens (1) is a plastic lens having an Abbe number of 45-60. The lens (2) is a lens injection molded from a polycarbonate material comprising a structure derived from spirobiindan and having a glass transition temperature of 120-150° C.Type: GrantFiled: August 16, 2005Date of Patent: September 1, 2009Assignee: FUJIFILM CorporationInventors: Fumiyuki Suzuki, Noriko Eiha
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Patent number: 7579404Abstract: Disclosed are a cycloolefin resin molded product having excellent flame retardance and a polymerizable composition used for producing such a molded-product. A polymerizable composition comprising the cycloolefin monomer, a flame retardant and a metathesis polymerization catalyst is characterized in that a monomer having a condensed ring formed of an aliphatic ring having one or more carbon-carbon double bonds and a ring with aromatic characteristics is used as the cycloolefin monomer. A molded product can be produced through bulk polymerization of this polymerizable composition.Type: GrantFiled: August 9, 2004Date of Patent: August 25, 2009Assignee: Zeon CorporationInventor: Tomoo Sugawara
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Publication number: 20090198030Abstract: The present invention relates to a stable storable composition for the chemical grafting of at least one filler comprising a hydroxyl group, onto a polymer. The composition according to the invention comprises at least one organic carboxylic acid comprising a carbon/carbon double bond that forms a resonance structure with the carbon/oxygen double bond of the carboxyl group, said composition being characterized in that it comprises a dispersing agent of the polyethylene oxide-based block polymer or copolymer type. The invention also relates to a process for chemical grafting of an organic acid onto a filler comprising at least one hydroxyl group, using said composition, so as to obtain a polymerizable liquid mixture.Type: ApplicationFiled: June 21, 2007Publication date: August 6, 2009Applicant: GTI PROCESSInventors: Hervé Farge, Jean-Claude Lapairy
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Patent number: 7569157Abstract: A rotted wood stabilizer composition is provided, the composition comprising: from about 75 to about 90 weight percent of a crosslinking polymer; from about 1.5 to about 0.5 to about 1.5 weight percent of a film forming agent, and from about 8 to about 15 weight percent water, and optionally further comprising a biocide and a defoamer. The composition preferably has a pH in the range of from about 2.8 to about 3.0. Further the composition preferably has a viscosity of between about 750 to about 1250 cps as measured on a BROOKFIELD RV viscometer (helipath on) with a #2 T/E spindle at about 12 rpm and about 25° C. The invention further provides for methods of manufacturing the composition, as well as for methods of repairing a rotted area of a wood component by applying the composition of the present invention.Type: GrantFiled: June 22, 2005Date of Patent: August 4, 2009Assignee: Hunt Holdings, Inc.Inventor: Van R. Foster
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Publication number: 20090178588Abstract: Pre-treatment compositions include organic liquids and cross-linking initiators. Pre-treatment compositions are included in ink sets that also include oil-based ink compositions. Oil-based ink compositions include organic liquids, unsaturated fatty materials having terminal polar functional groups, colorants, and metal salts. Methods for ink-jet printing use pre-treatment compositions and oil-based ink compositions.Type: ApplicationFiled: March 19, 2009Publication date: July 16, 2009Applicant: XEROX CORPORATIONInventors: Gregory J. Kovacs, Marcel P. Breton
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Publication number: 20090175921Abstract: The present invention relates to chain extenders, processes for their preparation and their use in the preparation of biocompatible biodegradable polyurethanes and polyurethane ureas for biomedical applications such as stents, scaffolds for tissue engineering.Type: ApplicationFiled: September 20, 2006Publication date: July 9, 2009Inventors: Pathiraja Arachchillage Gunatillake, Timothy Graeme Moore, Raju Adhikari
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Publication number: 20090176915Abstract: The present invention relates to microemulsions of immiscible fluids stabilized by reactive ionic liquid surfactant wherein the ionic liquid surfactant has a melting point less than 80° C. The invention also relates to composite materials comprising a copolymer of ethylenically reactive species, wherein one of the species is a reactive ionic liquid surfactant having a melting point less than 80° C., and wherein the material also comprises non-reactive Class I fluid. The invention further relates to methods for synthesizing the composite materials comprising preparing a microemulsion of immiscible Class I fluid and Class II fluid stabilized by reactive ionic liquid surfactant wherein the ionic liquid surfactant has a melting point less than 80° C., and polymerizing the microemulsion to form a composite material.Type: ApplicationFiled: March 22, 2007Publication date: July 9, 2009Inventors: Feng Yan, John Texter
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Publication number: 20090156743Abstract: The present invention discloses a nucleating microemulsion comprising nanovehicles, each comprising an amphiphilic shell surrounding a nucleating agent. The microemulsion is suitable for the delivery of the nucleating agents into a thermoplastic polymer, thereby allowing crystallization of the polymer.Type: ApplicationFiled: February 27, 2007Publication date: June 18, 2009Applicant: Yissum Research Development Company of the Hebrew University of JerusalemInventors: Nissim Garti, Abraham Aserin, Dima Libster
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Publication number: 20090030125Abstract: The present invention provides epoxy curing agent compositions comprising benzylated aminopropylated alkylenediamine compounds. Amine-epoxy compositions and articles produced from these amine-epoxy compositions are also disclosed.Type: ApplicationFiled: August 6, 2008Publication date: January 29, 2009Applicant: Air Products and Chemicals, Inc.Inventors: Gamini Ananda Vedage, Williams Rene Edouard Raymond, Michael Ian Cook, Robert Marjo Theodoor Rasing, Ellen Margaret O'Connell, Maw Lin Foo
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Publication number: 20090030127Abstract: The present invention provides a stabilizer containing, as a main component, a bisphenol monoester and a bisphenol-based compound, wherein the area of the bisphenol-based compound is 0.15 to 70 when the area of the bisphenol monoester is set to be 100 in a chromatograph obtained by liquid chromatography analysis of the stabilizer, a method of manufacturing the same, a thermoplastic polymer composition containing the stabilizer, as well as a stabilizer that can further improve the process stability of the thermoplastic polymer, as compared with the conventional one, by compounding the stabilizer into the thermoplastic polymer through a method of stabilizing the thermoplastic polymer using the stabilizer and a method of manufacturing the stabilizer.Type: ApplicationFiled: July 16, 2008Publication date: January 29, 2009Inventors: Ryoji Soma, Kenji Kimura, Masatsugu Akiba
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Publication number: 20090030159Abstract: The present invention provides epoxy curing agent compositions comprising alkylated aminopropylated alkylenediamine compounds. Amine-epoxy compositions and articles produced from these amine-epoxy compositions are also disclosed.Type: ApplicationFiled: August 6, 2008Publication date: January 29, 2009Applicant: AIR PRODUCTS AND CHEMICALS, INC.Inventors: Gamini Ananda Vedage, Williams Rene Raymond, Ellen Margaret O'Connell, Maw Lin Foo, Peter Andrew Lucas
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Publication number: 20080308765Abstract: The present invention relates to a process for preparing vinyl carboxylates, wherein a carboxylic acid is reacted with an alkyne compound in the presence of a catalyst which is selected from carbonyl complexes, halides and oxides of rhenium, of manganese, of tungsten, of molybdenum, of chromium and of iron and rhenium metal at a temperature of ?300° C. The process gives the desired vinyl esters with high yield.Type: ApplicationFiled: November 22, 2006Publication date: December 18, 2008Applicant: BASF SEInventors: Wolfgang Staffel, Roland Kessinger, Jochem Henkelmann
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Publication number: 20080287644Abstract: The present invention relates to a hardener for epoxy resins, which on the one hand contains a Michael adduct of a bifunctional amine and of an acrylic acid derivative and also an adduct from a epoxy and the bifunctional amine. The invention likewise relates to a method for hardening an epoxy resin by mixing of a not yet hardened epoxy resin with a Michael adduct of a bifunctional amine and of an acrylic acid derivative. Furthermore, purposes of use of the hardener according to the invention are provided.Type: ApplicationFiled: April 3, 2008Publication date: November 20, 2008Applicant: UPPC AGInventors: Marcus HUMMEL, Markus SCHROTZ
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Patent number: 7445728Abstract: The invention relates to mixtures for producing transparent plastic, which mixtures comprise: a) compounds of formulae (I) and (II), wherein R1 independently represents hydrogen or a methyl group, R2 independently represents a linear or branched, aliphatic or cycloaliphatic group or a substituted or unsubstituted aromatic or heteroaromatic group and m and n independently represent an integer ?0, with m+n>0, b) a prepolymer produced from polymethacrylate and alkyldithiols or polythiols, preferably HS—R3—SH (III), wherein R3 is the same or different from R2 and may have the definition of R2, and c) aromatic vinyl compounds.Type: GrantFiled: January 19, 2005Date of Patent: November 4, 2008Assignee: Roehm GmbH & Co. KGInventors: Bardo Schmitt, Patrik Hartmann
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Patent number: 7438830Abstract: The present invention relates to mixtures for preparing transparent plastics, encompassing a) a prepolymer prepared from compounds of the formula (I) and (II) ?where each R1, independently of the others, is hydrogen or a methyl radical, ?each R2, independently of the others, is a linear or branched, aliphatic or cycloaliphatic radical, or a substituted or unsubstituted aromatic or heteroaromatic radical, and each of m and n, independently of the other, is a whole number greater than or equal to 0, where m+n>0, and from compounds of the formula (III), or from alkyl dithiols or from polythiols, preferably HS—R3—SH (III) ?where R3, identical with or different from R2, can be as defined for R2, and b) at least one monomer (A) capable of free-radical polymerization and having at least 2 methacrylate groups, and c) aromatic vinyl compounds, such as styrene, and d) if appropriate, a monomer capable of free-radical polymerization and having at least two terminal olefinic groups whose reactivity differs, aType: GrantFiled: January 19, 2005Date of Patent: October 21, 2008Assignee: Roehm GmbH & Co. KGInventors: Bardo Schmitt, Patrik Hartmann
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Patent number: 7419619Abstract: The invention relates to mixtures for producing transparent plastics, comprising a) a prepolymer, produced from the compounds of formulae (I) and (II), wherein R1 independently represents hydrogen or a methyl group, R2 independently represents a linear or branched, aliphatic or cycloaliphatic group or a substituted or unsubstituted aromatic or heteroaromatic group and m and n independently represent an integer greater or equal 0, with m+1>0, and compounds of formula (III), alkyldithiols or polythiols, preferably HS—R3—SH (III), wherein R3 is equal or different from R2 and can have the meaning indicated in R2, and b) at least one radically polymerizable monomer (A) having at least two methacrylate groups and c) aromatic vinyl compounds, such as styrene and d) optionally a radically polymerizable monomer having at least two terminal olefinic groups that have different reactivity, and/or e) optionally at least one monomer (B) from the group of methacrylates, preferably 2-hydroxyethylmethacrylate.Type: GrantFiled: January 19, 2005Date of Patent: September 2, 2008Assignee: Roehm GmbH & Co. KGInventors: Bardo Schmitt, Patrik Hartmann
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Patent number: 7390430Abstract: Difunctional oxazoline resins, which may be produced in a convenient one-step reaction from an arylalkylene dinitrile by reaction with an amino alcohol, are used in compositions with an additional curable compound or resin containing one or more carbon to carbon double bonds. The composition can be cured to a thermoset material, the curing mechanism occurring by the zwitterion polymerization of the bisoxazoline resin with the resin containing the one or more carbon to carbon double bonds. The reaction occurs without the need for curing initiators.Type: GrantFiled: February 17, 2004Date of Patent: June 24, 2008Assignee: National Starch and Chemical Investment Holding CorporationInventors: Osama M. Musa, Ruzhi Zhang
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Patent number: 7323532Abstract: The present invention concerns a process for producing low-viscosity polyisocyanates or secondary products thereof, which carry activated, radiation-curable double bonds and can optionally also cure thermally, and low-viscosity polyisocyanate mixtures or secondary products thereof and their use in coating compounds.Type: GrantFiled: September 29, 2003Date of Patent: January 29, 2008Assignee: Bayer MaterialScience AGInventors: Thomas Fäcke, Jan Weikard, Wolfgang Fischer
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Patent number: 7160975Abstract: This invention relates to ethylenically unsaturated macromers which contain reactive unsaturation, and to a process for preparing these ethylenicallly unsaturated macromers which contain reactive unsaturation. The process of preparing these ethylenically unsaturated macromers comprises reacting a monofunctional compound which corresponds to a specific formula with at least one alkylene oxide, in the presence of at least one alkoxylation catalyst. The ethylenically unsaturated macromers correspond to the formula set forth herein. This invention also relates to preformed stabilizers comprising ethylenically unsaturated macromers, to a process for preparing these preformed stabilizers, to polymer polyols comprising these preformed stabilizers, and to a process of preparing these polymer polyols which comprise these preformed stabilizers. Polymer polyols comprising ethylenically unsaturated macromers and a process for their preparation are also described.Type: GrantFiled: August 2, 2004Date of Patent: January 9, 2007Assignee: Bayer MaterialScience LLCInventors: Rick L. Adkins, Scott A. Guelcher
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Patent number: 7125950Abstract: A solvent-free process for making a polyol fatty acid polyester composition useful for preparation of polyurethanes is described. These compositions are preferably made by reaction of a natural oil (from plant or animal) with a multi-functional hydroxyl compound derived from a natural source, such as sorbitol, in presence of an alkali metal salt or base such as potassium hydroxide as a catalyst which also acts to saponify the reaction mixture. The hydroxyl content of the prepared composition depends on the amount of the multi-functional hydroxyl compound used in the preparation. In another embodiment, the hydroxyl groups of these compositions are reacted with an isocyanate, such as the polymeric diphenylmethane diisocyanate (also known as 4,4?-diphenyl methane diisocyanate, or MDI) to form polyurethanes in a conventional manner.Type: GrantFiled: April 29, 2004Date of Patent: October 24, 2006Assignee: Board of Trustees of Michigan State UniversityInventors: Jean-Pierre L. Dwan'Isa, Lawrence T. Drzal, Amar K. Mohanty, Manjusri Misra
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Patent number: 7077977Abstract: A discrete polyolefin catalyst activator is disclosed. A salient feature of invention borate-based activators is that at least one of the ligands on the borate non-coordinating anion (NCA) comprises a fluorinated aryl group linked to the boron atom through an acetylenic group appropriate pairing of invention activators with olefin polymerization. Catalyst precursors yield increased catalytic activity. Polymerization results are disclosed.Type: GrantFiled: December 3, 2002Date of Patent: July 18, 2006Assignee: ExxonMobil Chemical Patents Inc.Inventors: George Rodriguez, Francis C. Rix, Matthew C. Kuchta, John F. Walzer, Jr.
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Patent number: 7071242Abstract: A process for the production of polyurethane di(meth)acrylates in which a diisocyanate component, a diol component and hydroxy-C2–C4-alkyl (meth)acrylate in the molar ratio x:(x?1):2 are reacted without solvent and without subsequent purification operations, wherein x means any desired value from 2 to 5, wherein 50 to 80 mol % of the diisocyanate component is formed by 1,6-hexane diisocyanate, and 20 to 50 mol % by one or two diisocyanates, each forming at least 10 mol % of the diisocyanate component and being selected from the group consisting of toluylene diisocyanate, diphenylmethane diisocyanate, dicyclohexylmethane diisocyanate, isophorone diisocyanate, trimethylhexane diisocyanate, cyclohexane diisocyanate, cyclohexanedimethylene diisocyanate and tetramethylenexylylene diisocyanate, wherein the mol % of the respective diisocyanates add up to 100 mol %, wherein the diol component comprises no more than four different diols, and 20 to 100 mol % of the diol component is formed by at least one linear aliphaType: GrantFiled: October 13, 2004Date of Patent: July 4, 2006Assignee: E. I. duPont de Nemours and CompanyInventors: Carmen Flosbach, Stefanie Matten
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Patent number: 7019042Abstract: A novel thixotropic agent comprising urea crystals which comprises at least one compound containing at least one functional group having at least one bond which can be activated with actinic radiation; a novel process for preparing a thixotropic agent comprising urea crystals by reacting at least one primary and/or secondary amine and/or water with at least one polyisocyanate in a liquid organic medium consisting of or comprising at least one compound containing at least one functional group having at least one bond which can be activated with actinic radiation; and the use of the thixotropic agents to prepare coating materials, adhesives and sealing compounds curable thermally and with actinic radiation.Type: GrantFiled: August 22, 2001Date of Patent: March 28, 2006Assignee: BASF Coatings AGInventors: Ulrike Röckrath, Uwe Conring, Hurbert Baumgart, Ingrid Heid