Reactant Contains Ether Linkage Patents (Class 252/182.27)
  • Publication number: 20090281214
    Abstract: Disclosed are plasticizer compositions including cyclodextrin derivatives, a flexible PVC composition with suppression of the migration of a plasticizer containing the same, and a manufacturing method thereof. The manufacturing method of the flexible PVC composition of the present invention includes steps of (S1) preparing cyclodextrin derivatives; (S2) mixing the cyclodextrin derivatives, PVC and a low molecular weight liquid plasticizer to form a plastisol; and (S3) heating the plastisol to form a solution and cooling the solution. The manufacturing method of the present invention may be useful to mass-produce flexible PVC with suppression of the migration of a plasticizer in a simple and economic manner without using solvents since the cyclodextrin derivatives are used as a compound that can suppress the migration of a plasticizer The flexible PVC has an effect of reducing an amount of the migrated plasticizer without deterioration in its physical properties.
    Type: Application
    Filed: December 7, 2005
    Publication date: November 12, 2009
    Applicant: Seoul National University Industry Foundation
    Inventors: Seung-Yeop Kwak, Sung-Ho Kim, Seok-Bong Lee
  • Publication number: 20090281203
    Abstract: Biocomposite compositions and compositions, which include dried distillers solubles, and which can be used in making biocomposite compositions are described. Methods for preparing the compositions are also described.
    Type: Application
    Filed: May 14, 2009
    Publication date: November 12, 2009
    Inventors: Michael J. Riebel, Jeffrey L. Tate
  • Publication number: 20090258983
    Abstract: Disclosed are surfactant compositions comprising: (a) at least one alkoxylated glycol ether; and (b) at least one compound in accordance with Formula VII; where x is from about 1 to about 100, and each R4 is independently H or an alkyl moiety having from about 1 to about 2 carbon atoms, provided that the total number of carbon atoms within each x unit is not greater than about 8.
    Type: Application
    Filed: February 16, 2009
    Publication date: October 15, 2009
    Applicant: Cognis IP Management GmbH
    Inventors: Ana Maria Fernandez, Michael Allen, Richard Crews, Loubna Jebbanema
  • Patent number: 7442325
    Abstract: This invention relates to a crosslinking composition comprising an organic acid and a compound having the structure of Formula I: A?-NRA—RD wherein A?, RA, and RD are defined in the specification. This invention also relates to a process for producing the crosslinking composition by reacting an amino compound containing amino groups; a mono(alkylaldehyde) and/or a poly(alkylaldehyde), and an alcohol; and adding an organic compound where said amino compound is selected from the group consisting of: triazine, linear or cyclic ureas, cyanuric acid, substituted cyanuric acids, linear or cyclic amides, glycolurils, hydantoins, linear or cyclic carba mates and mixtures thereof.
    Type: Grant
    Filed: September 29, 2004
    Date of Patent: October 28, 2008
    Assignee: Cytec Technology Corp.
    Inventors: Lon-Tang Wilson Lin, William Jacobs, III
  • Patent number: 7393465
    Abstract: A process for preparing hydrophobic polyols that includes reacting A) a mixture having an OH content of from 180 to 300 mg KOH/g, a viscosity at 23° C. of from 5000 to 20 000 mPas and an OH functionality of from 2.8 to 4.5 including from 5 to 20 wt. % of 3-pentadecadienylphenol, from 5 to 10 wt. % of 3-pentadecadienyl-recorcinol and from 1 to 5 wt. % of 2-methyl 3-pentadecadienylrecorcinol; with B) alkylene oxides (AO) with addition of the AO monomers onto the AO-reactive groups of component A); the ratio of the amounts of A) to B) being from 1:9 to 9:1; where the hydrophobic polyols have an OH number of from 140 to 220 mg KOH/g and a viscosity at 23° C. of from 1000 to 4000 mPas. The hydrophobic polyols can be used in polyurethane systems, in coatings, adhesive bonds, sealants or moulding compounds, which can be used to coat substrates.
    Type: Grant
    Filed: February 24, 2005
    Date of Patent: July 1, 2008
    Assignee: Bayer MaterialScience AG
    Inventors: Meike Niesten, Jack Reese, Joachim Simon, Gerhard Ruttmann
  • Patent number: 7381347
    Abstract: This invention relates to a crosslinking composition comprising a compound having the structure of Formula I: A?-NRA—RD where A? is a moiety derived from the group consisting of linear or cyclic ureas, cyanuric acid, substituted cyanuric acids, linear or cyclic amides, glycolurils, hydantoins, linear or cyclic carbamates and mixtures thereof, or a moiety comprising the structure: where RA is RD, hydrogen, an alkyl of 1 to 20 carbon atoms, or taken together with A? forms a cyclic compound; RD is —CHRC ORB, wherein RB is hydrogen, alkyl, aryl, aralkyl or an alkaryl having from 1 to about 24 carbon atoms and RC is an alkyl, halogenated alkyl, aryl, aralkyl, halogenated aralkyl, alkoxyalkyl or an alkaryl having from 1 to about 24 carbon atoms; A is a moiety derived from the group consisting of linear or cyclic ureas, cyanuric acid, substituted cyanuric acids, linear or cyclic amides, glycolurils, hydantoins, linear or cyclic carbamates and mixtures thereof; B is a residue of a poly(alkylaldehyde) with n al
    Type: Grant
    Filed: March 31, 2003
    Date of Patent: June 3, 2008
    Assignee: Cytec Technology Corp.
    Inventors: William Jacobs, III, Lon-Tang W. Lin
  • Patent number: 7323119
    Abstract: The present invention relates to the color stabilization of hydroquinone hydroxyethyl ethers by phosphite compounds containing the bis-cyclic structure of spiro phosphites, both rings being attached to the same tertiary carbon atom in the phosphite molecule.
    Type: Grant
    Filed: October 26, 2005
    Date of Patent: January 29, 2008
    Assignee: Arch Chemicals, Inc.
    Inventors: Jayne Mallwitz, Robert C. Hire, Kiran B. Chandalia
  • Patent number: 7262227
    Abstract: The present invention relates to a process for producing a synthetic resin foam which comprises reacting at least one polyol with at least one polyisocyanate compound in the presence of an organic blowing agent, wherein the organic blowing agent is a blowing agent for synthetic resin foams which is characterized by being a mixture comprising 1,1,1,3,3-pentafluorobutane (HFC-365mfc) and at least one halogen-containing compound and optionally containing at least one member selected from the group consisting of glycol compounds and amide compounds. Also provided are: a premix comprising the blowing agent and a polyol mixture; and a process for producing a synthetic resin foam from these.
    Type: Grant
    Filed: April 25, 2003
    Date of Patent: August 28, 2007
    Assignee: Daikin Industries, Ltd.
    Inventors: Takashi Shibanuma, Noriaki Shibata
  • Patent number: 7157444
    Abstract: Therapeutic 5-aminosalicylic acid derivative compositions having general formula (I), wherein R is a 1-deoxy sugar residue or a poly(ethylene glycol) chain-containing residue, are provided. The compositions enable topical delivery of 5-aminosalicylic acid to the gastrointestinal tract following oral administration in pharmaceutical preparations.
    Type: Grant
    Filed: October 18, 2003
    Date of Patent: January 2, 2007
    Inventor: Deanna Jean Nelson
  • Patent number: 7135525
    Abstract: The present invention relates to a sinter powder composed of polyamide which also comprises PMMI, PMMA, or copolymers with PMMI, in particular PMMI-PMMA copolymers, to the use of this sinter powder for laser-sintering, and also to moldings produced from this sinter powder. The moldings made from the powder of the invention have marked advantages over conventional products in their appearance and in their surface quality, especially as far as roughness and dimensional stability during selective laser sintering (SLS) are concerned. In addition, moldings produced from the sinter powder of the invention also have better mechanical properties than moldings based on conventional nylon-12 powders, in particular in terms of modulus of elasticity and tensile strength. These moldings also have a density close to that of injection moldings.
    Type: Grant
    Filed: March 15, 2004
    Date of Patent: November 14, 2006
    Assignee: Degussa AG
    Inventors: Christoph Petter, Maik Grebe, Sylvia Monsheimer, Franz-Erich Baumann
  • Patent number: 7094357
    Abstract: A compatibilizing agent is described for a mixture of (1) a polyester polyol containing units derived from at least one aliphatic dicarboxylic acid (A) having n carbon atoms (10?n?20) and at least one aliphatic diol having k carbon atoms (2?k?12) and (2) a polyester polyol containing units derived from at least one aliphatic dicarboxylic acid (B) having m carbon atoms (2?m?9) and at least one aliphatic diol having k carbon atoms (2?k?12), the compatibilizing agent containing a polyester polyol which contains units derived from at least one aliphatic dicarboxylic acid (A) having n carbon atoms (10?n?20), at least one aliphatic dicarboxylic acid (B) having m carbon atoms (2?m?9), and at least one aliphatic diol having k carbon atoms (2?k?12) and in which the ratio of ingredient (A) to ingredient (B) used is from 90:10 to 10:90 in terms of molar ratio (provided that n-m?4).
    Type: Grant
    Filed: December 16, 2002
    Date of Patent: August 22, 2006
    Assignee: UBE Industries, Ltd.
    Inventors: Hideki Ichihashi, Yukio Kaneko
  • Patent number: 7087657
    Abstract: The present invention relates to polyol dispersions with long-term stability, to cellular polyurethane moldings produced therewith, to processes for their preparation and to their use.
    Type: Grant
    Filed: December 15, 2003
    Date of Patent: August 8, 2006
    Assignee: Bayer Aktiengesellschaft
    Inventors: Peter Haas, Alfred Neuhaus
  • Patent number: 7022257
    Abstract: A floor coating composition containing one or more unsaturated urethane compounds, which is(are) obtained from an isocyanate compound(s) and a hydroxyl compound(s) as starting materials, wherein at least one of the isocyanate compound(s) and the hydroxyl compound(s) has an unsaturated bond(s), wherein the poly(alkyleneoxy) group content (as defined in the specification) is 2–16 wt % and the proportion of the number of the unsaturated bonds (as defined in the specification) is not less than 6, can form a coating film superior in staining resistance against extremely powerful staining substances and gloss retentivity against extremely great load from walking, and which permits easy polishing away of damages and color stain, as well as use of water as a solvent. When a coating object is covered with a film made from the composition, a coated material can be obtained, wherein warpage of a coating object (floor, floor material, plastic film and the like) and cracks in the film are suppressed.
    Type: Grant
    Filed: October 11, 2000
    Date of Patent: April 4, 2006
    Assignees: Shin-Nakamura Chemical Co., Ltd., GEN Maintenance Technology Inc.
    Inventors: Masaji Ohkido, Yoji Tominaga, Ryo Imami
  • Patent number: 7022767
    Abstract: The present invention provides a composition of matter having the structure: where Q is a multi-valent organic moiety containing isocyanurate functionality; X is H, —CH2OH, or —CH2OR?; R? is an alkyl or aryl group having from 1 to 12 carbon atoms; and y is at least 2. Also provided is a curable composition containing the composition of matter.
    Type: Grant
    Filed: February 5, 2004
    Date of Patent: April 4, 2006
    Assignee: PPG Industries Ohio, Inc.
    Inventors: Michael A. Mayo, Steven V. Barancyk, Jane N. Valenta, Sherry M. Gaggini, William A. Humphrey
  • Patent number: 6994804
    Abstract: The present invention relates to the color stabilization of hydroquinone hydroxyethyl ethers by phosphite compounds containing the bis-cyclic structure of spiro phosphites, both rings being attached to the same tertiary carbon atom in the phosphite molecule.
    Type: Grant
    Filed: June 30, 2004
    Date of Patent: February 7, 2006
    Assignee: Arch Chemicals, Inc.
    Inventors: Jayne Mallwitz, Robert C. Hire, Kiran B. Chandalia
  • Patent number: 6946497
    Abstract: Process for preparing a visco-elastic polyurethane foam by reacting a polyisocyanate composition with a polyol composition comprising b1) an EO-rich polyol; b2) a polyol with an EO content between 20-50% and a primary hydroxy content of at least 50%; b3) a polyol with an EO content between 10-20% and a primary hydroxy content of at least 50%; and b4) a polyoxyalkyleneglycol. Further provided is a polyol composition.
    Type: Grant
    Filed: October 27, 2003
    Date of Patent: September 20, 2005
    Assignee: Huntsman International LLC
    Inventor: Jianming Yu
  • Patent number: 6911503
    Abstract: An epoxy resin composition comprising an epoxy resin (A), a curing agent (B) and a curing accelerator (C), wherein the curing agent (B) is a phenol compound having two or more hydroxyl functional groups or a compound obtained by esterification of the phenol compound or a mixture of these compounds, and the curing accelerator (C) is a salt of a phosphazenium compound represented by a formula (I): (wherein R1s each represent a hydrogen atom, a linear, branched or cyclic alkyl group having 1 to 10 carbon atoms or an aryl or aralkyl group having 6 to 10 carbon atoms and may be all the same or different from one another; and Z? represents a halogen anion, hydroxy anion, alkoxy anion, aryloxy anion or carboxy anion).
    Type: Grant
    Filed: September 27, 2002
    Date of Patent: June 28, 2005
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Sunao Maeda, Tatsuhiro Urakami, Tomoyuki Kawabata, Koutarou Suzuki, Tadahito Nobori
  • Patent number: 6906110
    Abstract: In a process for producing polyurethanes by reacting at least one polyisocyanate with at least one compound containing at least two hydrogen atoms which are reactive toward isocyanate groups, the compound having at least two active hydrogen atoms which is used is at least one polyether alcohol prepared by addition of alkylene oxides onto H-functional initiator substances by means of multimetal cyanide catalysis and the reaction is carried out in the presence of at least one metal salt.
    Type: Grant
    Filed: November 4, 2000
    Date of Patent: June 14, 2005
    Assignee: BASF Aktiengesellschaft
    Inventors: Reinhard Lorenz, Stephan Bauer, Dieter Junge, Eva Baum, Kathrin Harre, Jörg Erbes, Thomas Ostrowski, Georg Heinrich Grosch
  • Patent number: 6881783
    Abstract: Process for preparing a polyol comprising particulate material is dispersed from and in an amount 30-80% by weight.
    Type: Grant
    Filed: May 5, 2000
    Date of Patent: April 19, 2005
    Assignee: Huntsman International LLC
    Inventors: Gabriel A Verhelst, Alphonse E J Bruyninckx
  • Patent number: 6869543
    Abstract: Clear, amine-initiated polyether polyols are made by epoxidizing an amine in the presence of an alkali metal hydroxide catalyst. By reducing the amount of catalyst used during the polyol synthesis and by adding the catalyst after between 5 and 30% of the total amount of at least one alkylene oxide has been added, after lactic acid neutralization, gives a short chain polyol that has foam processing characteristics similar to the conventional sulfuric acid neutralized polyol. The polyols produced in this manner are particularly useful for the production of polyurethane and polyisocyanurate foams.
    Type: Grant
    Filed: February 21, 2003
    Date of Patent: March 22, 2005
    Assignee: Bayer Polymers LLC
    Inventors: Nathan L. Anderson, Karl W. Haider, Keith J. Headley, Kerry A. Ingold, Herman P. Doerge
  • Patent number: 6855844
    Abstract: Disclosed are polyester-ether polyols and their use in urethane prepolymers, urethane foams and non-foam urethane coatings, adhesives, sealants and/or elastomers. Methods for producing such polyester-ether polyols using double metal cyanide catalysts are disclosed, along with methods for producing urethane prepolymers. The polyester-ether polyols of the instant invention are preferably the reaction product of phthalic anhydride, diethylene glycol, and propylene oxide. These polyester-ether polyols are useful as either the primary polyol in urethane compositions or in combination with conventional auxiliary polyester- and/or polyether-based polyols. The polyester-ether polyols impart greatly improved solubility and compatibility to mixtures of either polyether and/or polyester polyols. The polyester-ether polyols of the instant invention are desirably of lower viscosity than their precursor intermediate polyester polyols and are generally soluble in either polyester- and/or polyether-based polyols.
    Type: Grant
    Filed: October 25, 2000
    Date of Patent: February 15, 2005
    Assignee: Stepan Company
    Inventors: Eric J. Geiger, Douglas K. Hillshaffer
  • Patent number: 6835325
    Abstract: A crosslinking agent containing a polyallyl ether compound having at least one hydroxyl group derived from a glycidyl group and at least two allyl groups can be used for the production of a highly water-absorbing polymer comprising a polymerizable compound having a carbon-carbon double bond or a salt thereof, has a high solubility in aqueous solution of the monomer and gives a highly water-absorbing polymer having water absorptivity required at practical levels.
    Type: Grant
    Filed: April 19, 2002
    Date of Patent: December 28, 2004
    Assignee: Daiso Co., Ltd.
    Inventors: Shin-ichiro Nakamura, Yasumi Shimizu, Tohru Matsutomi
  • Patent number: 6830705
    Abstract: The invention relates to liquid stable MDI prepolymers and curative systems which are suitable for room temperature casting and which yield high performance low-shrinkage urethane elastomers upon room-temperature curing, the prepolymer and curative components, the elastomers themselves, and separately packaged prepolymer component and its complementary curative component provided as a single unit or kit.
    Type: Grant
    Filed: June 14, 2000
    Date of Patent: December 14, 2004
    Assignee: AZON USA Inc.
    Inventors: Gerard Scott Freeland, James E. Doyle
  • Patent number: 6831112
    Abstract: The present invention relates to polyether compounds, active hydrogen compounds and resin-forming compositions composed of the polyols, and methods for producing foams by employing the active hydrogen components. These polyether compounds have a decreased number of moles of added EO thereby maintaining the hydrophobicity and have sufficient reactivity as polyol components of resins, thereby having high reaction rates. Therefore, it is possible to provide resins having excellent resin properties (tensile strength, flexural strength, water-absorption swelling ratio, etc.).
    Type: Grant
    Filed: May 24, 2002
    Date of Patent: December 14, 2004
    Assignee: Sanyo Chemical Industries, Ltd.
    Inventors: Motonao Kaku, Hidefumi Ohta, Hideo Kitagawa, Kenji Nishiyama, Munekazu Satake, Kunikiyo Yoshio, Koji Tsutsui
  • Patent number: 6824703
    Abstract: A polyol composition having a number average molecular weight of from about 1,000 to about 3,000 Daltons is made up of (1) at least 60% by weight of a low monol polyoxypropylene polyol having a number average molecular weight of from about 2,000 to 12,000 Da and a degree of unsaturation less than or equal to 0.02 meq/g and (2) no more than 40% by weight of a polyol having a number average molecular weight of from about 400 to about 1,000 Da and a polydispersity index greater than 1.1. This polyol composition is reacted with a diisocyanate, a polyisocyanate, an isocyanate-terminated prepolymer or an isocyanate-terminated quasi-prepolymer to produce polyurethane elastomers having good physical and mechanical properties. Any of the known processes for producing polyurethane elastomers, including one-shot processes, may be used to produce elastomers in accordance with the present invention.
    Type: Grant
    Filed: March 8, 2002
    Date of Patent: November 30, 2004
    Assignee: Bayer MaterialScience LLC
    Inventors: Bruce D. Lawrey, Kurt C. Frisch, Nigel Barksby
  • Patent number: 6790820
    Abstract: The present invention provides compositions comprising an HFC component and a non-HFC component consisting essentially of methanol, having boiling points that are unexpectedly low and relatively constant, and uses thereof.
    Type: Grant
    Filed: June 3, 2002
    Date of Patent: September 14, 2004
    Assignee: Honeywell International, Inc.
    Inventors: Mary C. Bogdan, Gary M. Knopeck, Hang T. Pham, Rajiv R. Singh, Kane D. Cook
  • Patent number: 6787575
    Abstract: The invention relates to the technological sector of mineral fillers used in the sector which manufactures polyurethane foams and in particular fillers of the carbonate, hydroxide, silicate, sulphate type and similar mineral fillers. The invention relates in particular to a method of treating mineral fillers of a specific grain size with the aid of treatment agents of the organic phosphate type, incorporating a de-agglomeration step, and optionally a selection step, with a view to improving the techniques used to manufacture polyurethane foams either by foaming without an auxiliary blowing agent or with a blowing agent such as CO2, and composite polyurethane, whilst reducing the time needed to mix this treated filler treated with the polyol and other reagents. Numerous applications for block foams or moulded foams, for mattresses and similar, the automotive industry, various industrial components, etc . . .
    Type: Grant
    Filed: May 14, 2001
    Date of Patent: September 7, 2004
    Assignee: Omya SA
    Inventors: Jean Pierre Fichou, Maurice Husson, Georges Ravet, Pierre Blanchard
  • Patent number: 6776925
    Abstract: The present invention relates to a process for the production of polyether polyols by polyaddition of alkylene oxides onto starter compounds containing active hydrogen atoms conducted in the presence of a double-metal cyanide catalyst wherein a reaction mixture is guided at least once through a zone which has an energy density of at least 105 J/m3 and wherein the residence time of the reaction mixture in this zone is at least 10−6 seconds per pass.
    Type: Grant
    Filed: February 19, 2002
    Date of Patent: August 17, 2004
    Assignees: Bayer Aktiengesellschaft, Bayer Polymers LLC
    Inventors: Jörg Hofmann, Stephan Ehlers, Bernd Klinksiek, Lars Obendorf, Christian Steinlein, Bert Klesczewski, Jose F. Pazos
  • Patent number: 6777382
    Abstract: The present invention provides compositions comprising an HFC component and a non-HFC component consisting essentially of methanol, having boiling points that are unexpectedly low and relatively constant, and uses thereof.
    Type: Grant
    Filed: June 3, 2002
    Date of Patent: August 17, 2004
    Assignee: Honeywell International Inc.
    Inventors: Mary C. Bogdan, Kane D. Cook, Hang T. Pham, Gary M. Knopeck, Rajiv R. Singh
  • Patent number: 6770684
    Abstract: The present invention relates to a process for the production of flexible polyurethane foams by reaction of a) at least one compound having at least two isocyanate-reactive hydrogen atoms, with b) polyisocyanates, wherein the compund used as said compound having at least two isocyanate-reactive hydrogen atoms a) comprises at least one block polyoxypropylene/polyoxyethylene/polyol having a hydroxyl value of from 25 to 45 mg KOH/g and a content of terminally bound ethylene oxide units of from 15 to 17 wt %, based on the total amount of the alkylene oxide, obtained by attachment of ethylene oxide and propylene oxide to an initiator having an average functionality of 3.
    Type: Grant
    Filed: March 12, 2002
    Date of Patent: August 3, 2004
    Assignee: BASF Aktiengesellschaft
    Inventors: Heinz-Dieter Lutter, Bernd Bruchmann, Klaus Wagner, Jens Müller
  • Patent number: 6756414
    Abstract: This invention provides a polymer polyol composition (I) comprising a polyol (A) and polymer particles (B) dispersed in (A), the polymer particles (B) being formed by polymerizing an ethylenically unsaturated compound (b) in a polyol, wherein the content of (B) in (I) is from 35 to 75 mass %, based on the mass of (I), and the amount of soluble polymers (P) dissolved in (A) is not more than 5 mass %, based on the mass of (A), and provides methods for producing the polymer polyol composition (I). Further, this invention provides a method for producing a foamed or non-foamed polyurethane resin, which method comprises reacting a polyol component with a polyisocyanate component in the presence or absence of a blowing agent, wherein the above polymer polyol composition is used at least as a portion of the polyol component.
    Type: Grant
    Filed: June 17, 2003
    Date of Patent: June 29, 2004
    Assignee: Sanyo Chemical Industries, Ltd.
    Inventors: Tetsuji Kawamoto, Tomio Kawazoe, Kiyoshi Ikeda, Munekazu Satake, Futoshi Kitatani, Tsuyoshi Tomosada, Takeshi Furuta, Takayuki Tsuji
  • Patent number: 6753402
    Abstract: Polyester-polyether block copolymers can be prepared by catalytic addition of alkylene oxides onto H-functional initiator substances, using polyester alcohols as H-functional initiator substances and multimetal cyanide compounds as catalysts.
    Type: Grant
    Filed: April 10, 2002
    Date of Patent: June 22, 2004
    Assignee: BASF Aktiengesellschaft
    Inventors: Stephan Bauer, Georg Heinrich Grosch, Gerlinde Tischer, Kathrin Harre, Eva Baum, Thomas Ostrowski, Reinhard Lorenz, Regina Pretzsch, Michael Pcolinski, Stefan Dinsch, Inge Rotermund
  • Patent number: 6740686
    Abstract: The invention concerns a method for making a polyurethane foam by reacting at least a polyester polyol with at least a polyisocyanate in the presence of a foaming agent and a catalytic agent, such a polyester polyol having been previously obtained by reacting a reactive acid A comprising at least an aliphatic or aromatic polyacid with functionality not less than 2 with at least a polyol P2 with functionality equal to 2 and at least an aliphatic or aromatic polyacid with functionality not less than 2 with at least a polyol P2 with functionality equal to 2 and at least a polyol P3 with functionality not less than 3, being thereafter called AP2P3, wherein the catalytic agent at least partly consists of at least one amine polyester polyol AP2P3, wherein at least part of polyol P3 consists of at least a polyoxyalkylene polyalkanolamine having at least a tertiary amine function, the alkanol radicals of said polyalkanolamine being C1-C6, the alkylene oxide units being C2-C4 and the statistical mean of the number N o
    Type: Grant
    Filed: November 27, 2000
    Date of Patent: May 25, 2004
    Assignee: Crompton Corporation
    Inventors: Denis Ghesquiere, Remy Dumont
  • Patent number: 6710096
    Abstract: Polyols initiated with a first initiator having a relatively high functionality averaging greater than eight and comprising a range of species of different functionality, and optionally a second initiator, having low functionality, i.e. a two to eight nominal functionality initiator molecule. Another aspect of the invention is a process for making the polyol. The invention is also directed to a process for producing polyurethane foam by reacting the polyol of the invention with isocyanates, and the foam produced thereby.
    Type: Grant
    Filed: July 22, 2002
    Date of Patent: March 23, 2004
    Assignee: BASF Corporation
    Inventors: Raymond A. Neff, Duane A. Heyman
  • Patent number: 6710095
    Abstract: A polyol composition containing a polyester polyol, at least 5 weight % of a compatibilizing agent, based on the weight of the polyol and compatibilizing agent, and a hydrocarbon blowing agent. The compatibilizing agent is one or a combination of a benzoate glycol adduct, a substituted benzoate glycol adduct, a naphthenate glycol adduct, a substituted naphthenate glycol adduct, a toluate glycol adduct, or a substituted toluate glycol adduct. The hydrocarbon blowing agent is selected from cyclopentane, isopentane, n-pentane, 2-chloropropane; 1,1,1,2-tetrafluoroethane (HFC-134a); 1,1,1,3,3-pentafluoropropane (HFC-245fa); and n-propylbromide, or mixtures thereof. The compatibilizing agent improves the miscibility of conventional polyester polyols with hydrocarbon blowing agents. The polyol composition can be reacted with a polyisocyanate to form a foam.
    Type: Grant
    Filed: January 16, 2003
    Date of Patent: March 23, 2004
    Assignee: Arteva North America S.A.R.L.
    Inventors: Carina Araullo-McAdams, John Canaday, Kelly Brown
  • Patent number: 6670406
    Abstract: The present invention relates to a process for the production of a polyether polyol by polyaddition of an alkylene oxide onto a starter compound containing active hydrogen atoms conducted in the presence of a double metal cyanide catalyst comprising conducting a reaction mixture at least once through a zone which has an energy density of at least 5×106 J/m3, wherein the dwell time of the reaction mixture in this zone is at least 10−6 seconds per pass.
    Type: Grant
    Filed: February 19, 2002
    Date of Patent: December 30, 2003
    Assignees: Bayer Aktiengesellschaft, Bayer Polymers LLC
    Inventors: Jörg Hofmann, Stephan Ehlers, Bernd Klinksiek, Bert Klesczewski, Christian Steinlein, Lars Obendorf, Harald Pielartzik, Jose F. Pazos
  • Patent number: 6624209
    Abstract: This invention provides a polymer polyol composition (I) comprising a polyol (A) and polymer particles (B) dispersed in (A), the polymer particles (B) being formed by polymerizing an ethylenically unsaturated compound (b) in a polyol, wherein the content of (B) in (I) is from 35 to 75 mass %, based on the mass of (I), and the amount of soluble polymers (P) dissolved in (A) is not more than 5 mass %, based on the mass of (A), and provides methods for producing the polymer polyol composition (I). Further, this invention provides a method for producing a foamed or non-foamed polyurethane resin, which method comprises reacting a polyol component with a polyisocyanate component in the presence or absence of a blowing agent, wherein the above polymer polyol composition is used at least as a portion of the polyol component.
    Type: Grant
    Filed: February 6, 2002
    Date of Patent: September 23, 2003
    Assignee: Sanyo Chemical Industries, Ltd.
    Inventors: Tetsuji Kawamoto, Tomio Kawazoe, Kiyoshi Ikeda, Munekazu Satake, Futoshi Kitatani, Tsuyoshi Tomosada, Takeshi Furuta, Takayuki Tsuji
  • Patent number: 6599952
    Abstract: This invention relates to a process for the preparation an epoxide-reactive compound having a functionality of at least 3, a molecular weight of from about 250 to about 1,900, and an OH number of from about 85 to about 1,400. This process comprises reacting (a) an organic compound which is free of ether groups, having a molecular weight of from about 60 to about 600, and containing from about 2 to about 8 reactive sites; with (b) cyanuric chloride; optionally, in the presence of (c) one or more catalysts; wherein the functionality of the resultant epoxide-reactive compound equals three times the functionality of (a) said organic compound minus three. This invention also relates to further reacting the epoxide-reactive compound produced by the above process with an alkylene oxide, optionally in the presence of a catalyst to form a polyether polyol having a functionality of at least about 3, a molecular weight of from about 300 to about 18,000, and an OH number of from about 10 to about 565.
    Type: Grant
    Filed: December 13, 2001
    Date of Patent: July 29, 2003
    Assignee: Bayer Corporation
    Inventors: Rick L. Adkins, Harold R. Parsons
  • Publication number: 20030134919
    Abstract: The invention is directed to polyurethane foam shoe soles containing an additive comprising a mixture of polyethylene wax and PTFE (polytetrafluoroethylene), and to polyol components containing the additive. The additive is produced to include the mixture at a density from greater than 0.97 to about 1.1 times the density of the polyol component.
    Type: Application
    Filed: December 21, 2001
    Publication date: July 17, 2003
    Inventors: Gary Brant, Dragoljub Todoroski
  • Patent number: 6590008
    Abstract: The invention relates to a polyol composition comprising by weight 60-97% of b1) a polyoxyethylene-polyoxypropylene polyol, having a functionality of 2-6, with 10-25% tipped EO, 3-40% of b2) a polyoxyethylene-polyoxypropylene polyol, having a functionality of 2-6, with 20-50% total EO and 10-20% tipped EO; and 0-25% of b3) a polyol, having a functionality of 2-6, with at least 50% random EO. The invention also relates to a process for preparing a flexible polyurethane foam by reacting a) a polyisocyanate composition; b) a polyol composition of the invention; c) water; and d) additives and auxiliaries known per se. The invention finally relates to a reaction system comprising A) a polyisocyanate and B) an isocyanate-reactive component comprising the polyol of the invention.
    Type: Grant
    Filed: March 1, 2002
    Date of Patent: July 8, 2003
    Assignee: Huntsman International LLC
    Inventors: Alain Parfondry, Jianming Yu
  • Patent number: 6586490
    Abstract: The present invention relates to polyol mixtures which are suitable for the preparation of rigid polyurethane foams and comprise addition products of alkylene oxide on aromatic di- or polyamines, and rigid foams prepared with these polyol mixtures.
    Type: Grant
    Filed: October 10, 2001
    Date of Patent: July 1, 2003
    Assignee: Bayer Aktiengesellschaft
    Inventors: Karl-Werner Dietrich, Torsten Heinemann, Manfred Dietrich
  • Patent number: 6569352
    Abstract: Disclosed are polyester-ether polyols and their use in urethane prepolymers, urethane foams and non-foam urethane coatings, adhesives, sealants and/or elastomers. Methods for producing such polyester-ether polyols are disclosed, along with methods for producing urethane prepolymers. The polyester-ether polyols of the instant invention are preferably the reaction product of phthalic anhydride, diethylene glycol, and propylene oxide. These polyester-ether polyols are useful as either the primary polyol in urethane compositions or in combination with conventional auxiliary polyester- and/or polyether-based polyols. The polyester-ether polyols impart greatly improved solubility and compatibility to mixtures of either polyether and/or polyester polyols. The polyester-ether polyols of the instant invention are desirably of lower viscosity than their precursor intermediate polyester polyols and are generally soluble in either polyester- and/or polyether-based polyols.
    Type: Grant
    Filed: October 25, 1999
    Date of Patent: May 27, 2003
    Assignee: Stepan Company
    Inventors: Douglas K. Hillshafer, George Magnus
  • Patent number: 6569981
    Abstract: This invention relates to crystallizing polyether polyols which can be produced firstly by the reaction of propylene oxide and polyhydroxy compounds in the presence of an alkoxy compound which contains zinc and/or aluminium atoms to form a crystallizing polyether polyol with an average molecular weight Mn from 500 to 5000, followed by the further reaction of the crystallizing polyether polyol which is thus obtained with 10 to 90% by weight, with respect to the amount of crystallizing polyol, of an epoxide in the presence of a catalyst which does not polymerize propylene oxide stereospecifically, to form a crystallizing polyether polyol with an average molecular weight Mn from 1000 to 20,000. The invention further relates to a method for the production thereof and to the use thereof for the production of polyurethane materials, particularly polyurethane foams, polyurethane elastomers and polyurethane coatings.
    Type: Grant
    Filed: October 25, 2001
    Date of Patent: May 27, 2003
    Assignee: Bayer Aktiengesellschaft
    Inventors: Walter Schäfer, Jörg Hofmann, Pramod Gupta, Pieter Ooms
  • Publication number: 20030073764
    Abstract: Certain thermoplastic additives (combinations of clarifying and nucleating compounds) that induce simultaneously low clarity and high nucleation efficacy are provided. Such additives include combinations of certain bicyclic salts (which by themselves induce very high nucleation efficacy) and thermoplastic clarifying agents, including certain dibenzylidene sorbitol acetals and derivatives (hereinafter collectively referred to as “DBSs”)(which alone provide very low haze measurements and thus highly desirable clarity characteristics). In comparison, other types of standard thermoplastic nucleators, such as sodium benzoate and sodium 2,2′-methylene-bis-(4,6-di-tert-butylphenyl) phosphate provide relatively high peak crystallization temperatures, but do not combine synergistically with clarifiers, such as DBSs, to provide the same results as for the inventive combination of bicyclic salts and DBSs.
    Type: Application
    Filed: August 11, 2001
    Publication date: April 17, 2003
    Inventor: Xiaodong Edward Zhao
  • Patent number: 6548564
    Abstract: This invention relates to a process for the preparation of a polyether polyol having a functionality of at least about 3, a molecular weight of from about 560 to about 35,000 and an OH number of from about 10 to about 1,100. This process comprises reacting (a) a polyether polyol containing one or more ether groups, having a functionality of about 2 to about 8, a molecular weight of about 106 to about 12,000, and an OH number of about 28 to about 1,400, with (b) cyanuric chloride, optionally, in the presence of (c) one or more catalysts; wherein the functionality of the resultant polyether polyols equals three times the functionality of (a) said polyether polyol, minus three.
    Type: Grant
    Filed: December 13, 2001
    Date of Patent: April 15, 2003
    Assignee: Bayer Corporation
    Inventors: Rick L. Adkins, Harold R. Parsons
  • Patent number: 6541532
    Abstract: New, useful and surprisingly effective antiscorch compositions for utilization within polyurethane foam production methods which utilize very popular tertiary amine catalysts are provided. Such compositions require the presence of nominal yet effective amounts of organic cyclic ester materials. The ring systems of such materials appear to open during exposure to heat (during the curing process) and release carboxylic acids into the curing formulation. The tertiary amines become quenched by the carboxylic acids and thus do not exhibit heat destabilization. The resultant foams exhibit extremely low, if no, areas of excessive heating (i.e., scorch) and thus are substantially uniformly colored throughout. The processes and resultant foams are also contemplated within this invention.
    Type: Grant
    Filed: June 2, 2000
    Date of Patent: April 1, 2003
    Assignee: Milliken & Company
    Inventors: Mark E. Ragsdale, Sandy G. Belue
  • Patent number: 6538043
    Abstract: A process for the preparation of a co-initiated polyether polyol, which process comprises the steps of: (a) preparing a mixture of at least one aromatic initiator, at least one polyethylene glycol and optionally one or more aliphatic initiators, (b) reacting the mixture obtained in step (a) in the presence of a suitable alkoxylation catalyst with at least one alkylene oxide having three or more carbon atoms per molecule using such quantity of alkylene oxide that the polyether polyol obtained has a hydroxyl value in the range of from 150 to 400 mg KOH/g, and (c) recovering the co-initiated polyether polyol. The co-initiated polyether polyol is [very] suitable for the preparation of rigid polyisocyanurate-modified polyurethane foams. Such foams have a good flame retardancy.
    Type: Grant
    Filed: March 8, 2001
    Date of Patent: March 25, 2003
    Assignee: Shell Oil Company
    Inventors: Thomas Bronnum, Melis Hasselaar, Parminder Singh Sangha, Francoise Van Tiggelen
  • Patent number: 6534556
    Abstract: A formulated resin composition for producing a closed cell rigid polyisocyanate based foam is disclosed. The formulated resin composition for use in a polyurethane froth spraying system includes a hydrofluorocarbon blowing agent, a Mannich polyol, at least one additional polyol, a catalyst system, and a surfactant. The formulated resin composition has a hydroxyl content of at least 400 mg KOH/g and a polyurethane foam produced utilizing the formulated resin composition has a closed cell content of at least 90 percent. The formulated resin composition exhibits a zero ozone depleting potential and produces a polyurethane foam that cures faster than conventional sprayed polyurethane foams.
    Type: Grant
    Filed: February 20, 2001
    Date of Patent: March 18, 2003
    Assignee: BASF Corporation
    Inventors: Chris Lacarte, Greg Gardin, Thomas Harris
  • Patent number: 6531566
    Abstract: A polyoxyalkylene polyol or monool (I) of the general formula (1) below, in which not less than 40% of the terminally located hydroxyl-containing groups, namely —AO—H groups, are primary hydroxyl-containing groups of the general formula (2) below, or; a method of producing ring-opening polymerization products, by subjecting a heterocyclic compound to ring-opening addition polymerization with an active hydrogen-containing compound, using as a catalyst tris(pentafluorophenyl)borane, tris(pentafluorophenyl)aluminum, etc.
    Type: Grant
    Filed: March 7, 2001
    Date of Patent: March 11, 2003
    Assignee: Sanyo Chemical Industries, Ltd.
    Inventor: Munekazu Satake
  • Patent number: 6515036
    Abstract: A method of recovering a decomposition product from a polyurethane, the method comprising the steps of thermally decomposing a polyurethane into a liquid containing a polyol and a urea compound which is soluble in the polyol, and solids containing a urea compound which is insoluble in the liquid in the presence of a polyamine compound at a temperature of 120 to 250° C.; removing the solids; hydrolyzing the residue with water retained at a high temperature of 200 to 320° C. and a high pressure; and recovering the resulting polyamine and/or polyol.
    Type: Grant
    Filed: April 2, 2001
    Date of Patent: February 4, 2003
    Assignee: Mitsui Takeda Chemicals Inc.
    Inventors: Koichi Murayama, Katsuhisa Kodama, Takashi Kumaki