Chloroisocyanurate Patents (Class 252/186.35)
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Patent number: 11406595Abstract: The present invention is related to a mesoscale colloidal particle including a hydrophobe-rich core surrounded by hydrogen bonded outer shell. The outer shell includes water and at least one hydrotrope wherein the hydrotrope molecules form hydrogen bonds with water molecules. The invention is also related to an aqueous solution including at least one mesoscale colloidal particle as well as methods of making and using such mesoscale colloidal particles and their solutions.Type: GrantFiled: May 21, 2013Date of Patent: August 9, 2022Assignee: University of Maryland, College ParkInventors: Deepa Subramanian, Mikhail A. Anisimov
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Patent number: 11060048Abstract: The invention includes a solid rinse aid that is particularly designed for extrusion solid formation and which is effective for creating spotless surfaces after rinsing. According to the invention, application has identified the critical combination of solid surfactants, coupling agents, hydrotrope, and hardening agents that is acceptable in the extrusion process to create a solid. The hydrotrope includes one or more short-chain alkylbenzene and/or alkyl naphthalene sulfonates. The composition hardens quickly but not so quick as to negatively impact the extrusion process. The compositions may also be used to form pressed or cast solids.Type: GrantFiled: July 13, 2020Date of Patent: July 13, 2021Assignee: Ecolab USA Inc.Inventors: Janel Marie Kieffer, Katherine Molinaro, Gary Becker, Tobias Foster, Karina Labusga
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Patent number: 10745650Abstract: The invention includes a solid rinse aid that is particularly designed for extrusion solid formation and which is effective for creating spotless surfaces after rinsing. According to the invention, application has identified the critical combination of solid surfactants, coupling agents, hydrotrope, and hardening agents that is acceptable in the extrusion process to create a solid. The hydrotrope includes one or more short-chain alkylbenzene and/or alkyl naphthalene sulfonates. The composition hardens quickly but not so quick as to negatively impact the extrusion process. The compositions may also be used to form pressed or cast solids.Type: GrantFiled: January 9, 2019Date of Patent: August 18, 2020Assignee: Ecolab USA Inc.Inventors: Janel Marie Kieffer, Katherine Molinaro, Gary Becker, Tobias Foster, Karina Labusga
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Patent number: 10584823Abstract: A method includes transporting water containing chlorine dioxide, chlorine, chloramines, or hypochlorites through a pipe. The method includes forming a polyethylene resin using a catalyst, mixing the polyethylene resin with an antioxidant, wherein the antioxidant is a thioester, a hindered amine light stabilizer or 1,3,5-trimethyl-2,4,6-tris (3,5-di-tert-butyl-4-hydroxybenzyl) benzene to form a resin/antioxidant mixture, extruding pipe from the resin/antioxidant mixture, and flowing water containing chlorine dioxide, chlorine, chloramines, or hypochlorites through the pipe. An extruded article is adapted for use in containment and/or transport of water that contains chlorine dioxide, chlorine, chloramines, or hypochlorites. The extruded article includes a polyethylene resin and an antioxidant. The antioxidant is a thioester, a hindered amine light stabilizer or 1,3,5-trimethyl-2,4,6-tris (3,5-di-tert-butyl-4-hydroxybenzyl) benzene.Type: GrantFiled: June 10, 2015Date of Patent: March 10, 2020Assignee: FINA TECHNOLOGY, INC.Inventors: William J Gauthier, Crystal Bryson, Diana Nash, Lu Ann Kelly, Jason Clark, Ruby Curtis, Toby Stevens
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Patent number: 8975257Abstract: Disclosed are methods for making aldehydes and ketones comprising allowing the corresponding primary or secondary alcohol to react in the presence of trichoroisocyanuric acid, a compound of formula R1SR2 and a base. In one embodiment, the alcohol is a compound of formula (I): wherein R3 is a protecting group. Also disclosed are methods for making 3-O-protected morphine dienol carboxylates comprising allowing a compound of formula (I) to oxidize in the presence of a chlorine-containing compound and a compound of formula R1SR2; and allowing the product of the oxidation step to react with an acylating agent.Type: GrantFiled: February 24, 2014Date of Patent: March 10, 2015Assignee: Purdue Pharma L.P.Inventor: Andreas Stumpf
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Patent number: 8685996Abstract: Disclosed are methods for making aldehydes and ketones comprising allowing the corresponding primary or secondary alcohol to react in the presence of trichoroisocyanuric acid, a compound of formula R1SR2 and a base. In one embodiment, the alcohol is a compound of formula (I): wherein R3 is a protecting group. Also disclosed are methods for making 3-O-protected morphine dienol carboxylates comprising allowing a compound of formula (I) to oxidize in the presence of a chlorine-containing compound and a compound of formula R1SR2; and allowing the product of the oxidation step to react with an acylating agent.Type: GrantFiled: May 15, 2012Date of Patent: April 1, 2014Assignee: Purdue Pharma L.P.Inventor: Andreas Stumpf
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Patent number: 8017032Abstract: A solid composition in the form of a tablet that generates and releases a biocidal solution comprising at least chlorine dioxide with an enhanced weight percent yield is presented. The composition comprises reactants capable of in-situ generation of chlorine dioxide comprising a chlorite donor that is coated with a gel-forming material that slows the rate of dissolution of the high solubility chlorite donor, a free halogen donor, and an acid source, resulting in an unexpectedly high weight percent yield and providing a controlled release of biocidal solution. The compositions of the invention show improved environmental stability which can reduce the cost of packaging and significantly increase the utility of the composition. The controlled release allows the use in multi-tablet chemical dispensers which may otherwise induce potentially explosive conditions or allow rapid release of the biocidal solution thereby inducing a spike in chemical concentration rather than a controlled and sustained release.Type: GrantFiled: August 25, 2010Date of Patent: September 13, 2011Assignee: Truox, Inc.Inventor: Roy W. Martin
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Patent number: 7993545Abstract: A solid composition in the form of a tablet that generates and releases a biocidal solution comprising at least chlorine dioxide with an enhanced weight percent yield is presented. The composition comprises reactants capable of in-situ generation of chlorine dioxide comprising a chlorite donor that is coated with a gel-forming material that slows the rate of dissolution of the high solubility chlorite donor, a free halogen donor, and an acid source, resulting in an unexpectedly high weight percent yield and providing a controlled release of biocidal solution. The compositions of the invention show improved environmental stability which can reduce the cost of packaging and significantly increase the utility of the composition. The controlled release allows the use in multi-tablet chemical dispensers which may otherwise induce potentially explosive conditions or allow rapid release of the biocidal solution thereby inducing a spike in chemical concentration rather than a controlled and sustained release.Type: GrantFiled: June 2, 2010Date of Patent: August 9, 2011Assignee: Truox, Inc.Inventor: Roy W. Martin
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Patent number: 7794607Abstract: Compositions and methods for their use are presented that substantially increase the rate of inactivation of microbiological organisms, especially those resistant to inactivation from free halogen based sanitizers, and oxidation of oxidation resistant organic based compounds in aqueous solution. Aquatic facilities susceptible to accumulation of organic N-chloramines, cyanuric acid and other oxidation resistant compounds, as well as oxidation resistant parasitic organisms such as cryptosporidium and Giardia, obtain dramatic improvements in the rate of oxidation and subsequent inactivation of these undesirable contaminants.Type: GrantFiled: November 13, 2006Date of Patent: September 14, 2010Assignee: Truox, Inc.Inventor: Roy W. Martin
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Patent number: 7695631Abstract: A method and composition for reducing chemical oxygen demand is presented. The composition includes a persulfate donor and a transition metal catalyst in contact with the persulfate donor. When the composition is contacted by water, the transition metal catalyst reacts with persulfate and reduces the persulfate concentration in the water. The composition allows the use of persulfate, which is known to cause irritation to users of aquatic facilities (e.g., pools, spas) that come in contact with it. As the persulfate concentration is reduced rapidly in the water by the catalyzed reaction, the persulfate-containing cleaning product may even be used while the aquatic facilities are being used. Optionally, a free halogen donor may be incorporated into the composition. The composition may be in the form of powder, granules (coated or uncoated), or agglomerate.Type: GrantFiled: March 26, 2009Date of Patent: April 13, 2010Assignee: Truox, Inc.Inventor: Roy W Martin
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Patent number: 7572390Abstract: A method and composition for reducing chemical oxygen demand is presented. The composition includes a persulfate donor, a transition metal catalyst in contact with the persulfate donor, and a cationic electrolyte. When the composition is contacted by water, the transition metal catalyst reacts with persulfate and reduces the persulfate concentration in the water. The composition allows the use of persulfate, which is known to cause irritation to users of aquatic facilities (e.g., pools, spas) that come in contact with it. As the persulfate concentration is reduced rapidly in the water by the catalyzed reaction, the persulfate-containing product may be applied while the aquatic facilities are being used. A free halogen donor may be incorporated into the composition. The composition may be in the form of powder, granules (coated or uncoated), or agglomerate. The cationic electrolyte facilitates the removal of the catalyst from the water.Type: GrantFiled: September 14, 2005Date of Patent: August 11, 2009Assignee: Truox, Inc.Inventor: Roy W. Martin
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Patent number: 7572384Abstract: A method and composition for reducing chemical oxygen demand is presented. The composition includes a persulfate donor and a transition metal catalyst in contact with the persulfate donor. When the composition is contacted by water, the transition metal catalyst reacts with persulfate and reduces the persulfate concentration in the water. The composition allows the use of persulfate, which is known to cause irritation to users of aquatic facilities (e.g., pools, spas) that come in contact with it. As the persulfate concentration is reduced rapidly in the water by the catalyzed reaction, the persulfate-containing cleaning product may even be used while the aquatic facilities are being used. Optionally, a free halogen donor may be incorporated into the composition. The composition may be in the form of powder, granules (coated or uncoated), or agglomerate.Type: GrantFiled: October 16, 2008Date of Patent: August 11, 2009Assignee: Truox, Inc.Inventor: Roy W. Martin
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Patent number: 7476333Abstract: A method and composition for reducing chemical oxygen demand is presented. The composition includes a persulfate donor and a transition metal catalyst in contact with the persulfate donor. When the composition is contacted by water, the transition metal catalyst reacts with persulfate and reduces the persulfate concentration in the water. The composition allows the use of persulfate, which is known to cause irritation to users of aquatic facilities (e.g., pools, spas) that come in contact with it. As the persulfate concentration is reduced rapidly in the water by the catalyzed reaction, the persulfate-containing cleaning product may even be used while the aquatic facilities are being used. Optionally, a free halogen donor may be incorporated into the composition. The composition may be in the form of powder, granules (coated or uncoated), or agglomerate.Type: GrantFiled: June 22, 2005Date of Patent: January 13, 2009Assignee: Truox, Inc.Inventor: Roy W. Martin
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Patent number: 7465410Abstract: A reactor for an in-situ production of a chemical product in high yield are presented. The reactor, which may be placed in a main solvent, includes a core and a reactor wall around the core. The reactor wall allows controlled permeation of the main solvent to the core. The core contains a reactant that reacts to produce a target product upon being contacted by a main solvent. The target product leaves the reactor at a controlled rate. Because the amount of the main solvent that permeates into the reactor is controlled, a high concentration of the reactant is maintained inside the reactor, resulting in a higher yield of the desired chemical product than if the reactants were directly added to the body of main solvent.Type: GrantFiled: February 18, 2005Date of Patent: December 16, 2008Assignee: Truox, Inc.Inventors: Perry L. Martin, Roy W. Martin
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Publication number: 20040051079Abstract: A compression molded product of quick-dissolving chlorinated isocyanuric acid, comprising:Type: ApplicationFiled: September 9, 2003Publication date: March 18, 2004Applicant: SHIKOKU CORPORATIONInventors: Shigeru Morioka, Yoshiya Iwasaki, Yasufumi Seo
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Patent number: 6699404Abstract: A massive body, e.g., a tablet, for producing a solution of chlorine dioxide when the massive body is added to liquid water. The massive body comprises a metal chlorite such as sodium chlorite, an acid source such as sodium bisulfate and a source of free halogen such as the sodium salt of dichloroisocyanuric acid or a hydrate thereof. The concentration of free halogen in the solution will be: (a) less than the concentration of chlorine dioxide in said solution on a weight basis and the ratio of the concentration of chlorine dioxide to the sum of the concentrations of chlorine dioxide and chlorite anion in said solution is at least 0.25:1 by weight; or (b) equal to or greater than the concentration of chlorine dioxide in said solution on a weight basis and the ratio of the concentration of chlorine dioxide to the sum of the concentrations of chlorine dioxide and chlorite anion in said solution is at least 0.50:1 by weight.Type: GrantFiled: June 17, 2002Date of Patent: March 2, 2004Assignee: Engelhard CorporationInventors: Barry K. Speronello, Gerald S. Koermer, Appadurai Thangaraj, Ahmad Moini
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Patent number: 6589443Abstract: Aqueous bleach solutions can be made by directing a spray of water onto a bulk or shaped solid (brick, tablet, block, etc.) comprising a continuous solid phase of an encapsulated source of an active halogen bleach or a solid comprising a source of an oxidizing active halogen bleach, and an encapsulated oxidizing halogen bleach source. Such shaped solids can be used to dispense uniform quantities of an aqueous bleach concentrate to bleaching locus such as a washing machine. The tablets can be made from the encapsulated bleach or from a powder mixture of a particulate, granulated or powdered unencapsulated source of active oxidizing bleach and an encapsulated source of active oxidizing bleach by forming the powder mixture into a desired shape. Such a shaped solid bleach can be packaged in a container and can then be contacted with an aqueous spray in a dispenser to create a solution of active bleach for cleaning bleaching processes.Type: GrantFiled: August 7, 1996Date of Patent: July 8, 2003Assignee: Ecolab Inc.Inventors: Keith E. Olson, Victor F. Man
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Publication number: 20030059483Abstract: Manual warewashing in common food service locations is typically performed in a multicompartment sink within three or more basins. In one basin the ware is contacted with an aqueous solution of a detergent composition. The ware is cleaned using mechanical action to remove soil. The cleaned ware is often rinsed in a subsequent sink in a potable water rinse and is then sanitized in a sanitizing solution in a subsequent basin, typically the third sink in sequence. The sanitizing solution can be rapidly depleted during periods of large volumes of hand washed ware. In order to monitor and control the concentration of the sanitizer in the sanitizer sink, we have found that even highly oxidizing hypochlorite bleaches, if adjusted to an appropriate pH, can maintain substantial sanitizing capacity while not decolorizing otherwise oxidatively sensitive dyes.Type: ApplicationFiled: February 10, 2000Publication date: March 27, 2003Inventors: Eddie D. Sowle, Darryl C. Bowling
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Patent number: 6514429Abstract: Composition for use in a water tank in the kitchen or sanitary sector, characterized by a basic composition essentially evolving its function following addition to a first water filling of the water tank, in the form of a tablet and at least one particle, with at least one core, which comprises at least one substance evolving its function essentially following an at least partial emptying of the first water filling from the water tank and the inflow of fresh water and a covering substantially completely surrounding the core or cores comprising at least one compound, whose solubility increases with decreasing concentration of a specific ion in the surrounding medium, the at least one particle being so arranged in or on the tablet that the surface of the particle or particles is at most only partly in direct contact with the surface of the basic composition surrounding the same and the concentration of the specific ion in the local environment of the particle or particles is sufficiently high up to a substantiaType: GrantFiled: October 23, 2000Date of Patent: February 4, 2003Assignee: Reckitt Benckiser N.V.Inventors: Guido Waschenbach, Ralf Wiedemann, Enric Carbonell, Edgar Endlein, Karl-Ludwig Gibis
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Patent number: 6447722Abstract: The present invention relates generally to novel water treatment compositions and methods of preparation and use. More particularly, the invention relates to solid water treatment compositions containing at least one halogen source and at least one amine compound. Methods of preparing solid water treatment compositions and methods for controlling biofouling, disinfecting, cleaning and water systems are also provided.Type: GrantFiled: December 4, 1998Date of Patent: September 10, 2002Assignee: Stellar Technology CompanyInventor: Lawrence F. Rakestraw
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Patent number: 6294510Abstract: A solid lavatory cleansing composition comprises: (i) a halogen-release agent containing at least 30 mole % of active halogen; (ii) a substantially non-oxidizable, substantially anhydrous surfactant component; and (iii) a substantially non-oxidizable solubility retardant agent.Type: GrantFiled: January 8, 1998Date of Patent: September 25, 2001Assignee: Jeyes Group LimitedInventors: Russell Norman, Brain Murie Wilson, John Marshall