Contains Alkaline Earth Metal Patents (Class 252/186.37)
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Patent number: 12134750Abstract: The invention includes a solid rinse aid that is particularly designed for extrusion solid formation and which is effective for creating spotless surfaces after rinsing. According to the invention, application has identified the critical combination of solid surfactants, coupling agents, hydrotrope, and hardening agents that is acceptable in the extrusion process to create a solid. The hydrotrope includes one or more short-chain alkylbenzene and/or alkyl naphthalene sulfonates. The composition hardens quickly but not so quick as to negatively impact the extrusion process. The compositions may also be used to form pressed or cast solids.Type: GrantFiled: August 16, 2023Date of Patent: November 5, 2024Assignee: ECOLAB USA INC.Inventors: Janel Marie Kieffer, Katherine Molinaro, Gary Becker, Tobias Foster, Karina Labusga
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Patent number: 11773348Abstract: The invention includes a solid rinse aid that is particularly designed for extrusion solid formation and which is effective for creating spotless surfaces after rinsing. According to the invention, application has identified the critical combination of solid surfactants, coupling agents, hydrotrope, and hardening agents that is acceptable in the extrusion process to create a solid. The hydrotrope includes one or more short-chain alkylbenzene and/or alkyl naphthalene sulfonates. The composition hardens quickly but not so quick as to negatively impact the extrusion process. The compositions may also be used to form pressed or cast solids.Type: GrantFiled: June 8, 2021Date of Patent: October 3, 2023Assignee: Ecolab USA Inc.Inventors: Janel Marie Kieffer, Katherine Molinaro, Gary Becker, Tobias Foster, Karina Labusga
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Patent number: 8486879Abstract: A solid composition including calcium and/or magnesium hypochlorite, a builder (e.g., one or more of carbonate, bicarbonate, sesquicarbonate), an acid, a water-soluble polymer, at least one anionic surfactant, and optionally, a hydrotrope. The composition does not include any potassium hypochlorite, sodium hypochlorite, lithium hypochlorite, N-halogenated compounds, peroxides, persulfates, hydantoins, isocyanurates, or carboxylic acids that also have hydroxyl, amino, amido, imino, or imido groups. Upon dissolution of the composition in water, the calcium and/or magnesium hypochlorite and acid react to form hypochlorous acid. The use of hypochlorous acid, rather than direct use of an alkaline or alkaline earth hypochlorite results in a composition that is typically acidic rather than basic, and that results in improved cleaning. The composition is particularly suited for cleaning and disinfecting dentures.Type: GrantFiled: December 19, 2012Date of Patent: July 16, 2013Assignee: The Clorox CompanyInventors: Evan Rumberger, William L. Smith
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Patent number: 8481471Abstract: The present invention provides a solid-layered composition having at least two parts. The first part comprises a) calcium hypochlorite, magnesium hypochlorite and mixtures thereof, b) a builder, c) a water-soluble polymer, d) an acid, and e) wherein the first part does not contain sodium hypochlorite, lithium hypochlorite, potassium hypochlorite and mixtures thereof. The second part comprises a) a functional ingredient, b) a builder or filler, and c) wherein the second part does not contain any oxidant.Type: GrantFiled: December 19, 2012Date of Patent: July 9, 2013Assignee: The Clorox CompanyInventors: William L. Smith, Evan M. Rumberger
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Patent number: 8475678Abstract: The present invention provides a method of using a solid-layered composition having at least two parts. The first past comprises a) calcium hypochlorite, magnesium hypochlorite and mixtures thereof, b) a builder, c) a water-soluble polymer, d) an acid, and e) wherein the first part does not contain sodium hypochlorite, lithium hypochlorite, potassium hypochlorite and mixtures thereof. The second part comprises a) a surfactant, b) a builder, c) an acid, and d) wherein the second part does not contain any oxidant.Type: GrantFiled: September 11, 2012Date of Patent: July 2, 2013Assignee: The Clorox CompanyInventors: William L. Smith, Evan M. Rumberger
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Patent number: 8361945Abstract: The present invention provides a method for cleaning dentures by contacting the dentures with a solid, multi-layered composition having at least two parts in water. The first part of the composition comprises a) calcium hypochlorite, magnesium hypochlorite and mixtures thereof, b) a builder, c) a water-soluble polymer, d) an acid, and e) wherein the first part does not contain sodium hypochlorite, lithium hypochlorite, potassium hypochlorite and mixtures thereof. The second part comprises a) a functional ingredient, b) a builder or filler, and c) wherein the second part does not contain any oxidant.Type: GrantFiled: November 10, 2010Date of Patent: January 29, 2013Assignee: The Clorox CompanyInventors: William L. Smith, Evan Rumberger
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Patent number: 8361942Abstract: A solid composition including calcium and/or magnesium hypochlorite, a builder (e.g., one or more of carbonate, bicarbonate, sesquicarbonate), an acid, a water-soluble polymer, at least one anionic surfactant, and optionally, a hydrotrope. The composition does not include any potassium hypochlorite, sodium hypochlorite, lithium hypochlorite, N-halogenated compounds, peroxides, persulfates, hydantoins, isocyanurates, or carboxylic acids that also have hydroxyl, amino, amido, imino, or imido groups. Upon dissolution of the composition in water, the calcium and/or magnesium hypochlorite and acid react to form hypochlorous acid. The use of hypochlorous acid, rather than direct use of an alkaline or alkaline earth hypochlorite results in a composition that is typically acidic rather than basic, and that results in improved cleaning. The composition is particularly suited for cleaning and disinfecting dentures.Type: GrantFiled: October 13, 2010Date of Patent: January 29, 2013Assignee: The Clorox CompanyInventors: William L. Smith, Evan Rumberger
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Patent number: 8361944Abstract: The present invention provides a solid-layered composition having at least two parts. The first part comprises a) calcium hypochlorite, magnesium hypochlorite and mixtures thereof, b) a builder, c) a water-soluble polymer, d) an acid, and e) wherein the first part does not contain sodium hypochlorite, lithium hypochlorite, potassium hypochlorite and mixtures thereof. The second part comprises a) a functional ingredient, b) a builder or filler, and c) wherein the second part does not contain any oxidant.Type: GrantFiled: November 10, 2010Date of Patent: January 29, 2013Assignee: The Clorox CompanyInventors: William L. Smith, Evan Rumberger
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Patent number: 8361943Abstract: A solid composition including calcium and/or magnesium hypochlorite, a builder (e.g., one or more of carbonate, bicarbonate, sesquicarbonate), an acid, a water-soluble polymer, at least one anionic surfactant, and optionally, a hydrotrope. The composition does not include any potassium hypochlorite, sodium hypochlorite, lithium hypochlorite, N-halogenated compounds, peroxides, persulfates, hydantoins, isocyanurates, or carboxylic acids that also have hydroxyl, amino, amido, imino, or imido groups. Upon dissolution of the composition in water, the calcium and/or magnesium hypochlorite and acid react to form hypochlorous acid. The use of hypochlorous acid, rather than direct use of an alkaline or alkaline earth hypochlorite results in a composition that is typically acidic rather than basic, and that results in improved cleaning. The composition is particularly suited for cleaning and disinfecting dentures.Type: GrantFiled: October 14, 2010Date of Patent: January 29, 2013Assignee: The Clorox CompanyInventors: William L. Smith, Evan M. Rumberger
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Publication number: 20120305841Abstract: A method of making a bleach tablet includes mixing ingredients by weight that include 35 to 85% hypochlorite calcium/sodium, 0 to 80% bleach activator, 1 to 50% layered silicate and/or alkali metal silicate, 0 to 25% sodium/potassium bicarbonate, 5 to 45% by weight sodium dichloroisocyanurate, 0 to 5% disintegrating agent, 0 to 10% polymer, and 0 to 2% improvement additives; adding a builder compound to the mixed ingredients in an amount from 1% to 80% by weight; compressing the mixed ingredients to form the bleach tablet; and spraying a binder on the bleach tablet.Type: ApplicationFiled: May 31, 2012Publication date: December 6, 2012Inventor: Ali Almasri
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Patent number: 8309508Abstract: A cleaning substrate which comprises at least one layer of a solid hypohalite precipitate, wherein the hypohalite precipitate is formed in situ on the layer of substrate material. A process for making a fibrous cleaning substrate comprising the steps of: a) providing at least one layer of fibrous material; b) exposing the fibrous layer to an aqueous alkaline earth salt solution; c) treating the fibrous layer with a hypochlorite solution; d) allowing the aqueous alkaline earth salt solution combine with the hypochlorite solution to form a solid hypochlorite precipitate around the fibers in the fibrous material and a liquid phase, and e) removing at least 65% of the liquid phase from the fibrous substrate.Type: GrantFiled: December 3, 2010Date of Patent: November 13, 2012Assignee: The Clorox CompanyInventors: Marc P. Privitera, William L. Smith, Edward Jason White, Leslie N. Adams
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Patent number: 8287755Abstract: The present invention provides a solid-layered composition having at least two parts. The first part comprises a) calcium hypochlorite, magnesium hypochlorite and mixtures thereof, b) a builder, c) a water-soluble polymer, d) an acid, and e) wherein the first part does not contain sodium hypochlorite, lithium hypochlorite, potassium hypochlorite and mixtures thereof. The second part comprises a) a surfactant, b) a builder, c) an acid, and d) wherein the second part does not contain any oxidant.Type: GrantFiled: November 18, 2009Date of Patent: October 16, 2012Assignee: The Clorox CompanyInventors: William L. Smith, Evan M. Rumberger
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Patent number: 8268770Abstract: A cleaning substrate which comprises at least one layer of a solid hypohalite precipitate, wherein the hypohalite precipitate is formed in situ on the layer of substrate material. A process for making a fibrous cleaning substrate comprising the steps of: a) providing at least one layer of fibrous material; b) exposing the fibrous layer to an aqueous alkaline earth salt solution; c) treating the fibrous layer with a hypochlorite solution; d) allowing the aqueous alkaline earth salt solution combine with the hypochlorite solution to form a solid hypochlorite precipitate around the fibers in the fibrous material and a liquid phase, and e) removing at least 65% of the liquid phase from the fibrous substrate.Type: GrantFiled: January 28, 2011Date of Patent: September 18, 2012Assignee: The Clorox CompanyInventors: Marc P. Privitera, William L. Smith, Edward Jason White, Leslie N. Adams
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Patent number: 8115046Abstract: A two-component, water based micro encapsulation composition and method for the cleanup of hydrocarbon spills or contaminates on various surfaces and media. The two-part formulation includes a first solution including water in a predetermined ratio of a water soluble alkaline silicate solution having at least one alkali metal and a predetermined ratio of at least one water soluble surfactant; and a second solution including water, a predetermined ratio of water soluble acid, a predetermined ratio of water dispersible polymer, a predetermined ratio of water soluble hydrotrope, and a predetermined ratio of at least one water soluble flocculating agent. A method of using the two-part formulation includes preparing the two-part formulation, allowing the first solution to contact the hydrocarbon or chemical contaminate; allowing the second solution to contact the first solution and contaminate to form a homogeneous mixture; and removing the homogeneous mixture.Type: GrantFiled: January 19, 2009Date of Patent: February 14, 2012Assignee: RTA Systems, Inc.Inventors: Lyle D. Burns, Geoffrey O. Mitchell, Marcus S. Burns, Michael A. Burns
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Patent number: 7695639Abstract: Stable compositions of calcium hypochlorite containing selected hydrated inorganic salts having a sufficiently high enthalpy and the ability to provide water release to sufficiently quench reactions and reduce the potential for conflagration.Type: GrantFiled: March 17, 2008Date of Patent: April 13, 2010Inventor: John P. Garris
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Patent number: 7431863Abstract: Describes a composition comprising a mixture of calcium hypochlorite and hydrated magnesium sulfate having an average of from 3 to 5.5 moles of water of hydration per mole of magnesium sulfate. The amount of hydrated magnesium sulfate in the composition is such that the composition has at least a DOT Packing Group III Division 5.1 Classification.Type: GrantFiled: March 8, 2006Date of Patent: October 7, 2008Assignee: PPG Industries Ohio, Inc.Inventor: Stanley R. Pickens
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Patent number: 7364669Abstract: Stable compositions of calcium hypochlorite containing selected hydrated inorganic salts having a sufficiently high enthalpy and the ability to provide water release to sufficiently quench reactions and reduce the potential for conflagration.Type: GrantFiled: June 4, 2007Date of Patent: April 29, 2008Assignee: BIO-Lab, Inc.Inventor: John P. Garris
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Patent number: 7160484Abstract: The present invention is generally directed to a method of producing an aqueous solution of chlorine dioxide from the reaction of a metal chlorite and an acid forming component which do not react to produce chlorine dioxide in the substantial absence of water. The reactants are separated from liquid water by a membrane which allows the controlled passage of liquid water and/or water vapor into contact with the reactants. The chlorine dioxide thus generated passes out through the membrane into the liquid water to produce the desired aqueous solution. Aqueous solutions containing chlorine dioxide produced in this manner can be conveniently used for commercial and domestic cleaning operations such as in the food industry.Type: GrantFiled: January 12, 2001Date of Patent: January 9, 2007Assignee: Engelhard CorporationInventors: Appadurai Thangaraj, Barry K. Speronello, Timothy D. Wildman
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Patent number: 7045077Abstract: Stable compositions of calcium hypochlorite containing selected hydrated inorganic salts having a sufficiently high enthalpy and the ability to provide water release to sufficiently quench reactions and reduce the potential for conflagration.Type: GrantFiled: June 18, 2004Date of Patent: May 16, 2006Assignee: BioLab, Inc.Inventor: John P. Garris
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Patent number: 7033510Abstract: This invention relates to a method for preparing a stabilised stock hypobromous acid solution, and to a stabilised stock hypobromous acid solution. The stabilised stock solution has a hypobromous acid concentration of less than 30% (m/m) and contains an amount of cyanuric acid as a stabiliser not exceeding 1 ppm. The solution may be used for treating any type of water, but has particular application in treating drinking water and irrigation water.Type: GrantFiled: March 1, 2002Date of Patent: April 25, 2006Assignee: Milbridge Investments (Pty) Ltd.Inventors: Jan Bastiaan Cilliers, Martha Sophia Cilliers
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Publication number: 20040023837Abstract: Liquid compositions containing alkali or alkaline-earth hypochlorites, and possibly other active chlorine releasers such as trichlorocyanuric acid, dichlorocyanuric acid and its alkali salts, with special reference to those used for bleaching and sanitising fabrics and surfaces.Type: ApplicationFiled: July 10, 2003Publication date: February 5, 2004Inventors: Andrea Zanardi, Italo Accardi
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Patent number: 6251684Abstract: The present invention provides dried chemical compositions comprising dried beads. Typically, the beads comprise reagents suitable for analysis of biological samples, in particular analysis of blood samples in centrifugal analyzers.Type: GrantFiled: April 24, 1998Date of Patent: June 26, 2001Assignee: Abaxis, Inc.Inventors: Steven N. Buhl, Bhaskar Bhayani, Chi-Sou Yu, Thuy N. Tang