Contains Activator Admixed With Inorganic Peroxide Patents (Class 252/186.38)
  • Patent number: 11311011
    Abstract: Methods and systems for on-site, continuous generation of peracid chemistry, namely peroxycarboxylic acids and peroxycarboxylic acid forming compositions, are disclosed. In particular, an adjustable biocide formulator or generator system is designed for on-site generation of peroxycarboxylic acids and peroxycarboxylic acid forming compositions from sugar esters. Methods of using the in situ generated peroxycarboxylic acids and peroxycarboxylic acid forming compositions are also disclosed.
    Type: Grant
    Filed: December 26, 2018
    Date of Patent: April 26, 2022
    Assignee: Ecolab USA Inc.
    Inventors: Paul R. Kraus, Thomas C. Rustad
  • Patent number: 11071840
    Abstract: The present invention includes a device for hypoxia training comprising: one or more electrochemical cells each comprising: a cathode and an anode separated by a proton exchange membrane, each of the anode and cathode in communication with an input and an output, wherein the input of the cathode is in fluid communication with ambient air, and wherein the input of the anode is in fluid communication with a source of liquid water; a power supply connected to the one or more electrochemical cells; and a mask in fluid communication with the output from the cathode of the one or more electrochemical cells, wherein oxygen is removed from the ambient air during contact with the cathode when hydrogen ions separated from liquid water by a catalyst on the anode convert oxygen in the ambient air into water.
    Type: Grant
    Filed: May 2, 2017
    Date of Patent: July 27, 2021
    Assignee: Lynntech, Inc.
    Inventors: Jonathan Reeh, Mahesh Waje, Mehmet Kesmez, Carlos Salinas, Jibi Varughese, John Zbranek, Seth Cocking, Ashwin Balasubramanian, Cory Teurman, James Netherland, Geoffrey Duncan Hitchens
  • Patent number: 11033600
    Abstract: Disclosed herein are protease transition state inhibitor/analogue prodrug compounds selected from the group consisting of esters, carbamates, ester phosphates, and pharmaceutically acceptable salts thereof. Compositions containing such prodrugs are also disclosed, along with methods of using such compounds therapeutically or prophylactically against calicivirus, picornavirus, and/or coronavirus infection, as well as other conditions, such as malaria, cancer, stroke, heart attack, neural degeneration, cataracts, and glaucoma through inhibition of the variety of proteases associated with progression of such conditions.
    Type: Grant
    Filed: July 28, 2017
    Date of Patent: June 15, 2021
    Assignees: Kansas State University Research Foundation, Wichita State University
    Inventors: Kyeong-Ok Chang, William C. Groutas
  • Patent number: 10793810
    Abstract: A stable liquid detergent composition containing a self-structuring surfactant system, where without using external structurants, the liquid detergent composition exhibits good shear thinning properties while maintaining stability under high shear. A liquid detergent composition comprising a linear alkyl benzene sulfonate, a zwitterionic and/or amphoteric surfactant and optionally polyethylene glycol.
    Type: Grant
    Filed: April 6, 2017
    Date of Patent: October 6, 2020
    Assignee: The Procter & Gamble Company
    Inventors: Liangjing Fang, Ming Tang, Karl Shiqing Wei, Peng Qin, Ting He
  • Patent number: 10669510
    Abstract: The invention provides a concentrated detergent composition comprising alkali metal carbonate, alkali metal percarbonate, and a peroxidation catalyst according to formula (I) [(LpMq)nXr]Ys, wherein each L independently is an organic ligand containing at least three nitrogen atoms that coordinate with the metal M; M is Mn or Fe; each X independently is a coordinating or bridging group selected from the group consisting of H2O, OH?, SH?, HO2?, O2?, O22?, S2?, F?, Cl?, Br?, I?, NO3?, NO2?, SO42?, SO32?, PO43?, N3?, CN?, NR3, NCS?, RCN, RS?, RCO2?, RO?, and with R being hydrogen or a C1 to C6 alkyl group; p is an integer from 1 to 4; q is an integer from 1 to 2; r is an integer from 0 to 6; Y is a counter ion; and s is the number of counter ions. The invention also relates to the use of said concentrated detergent composition as a warewashing detergent for the removal of starch soil.
    Type: Grant
    Filed: February 21, 2019
    Date of Patent: June 2, 2020
    Assignee: Ecolab USA Inc.
    Inventors: David Dotzauer, Tobias Foster, David W. Gohl, Dirk Kullwitz, John Mansergh
  • Patent number: 10492496
    Abstract: This application relates to disinfectant formulations including calcium hydroxide and sodium hypochlorite and further relates to method of manufacturing the disinfectant formulations and methods of using the formulations.
    Type: Grant
    Filed: December 14, 2016
    Date of Patent: December 3, 2019
    Assignee: Biosenta, Inc.
    Inventors: Marcus E. Martin, Edward K. Pardiak
  • Patent number: 10253278
    Abstract: The invention provides a concentrated detergent composition comprising alkali metal carbonate, alkali metal percarbonate, and a peroxidation catalyst according to formula (I) [(LpMq)nXr]Ys, wherein each L independently is an organic ligand containing at least three nitrogen atoms that coordinate with the metal M; M is Mn or Fe; each X independently is a coordinating or bridging group selected from the group consisting of H2O, OH?, SH?, HO2?, O2?, O22?, S2?, F?, Cl?, Br?, I?, NO3?, NO2?, SO42?, SO32?, PO43?, N3?, CN?, NR3, NCS?, RCN, RS?, RCO2?, RO?, and with R being hydrogen or a C1 to C6 alkyl group; p is an integer from 1 to 4; q is an integer from 1 to 2; r is an integer from 0 to 6; Y is a counter ion; and s is the number of counter ions. The invention also relates to the use of said concentrated detergent composition as a warewashing detergent for the removal of starch soil.
    Type: Grant
    Filed: April 11, 2018
    Date of Patent: April 9, 2019
    Assignee: Ecolab USA Inc.
    Inventors: David Dotzauer, Tobias Foster, David W. Gohl, Dirk Kullwitz, John Mansergh
  • Patent number: 10239959
    Abstract: The invention concerns a process for the manufacture of an acylated polymer composition comprising amylose and/or amylopectin, comprising a pre-treatment step in the presence of an acid and a hydroxycarboxylic acid, subsequent acylation and, preferably, a post-treatment step with an acid. The products obtained are useful as additives in inks, varnishes, lacquers, coatings, thickeners, adhesives or binders.
    Type: Grant
    Filed: October 15, 2014
    Date of Patent: March 26, 2019
    Assignee: SOLVAY ACETOW GMBH
    Inventors: Jana Lubkoll, Armin Stein
  • Patent number: 10040105
    Abstract: A method of decontaminating soil and ground water containing organic contaminants and metal compounds. It comprises the steps of first treating such soils and ground water with an effective amount an aqueous solution containing a peroxide and a water soluble chelating agent for a time sufficient to have the water soluble chelating agent chelate at least one of the metals of the metal compounds present in the soil and ground water. Next, the chelated metals are brought into contact with the peroxide to catalytically convert the peroxide to an oxidizing agent and hydroxyl ion. The hydroxyl ion converts the halogenated organic compound into environmentally safe, non-toxic compounds. Gases that are produced from this reaction, and from the oxidation of organic compounds, are used to diffuse solution into the soil to chelate calcium and magnesium, thereby causing the sodium to be dislodged from the soil and reduce sodicity in the soil.
    Type: Grant
    Filed: August 23, 2016
    Date of Patent: August 7, 2018
    Inventor: William L. Lundy
  • Patent number: 9994797
    Abstract: Formulations, comprising (A) in total in the range of 1 to 50% by weight of at least one compound, selected from methylglycinediacetic acid (MGDA), glutamic acid diacetate (GLDA) and salts thereof, (B) in total in the range of 0.01 to 0.4% by weight of at least one zinc salt, stated as zinc, (C) in total in the range of 0.001 to 0.045% by weight of homo- or copolymer of ethyleneimine, and (D) optionally 0.5 to 15% by weight of bleach, based in each case on the solids content of the respective formulation.
    Type: Grant
    Filed: March 28, 2014
    Date of Patent: June 12, 2018
    Assignee: BASF SE
    Inventors: Stephan Hueffer, Alejandra Garcia Marcos, Markus Hartmann, Heike Weber
  • Patent number: 9969958
    Abstract: The invention provides a concentrated detergent composition comprising alkali metal carbonate, alkali metal percarbonate, and a peroxidation catalyst according to formula (I) [(LpMq)nXr]Ys, wherein each L independently is an organic ligand containing at least three nitrogen atoms that coordinate with the metal M; M is Mn or Fe; each X independently is a coordinating or bridging group selected from the group consisting of H2O, OH?, SH?, HO2?, O2?, O22?, S2?, F?, Cl?, Br?, I?, NO3?, NO2?, SO42?, SO32?, PO43?, N3?, CN?, NR3, NCS?, RCN, RS?, RCO2?, RO?, and with R being hydrogen or a C1 to C6 alkyl group; p is an integer from 1 to 4; q is an integer from 1 to 2; r is an integer from 0 to 6; Y is a counter ion; and s is the number of counter ions. The invention also relates to the use of said concentrated detergent composition as a warewashing detergent for the removal of starch soil.
    Type: Grant
    Filed: May 2, 2013
    Date of Patent: May 15, 2018
    Assignee: Ecolab USA Inc.
    Inventors: David Dotzauer, Tobias Foster, David W. Gohl, Dirk Kullwitz, John Mansergh
  • Patent number: 9919923
    Abstract: An object of the present invention is to provide a method by which hydrogen peroxide can be produced at a satisfactory level from an industrial and economical viewpoint without causing the load of purification to be large and without needing too large facilities for production. The present invention is directed to a method for producing hydrogen peroxide, which comprises reacting hydrogen and oxygen in a reaction medium in the presence of a noble metal catalyst and a radical scavenger.
    Type: Grant
    Filed: June 17, 2013
    Date of Patent: March 20, 2018
    Assignees: MITSUBISHI GAS CHEMICAL COMPANY, INC., KYUSHU UNIVERSITY, NATIONAL UNIVERSITY CORPORATION
    Inventors: Tatsumi Ishihara, Kohei Shigeta, Katsuhiro Iura, Kenji Kato, Norikazu Okuda
  • Patent number: 9616472
    Abstract: Various embodiments of contaminant removal systems, compositions, and methods are described herein. In one embodiment, a method for oxidizing a contaminant includes contacting the contaminant with a peroxygen compound and initializing, maintaining, or propagating degradation of the peroxygen compound with an oxygenated organic compound, thereby releasing oxidizing radicals. The method also includes oxidizing the contaminant with the released oxidizing radicals.
    Type: Grant
    Filed: June 17, 2012
    Date of Patent: April 11, 2017
    Assignee: Washington State University
    Inventors: Richard J. Watts, Mushtaque Ahmad
  • Patent number: 8961822
    Abstract: A bleaching composition comprising a peroxy compound and one or more activator present in an effective amount to activate the peroxy compound, present in an amount effective to accomplish bleaching or cleaning or oxidation. The activator is a metallocarbene of the general structure (XX?C)yMLn? where M represents a metal center, C represents the carbene carbon bound to the metal center, X and X? may be the same or different and may furthermore be part of a cyclic structure, Ln? represents one or more other ligands which may or may not include one or more metal centers, and where y?1.
    Type: Grant
    Filed: March 11, 2013
    Date of Patent: February 24, 2015
    Assignee: Arkema Inc.
    Inventors: Michael B. Abrams, Xiawei Zhang
  • Patent number: 8741174
    Abstract: A reduced weight DF-200 decontamination formulation that is stable under high temperature storage conditions. The formulation can be pre-packed as an all-dry (i.e., no water) or nearly-dry (i.e., minimal water) three-part kit, with make-up water (the fourth part) being added later in the field at the point of use.
    Type: Grant
    Filed: May 21, 2008
    Date of Patent: June 3, 2014
    Assignee: Sandia Corporation
    Inventor: Mark D. Tucker
  • Patent number: 8431519
    Abstract: A process for preparation of co-granules including one or more bleach activators and one or more bleach agent compounds is described. The bleach component is mixed and coated with a binder selected from the group of fatty acids, fatty acid polyol esters, polyglycols and fatty alcohol oxalkylates. One or more bleach activators is added to this mixture followed by granulation or agglomeration in a mixer, resulting in a bleach co-granule composition including the bleach activator and peroxide components.
    Type: Grant
    Filed: April 29, 2010
    Date of Patent: April 30, 2013
    Assignee: OCI Chemical Corp.
    Inventors: Robert Scarella, Georg Borchers
  • Patent number: 8414793
    Abstract: A bleaching composition comprising a peroxy compound and one or more activator present in an effective amount to activate the peroxy compound, present in an amount effective to accomplish bleaching or cleaning or oxidation. The activator is a metallocarbene of the general structure (XX?C)yMLn? where M represents a metal center, C represents the carbene carbon bound to the metal center, X and X? may be the same or different and may furthermore be part of a cyclic structure, Ln? represents one or more other ligands which may or may not include one or more metal centers, and where y>1.
    Type: Grant
    Filed: May 12, 2009
    Date of Patent: April 9, 2013
    Assignee: Arkema Inc.
    Inventors: Michael B. Abrams, Xiawei Zhang
  • Patent number: 8048965
    Abstract: Disclosed is a method for extending a shelf life of vinyl ester resin or unsaturated polyester resin during transportation or general storage. The method includes the step of enhancing an oxygen content of the vinyl ester resin or the unsaturated polyester resin, such that the self-polymerization reaction of reactive functional groups having carbon-carbon unsaturated double bonds of the vinyl ester resin or the unsaturated polyester resin can be minimized, so as to slow down occurrence of a gelation phenomenon of the vinyl ester resin or the unsaturated polyester resin in a long-time transportation or storage, and further to decrease a monetary loss.
    Type: Grant
    Filed: July 30, 2009
    Date of Patent: November 1, 2011
    Assignee: Swancor Inc. Co., Ltd.
    Inventors: Feng-Mao Huang, Shih-Wen Yur, Ming-Zhou Chuang
  • Patent number: 8034851
    Abstract: The present invention relates to new cure accelerator systems for anaerobic curable compositions. These anaerobic cure systems include tetraalkyl ammonium oxidizing salts that are soluble in the (meth)acrylate component of the composition.
    Type: Grant
    Filed: November 25, 2008
    Date of Patent: October 11, 2011
    Assignee: Henkel Corporation
    Inventor: Philip T. Klemarczyk
  • Publication number: 20100331229
    Abstract: Particulate bleaching composition comprising a bleaching system, as a first essential component, which comprises oxygen bleach, a bleach activator and a perfume delivery system. Such perfume delivery system is preferably chosen among an amine reaction product containing perfume or an encapsulated perfume made of starch.
    Type: Application
    Filed: June 30, 2010
    Publication date: December 30, 2010
    Inventors: Giulia Ottavia Bianchetti, Gloria Dicapua, Andrea Esposito, Sarah Germana, Vincenzo Guida, Luca Sarcinelli
  • Patent number: 7708905
    Abstract: A method for preparing an ester bleach activator compound is disclosed. The method includes (A) preparing fatty acid monoester; (B) making chloroformate by reacting the fatty acid monoester with at least one selected from the group consisting of phosgene, diphosgene and triphosgene in the presence of base; and (C) reacting the chloroformate with hydroxybenzene, its derivatives, or its salts in solvent. According to the method, the ester bleach activator compound can be made in a simple and economic way.
    Type: Grant
    Filed: May 25, 2004
    Date of Patent: May 4, 2010
    Assignee: LG Household & Health Care Ltd.
    Inventors: Chang-Woo Lee, Wan-Goo Cho, Jin-Young Hyun, Kyung-Hee Oh
  • Patent number: 7709437
    Abstract: A process for preparation of co-granules including one or more bleach activators and one or more bleach agent compounds is described. The bleach component is mixed and coated with a binder selected from the group of fatty acids, fatty acid polyol esters, polyglycols and fatty alcohol oxalkylates. One or more bleach activators is added to this mixture followed by granulation or agglomeration in a mixer, resulting in a bleach co-granule composition including the bleach activator and peroxide components.
    Type: Grant
    Filed: April 27, 2006
    Date of Patent: May 4, 2010
    Assignee: OCI Chemical Corp.
    Inventors: Robert Scarella, Georg Borchers
  • Patent number: 7662759
    Abstract: Decontamination formulations with an additive for enhancing mold remediation. The formulations include a solubilizing agent (e.g., a cationic surfactant), a reactive compound (e.g., hydrogen peroxide), a carbonate or bicarbonate salt, a water-soluble bleaching activator (e.g., propylene glycol diacetate or glycerol diacetate), a mold remediation enhancer containing Fe or Mn, and water. The concentration of Fe2+ or Mn2+ ions in the aqueous mixture is in the range of about 0.0001% to about 0.001%. The enhanced formulations can be delivered, for example, as a foam, spray, liquid, fog, mist, or aerosol for neutralization of chemical compounds, and for killing certain biological compounds or agents and mold spores, on contaminated surfaces and materials.
    Type: Grant
    Filed: January 27, 2006
    Date of Patent: February 16, 2010
    Assignee: Sandia Corporation
    Inventors: Mark D. Tucker, Kevin Irvine, Paul Berger, Robert Comstock
  • Publication number: 20090281018
    Abstract: The present invention relates to a bleaching activator granule containing (a) a bleaching activator and (b) a specified alcohol which is liquid at room temperature (25° C.).
    Type: Application
    Filed: January 24, 2007
    Publication date: November 12, 2009
    Inventors: Keiichi Onoda, Masakazu Furukawa, Kazuyoshi Ozaki, Hiroshi Noro, Yasumitsu Sakuma
  • Patent number: 7615187
    Abstract: This present invention provides materials for use as solid or concentrated chemical precursors for the production of organic peroxy acids (peracids). Organic peroxy acids are formed using a precursor according to the invention when they are combined with hydrogen peroxide or a hydrogen peroxide precursor such as a percarbonate or a perborate in aqueous medium. Organic peroxy acids, such as peroxyacetic acid, are used currently to disinfect medical equipment such as endoscopes and related items.
    Type: Grant
    Filed: August 24, 2007
    Date of Patent: November 10, 2009
    Assignee: D H Technologies, LLP
    Inventors: Danny O. Helton, David W. Hobson
  • Patent number: 7541324
    Abstract: What are claimed are synergistically active bleach activator mixtures consisting of a) a hydroxybenzoic acid derivative of the formula 1 in which R is C8-C11-alkyl, and b) tetraacetylethylenediamine and/or 1,5-diacetyl-2,4-dioxo-1,3,5-hexahydrotriazine.
    Type: Grant
    Filed: September 3, 2005
    Date of Patent: June 2, 2009
    Assignee: Clariant Produkte (Deutschland) GmbH
    Inventors: Gerd Reinhardt, Georg Borchers
  • Patent number: 7507700
    Abstract: This invention relates to organic catalysts comprising iminium or oxaziridinium moieties, cleaning compositions comprising such catalysts; and processes for making and using such catalysts and cleaning products.
    Type: Grant
    Filed: May 19, 2006
    Date of Patent: March 24, 2009
    Assignee: The Procter & Gamble Company
    Inventors: Gregory Scot Miracle, George Douglas Hiler, II, Susumu Murata, Rebecca Massie Grey
  • Patent number: 7465411
    Abstract: A composition capable of expedited in-situ generation of dioxirane and a method of preparing the composition are presented. The composition includes a transition metal catalyst, peracid donor, and carbonyl donor, and forms an effective multi-purpose oxidizing (e.g., bleaching) solution. Methods of using the bleaching solutions and their application are also presented. The composition provides a cost-effective means of producing a dioxirane-based multi-purpose bleaching solution for use on laundries, carpets, hard surfaces, bathroom surfaces, floors and the like.
    Type: Grant
    Filed: March 16, 2006
    Date of Patent: December 16, 2008
    Assignee: Truox, Inc.
    Inventor: Roy W. Martin
  • Patent number: 7425527
    Abstract: The present invention relates to organic activators having the following general formula: Wherein R1 is a substituted or unsubstituted alkyl or aryl moiety comprising at least five carbons, R2 is a substituted or unsubstituted alkyl moiety comprising less than five carbons, R3 is a suitable bridging moiety, R4 is a charged moiety, N is nitrogen, each G is, independently, an oxygen containing moiety and Z, when present, is a charge balancing counter ion. The present invention also relates to cleaning compositions comprising said organic activators, and processes for making and using the aforementioned organic activators and cleaning compositions.
    Type: Grant
    Filed: April 28, 2005
    Date of Patent: September 16, 2008
    Assignee: The Procter & Gamble Company
    Inventors: Gregory Scot Miracle, Robert Richard Dykstra, George Douglas Hiler, II
  • Patent number: 7307191
    Abstract: This present invention provides materials for use as solid or concentrated chemical precursors for the production of organic peroxy acids (peracids). Organic peroxy acids are formed using a precursor according to the invention when they are combined with hydrogen peroxide or a hydrogen peroxide precursor such as a percarbonate or a perborate in aqueous medium. Organic peroxy acids, such as peroxyacetic acid, are used currently to disinfect medical equipment such as endoscopes and related items.
    Type: Grant
    Filed: March 16, 2004
    Date of Patent: December 11, 2007
    Assignee: OH Technologies LLP
    Inventors: David W. Hobson, Danny O. Helton
  • Patent number: 7282470
    Abstract: A decontamination formulation and method of making that neutralizes the adverse health effects of both chemical and biological compounds, especially chemical warfare (CW) and biological warfare (BW) agents, and toxic industrial chemicals. The formulation provides solubilizing compounds that serve to effectively render the chemical and biological compounds, particularly CW and BW compounds, susceptible to attack, and at least one reactive compound that serves to attack (and detoxify or kill) the compound. The formulation includes at least one solubilizing agent, a reactive compound, a bleaching activator, a sorbent additive, and water. The highly adsorbent, water-soluble sorbent additive (e.g., sorbitol or mannitol) is used to “dry out” one or more liquid ingredients, such as the liquid bleaching activator (e.g., propylene glycol diacetate or glycerol diacetate) and convert the activator into a dry, free-flowing powder that has an extended shelf life, and is more convenient to handle and mix in the field.
    Type: Grant
    Filed: July 18, 2003
    Date of Patent: October 16, 2007
    Assignee: Sandia Corporation
    Inventors: Mark D. Tucker, Robert H. Comstock
  • Patent number: 7276468
    Abstract: A decontamination formulation and method of making that neutralizes the adverse health effects of both chemical and biological compounds, especially chemical warfare (CW) and biological warfare (BW) agents, and toxic industrial chemicals. The formulation provides solubilizing compounds that serve to effectively render the chemical and biological compounds, particularly CW and BW compounds, susceptible to attack, and at least one reactive compound that serves to attack (and detoxify or kill) the compound. The formulation includes at least one solubilizing agent, a reactive compound, a sorbent additive, and water. A highly adsorbent sorbent additive (e.g., amorphous silica, sorbitol, mannitol, etc.) is used to “dry out” one or more liquid ingredients into a dry, free-flowing powder that has an extended shelf life, and is more convenient to handle and mix in the field.
    Type: Grant
    Filed: December 18, 2003
    Date of Patent: October 2, 2007
    Assignee: Sandia Corporation
    Inventor: Mark D. Tucker
  • Patent number: 7271137
    Abstract: Aqueous decontamination formulations that neutralize biological pathogens for disinfection and sterilization applications. Examples of suitable applications include disinfection of food processing equipment, disinfection of areas containing livestock, mold remediation, sterilization of medical instruments and direct disinfection of food surfaces, such as beef carcasses. The formulations include at least one reactive compound, bleaching activator, inorganic base, and water. The formulations can be packaged as a two-part kit system, and can have a pH value in the range of 7-8.
    Type: Grant
    Filed: January 27, 2004
    Date of Patent: September 18, 2007
    Assignee: Sandia Corporation
    Inventors: Mark D. Tucker, Daniel E. Engler
  • Patent number: 7169744
    Abstract: This invention relates to organic catalysts comprising iminium or oxaziridinium moieties, cleaning compositions comprising such catalysts; and processes for making and suing such catalysts and cleaning products.
    Type: Grant
    Filed: May 29, 2003
    Date of Patent: January 30, 2007
    Assignee: Procter & Gamble Company
    Inventors: Gregory Scot Miracle, George Douglas Hiler, II, Susumu Murata, Rebecca Massie Grey
  • Patent number: 7125497
    Abstract: Decontamination formulations for neutralization of toxic industrial chemicals, and methods of making and using same. The formulations are effective for neutralizing malathion, hydrogen cyanide, sodium cyanide, butyl isocyanate, carbon disulfide, phosgene gas, capsaicin in commercial pepper spray, chlorine gas, anhydrous ammonia gas; and may be effective at neutralizing hydrogen sulfide, sulfur dioxide, formaldehyde, ethylene oxide, methyl bromide, boron trichloride, fluorine, tetraethyl pyrophosphate, phosphorous trichloride, arsine, and tungsten hexafluoride.
    Type: Grant
    Filed: May 21, 2004
    Date of Patent: October 24, 2006
    Assignee: Sandia Corporation
    Inventors: Mark D. Tucker, Rita G. Betty
  • Patent number: 7125832
    Abstract: Laundry or cleaning composition comprising: (a) a catalytically effective amount, preferably from about 1 ppb to about 99.9%, of a transition-metal bleach catalyst which is a complex of a transition-metal and a cross-bridged macropolycyclic ligand; and (b) at least about 0.1% of one or more laundry or cleaning adjunct materials, preferably comprising an oxygen bleaching agent. Preferred compositions are laundry compositions and automatic dishwashing detergents which provide enhanced cleaning/bleaching benefits through the use of such catalysts.
    Type: Grant
    Filed: May 14, 2003
    Date of Patent: October 24, 2006
    Assignee: Procter & Gambel Company
    Inventors: Daryle Hadley Busch, Simon Robert Collinson, Timothy Jay Hubin, Christopher Mark Perkins, Regine Labeque, Barbara Kay Williams, James Pyott Johnston, David Johnathan Kitko, James Charles Theophile Roger Burckett-St. Laurent
  • Patent number: 6991747
    Abstract: A new chromotropic compound, compositions containing such a compound and methods of using such compound, such as in a test method for identifying the presence of free radicals, are disclosed.
    Type: Grant
    Filed: March 11, 2003
    Date of Patent: January 31, 2006
    Assignee: Procter & Gamble Company
    Inventors: Giuseppina Chiaradonna, Francesca Cicogna, Giovanni Ingrosso, Emanuela Franchi, Calogero Pinzino, Valerio Del Duca, Stefano Scialla
  • Patent number: 6930054
    Abstract: Disclosed herein are slurry compositions for use in CMP(chemical mechanical polishing) process of metal wiring in manufacturing semiconductor devices, comprising a peroxide, an inorganic acid, a propylenediaminetetraacetate(PDTA)-metal complex, a carboxylic acid, a metal oxide powder, and de-ionized water, wherein the PDTA-metal complex plays a major role in improving overall polishing performance and reproducibility thereof by preventing abraded tungsten oxide from readhesion onto the polished surface, as well as in improving the dispersion stability of the slurry composition.
    Type: Grant
    Filed: August 6, 2002
    Date of Patent: August 16, 2005
    Assignees: Cheil Industries, Inc., Samsung Electronics Co., Ltd.
    Inventors: Jae Seok Lee, Won Joong Do, Hyun Soo Roh, Kil Sung Lee, Jong Won Lee, Bo Un Yoon, Sang Rok Hah, Joon Sang Park, Chang Ki Hong
  • Patent number: 6916432
    Abstract: The invention provides a bleach composition or a dye composition for hair which, during use, includes a mixture of a first composition containing an alkali agent and a second composition containing an oxidizing agent, the bleach or dye composition containing (A) an organic solvent having a partition coefficient (octanol-water) (log P) at 25° C. of 0.3-6 and a molecular weight of 200 or less, in an amount of 1-70 wt. %; (B) an organic solvent having a log P of less than 0.3, in an amount of 0-8 wt. % and less than that of component (A); (C) an alkali agent in an amount of 0.1-10 wt. %; (D) an oxidizing agent in an amount of 0.1-12 wt. % as reduced to H2O2; and (E) water in an amount of 20-70 wt. %, or (A) in an amount of 1-70 wt. %; (B) in an amount of 0-8 wt. % and less than that of component (A); (C) in an amount of 0.1-10 wt. %; (D) in an amount of 0.1-12 wt. % as reduced to H2O2; (E) in an amount of 20-70 wt. %, and (F) a cationic surfactant in an amount of 0.01-10 wt. %, and has a pH of 7.
    Type: Grant
    Filed: December 26, 2001
    Date of Patent: July 12, 2005
    Assignee: Kao Corporation
    Inventors: Takashi Matsuo, Hajime Miyabe, Yutaka Shibata, Yoshiaki Ito, Keiji Monda, Daisuke Misu
  • Patent number: 6833343
    Abstract: A bleaching detergent formulation comprising the components of: (A) particles comprising 0.
    Type: Grant
    Filed: March 29, 2002
    Date of Patent: December 21, 2004
    Assignee: Kao Corporation
    Inventors: Muneo Aoyagi, Hiroshi Danjo, Masakazu Furukawa, Kazuyoshi Ozaki
  • Patent number: 6797196
    Abstract: A bleaching formulation comprising (a) a peroxy bleaching agent selected from hydrogen peroxide and a peroxide or an organic peracid capable of generating hydrogen peroxide in an aqueous solution, (b) an anionic bleaching catalyst containing a metal, and (c) a cationic compound, and a bleaching method comprising using the bleaching formulation wherein pretreatment with component (c) precedes treatment with components (a) and (b), or components (a), (b), and (c) are used simultaneously.
    Type: Grant
    Filed: January 2, 2002
    Date of Patent: September 28, 2004
    Assignee: Kao Corporation
    Inventor: Hiroshi Danjo
  • Patent number: 6764613
    Abstract: Substantially solid compositions are provided having therein a compound with the structure of Formula I wherein A is a saturated ring formed by a plurality of atoms in addition to the N1 atom, the saturated ring atoms including at least one carbon atom and at least one of O, S, and N atoms, the substituent R1 bound to the N1 atom of the Formula I structure including either (a) a C1-24 alkyl or alkoxylated alkyl where the alkoxy is C2-4, (b) a C4-24 cycloalkyl, (c) a C7-24 alkaryl, (d) a repeating or nonrepeating alkoxy or alkoxylated alcohol, where the alkoxy unit is C2-4, or (e) —CR2R3C≡N where R2 and R3 are each H, a C1-24 alkyl, cycloalkyl, or alkaryl, or a repeating or nonrepeating alkoxyl or alkoxylated alcohol where the alkoxy unit is C2-4, the R2 and R3 substituents being each H, a C1-24 alkyl, cycloalkyl, or alkaryl, or a repeating or nonrepeating alkoxyl or alkoxylated alcohol where the alkoxy unit is C2-4, Z is a value in the range of 0 to 10, and wherein Y is monovalen
    Type: Grant
    Filed: May 3, 2001
    Date of Patent: July 20, 2004
    Assignee: Mid-America Commercialization Corporation
    Inventors: Ulrich Annen, James E. Deline, Kevin A. Klotter, Michael Müller, Klaus Mundinger, Sarah A. Perkins, Martin J. Phillippi, Martin Scholtissek, Michael Schönherr, William L. Smith, Alfred G. Zielske
  • Patent number: 6653093
    Abstract: Enzyme granulates contain besides the enzyme water-soluble and water-insoluble fillers, binders and if required other additives for granulates. In order to stabilize the enzyme, an alkaline or earth alkaline metal formiate is added, as well as reducing sugar, if required. These enzyme granulates may contain all usual enzymes for washing and cleaning purposes, in particular alkaline proteases. A process for preparing these enzyme granulates, as well as their use in powdery washing product compositions are also disclosed.
    Type: Grant
    Filed: June 13, 2000
    Date of Patent: November 25, 2003
    Assignee: Genencor International, Inc.
    Inventors: Peter F. Plank, Thomas P Graycar, Matthew J. Flynn
  • Patent number: 6645927
    Abstract: A process for producing coated bleach activator granules in which bleach activator base granules are coated with a coating substance and are simultaneously and/or subsequently thermally conditioned.
    Type: Grant
    Filed: July 21, 2000
    Date of Patent: November 11, 2003
    Assignee: Clariant GmbH
    Inventors: Johannes Himmrich, Georg Borchers
  • Patent number: 6583095
    Abstract: The present invention relates to an improved process for synthesizing organic compounds for use as bleach activators.
    Type: Grant
    Filed: May 7, 2001
    Date of Patent: June 24, 2003
    Assignee: Procter & Gamble Company
    Inventors: Jeffrey Scott Dupont, Robert Richard Dykstra
  • Patent number: 6569826
    Abstract: A new chromotropic compound, compositions containing such a compound and methods of using such compound, such as in a test method for identifying the presence of free radicals, are disclosed.
    Type: Grant
    Filed: April 17, 2002
    Date of Patent: May 27, 2003
    Assignee: The Procter & Gamble Company
    Inventors: Giusepp Chiaradonna, Francesca Cicogna, Giovanni Ingrosso, Emanuela Franchi, Calogero Pinzino, Valerio Del Duca, Stefano Scialla
  • Patent number: 6569353
    Abstract: The present invention provides a universal decontamination formulation and method for detoxifying chemical warfare agents (CWA's) and biological warfare agents (BWA's) without producing any toxic by-products, as well as, decontaminating surfaces that have come into contact with these agents. The formulation includes a sorbent material or gel, a peroxide source, a peroxide activator, and a compound containing a mixture of KHSO5, KHSO4 and K2SO4. The formulation is self-decontaminating and once dried can easily be wiped from the surface being decontaminated. A method for decontaminating a surface exposed to chemical or biological agents is also disclosed.
    Type: Grant
    Filed: June 11, 1998
    Date of Patent: May 27, 2003
    Assignee: Lynntech, Inc.
    Inventors: Anthony Giletto, William White, Alan J. Cisar, G. Duncan Hitchens, James Fyffe
  • Patent number: 6566320
    Abstract: A bleaching composition that contains a bleaching agent and a chromotrophic radical scavenging compound, and a test method for identifying the presence of free radicals is disclosed. Such compositions offer improved stability.
    Type: Grant
    Filed: April 17, 2002
    Date of Patent: May 20, 2003
    Assignee: The Procter & Gamble Company
    Inventors: Giusepp Chiaradonna, Frencesca Cicogna, Giovanni Ingrosso, Calogero Pinzino, Valerio Del Duca, Stefano Scialla
  • Patent number: 6514925
    Abstract: N,N diacyl O-substituted imide bleach activators and compositions employing them are provided. The activators have the general formula: wherein X is selected from O, NR16 and S; e is 0 or 1; f is 0 or 1; R16 is selected from H and C1-C4 linear or branched, saturated or unsaturated alkyl groups; and R1 is preferably phenyl or C7-C13 linear or branched chain, saturated or unsaturated alkyl; R2 is preferably C1-C10 branched or unbranched, saturated or unsaturated alkyl and R3 is preferably C1-C12 linear or branched chain, saturated or unsaturated alkyl. Bleach additive and bleaching compositions including the bleach activators and methods of cleaning fabrics are also provided.
    Type: Grant
    Filed: May 23, 2002
    Date of Patent: February 4, 2003
    Assignee: The Procter & Gamble Company
    Inventors: Gregory Scot Miracle, Robert Richard Dykstra
  • Publication number: 20020134965
    Abstract: A bleaching formulation comprising (a) a peroxy bleaching agent selected from hydrogen peroxide and a peroxide or an organic peracid capable of generating hydrogen peroxide in an aqueous solution, (b) an anionic bleaching catalyst containing a metal, and (c) a cationic compound, and a bleaching method comprising using the bleaching formulation wherein pretreatment with component (c) precedes treatment with components (a) and (b), or components (a), (b), and (c) are used simultaneously.
    Type: Application
    Filed: January 2, 2002
    Publication date: September 26, 2002
    Inventor: Hiroshi Danjo