Abstract: The present invention aims at providing a blue-aimed phosphor powder which is more excellent in emission characteristic than the conventional rare-earth activated sialon phosphors and which is more excellent in durability than the conventional oxide phosphors. The solving means resides in: firing a starting material mixture in a nitrogen atmosphere at a temperature range between 1,500° C. inclusive and 2,200° C. inclusive, wherein the starting material mixture is a mixture of metallic compounds, and is capable of constituting a composition comprising M, A, Si, Al, O, and N (M is one kind or two or more kinds of element(s) selected from Mn, Ce, Nd, Sm, Eu, Tb, Dy, Ho, Er, Tm, and Yb; and A is one kind or two or more kinds of element(s) selected from C, Si, Ge, Sn, B, Ga, In, Mg, Ca, Sr, Ba, Sc, Y, La, Gd, Lu, Ti, Zr, Hf, Ta, and W) by firing; to obtain a phosphor which emits fluorescence having a peak at a wavelength within a range of 400 nm to 700 nm, by irradiation of an excitation source.

Abstract: Provided is a red emitting fluorescent material, which has a large excitation band and which is capable of efficiently emitting red fluorescence when excited by light emitted from an ultraviolet light emitting device and a blue light emitting device serving as an excitation source, in particular, even by use of an ultraviolet LED having an emission peak at near 390 nm to 400 nm, and which is capable of emitting red fluorescence when excited not only by ultraviolet and blue light form an ultraviolet light emitting device and a blue light emitting device also by fluorescence emitted from a fluorescence material upon receipt these light beams, thereby emitting high brightness red light, and then, provided is a white light emitting device capable of emitting white light having excellent color reproducing and rendering properties.

Abstract: The present invention is a creation of advanced scintillation materials having emission maximum in the range of about 400-450 nm and based on cerium doped a rare-earth oxyorthosilicate including LFS, LSO, LYSO, LGSO, GSO crystals having defects in comparison with ideal crystal structure, and said defects change the optical transmission and absorption spectra in the range about of 200-340 nm. The picks of maximum absorptions characterised in that the ratio of A(?1=250-270 nm)/A(?3=280-300 nm)?1, A(?2=280-300)/A(?3=340-380)?1, A(?1=250-270)/A(?2=280-300 nm)>1.

Abstract: The embodiment provides a red light-emitting fluorescent substance represented by the following formula (1): (M1-xECx)aM1bAlOcNd??(1). In the formula (1), M is an element selected from the group consisting of IA group elements, IIA group elements, IIIA group elements, IIIB group elements, rare earth elements and IVA group elements; EC is an element selected from the group consisting of Eu, Ce, Mn, Tb, Yb, Dy, Sm, Tm, Pr, Nd, Pm, Ho, Er, Cr, Sn, Cu, Zn, As, Ag, Cd, Sb, Au, Hg, Tl, Pb, Bi and Fe; M1 is different from M and is selected from the group consisting of tetravalent elements; and x, a, b, c and d are numbers satisfying the conditions of 0<x<0.2, 0.55<a<0.80, 2.10<b<3.90, 0<c?0.25 and 4<d<5, respectively. This substance emits luminescence having a peak in the wavelength range of 620 to 670 nm when excited by light of 250 to 500 nm.

Abstract: An oxynitride phosphor powder contains ?-SiAlON and aluminum nitride, obtained by mixing a silicon source, an aluminum source, a calcium source, and a europium source to produce a composition represented by a compositional formula: Cax1Eux2Si12-(y+z)Al(y+z)OzN16-z (wherein x1, x2, y and z are 0<x1?3.40, 0.05?x2?0.20, 4.0?y?7.0, and 0?z?1), and firing the mixture.

Abstract: The invention refers to a method for producing a dental restoration comprising a lithium silicate glass or glass ceramic as well as a dental restoration inself. The invention further refers to a ingot with the same composition having a defined strength.

Abstract: A phosphor includes a crystal phase of a formula (Ln,Ca,Ce)3+?Si6N11. In this formula, ? is from ?0.1 to 1.5, inclusive. When an object color of the phosphor is expressed by the L*a*b* color system, the value of (a*2+b*2)1/2 satisfies 71?(a*2+b*2)1/2. Also in the formula, Ln is La, Gd, Lu, Y, Sc, or any combination of these. When the phosphor is excited with light having a wavelength of 455 nm, it emits a color wherein x is from 0.400 to 0.570 inclusive, and y is from 0.420 to 0.590, inclusive, as expressed in the CIE standard coordinate system.

Abstract: Problem to be solved is to provide a nitride phosphor having enhanced luminance, internal quantum efficiency and external quantum efficiency compared to those of conventional nitride phosphors. The nitride phosphor is represented by the general formula (1) shown below and it is characterized in that the infrared spectroscopy measured by the diffuse reflection method at the measurement intervals of 2 cm?1 or lower, satisfies predetermined conditions: LnxSiyNn:Z??(1) (In the general formula (1), Ln represents rare earth element excluding the element to be used as an activator, Z represents an activator, x satisfies the condition of 2.7?x?3.3, y satisfies the condition of 5.4?y?6.6, and n satisfies the condition of 10?n?12.

Abstract: A complex crystal phosphor is an inorganic composition containing at least an M element, an Al element, silicon, oxygen, and nitrogen. The inorganic composition has particles having at least two types of crystal phase, and the at least two types of crystal phase include a first crystal phase which is the same as a M2SiO4 crystal and a second crystal phase as a ?-sialon crystal. Here, M is at least one element selected from the group consisting of (Mg), calcium (Ca), strontium (Sr), and barium (Ba).

Abstract: A polycrystalline scintillator for detecting soft X-rays, which comprises Ce as a light-emitting element and at least Y, Gd, Al, Ga and O, and has a garnet crystal structure, and a composition represented by the general formula of (Y1-x-zGdxCez)3+a(Al1-uGau)5-aO12, wherein 0?a?0.1, 0.15?x?0.3, 0.002?z?0.015, and 0.35?u?0.55, with 0.05-1 ppm by mass of Fe and 0.5-10 ppm by mass of Si by outer percentage, a ratio ?50/?100 of 3 or more, wherein ?50 is an absorption coefficient of X-rays at 50 keV, and ?100 is an absorption coefficient of X-rays at 100 keV, and afterglow of 800 ppm or less after 3 ms from the termination of X-ray irradiation.

Abstract: A red phosphor is provided. Also provided is a lighting apparatus containing a red phosphor.

Abstract: The present invention relates to alkaline earth metal silicate luminophores having improved long-term stability and to a corresponding method for improving the long-term stability of alkaline earth metal silicate luminophores. The luminophore according to the invention is a luminophore comprising a base lattice according to the general chemical formula EAxSiyOz, where x, y, z>0. The component EA is formed by one or more alkaline earth metals. An activator, for example Eu2+ or Mn2+, is doped into the base lattice. The luminophore has the fundamental property to absorb radiation in a first wavelength range and emit radiation in a second wavelength range that is different from the first wavelength range. The luminophore is designed in the form of crystals. According to the invention, the surfaces of the crystals of the luminophore are chemically modified such that at least portions of the surfaces thereof are formed by a chemical compound of the general formula EauZ2.

Abstract: A red phosphor of high efficiency and a method for producing it are provided. A white light source and an illumination device that allow illumination with the pure white color using the red phosphor are also provided. In addition, a liquid crystal display device using the red phosphor and exhibiting good color reproducing performance is provided. The red phosphor contains an element A, europium (Eu), silicon (Si), carbon (C), oxygen (O) and nitrogen (N) in the ratios of the numbers of atoms of the following compositional formula (1): [Chemical Formula 1] [A(m-x)Eux][Si(9-y)Cy]OnN[12-2(n-m)/3]??compositional formula (1) where the element A is at least one of magnesium (Mg), calcium (Ca), strontium (Sr) and barium (Ba), and where m, x and n in the compositional formula (1) satisfy the relationships of 3<m<5, 0<x<1, 0<y<2 and 0<n<10 (FIG. 5A).

Abstract: A thermally stable phosphor made of the M-Si—O—N system, having a cation M and an activator D, M being represented by Ba or Sr alone or as a mixture and optionally also being combined with at least one other element from the group Ca, Mg, Zn, Cu. The phosphor is activated with Eu or Ce or Tb alone or as a mixture, optionally in codoping with Mn or Yb. The activator D partially replaces the cation M. The phosphor is produced from the charge stoichiometry MO—SiO2—SiN4/3 with an increased oxygen content relative to the known phosphor MSi2O2N2:D, where MO is an oxidic compound.

Abstract: A nitride phosphor contains europium as an activating element and strontium, or strontium and calcium, as divalent metal elements. The phosphor further includes aluminum and silicon. Of the europium in the phosphor, at least 85% is in the form of Eu2+. The phosphor has a peak emission wavelength of from 590 nm to 650 nm. A phosphorescent body that includes the phosphor can be suitable for converting a wavelength of at least a portion of light emitted from an excitation light source in a light-emitting device.

Abstract: Disclosed herein is a novel group of carbonitride and carbidonitride phosphors and light emitting devices which utilize these phosphors. In certain embodiments, the inventive phosphors are expressed as follows: Cam/2Si12-(m+n)?xCxAlm+nN16-nOnEu2+??(1) M(II)m/2Si12-(m+n)?xCxM(III)m+nN16-nOn-y/2Hy:A??(2) Mm/vSi12-(m+n)?xCxM(III)m+nN16-nOn-y/2Hy:A??(3) Cam/2Si12-(m+n)+xAlm+n?xN16-n?xCxOn:Eu2+??(4) M(II)m/2Si12-(m+n)+xM(III)m+n?xN16-n?xCxOn-y/2Hy:A??(5) Mm/vSi12-(m+n)+xM(III)m+n?xN16-n?xCxOn-y/2Hy:A??(6) wherein v is the valence number of M, 0?m<5, 0?n?3, 0?x<4, and 0?y<1, M is at least one cation, M(II) is at least one divalent cation, M(III) is at least one trivalent cation, H is at least one monovalent anion, and A is a luminescence activator.

Abstract: An Li-containing ?-sialon-based phosphor represented by the formula (1): LixEuySi12?(m+n)Al(m+n)On+?N16?n?? (wherein assuming that average valence of Eu is a, x+ya+?=m; 0.455?x<1.2, 0.001?y?0.2, 0.9?m?2.5, 0.5?n?2.4, and ?>0).

Abstract: The present invention provides an organic/inorganic composite containing an inorganic phase dispersed in an organic polymer, the inorganic phase comprises one or more metal atoms that are coordinated to at least one rare earth metal atom via oxygen. The composite contains at least 5 mass % of rare earth metal. This rare earth metal is dispersed in the inorganic phase.

Abstract: Disclosed herein is a method of stabilizing alpha-sialon phosphor raw powder, including the steps of: mixing alpha-sialon phosphor raw powder including Si3N4, AlN, a rare-earth metal oxide and calcium nitride (Ca3N2) as a calcium source and having Composition Formula represented by CaxSi12?m?nAlm+nOnN16?n:Rey (here, Re is an activator and is at least one selected from the group consisting of Eu, Ce, Tb, Yb, Sm and Dy, 0.3?m?1.0, 0.02?y?0.15, m=2x+3y); and heat-treating the alpha-sialon phosphor raw powder to convert the calcium source into a Ca—Al—Si—N based compound. This method is advantageous in that a reliable alpha-sialon phosphor having high photoluminescence intensity can be manufactured regardless of weather, season, environment and the like.

Abstract: Disclosed herein is a novel family of oxycarbonitride phosphor compositions and light emitting devices incorporating the same. Within the sextant system of M—Al—Si—O—N—C—Ln and quintuplet system of M—Si—O—N—C—Ln (M=alkaline earth element, Ln=rare earth element), the phosphors are composed of either one single crystalline phase or two crystalline phases with high chemical and thermal stability. In certain embodiments, the disclosed phosphor of silicon oxycarbonitrides emits green light at wavelength between 530-550 nm. In further embodiments, the disclosed phosphor compositions emit blue-green to yellow light in a wavelength range of 450-650 nm under near-UV and blue light excitation.

Abstract: A compound is provided containing silicon, aluminum, strontium, europium, nitrogen, and oxygen is used that enables a red phosphor having strong luminous intensity and high luminance to be obtained, and that enables the color gamut of a white LED to be increased with the use of the red phosphor. The red phosphor contains an element A, curopium, silicon, aluminum, oxygen, and nitrogen at the atom number ratio of the following formula: [A(m-x)Eux]Si9AlyOnN[12+y-2(n-m)/3]. The element A in the formula is at least one of magnesium, calcium, strontium, and barium, and m, x, y, and n in the formula satisfy the relations 3<m<5, 0<x<1, 0<y<2, and 0<n<10.

Abstract: A green phosphor for emitting light, a spectrum of which is sharp, in an ultraviolet and visible light region, which has higher green light brightness than the conventional rare earth-activated sialon phosphor and has higher durability than the conventional oxide phosphor, is provided. The phosphor being characterized in that Al and a metal element M (here, M is Eu) are incorporated into a crystal of a nitride or oxynitride having a ?-type Si3N4 crystal structure as a solid solution, the content of oxygen in the crystal does not exceed 0.8% by mass, and the phosphor emits a visible light having a luminescence peak wavelength in the range of 450 nm to 650 nm upon exposure to an excitation source is provided. This luminescence spectrum has a sharp spectrum shape. Further, a manufacturing method of the phosphor, a lighting device and an image display device utilizing the phosphor are also provided.

Abstract: Compositions, methods of making compositions, materials including compositions, crayons including compositions, paint including compositions, ink including compositions, waxes including compositions, polymers including compositions, vesicles including the compositions, methods of making each, and the like are disclosed.

Abstract: A titanium doped ternary system silicate film is provided, wherein the titanium doped ternary system silicate film has the general formula, of Ca2-xMgSi2O7:xTi4+, where x has a value of 0.00017˜0.0256. The preparation method of the titanium doped tenuity system silicate film and the application of the titanium doped ternary system ,silicate film obtained by the method in field emission de ices cathode my tubes and/or electroluminescent devices are also provided.

Abstract: Blue light emitting glass and the preparation method thereof are provided. The blue light emitting glass has the following composition: aCaO.bAl2O3.cSiO2.xCeO2, wherein a, b, c and x are, by mol part, 15-55, 15-35, 20-60 and 0.01-5 respectively. The preparation method comprises: weighing the raw materials according to the composition of the blue light emitting glass; mixing the raw materials uniformly and melting the raw materials to obtain glass melt; molding the glass melt to obtain transparent glass; thermally treating the transparent glass under reducing atmosphere, and thereafter obtaining the finished product. The blue light emitting glass obtained has intense broadband excitation spectrum in ultraviolet region and emits intense blue light under the excitation of ultraviolet light. It is suitable for using as luminescent medium material.

Abstract: There are provide a silicate-based phosphor excellent in emission intensity and a manufacturing method of the same. A manufacturing method of a silicate-based phosphor is characterized by: introducing in a vessel raw material powders having a compound containing light-emitting ions selected from at least one of Eu, Ce, Mn, and Tb; and firing the raw material powders while supplying SiOx (0.5?x?1.9, preferably, 0.8?x?1.2) in a gas phase. The raw material powders preferably further contains at least one of an alkali metal compound, an alkaline-earth metal compound, a magnesium compound, and a rare-earth compound. The silicate-based phosphor is preferably M2SiO4:Eu2+ (wherein M is one or more selected from a group consisting of Ca, Sr and Ba). The firing is preferably performed by supplying the SiOx to the raw material powders in a gas atmosphere at a temperature of 1200 to 1700° C. and subjecting the raw material powders to a gas-solid phase reaction at a temperature of 700 to 1700° C.

Abstract: The present invention provides a fluorescent substance excellent both in quantum efficiency and in temperature characteristics, and also provides a light-emitting device utilizing the fluorescent substance. This fluorescent substance contains an inorganic compound comprising a metal element M, a trivalent element M1 other than the metal element M, a tetravalent element M2 other than the metal element M, and either or both of O and N. In the inorganic compound, the metal element M is partly replaced with a luminescence center element R. The crystal structure of the fluorescent substance is basically the same as Sr3Al3Si13O2N21, but the chemical bond lengths of M1-N and M2-N are within the range of ±15% based on those of Al—N and Si—N calculated from the lattice constants and atomic coordinates of Sr3Al3Si13O2N21, respectively. The fluorescent substance emits luminescence having a peak in the range of 490 to 580 nm when excited with light of 250 to 500 nm.

Abstract: The invention relates to compounds of the formula (I) (Ca,Sr,Ba)6-X(Si1-yMey)3(O1-zMa2z)6N4:Eux (I), where Me=Th, Ru and/or Os Ma=F and/or Cl, x<0.5, y<1 and z<0.1, and to a process for the preparation of these compounds and use as phosphors and conversion phosphors for the conversion of the blue or near-UV emission from an LED.

Abstract: Disclosed is a phosphor having a formula of (Sr1?a?b?cMaTmbEuc)3Si1?dGedO5. Sr, M, Tm, and Eu are divalent metal ions, and M is selected from Ca, Ba, Mg, or combinations thereof. Si and Ge are tetravalent ions. 0?a?0.5, 0?b?0.03, 0<c?0.1, and 0<d?0.005. The phosphor can be collocated with a yellow phosphor and a blue light excitation source to complete a warm white light emitting device.

Abstract: The invention relates to a persistent phosphorescent ceramic composite material which is a sintered dense body comprising two or more phases, a first phase consisting of at least one metal oxide and a second phase consisting of a metal oxide containing at least one activating element in a reduced oxidation state. The invention furthermore relates to a method for the preparation of a phosphorescent ceramic composite material as defined in any of the previous claims, the method comprising the following steps: preparing a mixture of a metal oxide and a phosphor; fabricating a green body from the mixture; and heat treating the green body in a reducing atmosphere.

Abstract: Provided is a production method of a ?-type sialon fluorescent substance, where luminescence intensity can be improved without adding a metal element other than elements composing a ?-type sialon fluorescent substance. Namely, in a production method of a fluorescent substance containing an optically-active element as the luminescence center in a crystal of nitride or acid nitride, a ?-type sialon fluorescent substance is produced by a burning process for heat-treating a mixture including metal compound powder and an optically-active element compound; a high-temperature annealing process for heat-treating the burned product after cooling under a nitrogen atmosphere; a rare-gas annealing process for heat-treating the high-temperature annealed product under a rare gas atmosphere; and a process for treating the rare-gas treated product with an acid.

Abstract: A phosphor as a divalent europium-activated oxynitride green light emitting phosphor which is a ?-type SiAlON substantially represented by a general formula (A): EuaSibAlcOdNe (where a, b, c, d, and e are numbers satisfying 0.005?a?0.4, b+c=12, and d+e=16), and having an average particle size (d1) (determined by an air permeability method) of 9 to 16 ?m, a median diameter (50% D) in particle size distribution of 12.5 to 35 ?m, 50% D/d1 of 1.4 to 2.2, and an absorptance at 600 nm of not more than 8.0%, and a light emitting apparatus, a BL light source apparatus, and a liquid crystal display device using the same are provided, to provide a light emitting apparatus with a high efficiency and a stable characteristic and a liquid crystal display apparatus using the same by using the ?-type SiAlON having controlled dispersibility and improved transparency.

Abstract: Provided is a metal oxonitridosilicate phosphor of a general formula M5?z?a?bAl3+xSi23?xN37?x?2aOx+2a: Euz, Mnb, wherein M is one or more alkaline earth metals; 0?x?7; 0?a?1; 0<z?0.3; and 0<b?0.3.

Abstract: A method of modifying a phosphor and a phosphor composition and a manufacturing method of the same and a phosphor solution are provided. The phosphor composition includes a silicone resin and a modified phosphor. The modified phosphor includes a phosphor and a nano-silica particle. The nano-silica particle is adhered to the phosphor. A weight ratio of the modified phosphor to the silicone resin is substantially between 1:0.005 and 1:0.1.

Abstract: A compound is provided containing silicon, aluminum, strontium, europium, nitrogen, and oxygen is used that enables a red phosphor having strong luminous intensity and high luminance to be obtained, and that enables the color gamut of a white LED to be increased with the use of the red phosphor. The red phosphor contains an element A, europium, silicon, aluminum, oxygen, and nitrogen at the atom number ratio of the following formula: [A(m?x)Eux]Si9AlyOnN[12+y?2(n?m)/3]. The element A in the formula is at least one of magnesium, calcium, strontium, and barium, and m, x, y, and n in the formula satisfy the relations 3<m<5, 0<x<1, 0<y<2, and 0<n<10.

Abstract: Exemplary embodiments of the present invention disclose inorganic luminescent substances with Eu2+-doped silicate luminophores, in which solid solutions in the form of mixed phases between alkaline earth metal oxyorthosilicates and rare earth metal oxyorthosilicates are used as base lattices for the Eu2+ activation leading to the luminescence. These luminophores are described by the general formula (1-x) MII3SiO5.xSE2SiO5:Eu, in which MII preferably represents strontium ion or another alkaline earth metal ion, or another divalent metal ion selected from the group consisting of the magnesium, calcium, barium, copper, zinc, and manganese. These ions may be used in addition to strontium and also as mixtures with one another.

Abstract: Bismuth ion sensitized rare earth germanate luminescence materials and preparation methods are disclosed. The luminescence materials are the compounds of the following general formula (Y1-x-y-zAxBiyLnz)2GeO5. The preparation methods comprise: using oxides, carbonates, oxalates, acetates, nitrates or halides of Y, A, Bi, Ln and Ge as raw materials, wherein A is one of Gd, Lu, Sc and La, and Ln is at least one of Tm, Ho, Sm, Tb, Eu and Dy, homogeneously grinding the raw materials, sintering at 1300-1500° C. for 6-24 h, and then cooling them to room temperature to obtain the bismuth ion sensitized rare earth germanate luminescence materials.

Abstract: A phosphor which emits light having high brightness, serves as an excellent orange or red phosphor whose light brightness is less decreased when exposed to an excitation source contains a crystal phase having the chemical composition expressed by the general formula [1]: (1?a?b)(Ln?pMII?1?pMIII?MIV?N3).a(MIV?(3n+2)/4NnO).b(AMIV?2N3)??[1] wherein Ln? represents a metal element selected from the group consisting of lanthanoids, Mn, and Ti; MnII? represents a divalent metal element except the Ln? element; MIII? represents a trivalent metal element; MIV? represents a tetravalent metal element; A represents a metal element selected from the group consisting of Li, Na, and K; 0<p?0.2; 0?a, 0?b, a+b>0, 0?n, and 0.002?(3n+2)a/4?0.9.

Abstract: The invention relates to an inorganic scintillator material of formula Lu(2-y)Y(y-z-x)CexMzSi(1-v)M?vO5, in which: M represents a divalent alkaline earth metal and M? represents a trivalent metal, (z+v) being greater than or equal to 0.0001 and less than or equal to 0.2; z being greater than or equal to 0 and less than or equal to 0.2; v being greater than or equal to 0 and less than or equal to 0.2; x being greater than or equal to 0.0001 and less than 0.1; and y ranging from (x+z) to 1. In particular, this material may equip scintillation detectors for applications in industry, for the medical field (scanners) and/or for detection in oil drilling. The presence of Ca in the crystal reduces the afterglow, while stopping power for high-energy radiation remains high.

Abstract: A compound is provided containing silicon, aluminum, strontium, europium, nitrogen, and oxygen is used that enables a red phosphor having strong luminous intensity and high luminance to be obtained, and that enables the color gamut of a white LED to be increased with the use of the red phosphor. The red phosphor contains an element A, europium, silicon, aluminum, oxygen, and nitrogen at the atom number ratio of the following formula: [A(m?x)Eux]Si9AlyOnN[12+y?2(n?m)/3]. The element A in the formula is at least one of magnesium, calcium, strontium, and barium, and m, x, y, and n in the formula satisfy the relations 3<m<5, 0<x<1, 0<y<2, and 0<n<10.

Abstract: It is provided a fluorescent zirconia material including a fluorescent component and emitting fluorescence when excited with a light of a predetermined wavelength, the fluorescent component including a fluorescent material, the fluorescent material including at least one kind of Y2SiO5:Ce, Y2SiO5:Tb, (Y, Gd, Eu)BO3, Y2O3:Eu, YAG:Ce, ZnGa2O4:Zn and BaMgAl10O17:Eu and the fluorescent material being capable of emiting the fluorescence when subjected to firing treatment at temperatures ranging from 1300 to 1600(° C.) under oxidizing environments.

Abstract: Phosphor that can provide white LED that uses a blue LED or an ultraviolet LED as a light source and that has superior luminous efficiency. This phosphor includes, as a main component, ?-type sialon represented by a general expression: (M1)x(M2)y(Si,Al)12(O,N)16 (where M1 is one or more types of elements selected from a group consisting of Li, Mg, Ca, Y, and lanthanide element (except for La and Ce) and M2 is one or more types of elements selected from a group consisting of Ce, Pr, Eu, Tb, Yb, and Er, and 0.3?X+Y?1.5 and 0<y?0.7 are established and the sialon phosphor consists of a powder having a specific surface area of 0.2 to 0.5 m2/g.

Abstract: The present invention provides a fluorescent substance excellent both in quantum efficiency and in temperature characteristics, and also provides a light-emitting device utilizing the fluorescent substance. This fluorescent substance contains an inorganic compound comprising a metal element M, a trivalent element M1 other than the metal element M, a tetravalent element M2 other than the metal element M, and either or both of O and N. In the inorganic compound, the metal element M is partly replaced with a luminescence center element R. The crystal structure of the fluorescent substance is basically the same as Sr3Al3Si13O2N21, but the chemical bond lengths of M1-N and M2-N are within the range of ±15% based on those of Al—N and Si—N calculated from the lattice constants and atomic coordinates of Sr3Al3Si13O2N21, respectively. The fluorescent substance emits luminescence having a peak in the range of 490 to 580 nm when excited with light of 250 to 500 nm.

Abstract: A green-emitting phosphor having the formula AaBbCcOdNe:RE, wherein A is a positively charged divalent element; B is a positively charged trivalent element; C is a positively charged tetravalent element; and RE is a rare earth activator. The parameter a ranges from about 0.5 to about 1.5; the parameter b ranges from about 0.8 to about 3.0; the parameter c ranges from about 3.5 to about 7.0; the parameter d ranges from about 0.1 to about 3.0; and the parameter e ranges from about 5.0 to about 11.0. A is at least one of Mg, Ca, Sr, Ba, and Zn; B (the letter) is at least one of B (boron), Al, Ga, and In; C (the letter) is at least one of C (carbon), Si, Ge, and Sn; O is oxygen; N is nitrogen; and RE is at least one of Eu, Ce, Pr, Tb, and Mn.

Abstract: Light emitting devices that include an energy source configured to generate light energy and an up-conversion phosphor configured to emit light having a wavelength shorter than that of the light energy generated from the energy source are provided. The up-conversion phosphor comprises an ordered oxyfluoride compound having a formula: A3?3a/2RaMO4??1?w?F1??2?w?Nw. Methods are also generally disclosed for up-converting light energy.

Abstract: A red-emitting phosphor comprises a nitride-based composition represented by the chemical formula M(x/v)M?2Si5-xAlxN8:RE, wherein: M is at least one monovalent, divalent or trivalent metal with valence v; M? is at least one of Mg, Ca, Sr, Ba, and Zn; and RE is at least one of Eu, Ce, Tb, Pr, and Mn; wherein x satisfies 0.1?x<0.4, and wherein the phosphor has the general crystalline structure M?2Si5N8:RE, Al substitutes for Si within the crystalline structure, and M is located substantially at interstitial sites. Furthermore, the phosphor is configured such that 1,000 hours of aging at 85° C. and 85% humidity results in a deviation in chromaticity coordinates CIE ?x and ?y of less than about 0.03. Furthermore, the phosphor absorbs radiation in the UV and blue and emits light with a photoluminescence peak wavelength within the range from about 620 to 650 nm.

Abstract: There are provided a phosphor which is a divalent europium-activated oxynitride phosphor substantially represented by General formula (A): EuaSibAlcOdNe, a divalent europium-activated oxynitride phosphor substantially represented by General formula (B): MIfEugSihAlkOmNn or a divalent europium-activated nitride phosphor substantially represented by General formula (C): (MIIl-pEup)MIIISiN3, having a reflectance of light emission in a longer wavelength region of visible light than a peak wavelength of 95% or larger, and a method of producing such phosphor; a nitride phosphor and an oxynitride phosphor which emit light efficiently and stably by the light having a wavelength ranging from 430 to 480 nm from a semiconductor light emitting device by means of a light emitting apparatus using such phosphor, and a producing method of such phosphor; and a light emitting apparatus having stable characteristics and realizing high efficiency.

Abstract: ?-sialon phosphor that is ?-sialon represented by a general expression: (M)x(Eu)y(Si, Al)12(O, N)16 (where M is one or more types of elements selected from a group consisting of Li, Mg, Ca, and Y as well as lanthanide element (except for La and Ce) and including at least Ca), the ?-sialon phosphor being structured so that an oxygen content is 1.2 mass % or less and primary particles constituting the ?-sialon have a columnar shape. When the ?-sialon phosphor receives ultraviolet rays or visible light having a wavelength from 250 to 500 nm as an excitation source, the ?-sialon phosphor shows a fluorescent characteristic having a peak in a wavelength region from 595 to 630 nm.

Abstract: The embodiment provides a process for production of an oxynitride fluorescent substance. In the process, a compound represented by the formula: (Sr,Eu)2Si5N8, silicon nitride and aluminum nitride are mixed and then fired in a nitrogen atmosphere under high pressure.

Abstract: A phosphor including a main production phase of a phosphor expressed by a composition formula of MmAaBbOoNn:Zz (where an element M is one or more bivalent elements, an element A is one or more trivalent elements, an element B is one or more tetravalent elements, O is oxygen, N is nitrogen, an element Z is an activator, n=2/3m+a+4/3b?2/3o, m/(a+b)?1/2, (o+n)/(a+b)>4/3, wherein m=a=b=1 and o and n is not 0). A phosphor including 24 wt % to 30 wt % of Ca (calcium), 17 wt % to 21 wt % of Al (aluminum), 18 wt % to 22 wt % of Si (silicon), 1 wt % to 15 wt % of oxygen, 15 wt % to 33 wt % of nitrogen and 0.01 wt % to 10 wt % of Eu (europium), wherein an emission maximum in an emission spectrum is in a range of 600 nm to 660 nm; and wherein color chromaticity x of light emission is in a range of 0.5 to 0.7, and color chromaticity y of the light emission is in a range of 0.3 to 0.5.