Group Iv Element Containing Patents (Class 252/301.4F)
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Publication number: 20140048742Abstract: The fluorescent substance according to one embodiment of the present invention has the following compositional formula (1): [Compositional formula 1] SrySi(6?z)AlzOzN(8?z):Rex. Here, x, y and z are respectively 0.005?x?0.05, 0.05?y?0.5, 0.001?z?0.50, and Re is a rare earth element. As a result, the fluorescent substance according to one embodiment of the present invention can exhibit a short wavelength of between 525 nm and 537 nm when the concentration of strontium is between 0.05 moles and 0.5 moles. Also, the fluorescent substance can exhibit a short wavelength of between 525 nm and 537 nm by the addition of barium in a range of between 0.003 moles and 0.125 moles when the concentration of aluminium is high. Also, the fluorescent substance can exhibit a short wavelength of between 525 nm and 537 nm by adjusting the oxygen concentration by the addition not only of AlN but also of Al2O3 as an aluminium precursor when the concentration of aluminium is high.Type: ApplicationFiled: February 6, 2012Publication date: February 20, 2014Applicant: SAMSUNG ELECTRONICS CO., LTD.Inventors: Hyong Sik Won, Seong Min Kim, Chan Suk Min, Chul Soo Yoon
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Patent number: 8652358Abstract: The present invention provides an Al—C—O based phosphor using neither heavy metal nor rare metal and composed of elements with high environmental compatibility and excellent economic efficiency, wherein the wavelength of the peak intensity of the emission spectrum can be changed without changing the basic composition. An aluminum oxide phosphor which comprises aluminum (Al), carbon (C), and oxygen (O) respectively in an amount of 30 mol %<Al<60 mol %, 0 mol %<C<10 mol %, 30 mol %<O<70 mol % is provided. The above problem is solved in the production of an Al—C—O phosphor comprising aluminum (Al), carbon (C), and oxygen (O) by heating and firing a mixture comprising an aluminum-containing compound and a coordinatable oxygen-containing compound.Type: GrantFiled: March 31, 2010Date of Patent: February 18, 2014Assignees: Hiroshima University, Kuraray Co., Ltd.Inventors: Kikuo Okuyama, Ferry Iskandar, Yutaka Kaihatsu, Jun Takai, Hideharu Iwasaki
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Patent number: 8652357Abstract: Disclosed are a phosphor, a method for preparing and using the same, a light emitting device package, a surface light source apparatus, a lighting apparatus using the phosphor, and a display apparatus. The phosphor includes an inorganic compound represented by an empirical formula (Sr, M)2SiO4-xNy:Eu, where M is a metallic element, 0<x<4, and y=2x/3.Type: GrantFiled: October 22, 2010Date of Patent: February 18, 2014Assignee: Samsung Electronics Co., Ltd.Inventors: Jeong Ho Ryu, Chul Soo Yoon, Hyong Sik Won
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Patent number: 8652359Abstract: The embodiment provides a red light-emitting fluorescent substance represented by the following formula (1): (M1-xECx)aM1bAlOcNd??(1). In the formula (1), M is an element selected from the group consisting of IA group elements, IIA group elements, IIIA group elements, IIIB group elements, rare earth elements and IVA group elements; EC is an element selected from the group consisting of Eu, Ce, Mn, Tb, Yb, Dy, Sm, Tm, Pr, Nd, Pm, Ho, Er, Cr, Sn, Cu, Zn, As, Ag, Cd, Sb, Au, Hg, Tl, Pb, Bi and Fe; M1 is different from M and is selected from the group consisting of tetravalent elements; and x, a, b, c and d are numbers satisfying the conditions of 0<x<0.2, 0.63<a<0.80, 2.1<b<2.63, 0<c?0.24 and 4<d<5, respectively. This substance emits luminescence having a peak in the wavelength range of 620 to 670 nm when excited by light of 250 to 500 nm.Type: GrantFiled: February 25, 2013Date of Patent: February 18, 2014Assignee: Kabushiki Kaisha ToshibaInventors: Aoi Okada, Yumi Fukuda, Naotoshi Matsuda, Iwao Mitsuishi, Shinya Nunoue
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Publication number: 20140042365Abstract: A green-emitting phosphor having the formula AaBbCcOdNe,:RE, wherein A is a positively charged divalent element; B is a positively charged trivalent element; C is a positively charged tetravalent element; and RE is a rare earth activator. The parameter a ranges from about 0.5 to about 1.5; the parameter b ranges from about 0.8 to about 3.0; the parameter c ranges from about 3.5 to about 7.0; the parameter d ranges from about 0.1 to about 3.0; and the parameter e ranges from about 5.0 to about 11.0. A is at least one of Mg, Ca, Sr, Ba, and Zn; B (the letter) is at least one of B (boron), Al, Ga, and In; C (the letter) is at least one of C (carbon), Si, Ge, and Sn; O is oxygen; N is nitrogen; and RE is at least one of Eu, Ce, Pr, Tb, and Mn.Type: ApplicationFiled: October 2, 2012Publication date: February 13, 2014Applicant: INTEMATIX CORPORATIONInventors: Shengfeng Liu, Dejie Tao, Yi-Qun Li
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Patent number: 8636920Abstract: A method for industrially producing a phosphor with high performance, in particular, high brightness. Also disclosed is a nitrogen-containing alloy and an alloy powder useful for producing the high performance phosphor. The method for producing the phosphor includes heating a raw material for a phosphor in whole or in part comprising an alloy containing two or more different metal elements under a nitrogen-containing atmosphere and heating the raw material for a phosphor under conditions such that the temperature change per minute is 50° C. or lower. Using an alloy as all or part of the raw material constituting the phosphor precursor, it is possible to suppress the rapid progression of nitridation during heat treatment and industrially produce a phosphor with high performance, in particular, high brightness.Type: GrantFiled: January 5, 2012Date of Patent: January 28, 2014Assignee: Mitsubishi Chemical CorporationInventors: Naoto Kijima, Hiromu Watanabe, Keiichi Seki
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Patent number: 8628686Abstract: The embodiment provides a process for production of an oxynitride fluorescent substance. In the process, a compound represented by the formula: (Sr,Eu)2Si5N8, silicon nitride and aluminum nitride are mixed and then fired in a nitrogen atmosphere under high pressure.Type: GrantFiled: February 28, 2011Date of Patent: January 14, 2014Assignee: Kabushiki Kaisha ToshibaInventors: Naotoshi Matsuda, Yumi Fukuda, Masahiro Kato
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Patent number: 8628687Abstract: An oxynitride phosphor includes an ?-sialon as the main component, which is represented by the formula: MxSi12?(m+n)Al(m+n)OnN16?n:Lny (wherein 0.3?x+y<1.5, 0<y<0.7, 0.3?m<4.5, 0<n<2.25, and assuming that the atomic valence of the metal M is a and the atomic valence of the lanthanide metal Ln is b, m=ax+by) and in which the aggregation index, A1=D50/DBET?3.0 or the aggregation index A2=D50/Dparticle?3.0; and a production method and usage of the phosphor.Type: GrantFiled: September 12, 2012Date of Patent: January 14, 2014Assignee: Ube Industries, Ltd.Inventors: Takeshi Yamao, Tetsuo Yamada, Shin-ichi Sakata
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Publication number: 20140001403Abstract: Provided is a phosphor which comprises alkali earth ions, Si ion, N ion and Tb ion. Tb ion is used as a luminescence center. The phosphor has broad emission bands after excitation. The phosphor of the present invention can be used for a light emitting apparatus, and meets the need of the industrial application.Type: ApplicationFiled: April 1, 2013Publication date: January 2, 2014Applicant: NATIONAL TAIWAN UNIVERSITYInventor: NATIONAL TAIWAN UNIVERSITY
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Publication number: 20140001404Abstract: The present invention relates to an inorganic nitride-based fluorescent material, comprising an inorganic fluorescent host material represented by the following formula (I): (M)xSiyNz:At ??(I) wherein, M is at least one metal selected from the group consisting of metals of IIA and IIIA, and x is from 1.0 to 3.0, and y is from 0.7 to 6.0, and z is from 1.0 to 9.0 and At is an activator; and a surface coating material is at least one metal oxide, metal hydroxide or metal carbonate, and the metal of the metal oxide, the metal hydroxide or the metal carbonate is selected from the group consisting of Mg, Ca, Sr, Ba, V, Cr, Mn, Fe, Co, Ni, Cu, La, Ga, In, Sn, Sb and Bi.Type: ApplicationFiled: June 28, 2013Publication date: January 2, 2014Inventor: Chung-Hsin LU
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Patent number: 8617422Abstract: Crystals with improved scintillation and optical properties are achieved by codoping with a trivalent dopant and a divalent and/or a monovalent dopant. Embodiments include codoping LSO, YSO, GSO crystals and LYSO, LGSO, and LYGSO crystals. Embodiments also include codoped crystals with a controlled monovalent or divalent:trivalent dopant ratio of from about 1:1 for increased light yield to about 4:1 for faster decay time.Type: GrantFiled: September 28, 2009Date of Patent: December 31, 2013Assignees: Siemens Medical Solutions USA, Inc., University of Tennessee Research FoundationInventors: Merry Anna Koschan, Charles L. Melcher, Lars A. Erikkson, Harold E. Rothfuss
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Patent number: 8613869Abstract: A practical novel phosphor material composed of an ?-type silicon nitride, i.e., an ?-type silicon nitride phosphor containing a fluorescence-emittable element throughout an ?-type silicon nitride particle from the surface to the inside, is provided. Portions having a high emittable element concentration are preferably present like islands, and the fluorescence-emittable element is preferably a lanthanide metal. A powder composed of a fluorescence-emittable element is added to silicon diimide (Si(NH)2) or an amorphous silicon nitride powder obtained by thermally decomposing silicon diimide (Si(NH)2), the powders are mixed, and the mixture is fired in a non-oxidizing atmosphere, whereby the phosphor material is obtained.Type: GrantFiled: March 4, 2008Date of Patent: December 24, 2013Assignee: Ube Industries, Inc.Inventors: Shin-ichi Sakata, Hiroshi Oda, Takuma Sakai
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Patent number: 8608980Abstract: A method for providing a phosphor, including a kneading step in which a raw material is kneaded to provide a raw material mixture; a sintering step in which the raw material mixture is sintered; and a heat treatment step in which the sintered raw material mixture is heat-treated, wherein the raw material includes at least one or more M-containing materials selected from MSi2, MSiN2, M2Si5N8, M3Al2N4 and MSi6N8, wherein M is one or more divalent elements selected from M(0) and M(1).Type: GrantFiled: February 12, 2013Date of Patent: December 17, 2013Assignee: National Institute for Materials ScienceInventors: Kousuke Shioi, Naoto Hirosaki, Hisayuki Miki
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Patent number: 8608979Abstract: A luminescent particle includes an interior portion of the luminescent particle comprising a luminescent compound that reacts with atmospherically present components and a passivating layer on an outer surface of the luminescent particle that is operable to inhibit the reaction between the luminescent compound and the atmospherically present components.Type: GrantFiled: September 12, 2012Date of Patent: December 17, 2013Assignee: Cree, Inc.Inventors: Brian Thomas Collins, Jesse Colin Reiherzer, Florin A. Tudorica
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Patent number: 8603361Abstract: Provided is a fluorescent substance excellent in quantum efficiency and in temperature characteristics, and a light-emitting device utilizing the fluorescent substance. This fluorescent substance contains an inorganic compound comprising a metal element M, a trivalent element M1 other than the metal element M, a tetravalent element M2 other than the metal element M, and either or both of O and N. In the inorganic compound, the metal element M is partly replaced with a luminescence center element R. The crystal structure of the fluorescent substance is basically the same as Sr3Al3Si13O2N21, but the chemical bond lengths of M1-N and M2-N are within the range of ±15% based on those of Al—N and Si—N calculated from the lattice constants and atomic coordinates of Sr3Al3Si13O2N21, respectively. The fluorescent substance emits luminescence having a peak in the range of 490 to 580 nm when excited with light of 250 to 500 nm.Type: GrantFiled: May 15, 2012Date of Patent: December 10, 2013Assignee: Kabushiki Kaisha ToshibaInventors: Yumi Fukuda, Hironori Asai
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Publication number: 20130320261Abstract: A method for preparing a phosphor that comprises a crystalline oxide having M1O3 (M1 is a tetravalent metallic element) as a main backbone thereof and essentially including a halogen element X (X is at least one element selected from a group consisting of F, Cl, Br, and I) and divalent metal ions M2 and Eu2+, includes using a compound represented by a compositional formula NH4X as a starting material when synthesizing the phosphor. At least a compound represented by a compositional formula NH4Cl may be used as the starting material.Type: ApplicationFiled: August 7, 2013Publication date: December 5, 2013Applicant: Koito Manufacturing Co., Ltd.Inventors: Yasutaka SASAKI, Hisayoshi DAICHO, Takeshi IWASAKI
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Patent number: 8597542Abstract: The invention relates to luminous substances which contain Eu2+ doping and at least one silicate mineral from the garnet group and/or a mono and/or polycrystalline yttrium-aluminum garnet (YAG) and/or a luminous substance derived from Y3Al5O12 by partial or complete substitution, and to the production and use thereof.Type: GrantFiled: May 7, 2010Date of Patent: December 3, 2013Assignee: Schott AGInventor: Peter Nass
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Patent number: 8597543Abstract: Compounds of the following Formula may be useful as phosphors in solid state light emitting devices: AaBbCcDdEe, wherein A includes calcium (Ca), strontium (Sr), barium (Ba), magnesium (Mg), yttrium (Y), hafnium (Hf), the lanthanide elements and/or the other alkaline earth (Group IIA) metals; B includes Eu2+ and Ce3+; C includes at least one tetrahedrally-coordinated trivalent element; D includes at least one tetrahedrally-coordinated tetravalent element; E includes N, O, F, C, S, Cl, Br and/or I, wherein a+b=1, c+d=2, and wherein the compound has a CaAlSiN3-type crystal structure. Light emitting devices including such phosphors may emit warm white light.Type: GrantFiled: February 6, 2012Date of Patent: December 3, 2013Assignee: Cree, Inc.Inventor: Ronan P. Le Toquin
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Patent number: 8597545Abstract: Red-emitting phosphors may comprise a nitride-based composition represented by the chemical formula MaSrbSicAldNeEuf, wherein: M is at least one of Mg, Ca, Sr, Ba, Y, Li, Na, K and Zn, and 0<a<1.0; 1.5<b<2.5; 4.0?c?5.0; 0?d?1.0; 7.5<e<8.5; and 0<f<0.1; wherein a+b+f>2+d/v and v is the valence of M. Furthermore, nitride-based red-emitting phosphor compositions may be represented by the chemical formula MxM?2Si5?yAlyN8:A, wherein: M is Mg, Ca, Sr, Ba, Y, Li, Na, K and Zn, and x>0; M? is at least one of Mg, Ca, Sr, Ba, and Zn; 0?y?0.15; and A is at least one of Eu, Ce, Tb, Pr, and Mn; wherein x>y/v and v is the valence of M, and wherein the red-emitting phosphors have the general crystalline structure of M?2Si5N8:A.Type: GrantFiled: June 19, 2013Date of Patent: December 3, 2013Assignee: Intematix CorporationInventors: Shengfeng Liu, Yi-Qun Li, Ka Y. Leung, Dejie Tao
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Publication number: 20130313478Abstract: The present invention relates generally to the field of synthetic crystal, and more particularly, this invention relates to doped low-temperature phase barium metaborate single crystal, growth method and frequency-converter. Molten salt method was adopted. The single crystal completely overcome the shortcomings of BBO with strong deliquescence, almost no deliquescence; its frequency doubling effect and optical damage threshold has improved greatly compared with the BBO; its hardness increased significantly, the single crystal with Shore hardness of 101.3 and Mohs hardness of 6, however, BBO with Shore hardness of 71.2 and Mohs hardness of 4. From the UV-Vis region transmittance curves tests, the cut-off wavelength of the single crystal is 190 nm, wavelength of absorption onset is 205 nm. BBSAG is widely applied in the fields of laser and nonlinear optics, and in terms of frequency-converter of ultraviolet and deep-ultraviolet due to its excellent properties better than BBO.Type: ApplicationFiled: May 7, 2013Publication date: November 28, 2013Applicant: FUJIAN INSTITUTE OF RESEARCH ON THE STRUCTURE OF MATTER, CHINESE ACADEMY OF SCIENCESInventor: FUJIAN INSTITUTE OF RESEARCH ON THE STRUCTURE OF MATTER, CHINESE ACADEMY OF SCIENCES
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Patent number: 8591768Abstract: A kind of germanate luminescence material and its preparation. The germanate luminescence material is a compound of following formula: (Y1-xLnx)2GeO5, or Y in the said formula is partly or entirely substituted by at least one of Gd, Lu, Sc and La, and x is 0<x?0.3, and Ln is one of Ce, Tm, Ho, Sm, Tb, Eu and Dy. The preparation is grinding the raw material, and then sintering at 1300-1500° C. for 6-24 h, and cooling the sintered product to room temperature, and obtaining the germanate luminescence material.Type: GrantFiled: March 18, 2009Date of Patent: November 26, 2013Assignee: Ocean's King Lighting Science & Technology Co., Ltd.Inventors: Mingjie Zhou, Wenbo Ma, Zhaopu Shi
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Publication number: 20130306911Abstract: A method of manufacturing fluorescent material-dispersed glass, comprising: performing production of a fluorescent material-dispersed gel utilizing sol-gel reaction and acid-base reaction by preparing a fluorescent material-dispersed sol containing silicon alkoxide, metal chloride and/or metal aklkoxide, and fluorescent material, and subsequently gelling the fluorescent material-dispersed sol; and performing production of a fluorescent material-dispersed glass by heating the fluorescent material-dispersed gel.Type: ApplicationFiled: February 1, 2012Publication date: November 21, 2013Applicant: NATIONAL INSTITUTE FOR MATERIALS SCIENCEInventors: Hiroyo Segawa, Hisato Yoshimizu, Satoru Inoue, Naoto Hirosaki
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Patent number: 8585927Abstract: The present invention provides semiconductor-nanoparticle-dispersed small silica glass particles that emit bright fluorescent light with high fluorescence quantum yield and high density, compared to the conventional semiconductor-nanoparticle-dispersed small glass particles, and that have excellent fluorescence intensity stability over time; and a process for preparing the same. The semiconductor-nanoparticle-dispersed silica glass particles have a mean particle size of not less than 10 nanometers and not more than 5 micrometers, and contain a hydrolyzed alkoxide and semiconductor nanoparticles at a concentration of not less than 2×10?5 mol/l and not more than 1×10?2 mol/l. The particles emit fluorescent light with a fluorescence quantum yield (quantum yield) of 25% or more (and 60% or more), when dispersed in a solution.Type: GrantFiled: September 21, 2006Date of Patent: November 19, 2013Assignee: National Institute of Advanced Industrial Science and TechnologyInventors: Masanori Ando, Norio Murase, Chunliang Li, Ping Yang
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Patent number: 8585929Abstract: Disclosed is a phosphor and a method for preparing the same. The phosphor comprises a material having a general composition formula expressed by M1Si6N8-XOX (satisfying 0?x?1), where M is alkaline earth metal.Type: GrantFiled: September 23, 2011Date of Patent: November 19, 2013Assignee: Epistar CorporationInventors: Chiao-Wen Yeh, Ru-Shi Liu
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Publication number: 20130292609Abstract: A method for producing a silicate-based oxynitride phosphor, comprising a step of firing a raw material mixture while contacting the raw material mixture with a Si-containing gas containing gas phase Si to generate a silicate-based oxynitride phosphor.Type: ApplicationFiled: December 2, 2011Publication date: November 7, 2013Applicants: SUMITOMO CHEMICAL COMPANY, LIMITED, NIIGATA UNIVERSITYInventors: Kenji Toda, Kazuyoshi Uematsu, Mineo Sato, Tadashi Ishigaki, Yoshitaka Kawakami, Tetsu Umeda
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Patent number: 8574459Abstract: To provide a yellow to orange phosphor which has high luminance and excellent temperature characteristics and which also has high luminance when mixed with a phosphor of a different color. A phosphor containing a crystal phase represented by the following formula [I], wherein when its object color is expressed by the L*a*b* color system, the values of a*, b* and (a*2+b*2)1/2 satisfy ?20?a*??2, 71?b* and 71?(a*2+b*2)1/2, respectively: R3?x?y?z+w2MzA1.5x+y?w2Si6?w1?w2Alw1+w2Oy+w1N11?y?w1??[I].Type: GrantFiled: September 23, 2011Date of Patent: November 5, 2013Assignee: Mitsubishi Chemical CorporationInventors: Takatoshi Seto, Naoto Kijima, Keiichi Seki, Ryuji Adachi, Hiroyasu Yamada, Tatsuya Inoue
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Publication number: 20130284975Abstract: The present disclosure relates to a method for preparing a silicate phosphor and the silicate phosphor. The method includes (1) a hydrothermal treatment step of obtaining a layered silicate substituted with a rare-earth metal by hydrothermally treating an aqueous solution as a reaction solution, the solution containing rare-earth metal ions, NaOH and silica, and (2) a calcinating step of forming a crystalline silicate by calcinating the layered silicate substituted with the rare-earth metal. According to the method for preparing the silicate phosphor, the silicate phosphors, which can be used as phosphors for LEDs in the aspects of high covalent character, high luminescent intensity and stability at high temperature, may be prepared by a simplified, economic process. Also, the silicate phosphors may selectively emit red, green or blue light by virtue of the substitution of a silicon position with rare-earth metals of various types.Type: ApplicationFiled: April 16, 2013Publication date: October 31, 2013Inventors: Sunjin KIM, Kyoungja WOO, Sohye CHO, Yumi NA, Jongku PARK
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Publication number: 20130284976Abstract: A method for producing a crystalline material comprising a step of firing a raw material mixture containing M1, M2, M3, and L in an atmosphere containing NH3 gas to generate a crystalline material represented by M12a(M2bLc)M3dOyNxType: ApplicationFiled: December 2, 2011Publication date: October 31, 2013Applicants: SUMITOMO CHEMICAL COMPANY, LIMITED, NIIGATA UNIVERSITYInventors: Kenji Toda, Kazuyoshi Uematsu, Mineo Sato, Tadashi Iishigaki, Yoshitaka Kawakami, Tetsu Umeda
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Patent number: 8568615Abstract: A full-color light-emitting material and preparation method thereof are provided. A light-emitting material is following general formula compound (Y1-x-y-zAxByCz)2GeO5, wherein 0<x?0.05, 0<y?0.15, 0<z?0.15, x:y:z=1:1˜10:1˜10, A is one of Tm and Ce, B is one of Tb, Ho, Er and Dy, C is one of Eu, Pr and Sm. Preparation method is: grinding the raw material uniformly, then sintering the material at 1300˜1500 ° C. for 6˜24 h, cooling down the material to room temperature then getting the product. A full-color light-emitting material which can emit red-green-blue full-color light directly and be adapted for light-emitting device excited in ultraviolet zone without other doped material is provided. And a preparation method having simple process, stable product quality for full-color light-emitting materials is provided.Type: GrantFiled: May 11, 2009Date of Patent: October 29, 2013Assignee: Oceans King Lighting Science & Technology Co., Ltd.Inventors: Mingjie Zhou, Wenbo Ma, Zhaopu Shi
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Patent number: 8562865Abstract: A method of producing an M-C-N-O based phosphor with reduced non-uniform emission and improved color purity is provided. The method of producing an M-C-N-O based phosphor comprising a group IIIB element (M), carbon (C), nitrogen (N) and oxygen (O) comprises: heating a mixture comprising a group IIIB element-containing compound and a nitrogen-containing organic compound to form a pyrolysate; disintegrating the resulting pyrolysate-containing product; and firing the disintegrated product.Type: GrantFiled: December 7, 2009Date of Patent: October 22, 2013Assignees: Hiroshima University, Kuraray Co., Ltd.Inventors: Jun Takai, Hideharu Iwasaki, Ferry Iskandar, Kikuo Okuyama
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Patent number: 8551361Abstract: Disclosed herein is a novel family of oxycarbidonitride phosphor compositions and light emitting devices incorporating the same. Within the sextant system of M—Al—Si—O—N—C—Ln and quintuplet system of M—Si—O—N—C—Ln (M=alkaline earth element, Ln=rare earth element), the phosphors are composed of either one single crystalline phase or two crystalline phases with high chemical and thermal stability. In certain embodiments, the disclosed phosphor of silicon oxycarbidonitrides emits green light at wavelength between 530-550 nm. In further embodiments, the disclosed phosphor compositions emit blue-green to yellow light in a wavelength range of 450-650 nm under near-UV and blue light excitation.Type: GrantFiled: March 11, 2011Date of Patent: October 8, 2013Assignee: Lightscape Materials, Inc.Inventors: Yuanqiang Li, Michael Dennis Romanelli, Yongchi Tian
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Patent number: 8551360Abstract: The invention relates to a method of manufacturing a rare-earth doped alkaline-earth silicon nitride phosphor of a stoichiometric composition. Said method comprising the step of selecting one or more compounds each comprising at least one element of the group comprising the rare-earth elements (RE), the alkaline-earth elements (AE), silicon (Si) and nitrogen (N) and together comprising the necessary elements to form the rare-earth doped alkaline-earth silicon nitride phosphor (AE2Si5N8:RE). The method further comprises the step of bringing the compounds at an elevated temperature in reaction for forming the rare-earth doped alkaline-earth silicon nitride phosphor (AE2Si5N8:RE). In such a method normally a small amount of oxygen, whether intentionally or not-intentionally added, will be incorporated in the rare-earth doped alkaline-earth silicon nitride phosphor (AE2Si5N8:RE).Type: GrantFiled: October 14, 2008Date of Patent: October 8, 2013Assignees: Leuchtstoffwerk Breitungen GmbH, Ledon Lighting Jennersdorf GmbHInventors: Cheng-Jun Duan, Hubertus Theresia Hitzen, Sylke Rösler, Detlef Starick, Sven Rösler, Anne Charlotte Antoinette Delsing
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Publication number: 20130256597Abstract: According to one embodiment of the present invention, a phosphor has the following composition formula (1): [composition formula 1] Si(6-z)AlzOyN(8-z):Rex, where x, y and z are 0.018?x?0.3, 0.3?y?0.75, 0.42?z?1.0, respectively, and Re is a rare earth element. Therefore, even when the aluminum concentration is 0.42 mol to 1.0 mol, a sialon phosphor of the present invention exhibits high luminance and has a particle size D50 varying between 5 to 20 ?m. In addition, a method for preparing a phosphor according to one embodiment of the present invention involves adjusting the oxygen concentration to ensure the superior crystallinity of the phosphor and thus improve the luminance thereof.Type: ApplicationFiled: September 20, 2011Publication date: October 3, 2013Applicant: SAMSUNG ELECTRONICS CO., LTD.Inventors: Seong Min Kim, Hyong Sik Won, Chan Suk Min, Chul Soo Yoon, Youn Gon Park
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Patent number: 8545722Abstract: An illumination system, comprising a radiation source and a luminescent material comprising at least one phosphor capable of absorbing a part of light emitted by the radiation source and emitting light of wavelength different from that of the absorbed light; wherein said at least one phosphor is a yellow red-emitting cerium(III)-activated alkaline earth oxonitridoaluminosilicate of general formula Ca1?x?yAxAl1+a?bBbSi1?aN3?aOa:Cey, wherein A selected from the group comprising beryllium, magnesium, strontium, barium, zinc, manganese, lithium, sodium, potassium, rubidium, praseodymium, samarium, europium, and B selected from the group comprising boron, gallium, scandium and wherein 0<x?1; 0<y<0.2; 0.001<a<1 and 0.001<b<1 can provide light sources having high luminosity and color-rendering index, especially in conjunction with a light emitting diode as a radiation source.Type: GrantFiled: February 10, 2006Date of Patent: October 1, 2013Assignee: Koninklijke Philips N.V.Inventors: Peter Schmidt, Jorg Meyer, Walter Mayr, Hans-Helmut Bechtel
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Patent number: 8535566Abstract: Disclosed herein are novel families of silicon carbidonitride phosphor compositions. In certain embodiments, optimal ranges of carbon content have been identified which provide excellent luminescence and thermal stability characteristics.Type: GrantFiled: June 20, 2011Date of Patent: September 17, 2013Assignee: Lightscape Materials, Inc.Inventors: Yuanqiang Li, Michael Dennis Romanelli, Yongchi Tian
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Patent number: 8535564Abstract: A light emitting device having oxyorthosilicate luminophores is disclosed. The light emitting device includes a light emitting diode and luminescent substances disposed around the light emitting diode, to absorb at least a portion of light emitted from the light emitting diode and emitting light having different wavelength from that of the absorbed light. The luminescent substances have Eu2+-doped silicate luminophores in which solid solutions in the form of mixed phases between alkaline earth metal oxyorthosilicates and rare earth metal oxyorthosilicates are used as base lattices for the Eu2+activation leading to luminescence. The luminescent substances are used as radiation converters to convert a higher-energy primary radiation, for example, ultra violet (UV) radiation or blue light, into a longer-wave visible radiation and are therefore preferably employed in corresponding light-emitting devices.Type: GrantFiled: April 26, 2010Date of Patent: September 17, 2013Assignee: Seoul Semiconductor, Co., Ltd.Inventors: Chung Hoon Lee, Walter Tews, Gundula Roth, Detlef Starick
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Patent number: 8524118Abstract: A nitride phosphor represented by Formula 1: M1a-zCezM2b-xM3xNc-yOy,??Formula 1 wherein M1 is at least one metal selected from the group consisting of Sc3+, Y3+, Lu3+, La3+, Pr3+, Sm3+, Gd3+, Tb3+, Yb3+, Dy3+, Eu3+, and Bi3+, M2 is at least one metal selected from the group consisting of Si4+ and Ge4+, M3 is at least one metal selected from the group consisting of Al3+, B3+, and Ga3+, a is equal to or greater than about 1.8 and equal to or less than about 2.2, b is equal to or greater than about 3.8 and equal to or less than about 4.2, c is equal to or greater than about 6.7 and equal to or less than about 7.3, x is equal to or greater than about 0.7 and less than about 3, y is equal to or greater than 0 and less than about 3, and z is greater than 0 and less than about 1.Type: GrantFiled: October 13, 2010Date of Patent: September 3, 2013Assignees: Samsung Electronics Co., Ltd., Samsung Electro-Mechanics Co., Ltd.Inventors: Tae-gon Kim, Tae-hyung Kim, Seung-jae Im
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Publication number: 20130221275Abstract: Halo-silicate luminescent materials and preparation methods thereof are provided. The said luminescent materials are represented by the following general formula: (Ba1-yAy)2-xSiO4:Eux, Dz@Mn, wherein A is selected from one or two of Sr, Ca, Mg or Zn, D is selected from one of F or Cl, M is selected from at least one of Ag, Au, Pt, Pd or Cu metal nano-particles; @ is coating; (Ba1-yAy)2-xSiO4:Eux, Dz, is shell; 0.001<x?0.15, 0?y?0.5, 0?z?0.5, 0<n?1×10?2. The said luminescent materials have excellent chemical stability and high luminous intensity. Furthermore, the luminescent materials have controlled spherical shape which is beneficial to the coating screen process and the improved displaying effect. The said preparation methods have simple technique, no pollution, manageable process conditions and low equipment requirement, and are beneficial to industry production.Type: ApplicationFiled: December 14, 2010Publication date: August 29, 2013Inventors: Mingjie Zhou, Rong Wang, Wenbo Ma
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Patent number: 8518300Abstract: A ?-sialon phosphor particle in which Eu (europium) is solid-soluted in a crystal having a ?-type Si3N4 crystal structure, wherein the median diameter (D50) in the particle size distribution curve of the primary particle is from 3.0 to 10 ?m and the aspect ratio is less than 1.5.Type: GrantFiled: October 6, 2008Date of Patent: August 27, 2013Assignee: Ube Industries, Ltd.Inventors: Takuma Sakai, Shin-ichi Sakata
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Patent number: 8512599Abstract: Disclosed herein is a novel group of carbidonitride phosphors and light emitting devices which utilize these phosphors. In certain embodiments, the present invention is directed to a novel family of carbidonitride-based phosphors expressed as follows: Ca1?xAlx?xySi1?x+xyN2?x?xyCxy:A;??(1) Ca1?x?zNazM(III)x?xy?zSi1?x+xy+zN2?x?xyCxy:A;??(2) M(II)1?x?zM(I)zM(III)x?xy?zSi1?x+xy+zN2?x?xyCxy:A;??(3) M(II)1?x?zM(I)zM(III)x?xy?zSi1?x+xy+zN2?x?xy?2w/3CxyOw?v/2Hv:A; and??(4) M(II)1?x?zM(I)zM(III)x?xy?zSi1?x+xy+zN2?x?xy?2w/3?v/3CxyOwHv:A,??(4a) wherein 0<x<1, 0<y<1, 0?z<1, 0?v<1, 0<w<1, x+z<1, x>xy+z, and 0<x?xy?z<1, M(II) is at least one divalent cation, M(I) is at least one monovalent cation, M(III) is at least one trivalent cation, H is at least one monovalent anion, and A is a luminescence activator doped in the crystal structure.Type: GrantFiled: July 19, 2010Date of Patent: August 20, 2013Assignee: Lightscape Materials, Inc.Inventors: Yuanqiang Li, Yongchi Tian, Michael Dennis Romanelli
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Patent number: 8501040Abstract: Disclosed are non-stoichiometric Copper Alkaline Earth Silicate phosp hors activated by divalent europium for using them as high temperature stable luminescent mat erials for ultraviolet or daylight excitation. The phosphors are represented as the formula (BauSryCawCux)3?y(Zn,Mg,Mn)zSi1+bO5+2b:Eua. The non-stoichiometric tetragonal silicat e is prepared in a high temperature solid state reaction with a surplus of silica in the starting mixture. Furthermore, luminescent tetragonal Copper Alkaline Earth Silicates are provided for LED applications, which have a high color temperature range from about 2,000K to 8,000K or 10,000 K showing a CRI with Ra=80˜95, when mixed with other luminescent materials.Type: GrantFiled: January 31, 2012Date of Patent: August 6, 2013Assignee: Seoul Semiconductor Co., Ltd.Inventors: Chung Hoon Lee, Walter Tews, Gundula Roth, Stefan Tews
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Patent number: 8501039Abstract: The embodiment provides a process for production of a green light-emitting oxynitride fluorescent material having Sr3Al3Si13O2N21 crystal structure, and also provides the fluorescent material produced by that process. An metal halide is adopted in the process as one of the starting material metal compounds. As the metal halide, a Ca or Na compound as well as a Sr compound can be preferably employed.Type: GrantFiled: August 26, 2010Date of Patent: August 6, 2013Assignee: Kabushiki Kaisha ToshibaInventors: Yumi Fukuda, Aoi Okada, Naotoshi Matsuda
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Patent number: 8491817Abstract: A luminescent material which is featured in that it exhibits an emission peak at a wavelength ranging from 490 to 580 nm as it is excited by light having a wavelength ranging from 250 to 500 nm and that it has a composition represented by the following general formula (2): (M1-xRx)a2AlSib2Oc2Nd2??(2) (In the general formula (2), M is at least one metallic element excluding Si and Al, R is a luminescence center element, and x, a2, b2, c2 and d2 satisfy the following relationships: 0<x?1, 0.93<a2<1.3, 4.0<b2<5.8 0.6<c2<1, 6<d2<11).Type: GrantFiled: November 12, 2010Date of Patent: July 23, 2013Assignee: Kabushiki Kaisha ToshibaInventors: Yumi Fukuda, Hironori Asai, Ryosuke Hiramatsu, Junichi Tatami, Katsutoshi Komeya, Toru Wakihara, Katsuko Tamatani
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Publication number: 20130181164Abstract: Disclosure relates to a phosphor formed by using oxynitride having a good durability and possibly emits diverse color of light from green to yellow when using a blue emitting diode or a ultraviolet emitting diode as an excitation source. The phosphor includes a host material represented by the general formula of (Ca1-xM1x)a(La1-yM2y)bSicNdOe (in which 0.5?b/a?7, 1.5?c/(a+b)?3.5, 1?d/c?1.8, 0.6?e/(a+b)?2, 0?x?0.5, and 0?y?0.5) and having a monoclinic crystalline structure, and at least one dissolved activator selected from the group consisting of Mn, Ce, Pr, Nd, Sm, Eu, Gd, Dy, Tb, Ho, Er, Tm and Yb. M1 is at least one element selected from Ba, Mg, Sr, Mn and Zn, and M2 being at least one element selected from Y, Lu, Sc, Gd, Tb, Ce, Nd, Sm, Dy, Ho, Er, Tm, Yb, Al, Ga, Ge, Sn and In.Type: ApplicationFiled: January 6, 2012Publication date: July 18, 2013Applicant: Industry-Academy Coperation Corps of Sunchon National UniversityInventors: Kee Sun Sohn, Un Bae Park, Nam Soo Shin
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Publication number: 20130168606Abstract: Phosphors include a CaAlSiN3 family crystal phase, wherein the CaAlSiN3 family crystal phase comprises at least one element selected from the group consisting of Mn, Ce, Pr, Nd, Sm, Eu, Tb, Dy, Ho, Er, Tm, and Yb.Type: ApplicationFiled: February 25, 2013Publication date: July 4, 2013Inventors: Naoto HIROSAKI, Kyota Ueda, Hajime Yamamoto
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Publication number: 20130168604Abstract: A green light-emitting silicate phosphor comprising Eu-activated strontium barium silicate which has a crystal phase of magnesium oxide or a merwinite crystal phase and contains 0.15 to 0.90 mol of magnesium per one mol of silicon gives a light emission stable at elevated temperatures.Type: ApplicationFiled: December 28, 2012Publication date: July 4, 2013Applicant: UBE MATERIAL INDUSTRIES, LTD.Inventor: UBE MATERIAL INDUSTRIES, LTD.
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Publication number: 20130168605Abstract: Phosphors comprising a nitride-based composition represented by the chemical formula: M(x/v)(M?aM?b)Si(c-x)AlxNd:RE, wherein: M is a divalent or trivalent metal with valence v; M? is at least one divalent metal; M? is at least one trivalent metal; 2a+3b+4c=3d; and RE is at least one element selected from the group consisting of Eu, Ce, Pr, Nd, Sm, Gd, Tb, Dy, Ho, Er, Tm, Yb. Furthermore, the nitride-based composition may have the general crystalline structure of M?aM?bSicNd, where Al substitutes for Si within the crystalline structure and M is located within the crystalline structure substantially at the interstitial sites.Type: ApplicationFiled: December 31, 2012Publication date: July 4, 2013Applicant: Intematix CorporationInventor: Intematix Corporation
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Patent number: 8475682Abstract: To provide a phosphor for manufacturing an one chip type LED illumination, etc, by combining a near ultraviolet/ultraviolet LED and a blue LED, and having an excellent emission efficiency including luminance. The phosphor is given as a general composition formula expressed by MmAaBbOoNn:Z, (where element M is one or more kinds of elements having bivalent valency, element A is one or more kinds of elements having tervalent valency, element B is one or more kinds of elements having tetravalent valency, O is oxygen, N is nitrogen, and element Z is one or more kinds of elements acting as an activator.), satisfying a=(1+x)×m, b=(4?x)×m, o=x×m, n=(7?x)×m, 0?x?1, wherein when excited by light in a wavelength range from 300 nm to 500 nm, the phosphor has an emission spectrum with a peak wavelength in a range from 500 nm to 620 nm.Type: GrantFiled: October 24, 2011Date of Patent: July 2, 2013Assignee: Mitsubishi Chemical CorporationInventors: Akira Nagatomi, Kenji Sakane, Tomoya Yamada
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Patent number: 8475680Abstract: A luminescent material which is featured in that it exhibits an emission peak at a wavelength ranging from 490 to 580 nm as it is excited by light having a wavelength ranging from 250 to 500 nm and that it has a composition represented by the following general formula (2): (M1-xRx)a2AlSib2Oc2Nd2??(2) (In the general formula (2), M is at least one metallic element excluding Si and Al, R is a luminescence center element, and x, a2, b2, c2 and d2 satisfy the following relationships: 0<x?1, 0.93<a2<1.3, 4.0<b2<5.8 0.6<c2<1, 6<d2<11).Type: GrantFiled: September 10, 2008Date of Patent: July 2, 2013Assignee: Kabushiki Kaisha ToshibaInventors: Yumi Fukuda, Hironori Asai, Ryosuke Hiramatsu, Junichi Tatami, Katsutoshi Komeya, Toru Wakihara, Katsuko Tamatani
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Patent number: 8465676Abstract: In order to provide a phosphor for a low-voltage electron beam and a vacuum fluorescent display apparatus in which the phosphor is used, a deposition layer is formed on a surface of a main body of a phosphor shown by the following chemical formula (1), the deposition layer being a plurality of oxide layers sequentially deposited on the surface of the phosphor main body. The phosphor for a low-voltage electron beam contains no cadmium, but has exceptional high-temperature exposure characteristics, as well as prolonged service life and higher brightness. Ca1-xSrxTiO3:Pr,M??(1) where M is at least one element selected from Al, Ga, In, Mg, Zn, Li, Na, K, Gd, Y, La, Cs, and Rb; and 0?x?1.Type: GrantFiled: February 17, 2011Date of Patent: June 18, 2013Assignees: Noritake Itron Corporation, Noritake Co., LimitedInventor: Koji Kato