Carbon-oxide And Hydrogen Containing Patents (Class 252/373)
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Patent number: 11560308Abstract: Method and plant for generating a synthesis gas which consists mainly of carbon monoxide and hydrogen and has been freed of acid gases, proceeding from a hydrocarbonaceous fuel, and air and steam, wherein low-temperature fractionation separates air into an oxygen stream, a tail gas stream and a nitrogen stream, wherein the tail gas stream and the nitrogen stream are at ambient temperature and the nitrogen stream is at elevated pressure, wherein the hydrocarbonaceous fuel, having been mixed with the oxygen stream and steam at elevated temperature and elevated pressure, is converted to a synthesis gas by a method known to those skilled in the art, and wherein acid gas is subsequently separated therefrom by low-temperature absorption in an absorption column, wherein the nitrogen stream generated in the fractionation of air is passed through and simultaneously cooled in an expansion turbine and then used to cool either the absorbent or the coolant circulating in the coolant circuit of the compression refrigeratioType: GrantFiled: November 20, 2017Date of Patent: January 24, 2023Assignee: L'Air Liquide, Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges ClaudeInventors: Lucie Chaubet, Frederic Bonne, Camille Bouet, Holger Schlichting, Marc Wagner
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Patent number: 11547985Abstract: A catalyst support comprising at least 95% silicon carbide, having surface areas of ?10 m2/g and pore volumes of ?1 cc/g. A method of producing a catalyst support, the method including mixing SiC particles of 0.1-20 microns, SiO2 and carbonaceous materials to form an extrusion, under inert atmospheres, heating the extrusion at temperatures of greater than 1400° C., and removing residual carbon from the heated support under temperatures below 1000° C. A catalyst on a carrier, comprising a carrier support having at least about 95% SiC, with a silver solution impregnated thereon comprising silver oxide, ethylenediamine, oxalic acid, monoethanolamine and cesium hydroxide. A process for oxidation reactions (e.g., for the production of ethylene oxide, or oxidation reactions using propane or methane), or for endothermic reactions (e.g., dehydrogenation of paraffins, of ethyl benzene, or cracking and hydrocracking hydrocarbons).Type: GrantFiled: August 18, 2021Date of Patent: January 10, 2023Inventor: Madan Mohan Bhasin
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Patent number: 11518724Abstract: A method for preparing a carbonaceous product includes providing oxygen, in particular from electrolysis, and providing a fuel. The method also includes combusting the fuel with the oxygen by an oxy-fuel combustion process in order to provide energy, purifying a flue gas produced by the oxy-fuel combustion process, and separating carbon dioxide from the flue gas produced by the oxy-fuel combustion process, wherein energy provided by the oxy-fuel combustion process includes, in particular exclusively, heat which is used as process heat for purifying and/or for synthesising or providing the carbonaceous product. A corresponding system is designed to carry out the described method.Type: GrantFiled: July 30, 2019Date of Patent: December 6, 2022Assignee: Siemens Energy Global GmbH & Co. KGInventors: Frank Hannemann, Gerhard Zimmermann
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Patent number: 11506122Abstract: The present disclosure relates to systems and methods useful for power production. In particular, a power production cycle utilizing CO2 as a working fluid may be configured for simultaneous hydrogen production. Beneficially, substantially all carbon arising from combustion in power production and hydrogen production is captured in the form of carbon dioxide. Further, produced hydrogen (optionally mixed with nitrogen received from an air separation unit) can be input as fuel in a gas turbine combined cycle unit for additional power production therein without any atmospheric CO2 discharge.Type: GrantFiled: November 9, 2017Date of Patent: November 22, 2022Assignee: 8 Rivers Capital, LLCInventors: Rodney John Allam, Navid Rafati
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Patent number: 11498834Abstract: An H2-rich fuel gas stream can be advantageously produced by reforming a hydrocarbon/steam mixture in to produce a reformed stream, followed by cooling the reformed stream in a waste-heat recovery unit to produce a high-pressure steam stream, shifting the cooled reformed stream a first shifted stream, cooling the first shifted stream, shifting the cooled first shifted stream to produce a second shifted stream, cooling the second shifted stream, abating water from the cooled second shifted stream to obtain a crude gas mixture stream comprising H2 and CO2, and recovering a CO2 stream from the crude gas mixture stream. The H2-rich stream can be advantageously combusted to provide thermal energy needed for residential, office, and/or industrial applications including in the H2-rich fuel gas production process. The H2-rich fuel gas production process can be advantageously integrated with an olefins production plant comprising a steam cracker.Type: GrantFiled: September 24, 2021Date of Patent: November 15, 2022Assignee: ExxonMobil Chemical Patents Inc.Inventors: David Spicer, Thomas T. Hirst, James L. Kendall, You Fang
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Patent number: 11492315Abstract: There is a process for the production of methanol from gaseous hydrocarbons. The process has the following stages: (a) treating said gaseous hydrocarbons in a desulfurization unit to produce a desulfurized hydrocarbon gas; (b) reacting the desulfurized gas with an oxidizing flow by means of a short contact time partial catalytic oxidation reaction to produce synthesis gas; (c) producing hydrogen by electrolysis of water; (d) mixing and compressing synthesis gas and hydrogen; and (e) sending said compressed mixture to a methanol synthesis unit to produce methanol.Type: GrantFiled: September 18, 2019Date of Patent: November 8, 2022Assignee: ENI S.P.A.Inventors: Luca Eugenio Riccardo Basini, Chiara Busto, Michele Villani
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Patent number: 11479727Abstract: A feedstock flexible process for converting feedstock into oil and gas includes (i) indirectly heated hydrous devolatilization of volatile feedstock components, (ii) indirectly heated thermochemical conversion of fixed carbon feedstock components, (iii) heat integration and recovery, (iv) vapor and gas pressurization, and (v) vapor and gas clean-up and product recovery. A system and method for feedstock conversion includes a thermochemical reactor integrated with one or more hydrous devolatilization and solids circulation subsystems configured to accept a feedstock mixture, comprised of volatile feedstock components and fixed carbon feedstock components, and continuously produce a volatile reaction product stream therefrom, while simultaneously and continuously capturing, transferring, and converting the fixed carbon feedstock components to syngas.Type: GrantFiled: November 5, 2012Date of Patent: October 25, 2022Assignee: ThermoChem Recovery International, Inc.Inventors: Ravi Chandran, Daniel Michael Leo, Shawn Robert Freitas
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Patent number: 11472713Abstract: Disclosed herein are aluminum oxide aerogels and methods of making and use thereof. The methods of making the aluminum oxide aerogel include contacting a solid comprising aluminum with a Ga-based liquid alloy to dissolve at least a portion of the aluminum from the solid, thereby forming an aluminum-alloy mixture; and contacting the aluminum-alloy mixture with a fluid comprising water, thereby forming the aluminum oxide aerogel. In some examples, the methods can further comprise capturing and converting carbon dioxide to a syngas comprising carbon monoxide and hydrogen.Type: GrantFiled: October 3, 2018Date of Patent: October 18, 2022Assignee: North Carolina State UniversityInventors: Paul Maggard, Jerome J. Cuomo, Keith Markham, William Kiether
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Patent number: 11459281Abstract: A process for producing acetylene and syngas by partial oxidation of hydrocarbons with oxygen, involving: separately preheating a hydrocarbon and a oxygen-comprising input stream; mixing in a mass flow ratio of the oxygen-comprising to hydrocarbon stream at an oxygen number no more than 0.31; feeding the streams via a burner block to a combustion chamber and therein partially oxidizing the hydrocarbon(s) to a cracking gas; quenching the cracking gas to 80 to 90° C. downstream by injecting an aqueous quench medium to obtain a process water stream-1 and a product gas stream-2; cooling the product gas stream-2 in a cooling column by direct heat exchange with cooling water to obtain a process water stream-2 as bottoms, a product gas stream-2 as uppers, and a sidestream; and depleting the sidestream of soot in an electrofilter to generate therein a process water stream-3 combined with water streams-1/2 to afford the process water stream-4.Type: GrantFiled: April 8, 2019Date of Patent: October 4, 2022Assignee: BASF SEInventors: Maximilian Vicari, Christian Weichert, Christopher Alec Anderlohr, Wolfgang Reif
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Patent number: 11433353Abstract: Methods and systems for the separation of hydrogen isotopes from one another are described. Methods include utilization of a hydrogen isotope selective separation membrane that includes a hydrogen isotope selective layer (e.g., graphene) and a hydrogen ion conductive supporting layer. An electronic driving force encourages passage of isotopes selectively across the membrane at an elevated separation temperature to enrich the product in a selected hydrogen isotope.Type: GrantFiled: June 6, 2019Date of Patent: September 6, 2022Assignees: Savannah River Nuclear Solutions, LLC, Clemson University Research Foundation, Georgia Tech Research CorporationInventors: Dale A. Hitchcock, Steven M. Serkiz, Timothy M. Krentz, Josef A. Velten, Kyle S. Brinkman, Eric M. Vogel, Katherine T. Young
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Patent number: 11427467Abstract: The invention provides a calcined Fex—Aly—Oz based catalyst for the decomposition of hydrocarbons such as methane to produce hydrogen and carbon. The catalyst comprises iron oxide mixed with aluminum oxide and calcined at temperatures above 1100° C., where Fex—Aly—Oz is a chemical composition with x>0.1, y>0.1, z?0 and 0<x/y<200. Reaction of the calcined Fex—Aly—Oz catalyst with methane generates a product stream comprising at least 40 vol. % H2 and carbon. In an embodiment, carbon is separated from the catalyst and the catalyst is reused for continuous methane decomposition to produce H2.Type: GrantFiled: March 21, 2019Date of Patent: August 30, 2022Assignee: Energy, United States Department ofInventors: Ranjani Siriwardane, William Benincosa, Jarrett Riley
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Patent number: 11414610Abstract: A pyrolysis gasifier includes a tubular body configured to receive and pyrolyze a combustible waste, a bottom door disposed below the tubular body to selectively seal the tubular body, a main frame supporting the tubular body, a base frame supporting the bottom door, an automatic ash processor configured to, while traveling in one direction, push and remove ash remaining on the bottom door after pyrolysis of the combustible waste, and a guide frame supporting the automatic ash processor and configured to guide the travel of the automatic ash processor.Type: GrantFiled: March 2, 2021Date of Patent: August 16, 2022Inventors: Yung Taek Lim, Deok Jun Rim
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Patent number: 11377534Abstract: Methods of depolymerizing polyolefin-based material into useful petrochemical products using metal oxides and heat are described. The metal oxides improve the depolymerization reaction by decreasing the onset temperature for the depolymerization, which results in a higher depolymerization rate and a shorter residence time in the depolymerization unit, allowing for a predictable depolymerization reaction, and decreasing the branching or aromatic formations in the product.Type: GrantFiled: September 9, 2020Date of Patent: July 5, 2022Assignee: Basell Poliolefine Italia S.r.l.Inventors: Diego Brita, Sheri E. Davis, Yulenty Deal, Simona Guidotti, Dario Liguori, Sandor Nagy, Christopher D. Smith, Daniel F. White, Xueyong Yang, Shahram Mihan
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Patent number: 11365882Abstract: A gas combustion treatment device that subjects an ammonia-containing gas, a hydrogen cyanide-containing gas, and a hydrogen sulfide-containing gas to combustion treatment includes: a first combustion unit configured to introduce therein fuel, the ammonia-containing gas, the hydrogen cyanide-containing gas, and air and burn and reduce the fuel and the gases at an air ratio lower than 1; a second combustion unit provided downstream of the first combustion unit and configured to burn and reduce, in a reducing atmosphere, nitrogen oxide in a first combustion gas sent from the first combustion unit; and a third combustion unit provided downstream of the second combustion unit and configured to introduce therein hydrogen sulfide-containing gas with air in addition to a second combustion gas sent from the second combustion unit.Type: GrantFiled: July 4, 2018Date of Patent: June 21, 2022Assignee: Mitsubishi Heavy Industries Engineering, Ltd.Inventor: Kaori Yoshida
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Patent number: 11331649Abstract: A solvent comprised of (1) a caustic and an alcohol, (2) a caustic and a quaternary ammonium hydroxide, or (3) a caustic, an alcohol, and a quaternary ammonium hydroxide may contact an adsorbent bed that has been used to remove sulfur compounds from a hydrocarbon stream to extract adsorbed sulfur compounds from the adsorbent material in the bed to regenerate it. The regenerated adsorbent bed may be reused, either alone or in combination with a liquid-liquid extraction column, to remove sulfur compounds from a hydrocarbon stream.Type: GrantFiled: July 24, 2020Date of Patent: May 17, 2022Assignee: Baker Hughes Oilfield Operations LLCInventors: Sai Reddy Pinappu, Jerry J. Weers, Timothy J. O'Brien, Waynn C. Morgan
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Patent number: 11311860Abstract: This invention relates to a novel nickel catalyst and a novel one-pot solution combustion synthesis of that catalyst for the CO2 reforming and low temperature steam reformation of methane. The novel nickel catalyst has exceptional activity for dry reforming and steam reforming of methane, and exhibits excellent resilience to deactivation due to carbon formation.Type: GrantFiled: July 13, 2018Date of Patent: April 26, 2022Assignee: QATAR UNIVERSITYInventors: Mohammed J. Al-Marri, Mohammed Ali H. Salah Saad, Mahmoud M. Khader, Sardar Ali, Ahmed Gamal Abdelmoneim
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Patent number: 11312914Abstract: Pre-ground plastics of small particle size not more than 2 mm are co-fed into a solid fossil fuel fed entrained flow partial oxidation gasifier. High solids concentrations in the feedstock stream can be obtained without significant impact on the feedstock stream stability and pumpability. A consistent quality of syngas can be continuously produced, including generation of carbon dioxide and a carbon monoxide/hydrogen ratio while stably operating the gasifier and avoiding the high tar generation of fluidized bed or fixed bed waste gasifiers and without impacting the operations of the gasifier. The subsequent syngas produced from this material can be used to produce a wide range of chemicals.Type: GrantFiled: February 3, 2020Date of Patent: April 26, 2022Assignee: Eastman Chemical CompanyInventors: William Lewis Trapp, Justin William Murphy, Nathan Mitchell West
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Patent number: 11286159Abstract: In a process for the production of ammonia synthesis gas from a hydrocarbon-containing feedstock, comprising steam reforming of the feedstock and treatment of the synthesis gas obtained, the shift of the synthesis gas comprises two shift steps, both including stable catalysts, whereby the formation of hazardous by-products is avoided or at least reduced to an acceptable low level. The two shift steps can both be HTS, or they can be one HTS and one LTS or one HTS and one MTS. The catalyst used in the HTS and the LTS steps is based on zinc oxide and zinc aluminum spinel, and the catalyst used in the MTS and the LTS steps can be based on copper.Type: GrantFiled: June 28, 2018Date of Patent: March 29, 2022Assignee: HALDOR TOPSØE A/SInventors: Annette E. Krøll Jensen, Christian Henrik Speth, Thomas Rostrup-Nielsen
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Patent number: 11286160Abstract: Modified red mud catalyst compositions, methods for production, and methods of use in autothermal reforming, the composition comprising: red mud material produced from an alumina extraction process from bauxite ore; and nickel oxide, the nickel oxide present at between about 5 wt. % to about 40 wt. % of the modified red mud catalyst composition.Type: GrantFiled: January 28, 2020Date of Patent: March 29, 2022Assignee: SAUDI ARABIAN OIL COMPANYInventors: Bandar A. Fadhel, Bandar H. Alsolami, Rami Bamagain, Mohammed A. Albuali
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Patent number: 11279884Abstract: Reverse flow reactor (RFR) apparatuses exhibiting asymmetric feed profiles and improved flow distribution during heating mode and/or pyrolysis mode operation, and methods of using same to transform a hydrocarbon feed into a pyrolysed hydrocarbon product are disclosed. The RFR apparatus includes an RFR body with a reaction zone having at least one bed. The RFR body has a central vertical axis and is flanked by first and second void spaces. The method utilizes at least two oxygen-containing feeds, a combustion fuel feed, a purge feed, and a hydrocarbon pyrolysis feed. The RFR apparatus can cycle between an exothermic heating mode (heated to ?700° C.Type: GrantFiled: April 9, 2019Date of Patent: March 22, 2022Assignee: ExxonMobil Chemical Patents Inc.Inventors: Kevin B. Daly, Federico Barrai
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Patent number: 11255575Abstract: A thermal conveyance system and process for absorbing, transporting, storing, and recovering thermal energy (both hot and cold energy) over a wide range of temperatures from up to 2,100° F., or higher, or cool energy at subzero temperatures in inert and stable particles without the need to maintain a minimum temperature or requiring high system pressures. The process involving the transferring thermal energy to a first transfer fluid and recovering thermal energy from a second transfer fluid wherein the first and the second transfer fluids comprise a two phase thermal media including a gaseous carrier containing a quantity of micron to millimeter sized solid particles.Type: GrantFiled: March 20, 2017Date of Patent: February 22, 2022Assignee: GAS TECHNOLOGY INSTITUTEInventors: Hamid Abbasi, David Cygan, S. B. Reddy Karri, John Findlay
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Patent number: 11247898Abstract: Methods for bi-reforming with a red mud catalyst support composition, one method including providing a methane feed in the presence of carbon dioxide and steam to react over the red mud catalyst support composition at increased temperature and increased pressure to produce synthesis gas comprising H2 and CO, the composition comprising red mud material produced from an alumina extraction process from bauxite ore.Type: GrantFiled: January 28, 2020Date of Patent: February 15, 2022Assignee: SAUDI ARABIAN OIL COMPANYInventors: Mohammed A. Albuali, Bandar H. Alsolami, Bandar A. Fadhel, Rami Bamagain
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Patent number: 11247897Abstract: A system and method for converting (dry reforming) natural gas (methane) and carbon dioxide via reformer catalyst in a dry reformer into syngas including carbon monoxide and hydrogen, and discharging the syngas to a Fischer-Tropsch (FT) reactor. Supplemental hydrogen is generated via water electrolysis and added to the syngas in route to the FT reactor to increase the molar ratio of hydrogen to carbon monoxide in the syngas. The syngas may be converted via FT catalyst in the FT reactor into FT waxes.Type: GrantFiled: December 23, 2019Date of Patent: February 15, 2022Assignee: Saudi Arabian Oil CompanyInventors: Bandar H. Alsolami, Aqil Jamal
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Patent number: 11242246Abstract: Methods for autothermal reforming with a red mud catalyst support composition, one method including providing a methane feed with oxygen and carbon dioxide to react over the red mud catalyst support composition at increased temperature and increased pressure to produce synthesis gas comprising H2 and CO, the composition comprising red mud material produced from an alumina extraction process from bauxite ore.Type: GrantFiled: January 28, 2020Date of Patent: February 8, 2022Assignee: SAUDI ARABIAN OIL COMPANYInventors: Rami Bamagain, Bandar A. Fadhel, Bandar H. Alsolami, Mohammed A. Albuali
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Patent number: 11242245Abstract: Methods for steam reforming with a red mud catalyst support composition, one method including providing a methane feed and a steam feed to react over the red mud catalyst support composition at increased temperature and increased pressure to produce synthesis gas comprising H2 and CO, the composition comprising red mud material produced from an alumina extraction process from bauxite ore.Type: GrantFiled: January 28, 2020Date of Patent: February 8, 2022Assignee: SAUDI ARABIAN OIL COMPANYInventors: Bandar H. Alsolami, Bandar A. Fadhel, Rami Bamagain, Mohammed A. Albuali
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Patent number: 11235974Abstract: A process and a plant for the continuous conversion of a hydrocarbonaceous feed gas into a synthesis gas comprising carbon monoxide and hydrogen, wherein the H2/CO molar ratio of the product gases can be varied within a wide range. This is achieved in that at least a part of a methane-rich gas obtained during the fractionation of the raw synthesis gas is admixed to the feed gas mixture, and that in the alternative at least a part of the H2 product gas and/or a fraction of a hydrogen-rich gas increased with respect to the normal operation of the process is admixed to the heating gas mixture, in order to lower the H2/CO ratio, or at least a part of the CO product gas and/or a fraction of a carbon monoxide-rich gas increased with respect to the normal operation of the process is admixed to the heating gas mixture, in order to increase the H2/CO ratio.Type: GrantFiled: September 23, 2016Date of Patent: February 1, 2022Assignee: L'Air Liquide, Société Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges ClaudeInventors: Bernd Polster, Antoine Hernandez
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Patent number: 11207649Abstract: Methods, reactor tubes, reactors, and systems for catalysis are disclosed. A reactor tube includes an outer shell defining a catalyst bed, a catalyst within the catalyst bed, and an inner tube extending through the catalyst bed. An interior of the inner tube is isolated from the catalyst within the catalyst bed. Methods of activating a catalyst are also disclosed herein.Type: GrantFiled: March 13, 2019Date of Patent: December 28, 2021Assignee: West Biofuels, LLCInventors: Matthew B. Hoffman, Matthew D. Summers
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Patent number: 11208323Abstract: The present disclosure relates to a power production system that is adapted to achieve high efficiency power production with carbon capture when using a solid or liquid hydrocarbon or carbonaceous fuel. More particularly, the solid or liquid fuel first is partially oxidized in a partial oxidation reactor that is configured to provide an output stream that is enriched in methane content. The resulting partially oxidized stream can be cooled, filtered, additionally cooled, and then directed to a combustor of a power production system as the combustion fuel. The partially oxidized stream is combined with a compressed recycle CO2 stream and oxygen. The combustion stream is expanded across a turbine to produce power and passed through a recuperator heat exchanger. The recycle CO2 stream is compressed and passed through the recuperator heat exchanger and optionally the POX heat exchanger in a manner useful to provide increased efficiency to the combined systems.Type: GrantFiled: March 24, 2020Date of Patent: December 28, 2021Assignee: 8 Rivers Capital, LLCInventors: Brock Alan Forrest, Xijia Lu
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Patent number: 11148094Abstract: An adsorptive gas separation process and system is provided for separating at least a first component from a multi-component fluid mixture, or specifically for separating carbon dioxide from a combustion gas stream. The adsorptive gas separation process comprises an adsorbing step, a first regenerating step, an optional second regenerating step and an optional conditioning step.Type: GrantFiled: March 31, 2017Date of Patent: October 19, 2021Assignee: Svante Inc.Inventors: Andre Boulet, Soheil Khiavi
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Patent number: 11130676Abstract: The present invention relates to reactor tubes packed with a catalyst system employed to deliberately bias process gas flow toward the hot tube segment and away from the cold segment in order to reduce the circumferential tube temperature variation.Type: GrantFiled: March 10, 2020Date of Patent: September 28, 2021Assignee: PRAXAIR TECHNOLOGY, INC.Inventors: Kelly Nicholson, Troy M Raybold, Bo Jin
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Patent number: 11111142Abstract: Processes and catalysts for producing hydrogen by reforming methane are disclosed, which afford considerable flexibility in terms of the quality of the reformer feed. This can be attributed to the robustness of the noble metal-containing catalysts described herein for use in reforming, such that a number of components commonly present in methane-containing process streams can advantageously be maintained without conventional upgrading (pretreating) steps, thereby improving process economics. This also allows for the reforming of impure reformer feeds, even in relatively small quantities, which may be characterized as complex gas mixtures due to significant quantities of non-methane components. A representative reforming catalyst comprises 1 wt-% Pt and 1 wt-% Rh as noble metals, on a cerium oxide support.Type: GrantFiled: September 18, 2018Date of Patent: September 7, 2021Assignee: Gas Technology InstituteInventors: Terry Marker, Jim Wangerow, Pedro Ortiz-Toral, Martin Linck
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Patent number: 11078077Abstract: A method for producing synthesis gas may involve introducing a hydrocarbon-containing coke-oven gas and a carbon dioxide-containing converter gas into a first reaction zone where hydrogen present in the hydrocarbon-containing coke-oven gas reacts at least partly with carbon dioxide to form water, which reacts thermally with hydrocarbon to form synthesis gas containing carbon monoxide and hydrogen. The method may further involve introducing an oxygen-containing gas in a second reaction zone, and using the oxygen-containing gas and some hydrogen from the first reaction zone to produce thermal energy. Still further, the method may involve supplying the thermal energy produced in the second reaction zone to the first reaction zone.Type: GrantFiled: November 28, 2016Date of Patent: August 3, 2021Assignees: THYSSENKRUPP INDUSTRIAL SOLUTIONS AG, THYSSENKRUPP AGInventors: Hans-Jürgen Maass, Volker Göke, Otto Machhammer, Andreas Bode, Grigorios Kolios, Karsten Büker
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Patent number: 11066613Abstract: An apparatus and a method for gasifying carbon-containing materials in which the material for gasification and oxygen, usually in the form of air, are supplied to a gas generator where the gasification takes place in a fixed bed reactor. The product gas is drawn off via a product gas line and introduced into a hot gas filter. A filter, preferably provided with filter candles, removes solids such as particles not yet gasified, ash and foreign bodies, while clean gas passes through and is taken off via a clean gas line. An outlet is provided in the bottom region of the hot gas filter to remove residual solids. The hot gas filter is supplied through a line with oxygen, preferably in the form of air, in its middle height region, between the filter bottom and the outlet.Type: GrantFiled: July 7, 2016Date of Patent: July 20, 2021Inventor: Gaston Glock
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Patent number: 11066299Abstract: Methods for steam reforming over a modified red mud catalyst composition, one method including providing a methane feed and a steam feed to react over the modified red mud catalyst composition at increased temperature and increased pressure to produce synthesis gas comprising H2 and CO, the composition comprising red mud material produced from an alumina extraction process from bauxite ore; nickel oxide, the nickel oxide present at between about 5 wt. % to about 40 wt. % of the modified red mud catalyst composition; and a Periodic Table Group VIB metal oxide, the Group VIB metal oxide present at between about 1 wt. % and about 30 wt. % of the modified red mud catalyst composition.Type: GrantFiled: January 28, 2020Date of Patent: July 20, 2021Assignee: SAUDI ARABIAN OIL COMPANYInventors: Bandar A. Fadhel, Bandar H. Alsolami, Rami Bamagain, Mohammed A. Albuali
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Patent number: 11059720Abstract: Methods for dry reforming with a red mud catalyst support composition, one method including providing a methane feed and carbon dioxide feed to react over the red mud catalyst support composition at increased temperature and increased pressure to produce synthesis gas comprising H2 and CO, the composition comprising red mud material produced from an alumina extraction process from bauxite ore.Type: GrantFiled: January 28, 2020Date of Patent: July 13, 2021Assignee: SAUDI ARABIAN OIL COMPANYInventors: Bandar A. Fadhel, Bandar H. Alsolami, Rami Bamagain
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Patent number: 11059030Abstract: Methods for bi-reforming over a modified red mud catalyst composition, one method including providing a methane feed in the presence of carbon dioxide and steam to react over the modified red mud catalyst composition at increased temperature and increased pressure to produce synthesis gas comprising H2 and CO, the composition comprising red mud material produced from an alumina extraction process from bauxite ore; nickel oxide, the nickel oxide present at between about 5 wt. % to about 40 wt. % of the modified red mud catalyst composition; and a Periodic Table Group VIB metal oxide, the Group VIB metal oxide present at between about 1 wt. % and about 30 wt. % of the modified red mud catalyst composition.Type: GrantFiled: January 28, 2020Date of Patent: July 13, 2021Assignee: SAUDI ARABIAN OIL COMPANYInventors: Bandar H. Alsolami, Bandar A. Fadhel, Mohammed A. Albuali, Rami Bamagain
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Patent number: 11059011Abstract: A reforming device 1 for producing a reformed gas from a methane-containing gas containing methane and carbon dioxide includes a reforming reaction tube 10 containing a catalyst layer 12 filled with a reforming catalyst 12a for reforming the methane-containing gas, and a multilayer pipe 103 for spraying a cooling fluid to an outer peripheral surface of the reforming reaction tube 10 at a position corresponding to a gas inlet of the catalyst layer 12 in a length direction of the catalyst layer 12.Type: GrantFiled: November 4, 2019Date of Patent: July 13, 2021Assignee: MITSUBISHI HEAVY INDUSTRIES, LTD.Inventors: Atsuhiro Yukumoto, Shinya Tachibana
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Patent number: 11052365Abstract: Reactive diluent fluid (22) is introduced into a stream of synthesis gas (or “syngas”) produced in a heat-generating unit such as a partial oxidation (“POX”) reactor (12) to cool the syngas and form a mixture of cooled syngas and reactive diluent fluid. Carbon dioxide and/or carbon components and/or hydrogen in the mixture of cooled syngas and reactive diluent fluid is reacted (26) with at least a portion of the reactive diluent fluid in the mixture to produce carbon monoxide-enriched and/or solid carbon depleted syngas which is fed into a secondary reformer unit (30) such as an enhanced heat transfer reformer in a heat exchange reformer process. An advantage of the invention is that problems with the mechanical integrity of the secondary unit arising from the high temperature of the syngas from the heat-generating unit are avoided.Type: GrantFiled: January 9, 2019Date of Patent: July 6, 2021Inventors: Shoou-I Wang, John Michael Repasky, Shankar Nataraj, Xiang-Dong Peng
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Patent number: 11041078Abstract: A photosensitive reducible silver ion-containing composition can be used to provide electrically-conductive silver metal in thin films or patterns. This composition comprises: a) a non-hydroxylic-solvent soluble silver complex represented by the following formula (I): (Ag+)a(L)b(P)c??(I) wherein L represents an ?-oxy carboxylate; P represents an oxime compound; a is 1 or 2; b is 1 or 2; and c is 1, 2, 3, or 4, provided that when a is 1, b is 1, and when a is 2, b is 2; b) a photosensitizer that can either reduce the reducible silver ion or oxidize the ?-oxy carboxylate; and c) a solvent medium comprising at least one non-hydroxylic solvent. Electrically-conductive silver can be provided by photochemical conversion of the reducible silver ions in the complex.Type: GrantFiled: October 10, 2019Date of Patent: June 22, 2021Assignee: EASTMAN KODAK COMPANYInventor: Deepak Shukla
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Patent number: 11034901Abstract: The invention relates to a plant for generating negative emissions of CO2. The plant 100 comprises a gasifier 110, a lime kiln 130, a separator 150, and a CO2 permanent storage 170. The gasifier is suitable for receiving as input a fuel 111 and for producing as output a high-temperature syngas flow 114. The lime kiln is suitable for receiving as input carbonate mineral 131 and the high-temperature syngas flow, the lime kiln being further suitable for producing an oxide 134 and for releasing as output a flow of syngas 133 enriched with CO2. The separator is suitable for receiving as input a gas flow containing CO2 and for treating it so as to separately provide at least CO2 151. The CO2 permanent storage is suitable for enclosing along time the CO2. The invention also relates to a method for generating negative emissions of CO2.Type: GrantFiled: January 19, 2018Date of Patent: June 15, 2021Assignee: CO2APPS S.R.L.Inventors: Dennis Alexander Ross Morrey, Giovanni Cappello
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Patent number: 11034900Abstract: A system for gasification of a material includes a plasma generator interfaced to a reaction chamber. A feedstock such as pulverized coal is fed into a plasma jet created by the plasma generator and is gasified by the high temperatures of the plasma jet. The gas produced is then collected, filtered, and utilized, for example, in generating of electricity.Type: GrantFiled: August 2, 2018Date of Patent: June 15, 2021Assignee: MAGNEGAS IP, LLCInventors: Christopher Lynch, Christopher Carey, Kevin Andrew Smith, Richard Conz
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Patent number: 11021766Abstract: A method and apparatus for producing direct reduced iron (DRI), including: generating a reducing gas in a coal gasifier using coal, oxygen, steam, and a first coke oven gas (COG) stream as inputs to the coal gasifier; and delivering the reducing gas to a shaft furnace and exposing iron ore agglomerates to the reducing gas to form metallic iron agglomerates. The method further includes delivering a second COG stream directly to the shaft furnace.Type: GrantFiled: November 3, 2017Date of Patent: June 1, 2021Assignee: Midrex Technologies, Inc.Inventors: Haruyasu Michishita, John Winter
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Patent number: 11001547Abstract: A method for producing methanol includes obtaining reformed gas by subjecting raw material gas containing methane to partial oxidation reforming by use of oxygen; reducing a CO/CO2 ratio in the reformed gas; and obtaining produced gas containing methanol from the reformed gas with the reduced CO/CO2 ratio by using any of a fixed-bed reactor and an isothermal reactor.Type: GrantFiled: November 11, 2016Date of Patent: May 11, 2021Assignee: Mitsubishi Heavy Industries Engineering, Ltd.Inventor: Mikiya Sakurai
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Patent number: 10989113Abstract: The present disclosure relates to a power production system that is adapted to achieve high efficiency power production using partial oxidation of a solid or liquid fuel to form a partially oxidized stream that comprises a fuel gas. This fuel gas stream can be one or more of quenched, filtered, and cooled before being directed to a combustor of a power production system as the combustion fuel. The partially oxidized stream is combined with a compressed recycle CO2 stream and oxygen. The combustion stream is expanded across a turbine to produce power and passed through a recuperator heat exchanger. The expanded and cooled exhaust stream can be further processed to provide the recycle CO2 stream, which is compressed and passed through one or more recuperator heat exchangers in a manner useful to provide increased efficiency to the combined systems.Type: GrantFiled: September 13, 2017Date of Patent: April 27, 2021Assignee: 8 Rivers Capital, LLCInventors: Brock Alan Forrest, Xijia Lu, Rodney John Allam, Jeremy Eron Fetvedt, Miles R. Palmer
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Patent number: 10974183Abstract: A silicon carbide porous body includes a skeletal structure formed by a plurality of silicon carbide particles bonded to each other, a plurality of pores formed by the skeletal structure, neck parts formed by surface-contacting of adjacent silicon carbide particles, and an average pore size is larger than 3 ?m and equal to or smaller than 9 ?m, and a porosity ranges from 35% to 55%. A break filter using the silicon carbide porous body enables high performance of collection of particles, prevention of soaring up of particles, and shortening of a restoration time from the depressurized state of the chamber to the atmospheric state.Type: GrantFiled: March 12, 2019Date of Patent: April 13, 2021Assignee: COORSTEK KKInventors: Seiichi Fukuoka, Hiroki Watanabe
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Patent number: 10938046Abstract: A fuel cell system includes a fuel cell stack, an oxygen-containing gas flow rate control device, a reformer, a raw fuel flow rate control device, and an exhaust gas flow rate control device. In the fuel cell system, the oxygen-containing gas flow rate control device includes a start-up oxygen-containing gas flow rate regulator valve for supplying an oxygen-containing gas to the reformer to perform partial oxidation reforming from start-up of fuel cells until the temperature of the fuel cell stack is raised to a predetermined temperature. After the temperature of the fuel cell stack reaches the predetermined temperature, the exhaust gas flow rate control device supplies an exhaust gas to the reformer to perform the partial oxidation reforming and steam reforming.Type: GrantFiled: April 17, 2012Date of Patent: March 2, 2021Assignee: HONDA MOTOR CO., LTD.Inventor: Yukihiko Kiyohiro
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Patent number: 10927498Abstract: A process for the preparation of small aromatic compounds from black liquor comprising: providing black liquor that derives from alkaline treatment of wood chips; subjecting the black liquor to a pyrolysis treatment to yield a pyrolysed black liquor gas and a solid mass comprising char and salts in a first reactor, wherein the salts substantially derive from the treatment of black liquor; contacting at least part of the pyrolysed black liquor gas with a catalyst in a second reactor, which is different from the first reactor to provide a conversion treatment to yield a conversion product; and recovering small aromatic compounds from the conversion product.Type: GrantFiled: September 22, 2015Date of Patent: February 23, 2021Assignee: HUNTSMAN INTERNATIONAL LLCInventors: André Heeres, Niels Jan Schenk, Arend-Jan Zeeuw, Bart De Waele, Kornelis Jan Kamminga
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Patent number: 10888846Abstract: A methanation catalyst for the methanation of carbon monoxide and/or carbon dioxide is disclosed that provides high selectivity and stability, and additionally shows improved activity compared with prior catalysts. The methanation catalyst for the methanation of carbon monoxide and/or carbon dioxide comprises aluminum oxide, a Ni active mass, and Mn, wherein the Ni/Mn molar ratio in the catalyst is 3.0 to 10.0.Type: GrantFiled: January 26, 2018Date of Patent: January 12, 2021Assignee: CLARIANT PRODUKTE (DEUTSCHLAND) GMBHInventors: Klaus Koehler, Oliver Thomys, Kai-Olaf Hinrichsen, Franz Koschany, Thomas Burger
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Patent number: 10888833Abstract: The present invention relates to a reactor for producing synthesis gas which has a fluid-tight connection to a heat exchanger, and to a process for producing synthesis gas, preferably under high pressure, by using the reactor. The reactor comprises a mixer, a mixing space, a reactor space, separate inlets for at least two fluid reactants and an outlet for at least one fluid product, and a reactor shell surrounding these, and wherein the mixer comprises a mixer base, at least one mixer disk with channels for a first fluid, at least one mixer disk with channels for a second fluid, a mixer closure, and a mixer lid.Type: GrantFiled: March 21, 2017Date of Patent: January 12, 2021Assignee: KARLSRUHER INSTITUT FUER TECHNOLOGIEInventors: Peter Pfeifer, Paolo Piermartini, Tim Boeltken, Robin Duerrschnabel
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Patent number: 10844300Abstract: Method and reactor for producing a product gas from a fuel. The fuel is input into a pyrolysis chamber (6) and a pyrolysis process is executed for obtaining a product gas. Parts of the fuel exiting from the pyrolysis chamber (6) are recirculated to a combustion chamber (20, 23). In the combustion chamber (20, 23) a gasification process is executed in a fluidized bed (20) using a primary process fluid, followed by a combustion process in an area (23) above the fluidized bed (20) using a secondary process fluid.Type: GrantFiled: December 7, 2015Date of Patent: November 24, 2020Assignee: MILENA-OLGA Joint Innovation Assets B.V.Inventors: Berend Joost Vreugdenhil, Abraham van der Drift