Abstract: In a process for producing ammonia which comprises: (a) primary catalytically reforming at super atmospheric pressure in a direct-fired primary reforming zone, a hydrocarbon feedstock with steam to produce a gas containing carbon oxides, hydrogen and methane; (b) secondary catalytically reforming the gas from step (a) by introducing air and bringing the mixture towards equilibrium thereby producing a secondary reformer effluent gas containing nitrogen, carbon oxides, hydrogen and a decreased quantity of methane; (c) converting carbon monoxide catalytically with steam to carbon dioxide and hydrogen; (d) removing carbon oxides to give an ammonia synthesis gas comprising nitrogen and hydrogen and compressing the gas to ammonia synthesis pressure; (e) reacting the synthesis gas in an ammonia synthesis zone to produce ammonia and recovering ammonia from the reacted gas to produce an ammonia-depleted gas stream; (f) recycling at least a portion of the ammonia-depleted gas stream to the ammonia synthesis zone; and (
Abstract: Effluent gas streams for steam reforming, partial oxidation or coal gasification operations are advantageously treated in shift conversion, scrubbing and pressure swing adsorption units for recovery of a purified, hydrogen-containing product gas stream. By recycling a portion of the waste gas removed from the pressure swing adsorption system to the shift conversion unit and/or to the effluent gas generation operation, enhanced product recovery is achieved without the necessity for employing low temperature shift or for achieving essentially complete removal of the carbon dioxide content of the gas being treated prior to its passage to said pressure swing adsorption system.
Abstract: The present invention is a vapor phase activator pad which produces fluorescent vapor fumes for use in a self-contained fingerprinting kit. The vapor phase activator pad is placed into an enclosed area order to fume an object in the area suspected of containing latent fingerprints. The vapor phase activator pad includes a fluorescent dye impregnated gauze pad and a composition. The composition consists of specified chlorinated organic solvents. The gauze pad is chemically treated with the composition so that when a quantity of alkyl-cyanoacrylate is placed onto the vapor phase activator pad. The vapor phase activator pad generates fluorescent vapors of the chemical cyanoacrylate wherein the latent fingerprints become exposed when an ultraviolet light source is shined on the object suspected of containing the latent fingerprints.
Abstract: This is a partial oxidation process in which heavy hydrocarbonaceous fractions from a petroleum refinery and light liquid paraffinic hydrocarbon extractants are used in the production of synthesis gas, reducing gas, or fuel gas i.e. gaseous mixtures comprising H.sub.2 and CO. In the process, substantially all of the particulate carbon and soot that are simultaneously produced are recovered and recycled to the reaction zone.
Type:
Grant
Filed:
March 31, 1983
Date of Patent:
July 31, 1984
Assignee:
Texaco Inc.
Inventors:
Roger M. Dille, Harold A. Rhodes, Susan B. Wallon
Abstract: A method of and composition for developing latent fingerprints on various surfaces including but not limited to glass, plastic, various metals such as copper, brass and the like and other materials such as paper which involves subjecting the latent fingerprints to gaseous fumes produced by cyanoacrylate ester, sodium bicarbonate and sulfur which will develop the latent fingerprints in a very short period of time thereby enabling the fingerprints to be easily lifted by conventional techniques for comparison with known fingerprints. The method of developing latent fingerprints of this invention may be used at the site of a crime by providing the fumes in a pressurized container so that the fumes can be directed into contact with the surface on which the latent fingerprints appear. The method is also effective at the laboratory by providing a container of sufficient size to receive the article or articles on which the fingerprints occur and a quantity of the composition which produces the fumes.
Abstract: Leaks in a vessel or pipeline or the like, adapted for containing a fluid, are sealed by means of a volatilized polymerizable organosilane comprising a mercaptosilane, an acyloxysilane, or an alkoxysilane taken on conjunction either with acetic acid anhydride or an amine, or mixtures thereof, the organosilane being supplied to the interior of the vessel or pipeline under sufficient pressure and for a sufficient period of time to permit contact and chemical reaction thereof in the presence of moisture or sand at the situs of the leak to provide a solid polysiloxane seal.
Abstract: Leaks in a vessel or pipeline or the like adapted for containing a fluid, are sealed by means of a volatilized polymerizable aminosilane supplied to the interior of the vessel under sufficient pressure and for a sufficient period of time to permit contact thereof and react in the presence of moisture or sand at the situs of the leak to provide a solid polysiloxane seal.
Abstract: In welding or working operations using an electric arc a nitrogen compound is introduced into the working or welding area for the purpose of decomposing ozone in said area. The nitrogen compound is preferably purely nitric oxide, but may also be nitrous oxide (N.sub.2 O) or ammonia (NH.sub.3).
Type:
Grant
Filed:
July 5, 1979
Date of Patent:
September 29, 1981
Assignee:
AGA Aktiebolag
Inventors:
Lennart Selander, Lars Fahlen, Ladislav Sipek
Abstract: Ammonia and hydrogen values are recovered from the purge gas from an ammonia synthesis recycle stream by removing the ammonia from the purge gas by adsorption in an ammonia adsorber, thereafter separating the hydrogen by cryogenic partial condensation, the refrigeration for which is provided by expanding and evaporating the condensate, and recovering the ammonia from the adsorber by heating a part of the hydrogen and using it as the regenerating gas for the adsorber, the heat for heating the hydrogen preferably being provided by combusting a part of the evaporated condensate recovered from the cryogenic partial condensation.
Abstract: Leaks in a vessel or pipeline or the like adapted for containing a fluid, are sealed by means of a volatilized polymerizable aminosilane supplied to the interior of the vessel under sufficient pressure and for a sufficient period of time to permit contact thereof and react in the presence of moisture or sand at the situs of the leak to provide a solid polysiloxane seal.
Abstract: A catalyst bed containing alumina pellets on which an active catalyst metal selected from iridium, nickel, niobium, and molybdenium has been deposited is employed to decompose a compound selected from deuterohydrazine, deuteroammonia, hydrazine, and ammonia to yield ammonia free deuterium and nitrogen or hydrogen and nitrogen at a temperature required for immediate use in a DF or HF laser which uses F atoms as the fuel. The decomposition temperature of the catalyst bed is maintained by a hypergolic reaction produced from reacting a fuel selected from the group consisting of hydrazine, methylhydrazine, 1,2-dimethylhydrazine, and blends of the same with an oxidizer selected from the group consisting of inhibited red fuming nitric acid, dinitrogen tetroxide, chlorine trifluoride, and chlorine pentafluoride. A laser employing ammonia free decomposition products of hydrazine and ammonia produced at a temperature between about 500.degree. C. and 900.degree. C. operates at a higher power output. When NH.sub.
Type:
Grant
Filed:
September 12, 1977
Date of Patent:
June 5, 1979
Assignee:
The United States of America as represented by the Secretary of the Army
Inventors:
Pasquale Martignoni, William M. Chew, Orval E. Ayers, James A. Murfree, Jr.
Abstract: Steel powder metallurgy parts having approximately 0.2 to 10% carbon in the form of graphite and approximately 1% lubricant are sintered in the hot zone of a furnace under temperatures of approximately 2050.degree. F for periods of up to approximately 1.0 hour under an atmosphere comprised of at least 90% nitrogen, up to 9.75% hydrogen and carbon monoxide with a maximum 5% carbon monoxide, 0.25-2.0% methane or equivalent hydrocarbon and a dewpoint of the mixed atmosphere of less than -60.degree. F.
Abstract: A catalyst for dissociation of ammonia consists of iron oxides, aluminium oxide, calcium oxide, silicon dioxide, and potassium oxide. The components are present in the catalyst in the following quantities in per cent by weight:______________________________________ iron oxides 87.8 - 48.5 aluminium oxide 10 - 48 calcium oxide 1.35 - 2.15 silicon dioxide 0.35 - 0.4 potassium oxide 0.5 - 0.6 ______________________________________The catalyst is prepared by mixing 87.8 - 48.85 per cent by weight of iron oxides with 1.35 - 2.15 percent by weight of calcium oxide, 0.35 - 0.4 per cent by weight of silicon dioxide, and 0.5 - 0.6 per cent by weight of potassium oxide. The prepared mixture is melted at a temperature of 1600.degree. - 1700.degree.C with subsequent cooling to a temperature of not above 100.degree.C. The cooled mass is crushed and mixed with 10 - 48 per cent by weight of aluminium oxide. The obtained mixture is melted again at a temperature of 1600.degree. - 1700.degree.
Type:
Grant
Filed:
December 10, 1974
Date of Patent:
September 7, 1976
Inventors:
Evgeny Zinovievich Golosman, Viktor Stanislavovich Sobolevsky, Viktor Petrovich Lytkin, Nikolai Nikitovich Axenov, Alexandra Ivanovna Golovkova, Yakov Anatolievich Peker, Dmitry Ivanovich Zinchenko, Sergei Ivanovich Ruzinsky