Anti-corrosion Patents (Class 252/387)
  • Publication number: 20020008226
    Abstract: This invention provides a metal surface-treating method
    Type: Application
    Filed: May 14, 2001
    Publication date: January 24, 2002
    Inventors: Hiroshi Chihara, Kenji Tsuge, Yutaka Kinose, Toru Hata, Eriko Okuno, Takahiro Nagayama
  • Patent number: 6340438
    Abstract: A corrosion inhibiting admixture for concrete is disclosed comprising a combination of organic (amines) and inorganic (nitrites) fractions that provide a synergistic effect when present at a specific ratio. Such a synergistic effect occurs when the amine:nitrite ratio (% by weight) is between 1.5 to 2.5 resulting in the admixture providing excellent corrosion inhibiting capabilities.
    Type: Grant
    Filed: April 19, 1999
    Date of Patent: January 22, 2002
    Assignee: Tomahawk, Inc.
    Inventors: Donald R. Lane, Jose A. Melendez, Violeta F. Munteanu, Frederick D. Kinney
  • Patent number: 6339168
    Abstract: A composition comprising at least a phosphorus compound and a stabilizer compound having one of the formulae I to IV can be used for increasing the shelf life or reducing metal corrosion.
    Type: Grant
    Filed: April 12, 2000
    Date of Patent: January 15, 2002
    Assignee: BASF Aktiengesellschaft
    Inventors: Martin Klatt, Christa Hackl, Günter Scholz
  • Patent number: 6314153
    Abstract: Disclosed is a process for introducing zinc into a water-containing component of the primary system of a nuclear power plant, in particular for preventing the deposition of radioactive cobalt and/or for reducing the possible susceptibility of materials in the component to corrosion. An effective level of zinc is introduced into the component as a dissolved zinc compound which is a zinc complex and/or metal zincate.
    Type: Grant
    Filed: March 6, 2000
    Date of Patent: November 6, 2001
    Assignee: Siemens Aktiengesellschaft
    Inventors: Norbert Henzel, Uve Reitzner
  • Publication number: 20010035347
    Abstract: A method of treating a carbonaceous cell component of an electrolyte cell for the production of aluminum, to impart protection against deterioration during operation of the cell. A liquid suspension of a refractory material dispersed in a lignosulfonate binder solution is prepared and applied as a protective coating to the surface of carbonaceous cell components and allowed to dry.
    Type: Application
    Filed: February 6, 2001
    Publication date: November 1, 2001
    Inventors: Amir A. Mirtchi, Jules Bergeron
  • Publication number: 20010032966
    Abstract: The task of the invention is to provide an anti-corrosion layer for sheet metals, which exhibits corrosion inhibiting characteristics even after prolonged exposure to air and humidity.
    Type: Application
    Filed: March 15, 2001
    Publication date: October 25, 2001
    Inventor: Christina Schmidt
  • Publication number: 20010022947
    Abstract: Effective corrosion inhibitors having minimal organic content, particularly suitable for use in municipal drinking water systems, are described. The corrosion inhibiting additive is a stannous salt of a non-carbon acid.
    Type: Application
    Filed: December 19, 2000
    Publication date: September 20, 2001
    Applicant: A.S. Incorporated
    Inventor: Olen L. Riggs
  • Patent number: 6251305
    Abstract: The present invention relates to a process for reducing the acidity of a petroleum oil containing organic acids comprising treating said petroleum oil containing organic acids with an effective amount of an alcohol at a temperature and under conditions sufficient to form the corresponding ester of said alcohol.
    Type: Grant
    Filed: October 6, 1998
    Date of Patent: June 26, 2001
    Assignee: Exxon Research and Engineering Company
    Inventors: Guido Sartori, David W. Savage, David C. Dalrymple, Bruce H. Ballinger, Saul C. Blum, William E. Wales
  • Patent number: 6248184
    Abstract: A process for sealing the surface coating formed by anodizing an aluminum or aluminum alloy substrate (for example, aerospace, commercial, and architectural products), the process including the steps of: (a) providing an aluminum or aluminum alloy substrate with a surface coating formed thereon by anodizing the aluminum or aluminum alloy substrate; (b) providing a sealing solution comprising a dilute solution of a rare earth metal salt selected from the group consisting of cerium salts and yttrium salts; and (c) contacting the substrate with the sealing solution for a sufficient amount of time to seal the surface coating on the substrate. Also disclosed is a chemical sealing solution for sealing the surface coating formed by anodizing an aluminum or aluminum alloy substrate, the solution being a dilute solution of a rare earth metal salt selected from the group consisting of cerium salts and yttrium salts.
    Type: Grant
    Filed: May 11, 1998
    Date of Patent: June 19, 2001
    Assignees: The Boeing Company, University of Southern California
    Inventors: Dennis L. Dull, Florian B. Mansfeld
  • Patent number: 6248700
    Abstract: This invention relates to novel compositions and methods whereby a carboxylate based brine solution is used in drilling and/or well bore treating operations to inhibit corrosion of fluid handling equipment. In one embodiment of the invention the carboxylate based brine solution consists of a carboxylate salt dissolved in water. This brine solution is used to prepare halide-free drilling fluids. Use of halide-free drilling fluids inhibits corrosion stainless steel surfaces of fluid handling equipment. In an alternative embodiment of the present invention a mixed salt brine containing a carboxylate salt and a halide salt is provided for use in a drilling and/or well bore treating operations.
    Type: Grant
    Filed: November 4, 1998
    Date of Patent: June 19, 2001
    Assignee: Great Lakes Chemical
    Inventors: Daniel P. Vollmer, Robert L. Horton
  • Patent number: 6238594
    Abstract: An intumescent material includes a liquid carrier with a corrosion inhibitor, such as a coating forming material, expandable particulate graphite (flake graphite or lump graphite) and if desired a filler. The intumescent material has a pH greater than 7.0, to reduce the corrosive properties of the intumescent material for most metals used in the construction industry and to provide a chemical environment conducive to the forming of a corrosion inhibiting layer by the corrosion inhibitor. The method of making the intumescent material includes combining the liquid carrier, the corrosion inhibitor, the expandable particulate graphite, the filler (if used), and a pH enhancer (if necessary to bring the intumescent material within the desired pH range), to form an intumescent material having a pH greater than 7.0.
    Type: Grant
    Filed: November 12, 1998
    Date of Patent: May 29, 2001
    Assignee: Passive Fire Protection Partners
    Inventors: Kenneth Albert Turpin, Monroe W. Shumate, Robert D. Hamilton, Walter A. Johnson, Steven N. Volenec, Edward A. Bright, David J. Duquette
  • Patent number: 6207079
    Abstract: This invention relates to a scale inhibiting composition for aqueous systems comprising (a) polyaspartic acid, and (b) a water soluble phosphonated oligomer. The compositions are effective scale and/or corrosion inhibitors, but are also advantageous from an environmental standpoint because they are non-toxic, contain no heavy metals, and have little or no phosphorus. They also have sufficient calcium/hardness tolerance, are chlorine/bromine stable, and are effective corrosion inhibitors.
    Type: Grant
    Filed: January 28, 1999
    Date of Patent: March 27, 2001
    Assignee: Ashland Inc.
    Inventors: Pavol Kmec, Dwight E. Emerich
  • Patent number: 6193815
    Abstract: A highly corrosion resistant and paint adherent surface coating on aluminiferous metals can be provided very rapidly, if desired in less than one second, by contacting the surface with an aqueous acid liquid treating composition containing as solutes specified proportions of phosphate ions, titanium containing materials, fluoride, and an accelerator, the accelerator is preferably at least one of nitrous acid, nitric acid, tungstic acid, molybdic acid, permanganic acid, water soluble salts of all of these acids, and water-soluble organoperoxides.
    Type: Grant
    Filed: December 29, 1997
    Date of Patent: February 27, 2001
    Assignee: Henkel Corporation
    Inventors: Hiroyuki Wada, Kazuya Nakada
  • Patent number: 6183547
    Abstract: A composition for inhibiting corrosion of metal surfaces comprises permanganate and a very low concentration of chromium (VI). The concentration of chromium (VI) in the aqueous solution is less than about 100 micrograms per liter, and the concentration of permanganate is about 0.2% to about 20% by weight of the aqueous solution. In another embodiment of the invention, a composition for inhibiting corrosion of metal surfaces includes permanganate and acetic acid. The concentration of acetic acid in the aqueous solution is between about 0.2% and 2.0% by volume. The concentration of permanganate is about 0.2% to about 20% by weight of the aqueous solution. Other embodiments of the invention include methods of using the present sealant compositions and the resulting corrosion inhibited metal substrates. In yet another embodiment of the present invention there is provided a kit for preparing corrosion inhibiting solutions for metal treatment.
    Type: Grant
    Filed: March 5, 1999
    Date of Patent: February 6, 2001
    Assignee: The University of Notre Dame du Lac
    Inventors: Albert E. Miller, Gautam Banerjee
  • Patent number: 6103144
    Abstract: Non-halogen substituted, nitrogen containing, aromatic compounds are disclosed which are effective copper corrosion inhibitors in aqueous systems being treated with a halogen biocide. The materials of the present invention exhibit copper corrosion inhibition comparable to tolyltriazole in the absence of halogen, copper corrosion rates of less than about 2.5 mills per year in aqueous systems where halogen is present; and do not exhibit a detrimental effect on halogen demand in an aqueous system being treated.
    Type: Grant
    Filed: April 12, 1999
    Date of Patent: August 15, 2000
    Assignee: BetzDearborn Inc.
    Inventor: Longchun Cheng
  • Patent number: 6059996
    Abstract: The invention relates to low-viscosity, aqueous coolant brines based on inhibited alkali metal acetates and/or formates having improved corrosion protection, wherein the coolant brines contain 0.2 to 5% by weight of alkali metal sulfites or pyrosulfites, in particular 1 to 2.5% by weight of these sulfites. The brines according to the invention furthermore contain 0.3 to 5% by weight of basic substances from the alkali metal carbonates, hydroxides, borates and phosphates group and also 0 to 0.3% by weight of alkali metal silicates and 0.02 to 0.2% by weight of stabilizers from the triazoles, benzimidazoles and/or mercaptothiazoles group. The novel coolant brines result in very low corrosion rates, in particular with steel and cast iron.
    Type: Grant
    Filed: August 17, 1998
    Date of Patent: May 9, 2000
    Assignee: Clariant GmbH
    Inventors: Peter Minks, Johann Schuster
  • Patent number: 6056896
    Abstract: The present invention provides an improved metal corrosion inhibitor for use in aqueous acid solutions which is relatively non-toxic and inexpensive. The corrosion inhibitor is a mixture comprised of oligomerized aromatic amines prepared by contacting the still bottoms residue produced in the distillation of quinoline from coal tar with oxygen in the presence of a catalyst.
    Type: Grant
    Filed: May 28, 1998
    Date of Patent: May 2, 2000
    Assignee: Halliburton Energy Services, Inc.
    Inventor: Michael M. Brezinski
  • Patent number: 6042750
    Abstract: A composition for inhibiting corrosion of metal is described, wherein the composition comprises at least one tetraalkylammonium halide, at least one alkyldiamine, at least one polyethylene aliphatic hydrocarbon amine, at least one polyethylene fatty acid ester, at least one aliphatic hydrocarbon hydroxyalkyl imidazoline, at least one polyethylene glycol aliphatic ester, and at least one trialkanolamine, and at least one amine oxyalkylate.
    Type: Grant
    Filed: April 17, 1999
    Date of Patent: March 28, 2000
    Assignee: Joan Docter
    Inventor: James O. Burlew
  • Patent number: 6022494
    Abstract: The invention relates to processes for treating acidic crudes of fractions thereof to reduce or eliminate their acidity and corrosivity by addition of suitable amounts of Group IA of Group IIA oxides, hydroxides and hydrates. The process has the additional benefits of reducing materials handling problems associated with treating acidic crude oils using liquid solvents and in reducing emulsion formation.
    Type: Grant
    Filed: September 15, 1998
    Date of Patent: February 8, 2000
    Assignee: Exxon Research and Engineering Co.
    Inventors: Guido Sartori, David William Savage, Martin Leo Gorbaty, Bruce Henry Ballinger, Saul Charles Blum, Michael Paul Anderson, Trikur Anantharaman Ramanarayanan, David J. Martella
  • Patent number: 6017491
    Abstract: Elastomeric compositions having incorporated therein certain specific compounds and/or compositions which are non-toxic but render the metals to which the compositions are applied resistant to corrosion, particularly, when in a salt environment.
    Type: Grant
    Filed: June 11, 1998
    Date of Patent: January 25, 2000
    Assignees: Products Research & Chemical, Lockheed Corporation
    Inventors: Ahmed Sharaby, Robert N. Miller
  • Patent number: 6007610
    Abstract: Phase change (hot melt) ink compositions for use in a phase change (hot melt) ink jet recording device in which recording is conducted by thermally melting the ink at a temperature above ambient temperature (20.degree. C.) to provide prints that possess high quality images, scratch resistance, abrasion resistance, low-temperature storage stability and flexibility, offset and pick resistance, adhesion, and other desired properties are disclosed to comprise:(a) from about 0.1% to about 30% of one or more colorants; and(b) from about 0.1 to about 99.9% of one or more reversibly-crosslinked-polymers. Components other than those listed above may be included in the ink compositions to achieve specific printer, substrate, or end use requirements. Also, the present invention also includes methods for the preparation of reversibly-crosslinked-polymers and for their use in the above-described inks. Furthermore, the disclosed phase change inks inhibit corrosion of metallic internal printer parts.
    Type: Grant
    Filed: May 8, 1998
    Date of Patent: December 28, 1999
    Assignee: Westvaco Corporation
    Inventors: Michael D. Matzinger, Robert P. Rodebaugh
  • Patent number: 5961885
    Abstract: A corrosion inhibitor comprising a dispersant, an imidazoline, an amide, an alkyl pyridine and a heavy aromatic solvent. The resultant blend effectively inhibits corrosion of flow lines containing low pH mixtures of hydrocarbons, water, and acid gases.
    Type: Grant
    Filed: January 12, 1999
    Date of Patent: October 5, 1999
    Assignee: Champion Technologies, Inc.
    Inventors: Paul Eaton, Sumeet Kanwar
  • Patent number: 5948238
    Abstract: The present invention relates to a process for reducing the acidity of a petroleum oil containing organic acids comprising treating said petroleum oil containing organic acids with an effective amount of an alcohol at a temperature and under conditions sufficient to form the corresponding ester of said alcohol and wherein said treatment is conducted in the presence of a metal carboxylate.
    Type: Grant
    Filed: October 6, 1998
    Date of Patent: September 7, 1999
    Assignee: Exxon Research And Engineering Co.
    Inventors: Guido Sartori, David W. Savage, Saul C. Blum, David C. Dalrymple, William E. Wales
  • Patent number: 5902515
    Abstract: A corrosion inhibitor comprising a dispersant, an imidazoline, an amide, an alkyl pyridine and a heavy aromatic solvent. The resultant blend effectively inhibits corrosion of flow lines containing low pH mixtures of hydrocarbons, water, and acid gases.
    Type: Grant
    Filed: August 16, 1995
    Date of Patent: May 11, 1999
    Assignee: Champion Technologies, Inc.
    Inventors: Sumeet Kanwar, Paul Eaton
  • Patent number: 5888954
    Abstract: A process for inhibiting the corrosion of silver in a dishwashing detergent solution by adding to the solution an inorganic redox-active substance.
    Type: Grant
    Filed: August 28, 1997
    Date of Patent: March 30, 1999
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Juergen Haerer, Helmut Blum, Birgit Burg, Thomas Holderbaum, Willi Buchmeier, Peter Jeschke, Horst-Dieter Speckmann, Frank Wiechmann, Christian Nitsch
  • Patent number: 5855816
    Abstract: A substantially dust-free solid that is treated with a blend of water or other solvent and certain distillation bottoms. The distillation bottoms are at about 60.degree. C. or less and are obtained from production of an alcohol having the formula:R2--R1--OH,wherein R1 is substituted or unsubstituted branched, straight chain or cyclic C.sub.4 to C.sub.12 and R2 is OH or H.
    Type: Grant
    Filed: April 14, 1997
    Date of Patent: January 5, 1999
    Assignee: BASF Corporation
    Inventors: Andrew J. McNabb, Teresa C. Webb
  • Patent number: 5853662
    Abstract: Disclosed is a method for preserving a polished inorganic glass or an article obtained by using the same by enclosing the polished inorganic glass or the article obtained by using the same in a container having a gas barrier property, and then, sealing the container to remove substantially both oxygen and moisture from the container.
    Type: Grant
    Filed: April 17, 1996
    Date of Patent: December 29, 1998
    Assignee: Mitsubishi Gas Chemical Company, Inc.
    Inventor: Takayuki Watanabe
  • Patent number: 5750053
    Abstract: A corrosion inhibitor formulation for use in reinforced concrete structures, the inhibitor reducing the rate of corrosion in metallic reinforcing rods placed within the structures. The formulation comprises a mixture of alkali metal glucoheptonates and alkali metal molybdates.
    Type: Grant
    Filed: January 31, 1996
    Date of Patent: May 12, 1998
    Assignee: Cortec Corporation
    Inventors: Boris A. Miksic, Christophe Chandler, Margarita Kharshan, Alla Furman, Barry Rudman, Larry Gelner
  • Patent number: 5720983
    Abstract: An aqueous composition comprising a lower aliphatic peracid, a corrosion inhibitor and a peroxide stabilizer and/or peracid stabilizer, is useful for disinfecting medical equipment, particularly metal components of such equipment. A process for obtaining such compositions is also provided and comprises mixing a first aqueous solution comprising a lower aliphatic peracid with a second aqueous solution comprising hydrogen peroxide, a corrosion inhibitor and a hydrogen peroxide stabilizer and/or a peracid stabilizer. The first and second aqueous solutions can form a two pack system for obtaining such compositions.
    Type: Grant
    Filed: July 5, 1995
    Date of Patent: February 24, 1998
    Assignee: Solvay Interox Limited
    Inventor: Joseph William Gerard Malone
  • Patent number: 5704961
    Abstract: Non-corrosive nitrogen containing fertilizer solutions are provided which contain effective levels of corrosion inhibitors which are monocarboxylic acids or polycarboxylic acids, or their salts, or mixtures thereof.
    Type: Grant
    Filed: October 17, 1996
    Date of Patent: January 6, 1998
    Inventor: Alice P. Hudson
  • Patent number: 5705566
    Abstract: An adhesive mixture includes a block copolymer hot melt adhesive and particles of a vapor corrosion inhibitor mixed therein to protect products against corrosion. The adhesive is used to seal flaps of containers together, secure carpet to the floor of a vehicle, secure nonwoven fabric to a shrink film so that the additive is released when the shrink film is shrunk around a product to be protected, or used as an adhesive on a tape, so that the product is protected when the tape is wrapped around the product.
    Type: Grant
    Filed: August 19, 1996
    Date of Patent: January 6, 1998
    Assignee: Transhield Technology Co., LLC
    Inventor: Gregory L. Todt
  • Patent number: 5698504
    Abstract: There is provided a bleaching composition, suitable for use in a machine dishwashing method, containing: an oxygen-releasing bleaching agent, from 0.05% to 2.5% by weight, preferably 0.1% to 0.6% by weight of a paraffin oil, from 0.005% to 3%, preferably 0.02% to 1% and most preferably from 0.05% to 0.5% of a benzotriazole compound. Preferably the bleaching composition forms a part of a detergent composition.
    Type: Grant
    Filed: December 21, 1995
    Date of Patent: December 16, 1997
    Assignee: The Procter & Gamble Company
    Inventors: Julie Ann Christie, Fiona Susan Macbeath, John Christopher Turner
  • Patent number: 5683626
    Abstract: The invention relates to a process for treating naphthenic acid--containing whole crudes or fractions thereof to reduce or eliminate their acidity by contacting the acidic whole crude or fraction at a temperature of from about 50.degree. C. to 350.degree. C. with a neutralizing amount of tetraalkylammonium hydroxide, preferably tetramethyl-ammonium hydroxide. The process has the additional benefits of reducing materials handling problems associated with treating oils using liquid solvents and in reducing emulsion formation.
    Type: Grant
    Filed: August 25, 1995
    Date of Patent: November 4, 1997
    Assignee: Exxon Research and Engineering Company
    Inventors: Guido Sartori, David W. Savage, Bruce H. Ballinger
  • Patent number: 5665149
    Abstract: An active heavy metal-free and non-toxic anti-corrosion pigment based on phosphate, which is particularly environmentally friendly, is a mixture of .beta.-tricalcium phosphate and tertiary magnesium phosphate or dicalcium phosphate dihydrate. It has good compatibility with the usual raw materials of paints and additives.
    Type: Grant
    Filed: December 21, 1995
    Date of Patent: September 9, 1997
    Assignee: Chemische Fabrik Budenheim
    Inventors: Karl Gotzmann, Karlheinz Dorn, Hans-Dieter Nagerl, Sieghard Gobelbecker
  • Patent number: 5658498
    Abstract: An aqueous cleaning fluid is provided for retarding electrolysis between dissimilar metals in an electrical circuit and removing contaminates and metal said from electrical conductors. This reduces resistance within the circuit and increases circuit efficiency. The fluid is a complex of naturally occurring essential oils mixed with a surfactant mixture to form a concentrated solution. The concentrated solution is diluted with distilled water and drying agents to levels suitable for application in field operations at or near a job site. The cleaning fluid is applied to conductors within a circuit with a spray bottle. The electrical circuit is taken off line, the conductor surfaces are exposed, and the conductor surfaces are wetted with cleaning fluid until some of the cleaning fluid drips from the conductor surface. Then the circuit is reassembled and the circuit is put on line.
    Type: Grant
    Filed: August 29, 1996
    Date of Patent: August 19, 1997
    Inventor: Carl R. Driskill
  • Patent number: 5643439
    Abstract: The invention relates to a process for treating naphthenic acid-containing whole crudes or fractions thereof to reduce or eliminate their acidity by contacting the acidic whole crude at a temperature of from about 60.degree. C. to 170.degree. C. with a neutralizing amount of alkali metal trialkylsilanolates. The process has the additional benefits of reducing materials handling problems associated with treating crudes using liquid solvents and in reducing emulsion formation.
    Type: Grant
    Filed: August 25, 1995
    Date of Patent: July 1, 1997
    Assignee: Exxon Research and Engineering Company
    Inventors: Guido Sartori, David W. Savage, Martin L. Gorbaty, Bruce Henry Ballinger
  • Patent number: 5643499
    Abstract: Galvanic degradation under salt spray or salt water conditions in hybrid structures containing a corrosible metal and a conductive-fiber reinforced polymer matrix composite is reduced through the addition to the polymer matrix of the composite of an effective amount of an inorganic corrosion/degradation inhibitor.
    Type: Grant
    Filed: September 14, 1993
    Date of Patent: July 1, 1997
    Assignee: Cytec Technology Corp.
    Inventors: Jack D. Boyd, Lawrence C. Hopper
  • Patent number: 5639422
    Abstract: Disclosed is a method of reducing the corrosion of a carbon steel reboiler in which a reboiler fluid containing nitrogen trichloride is heated to decompose the nitrogen trichloride. About 1 to about 100 ppm, based on the reboiler fluid weight, of a source of iodine, is added to the reboiler.
    Type: Grant
    Filed: August 2, 1996
    Date of Patent: June 17, 1997
    Assignee: Occidental Chemical Corporation
    Inventors: Chao-Peng Chen, Tilak V. Bommaraju, Paul C. Williams
  • Patent number: 5624634
    Abstract: A multi-component product for providing, on mixing of the components, a disinfectant composition. A first component of the product comprises an aqueous solution of a lower aliphatic peracid and a second component comprises an aqueous solution containing a phosphate corrosion inhibitor and either a hydrogen peroxide stabilizer, a peracid stabilizer, or both.
    Type: Grant
    Filed: June 2, 1995
    Date of Patent: April 29, 1997
    Assignee: Solvay Interox Limited
    Inventors: Paul Brougham, Robert A. Simms
  • Patent number: 5597514
    Abstract: A corrosion inhibitor formulation for use in reinforced concrete structures, the inhibitor reducing the rate of corrosion in metallic reinforcing rods placed within the structures. The formulation comprises a mixture of benzoic acid, aldonic acid, and a triazole such as benzotriazole or tolyltriazole.
    Type: Grant
    Filed: January 24, 1995
    Date of Patent: January 28, 1997
    Assignee: Cortec Corporation
    Inventors: Boris A. Miksic, Christophe Chandler, Margarita Kharshan, Alla Furman, Barry Rudman, Larry Gelner
  • Patent number: 5589106
    Abstract: The prevention of corrosion on the surfaces of metallic pipes, heat exchangers, and the like which are in contact with industrial cooling waters, and particularly industrial cooling waters containing low levels of hardness is controlled utilizing a corrosion inhibiting amount of a composition including an alkali metal silicate, a hydroxycarboxylic acid or its water soluble salts, an organophosphonate, and a water soluble polymer which acts as a dispersant. Superior corrosion inhibition is achieved using the compositions of this invention as corrosion inhibitors, particularly in cooling water systems employing mild steel metallurgy.
    Type: Grant
    Filed: February 14, 1995
    Date of Patent: December 31, 1996
    Assignee: Nalco Chemical Company
    Inventors: Sang-Hea Shim, Dennis P. Bakalik, Donald A. Johnson, Bo Yang, Frank F. Lu
  • Patent number: 5578246
    Abstract: This invention relates to a metal corrosion inhibiting composition comprising in admixture: (a) an anodic silicate salt; (b) a silicate salt stabilizer; (c) a cathodic corrosion inhibitor; and water. Preferably, the corrosion inhibiting composition also contains a polymeric scale inhibitor. The invention also relates to a process for treating an open aqueous system with the corrosion inhibiting composition.
    Type: Grant
    Filed: October 3, 1994
    Date of Patent: November 26, 1996
    Assignee: Ashland Inc.
    Inventor: Edward S. Beardwood
  • Patent number: 5567354
    Abstract: The invention relates to a corrosion inhibitor for a metal material such as steel, of the type consisting of an aqueous solution containing an alkali metal nitrite, wherein said solution contains 0.01 to 0.3 mol/l of an alkali metal nitrite, 0.01 to 0.3 mol/l of an alkali metal phosphate, and phosphoric acid in a proportion of a quantity sufficient to maintain the pH of said solution, measured at ambient temperature, between 6.9 and 7.2.
    Type: Grant
    Filed: November 22, 1994
    Date of Patent: October 22, 1996
    Assignee: Sollac (Societe Anonyme)
    Inventors: Christian Schwendimann, Jacques Keller, Jean-Luc Auger, Philippe Fatrez
  • Patent number: 5560868
    Abstract: Halide glasses having particular utility as hosts for praseodynmium in order to provide optical amplification by laser activity have a halide content provided as a small proportion, e.g., 1-10 percent, of choride with the remainder as fluoride. The metal content is similar to conventional ZBLAN glasses. The replacement of A1 by Y and In and/or the partial replacement of Na by Cs has synergistic benefits. PR.sup.3+ constitutes a good lasing species for amplifying telecommunication signals at 1300 nm using pumped radiation at 1020 nm.
    Type: Grant
    Filed: May 22, 1995
    Date of Patent: October 1, 1996
    Assignee: British Telecommunications public limited company
    Inventors: Wayne G. Jordan, Animesh Jha, Steven T. Davey
  • Patent number: 5545343
    Abstract: A multi-component product for providing, on mixing of the components, a disinfectant composition. A first component of the product comprises an aqueous solution of a lower aliphatic peracid and a second component comprises an aqueous solution containing a corrosion inhibitor and either a hydrogen peroxide stabilizer, a peracid stabilizer, or both.
    Type: Grant
    Filed: June 21, 1994
    Date of Patent: August 13, 1996
    Assignee: Solvay Interox Limited
    Inventors: Paul Brougham, Robert A. Simms
  • Patent number: 5531931
    Abstract: Salt-based deicing compositions which are highly effective as deicers and which have significantly reduced corrosive effects are provided. One deicing composition comprises a deicing salt as the major component and an inhibitor system comprising either a water-soluble rare earth salt or a water-soluble organic acid salt selected from the group consisting of gluconate salts, ascorbate salts, tartrate salts, and saccharate salts. A more preferred deicing composition comprises a deicing salt as the major component and an inhibitor system comprising a mixture of a water-soluble rare earth salt and a water-soluble organic acid salt selected from the group consisting of gluconate salts, ascorbate salts, tartrate salts, and saccharate salts. The deicing salts include sodium chloride and mixtures of sodium chloride and up to 25 weight percent magnesium chloride or calcium chloride. The preferred deicing salt is sodium chloride.
    Type: Grant
    Filed: December 30, 1994
    Date of Patent: July 2, 1996
    Assignee: Cargill, Incorporated
    Inventor: Robert S. Koefod
  • Patent number: 5520837
    Abstract: A cleaning composition, method of manufacture and method of cleaning of for se in cleaning equipment including life support equipment employed in the generating, handling, storage and delivery of oxygen-enriched gases and liquids are provided in which the cleaning composition is inorganic, non-flammable, non-toxic, environmentally safe, non-corrosive, and ready to use and which includes an aqueous silicate solution together with fluoroborates and molybdates.
    Type: Grant
    Filed: June 28, 1995
    Date of Patent: May 28, 1996
    Assignee: The United States of America as represented by the Secretary of the Navy
    Inventors: Neil E. Antin, Douglas P. Jackson
  • Patent number: 5512212
    Abstract: A composition and method for inhibiting corrosion of iron and iron-containing metals in contact with aqueous systems containing sulfide compounds. The composition comprises (A) an aqueous solution of an alcohol, an acid, a fatty imidazoline, and an ethoxylated fatty diamine, and (B) an aqueous solution of a molybdate compound or salt thereof.
    Type: Grant
    Filed: January 17, 1995
    Date of Patent: April 30, 1996
    Assignee: Betz Laboratories, Inc.
    Inventors: J. Michael Brown, James R. Ohlsen, Richard D. McBride
  • Patent number: 5510057
    Abstract: The present invention provides a method and compositions useful for inhibiting corrosion of a corrodible metal resulting from contact of water and air with the metal. In this method, a stannous salt and a hydrocarbyl substituted succinimide of a polyethylene polyamine are added to the water in minor amounts and cooperatively reduce corrosion of the metal to a substantially zero rate. While the amount of each agent for an effective inhibition is minor, say in the range of from about 0.1 to 100 ppm, a relatively concentrated solution is required for addition to the water. Suitable solvent media include the lower alkanols and mixture thereof with or without added water. Isopropanol is preferred. The solvent component of the compositions also varies depending upon the particular imide and/or salt component employed and the concentration desired.
    Type: Grant
    Filed: May 6, 1994
    Date of Patent: April 23, 1996
    Inventor: Olen L. Riggs
  • Patent number: 5455206
    Abstract: Ceramic materials which exhibit stability in severely-corrosive environments having high alkali-metal activity, high sulfur/sulfide activity and/or molten halides at temperatures of 200.degree.-550.degree. C. or organic salt (including SO.sub.2 and SO.sub.2 Cl.sub.2) at temperatures of 25.degree.-200.degree. C. These sulfide ceramics form stoichiometric (single-phase) compounds with sulfides of Ca, Li, Na, K, Al, Mg, Si, Y, La, Ce, Ga, Ba, Zr and Sr and show melting-points that are sufficiently low and have excellent wettability with many metals (Fe, Ni, Mo) to easily form metal/ceramic seals. Ceramic compositions are also formulated to adequately match thermal expansion coefficient of adjacent metal components.
    Type: Grant
    Filed: March 10, 1993
    Date of Patent: October 3, 1995
    Inventor: Thomas D. Kaun