Anti-corrosion Patents (Class 252/387)
- Component inorganic or organic comprising element other than C,H,O,N,S, and halogen (Class 252/389.1)
- Amine, amide, azo, or nitrogen-base radical containing (Class 252/390)
- Phenol or quinone radical containing (Class 252/393)
- Nitrogen organic compound containing (Class 252/394)
- Sulphur organic compound containing (Class 252/395)
- Oxygen organic compound containing (Class 252/396)
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Patent number: 5435941Abstract: A method of extracting corrosion inhibiting constituents from tobacco comprises the steps of soaking tobacco in an aqueous solution under certain extraction conditions, followed by filtration to remove tobacco residue from the resultant aqueous tobacco solution. This tobacco solution is used as a corrosion inhibitor to minimize the amount of corrosion occurring at galvanic corrosion cells that are established at areas of union of metals having different electrochemical potentials.Type: GrantFiled: December 6, 1994Date of Patent: July 25, 1995Assignee: University of LouisvilleInventor: Joseph A. Von Fraunhofer
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Patent number: 5427709Abstract: A cleaning composition, method of manufacture and method of cleaning of for se in cleaning equipment including life support equipment employed in the generating, handling, storage and delivery of oxygen-enriched gases and liquids are provided in which the cleaning composition is inorganic, non-flammable, non-toxic, environmentally safe, non-corrosive, and ready to use and which includes an aqueous silicate solution together with fluoroborates and molybdates.Type: GrantFiled: January 14, 1994Date of Patent: June 27, 1995Assignee: The United States of America as represented by the Secretary of the NavyInventors: Neil E. Antin, Douglas P. Jackson
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Patent number: 5419779Abstract: An aqueous stripping composition comprising a mixture of about 55% to 70% by weight of monoethanolamine, about 22.5 to 15% by weight of hydroxylamine and water. The stripping composition is effective to strip photoresists, residues from plasma process generated, organic, metal-organic materials, inorganic salts, oxides, hydroxides or complexes in combination with or exclusive of organic photoresist films at low temperatures without redepositing any substantial amount of metal ions.Type: GrantFiled: December 2, 1993Date of Patent: May 30, 1995Assignee: Ashland Inc.Inventor: Irl E. Ward
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Patent number: 5416150Abstract: A resin composition comprises an aqueous emulsion of an acrylic resin, titanium oxide, iron oxide, and calcium carbonate.Type: GrantFiled: August 4, 1994Date of Patent: May 16, 1995Assignee: Hachiro ShinpoInventor: Harry Boeck
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Patent number: 5415805Abstract: A composition and method for inhibiting corrosion of iron and iron-containing metals in contact with aqueous systems containing sulfide compounds. The composition comprises (A) an aqueous solution of an alcohol, an acid, a fatty imidazoline, and an ethoxylated fatty diamine, and (B) an aqueous solution of a molybdate compound or salt thereof.Type: GrantFiled: February 25, 1994Date of Patent: May 16, 1995Assignee: Betz Laboratories, Inc.Inventors: J. Michael Brown, James R. Ohlsen, Richard D. McBride
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Patent number: 5411677Abstract: A corrosion inhibitor composition and a method for employing the same to prevent corrosion of copper and copper containing metals in contact are disclosed. Protection is afforded thereto by contacting the metal surface with the medium containing sufficient amount of benzotriazole/its derivatives and halogen, preferentially iodide or bromide ions. The inhibitor has particular utility in protecting metal surfaces which are subject to corrosion in aggressive aqueous systems.Type: GrantFiled: April 26, 1993Date of Patent: May 2, 1995Assignee: The Penn State Research FoundationInventors: Howard W. Pickering, Yongchun Wu
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Patent number: 5391349Abstract: The corrosion of ferrous-based metals imbedded in concrete containing a chloride is inhibited by drawing the chlorides away from the metal, and then applying a composition containing ammonium carbamate or ammonium carbonate to the concrete. An agent may be added to the solution to prevent any calcium hydroxide contained in the concrete from precipitating the corrosion inhibitor.Type: GrantFiled: November 12, 1993Date of Patent: February 21, 1995Inventor: Charles N. Hansen
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Patent number: 5378401Abstract: An improved method is disclosed for preparing zinc polyphosphate in a stable, concentrated solution, for water treatment purposes having a pH above 7.0 and in a preferred range of pH between 8.0 and 10.0. Without any acid solubilization required, an approximate 60% solution of tetrapotassium pyrophosphate (TKPP) is formulated and mixed thoroughly in a tank or similar container. Under constant stirring, a predetermined aqueous solution of a normal zinc salt, such as zinc chloride, gradually injected and mixed together into the TKPP solution at a preferred rate of about 5% of the zinc salt solution per minute and in a sufficient amount determined to add about 1 part of zinc to between 5-8 parts of TKPP by weight for maximum corrosion protection.Type: GrantFiled: January 31, 1992Date of Patent: January 3, 1995Assignee: Klenzoid, Inc.Inventors: James J. Derham, Joseph E. Lubitsky, William C. Flanagan
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Patent number: 5342578Abstract: A method of inhibiting corrosion in ammonia-water absorption machines that includes adding to an ammonia-water solution soluble silicon compounds. Examples of these silicon compounds include sodium silicate (Na.sub.2 SiO.sub.3), potassium silicate (K.sub.2 SiO.sub.3), lithium silicate (Li.sub.2 SiO.sub.3), silicic acid (H.sub.2 SiO.sub.5), and tetramethoxysilane (CH.sub.3 O).sub.4 Si. Sodium silicate is revealed as the preferred embodiment.Type: GrantFiled: February 23, 1993Date of Patent: August 30, 1994Assignee: Gas Research InstituteInventors: Arun K. Agrawal, Barry Hindin
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Patent number: 5330683Abstract: An environmentally acceptable and economically appealing method of inhibiting corrosion in brine solution systems wherein an aqueous brine solution is treated with gluconate or sorbitol.Type: GrantFiled: June 17, 1993Date of Patent: July 19, 1994Assignee: Nalco Chemical CompanyInventor: Barry W. Sufrin
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Patent number: 5296167Abstract: There is disclosed a method to inhibit the corrosion of metals by sodium chloride and calcium chloride solutions by incorporating in the solutions a mixture of mono- and di-hydrogen orthophosphates. Sodium chloride solutions which contain calcium chloride, e.g., rock salt solutions, are inhibited against corrosion when the percentage of dihydrogen orthophosphate is from 10 to 60 percent of the mixture of di- and mono-hydrogen orthophosphates. Calcium chloride solutions are inhibited against corrosion when the percentage of dihydrogen orthophosphate is from 50 to 100 percent of the mixture of di- and mono-hydrogen orthophosphates.Type: GrantFiled: May 13, 1991Date of Patent: March 22, 1994Inventor: W. Bruce Murray
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Patent number: 5268127Abstract: The present invention provides a method for inhibiting corrosion of carbon steel in contact with a mixture of hydrofluoric acid and tetrahydrothiophene-1,1-dioxide comprising adding a corrosion inhibiting amount of an alkali metal halide to said mixture of hydrofluoric acid and tetrahydrothiophene-1,1-dioxide.Type: GrantFiled: July 15, 1992Date of Patent: December 7, 1993Assignee: Mobil Oil CorporationInventor: Yiing-Mei Wu
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Patent number: 5250325Abstract: Coating composition comprising:A) an organic film-forming binder; andB) a corrosion-inhibiting amount of a water-insoluble salt of i) a carboxylic acid having the formula (I): ##STR1## and ii) a base selected from a) a cation of Group Ib, IIa, IIb, IIIa, IIIb, IVa, IVb, Va, VIa, VIIa or VIIIa of the Periodic Table of Elements, b) an amine of formula II: ##STR2## c) a guanidine of formula III:R.sub.7 --N.dbd.C(NH.sub.2).sub.2 IIId) an amidine of formula IV:R.sub.7 --C(.dbd.NH)NH.sub.2 IVor e) melamine.Type: GrantFiled: January 21, 1993Date of Patent: October 5, 1993Assignee: Ciba-Geigy CorporationInventors: Emyr Phillips, William P. Armstrong
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Patent number: 5242488Abstract: A coating composition for ferrous metal alloy surfaces comprises a slurry consisting essentially of an aluminum neutralized phosphate bonding solution and aluminum powder. A process for forming the bonding solution component of the coating slurry includes equilibrating an aqueous phosphate solution with a small but controlled and necessary amount of solute aluminum prior to adding aluminum powder to form the slurry. The bonding solution preferably also contains magnesium. The present invention overcomes the problem of bonding solutions which require environmentally disadvantageous chromates or molybdates to neutralize the bonding solution prior to formation of the slurry.Type: GrantFiled: June 1, 1992Date of Patent: September 7, 1993Assignee: Solar Turbines IncorporatedInventors: Alvin R. Stetson, William D. Brentnall, Zaher Z. Mutasim
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Patent number: 5232629Abstract: An orthophosphate salt and sodium silicate, when used in a 3:1 ratio by weight, and in a concentration of 0.1 to 100 mg/L, are found to have a synergistic effect in controlling the corrosion of carbon steel in an aqueous system, e.g., a municipal water supply system. The synergistic combination is also useful in reducing lead solubility and leaching, and in stabilizing soluble iron and manganese and their reaction products.Type: GrantFiled: March 2, 1992Date of Patent: August 3, 1993Assignee: Calgon CorporationInventor: Bennett P. Boffardi
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Patent number: 5232798Abstract: A method for the inhibition of corrosion in particulate zinc, comprises the step of subjecting the zinc in the form of an alkaline slurry to the action of a corrosion inhibiting effective amount of a corrosion inhibitor which is at least one oxide selected from the oxides of antimony, bismuth, cadmium, gallium, indium, lead, mercury, thallium and tin, and which preferably constitutes 0.05-4.0 parts by weight, based on the weight of the zinc. The particulate zinc may be that recovered electrolytically from at least partially spent electrolyte from a zinc-air battery. Corrosion inhibited particulate zinc which has been treated according to the above method, as well as a mixture of (untreated) particulate zinc with such treated zinc, also form part of the invention.Type: GrantFiled: December 31, 1990Date of Patent: August 3, 1993Assignee: Electric Fuel (E.F.L.) Ltd.Inventors: Jonathan Goldstein, Arieh Meitav, Michael Kravitz
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Patent number: 5225103Abstract: Aqueous aldehyde solutions for trapping hydrogen sulfide comprising 5 to 50% by weight of an aldehyde and 1 to 5% by weight, relative to the aldehyde solution of a formulation comprisinga) 10 to 80% by weight of a long-chain quaternary ammonium compound and 20 to 90% by weight of water or of a C.sub.1 -C.sub.4 -alcohol,b) 10 to 80% by weight of a condensation product of a C.sub.12 -C.sub.18 -fatty acid with a polyethylene polyamine of the formulaNH.sub.2 --(C.sub.2 H.sub.4 --NH).sub.x --C.sub.2 H.sub.4 --NH.sub.2in which x is 1, 2 or 3 and the molar ratio of fatty acid to basic nitrogen in the polyethylene polyamine is 3:1 to 3:2, and 20 to 90% by weight of water or of a C.sub.1 -C.sub.4 -alcohol, orc) 50 to 95% by weight of the fatty acid-polyethylene polyamine condensation product as defined in b) and 5 to 50% by weight of a nonionic or anionic surfactant.Type: GrantFiled: July 7, 1992Date of Patent: July 6, 1993Assignee: Hoechst AktiengesellschaftInventors: Hermann Hoffmann, Frederic Mabire
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Patent number: 5211881Abstract: Corrosion resistance of metals such as aluminum is promoted by contact with a formulation containing a solution of an acrylic polymer; a blocked water-soluble zirconium or zinc catalyst; a mixture of water and an organic solvent; and a corrosion additive component.Type: GrantFiled: January 30, 1992Date of Patent: May 18, 1993Assignee: Elf Atochem North America, Inc.Inventors: Frank A. Muller, Ronald F. Dubs
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Patent number: 5202058Abstract: The present invention provides a method and compositions useful for inhibiting corrosion of a corrodible metal resulting from contact of water and air with the metal. In this method, a stannous salt and a hydrocarbyl substituted succinimide of a polyethylene polyamine are added to the water in minor amounts and cooperatively reduce corrosion of the metal to a substantially zero rate. While the amount of each agent for an effective inhibition is minor, say in the range of from about 0.1 to 100 ppm, a relatively concentrated solution is required for addition to the water. Suitable solvent media include the lower alkanols and mixture thereof with or without added water. Isopropanol is preferred. The solvent component of the compositions also varies depending upon the particular imide and/or salt component employed and the concentration desired.Type: GrantFiled: November 6, 1991Date of Patent: April 13, 1993Assignee: A.S. IncorporatedInventor: Olen L. Riggs, Jr.
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Patent number: 5198189Abstract: A liquid metal matrix thermal paste comprises a dispersion of non-reacting thermally conductive particles in a low melting temperature liquid metal matrix. The particles preferably are silicon, molybdenum, tungsten or other materials which do not react with gallium at temperatures below approximately 100.degree. C. The preferred liquid metals are gallium and indium eutectic, gallium and tin eutectic and gallium, indium and tin ternary eutectic. The particles may be coated with a noble metal to minimize surface oxidation and enhance wettability of the particles. The liquid metal matrix thermal paste is used as a high thermally conducting paste in cooling high power dissipation components in conjunction with a conventional fluid cooling system.Type: GrantFiled: April 13, 1992Date of Patent: March 30, 1993Assignee: International Business Machines CorporationInventors: Richard B. Booth, Gary W. Grube, Peter A. Gruber, Igor Y. Khandros, Arthur R. Zingher
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Patent number: 5191803Abstract: A method for detecting the presence of any discontinuity in an anticorrosion oil coating applied onto the internal walls of a nautical ballast. The method comprises the steps of (1) adding an oil-soluble tracer to the anticorrosion oil coating prior to its application onto the internal walls of the ballast, the tracer being insoluble in water and rust; inert to rust, water and the oil; and capable of emitting visible light under the effect of a black light; (2) after application of the oil coating, submitting the inside walls coated with the oil to the effect of a black light, and (3) checking the continuity of the visible light that is emitted by the oil coating, whereby the presence of oil is detected by visible light emitted by the tracer and its absence is detected by the absence of any emitted visible light. An anticorrosion oil containing such a tracer is also disclosed.Type: GrantFiled: January 22, 1991Date of Patent: March 9, 1993Assignee: Mag Chem Inc.Inventor: Roger A. Gamache
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Patent number: 5164110Abstract: New oxygen scavengers for boiler waters have been discovered, which oxygen scavengers are based upon N,N,N',N'-tetra substituted phenylenediamines. These compounds provide oxygen scavenging capabilities, metal passivating capabilities, volatility such that condensate systems in an operating boiler are protected, and may be formulated with other oxygen scavengers and other common treatment agents used in boiler waters.The preferred tetra substituted phenylenediamines are N,N,N',N'-tetramethyl-1,4-phenylenediamines, or its precursors.Type: GrantFiled: October 11, 1991Date of Patent: November 17, 1992Assignee: Nalco Chemical CompanyInventors: Scott R. Haraer, Cynthia A. Soderquist, Claudia C. Pierce
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Patent number: 5154860Abstract: Disclosed is a method of inhibiting the electrochemical corrosion of stainless steel immersed in an aqueous solution of about 20 to about 40 wt % alkali metal hydroxide at a temperature of less than 100.degree. C. About 2 to about 500 ppm of sodium borohydride, hydrazine, or a mixture thereof is added to the aqueous solution.Type: GrantFiled: September 16, 1991Date of Patent: October 13, 1992Assignee: Occidental Chemical CorporationInventors: Tilak V. Bommaraju, Robert G. Adams
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Patent number: 5152916Abstract: Aqueous aldehyde solutions for trapping hydrogen sulfide comprising 5 to 50% by weight of an aldehyde and 1 to 5% by weight, relative to the aldehyde solution of a formulation comprising10 to 80% by weight of an ester of oxalkylated alkylalkylenediamines, which may be quaternized and 20 to 90% by weight of water or of a C.sub.1 -C.sub.4 -alcohol.Type: GrantFiled: August 21, 1990Date of Patent: October 6, 1992Assignee: Hoechst AktiengesellschaftInventors: Hermann Hoffmann, Frederic Mabire
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Synergistic combination of sodium silicate and orthophosphate for controlling carbon steel corrosion
Patent number: 5137657Abstract: An orthophosphate salt and sodium silicate, when used in a 3:1 ratio by weight, and in a concentration of 0.1 to 100 mg/L, are found to have a synergistic effect in controlling the corrosion of carbon steel in an aqueous system, e.g., a municipal water supply system. The synergistic combination is also useful in reducing lead solubility and leaching, and in stabilizing soluble iron and manganese and their reaction products.Type: GrantFiled: April 24, 1991Date of Patent: August 11, 1992Assignee: Merck & Co., Inc.Inventor: Bennett P. Boffardi -
Patent number: 5130052Abstract: A method of inhibiting corrosion of a metal surface in an aqueous system having a pH of at least 6, comprising maintaining in the aqueous system, in an amount effective to inhibit corrosion, a water-soluble, organic-rare earth metal chelate which is derived from a rare earth metal having an atomic number from 57 to 71 and an organic chelant. The organic chelant provides not only water solubility but surprisingly enhanced corrosion inhibiting activity. The water-soluble, organic-rare earth chelates may be advantageously combined with other corrosion inhibitors such as zinc chelates, organophosphonates, phosphates, chromates, molybdates, and the like.Type: GrantFiled: October 24, 1991Date of Patent: July 14, 1992Assignee: W. R. Grace & Co.-Conn.Inventors: Robert P. Kreh, Vincent R. Kuhn, John Richardson, Robert M. Spotnitz, Charles G. Carter, Vladimir Jovancicevic
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Patent number: 5126074Abstract: The invention shows anticorrosive pigments on the basis of alkaline earth hydrogen phosphates, which are distinguished in that they contain from 20 mole-% to 60 mole-% of alkaline earth carbonate, the balance being alkaline earth hydrogen phosphate of the particular like alkaline earth metal, as well as a process of producing them in that alkaline earth carbonate and phosphoric acid are in per se known manner reacted with one another at the desired molar ratio, as well as the use of the anticorrosive pigments for corrosion protection of aluminum substrates, particularly for preventing filiform corrosion in aircraft coatings.Type: GrantFiled: July 23, 1991Date of Patent: June 30, 1992Assignee: Dr. Hans Heubach GmbH & Co. KGInventor: Annegret Bittner
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Patent number: 5118444Abstract: The present invention discloses a method of producing as aqueous agricultural composition exhibiting reduced irritation to animals and corrosiveness to materials by admixing an agriculturally acceptable pesticide and an amine-oxide surfactant having the Formula: ##STR1## wherein R.sup.1 is a straight or branched chain about C.sub.6 to about C.sub.20 alkyl or alkenyl group, R.sup.2, R.sup.3, R.sup.4 and R.sup.5 are each independently selected from the group of straight and branched chain lower alkylenyl groups, and a+b+c+d is about 5 to about 25. The compositions exhibit reduced eye irritation to animals and reduced corrosiveness to metals. A method of treating plants is also disclosed.Type: GrantFiled: April 10, 1991Date of Patent: June 2, 1992Assignee: Witco CorporationInventor: Giao V. Nguyen
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Patent number: 5104577Abstract: A surface treatment chemical for aluminum or its alloy consisting essentially of 10-1000 parts by weight of one or more ions of metals selected from the group consisting of scandium, yttrium, lanthanum, praseodymium, neodymium, samarium, europium, gadolinium, terbium, dysprosium, holmium, erbium, thulium, ytterbium and lutetium, 10-500 parts by weight of zirconium ion, 10-500 parts by weight of phosphate ion and 1-50 parts by weight of effective fluorine ion. A surface treatment bath for aluminum or its alloy consisting essentially of 10-1000 ppm of one or more ions of metals selected from the group consisting of scandium, yttrium, lanthanum, praseodymium, neodymium, samarium, europium, gadolinium, terbium, dysprosium, holmium, erbium, thulium, yttterbium and lutetium, 10-500 ppm of zirconium ion, 10-500 ppm of phosphate ion and 1-50 ppm of effective fluorine ion, and having a pH of 1.8-4.0.Type: GrantFiled: August 1, 1990Date of Patent: April 14, 1992Assignee: Nippon Paint Co., Ltd.Inventors: Satoshi Ikeda, Shigeyuki Meguro
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Patent number: 5091112Abstract: Reducing the copper corrosiveness of organic sulfides by treating them with an alkali metal-containing or alkaline earth metal-containing substance capable of dissolving elemental sulfur (e.g., sodium hydroxide, sodium sulfide, etc.). The process is conducted in a substantially homogeneous liquid reaction medium composed of a mixture of water and at least one ketone. Experiments have shown that it is possible by use of this process to reduce the copper corrosiveness to a level below that exhibited by a product formed by treating the same initial organic sulfide in the same way but in a liquid medium composed solely of water.Type: GrantFiled: March 19, 1990Date of Patent: February 25, 1992Assignee: Ethyl Petroleum Additives, Inc.Inventors: Edmund F. Perozzi, John F. Sieberth
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Patent number: 5076941Abstract: Monofluorophosphate salts, especially sodium monofluorophosphate (Na.sub.2 PO.sub.3 F), when added to potable water sources in concentrations between 0.1 mg/L and 500 mg/L, significantly reduces lead (Pb) leaching into said water, producing the double benefit of reducing lead solubility and thus content in drinking water, while at the same time adding fluoride to that drinking water, with the anticaries benefit that fluoridation provides.Type: GrantFiled: October 15, 1990Date of Patent: December 31, 1991Assignee: Calgon Corp.Inventors: Bennett P. Boffardi, Ann M. Sherbondy
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Patent number: 5071579Abstract: The corrosion inhibiting systems comprise at least one of the following: sodium fluorophosphate, and a water soluble salt of phosphonic acid derivatives having the general formula R.sub.n R.sub.1 N(CH.sub.2 PO.sub.3 H.sub.2).sub.2-n wherein R.sub.n and R.sub.1 are each independently selected from a member selected from the group consisting of alkyl, aminoalkyl and N-hydroxyalkyl and n is an integer selected from 1 and 0. The methods comprise laying on a surface a system as defined above. The invention also discloses deicers, paints and other corrosion inhibitors in numerous carriers. Products containing at least residual amounts of a system as defined above are also disclosed.Type: GrantFiled: December 12, 1988Date of Patent: December 10, 1991Assignee: Domtar Inc.Inventors: Allan Johnston, Dean Mason, Darren F. Lawless, Terrence E. Peel
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Patent number: 5041241Abstract: A corrosion-inhibiting composition comprises a blend of particles of two amorphous silicas; one containing corrosion-inhibiting cations releasable by ion-exchange and the second being substantially free of any corrosion-inhibiting ions. The weight ratio of the cation-containing silica to non ion containing silica is in the range 20:80 to 60:40.The corrosion-inhibiting composition may be incorporated into liquid media and protective coatings, which are based on film-forming polymers e.g. epoxy resins, vinyl resins, epoxy esters.The amorphous silica used is preferably of a microporous type. Calcium cations are the preferred corrosion inhibiting cations. The composition is preferable used to inhibit corrosion of aluminium surfaces.Type: GrantFiled: October 20, 1988Date of Patent: August 20, 1991Assignee: The British Petroleum Company, p.l.c.Inventor: Timothy E. Fletcher
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Patent number: 5023016Abstract: A concentrate composition is disclosed which comprises (a) a blend of (i) a metal sulfonate and (ii) an alkali or alkaline earth metal or zinc salt of a carboxylic acid and (b) a carrier. The composition is useful as a rust- and corrosion-inhibitor in a petroleum or synthetic base medium and is capable of maintaining metal sulfonate content at temperatures greater than 150.degree. C., e.g., 200.degree. C., for 20 hours.Type: GrantFiled: November 22, 1989Date of Patent: June 11, 1991Assignee: King Industries, Inc.Inventors: Lawrence V. Gallacher, Alfen J. Gustavsen, Robert L. Kugel
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Patent number: 5019343Abstract: This invention relates to a method for preventing corrosion and inhibiting the formation of scale deposition in aqueous systems. More specifically, it relates to using certain calcium insensitive phosphonomethyl amine compounds having the formula: ##STR1## wherein either R.sub.1 is selected from hydrogen, hydrocarbyl, hydroxy-substituted hydrocarbyl, alkoxy-substituted hydrocarbyl; and R.sub.2 is selected from hydrocarbyl, hydroxy-substituted hydrocarbyl, alkoxy-substituted hydrocarbyl, carboxyl-substituted hydrocarbyl, --CH.sub.2 PO.sub.3 H.sub.2, and --C.sub.2 H.sub.4 N(CH.sub.2 PO.sub.3 H.sub.2).sub.2 ; or R.sub.1 and R.sub.2 together form an alicyclic ring having 3 to 5 carbon atoms, optionally along with oxygen atoms, phosphorus atoms or both oxygen and phosphorus atoms in the ring, and water soluble salts thereof.Type: GrantFiled: December 15, 1989Date of Patent: May 28, 1991Assignee: W. R. Grace & Co.-Conn.Inventors: Chih M. Hwa, John A. Kelly, Janet Neton, Patricia M. Scanlon, Roger R. Gaudette
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Patent number: 5015409Abstract: Aqueous-based functional products or corrosive products such as cleansers, household products, commercial products, and personal care products are thickened or viscosity-modified by the addition of at least a small, but effective, amount of at least one crystalline mixed metal hydroxide conforming substantially to the formulaLi.sub.m D.sub.d T(OH).sub.(m+2d+3+n.a) A.sub.a.sup.n.xH.sub.2 Owhere m is zero to one, D is a divalent metal, d is from zero to 4, T is a trivalent metal, A represents at least one anion or negative-valence radial of valence n, where n is 1 or more, (m+2d+3+n.a) is equal to or greater than 3, (m+d) is greater than zero, and xH.sub.2 O represents excess waters of hydration.Type: GrantFiled: March 11, 1988Date of Patent: May 14, 1991Assignee: The Dow Chemical CompanyInventors: Arthur E. Read, Jr., John L. Burba, III, Peter A. Doty, Clarence R. Crabb
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Patent number: 5006588Abstract: A corrosion and crack growth inhibitor and method of making are disclosed, the inhibitor being relatively non-toxic as well as unreactive with elastomeric material so as to form a coating and sealing composition for application to metal surfaces.Type: GrantFiled: June 30, 1989Date of Patent: April 9, 1991Assignee: Lockheed CorporationInventor: Robert N. Miller
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Patent number: 5000916Abstract: Directed to a new molybdenum carboxylic compound and the use thereof as a corrosion inhibitor of steel and other metals particularly in cooling water.Type: GrantFiled: July 17, 1989Date of Patent: March 19, 1991Assignee: Amax Inc.Inventors: Mark S. Vukasovich, Roger F. Sebenik
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Patent number: 4992209Abstract: The method of adding to a nitrite corrosion inhibitor composition an effective amount of a bromosulfamate which is stable with respect to the nitrite corrosion inhibitor and provides an effective biocide, bactericide and fungicide. The composition using this bromosulfamate component to nitrite is utilized at about 0.1 to 10 ppm (residual) with an optimum of about 0.2 ppm of bromosulfamate. The bromosulfamate composition comprises reacting together sodium bromide (NaBr), sodium hypochlorite (NaOCl) or chlorine, and sodium sulfamate (NaSO.sub.3 NH.sub.2) or sulfamic acid, and using the product "fresh" in treating the nitrite solution.Type: GrantFiled: October 26, 1989Date of Patent: February 12, 1991Assignee: Nalco Chemical CompanyInventors: Eugene B. Smyk, Chris R. Smyrniotis, Christopher L. Wiatr
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Patent number: 4990592Abstract: An anionic emulsifier obtained from the reaction products of an alkyl phenol, polyamine, and formaldehyde or of an alkyl phenol, fatty acid/polyamine condensate, and formaldehyde followed by the reaction of such products with acrylic acid, and the uses of the emulsifier in anionic bituminous emulsions and paving slurry seal mixtures are disclosed.Type: GrantFiled: November 27, 1989Date of Patent: February 5, 1991Assignee: Westvaco CorporationInventor: Peter Schilling
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Patent number: 4990591Abstract: An anionic emulsifier obtained from the reaction products of an alkyl phenol, polyamine, and formaldehyde or of an alkyl phenol, fatty acid/polyamine condensate, and formaldehyde followed by the reaction of such products with acrylic acid, and the uses of the emulsifier in anionic bituminous emulsions and paving slurry seal mixtures are disclosed.Type: GrantFiled: April 7, 1989Date of Patent: February 5, 1991Assignee: Westvaco CorporationInventor: Peter Schilling
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Patent number: 4990590Abstract: An anionic emulsifier obtained from the reaction products of an alkyl phenol, polyamine, and formaldehyde or of an alkyl phenol, fatty acid/polyamine condensate, and formaldehyde followed by the reaction of such products with acrylic acid, and the uses of the emulsifier in anionic bituminous emulsions and paving slurry seal mixtures are disclosed.Type: GrantFiled: November 27, 1989Date of Patent: February 5, 1991Assignee: Westvaco CorporationInventor: Peter Schilling
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Patent number: 4983321Abstract: A corrosion-preventing soyabean-glycerol alkyd resin is preprared by combng soyabean oil and glycerol in a reaction kettle, and after heating to about 400.degree. F., fused litharge is loaded. The temperature is then increased to about 440.degree. F. and held until a clear solution is formed. Phthalic anhydride is then loaded and heat gained cautiously to about 450.degree. F. Butylphenol resin is loaded. Then China wood oil is loaded. A first carbon dioxide blow is commenced. Then a second carbon dioxide blow is initiated. The mixture is then cooled to about 425.degree. F. and held. The mixture is dropped into xylene and thinned with Varnish Makers' and Painter's Naptha (petroleum thinner) prior to use with the barium metaborate corrosion preventer compound of this invention which was developed to replace chromium which has reduced availability due to exportation restrictions from the major supplier country.Type: GrantFiled: June 5, 1989Date of Patent: January 8, 1991Assignee: The United States of America as represented by the Secretary of the ArmyInventor: David C. Sayles
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Patent number: 4971709Abstract: A method of inhibiting corrosion of ferrous metals by zinc-containing brines by mixing with the brine a particulate metal additive, the metal of the additive having a standard oxidation-reduction potential above 0.5 and below 2.5 volts, the metal additive being present in an amount sufficient to inhibit corrosion of the ferrous metals contacted by the brine.Type: GrantFiled: February 3, 1989Date of Patent: November 20, 1990Assignee: Baroid Technology, Inc.Inventors: William J. Tillis, John J. Augsburger
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Patent number: 4968231Abstract: In order to produce oil-free compressed air with a rotary compressor while avoiding the costs involved by a liquid-free compressor, a rotary compressor, especially a single screw rotary compressor is injected with water in which borate, preferably potassium borate is dissolved. This prevents corrosion at no additional cost while improving the bacterial purity of the air produced.Type: GrantFiled: February 17, 1989Date of Patent: November 6, 1990Assignee: Bernard ZimmernInventors: Bernard Zimmern, Ernest Kallmann
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Patent number: 4963290Abstract: This invention relates to corrosion inhibitors of steels, particularly carbon steels or low-alloy steels. They are ternary mixtures with synergetic action containing at least one strong base, at least one molybdate and at least one phosphate. This invention also relates to aqueous compositions of alkali metal halide containing said inhibitors. Such compositions are advantageously used as working fluid in high temperature absorption heat pump systems.Type: GrantFiled: February 13, 1989Date of Patent: October 16, 1990Assignee: Gaz de France (Service National)Inventors: Joelle Bressan, Jacques Mezon
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Patent number: 4946502Abstract: A coating composition is disclosed for protecting from corrosion and oxidation in the hot condition carrier bars of pre-baked anodes and the emergent carbonaceous part of the anodes for the protection of aluminum in the Hall-Heroult process. The composition consists essentially of dry matter formed by calcium alumnate cement having an alumina content of at least 70% and a low content of impurities, magnesium spinel, and optionally, further alumina, together with water in the amount of 10 to 80% by weight of the total dry matter.Type: GrantFiled: October 25, 1989Date of Patent: August 7, 1990Assignee: Societe des Electrodes & Refractaires SavoieInventors: Gabriel Audras, Bernard Samanos
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Patent number: 4944917Abstract: Disclosed is a method for inhibiting corrosion of metal surfaces in contact with H.sub.2 S-containing acid gases streams and aqueous amine scrubbing solutions, which method comprises: contacting the H.sub.2 S-containing stream with amine scrubbing solution in the presence of an effective amount of an ammonium or alkali-metal thiosulfate salt and an effective amount of sulfide and/or hydrosulfide ions.Type: GrantFiled: December 28, 1987Date of Patent: July 31, 1990Assignee: Exxon Research and Engineering CompanyInventors: Patrick C. Madden, II, Z. Andrew Foroulis
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Patent number: 4933101Abstract: Disclosed are liquid automatic dishwashing detergent compositions containing an insoluble inorganic zinc salt useful for inhibition of glassware corrosion in the dishwasher. These compositions are particularly desirable because use of them in the dishwasher does not result in precipitation of insolubles on the dishware or dishwasher parts.Type: GrantFiled: February 13, 1989Date of Patent: June 12, 1990Assignee: The Procter & Gamble CompanyInventors: William A. Cilley, Rodney M. Wise
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Patent number: 4926449Abstract: A potassium inhibitive blend and corrosion protection method for closed cooling water systems. The closed cooling system circulates about 35 to 40 gallons of corrosion inhibitor per 10,000 gallons of circulating water. The corrosion inhibitor contains potassium molybdate, potassium nitrite, and potassium borate in an aqueous solution so that if leakage of the circulated water occurs, the leaked corrosion inhibitive liquid does not cause dangerous radiation in any amounts dangerous to the environment. The potassium molybdate and potassium nitrate each constitute about 12% of the aqueous solution. Potassium based borate at 2 to 2.5%, ethylene glycol preferably at about 10%, and benzotriazole or tolyltriazole of about 0.4% with up to 1% polymeric scale suppressant are also included in the corrosion inhibitive blend.Type: GrantFiled: February 22, 1988Date of Patent: May 15, 1990Inventor: Paul A. Burda