Phosphorus Containing Patents (Class 252/389.2)
  • Patent number: 10953434
    Abstract: The present invention relates to a method for producing a multilayer coating on a metallic substrate, comprising, in the given order, (1) producing a polyvinyl chloride plastisol layer on the metallic substrate, comprising the application of a polyvinyl chloride plastisol material to the metallic substrate, (2) producing a thermosetting and/or thermoplastic topcoat layer directly on the polyvinyl chloride plastisol layer, comprising the application of a thermosetting and/or thermoplastic coating material directly to the polyvinyl chloride plastisol layer, wherein both the polyvinyl chloride plastisol material and the thermosetting and/or thermoplastic coating material comprise a layered double hydroxide.
    Type: Grant
    Filed: January 28, 2016
    Date of Patent: March 23, 2021
    Assignee: AKZO NOBEL COATINGS INTERNATIONAL B.V.
    Inventors: Rafael Bautista Mester, Paul Davies, Stephen Corkish, Stephen Birch
  • Patent number: 10072191
    Abstract: A de/anti-icer composition comprises one or more de/anti-icer moieties and a marker material, the marker material being selected such that, after application of the de/anti-icer composition to a traveled surface, the amount of the marker material at or on the traveled surface at a given time correlates to the amount of said one or more de/anti-icer moieties on the said surface at such time. The presence of the marker material enables the user readily to determine the concentration of the de/anti-icer moiety or the freezing point of liquid on the traveled surface. Methods of using such compositions for concentration and/or freezing point determination of de/anti-icer materials applied to traveled surfaces are described, together with systems and kits of parts utilizing such compositions.
    Type: Grant
    Filed: June 24, 2013
    Date of Patent: September 11, 2018
    Assignee: ESSECO UK LIMITED
    Inventor: Alistair McConnell
  • Patent number: 9985316
    Abstract: Described herein are additives for use in electrolytes that provide a number of desirable characteristics when implemented within batteries, such as high capacity retention during battery cycling at high temperatures. In some embodiments, a high temperature electrolyte includes a base electrolyte and one or more polymer additives, which impart these desirable performance characteristics. The polymer additives can be homopolymers or copolymers.
    Type: Grant
    Filed: February 24, 2017
    Date of Patent: May 29, 2018
    Assignee: WILDCAT DISCOVERY TECHNOLOGIES, INC
    Inventors: Gang Cheng, Jinhua Huang, Ye Zhu
  • Patent number: 9885003
    Abstract: The invention relates to thiophosphates and derivatives thereof useful as antiwear additive components, lubricant additive compositions and lubricant compositions each comprising such compounds, methods for making and using the same, including methods of lubricating machines and machine parts and methods of extending the useful life of elastomeric seal components of such machines.
    Type: Grant
    Filed: October 10, 2016
    Date of Patent: February 6, 2018
    Assignee: Afton Chemical Corporation
    Inventors: David Edwards, Kristine Durbin, Robert E. McCovick
  • Patent number: 9657398
    Abstract: Compositions for inhibiting the corrosion of metals in contact with an aqueous system are provided. The corrosion inhibiting compositions may be used to maintain effective amounts of (1) an amino acid-based polymer, such as a polyaspartic acid compound, and (2) a dispersible and/or soluble tin compound in the aqueous system. The corrosion inhibiting compositions include the amino acid-based polymer and a dispersible and/or soluble tin compound and may optionally include a polycarboxylic acid chelating agent and/or a carboxylate/sulfonate functional copolymer.
    Type: Grant
    Filed: June 23, 2015
    Date of Patent: May 23, 2017
    Assignee: U.S. Water Services Inc.
    Inventors: Donovan L. Erickson, Roy A. Johnson, Matthew Ryan LaBrosse, Paul R. Young
  • Patent number: 9518242
    Abstract: The invention relates to thiophosphates and derivatives thereof useful as antiwear additive components, lubricant additive compositions and lubricant compositions each comprising such compounds, methods for making and using the same, including methods of lubricating machines and machine parts and methods of extending the useful life of elastomeric seal components of such machines. In one aspect, the invention relates to a lubricant additive composition comprising a compound of formula (I): or a tribologically acceptable salt thereof, and a sulfonate or a phenate detergent.
    Type: Grant
    Filed: May 24, 2016
    Date of Patent: December 13, 2016
    Assignee: Afton Chemical Corporation
    Inventors: David Edwards, Kristine Durbin, Robert E. McCovick
  • Patent number: 9481696
    Abstract: The present invention provides thiophosphates and thiophosphate derivatives useful as antiwear additive components, lubricant additive compositions and lubricant compositions each comprising such compounds, and methods for making and using the same. In one aspect, the invention relates to a compound of formula (I): or a tribologically acceptable salt thereof.
    Type: Grant
    Filed: August 19, 2015
    Date of Patent: November 1, 2016
    Assignee: Afton Chemical Corporation
    Inventors: David Edwards, Kristine Durbin, Robert E. McCovick
  • Patent number: 9115302
    Abstract: It has been found that the chemical reactivity of the metal surface of heat exchangers with coolants in presence of nitrites can be reduced by the addition of additives such as phosphonates or phosphinates. Aluminum, other Group III metals, as well as other metals commonly used in cooling systems, such as those of automobile engines, may thus be effectively protected.
    Type: Grant
    Filed: September 5, 2012
    Date of Patent: August 25, 2015
    Assignee: Chevron U.S.A. Inc.
    Inventors: Sandra G. Claeys, Serge S. Lievens
  • Patent number: 8845930
    Abstract: The invention provides a method for pre-treating a metal surface with a corrosion inhibitor prior to painting, a method for inhibiting corrosion in a cooling system, wherein the cooling system includes a metal surface and a coolant; and a method for inhibiting corrosion of a reinforcement steel in concrete wherein the method comprising the step of adding to a concrete mixture an anti-corrosive mixture.
    Type: Grant
    Filed: November 28, 2005
    Date of Patent: September 30, 2014
    Assignee: Pigmentan Ltd.
    Inventors: Gregory Pipko, Zvi Miller
  • Patent number: 8758876
    Abstract: A coating which provides corrosion resistance, wear resistance, and, optionally, lubrication, for deposition on a threaded article is disclosed. The coating comprises a polymer matrix, such as a polyimide, which is modified with small amounts of a fluorine containing polymer modifier, as well as other compounds or additives to improve performance of the coating. Additionally, the coating can further comprise a solid lubricant or an anticorrosion compound dispersed within the polymer matrix.
    Type: Grant
    Filed: October 30, 2012
    Date of Patent: June 24, 2014
    Assignee: Tenaris Connections Limited
    Inventors: Gabriel Eduardo Carcagno, Klaus Endres
  • Patent number: 8637158
    Abstract: The present invention relates to a polymerizable composition and to a method for coating metal surfaces, in particular steel, galvanized and alloy-galvanized steel, and also aluminum and alloys thereof, as protection against corrosion. The polymerizable composition preferably contains less than 10% by weight of portions which are not incorporated in the cured coating. In a further aspect, the invention relates to the use of the claimed composition for coating workpieces consisting of the above-mentioned metals, particularly metal surfaces in blanking lines (coil coating). The present invention therefore also comprises the use of metal surfaces, coated according to the invention, for the production of “white goods” (household appliances), automobile bodies, electronic component housings, and for the building trade and the transport sector.
    Type: Grant
    Filed: September 23, 2009
    Date of Patent: January 28, 2014
    Assignee: Henkel AG & Co. KGaA
    Inventors: Jörg Sander, Jürgen Stodt, Holger Endres
  • Patent number: 8628689
    Abstract: The invention relates to a low temperature-curable coating composition comprising a film-forming resin, a curing agent for the film-forming resin, and a lithium salt.
    Type: Grant
    Filed: April 2, 2010
    Date of Patent: January 14, 2014
    Assignee: Akzo Nobel Coatings International B.V.
    Inventors: Peter Visser, Scott Alan Hayes
  • Publication number: 20130234070
    Abstract: Epoxy-polysiloxane based coating and flooring compositions exhibiting improved flexibility, and excellent weatherability and corrosion resistance after curing are described. The epoxy-polysiloxane polymer coating composition may be prepared by combining a polysiloxane, an epoxide resin material and a cure system including a blend of compounds selected from a dialkoxy functional aminosilane, a trialkoxy functional aminosilane, and an amino functional polysiloxane resin, where the blend has an average alkoxy functionality value of 2.0 to 2.8.
    Type: Application
    Filed: March 12, 2013
    Publication date: September 12, 2013
    Applicant: PPG Industries Ohio, Inc.
    Inventor: Norman R. Mowrer
  • Patent number: 8491713
    Abstract: Described is a new a solution comprising a phosphorous compound and optionally a solderability-enhancing compound and its use in a process for increasing the solderability and corrosion resistance of a metal or metal alloy surface.
    Type: Grant
    Filed: January 13, 2010
    Date of Patent: July 23, 2013
    Assignee: Atotech Deutschland GmbH
    Inventors: Jürgen Barthelmes, Robert Ruether, Olaf Kurtz, Jana Breitfelder
  • Publication number: 20130142977
    Abstract: The present invention includes compositions and methods of supplying a corrosion inhibitor including placing a corrosion inhibitor attached to a nanostructure carrier, placing the nanostructure carrier containing the corrosion inhibitor at a location and the nanostructure carrier is capable of releasing the corrosion inhibitor.
    Type: Application
    Filed: January 28, 2013
    Publication date: June 6, 2013
    Applicant: NATIONAL OILWELL VARCO, L.P.
    Inventor: NATIONAL OILWELL VARCO, L.P.
  • Patent number: 8409478
    Abstract: The invention relates to a flame retardant composition, particularly designed for fire fighting with aerial means. The retardant composition comprises a liquid ammonium polyphosphate of chain length with a value of n between 2 and 3, n being the number of condensation groups, and an ammonium polyphosphate in powder form in suspension, with a chain length with a value of n between 100 and 1500. In addition to the above, the flame retardant composition comprises corrosion inhibitors, in particular zinc orthophosphate dihydrate, and at least one surfactant agent as wetting agent or dispensing agent, an organic or inorganic thickening agent and at least one coloring agent.
    Type: Grant
    Filed: May 20, 2008
    Date of Patent: April 2, 2013
    Assignee: Budenheim Iberica, S.L. Sociedad En Comandita
    Inventors: Vicente Mans Fibla, David Garcia Martinez
  • Patent number: 8404181
    Abstract: The present invention relates to a method of preventing or alleviating the problems associated with corrosion and to novel formulations for use in such a method.
    Type: Grant
    Filed: November 9, 2006
    Date of Patent: March 26, 2013
    Assignee: Rhodia UK Limited
    Inventors: Chris Jones, Julie Hardy
  • Patent number: 8337606
    Abstract: Described is a new a solution comprising a phosphorous compound and a solderability-enhancing compound and its use in a process for increasing the solderability and corrosion resistance of a metal or metal alloy surface.
    Type: Grant
    Filed: July 10, 2008
    Date of Patent: December 25, 2012
    Assignee: Atotech Deutschland GmbH
    Inventor: Peter Kuhlkamp
  • Patent number: 8322754
    Abstract: Coating systems which provide corrosion resistance and, optionally, lubrication, for threaded connections are disclosed. The compositions comprise a first coating composition comprising polymer matrices of polyimides or epoxies which are modified with small amounts of a fluorine containing polymer. Also present in the coating compositions are corrosion inhibiting agents and inorganic particles having a mean diameter of between approximately 10 nm and 10 ?m. Solid lubricants, which may include at least one of PTFE, HDPE, Graphite, and MoS2, are optionally added to provide the first coating with a low coefficient of friction. The coating systems may further comprise a second coating composition, comprising a solid lubricant dispersed within an epoxy resin and a solvent. The first and second coating compositions are deposited on at least a portion of at least one of the pin and box members of the threaded connections.
    Type: Grant
    Filed: August 28, 2007
    Date of Patent: December 4, 2012
    Assignee: Tenaris Connections Limited
    Inventors: Gabriel Eduardo Carcagno, Klaus Endres
  • Patent number: 8303850
    Abstract: A rust preventive oil composition includes at least one base oil selected from the group consisting of mineral oils and synthetic oils, having a 5%-distillation temperature of not less than 140° C. and not more than 250° C., a 95%-distillation temperature of 250° C. or less, a difference between the 5%-distillation temperature and the 95%-distillation temperature of 90° C. or less, an aromatic content of 5% by volume or less, a naphthene content of not less than 30% by volume and not more than 95% by volume, a density at 15° C. of 0.75 g/cm3 or more, and a kinematic viscosity at 40° C. of not less than 0.3 mm2/s and not more than 5.0 mm2/s; at least one base oil selected from the group consisting of mineral oils and synthetic oils; and a rust-preventing additive.
    Type: Grant
    Filed: July 14, 2010
    Date of Patent: November 6, 2012
    Assignee: JX Nippon Oil & Energy Corporation
    Inventors: Junichi Shibata, Tadaaki Motoyama, Kazuhiko Endou
  • Patent number: 8287764
    Abstract: The invention relates to coated particles comprising a core material and a shell and wherein said core material is an organic compound and wherein said shell comprises a layered double hydroxide comprising a hydroxide or an organic anion as charge-balancing anion.
    Type: Grant
    Filed: July 20, 2009
    Date of Patent: October 16, 2012
    Assignee: Akzo Nobel N.V.
    Inventors: Cornelis Elizabeth Johannus Van Lare, Auke Gerardus Talma, Hendrika Petronella Maria Verlaan-Hooft
  • Patent number: 8202449
    Abstract: A fire-retardant composition comprising an ammonium polyphosphate, a suspending agent and an effective amount of a corrosion inhibiting agent. When in solution the corrosion inhibiting agent includes at least one ion selected from the group of ions consisting of aluminum ions, ferric ions, calcium ions and magnesium ions. Said ions complex an effective amount of fluoride ions present in the fire-retardant composition to reduce the corrosiveness of the fire-retardant composition.
    Type: Grant
    Filed: October 31, 2006
    Date of Patent: June 19, 2012
    Assignee: ICL Performance Products, LP
    Inventors: Andrew Garner, Neville James Stead
  • Publication number: 20120094130
    Abstract: Anticorrosive coating compositions comprise a binding polymer and an amorphous aluminum phosphate corrosion inhibiting pigment. The composition comprises from about 1 to 25 percent by weight amorphous aluminum phosphate. The amorphous aluminum phosphate has a water adsorption potential of up to about 25 percent by weight water. The composition provides a controlled phosphate delivery of from about 50 to 500 ppm, and preferably of from about 100 to 200 ppm. The composition has a total solubles content of less than about 1,500 ppm. The amorphous aluminum phosphate is preferably substantially free of alkali metals. The amorphous aluminum phosphate is made by combining aluminum hydroxide with phosphoric acid and sodium aluminate. The amorphous aluminum phosphate is treated to reduce the level of unwanted solubles, and the treated amorphous aluminum phosphate is dried at less than about 300° C. The composition is used as a primer coat, a mid-coat, and/or a top-coat coating.
    Type: Application
    Filed: October 15, 2010
    Publication date: April 19, 2012
    Applicants: UNIVERSIDADE ESTADUAL DE CAMPINAS, BUNGE FERTILIZANTES S.A.
    Inventors: Raymond E. Foscante, Fernando Galembeck, Melissa Braga
  • Publication number: 20120094128
    Abstract: Anticorrosive coating compositions comprise a binding polymer and an amorphous aluminum phosphate corrosion inhibiting pigment dispersed therein. The coating composition comprises 1 to 25 percent by weight aluminum phosphate. The binding polymer can include solvent-borne polymers, water-borne polymers, solventless polymers, and combinations thereof. The aluminum phosphate is made by combining an aluminum source with a phosphorous source to form an amorphous aluminum phosphate solid condensate. The coating composition is specially engineered to provide a controlled delivery of phosphate anions of 50 to 500 ppm, and has a total solubles content of less than 1500 ppm. The amorphous aluminum phosphate is preferably free of alkali metals and alkaline earth metals. The amorphous aluminum phosphate has an oil absorption of less than 50, and a surface area of less than about 20 m2/g, The coating composition has a water adsorption potential of up to 25% by weight water.
    Type: Application
    Filed: October 15, 2010
    Publication date: April 19, 2012
    Applicant: BUNGE LIMITED CORPORATION
    Inventor: Raymond E. Foscante
  • Publication number: 20120091397
    Abstract: Anticorrosive coating compositions as disclosed comprise a binding polymer and an aluminum phosphate corrosion inhibiting pigment dispersed therein. The coating composition comprises up to 25 percent by weight aluminum phosphate. The binding polymer can include solvent-borne polymers, water-borne polymers, solventless polymers, and combinations thereof. The aluminum phosphate is made by sol gel process of combining an aluminum salt with phosphoric acid and a base material. Aluminum phosphate colloidal particles are nanometer sized, and aggregate to form substantially spherical particles. The coating composition provides a controlled delivery of phosphate anions of 100 to 1,500 ppm, depending on post-formation treatment of the aluminum phosphate, and has a total solubles content of less than 1500 ppm, The amorphous aluminum phosphate is free of alkali metals and alkaline earth metals, and has a water adsorption potential of up to about 25 percent by weight water when present in a cured film.
    Type: Application
    Filed: October 15, 2010
    Publication date: April 19, 2012
    Applicant: BUNGE LIMITED CORPORATION
    Inventor: Raymond E. Foscante
  • Publication number: 20120088704
    Abstract: The present invention is a lubricant or functional fluid additive for a polyolefin oil blend, comprising a mixture of: (a) an anti-wear component consisting essentially of 95% isopropylated triarylphosphate and 5% dodecyl phosphate, the dodecyl phosphate being only partially esterified, the anti-wear component present in the polyolefin oil blend in a range of from about 0.75 percent to about 2.00 percent by weight; (b) an antioxidant component selected from the group consisting of alkylated phenyl-alpha-naphthylamine, phenyl-alpha-naphthylamine and mixtures thereof, and present in the polyolefin oil blend in a range of from about 0.75 percent to about 2.00 percent by weight; (c) an anti-rust component comprising an alkylated succinic acid ester anti-rust agent, and present in the polyolefin oil blend in a range of from about 0.050 percent to about 0.
    Type: Application
    Filed: October 8, 2010
    Publication date: April 12, 2012
    Inventor: William F. Ricks
  • Patent number: 8057642
    Abstract: This invention relates to a process for reducing the corrosion rate of iron-containing vessels within an ethylene glycol distillation system. The inventive process includes the addition of an additive component of sodium nitrite and sodium hypophosphite into such iron-containing vessels, to thereby react with iron of the inside walls and form a protective coating thereon. This process reduces the corrosion rate in iron-containing vessels of the apparatus, and reduces the catalytic effects of iron corrosion products within the system. Thus, not only is the on-stream time of the vessels extended, but also product quality is improved by reducing the aldehyde content of the final ethylene glycol product.
    Type: Grant
    Filed: August 3, 2010
    Date of Patent: November 15, 2011
    Assignee: SD Lizenzverwertungsgesellschaft mbH & Co. KG
    Inventors: Barry Billig, James Mann
  • Patent number: 8043531
    Abstract: The invention provides a surface conditioner which can prevent an aluminum alloy from stray current corrosion in chemical conversion treatment and reduce the difference between contact and noncontact areas in conversion coating build-up on an aluminum alloy and which enables the formation of excellent chemical conversion coatings on various metal materials and a surface conditioner which can prevent metal from rusting after surface conditioning and is excellent in dispersion stability in a treating bath. A surface conditioner to be applied prior to the phosphating of metal which contains (A) zinc phosphate particles having D50 of 3 ?m or below, (B) a water-soluble organic polymer, and (C) a layer clay mineral and has a pH of 3 to 12, characterized by further containing as the function imparting agent (D) a di- or tri-valent metal nitrite, zinc oxide and/or sodium hydroxide, or a nonionic or anionic surfactant.
    Type: Grant
    Filed: July 28, 2006
    Date of Patent: October 25, 2011
    Assignee: Nippon Paint Co., Ltd.
    Inventors: Toshiko Nakazawa, Seiichiro Shirahata
  • Patent number: 8003013
    Abstract: A waterborne thermoset cured anticorrosion formulation includes a water dispersed or emulsified phosphonated or water dispersed or emulsified sulfonated epoxy resin that is cured with a phenoxy resin having a polyhydroxyl ether backbone and terminal alpha glycol moieties. Water is present as a predominant volatile in which the epoxy resin and phenoxy resin are present in a weight ratio of epoxy resin to phenoxy resin of between 0.1 and 3:1. An aqueous curative is provided to induce cure between the epoxy resin and phenoxy resin, A corrosion inhibiting metal salt is also present having a salt anion of phosphate, biphosphate or tetraborate and a metal cation with the proviso that the metal cation formulation as a whole is devoid of chromium, lead, cobalt, and cadmium. Ideal curatives include aqueous aminoplast crosslinkers, aqueous unblocked isocyanates, aqueous blocked isocyanates, and a mixture thereof.
    Type: Grant
    Filed: September 18, 2008
    Date of Patent: August 23, 2011
    Assignee: Martinrea Industries, Inc.
    Inventors: Ronald J. Lewarchik, Scott Rier
  • Publication number: 20110189481
    Abstract: The present invention relates to aqueous post-treatment compositions and an immersion and/or electrolytical process using said compositions for corrosion protection of metal and/or metal alloy surfaces. The aqueous post-treatment compositions comprise at least one polysiloxane betaine compound and at least one phosphorus containing compound.
    Type: Application
    Filed: October 21, 2009
    Publication date: August 4, 2011
    Inventors: Jürgen Barthelmes, Michael Danker, Olaf Kurtz, Florence Lagorce-Broc, Robert Rüther
  • Publication number: 20110165330
    Abstract: A coating composition comprising: (i) at least one polyepoxide; (ii) at least one polyvinyl butyral resin; (iii)a corrosion inhibiting amount of cerium molybdate; (v) phosphoric acid; (v) a water miscible organic solvent ; and (vii) water; wherein the coating composition is free of hexavalent chromium.
    Type: Application
    Filed: January 5, 2011
    Publication date: July 7, 2011
    Applicant: The Sherwin-Williams Company
    Inventors: Keith A. Rawlins, Wai-Kwong Ho, Joseph K. Walker, Charles H. Simpson, Frank K. Bonney
  • Publication number: 20110133128
    Abstract: The invention relates to coated particles comprising a core material and a shell and wherein said core material is an organic compound and wherein said shell comprises a layered double hydroxide comprising a hydroxide or an organic anion as charge-balancing anion.
    Type: Application
    Filed: July 20, 2009
    Publication date: June 9, 2011
    Applicant: Akzo Nobel N.V.
    Inventors: Cornelis Elizabeth Johannus Van Lare, Auke Gerardus Talma, Hendrika Petronella Maria Verlaan-Hooft
  • Publication number: 20110124738
    Abstract: The present invention relates to a chromate-free composition, to the use thereof for corrosion protection, and to a corrosion protection coating for the inside surfaces of fuel tanks, wherein the composition comprises binding agents, hardening agents, corrosion inhibitors and quaternary ammonium compounds in a quantity of at least 0.1% by weight.
    Type: Application
    Filed: January 15, 2009
    Publication date: May 26, 2011
    Inventors: Sven Schroeder, Diana Becker, Jan Kuever, Andreas Rabenstein, Martin Kaune, Yvonne Wilke, Matthias Geistbeck, Carmen Gerlach, Ottmar Schramm, Tanja Pietzker
  • Patent number: 7935274
    Abstract: Compositions for preparing coatings on metal substrates include a phosphonic acid, polyvinyl alcohol, an optional catalyst, and optionally an organo-functional silane. The catalyst may be a group IV-B compound, a boron compound, a vanadium compound, or a molybdenum compound. The compositions may be applied from an aqueous carrier to a metal surface and then dried to form a coating imparting good paint adhesion and corrosion resistance to the metal substrate.
    Type: Grant
    Filed: March 25, 2005
    Date of Patent: May 3, 2011
    Assignee: Bulk Chemicals, Inc.
    Inventor: Ted M. Schlosser
  • Publication number: 20110012065
    Abstract: A method for manufacturing a polyaniline by preparing an aniline mixed solution in which an antirust additive and at least one of aniline and aniline derivatives are mixed and polymerizing at least one of the aniline and the aniline derivatives by adding a polymerization initiator to the aniline mixed solution, polyaniline obtained by the method, a polyaniline-containing solution, and a coating material containing the polyaniline.
    Type: Application
    Filed: September 26, 2008
    Publication date: January 20, 2011
    Applicant: TOYOTA JIDOSHA KABUSHIKI KAISHA
    Inventors: Noriyuki Kuramoto, Shigeyoshi Maeda, Yu Takada, Masahiko Ishii
  • Patent number: 7820076
    Abstract: The invention relates to an oleaginous mildew and corrosion-inhibiting composition, and the use of said composition to protect metal from corrosion and mildew. The composition comprises, in parts by weight, from about 20 to 60 parts of an oleaginous material such as a lubricating oil, 10 to 40 parts of organic solvent, 20 to 60 parts of corrosion-inhibitor consisting of a sulfonic acid-carboxylic acid metal complex or a mixture of said metal complex with a small but effective amount of an oil soluble alkyl phosphate, from 0.1 to 2.0 parts of an oil soluble antioxidant, from 0.0 to 5.0 parts of a water-displacing compound, an effective amount of a mildew-inhibiting compound, and from 0.0 to 1.0 part of a heterocyclic metal deactivator.
    Type: Grant
    Filed: December 20, 2005
    Date of Patent: October 26, 2010
    Assignee: The United States of America as represented by the Secretary of the Navy
    Inventors: El Sayed S. Arafat, Craig A. Matzdorf, James A. Whitfield
  • Patent number: 7811670
    Abstract: Coating compositions are disclosed that include corrosion resisting particles such that the coating composition can exhibit corrosion resistance properties. Also disclosed are substrates at least partially coated with a coating deposited from such a composition and multi-component composite coatings, wherein at least one coating later is deposited from such a coating composition. Methods and apparatus for making ultrafine solid particles are also disclosed.
    Type: Grant
    Filed: August 13, 2007
    Date of Patent: October 12, 2010
    Assignee: PPG Industries Ohio, Inc.
    Inventors: Kaliappa G. Ragunathan, John R. Schneider
  • Publication number: 20100233471
    Abstract: The anti-corrosion coating material contains corrosion inhibiting inorganic constituents, or a combination of inorganic and organic corrosion inhibiting constituents, suspended in a polymeric resin. The corrosion resistant composition includes a salt of inorganic constituents, and alkaline polyamine fatty acid salt (PFAS) as a corrosion inhibitor, suspended in a polymeric resin remainder. The coating material may be applied to metal parts but not limited to aircraft fasteners, such as aircraft fastener parts, including nuts and bolts, screws, rivets, and sleeved systems.
    Type: Application
    Filed: August 5, 2009
    Publication date: September 16, 2010
    Inventors: Jeffrey Hayes, Johan Stephan
  • Patent number: 7776233
    Abstract: The invention relates to an oleaginous corrosion-inhibiting composition, and the use of said composition to protect metal from corrosion. The composition comprises, in parts by weight, from about 20 to 60 parts of lubricating oil, 10 to 40 parts of organic solvent, 20 to 60 parts of corrosion-inhibitor consisting of a sulfonic acid-carboxylic acid metal complex or a mixture of said metal complex with a small but effective amount of an oil soluble alkyl phosphate, from 0.1 to 2.0 parts of an oil soluble antioxidant, from 0.1 to 5.0 parts of a water-displacing compound and from 0.0 to 1.0 part of a metal deactivator.
    Type: Grant
    Filed: October 27, 2005
    Date of Patent: August 17, 2010
    Assignee: The United States of America as represented by the Secretary of the Navy
    Inventors: El Sayed Arafat, Judy Butler-Kowalik, Kenneth Clark, David L. Gauntt
  • Patent number: 7767111
    Abstract: A surface conditioner contains zinc phosphate particles of D50 of 3 ?m or less and has a pH of 3 to 12, and also contains at least one of (1) carboxylate group-containing copolymers obtained by copolymerizing a monomer composition containing at least one species selected from acrylic acid, maleic acid, maleic anhydride, itaconic acid and itaconic anhydride in an amount less than 50% by weight and at least one species selected from the group consisting of a sulfonic acid monomer, styrene, olefin monomers, amino group-containing monomers and certain polyoxyalkylene derivatives, (2) certain polyamino acids, and (3) certain phosphate esters.
    Type: Grant
    Filed: February 18, 2005
    Date of Patent: August 3, 2010
    Assignee: Nippon Paint Co., Ltd.
    Inventor: Toshiko Nakazawa
  • Patent number: 7744775
    Abstract: In one embodiment, a corrosion inhibiting composition is formed by combining: (a) an inorganic phosphate; (b) a water soluble polyelectrolyte polymer dispersant; (c) a tri or tetracarboxylic acid; and (d) at least one additional component comprising at least one of a C4-C22 aliphatic or aromatic mono- or dicarboxylic acid, a silicate and at least one of a silicone or a silicate stabilizing siloxane compound, and mixtures thereof. Also disclosed are heat transfer fluids that include about 5% to about 99% by weight of freezing point-depressing agent; about 1% to about 95% by weight of water; and the disclosed corrosion inhibitor composition. A method of reducing corrosion in a heat transfer system containing one or more components that contain magnesium or a magnesium alloy requires that the system and the magnesium containing components be in contact with the disclosed heat transfer fluid.
    Type: Grant
    Filed: November 17, 2009
    Date of Patent: June 29, 2010
    Assignee: Honeywell International Inc.
    Inventors: Bo Yang, Filipe J. Marinho
  • Patent number: 7645331
    Abstract: In one embodiment, a corrosion inhibiting composition is formed by combining: (a) an inorganic phosphate; (b) a water soluble polyelectrolyte polymer dispersant; (c) a tri or tetracarboxylic acid; and (d) at least one additional component comprising at least one of a C4-C22 aliphatic or aromatic mono- or dicarboxylic acid, a silicate and at least one of a silicone or a silicate stabilizing siloxane compound, and mixtures thereof. Also disclosed are heat transfer fluids that include about 5% to about 99% by weight of freezing point-depressing agent; about 1% to about 95% by weight of water; and the disclosed corrosion inhibitor composition. A method of reducing corrosion in a heat transfer system containing one or more components that contain magnesium or a magnesium alloy requires that the system and the magnesium containing components be in contact with the disclosed heat transfer fluid.
    Type: Grant
    Filed: October 25, 2006
    Date of Patent: January 12, 2010
    Assignee: Honeywell International Inc.
    Inventors: Bo Yang, Filipe J. Marinho
  • Publication number: 20090170817
    Abstract: The present invention relates to a method of preventing or alleviating the problems associated with corrosion and to novel formulations for use in such a method.
    Type: Application
    Filed: November 9, 2006
    Publication date: July 2, 2009
    Applicant: Rhodia UK Limited
    Inventors: Chris Jones, Julie Hardy
  • Patent number: 7513948
    Abstract: Systems and methods for enhanced autogenous healing of cracks that are formed or are present in concrete-containing materials and surfaces are disclosed. Treatment modalities that include addition of the disclosed materials, compositions and systems to pre- and post-construction concrete-containing materials and surfaces are provided. Autogenous healing is effected at a greater rate and to a larger degree as compared to control systems. The disclosed compositions and systems also yield reductions in the rate and/or impact of corrosion are achieved for concrete-containing structures and surfaces and, despite the water soluble properties of the compositions and systems, the treatments are effective in delivering an advantageous level of moisture resistance to the treated concrete-containing structure and/or surface. The composition is synthesized from a feedstock that includes C9 to C16 branched hydrocarbons of varying structures.
    Type: Grant
    Filed: August 31, 2007
    Date of Patent: April 7, 2009
    Assignee: Hycrete, Inc.
    Inventors: Todd B Humphrey, legal representative, Philip S. Rhodes, legal representative, Philip S. Rhodes, James R. Humphrey, Leonid Izrailev, David Rosenberg, John Wojakowski, Jason Tuerack, Eugene B. Humphrey, Michael S. Rhodes
  • Patent number: 7513946
    Abstract: Chromium-free, low-zinc, corrosion-inhibiting pigment mixture (A) comprising (a1) 30% to 60% by weight of at least one calcium hydrogen phosphate pigment, (a2) 15% to 45% by weight of at least one amorphous, calcium-modified silicon dioxide, (a3) 5% to 25% by weight of at least one calcium borosilicate pigment, and (a4) 1% to 15% by weight of at least one zinc salt of an organic nitro compound with the proviso that the zinc content of (A) does not exceed 10% by weight; process for preparing it, and its use.
    Type: Grant
    Filed: July 26, 2006
    Date of Patent: April 7, 2009
    Assignee: BASF Coatings Aktiengesellschaft
    Inventors: Gisela Laumann, Ewald Philips, Andreas Vogt
  • Patent number: 7498090
    Abstract: A combination includes a composition providing corrosion resistance for application to a post-construction material, and a post-construction material, wherein the composition is applied to at least one surface of the post-construction material after the post-construction material has hardened. The composition may include an effective amount of a thinning agent, e.g., isopropyl alcohol, ethanol, xylene or similar composition. The composition may be an aqueous solution of a metal salt of a dioic acid. The post-construction material may be reinforced or unreinforced concrete. The post-construction material may be a concrete-containing structure, and the composition may be applied to an exterior surface thereof.
    Type: Grant
    Filed: August 21, 2007
    Date of Patent: March 3, 2009
    Assignee: Hycrete, Inc.
    Inventors: Philip S. Rhodes, David Rosenberg, John Wajakowski
  • Patent number: 7459102
    Abstract: A corrosion inhibitor that includes several oxo-anion compositions useful for preventing the propagation of pit corrosion on aluminum and aluminum alloys. The oxo-anion compositions may include soluble polymeric oxidic acids comprising combinations of molybdenum, phosphorous, tungsten, and silicon. These compositions are useful as corrosion inhibitors in high-moisture, corrosive environments, such as radiators and cooling systems. For low-moisture environments, these oxo-anion compositions can be reacted with a counter-ion, such as various metals, including, but not limited to the rear earth metals, to form a soluble salt. The salt can then be adsorbed onto a carrier, such as paint pigments, which can then be applied to the surfaces of aluminum and aluminum alloys. These surface adsorbates then become sparingly soluble and are gradually released over time in the presence of an aqueous corrosive agent so as to prevent propagation of pit corrosion.
    Type: Grant
    Filed: March 18, 2004
    Date of Patent: December 2, 2008
    Assignee: The Boeing Company
    Inventor: Martin W Kendig
  • Patent number: 7422793
    Abstract: Rinsing or sealing solutions comprising a rare earth element and a valence stabilizer for barrier films. The treated films contain a rare earth/valence stabilizer complex. The rare earth element is selected from cerium, praseodymium, terbium, or combinations thereof, and at least one rare earth element is in the tetravalent oxidation state. The rinsing or sealing solution may also contain an optional preparative or solubility control agent. The oxidized rare earth element is present in the coating in a “sparingly soluble” form. The valence stabilizers can be either inorganic or organic in nature. A number of rare earth/valence stabilizer combinations that match the performance of conventional hexavalent chromium systems are presented.
    Type: Grant
    Filed: July 23, 2003
    Date of Patent: September 9, 2008
    Assignee: University of Dayton
    Inventors: Andrew Wells Phelps, Jeffrey Allen Sturgill, Joseph Thomas Swartzbaugh
  • Patent number: 7407711
    Abstract: Conversion coatings comprising a rare earth element and a valence stabilizer combined to form a rare earth/valence stabilizer complex are described for substrate metals. The rare earth element is selected from cerium, praseodymium, terbium, or combinations thereof, and at least one rare earth element is in the tetravalent oxidation state. The coating bath may also contain a preparative or solubility control agent. The oxidized cerium, praseodymium or terbium is present in the coating in a “sparingly soluble” form. The valence stabilizers can be either inorganic or organic in nature. A number of cerium, praseodymium, or terbium/valence stabilizer combinations are presented that can equal the performance of conventional hexavalent chromium systems.
    Type: Grant
    Filed: July 23, 2003
    Date of Patent: August 5, 2008
    Assignee: University of Dayton
    Inventors: Andrew Wells Phelps, Jeffrey Allen Sturgill, Joseph Thomas Swartzbaugh
  • Patent number: RE42384
    Abstract: Water soluble materials, compositions and systems for use in treating concrete-containing materials and surfaces are disclosed. Treatment modalities that include addition of the disclosed materials, compositions and systems to pre- and post-construction concrete-containing materials and surfaces are provided. Reductions in the rate and/or impact of corrosion are achieved for concrete-containing structures and surfaces. In addition, despite the water soluble properties of the material, composition or system, the treatments are effective in delivering an advantageous level of moisture resistance to the treated concrete-containing structure and/or surface. The composition is synthesized from a feedstock that includes C9 to C16 branched hydrocarbons of varying structures.
    Type: Grant
    Filed: August 4, 2010
    Date of Patent: May 24, 2011
    Assignee: Hycrete, Inc.
    Inventors: Eugene B. Humphrey, Todd B. Humphrey, legal representative, Michael S. Rhodes, Philip S. Rhodes, legal representative, James R. Humphrey, Leonid Izrailev, David Rosenberg, John Wojakowski, Jason S. Tuerack