Pentavalent P, Except H(n+2)pno(3n+1) Patents (Class 252/389.23)
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Patent number: 9873776Abstract: The present invention relates to a polyolefin composition with increased resistance to degradation caused by ClO2-containing water and to a pipe or a fitting made of such a polyolefin composition. The polyolefin composition comprises a polyolefin base resin (A), an antioxidant (B) having a chroman-6-ol structure, and an antioxidant (C) having a phenolic structure and the molecule comprises at least one ester group. The present invention further relates to the use of the polyolefin composition for the production of a pipe or a fitting and to the use of the polyolefin composition for increasing the lifetime of a pipe or a fitting providing the polyolefin composition with resistance against degradation caused by contact with ClO2-containing water.Type: GrantFiled: July 24, 2012Date of Patent: January 23, 2018Assignee: BOREALIS AGInventors: Martin Anker, Tanja Piel
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Patent number: 9140640Abstract: A method for determining and identifying corrosion protective layers that provide corrosion protection against crude oils and crude oil fractions is disclosed. The method identifies naturally occurring constituents in crude oils that indirectly provide corrosion protection. A method assessing the potential of these constituents is also disclosed. The method includes exposing metal coupons with the crude oil or crude fraction of interest at the expected operating temperature of concern. The corrosion potential assessment further analyzes the exposed coupons with transmission electron microscopy and an additional high temperature exposure that challenges the tenacity of the protection offered by the corrosion protective layer.Type: GrantFiled: November 4, 2013Date of Patent: September 22, 2015Assignee: EXXONMOBIL RESEARCH AND ENGINEERING COMPANYInventors: H. Alan Wolf, Fang Cao, Saul C. Blum, Alan M. Schilowitz, Shiun Ling, James E. McLaughlin, Srdan Nesic, Peng Jin, Gheorghe Bota
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Publication number: 20150125544Abstract: A solid composition for treating cooling or heated water systems to remove scale, microorganisms and biofilm, and corrosion by-products. The composition for cooling towers and chilled water systems comprises chelating agents and an anionic surfactant. The composition for boilers and heated water systems comprises a sulfite, neutralizing amines, sodium phosphate, and, optionally, a polymethacrylate or polyacrylate polymer. A method for using such a treatment composition comprises contacting the treatment composition with substantially all parts of the water system.Type: ApplicationFiled: November 4, 2014Publication date: May 7, 2015Inventors: Ecaterina Henderson, Pedro G. Gomez, John T. Buxton, Lyle H. Steimel
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Publication number: 20150118103Abstract: Compositions and methods for inhibiting the corrosion of metals in contact with an aqueous system are provided. The method of inhibiting corrosion includes maintaining effective amounts of (1) an amino acid-based polymer, such as a polyaspartic acid compound, and (2) a dispersible and/or soluble tin compound in the aqueous system. The corrosion inhibiting components of the treatment may be added simultaneously or separately into the water of the aqueous system, i.e., provided either in a single treatment product or as separate products. The single treatment single treatment product may include the amino acid-based polymer and a dispersible and/or soluble tin compound. Such a corrosion inhibiting composition may optionally also include a polycarboxylic acid chelating agent and/or a carboxylate/sulfonate functional copolymer.Type: ApplicationFiled: October 31, 2013Publication date: April 30, 2015Inventors: Donovan L. Erickson, Roy A. Johnson, Matthew Ryan LaBrosse, Paul R. Young
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Publication number: 20150040796Abstract: A corrosion inhibitor composition for use in coating compositions on metal surfaces, or in metal containers, to provide corrosion resistance to said metals. The corrosion inhibitor comprises at least one alkoxylated phosphate ester; and at least one borate ester. The corrosion inhibitor composition optionally comprises at least one inorganic metal salt. There is also provided an end-use coating composition comprising said corrosion inhibitor composition, and a method of providing corrosion resistance to a metal surface by applying said coating composition thereto.Type: ApplicationFiled: January 29, 2013Publication date: February 12, 2015Applicant: CRODA, INC.Inventors: John Ernest Hughes, William Harry McNamee
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Patent number: 8951363Abstract: The invention refers to a process for producing an anticorrosive coating in which a surface to be treated is brought into contact with an aqueous treatment solution containing chromium(III) ions and at least one phosphate compound and an organosol. The corrosive protection of metal surfaces, in particular those containing zinc and zinciferous surfaces with conversion layers is improved. The decorative and functional properties of the surfaces are retained or improved. In addition, the well-known problems associated with the use of compounds containing chromium(VI) or with multi-stage processes are avoided in which a passivation layer containing chromium ions and a sealing are applied one after the other.Type: GrantFiled: July 5, 2010Date of Patent: February 10, 2015Assignee: Atotech Deutschland GmbHInventors: Udo Hofmann, Hermann Donsbach, Joerg Unger, Volker Krenzel
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Publication number: 20150008370Abstract: Epoxy-polysiloxane based coating and flooring compositions exhibiting improved flexibility, and excellent weatherability and corrosion resistance after curing are described. The epoxy-polysiloxane polymer coating composition may be prepared by combining a polysiloxane, an epoxide resin material and a cure system including a blend of compounds selected from a dialkoxy functional aminosilane, a trialkoxy functional aminosilane, and an amino functional polysiloxane resin, where the blend has an average alkoxy functionality value of 2.0 to 2.Type: ApplicationFiled: September 19, 2014Publication date: January 8, 2015Inventor: Norman R. Mowrer
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Patent number: 8845930Abstract: The invention provides a method for pre-treating a metal surface with a corrosion inhibitor prior to painting, a method for inhibiting corrosion in a cooling system, wherein the cooling system includes a metal surface and a coolant; and a method for inhibiting corrosion of a reinforcement steel in concrete wherein the method comprising the step of adding to a concrete mixture an anti-corrosive mixture.Type: GrantFiled: November 28, 2005Date of Patent: September 30, 2014Assignee: Pigmentan Ltd.Inventors: Gregory Pipko, Zvi Miller
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Publication number: 20140264179Abstract: An anti-corrosion composition containing at least one fatty acid ester, at least one glycol, at least one ethylene oxide/propylene oxide (EO/PO) alkoxylate, at least one polyethylene glycol ester, and at least one modified lecithin is provided. An anti-corrosion composition also is provided which contains at least one fatty acid ester, at least one glycol, at least one sorbate, and at least one modified lecithin. A method of preparing an anti-corrosion composition is also provided. At least one modified lecithin can be blended with at least one fatty acid ester, at least one glycol, at least one EO/PO alkoxylate, or at least one polyethylene glycol ester, or any combination thereof. A method of inhibiting corrosion of a metal surface including applying an anti-corrosion composition to the metal surface in an amount effective to inhibit corrosion of the metal surface is further provided.Type: ApplicationFiled: March 10, 2014Publication date: September 18, 2014Applicant: Buckman Laboratories International, Inc.Inventors: Amy E. Carter, Donald G. Jenkins, Daniel Glover, Carlton E. Hagen
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Publication number: 20140272392Abstract: A corrosion inhibiting composition includes one or more of a plurality of carriers, each having a carrier body and an organic corrosion inhibitor, such that the carrier body encapsulates the organic corrosion inhibitor, and the carrier body is formed of a degradable material. Coatings and methods for inhibiting corrosion on a metal substrate are also described herein.Type: ApplicationFiled: March 15, 2013Publication date: September 18, 2014Applicant: Honda Motor Co., Ltd.Inventors: Todd Andrew Fitz, Mariko Elaine Berg
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Publication number: 20140272133Abstract: Corrosion inhibitor compositions are provided that can include a mixture of one or more transition metals, one or more organic phosphates, one or more inorganic phosphates, optionally a dispersant, and hydroxyphosphono acetic acid and/or salts thereof. Methods of mitigating or inhibiting corrosion of housing or conduits containing aqueous mediums are also disclosed. The methods can include the steps of pretreating the metal conduit with a mixture of one or more transition metals, one or more organic phosphates, one or more inorganic phosphates, and hydroxyphosphono acetic acid, introducing an aqueous medium into the metal conduit, and injecting a mixture of one or more transition metals, one or more organic phosphates, one or more inorganic phosphates, and hydroxyphosphono acetic acid and/or salts thereof into the aqueous medium.Type: ApplicationFiled: March 15, 2013Publication date: September 18, 2014Inventors: Jasbir S. Gill, Danilo Zim, Matheus Paschoalino
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Patent number: 8828273Abstract: Disclosed is a concentrated cooling water additive that is substantially non-corrosive within a pH range of 2-12 and contains polymeric dispersant(s) and aromatic azole(s) that exhibits improved stability, possibly as a result of the interaction of the hydrophobic groups in the dispersant polymer and the aromatic azole(s). This improved stability allows for both reduced corrosivity of the formula and reduced manufacturing costs. Benefits of the disclosed formulations include improved safety for handling and shipment, more concentrated formulations available in liquid form, reduced shipping costs and storage space, reduced heat of neutralization during product manufacture, reduced costs of manufacture due to removal of need for caustic or acid addition and reduced environmental compliance costs associated with washing and waste handling step.Type: GrantFiled: May 28, 2010Date of Patent: September 9, 2014Assignee: Chemtreat, Inc.Inventors: John Richardson, Dale P. Stuart
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Patent number: 8758876Abstract: A coating which provides corrosion resistance, wear resistance, and, optionally, lubrication, for deposition on a threaded article is disclosed. The coating comprises a polymer matrix, such as a polyimide, which is modified with small amounts of a fluorine containing polymer modifier, as well as other compounds or additives to improve performance of the coating. Additionally, the coating can further comprise a solid lubricant or an anticorrosion compound dispersed within the polymer matrix.Type: GrantFiled: October 30, 2012Date of Patent: June 24, 2014Assignee: Tenaris Connections LimitedInventors: Gabriel Eduardo Carcagno, Klaus Endres
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Publication number: 20140134426Abstract: The present invention is directed to a synergistic multilayer anti-corrosion resistant coating for a metal surface, the coating having three subcoatings, a) a self assembled monolayer nanoprimer; b) a polymeric primer; c) a polymeric top coat containing microcapsules for self-healing. The present invention is further direction to systems and methods for producing the coating in situ on the metal surface. The present invention provides an economical, non-epoxy-based, corrosion coating having favorable resistance to acid and to salt water, and having favorable adhesion properties.Type: ApplicationFiled: June 25, 2012Publication date: May 15, 2014Applicant: ROK Investment Group LimitedInventor: James Jackson Milham Henry
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Patent number: 8642698Abstract: The invention relates to a copolymerizable emulsifier comprising (meth)acrylic acid esters, selected from compounds of the general formula (1) and (II), where: A is an acrylic group having 3 to 40 carbon atoms, x and y independently of each other are a hydrogen group or a methyl group, B is hydrogen or a sulfate or phosphate group, and n a number in the range of 0 to 40. The invention further relates to methods of using said copolymerizable emulsifier in the emulsion polymerization of olefinically unsaturated monomers to prepare polymers.Type: GrantFiled: November 26, 2009Date of Patent: February 4, 2014Assignee: Cognis IP Management GmbHInventors: Ronald Klagge, Thomas Schliwka, Uwe Held, Thomas Mausberg, Katharina Hömberg, Stefan Busch, Shailesh C. Shah
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Publication number: 20130302600Abstract: A process for making a corrosion-resistant metal component. The process having the steps of: combining water, at least one zinc phosphate compound and at least one chromium compound, being chromium (III) or chromium (IV) compounds, to form a first solution; separately combining at least one silicate compound with water to form a second solution; combining the first solution with the second solution such as to form a mixed aqueous solution; optionally combining the mixed aqueous solution with at least one acrylic resin to form a coating mixture; and, applying the coating mixture to a metal substrate having a zinc or zinc-alloy surface to form a coating on the metal substrate, the coating providing chemical resistance for at least 150 hours in accordance with ASTM B117 standards where the zinc or zinc-alloy coating of the metal substrate has a weight of 0.04 oz/ft2 (12.20 g/m2).Type: ApplicationFiled: July 19, 2013Publication date: November 14, 2013Applicant: ECO-GREEN COATINGS, L.L.C.Inventors: William D. KRIPPES, Theodore JAROSZ, Mike SERAFINI, William CAPIZZANO
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Patent number: 8491713Abstract: Described is a new a solution comprising a phosphorous compound and optionally a solderability-enhancing compound and its use in a process for increasing the solderability and corrosion resistance of a metal or metal alloy surface.Type: GrantFiled: January 13, 2010Date of Patent: July 23, 2013Assignee: Atotech Deutschland GmbHInventors: Jürgen Barthelmes, Robert Ruether, Olaf Kurtz, Jana Breitfelder
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Publication number: 20130175477Abstract: Corrosion inhibiting and management systems and for methods of making and using same are presented, where the corrosion systems comprise a reaction product or mixture of reaction products of medium to high carbon count phosphate ester or mixture of medium to a high carbon count phosphate esters and an amine or mixture of amines and where the reaction product or products form a partial or complete coating on surfaces of pipe, piping, pipeline, flowline, and other downhole equipment in contact with aqueous and non-aqueous fluids to protect the surfaces from corrosion at temperature up to up to 750° F. (398.9° C.), and especially, for use in applications using low to moderate temperature geothermal fluids.Type: ApplicationFiled: January 11, 2012Publication date: July 11, 2013Applicant: Clearwater International, LLCInventors: Olusegun Matthew Falana, Khalid Ali Shah, Thomas P. Wilson, JR., Frank Zamora
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Publication number: 20130136947Abstract: A process for making a corrosion-resistant metal component. The process having the steps of: combining water, at least one zinc phosphate compound and at least one chromium compound, being chromium (III) or chromium (IV) compounds, to form a first solution; separately combining at least one silicate compound with water to form a second solution; combining the first solution with the second solution such as to form a mixed aqueous solution; optionally combining the mixed aqueous solution with at least one acrylic resin to form a coating mixture; and, applying the coating mixture to a metal substrate having a zinc or zinc-alloy surface to form a coating on the metal substrate, the coating providing chemical resistance for at least 150 hours in accordance with ASTM B117 standards where the zinc or zinc-alloy coating of the metal substrate has a weight of 0.04 oz/ft2 (12.20 g/m2).Type: ApplicationFiled: November 28, 2011Publication date: May 30, 2013Applicant: ECO-GREEN COATINGS, L.L.C.Inventors: William D. Krippes, Theodore Jarosz, Mike Serafini, William Capizzano
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Publication number: 20130112908Abstract: This invention is directed to a composition capable of imparting surface effects to a liquid by contacting the liquid with a partially fluorinated phosphate with an ammonium cation (NH2R1R2)+ wherein R1 and R2 are independently linear or branched organic groups containing at least one carboxylate moiety and one amino moiety, and optionally be substituted, interrupted, or both with oxygen, sulfur, or nitrogen-containing moieties, or with cyclic alkyl or aryl moieties containing up to 10 carbon atoms.Type: ApplicationFiled: February 20, 2012Publication date: May 9, 2013Applicant: E.I. DU PONT DE NEMOURS AND COMPANYInventors: Sheng PENG, Allison Mary YAKE, Xianjun MENG
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Patent number: 8409478Abstract: The invention relates to a flame retardant composition, particularly designed for fire fighting with aerial means. The retardant composition comprises a liquid ammonium polyphosphate of chain length with a value of n between 2 and 3, n being the number of condensation groups, and an ammonium polyphosphate in powder form in suspension, with a chain length with a value of n between 100 and 1500. In addition to the above, the flame retardant composition comprises corrosion inhibitors, in particular zinc orthophosphate dihydrate, and at least one surfactant agent as wetting agent or dispensing agent, an organic or inorganic thickening agent and at least one coloring agent.Type: GrantFiled: May 20, 2008Date of Patent: April 2, 2013Assignee: Budenheim Iberica, S.L. Sociedad En ComanditaInventors: Vicente Mans Fibla, David Garcia Martinez
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Patent number: 8404181Abstract: The present invention relates to a method of preventing or alleviating the problems associated with corrosion and to novel formulations for use in such a method.Type: GrantFiled: November 9, 2006Date of Patent: March 26, 2013Assignee: Rhodia UK LimitedInventors: Chris Jones, Julie Hardy
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Patent number: 8337606Abstract: Described is a new a solution comprising a phosphorous compound and a solderability-enhancing compound and its use in a process for increasing the solderability and corrosion resistance of a metal or metal alloy surface.Type: GrantFiled: July 10, 2008Date of Patent: December 25, 2012Assignee: Atotech Deutschland GmbHInventor: Peter Kuhlkamp
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Patent number: 8322754Abstract: Coating systems which provide corrosion resistance and, optionally, lubrication, for threaded connections are disclosed. The compositions comprise a first coating composition comprising polymer matrices of polyimides or epoxies which are modified with small amounts of a fluorine containing polymer. Also present in the coating compositions are corrosion inhibiting agents and inorganic particles having a mean diameter of between approximately 10 nm and 10 ?m. Solid lubricants, which may include at least one of PTFE, HDPE, Graphite, and MoS2, are optionally added to provide the first coating with a low coefficient of friction. The coating systems may further comprise a second coating composition, comprising a solid lubricant dispersed within an epoxy resin and a solvent. The first and second coating compositions are deposited on at least a portion of at least one of the pin and box members of the threaded connections.Type: GrantFiled: August 28, 2007Date of Patent: December 4, 2012Assignee: Tenaris Connections LimitedInventors: Gabriel Eduardo Carcagno, Klaus Endres
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Patent number: 8287764Abstract: The invention relates to coated particles comprising a core material and a shell and wherein said core material is an organic compound and wherein said shell comprises a layered double hydroxide comprising a hydroxide or an organic anion as charge-balancing anion.Type: GrantFiled: July 20, 2009Date of Patent: October 16, 2012Assignee: Akzo Nobel N.V.Inventors: Cornelis Elizabeth Johannus Van Lare, Auke Gerardus Talma, Hendrika Petronella Maria Verlaan-Hooft
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Patent number: 8178004Abstract: A composition and method for forming a hydrophobic coating on a metallic substrate are disclosed. The composition comprises: (a) a perfluorinated acid, (b) a surfactant, (c) an organic solvent, and (d) water. The composition is applied to the metal surface, the organic solvent and water permitted to evaporate and coalesce to form a substantially continuous film that preferably is in the form of a self-assembled monolayer covalently bonded to the surface of the substrate.Type: GrantFiled: June 17, 2009Date of Patent: May 15, 2012Assignee: Aculon, Inc.Inventor: Eric L. Hanson
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Publication number: 20120091398Abstract: The invention refers to a process for producing an anticorrosive coating in which a surface to be treated is brought into contact with an aqueous treatment solution containing chromium(III) ions and at least one phosphate compound and an organosol. The corrosive protection of metal surfaces, in particular those containing zinc and zinciferous surfaces with conversion layers is improved. The decorative and functional properties of the surfaces are retained or improved. In addition, the well-known problems associated with the use of compounds containing chromium(VI) or with multi-stage processes are avoided in which a passivation layer containing chromium ions and a sealing are applied one after the other.Type: ApplicationFiled: July 5, 2010Publication date: April 19, 2012Inventors: Udo Hofmann, Hermann Donsbach, Joerg Unger, Volker Krenzel
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Patent number: 8128841Abstract: A method and composition are provided for the operation of an evaporative cooling tower with minimal, or no, blowdown. In some embodiments, the method involves using sodium cation-exchanged softened water as makeup water for the cooling tower, providing a bypass filter for suspended solids removal from the cooling water, treating the cooling water with a composition for control of corrosion and deposition, and using an effective biocide for control of biological growth within the cooling tower system. In some embodiments, a composition is provided that comprises AMPS acrylic terpolymer, sodium silicate, phosphate ions, and polyphosphate ions. When dosed at the recommended levels, the composition controls corrosion of cooling system materials to generally acceptable levels in spite of the extremely corrosive environment resulting from the cycling of sodium cation-exchanged softened water in the cooling tower.Type: GrantFiled: September 11, 2009Date of Patent: March 6, 2012Assignee: Prochemtech International, Inc.Inventor: Timothy E. Keister
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Publication number: 20120045361Abstract: The present invention relates to inhibition of high temperature naphthenic acid corrosion occurring in hydrocarbon processing units.Type: ApplicationFiled: April 15, 2010Publication date: February 23, 2012Applicant: DORF KETAL CHEMICALS (I) PRIVATE LIMITEDInventor: Mahesh Subramaniyam
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Publication number: 20120009762Abstract: A solution for semiconductor wafer dicing is disclosed. The solution suppresses the adherence of contamination residues or particles, and reduces or eliminates the corrosion of the exposed metallization areas, during the process of dicing a wafer by sawing. The solution comprises at least one organic acid and/or salt thereof; at least a surfactant and/or at least a base; and deionized water, the composition has a pH is equal or greater than 4. The solution can further comprise, a chelating agent, a defoaming agent, or a dispersing agent.Type: ApplicationFiled: June 28, 2011Publication date: January 12, 2012Applicant: AIR PRODUCTS AND CHEMICALS, INC.Inventors: Dnyanesh Chandrakant Tamboli, Rajkumar Ramamurthi, David Barry Rennie, Madhukar Bhaskara Rao, Gautam Banerjee, Gene Everad Parris
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Publication number: 20110193027Abstract: A method for inhibiting corrosion comprises the steps of providing a fluid; adding a corrosion inhibitor comprising at least one amphiphilic chemical to the fluid; and monitoring micelles presence in the fluid. A method for determining the amount of corrosion inhibitor that is sufficient to inhibit corrosion, a method for monitoring the activity of an amphiphilic chemical and a system for inhibiting corrosion in a conduit are also disclosed.Type: ApplicationFiled: July 20, 2009Publication date: August 11, 2011Applicant: LUX INNOVATE LIMITEDInventors: Cameron Mackenzie, Vjera Magdalenic, Artin Moussavi, Michael Joosten, Mohsen Achour, David J. Blumer
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Publication number: 20110133128Abstract: The invention relates to coated particles comprising a core material and a shell and wherein said core material is an organic compound and wherein said shell comprises a layered double hydroxide comprising a hydroxide or an organic anion as charge-balancing anion.Type: ApplicationFiled: July 20, 2009Publication date: June 9, 2011Applicant: Akzo Nobel N.V.Inventors: Cornelis Elizabeth Johannus Van Lare, Auke Gerardus Talma, Hendrika Petronella Maria Verlaan-Hooft
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Publication number: 20110091408Abstract: Fluoroalkyl phosphates containing a tertiary carbon and a nonfluorinated chain are useful as surfactants and additives. The f can be used to alter a surface property of a medium and to provide resistance to blocking, open time extension, or oil repellency to a substrate.Type: ApplicationFiled: October 20, 2009Publication date: April 21, 2011Applicant: E. I. DU PONT DE NEMOURS AND COMPANYInventor: Anilkumar Raghavanpillai
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Patent number: 7910024Abstract: Compositions and methods are described for inhibiting corrosion of corrodible metals present in contact with water in cooling water and other water storage systems. The compositions include concentrated stannous salts and agents to solubilize such salts.Type: GrantFiled: September 7, 2007Date of Patent: March 22, 2011Assignee: A.S. Inc.Inventors: William E. Stapp, Gary Westlund
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Patent number: 7803278Abstract: The present invention provides a formulation for use in the treatment of corrosion and metal sulphide scale deposits in aqueous systems, said formulation comprising a tetrakis (hydroxyorgano) phosphonium salt (THP+ salt) and a primary, secondary or tertiary alcohol having an acetylenic bond in the carbon backbone. The invention also provides the use of such a formulation for treating corrosion of mild steel, copper or aluminium, and a method for treatment of an aqueous system containing or in contact with a metal sulphide scale while concomitantly inhibiting the corrosion of surfaces in contact with said aqueous system, which method comprises the addition to said aqueous system of a scale and corrosion inhibiting amount of such a formulation.Type: GrantFiled: October 14, 2004Date of Patent: September 28, 2010Assignee: Rhodia OperationsInventors: Robert Eric Talbot, Jason Grech
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Publication number: 20100196727Abstract: Described is a new a solution comprising a phosphorous compound and a solderability-enhancing compound and its use in a process for increasing the solderability and corrosion resistance of a metal or metal alloy surface.Type: ApplicationFiled: July 10, 2008Publication date: August 5, 2010Applicant: ATOTECH DEUTSCHLAND GMBHInventor: Peter Kuhlkamp
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Publication number: 20100111756Abstract: Methods and compositions are provided for corrosion inhibition treatment of aqueous systems such as cooling water systems. The methods include conjoint use of a polyvalent metal ion, such as Al or Mn and a corrosion inhibitor/deposit control agent (DCA) to the water system. The corrosion inhibitor DCA agent may be an organic compound such as a hydroxyacid, phosphonocarboxylic acid, polyhydroxysuccinic acid, or polymaleic acid or anhydride.Type: ApplicationFiled: October 31, 2008Publication date: May 6, 2010Applicant: GENERAL ELECTRIC COMPANYInventors: Rosa Crovetto, Claudia C. Pierce, Philip D. Deck
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Publication number: 20090214883Abstract: Chromium-free, curable corrosion protection composition for primary coating of metallic substrates, which has a pH in the range from 1 to 3 and contains water and a) fluorocomplex ions of titanium and/or zirconium, b), at least one corrosion protection pigment, c) at least one organic polymer which is soluble or dispersible in water in the specified pH range and on its own in aqueous solution at a concentration of 50% by weight has a pH in the range from 1 to 3, process for treating metal strip with this composition and treated metal strip which can be obtained in this way. The organic polymer c) is preferably selected so that it contains at least one monomer selected from among acrylic acid, methacrylic acid, acrylic esters and methacrylic esters as free-radically polymerizable, ethylenically unsaturated monomers and has at least one type of functional groups selected from among epoxy, silane, hydroxy, carboxyl, phosphoric acid and phosphoric ester groups.Type: ApplicationFiled: February 23, 2009Publication date: August 27, 2009Inventors: Ard De Zeeuw, Marcel Roth, Jorg Sander
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Publication number: 20090184287Abstract: The sarcosine compounds used as a corrosion inhibitor according to the present invention include sarcosine and salt compounds thereof. The corrosion inhibitor is used in chemical mechanical polishing compositions or post CMP clean agents, which forms a protective film on the surface of a work piece to prevent the work piece from corrosion in chemical mechanical polishing, and thus common residue defect on the surface of a work piece due to the use of a conventional corrosion inhibitor (e.g. benzotriazole (BTA)) can be improved or the surface of a work piece can be protected from corrosion in post-CMP cleaning.Type: ApplicationFiled: January 23, 2008Publication date: July 23, 2009Applicant: UWIZ Technology Co., Ltd.Inventor: SONG-YUAN CHANG
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Patent number: 7435359Abstract: An anti-corrosion composition for use with a liquid or the liquid resulting from the addition of components is provided. The composition can include an acid, a phosphate ester of an alcohol, an inorganic phosphate, a salt of polyacrylates and a salt of an organophosphonate. The composition can be used with anti-freeze compositions or heat transfer fluids and advantageously exhibits enhanced corrosion resistance properties. A heat transfer medium is also provide, having water, glycol, an ester of a phosphoric acid, a phosphate salt and an acid, wherein the medium is a GRAS composition capable of satisfying ASTM 1384 and 4340.Type: GrantFiled: December 21, 2004Date of Patent: October 14, 2008Assignee: Hercules Chemical Company IncorporatedInventor: Fred R. Scholer
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Patent number: 7341677Abstract: A non-carcinogenic corrosion inhibiting additive includes an anodic corrosion inhibitor and/or a cathodic corrosion inhibitor and a solubility enhancer for the inhibitors in the form of a metal complexing agent.Type: GrantFiled: June 30, 2003Date of Patent: March 11, 2008Assignee: United Technologies CorporationInventors: Xiaomei Yu, Weilong Zhang, Thomas Garosshen, Promila Bhatia, Mark Jaworowski, Foster Lamm, Xia Tang, Amy Besing, Mike A. Kryzman, Xiaoyuan Chang
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Patent number: 6953537Abstract: A corrosion inhibitor for use with Urea Ammonium Nitrate solutions is disclosed, comprising a blend of molybdate and one or more of the inorganic phosphates (including phosphates, polyphosphates, and pyrophosphates) and organic phosphates or phosphonates. Inorganic phosphates include, but are not limited to, SHMP (Sodium Hexametaphosphate) and TKPP (Tetra-Potassium Pyrophosphate). There are numerous other inorganic phosphates that will also serve as suitable secondary inhibitors. Organic phosphates or phosphonates include, but are not limited to, HEDP (1-Hydroxyethylidine-1,1-diphosphonic acid; also known as ethanol diphosphonate, acetodiphosphonic acid, or etidronic acid), ATMP or AMP (aminotri(methylenephosphonic acid)), PBTC (Phosphonobutane tricarboxylic acid), DETPMP (Diethylenetriaminepenta(methylene phosphonic acid)), and HPA (hydroxyphosphono acetic acid). There are numerous other organic phosphates and phosphonates that will also serve as suitable secondary inhibitors.Type: GrantFiled: January 23, 2003Date of Patent: October 11, 2005Inventors: Scott David Trahan, Eric Paul Mistretta
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Patent number: 6893680Abstract: The invention relates to a coating composition demonstrating improved adhesion and method for improving adhesion of a coating composition to metal. The coating and method of the invention provide improved adhesion of a coating when coating is applied directly over metal substrates, especially untreated metal substrates such as galvanized steel, unsanded aluminum and unsanded cold-rolled steel.Type: GrantFiled: May 2, 2003Date of Patent: May 17, 2005Assignee: BASF CorporationInventor: David L. Newton
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Patent number: 6866797Abstract: A class of quaternary ammonium compounds are found to be effective as corrosion inhibitors. These quaternary ammonium compounds may be used alone or in combination with additional components. For example, phosphate esters can be used with the quaternary ammonium compounds. Moreover, thiocarbonyl compounds can also be added to the corrosion inhibitor compositions. These corrosion inhibitors are effective against ferrous metal corrosion, especially under downhole conditions.Type: GrantFiled: August 3, 2001Date of Patent: March 15, 2005Assignee: BJ Services CompanyInventors: Richard L. Martin, Gene F. Brock, James B. Dobbs
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Patent number: 6846452Abstract: This invention relates to a composition and a method for inhibiting the formation of scale, particularly complex scale, in an aqueous system where more than one type of scale is present. The scale typically present in the aqueous system includes silica, silicates, and carbonates. The scale inhibiting composition comprises (1) 2-phosphonobutane-1,2,4-tricarboxylic acid and salts thereof, and (2) a copolymer of (1) one or more allyloxybenzenesulfonate monomers, and (2) one or more water-soluble acrylic monomers, substituted acrylic monomers, or mixtures thereof.Type: GrantFiled: May 29, 2002Date of Patent: January 25, 2005Assignee: Ashland Inc.Inventors: Pavol Kmec, Dwight E. Emerich
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Patent number: 6814930Abstract: A white rust inhibiting composition and method of inhibiting white rust for evaporative water coolers are disclosed. The composition includes, in combination, a blend of one or more organophosphorus compounds and one or more tannin compounds.Type: GrantFiled: June 10, 2002Date of Patent: November 9, 2004Inventors: Michael T. Oldsberg, Bruce D. Busch
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Patent number: 6814885Abstract: A scale and corrosion inhibitor for use in the treatment of water comprises at least one oxyalkylene unit and at least one phosphonate unit (e.g. a unit derived prom a mono- or di-phosphonic acid such as VPA or VDPA). Inhibitors according to the present invention have been found to exhibit both scale-inhibiting and corrosion-inhibiting properties, especially in the treatment of cooling water and water used in oilfield applications.Type: GrantFiled: December 30, 2002Date of Patent: November 9, 2004Assignee: Rhodia Consumer Specialties LimitedInventors: Gary Woodward, Graham Philip Otter, Keith Philip Davis, Robert Eric Talbot
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Patent number: 6780256Abstract: An aqueous solution and method for applying the solution to a metal surface form a zinc phosphate coating on the metal surface. The zinc phosphate coating minimizes corrosion and improves adhesion of subsequently coated materials such as sealants and paints. The solution of the composition and method of application consume free acidity otherwise left on the metal surface, and obviate the need for subsequent rinsing or extensive drying or stoving operations. The composition includes an aqueous solution including water, a zinc source, phosphoric acid, a polyhydric compound (preferably pentaerythritol), a metal salt, and optionally, an oxidizer.Type: GrantFiled: August 27, 2002Date of Patent: August 24, 2004Assignee: Bulk Chemicals, Inc.Inventor: José B. Rivera
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Patent number: 6706214Abstract: A composition and process for inhibiting the corrosion of metallic substrates is revealed. The process utilizes an aqueous treatment solution comprising chitosan which has been reacted with an additive selected from the group consisting of phosphorus-containing compounds and sulfur-containing compounds and mixtures thereof. More preferably, the phosphorus-containing compound is a phosphonic acid and the sulfur-containing compound is a mercapto, thio, or thienyl containing compound or a mercapto functional silane. The composition and process are particularly useful in providing corrosion protection for aluminum and aluminum alloys.Type: GrantFiled: December 23, 2002Date of Patent: March 16, 2004Inventor: Gerald Wojcik
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Publication number: 20030230742Abstract: A corrosion inhibitor for use with Urea Ammonium Nitrate solutions is disclosed, comprising a blend of molybdate and one or more of the inorganic phosphates (including phosphates, polyphosphates, and pyrophosphates) and organic phosphates or phosphonates. Inorganic phosphates include, but are not limited to, SHMP (Sodium Hexametaphosphate) and TKPP (Tetra-Potassium Pyrophosphate). There are numerous other inorganic phosphates that will also serve as suitable secondary inhibitors. Organic phosphates or phosphonates include, but are not limited to, HEDP (1-Hydroxyethylidine-1,1-diphosphonic acid; also known as ethanol diphosphonate, acetodiphosphonic acid, or etidronic acid), ATMP or AMP (aminotri(methylenephosphonic acid)), PBTC (Phosphonobutane tricarboxylic acid), DETPMP (Diethylenetriaminepenta(methylene phosphonic acid)), and HPA (hydroxyphosphono acetic acid). There are numerous other organic phosphates and phosphonates that will also serve as suitable secondary inhibitors.Type: ApplicationFiled: January 23, 2003Publication date: December 18, 2003Inventors: Scott David Trahan, Eric Paul Mistretta