Amine, Amide, Azo, Or Nitrogen-base Radical Containing Patents (Class 252/401)
  • Patent number: 5207939
    Abstract: A lubricating oil, grease or fuel composition contains an antioxidant amount of a Mannich base reaction product of an N-hydrocarbyl-substituted-phenylenediamine or an N,N'-dihydrocarbyl-substituted phenylenediamine such as N,N'-di-sec-butyl-para-phenylenediamine, an aldehyde or ketone and a hindered phenol such as 2,6-di-tert-butylphenol.
    Type: Grant
    Filed: August 23, 1990
    Date of Patent: May 4, 1993
    Assignee: Mobil Oil Corporation
    Inventors: L. Oscar Farng, Andrew G. Horodysky
  • Patent number: 5205949
    Abstract: An additive composition comprising a graft and derivatized block copolymer prepared from a styrene-ethylenebutylene-styrene characterized in that unsaturation in the styrene blocks is equal to or greater than 50 percent, and the ethylenebutylene block is hydrogenated leaving no more than 10 percent unsaturation which has been grafted with at least one olefinic carboxylic acid acylating agent and then derivatized with an aminoaromatic compound from the group consisting of aminopyridines, aminopyrazines and aminopyrimidines, and a lubricating oil composition containing same are provided.
    Type: Grant
    Filed: June 19, 1991
    Date of Patent: April 27, 1993
    Assignee: Texaco Inc.
    Inventors: Theodore E. Nalesnik, Benjamin J. Kaufman, James G. Dadura
  • Patent number: 5186852
    Abstract: A composition prepared by adding a p,p'-dinonyldiphenylamine represented by the following general formula: ##STR1## wherein R.sub.1 and R.sub.2 may be the same or different from each other and each stand for a branched alkyl group having 6 carbon atoms,and an N-p-alkylphenyl-.alpha.-naphthylamine represented by the following general formula: ##STR2## wherein R.sub.3 is an alkyl group having 12 to 15 carbon atoms derived from a propylene oligomer,as essential components to a mineral oil having an aromatic content of 30% by weight or below and/or a synthetic oil containing no aromatic ring in its structural unit.
    Type: Grant
    Filed: January 8, 1990
    Date of Patent: February 16, 1993
    Assignee: Nippon Oil Co., Ltd.
    Inventors: Noboru Ishida, Hiroyuki Takashima
  • Patent number: 5180514
    Abstract: Aqueous peroxide bleaching compositions including organic components such as surfactants, fluorescent whiteners and dyes are effectively stabilized by the addition of a stabilizing system comprising stabilizing effective amounts of a heavy metal chelating or sequestering agent and an aromatic amine free radical scavenging agent. Both agents must be present to achieve maximum stability. The aromatic amine free radical scavenging agent is preferably a primary or secondary aryl amine having at least one hydrogen on the nitrogen of the amine. The stabilizing system stabilizes the organic component as well as the peroxide oxidizing agent.
    Type: Grant
    Filed: December 6, 1990
    Date of Patent: January 19, 1993
    Assignee: The Clorox Company
    Inventors: James P. Farr, Daniel T. Carty
  • Patent number: 5171888
    Abstract: Methods and compositions are provided for inhibiting the polymerization of acrylic acid monomers during elevated temperature processing thereof or during storage or shipment of acrylic acid product. The compositions comprise a combination of a Mn source compound and a phenylenediamine compound having at least 1 N--H bond. The methods comprise adding from about 1-10,000 ppm of the combination to the particular acrylic acid containing medium for which such anti-polymerization protection is desired, per million parts of the acrylic acid medium.
    Type: Grant
    Filed: April 23, 1991
    Date of Patent: December 15, 1992
    Assignee: Betz Laboratories, Inc.
    Inventor: Paul V. Roling
  • Patent number: 5171462
    Abstract: Mixtures of block alkoxy co- or terpolymer hydrocarboxylates and aminopolyazole increase the oxidation and corrosion resistance of lubricants, particularly diesel engine oil.
    Type: Grant
    Filed: December 23, 1991
    Date of Patent: December 15, 1992
    Assignee: Texaco Inc.
    Inventors: Thomas F. DeRosa, Rodney L. Sung, Benjamin J. Kaufman, Ronald L. O'Rourke
  • Patent number: 5167847
    Abstract: The present invention is directed to the production of a formulated transformer oil by the process involving fractionating the product coming from a hydrocracker to produce a distillate boiling in the transformer oil range, dewaxing the fraction, optionally hydrofinishing the fraction and adding to said fraction an effective amount of anti-oxidant and/or pour point depressant. The formulated transformer oil produced by this process has properties equivalent to those of formulated naphthenic transformer oil.
    Type: Grant
    Filed: May 21, 1990
    Date of Patent: December 1, 1992
    Assignee: Exxon Research and Engineering Company
    Inventors: Christopher Olavesen, Kevin D. Butler
  • Patent number: 5160446
    Abstract: An additive reaction product prepared by the steps comprising reacting a copolymer selected from the group consisting of ethylene copolymers prepared from ethylene and at least one C.sub.3 -C.sub.10 alpha-monoolefin and, optionally, a polyene selected fron non-conjugated dienes and trienes comprising from about 15 to 80 mole percent of ethylene, from about 20 to 85 mole percent of said C.sub.3 -C.sub.
    Type: Grant
    Filed: May 22, 1991
    Date of Patent: November 3, 1992
    Assignee: Texaco Inc.
    Inventors: Theodore E. Nalesnik, Maria M. Kapuscinski
  • Patent number: 5155244
    Abstract: A method of solubilizing a first compound in a second medium where the first compound has a limited solubility in the second medium. In particular, the method comprises reacting the first compound with the second medium. By this reaction, a product is formed whereby an active component of the first compound is covalently incorporated into the second medium.The first compound and second medium each contain at least one reactive group which will react with a reactive group of the other. In addition, the first compound comprises at least one antioxidant which will be covalently bonded to and thus effectively solubilized in the second medium by the reaction.The second medium comprises glyceride derivatives, silicones, fluorocarbons and alkoxylates containing reactive groups such as hydroxy, amino, carboxyl, ester, or amides.
    Type: Grant
    Filed: February 28, 1990
    Date of Patent: October 13, 1992
    Assignee: Karlshamns AB
    Inventors: George H. Greene, James C. Phillips, Jerry F. Stults, Jan P. E. Tellings
  • Patent number: 5141716
    Abstract: The present invention utilizes low volatility amines or alkanol amines to control caustic corrosion which can take place when a boiler system, treated with a coordinated phosphate/pH program, is "out of control".N-substituted hydroxyalkyl piperazines are also capable of mitigating caustic corrosion in coordinated phosphate/pH programs. Combinations of the compounds of the present invention and phosphate have also been shown to be efficacious at mitigating caustic corrosion in coordinated phosphate/pH programs.
    Type: Grant
    Filed: January 18, 1991
    Date of Patent: August 25, 1992
    Assignee: Betz Laboratories, Inc.
    Inventors: John A. Muccitelli, Nancy Feldman
  • Patent number: 5110494
    Abstract: An aqueous alkaline cleaner and a process are described for reducing the discoloration of aluminum surfaces treated with are aqueous alkaline cleaner compositions. The process comprises including in the aqueous cleaner composition, an effective amount of at least one heterocyclic compound. Enhanced mobility of the aluminum surfaces also can be obtained when the heterocyclic compound is a solid particulate compound which is mixed with an oil prior to addition to the aqueous alkaline cleaner. In a preferred embodiment, the heterocyclic compounds are soluble pyrroles, imidazoles, pyrazoles, thiazoles or triazoles.
    Type: Grant
    Filed: August 24, 1990
    Date of Patent: May 5, 1992
    Assignee: Man-Gill Chemical Company
    Inventor: Leslie M. Beck
  • Patent number: 5094814
    Abstract: A combination product containing (a) dihydroxyacetone, (b) hydroquinone, and (c) a volatile amine that is capable of removing oxygen and neutralizing carbon dioxide in industrial waters, particularly boiler waters, including boiler feed waters, internal boiling waters, condensate waters, and return waters. The combination product preferably contains weight ratios of ingredients (a):(b):(c) ranging from 1:0.01:0.1 to about 1:1:100, and may additionally contain a filming amine.
    Type: Grant
    Filed: June 15, 1990
    Date of Patent: March 10, 1992
    Assignee: Nalco Chemical Company
    Inventors: Cynthia A. Soderquist, Mei-Jan L. Lin
  • Patent number: 5095062
    Abstract: Liquid substituted, 2H-benzotriazole mixtures are prepared by alkylation with concomitant dealkylation, fragmentation and realkylation of 2-(2-hydroxy-5-alkylphenyl)-2H-benzotriazoles or of 2-(2-hydroxy-3,5-dialkylphenyl)-2H-benzotriazoles with straight or branched alkenes of 8 to 30 carbon atoms in the presence of an acid catalyst at 100.degree.-200.degree. C. The liquid mixtures exhibit outstanding efficacy in protecting organic substrates from light induced deterioration as well as good resistance to loss by volatilization or exudation during the processing of stabilized compositions at elevated temperatures.
    Type: Grant
    Filed: September 5, 1990
    Date of Patent: March 10, 1992
    Assignee: Ciba-Geigy Corporation
    Inventors: Roland A. E. Winter, Robert E. Detiefsen, Werner Stegmann, Reto Luisoli, David Leppard
  • Patent number: 5075383
    Abstract: An additive composition comprising a graft and amine-derivatized copolymer prepared from ethylene and at least one C.sub.3 to C.sub.10 alpha-monoolefin and, optionally, a polyene selected from non-conjugated dienes and trienes comprising from about 15 to 80 mole percent of ethylene, from about 20 to 85 mole percent of said C.sub.3 to C.sub.10 alpha-monoolefin and from about 0 to 15 mole percent of said polyene, said copolymer having a number average molecular weight ranging from about 5,500 to 50,000 and having grafted thereon at least 1.8 molecules of a carboxylic acid acylating function per molecule of said copolymer and reacting said grafted copolymer with an amino-aromatic polyamine compound from the group consisting of an N-arylphenylenediamine, an aminocarbazole, an aminoindole, an amino-indazolinone, an aminomercaptotriazole, and an amino-perimidine to form said graft and amine-derivatized copolymer, and a lubricating oil composition containing same are provided.
    Type: Grant
    Filed: December 17, 1990
    Date of Patent: December 24, 1991
    Assignee: Texaco Inc.
    Inventors: Cyril A. Migdal, Theodore E. Nalesnik, Nicholas Benfaremo, Christopher S. Liu
  • Patent number: 5071574
    Abstract: A process for reducing the corrosiveness of aerated aqueous solutions, which comprises stripping the oxygen with gas containing hydrogen sulfide after addition of a composition which is both catalytic of the reduction of oxygen by hydrogen sulfide gas and inhibiting of hydrogen sulfide corrosion, such composition comprising certain metallic salts and a water-soluble oxyethylenated amine.
    Type: Grant
    Filed: April 5, 1990
    Date of Patent: December 10, 1991
    Assignee: CECA, S.A.
    Inventor: Tang E. Pou
  • Patent number: 5059689
    Abstract: Compounds which contain at least one group of the formula I ##STR1## in which X is a group which completes the ring to form a piperidine ring, are effective stabilizers for organic materials against damage by light, oxygen and heat.
    Type: Grant
    Filed: January 30, 1989
    Date of Patent: October 22, 1991
    Assignee: Ciba-Geigy Corporation
    Inventors: Jean Rody, Gerhard Rytz, Mario Slongo
  • Patent number: 5057563
    Abstract: Substituted aminoxy propionamide derivatives corresponding to the formula ##STR1## said derivatives being useful as color improvers and stabilizers in various polymeric substrates.
    Type: Grant
    Filed: March 13, 1990
    Date of Patent: October 15, 1991
    Assignee: Ciba-Geigy Corporation
    Inventor: Ramanathan Ravichandran
  • Patent number: 5049601
    Abstract: This invention relates to a process for enhancing the properties of alkylene(C.sub.1 -C.sub.6)-bis-(tetrabromophthalimide) or bis-(tetrabromophthalimide) produced by the bromination, respectively, of alkylene(C.sub.1 -C.sub.6)-bis-(phthalimide) or bis-(phthalimide) with a brominating agent in the presence of oleum, the process comprising curing the alkylene(C.sub.1 -C.sub.6)bis-(tetrabromophthalimide) or bis-(tetrabromophthalimide) at a temperature above about 150.degree. C. and below the melting point of the tetrabromophthalimide being cured for a period of from about 36 hours to about 5 hours. This enhanced product and its use in molding and extrusion compositions and in molded and extruded articles is also disclosed.
    Type: Grant
    Filed: July 24, 1989
    Date of Patent: September 17, 1991
    Assignee: Ethyl Corporation
    Inventor: Mo A. Khuddus
  • Patent number: 5045233
    Abstract: A method for inhibiting polymerization of a maleimide, which comprises adding to said maleimide, as a polymerization inhibitor, at least one compound selected from the group consisting of thiodipropionic esters, 4-t-butyl-catechol, 2,4-dimethyl-6-t-butyl phenol, 2,5-di-t-butylhydroquinone, 2-t-butyl-hydroquinone, 2,4-bis-(n-octylthio)-6-(4-hydroxy-3,5-di-t-butylanilino)-1,3,5-trizaine, 2,2'-thiobis-(4-methyl-6-t-butylphenol), 4,4'-thiobis-(6-butyl-m-cresol), and triethyleneglycol-bis-[3-(3-t-butyl-5-methyl-4-hydroxyphenyl)propionate].
    Type: Grant
    Filed: October 30, 1987
    Date of Patent: September 3, 1991
    Assignee: Nippon Shokubai Kagaku Kogyo Co., Ltd.
    Inventors: Yuichi Kita, Kentaro Sakamoto, Masao Baba, Tomoaki Tobo
  • Patent number: 5023235
    Abstract: An antioxidant system comprises at least one ascorbyl ester stabilized with at least one complexing agent and at least one thiol. The antioxidant system is usefully employed in fatty body containing compositions such as cosmetic or alimentary compositions.
    Type: Grant
    Filed: February 8, 1988
    Date of Patent: June 11, 1991
    Assignee: L'Oreal
    Inventors: Quang L. N'Guyen, Jacqueline Griat, Francois Millecamps
  • Patent number: 5023372
    Abstract: Methods and compositions are provided for inhibiting the polymerization of acrylic acid monomers during elevated temperature processing thereof or during storage or shipment of acrylic acid product. The compositions comprise a combination of a Mn source compound and a phenylenediamine compound having at least 1 N-H bond. The methods comprise adding from about 1-10,000 ppm of the combination to the particular acrylic acid containing medium for which such anti-polymerization protection is desired, per million parts of the acrylic acid medium.
    Type: Grant
    Filed: May 16, 1989
    Date of Patent: June 11, 1991
    Assignee: Betz Laboratories, Inc.
    Inventor: Paul V. Roling
  • Patent number: 5021710
    Abstract: An insect attraction lamp including a lamp for transmitting black light perceptible to insects as an attractant, and a coating providing the lamp with a safety coating for containing debris produced upon the lamp being broken and for allowing transmission of the black light therethrough.
    Type: Grant
    Filed: May 2, 1990
    Date of Patent: June 4, 1991
    Inventor: James D. Nolan
  • Patent number: 5019365
    Abstract: Inhibitors of oxidation of sulfites to sulfates in sulfur dioxide scrubbing solutions are disclosed. The inhibitors are cationic polyelectrolytes which are water soluble, have a molecular weight of at least 10,000 daltons and contain quaternary amine groups. The polyelectrolytes are preferably present at 1-3000 ppm in alkali solutions with which a sulfur dioxide containing gas stream is contacted.
    Type: Grant
    Filed: June 29, 1990
    Date of Patent: May 28, 1991
    Assignee: The Dow Chemical Company
    Inventor: Stephen A. Bedell
  • Patent number: 4992493
    Abstract: The compounds of the formula (I) ##STR1## in which R.sub.1 is C.sub.1 -C.sub.8 -alkyloxy, allyloxy, allylamino, di(C.sub.1 -C.sub.4 -alkyl)-amino, diallylamino, a 5-membered to 7-membered nitrogen containing heterocyclic group with the nitrogen atom linked to the triazine ring, or a group of the formula (II), ##STR2## R.sub.2 is hydrogen, O, OH, NO, CH.sub.2 CN, C.sub.1 -C.sub.8 -alkyl, allyl, benzyl, C.sub.1 -C.sub.8 -acyl, C.sub.1 -C.sub.18 -alkyloxy, C.sub.5 -C.sub.12 -cycloalkyloxy or OH-monosubstituted C.sub.2 -C.sub.4 -alkyl, R.sub.3 and R.sub.5 independently are hydrogen, C.sub.1 -C.sub.12 -alkyl, C.sub.5 -C.sub.12 -cycloalkyl, C.sub.7 -C.sub.9 -phenylalkyl, tetrahydrofurfuryl, C.sub.2 -C.sub.4 -alkyl monosubstituted by OH, by C.sub.1 -C.sub.4 -alkyloxy or by di(C.sub.1 -C.sub.4 -alkyl)amino, or a group of the formula (III) ##STR3## with R.sub.2 as defined above, R.sub.4 is hydrogen, C.sub.1 -C.sub.
    Type: Grant
    Filed: September 6, 1989
    Date of Patent: February 12, 1991
    Assignee: Ciba-Geigy Corporation
    Inventors: Giuseppe Cantatore, Valerio Borzatta, Franca Masina
  • Patent number: 4985159
    Abstract: This invention relates to organic materials normally susceptible to gradual degradation in the presence of oxygen during use over an extended period of time and of the type in which it is customary to add an antioxidant thereto to prevent degradation. The improvement constituting the basis of this invention comprises including an alkenylated toluenediamine having one alkenyl group ortho to an amine group. More particularly, the alkenylated toluenediamines suited as antioxidants are represented by the formulas: ##STR1## wherein R.sub.1, R.sub.2, R.sub.3, R.sub.4 and R.sub.5 are hydrogen, C.sub.1 to C.sub.3 aliphatic, or R.sub.1 and R.sub.2 or R.sub.3 are bridged via an alkylene radical --(CH.sub.2).sub.y -- wherein y=2 to 5, and at least one of R.sub.1, R.sub.2, R.sub.3, R.sub.4 or R.sub.5 is C.sub.1 or greater.
    Type: Grant
    Filed: October 14, 1987
    Date of Patent: January 15, 1991
    Assignee: Air Products and Chemicals, Inc.
    Inventors: William F. Burgoyne, Jr., Dale D. Dixon
  • Patent number: 4966721
    Abstract: N-N'-dihydrocarbyl substituted phenylenediamine-derived Mannich-type condensation products are effective antioxidants for lubricants.
    Type: Grant
    Filed: July 19, 1989
    Date of Patent: October 30, 1990
    Assignee: Mobil Oil Corporation
    Inventors: Liehpao O. Farng, Andrew G. Horodysky
  • Patent number: 4965006
    Abstract: Composition containing (a) at least one lubricant, hydraulic oil or metal-working fluid based on mineral oil or synthetic oils and (b) 0.05-5% by weight, based on the total weight of the lubricant, hydraulic oil or metal-working fluid composition, of at least one compound of the formula I, ##STR1## where R.sup.1 and R.sup.2 are independently alkyl, aryl, substituted aryl or benzyl, R.sup.3 is hydrogen or methyl, R.sup.4 and R.sup.5 are independently hydrogen, methyl, methoxy, chloro or nitro, R.sup.6 is alkyl, alkenyl, aralkyl or substituted benzyl, and R.sup.13 is hydrogen or methyl.
    Type: Grant
    Filed: February 2, 1989
    Date of Patent: October 23, 1990
    Assignee: Ciba-Geigy Corporation
    Inventors: Hans R. Meier, Samuel Evans
  • Patent number: 4954287
    Abstract: Mixtures containing active hydrogen compounds such as polyols and aminoalcohols useful for the production of polyurethane foams and also containing trichlorofluoromethane or 1,1,2-trichloro-1,2,2-trifluoroethane as foam blowing agent, are stabilized against reaction of the active hydrogen compound(s) with the chlorofluorohydrocarbon by incorporating a stabilizing amount of amylene, ortho-(isopropenyl) aniline or diisobutylene.
    Type: Grant
    Filed: April 1, 1988
    Date of Patent: September 4, 1990
    Assignee: Imperial Chemical Industries PLC
    Inventors: Neil Winterton, John G. Carey
  • Patent number: 4943391
    Abstract: Bicyclo[3.3.1]nonane derivatives of the general formula (I) ##STR1## where n is an integer from 1 to 70,R.sup.1 is hydrogen,R.sup.2 is hydrogen or hydroxyl, or the radical ##STR2## R.sup.3 and R.sup.4 are each independently of the other phenyl or 1- or 2-naphthyl, which phenyl or naphthyl may each be substituted by 1, 2 or 3 C.sub.1 -C.sub.12 -alkyls, C.sub.1 -C.sub.12 -alkoxys, chlorines, bromines, fluorines, trifluoromethyls or cyanos, in the case of 2 or 3 substituents these substituents being identical or different,A and B are each independently of the other a chemical bond, C.sub.1 -C.sub.22 -alkylene, cycloalkylene ##STR3## where m and o are each from 1 to 20 andR.sup.10 is hydrogen, C.sub.1 -C.sub.22 -alkyl, C.sub.5 -C.sub.12 -cycloalkyl, C.sub.7 -C.sub.18 -phenylalkyl, phenyl or C.sub.2 -C.sub.22 -cyanoalkyl,M is a radical of the formula ##STR4## which may be bonded to A not only via the nitrogen atom but also via the carbon atom, andR.sup.11, R.sup.12, R.sup.13 and R.sup.
    Type: Grant
    Filed: December 10, 1988
    Date of Patent: July 24, 1990
    Assignee: BASF Aktiengesellschaft
    Inventors: Alexander Aumueller, Peter Neumann, Hubert Trauth
  • Patent number: 4942048
    Abstract: A process for preserving food which comprises packing the food in a hermetically sealed container together with:(a) a deoxygenating material; and(b) at least one compound having amino group(s) selected from among a basic anion exchange resin optionally substituted by a halide ion, an amino acid having one to five carbon atoms in the alkylene chain and a polyamino acid obtained by polycondensing it or a salt thereof, a powdery or granular protein, a polypeptide of a molecular weight of 500 to 20,000 obtained by hydrolyzing a protein and a polymer comprising amino sugar(s);in such a manner that they are not in direct contact with the food. A deoxygenating composition including the components (a) and (b) as defined above is also disclosed.
    Type: Grant
    Filed: October 22, 1986
    Date of Patent: July 17, 1990
    Assignee: Nippon Kayaku Kabushiki Kaisha
    Inventors: Yasunobu Nasu, Taichi Ogishima, Akira Dei, Haruhiko Uchida, Mitsuru Inami, Tatsuo Furuhashi, Yasuhiko Hino, Hideo Sugimura
  • Patent number: 4938885
    Abstract: An antioxidant, dispersant lubricating composition comprises the product produced by first reacting an alkyl acrylate with an amine to produce an intermediate product, a first generation polyamine ester dendrimer which is then treated with an amine to produce a first generation polyamidoamine dendrimer which is then reacted with an acrylate to produce a second generation polyamidoamine ester dendrimer which with an amine is converted to a second generation polyamidoamine dendrimer which is then reacted with a polyisobutenyl succinic acid anhydride to produce the reactant product a polyisobutenyl succinimide-polyamidoamine dendrimer polymer.
    Type: Grant
    Filed: September 28, 1989
    Date of Patent: July 3, 1990
    Assignee: Texaco Inc.
    Inventor: Cyril A. Migdal
  • Patent number: 4927925
    Abstract: Compounds of formula (I) ##STR1## in which R.sub.1 is hydrogen, O.sup.., CN, NO, cyanomethyl, C.sub.1 -C.sub.12 -alkyl, C.sub.3 -C.sub.12 -alkenyl or C.sub.3 -C.sub.12 -alkynyl subject to the proviso that the carbon atom attached to the nitrogen atom is a primary carbon atom, C.sub.7 -C.sub.12 -aralkyl, C.sub.1 -C.sub.12 -acyl, 2,3-epoxypropyl, OH-monosubstituted C.sub.2 -C.sub.6 -alkyl or 2,3-dihydroxypropyl, R.sub.2 is hydrogen, C.sub.1 -C.sub.18 -alkyl, C.sub.5 -C.sub.18 -cycloalkyl, C.sub.6 -C.sub.18 -aryl or C.sub.7 -C.sub.18 -aralkyl, R.sub.3 is C.sub.6 -C.sub.18 -aryl or a group of the formula (II) ##STR2## in which R.sub.1 is as defined above, n is an integer from 1 to 4 and R.sub.4 is an organic or inorganic radical of a valency equal to n are useful for stabilizing organic material against oxidative, thermal and/or light induced degradation.
    Type: Grant
    Filed: October 13, 1988
    Date of Patent: May 22, 1990
    Assignee: Ciba-Geigy Corporation
    Inventors: Giuseppe Cantatore, Valerio Borzatta
  • Patent number: 4927930
    Abstract: The present invention relates to novel piperidyl-triazine compounds with 2 or more triazine rings, to their use as light stabilizers, heat stabilizers and oxidation stabilizers for organic materials, and to the organic materials thus stabilized.
    Type: Grant
    Filed: May 24, 1989
    Date of Patent: May 22, 1990
    Assignee: Ciba-Geigy Corporation
    Inventors: Giuseppe Cantatore, Valerio Borzatta, Franca Masina
  • Patent number: 4920107
    Abstract: A method of preserving an aqueous system which is susceptible to microbiological degradation, comprising the step of adding to the system a compound having the formula ##STR1## wherein X is an anion selected from the group consisting of sulfate, acetate and citrate groups, and wherein the compound is added in an amount sufficient to inhibit the growth and proleferation of at least one microogranism in the aqueous system.The compounds 1-methyl-3,5,7-triaza-1-azoniatricyclodecane acetate and 1-methyl-3,5,7-triaza-1-azoniatricyclodecane citrate, and a method for preparing these compounds comprising the reaction of ammonium citrate, or ammonium acetate, with methylamine, formaldehyde and ammonia in an aqueous medium.
    Type: Grant
    Filed: March 29, 1988
    Date of Patent: April 24, 1990
    Assignee: Buckman Laboratories International, Inc.
    Inventors: John D. Pera, S. Rao Rayudu
  • Patent number: 4888369
    Abstract: Disclosed is a high energy radiation resistant, polypropylene composition. It consists essentially of substantially crystalline normally solid polypropylene having a narrow molecular weight distribution, and, dispersed therein at a concentration effective to increase substantially the high energy radiation resistance of the polypropylene, a synergistic mixture of:(1) a hindered amine component,(2) a hindered phenolic component, and(3) a phosphorous containing component,the weight ratios of component (1) to component (2) to component (3) being about 1:(0.1-2):(0.1-2).Also disclosed are radiation sterilized articles in which at least part of the material of construction comprises the polypropylene composition.
    Type: Grant
    Filed: April 24, 1987
    Date of Patent: December 19, 1989
    Assignee: Himont Incorporated
    Inventor: Edward P. Moore, Jr.
  • Patent number: 4885150
    Abstract: The present invention is a composition comprising (a) thiocyanogen or a thiocyanogen halide and (b) an .alpha.,.beta.-unsaturated ketone, e.g. chloranil, in solution in (c) an inert organic solvent. The composition is useful for the introduction of thiocyanate functionality into organic compounds in the same manner as thiocyanogen or thiocyanogen chloride, but is stable over longer periods of time, i.e. one year or more.
    Type: Grant
    Filed: October 13, 1988
    Date of Patent: December 5, 1989
    Assignee: The Dow Chemical Company
    Inventor: Steven L. Brewster
  • Patent number: 4877541
    Abstract: A corrosion inhibitor for use in synthetic ester lubricating oils is disclosed which comprises an effective amount of:1. at least one aromatic amide; and2. at least one hydroxy substituted aromatic compound.The corrosion inhibitor thus formed is particularly useful in synthetic ester turbo lubricating oils.
    Type: Grant
    Filed: December 11, 1987
    Date of Patent: October 31, 1989
    Assignee: Exxon Research and Engineering Company
    Inventors: Max J. Wisotsky, Stephen J. Metro
  • Patent number: 4871473
    Abstract: Wood preservatives which are based on a zinc compound and an aliphatic carboxylic acid and additionally contain a polyamine and processes for preserving wood with these preservatives.
    Type: Grant
    Filed: December 16, 1988
    Date of Patent: October 3, 1989
    Assignee: Dr. Wolman GmbH
    Inventors: Reimer Goettsche, Hans-Norbert Marx
  • Patent number: 4863981
    Abstract: The present invention relates to a stabilizer system containing two high-molecular polyalkylpiperidines, the use thereof for stabilizing organic material and the organic material which has been protected by means of the stabilizer system mentioned against degradation induced by light.
    Type: Grant
    Filed: June 19, 1987
    Date of Patent: September 5, 1989
    Assignee: Ciba-Geigy Corporation
    Inventor: Francois Gugumus
  • Patent number: 4863982
    Abstract: Compounds of the formula I ##STR1## R.sup.4 is C.sub.5 -C.sub.7 -cycloalkyl which can be substituted by C.sub.1 -C.sub.4 -alkyl, and R.sup.5 to R.sup.9 are independently of one another C.sub.1 -C.sub.18 alkyl, unsubstituted or C.sub.1 -C.sub.4 -alkyl-substituted C.sub.5 -C.sub.7 -cycloalkyl, phenyl, benzyl or allyl, are suitable for stabilizing organic material against thermal, oxidative and/or actinic degradation.
    Type: Grant
    Filed: July 6, 1988
    Date of Patent: September 5, 1989
    Assignee: Ciba-Geigy Corporation
    Inventors: Werner Stegmann, Eduard Troxler, Peter Hofmann, Hans-Rudolf Meier, Paul Dubs
  • Patent number: 4843116
    Abstract: A cycloaliphatic epoxy compound in combination with a 2-hydroxy-substituted benzophenone compound and a polyalkyl-substituted dipiperidine compound provides a UV stabilizer that exhibits synergistic behavior. The compounds can be formulated into a composition that is coated on, or impregnated into, the surface of a plastic article or, alternatively, they can be incorporated into a thermoplastic composition which can be thereafter molded into a shaped article. The stabilizer combination succeeds in upgrading the resistance of polyphenylene ether resins and blends against the photo-deteriorative effects of sunlight and bright indoor light, for example, fluorescent lighting.
    Type: Grant
    Filed: March 17, 1986
    Date of Patent: June 27, 1989
    Assignee: General Electric Company
    Inventor: Richard C. Bopp
  • Patent number: 4836952
    Abstract: The present invention relates a deoxygenating composition comprising a metal-chelated resin and an iron powder.The composition of the present invention is useful, for example, as an agent for preservation of foods.
    Type: Grant
    Filed: April 9, 1987
    Date of Patent: June 6, 1989
    Assignee: Nippon Kayaku Kabushiki Kaisha
    Inventors: Yasunobu Nasu, Haruhiko Uchida
  • Patent number: 4836943
    Abstract: An oil containing a viscosity index improver of improved oxidative stability contains, as an anti-oxidant system 2,6-di-t-butylphenol and 1-3-aminopropyl-2-pipecoline.
    Type: Grant
    Filed: July 15, 1987
    Date of Patent: June 6, 1989
    Assignee: Texaco Inc.
    Inventors: Maria M. Kapuscinski, Christopher S. Liu, Ronald E. Jones, Larry D. Grina
  • Patent number: 4829115
    Abstract: This invention is concerned with the stabilization of organic materials subject to oxidative degradation. The synergists of this invention possess organothioethyl alcohol segmers or moieties which enhance the antioxidative activity of phenolic and amine stabilizers. The invention is also concerned with compounds that contain an organothioethyl alcohol moiety and their use in oxidizable materials in combination with polymerizable and/or conventional antidegradants.
    Type: Grant
    Filed: March 3, 1988
    Date of Patent: May 9, 1989
    Assignee: The Goodyear Tire & Rubber Company
    Inventor: Kirkwood S. Cottman
  • Patent number: 4829111
    Abstract: A stabilizer composition for synthetic resin is described comprising a piperazine derivative represented by the following formula (I): ##STR1## wherein R.sub.1 and R.sub.2 each represents an alkyl group having from 12 to 20 carbon atoms or a 2,2,6,6-tetramethyl-4-piperidyl group; R.sub.3 and R.sub.4 each represents a hydrogen atom or a methyl group; and n and m each represents 2 or 3.A synthetic resin composition is also described comprising polyolefin and the aforesaid piperazine derivative.
    Type: Grant
    Filed: February 2, 1988
    Date of Patent: May 9, 1989
    Assignee: Mitsubishi Petrochemical Co., Ltd.
    Inventors: Kazuyuki Iida, Hiroyuki Omori, Akiyoshi Oonishi, Masami Takahashi
  • Patent number: 4824601
    Abstract: Process is described for the production of a liquid antioxidant composition by reaction of diphenylamine with diisobutylene comprising reacting diphenylamine with diisobutylene in a molar ratio of from 1:1.1 to 1:2.5 and in the presence of an acid activated earth catalyst, while ensuring that the concentration of diisobutylene remains substantially constant throughout the reaction period at a reaction temperature of at least 160.degree. C., the reaction being effected for such a period that the content of 4,4'-dioctyldiphenylamine in the reaction mass, excluding catalyst, is below 25% by weight; and removing catalyst and unreacted diisobutylene; the product of this process; and the use of this product as a stabilizer for organic material against oxidative degradation.
    Type: Grant
    Filed: January 11, 1988
    Date of Patent: April 25, 1989
    Assignee: Ciba-Geigy-Corporation
    Inventor: Janet Franklin
  • Patent number: 4820442
    Abstract: Disclosed is a preservative composition for foodstuffs and the like, which is comprised of (i) a metal powder or a granulated product thereof, (ii) an oxidation accelerator for the metal, (iii) polyallylamine, and (iv) an optional ethanol vapor-generating member. The polyallylamine is preferably deodorized by loading a solution of polyallylamine or a salt thereof on a carrier, and heating and drying the polyallylamine-loaded carrier.
    Type: Grant
    Filed: December 22, 1986
    Date of Patent: April 11, 1989
    Assignee: Freund Industrial Co., Ltd.
    Inventors: Shimesu Motoyama, Shigeru Ohno, Seiichi Umeda
  • Patent number: 4812501
    Abstract: 1,3,2-oxazaphospholidine derivatives of the formula ##STR1## are effective in stabilizing organic materials against oxidative, thermal and actinic degradation, said derivatives being particularly effective as color improvers and process stabilizers in organic materials containing phenolic antioxidants.
    Type: Grant
    Filed: March 16, 1988
    Date of Patent: March 14, 1989
    Assignee: Ciba-Geigy Corporation
    Inventors: Paul A. Odorisio, Stephen D. Pastor, James L. Hyun
  • Patent number: 4808196
    Abstract: The invention provides certain N-alkylalkylenediamine amides and their use as friction reducing additives in lubricants. They are also antioxidants and are useful in applications where additive are not corrosive to copper.
    Type: Grant
    Filed: June 2, 1988
    Date of Patent: February 28, 1989
    Assignee: Mobil Oil Corporation
    Inventor: Andrew G. Horodysky
  • Patent number: 4803234
    Abstract: Compounds of formula (I) ##STR1## in which R.sub.1 is hydrogen, O.sup.., CN, NO, cyanomethyl, C.sub.1 -C.sub.12 -alkyl, C.sub.3 -C.sub.12 -alkenyl or C.sub.3 -C.sub.12 -alkynyl subject to the proviso that the carbon atom attached to the nitrogen atom is a primary carbon atom, C.sub.7 -C.sub.12 -aralkyl, C.sub.1 -C.sub.12 -acyl, 2,3-epoxypropyl, OH-monosubstituted C.sub.2 -C.sub.6 -alkyl or 2,3-dihydroxypropyl, R.sub.2 is hydrogen, C.sub.1 -C.sub.18 -alkyl, C.sub.5 -C.sub.18 -cycloalkyl, C.sub.6 -Chd 18-aryl or C.sub.7 -C.sub.18 -aralkyl, R.sub.3 is C.sub.6 -C.sub.18 -aryl or a group of the formula (II) ##STR2## in which R.sub.1 is as defined above, n is an integer from 1 to 4 and R.sub.4 is an organic or inorganic radical of a valency equal to n are useful for stabilizing organic material against oxidative, thermal and/or light induced degradation.
    Type: Grant
    Filed: January 29, 1987
    Date of Patent: February 7, 1989
    Assignee: Ciba-Geigy Corporation
    Inventors: Giuseppe Cantatore, Valerio Borzatta