Phenol Or Quinone Radical Containing Patents (Class 252/404)
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Patent number: 11312839Abstract: A method to extend a shelf life of a sodium nitroprusside solution includes: dissolving about two parts by weight of a 2-hydroxybenzyl alcohol and about one part by weight of a sodium nitroprusside in about seventy-five parts by weight of a polyethylene glycol. Compositions for preserving a sodium nitroprusside solution are also described.Type: GrantFiled: March 7, 2019Date of Patent: April 26, 2022Assignee: HF Scientific, LLCInventor: Dorian Cauceglia
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Patent number: 10654990Abstract: Provided are: a thermal stabilizer composition which does not generate an odor of a phosphorus-based antioxidant; and a synthetic resin composition comprising the same. The thermal stabilizer composition comprises: 100 parts by mass of a phosphorus-based antioxidant having a phosphite structure; and 0.001 to 10 parts by mass of a phenolic antioxidant having a substructure represented by the following Formula (1): (wherein, R1, R2, R3 and R4 each independently represent a hydrogen atom or a hydrocarbon group having 1 to 10 carbon atoms; a represents an integer of 0 to 2; and, when a is 2, plural R3s are optionally the same or different).Type: GrantFiled: August 4, 2015Date of Patent: May 19, 2020Assignee: ADEKA CORPORATIONInventors: Yoshinori Negishi, Yasuhiro Honma, Masaki Segawa, Yuto Ishizuka, Mariko Ishii
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Patent number: 10329243Abstract: The present invention relates to a biphenyl derivative and use thereof, and the biphenyl derivative has a structure represented by the formula (I) as defined in the specification. The use refers the use of the biphenyl derivative or a pharmaceutically acceptable salt or solvate thereof, or a pharmaceutical composition comprising the biphenyl derivative or a pharmaceutically acceptable salt or solvate thereof in the preparation of a medicament for the treatment and/or prevention of ischemic stroke.Type: GrantFiled: March 11, 2016Date of Patent: June 25, 2019Assignee: XI'AN LIBANG PHARMACEUTICAL CO., LTDInventors: Rutao Wang, Tao Chen, Long An, Yi Zhao, Weijiao Wang, Shupan Guo, Sa Xiao, Jinghua Pang, Huijing Hu
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Patent number: 10329405Abstract: Disclosed herein is a stabilizer mixture for modifying an olefin-based polymer, which comprises at least one organic phosphorus-containing antioxidant represented by a formula selected from the group consisting of formulae (1), (2), (3), (4), (5), (6), (7), and (8), as well as at least one sulfur-containing carboxylate salt represented by a formula selected from the group consisting of formulae (9), (10), (11), and (12). Also disclosed herein is a modified polymer composition prepared from an olefin-based polymer using the stabilizer mixture. The olefin-based polymer is selected from the group consisting of polyolefin, ethylene-vinyl acetate copolymer, and a combination thereof.Type: GrantFiled: September 19, 2017Date of Patent: June 25, 2019Assignee: FDC, Lees Co., Ltd.Inventors: Kun-Chang Lee, Chen-Kai Chen, Jen-Fu Wang
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Patent number: 10252965Abstract: A vinylbenzylated phenol compound represented by General Formula (1) below is provided. (In General Formula (1), Ar0 is a bifunctional phenol compound residue having one or more monocyclic or polycyclic aromatic nuclei, R1 to R5 may be the same or different and are each hydrogen or a methyl group, and p is an integer of 1 to 4.Type: GrantFiled: November 8, 2016Date of Patent: April 9, 2019Assignee: AIR WATER INC.Inventor: Shinji Onda
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Patent number: 10221199Abstract: The invention relates to a method for producing compounds containing isocyanate and silane groups by reacting at least A) one monomeric diisocyanate containing aliphatically, cycloaliphatically, araliphatically and/or aromatically bonded isocyanate groups with B) a mercaptosilane, characterized in that component A) is reacted with component B) in an equivalent ratio of isocyanate groups to mercapto groups of at least 06:01 to at most 40:1. Furthermore, the invention relates to the products which can be obtained using the method according to the invention, and to a composition containing compounds that contain isocyanate and silane groups. Moreover, the invention relates to the use of the products which can be obtained using the method according to the invention and the composition according to the invention as starting components in the production of silane group-containing polyurethanes, cross-linkable binders, varnish, and raw materials for sealants or adhesives.Type: GrantFiled: January 4, 2017Date of Patent: March 5, 2019Assignee: Covestro Deutschland AGInventor: Hans-Josef Laas
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Patent number: 10144898Abstract: The invention provides a composition comprising at least the following: an oil, and at least one compound selected from Compounds 1 through 3, or a combination thereof, as described herein. The composition can be used to improve the high pressure, free-radical polymerizations of ethylene-based interpolymers, and to reduce polymer build-up in reciprocation devices throughout the process.Type: GrantFiled: November 12, 2015Date of Patent: December 4, 2018Assignee: Dow Global Technologies LLCInventors: Bryan Gutermuth, Sean W. Ewart, Jeffery S. Bradley, Otto J. Berbee
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Patent number: 10119753Abstract: A gas sensor module, a refrigerator having the same and a control method for the refrigerator. In another aspect, in a gas sensor module, ion pairs are pre-dissolved in an aqueous solution while the amount thereof and pH of an initial aqueous solution may be adjusted to adjust a sensing range and sensitivity with respect to a target gas to be sensed. In another aspect, the gas sensor module senses the amount of target gas includes an aqueous solution in which ion pairs of a substance having the same dissociation constant as the target gas are dissolved, and senses a pH change of the aqueous solution that occurs due to the target gas being dissolved in the aqueous solution.Type: GrantFiled: July 28, 2014Date of Patent: November 6, 2018Assignee: SAMSUNG ELECTRONICS CO., LTD.Inventors: Yong Won Jeong, Young Chul Ko, Hyun Joo Jung, Youn Joo Song, Chang Hyun Lee, Ji Yeon Han
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Patent number: 10053406Abstract: Disclosed herein are improved methods for the synthesis of honokiol, as well as methods for the synthesis of 3,3?-di-tert-butyl-5,5?-dimethyl-[1,1?-biphenyl]-2,4?-diol, 3?,5-dimethyl-[1,1?-biphenyl]-2,4?-diol, and 2,4?-dimethoxy-3?,5-dimethyl-1,1?-biphenyl, 3,3?,5,5?-tetra-tert-butyl-[1,1?-biphenyl]-2,4?-diol, and certain tetrasubstituted bisphenols, and uses therefor.Type: GrantFiled: October 21, 2016Date of Patent: August 21, 2018Assignees: COLGATE-PALMOLIVE COMPANY, THE TRUSTEES OF THE UNIVERSITY OF PENNSYLVANIAInventors: Stanislav Jaracz, Marisa Kozlowski, Young Eun Lee, Sun Min Kim
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Patent number: 10047211Abstract: Silane-crosslinkable polymeric compositions comprising a polyolefin having hydrolyzable silane groups, an acidic silanol condensation catalyst, a phenolic antioxidant, and an ester-functionalized thioether. Such crosslinkable polymeric compositions can be employed in various articles of manufacture, such as in the wire and cable industry.Type: GrantFiled: June 15, 2015Date of Patent: August 14, 2018Inventors: Manish Talreja, Jessica D. Douglas, Jeffrey M. Cogen, Timothy J. Person, Paul J. Caronia
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Patent number: 9944885Abstract: The disclosure concerns an aqueous lubricant composition, characterized in that it comprises of: 50 wt % of water, 0.01-20 wt % of a thickening agent, 0.5-10 wt % of an antioxidant; 0.5-5 wt % of a pH regulating agent; and glycerol. There is also provided a method for manufacturing the aqueous lubricant composition, and uses of said aqueous lubricant composition.Type: GrantFiled: December 8, 2014Date of Patent: April 17, 2018Assignee: Sustainalube ABInventors: Yijun Shi, Mattias Grahn, Roland Larsson
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Patent number: 9796939Abstract: Described are multi-ring antioxidant products comprising at least one sulfur-bridged aromatic hydrocarbon compound substituted on at least one of its aromatic rings by at least one sterically hindered 3,5-dihydrocarbyl-4-hydroxybenzyl moiety. Such products have the formula: R—Sn—R[—S—R]m wherein each R is, independently, an aromatic hydrocarbon group having 6-12 carbon atoms, wherein m is 0-20, wherein n is 1-6 when m is 0, and when n is 1, m is 1-20; and wherein at least one of R, R1, and R2 is substituted by at least one such sterically hindered moiety. The preparation of such products and their use as antioxidants in compositions normally susceptible to oxidative degradation in oxygen or air, e.g., liquid fuel and lubricants, are also described.Type: GrantFiled: October 8, 2013Date of Patent: October 24, 2017Assignee: SI GROUP, INC.Inventor: Mahmood Sabahi
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Patent number: 9670430Abstract: A synergistic mixture comprising from 1 to 99.9% by weight of compounds having structural elements (I) in which the free valencies on the oxygen atom and on the nitrogen atom may be combined to form a five-, six- or seven-membered ring and the benzene ring may also bear substituents at one or more of the free positions, and from 0.1 to 99% by weight of sulfur-containing organic compounds with antioxidant action. This synergistic mixture is suitable as a stabilizer for stabilizing inanimate organic material, especially mineral oil products and fuels, against the action of light, oxygen and heat.Type: GrantFiled: December 8, 2015Date of Patent: June 6, 2017Assignee: BASF SEInventors: Arno Lange, Dietmar Posselt
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Patent number: 9637506Abstract: The invention relates to a method for producing compounds containing isocyanate and silane groups by reacting at least A) one monomeric diisocyanate containing aliphatically, cycloaliphatically, araliphatically and/or aromatically bonded isocyanate groups with B) a mercaptosilane, characterized in that component A) is reacted with component B) in an equivalent ratio of isocyanate groups to mercapto groups of at least 06:01 to at most 40:1. Furthermore, the invention relates to the products which can be obtained using the method according to the invention, and to a composition containing compounds that contain isocyanate and silane groups. Moreover, the invention relates to the use of the products which can be obtained using the method according to the invention and the composition according to the invention as starting components in the production of silane group-containing polyurethanes, cross-linkable binders, varnish, and raw materials for sealants or adhesives.Type: GrantFiled: August 29, 2013Date of Patent: May 2, 2017Assignee: Covestro Deutschland AGInventor: Hans-Josef Laas
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Patent number: 9562004Abstract: The application discloses monomers based on bisphenols with pendent reactive azido groups. The application further provides a process for preparation of bisphenol monomers with pendent reactive azido groups which are used further for preparing polymers with pendent reactive functional groups and graft copolymer.Type: GrantFiled: November 7, 2013Date of Patent: February 7, 2017Assignee: COUNCIL OF SCIENTIFIC & INDUSTRIAL RESEARCHInventors: Samadhan Suresh Nagane, Prakash Sudhir Sane, Bhausaheb Vilas Tawade, Prakash Purushottam Wadgaonkar
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Patent number: 9415526Abstract: In order to prolong the usage of wood one needs to prevent the growth of rot and fungi. The most common substances used today are not environmentally friendly and they need to be replaced by more environmentally friendly options. Water glass or sodium silicate has been known for a long time having properties which give the wood resistance to rot and fungi and in addition also fire retardant properties. The present invention discloses a method for treatment of wood to improve the flame retardant properties and also the resistance to rot, fungus, mold and insects of a wooden material. The wood treatment method of the invention comprises the steps of providing a wooden material and providing water based formulation which is stable in room temperature or in temperatures ranging from 15-35° C.Type: GrantFiled: November 28, 2011Date of Patent: August 16, 2016Assignee: OrganoWood ABInventors: Marten Hellberg, Anna Ohrn
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Patent number: 9186660Abstract: A process for using a solid acid catalyst having a strong acid cation exchange resin having a cross-linking network structure and free aromatic sulfonic acids adsorbed in the network for synthesis of rubber antioxidant RD and other strong-acid catalyzed reactions.Type: GrantFiled: September 19, 2012Date of Patent: November 17, 2015Assignee: Jiangsu Sinorgchem Technology Co., Ltd.Inventor: Xinmin Chen
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Publication number: 20150112105Abstract: A gas hydrate inhibitor composition including an aqueous solution of anthraquinones. Methods of making and using the inhibitor are also provided, as well as a method of evaluating effectiveness of an inhibitor using THF.Type: ApplicationFiled: October 22, 2013Publication date: April 23, 2015Applicant: Intevep, S.A.Inventors: Alfredo Viloria, Luis A. Castillo, Jose A. García, Rosa D. Nadales, Elluz V. Torín, María A. Carrasquero, María Llamedo
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Patent number: 8932724Abstract: A reflective coating is disclosed that has a base layer provided with a reflective surface for reflecting electromagnetic radiation, such as visible and solar near-infrared light. The reflective coating also has a dielectric layer formed on the reflective surface, and an absorber layer. The absorber layer is formed on the dielectric layer that is formed on the base layer. The reflective coating has an average reflectance greater than about 60% for wavelengths of electromagnetic radiation in the range of 800 to 2500 nm that is irradiated upon the reflective coating. Additionally, the reflective coating has an average reflectance for wavelengths of electromagnetic radiation in the range of 400 to 700 nm irradiated upon the reflecting coating that is less than the average reflectance of the reflective coating from 800 to 2500 nm.Type: GrantFiled: June 7, 2010Date of Patent: January 13, 2015Assignee: General AtomicsInventor: Lawrence D. Woolf
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Patent number: 8865024Abstract: The present invention relates to a composition containing a first component selected from the group consisting of at least one polyphenol, at least one phenolic diterpene and combinations thereof, (b) at least one glyceride, (c) at least one hydrophilic emulsifier, and (d) at least one hydrophobic emulsifier. Also disclosed is the use of this composition as a lipophilic antioxidant.Type: GrantFiled: December 11, 2008Date of Patent: October 21, 2014Assignee: Cognis IP Management GmbHInventors: Michael Müller, Peter Horlacher, Katja Beck
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Publication number: 20140303302Abstract: The present invention relates to a stabilizer composition for halogen-containing polymers and polymer mixtures, comprising at least one hydroquinone compound to prevent or reduce photoblueing of the polymers, polymer compositions comprising the stabilizer compositions, and to methods of using the stabilizer compositions.Type: ApplicationFiled: April 11, 2012Publication date: October 9, 2014Applicant: Chemson Polymer-Additive AGInventor: Bernhard Pelzl
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Patent number: 8852459Abstract: A polyphenol increasing agent for plant leaves, a polyphenol and amino acid increasing agent for plant leaves, a resin pellet, a plant leaf storage sheet, and a method for manufacturing a plant leaf storage sheet which can improve the storability of the plant leaves such as leafy vegetables and tea leaves are provided. A polyphenol increasing agent for plant leaves includes proanthocyanidins and trehalose. The polyphenol increasing agent for plant leaves preferably includes proanthocyanidins and trehalose at a weight ratio of 1:15 to 1:60. A plant leaf storage sheet includes the polyphenol increasing agent for plant leaves.Type: GrantFiled: April 2, 2012Date of Patent: October 7, 2014Inventor: Minoru Kanno
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Patent number: 8840810Abstract: The present invention relates to the antioxidant compounds which are synthesized or derived from benzofuranone compound and benzoic acid compound. The antioxidant compound with remarkable heat resistance possesses carbon-centered radical quencher and primary antioxidant synergism. It can be use as additive for polymer to enhance its stability of melting flow and color.Type: GrantFiled: August 24, 2011Date of Patent: September 23, 2014Assignees: Chitec Technology Co., Ltd., Double Bond Chemical Ind., Co., Ltd., FDC, Lees Chemical Industry Co. Ltd.Inventors: Ching-Fan Chiu, Ching-Yie Su, Eric Lee
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Publication number: 20140194559Abstract: The invention concerns a formulation and method which allow for the efficient delivery of antipolymerants of low solubility into processes for the production of ethylenically unsaturated monomers, and associated process streams, and which avoid the potential health and safety problems and economic disadvantages which are associated with the methods of the prior art and facilitate the safe and efficient production of these monomers. Specifically, the invention provides an antipolymerant composition for the prevention of unwanted polymerisation reactions during the production and processing of ethylenically unsaturated compounds, the composition comprising a concentrated liquid formulation, wherein said concentrated liquid formulation is a suspension concentrate which comprises: (a) at least one compound selected from the group comprising phenols, quinones, thiazines, hydroxylamines and aromatic amines; (b) at least one dispersing agent; and (c) at least one polar or non-polar liquid carrier.Type: ApplicationFiled: August 20, 2012Publication date: July 10, 2014Applicant: NuFarm UK LimitedInventors: Peter Price, Guillaume Duchamp, Angela Jane Glossop, Andrew Nigel Fawbert, Stephanie Mary Dwyer
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Publication number: 20140154419Abstract: The disclosure relates to compositions for wood preservation and methods of applying compositions for wood preservation. The compositions comprise nonionic surfactant mixtures and prepolymer. Compositions of nonionic surfactant mixtures and prepolymers can be used advantageously in methods to preserve wood by impregnation of the wood with preservatives at ambient atmospheric pressures.Type: ApplicationFiled: February 10, 2014Publication date: June 5, 2014Applicant: APINEE, INC.Inventor: Joseph L. Stark
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Publication number: 20140134436Abstract: Thiobis phenolic antioxidants are efficiently dry or melt blended with a tree-resistant, crosslinkable polyethylene by first forming a blend, preferably a dry blend, of the antioxidant with a polyalkylene glycol (PAG), and then mixing the blend with the polyethylene. The incorporation of thiobis phenolic antioxidant and PAG blend into polyethylene provides the PE with high oxidative induction time (OIT) which is a measure of the oxidative stability of the PE.Type: ApplicationFiled: January 21, 2014Publication date: May 15, 2014Applicant: Union Carbide Chemicals & Plastics Technology LLCInventors: Antoni Adamczyk, Daniel Emley, Neil W. Dunchus, Jeffrey M. Cogen, Susan Song
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Publication number: 20130240791Abstract: A method for making an antioxidant composition that is useful for the preservation of foodstuffs. The antioxidant composition contains soapbark tree polyphenols, and is obtained as a permeate from an extract of Quillaja saponaria Molina. The extract contains quantities of saponin, polyphenol, and polysaccharide. The permeate removes saponins, to provide a composition having enriched quantities of polyphenols and polysaccharides, and a reduced quantity of saponin in comparison to the quantity of saponin in the extract.Type: ApplicationFiled: April 29, 2013Publication date: September 19, 2013Inventors: Maria Angelica FELLENBERG PLAZA, John Gabriel ALARCON CAMACHO, Javier Ignacio SAINZ LOBO
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Patent number: 8536258Abstract: The present invention provides a stabilizer containing, as a main component, a bisphenol monoester and a bisphenol-based compound, wherein the area of the bisphenol-based compound is 0.15 to 70 when the area of the bisphenol monoester is set to be 100 in a chromatograph obtained by liquid chromatography analysis of the stabilizer, a method of manufacturing the same, a thermoplastic polymer composition containing the stabilizer, as well as a stabilizer that can further improve the process stability of the thermoplastic polymer, as compared with the conventional one, by compounding the stabilizer into the thermoplastic polymer through a method of stabilizing the thermoplastic polymer using the stabilizer and a method of manufacturing the stabilizer.Type: GrantFiled: July 16, 2008Date of Patent: September 17, 2013Assignee: Sumitomo Chemical Company, LimitedInventors: Ryoji Soma, Kenji Kimura, Masatsugu Akiba
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Publication number: 20130222468Abstract: A liquid composition including: a radical polymerization inhibitor; a solvent; and a surfactant, wherein the content of the radical polymerization inhibitor is 0.1 to 50% by weight.Type: ApplicationFiled: April 1, 2013Publication date: August 29, 2013Applicant: Seiko Epson CorporationInventor: Seiko Epson Corporation
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Publication number: 20130184190Abstract: Provided is an antioxidant composition, including: a compound (A) represented by the following general formula (1); and an amine-based antioxidant (B) and/or a phenol-based antioxidant (C) other than the compound (A): (wherein R represents a hydrogen atom or an alkyl group having 1 to 4 carbon atoms, and n represents a number from 1 to 3.Type: ApplicationFiled: August 26, 2011Publication date: July 18, 2013Applicant: Adeka Corporation of TokyoInventors: Yokio Tatsumi, Kazuhiro Umehara, Shinji Iino
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Patent number: 8409474Abstract: The use of polycyclic phenolic compounds which have up to 20 benzene rings per molecule and are obtainable by reacting a tetrahydrobenzoxazine I where R1 is a hydrocarbyl radical and R2, R3, R4 and R5 are each independently hydrogen atoms, hydroxyl groups or hydrocarbyl radicals with one or more of the same or different phenols II where R7, R8, R9 and R10 are each independently hydrogen atoms, hydroxyl groups or hydrocarbyl radicals, and/or with one or more of the same or different tetrahydrobenzoxazines I, with the proviso that at least one of the substituents has from 13 to 3000 carbon atoms and the remaining substituents, when they are hydrocarbyl radicals, have in each case from 1 to 20 carbon atoms as stabilizers for stabilizing inanimate organic material against the action of light, oxygen and heat.Type: GrantFiled: February 21, 2007Date of Patent: April 2, 2013Assignee: BASF SEInventors: Arno Lange, Helmut Mach, Hans Peter Rath, Dietmar Posselt
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Patent number: 8377336Abstract: The use of polycyclic phenolic compounds which have up to 20 benzene rings per molecule and are obtainable by reacting a tetrahydrobenzoxazine I where R1 is a hydrocarbyl radical and R2, R3, R4 and R5 are each independently hydrogen atoms, hydroxyl groups or hydrocarbyl radicals with one or more of the same or different phenols II where R7, R8, R9 and R10 are each independently hydrogen atoms, hydroxyl groups or hydrocarbyl radicals, and/or with one or more of the same or different tetrahydrobenzoxazines I, with the proviso that at least one of the substituents has from 13 to 3000 carbon atoms and the remaining substituents, when they are hydrocarbyl radicals, have in each case from 1 to 20 carbon atoms as stabilizers for stabilizing inanimate organic material against the action of light, oxygen and heat.Type: GrantFiled: January 28, 2011Date of Patent: February 19, 2013Assignee: BASF SEInventors: Arno Lange, Helmut Mach, Hans Peter Rath, Dietmar Posselt
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Publication number: 20130041086Abstract: The present invention provides a thermoplastic polymer composition containing a particular phenol compound or organic phosphorous compound, a compound represented by the formula (9) and a thermoplastic polymer, as well as a processing stabilizer containing a particular phenol compound or organic phosphorous compound and a compound represented by the formula (9). A combined use of a particular phenol compound or organic phosphorous compound and a compound represented by the formula (9) can improve processing stability of a thermoplastic polymer composition. wherein in the formula (9), m is an integer of 2 or more.Type: ApplicationFiled: April 14, 2011Publication date: February 14, 2013Applicant: SUMITOMO CHEMICAL COMPANY, LIMITEDInventors: Yoshikazu Kimura, Hideaki Awa
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Publication number: 20130034860Abstract: A method for preserving and processing cell-free nucleic acids located within a blood sample is disclosed, wherein a blood sample containing cell-free nucleic acids is treated to reduce both blood cell lysis and nuclease activity within the blood sample. The treatment of the sample aids in increasing the amount of cell-free nucleic acids that can be identified and tested while maintaining the structure and integrity of the nucleic acids.Type: ApplicationFiled: October 10, 2012Publication date: February 7, 2013Applicant: STRECK, INC.Inventor: Streck, Inc.
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Publication number: 20130030225Abstract: Methods and compositions are provided for inhibiting the polymerization of a vinyl aromatic monomer, such as styrene monomer, during elevated temperature processing thereof or during storage or shipment of polymer containing product. The compositions comprise a combination of a quinone methide derivative A) and a phenol compound B). The methods comprise adding from about 1-10,000 ppm of the combination to the monomer containing medium, per one million parts of the monomer.Type: ApplicationFiled: September 27, 2012Publication date: January 31, 2013Applicant: GENERAL ELECTRIC COMPANYInventor: GENERAL ELECTRIC COMPANY
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Publication number: 20130015407Abstract: A process for using a solid acid catalyst having a strong acid cation exchange resin having a cross-linking network structure and free aromatic sulfonic acids adsorbed in the network for synthesis of rubber antioxidant RD and other strong-acid catalyzed reactions.Type: ApplicationFiled: September 19, 2012Publication date: January 17, 2013Applicant: Jiangsu Sinorgchem Technology Co., Ltd.Inventor: Jiangsu Sinorgchem Technology Co., Ltd
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Publication number: 20120316369Abstract: The present invention provides a method for inhibiting unwanted polymerization of reactive monomers within a liquid. The method comprises the combined usage of a quinone methide with a quinone diimide to the liquid monomer. This combination has an unexpected synergistic effect. Thus, in some ratios, the combination results in practically 100% inhibition.Type: ApplicationFiled: June 13, 2011Publication date: December 13, 2012Inventor: Jonathon Masere
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Patent number: 8303851Abstract: Mixtures of additives in granular form comprising: one or more stabilizers for organic polymers; one or more organic or inorganic pigments; and/or one or more dyes; obtained by extrusion at a temperature capable of enabling the partial or total melting of the lowest-melting component. The above mixtures can be used in the stabilization and dyeing of organic polymers.Type: GrantFiled: January 18, 2008Date of Patent: November 6, 2012Assignee: Great Lakes Chemical (Europe) GmbHInventors: Carlo Neri, Corrado Callierotti
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Publication number: 20120276357Abstract: A material for active antioxidant packaging, flexible or rigid, is described, preferably for foods or products vulnerable to any type of oxidation, the material consists of a system promoting migration of an active component to the packaged product during its storage or marketing; it replaces the direct addition of antioxidants to the packaged product and lengthens its shelf life. This material is formed by ?89% of base polymer, 3.5 to 10% by weight of tocopherol antioxidant, and 0.1 to 1.0% by weight of any surface modifier having a hydrophobic portion and a hydrophilic portion in its molecule, whose use as additive in contact with foods is approved by FDA.Type: ApplicationFiled: August 8, 2008Publication date: November 1, 2012Applicant: CENTRO DE INVESTIGACIÓN EN ALIMENTACIÓN Y DESARROLLO A.C.Inventors: Herlinda Soto-Valdez, Abril Zoraida Graciano-Verdugo, Elizabeth Peralta, Cipactli Yuridia
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Patent number: 8287765Abstract: Systems and compositions have a three component antioxidant blend for extending color and clarity of a thermoplastic polymer. The antioxidant blend includes a zinc dithiocarbamate, a phenolic and a thioether with a weight ratio range of about 1-2:1-2:1-2. A loading level of the antioxidant blend is from about 0.01 wt. % to about 1 wt. % of the systems and compositions.Type: GrantFiled: January 16, 2009Date of Patent: October 16, 2012Assignee: R.T. Vanderbilt Company, Inc.Inventor: John DeMassa
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Patent number: 8262949Abstract: The instant invention relates to novel benzotriazole UV-absorbers having a long wavelength shifted absorption spectrum with significant absorbance up to 410-420 nm. Further aspects of the invention are a process for their preparation, a UV stabilized composition containing the new UV-absorbers and the use of the new compounds as UV-light stabilizers for organic materials.Type: GrantFiled: June 18, 2007Date of Patent: September 11, 2012Assignee: BASF SEInventors: Katharina Fritzsche, Markus Grob, Adalbert Braig, Ilona Marion Kienzle, Gérard Daniel Georges Vilain
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Patent number: 8252704Abstract: This disclosure relates to compositions that include (a) at least one substituted or unsubstituted cyclic alkene, and (b) an antioxidant composition including at least one compound of Formula (I): R1 through R4 in Formula (I) are described in the specification.Type: GrantFiled: July 11, 2011Date of Patent: August 28, 2012Assignee: Fujifilm Electronic Materials U.S.A., Inc.Inventors: Daniel J. Teff, John L. Chagolla
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Patent number: 8246859Abstract: The invention describes a process for reducing the surface energy of organic materials such as for example increasing the oil and water repellency and stain release of organic materials, which comprises treating the organic material with at least a compound of the formula I wherein the general symbols are as defined in claim 1; especially wherein at least one of the radicals R2, R3 or R4 is —CH(R11)—S(O)p—R12; R11 is hydrogen, C1-C8alkyl, unsubstituted or with C1-C4alkyl substituted phenyl; R12 is a monovalent perfluorinated alkyl or alkenyl, linear or branched organic radical having four to twenty fully fluorinated carbon atoms, and p is 0, 1 or 2.Type: GrantFiled: June 4, 2007Date of Patent: August 21, 2012Assignee: BASF SEInventors: Michèle Gerster, Manuel Mihalic
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Patent number: 8226850Abstract: An oxygen scavenging system comprising a free radical scavenger (e.g., ?-tocopherol, trimethylhydroquinone, ubiquinol, carotenoids, flavonoids, etc. and mixtures thereof) and a transition metal (e.g., iron (II), copper, manganese, cobalt, etc. and mixtures thereof) in a medium is generally provided. The medium containing the antioxidant and the transition metal has been thermally processed by heating to at least about 150° F. for at least about 10 minutes. Methods of removing oxygen from an environment surrounded by a medium containing the oxygen scavenging system and methods of making the oxygen scavenging system in a medium are also provided.Type: GrantFiled: September 22, 2009Date of Patent: July 24, 2012Assignee: Clemson University Research FoundationInventors: Youngjae Byun, William S. Whiteside
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Patent number: 8187510Abstract: A method for producing a granular composition including the steps of: stirring and granulating a mixture containing not less than 3 parts by weight and not more than 80 parts by weight of a phenol compound represented by the formula (1): wherein R1 is an alkyl group having 1 to 8 carbon atoms, X is an n-valent alcohol residue having 1 to 18 carbon atoms optionally containing a heteroatom, a cyclic group, or a heteroatom and a cyclic group, and n is an integer of 1 to 4, and not less than 20 parts by weight and not more than 50 parts by weight of a binder to obtain a granular agglomerate; and cracking the granular agglomerate at a temperature equal to or lower than the melting point of the binder and equal to or higher than the temperature which is 10° C. lower than the melting point, through a cracking machine equipped with a separation mechanism capable of recovering a granule having a particle size of not more than 5 mm, and a cracking mechanism, to obtain a granule.Type: GrantFiled: March 31, 2010Date of Patent: May 29, 2012Assignee: Sumitomo Chemical Company, LimitedInventors: Hideaki Awa, Masato Arai, Hajime Shinomiya
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Publication number: 20120129995Abstract: The present invention pertains to a concentrated aqueous polymer dispersion with an average particle size of less than 1000 nm comprising a polymer carrier, a non-polar organic phenolic antioxidant and a surfactant. The present invention also pertains to a process for the preparation of said concentrated aqueous polymer dispersion, to a polymer powder obtainable from said concentrated aqueous polymer dispersion, to a composition comprising an organic material and said concentrated aqueous polymer dispersion or said polymer powder and to the use of said concentrated aqueous polymer dispersion or said polymer powder as stabiliser for organic material.Type: ApplicationFiled: July 27, 2010Publication date: May 24, 2012Applicant: BASF SEInventors: Frank Oliver Heinrich Pirrung, Clemens Auschra, Christof Hasler
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Patent number: 8178017Abstract: A method for producing a granular composition including the steps of: stirring and granulating a mixture containing not less than 3 parts by weight and not more than 80 parts by weight of a phenol compound represented by the formula (1): wherein R1 is an alkyl group having 1 to 8 carbon atoms, X is an n-valent alcohol residue having 1 to 18 carbon atoms optionally containing a heteroatom, a cyclic group, or a heteroatom and a cyclic group, and n is an integer of 1 to 4, and not less than 3 parts by weight and less than 20 parts by weight of a binder to obtain a granular agglomerate; and cracking the granular agglomerate at a temperature of not lower than 25° C. and lower than the temperature which is 10° C. lower than the melting point of the binder, through a cracking machine equipped with a separation mechanism capable of recovering a granule having a particle size not more than 5 mm, and a cracking mechanism, to obtain a granule.Type: GrantFiled: March 31, 2010Date of Patent: May 15, 2012Assignee: Sumitomo Chemical Company, LimitedInventors: Hideaki Awa, Masato Arai, Hajime Shinomiya
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Patent number: 8173213Abstract: A stabilized cyclic alkene composition comprising one or more cyclic alkenes, and at least one stabilizer compound having the Formula (I), R1,R2,R3,R4,R5(C6)OH??Formula (I) wherein R? through R5 can each independently be H, OH, C1-C8 linear, branched, or cyclic alkyl, C1-C8 linear, branched, or cyclic alkoxy or substituted or unsubstituted aryl, and wherein the stabilizer compound is present in an amount greater than 200 ppm up to 20,000 ppm and has a boiling point lower than 265° C. A method for forming a layer of carbon-doped silicon oxide on a substrate, which uses the stabilized alkene composition and a silicon containing compound.Type: GrantFiled: May 21, 2009Date of Patent: May 8, 2012Assignee: Air Products and Chemicals, Inc.Inventors: Steven Gerard Mayorga, Mary Kathryn Haas, Mark Leonard O'Neill, Dino Sinatore
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Patent number: 8168706Abstract: A granular composition comprising an organic compound having a melting point of 30 to 100° C., and a compound represented by the formula (1): wherein R1 and R2 independently represent a hydrogen atom, a C1-8 alkyl group, or a C5-8 cycloalkyl group, R3 represents a hydrogen atom or a C1-8 alkyl group, and X represents a single bond, a sulfur atom, an oxygen atom, a C1-8 alkylidene group or a C5-8 cycloalkylidene group.Type: GrantFiled: January 29, 2009Date of Patent: May 1, 2012Assignee: Sumitomo Chemical Company, LimitedInventors: Kazuhiro Kitamura, Yoshikazu Kimura, Kenji Kimura
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Publication number: 20120088875Abstract: A stabilizer composition comprising a phenyl acrylate compound or phosphite compound, and a sugar alcohol. A thermoplastic polymer composition comprising a phenyl acrylate compound or phosphite compound, and a sugar alcohol, wherein the total weight of the phenyl acrylate compound or phosphite compound, and the sugar alcohol is 0.001 to 3 parts by weight with respect to 100 parts by weight of the thermoplastic polymer.Type: ApplicationFiled: April 16, 2010Publication date: April 12, 2012Applicant: SUMITOMO CHEMICAL COMPANY, LIMITEDInventors: Yoshikazu Kimmura, Tetsuya Shintaku