Phenol Or Quinone Radical Containing Patents (Class 252/404)
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Publication number: 20120045406Abstract: The present invention relates to a method for extracting phenolic compounds with low molecular weights from olive fruit water; the invention also relates to compositions enriched with phenolic compounds including at least 40% of dry matter, said dry matter consisting of at least 30% hydroxytyrosol; the invention also relates to a method for drying said compositions by spraying using grape polyphenol extracts as a drying medium as well as to powders titrated with phenolic compounds of olives and grapes obtained after drying.Type: ApplicationFiled: February 18, 2010Publication date: February 23, 2012Applicants: Centre De Cooperation Internationale En Recherche Agronomique Pour Le Developement (CIRAD), Centre International D'Etudes Superieures En Sciences Agronomiques (Montpellier Sup Agro), Grap SudInventors: Nelly Urban, Manuel Dornier, Dominique Pallet, Max Reynes
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Patent number: 8088205Abstract: The invention relates to a wood preservative, which wood preservative contains vegetable oils processed from crude tall oil, such as resin acids and fatty acids. The wood preservative according to the invention is characterized by that the wood preservative is crude tall oil, from which have been removed neutral components contained by the crude tall oil, especially compounds acting as the breeding ground and nutriment of rot fungi and/or compounds causing esterification reactions, such as fatty alcohols and/or steroid groups, such as sitosterol and sitostanol. The invention also relates to a method for manufacturing wood preservative according to the invention.Type: GrantFiled: August 7, 2007Date of Patent: January 3, 2012Assignee: Holjakka OyInventor: Hannu Boren
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Patent number: 8075804Abstract: Compositions containing phenolic antioxidant solutions are provided. The invention further provides methods of making and using such compositions as well as compositions that contain both biodiesel and at least one antioxidant concentrate solutions and blended fuel compositions containing biodiesel blended with other fuels.Type: GrantFiled: January 25, 2007Date of Patent: December 13, 2011Assignee: Eastman Chemical CompanyInventors: Thomas Edward Carter, Joy Lynn Laningham, Phillip Montgomery Hudnall, Sharon Metcalf Cline
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Patent number: 8021585Abstract: A method is described for preparing liquid concentrates of additives for incorporation in polymers, particularly polymers prepared in solution or slurry phase polymerization media. Additive concentrates according to the invention are characterized by a finer dispersion than would result from the direct addition of particulate or granular additives to the same liquid solvent.Type: GrantFiled: April 20, 2007Date of Patent: September 20, 2011Assignee: Ingenia Polymers Corp.Inventors: Zach Charlton, Larry Spino, George Kalantzakis, John Lefas, Salvatore D'Uva
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Publication number: 20110212183Abstract: The present invention relates to compositions suitable for improving oxidative stability of marine oils, marine oils having improved oxidative stability as well as methods for manufacturing such compositions.Type: ApplicationFiled: August 26, 2009Publication date: September 1, 2011Applicant: EPAX ASInventors: Harald Breivik, Charlotte Jacobsenq, Vidar Moen, Tania Vojnovic
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Publication number: 20110196082Abstract: The invention describes a storage-stable aqueous emulsion comprising a) a compound of the formula (I); wherein n is 4 to 23, b) a surfactant, and c) water, and describes a storage-stable liquid blend with low viscosity, which is not an aqueous emulsion, comprising a) a compound of the formula I d) at least a stabilizer selected from the group consisting of phosphites, phosphonites, aminic antioxidants, hydroxylamines, benzofuran-2-ones, thiosynergists, plasticizers, acid scavengers, lubricants, dispersing aids, sterically hindered amines, UV absorbers and sterically hindered phenols other than the compounds of the formula I according to component a). These emulsions and blends are useful as stabilizers for organic materials.Type: ApplicationFiled: June 23, 2009Publication date: August 11, 2011Applicant: BASF SEInventors: Karl-Heinz Hornbach, Roswell Easton King, Arpad Major, Jean-Roch Pauquet, Alex Wegmann, Thomas Wehrle, Philipp Walter, Andreas Cendra, Walid Al-akhdar
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Patent number: 7985350Abstract: This disclosure relates to compositions that include (a) at least one substituted or unsubstituted cyclic alkene, and (b) an antioxidant composition including at least one compound of Formula (I): R1 through R4 in Formula (I) are described in the specification.Type: GrantFiled: December 21, 2010Date of Patent: July 26, 2011Assignee: Fujifilm Electronic Materials U.S.A., Inc.Inventors: Daniel J. Teff, John L. Chagolla
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Patent number: 7977418Abstract: The present invention provides a bisphenol monoester-based stabilizer composition that can improve resistance to discoloration at high temperature of a thermoplastic polymer compared with a conventional one using a bisphenol monoester-based stabilizer composition including a bisphenol monoester-based compound mainly, wherein a compound represented by the following formula: is contained in an area percentage by liquid chromatography analysis of 0.1 to 3%, a thermoplastic polymer composition and a method of manufacturing the thermoplastic polymer composition, a thermoplastic polymer molded product, and a method of stabilizing a thermoplastic polymer, as well as a thermoplastic polymer composition in which resistance to discoloration at high temperature is improved by using the stabilizer composition and a method of manufacturing the thermoplastic polymer composition, a thermoplastic polymer molded product, and a method of stabilizing a thermoplastic polymer.Type: GrantFiled: July 21, 2008Date of Patent: July 12, 2011Assignee: Sumitomo Chemical Company, LimitedInventors: Kenji Kimura, Ryoji Soma, Masatsugu Akiba, Toyomochi Tamato
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Patent number: 7976729Abstract: A composition for stabilizing organic polymers comprising a sterically hindered phenol produced by reacting p-cresol and dicyclopentadiene to produce a precursor and alkylating the precursor with isobutylene, and a tertiary amine oxide.Type: GrantFiled: November 5, 2008Date of Patent: July 12, 2011Assignee: Chemtura CorporationInventor: Jonathan S. Hill
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Patent number: 7931823Abstract: A stabilized cyclic alkene composition comprising one or more cyclic alkenes, and at least one antioxidant compound having the formula (I), wherein R1 through R5 can each independently be H, OH, C1-C8 linear, branched, or cyclic alkyl, C1-C8 linear, branched, or cyclic alkoxy or substituted or unsubstituted aryl, and wherein the antioxidant compound is present in an amount between 1 ppm and 200 ppm and has a boiling point lower than 265° C. A method for forming a layer of carbon-doped silicon oxide on a substrate, which uses the stabilized alkene composition and a silicon containing compound.Type: GrantFiled: September 12, 2006Date of Patent: April 26, 2011Assignee: Fujifilm Electronic Materials U.S.A., Inc.Inventors: Daniel J. Teff, John L. Chagolla
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Patent number: 7902280Abstract: Disclosed herein are highly stable styrenated phenolic compositions that are liquids at room temperature, and polymer articles and lubricant compositions containing such styrenated phenolic compositions. Also disclosed are processes for forming such styrenated phenolic compositions, which processes afford distyrenated phenolics assaying at 70% minimum by total GC area, comprising reacting styrene with one or more phenolics, e.g., at least one of phenol, p-cresol and/or o-cresol, in the presence of an acid catalyst, preferably a sulfonic acid catalyst, at elevated temperature, wherein the resulting product mixture comprises one or more monostyrenated phenolics, one or more distyrenated phenolics, and one or more tristyrenated phenolics.Type: GrantFiled: July 7, 2008Date of Patent: March 8, 2011Assignee: Chemtura CorporationInventors: Michael E. Gelbin, Jonathan S. Hill, Maurice Power, Jun Dong, Cyril A. Migdal, Gerard Mulqueen, Joseph F. Stieber
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Patent number: 7883639Abstract: A stabilized cyclic alkene composition comprising one or more cyclic alkenes, and at least one antioxidant compound having the formula (I), wherein R1 through R5 can each independently be H, OH, C1-C8 linear, branched, or cyclic alkyl, C1-C8 linear, branched, or cyclic alkoxy or substituted or unsubstituted aryl, and wherein the antioxidant compound is present in an amount between 1 ppm and 200 ppm, and wherein said composition is purged with at least one inert gas after said composition is introduced to a container intended for storage or shipping of said composition. A method for forming a layer of carbon-doped silicon oxide on a substrate, which uses the stabilized alkene composition and a silicon containing compound.Type: GrantFiled: September 12, 2006Date of Patent: February 8, 2011Assignee: Fujifilm Electronic Materials, U.S.A., Inc.Inventors: Daniel J. Teff, John L. Chagolla
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Patent number: 7871536Abstract: This disclosure relates to compositions that includes (a) one or more substituted or unsubstituted cyclic alkenes, and (b) an antioxidant composition including at least one compound of Formula (I): R1 through R4 in Formula (I) are described in the specification.Type: GrantFiled: July 7, 2009Date of Patent: January 18, 2011Assignee: Fujifilm Electronic Materials U.S.A., Inc.Inventors: Daniel J. Teff, John L. Chagolla
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Patent number: 7824575Abstract: The present invention provides for liquid antioxidant mixtures of octylated/butylated diphenylamine, phenothiazine and octadecyl (3,5-di-tert-butyl-4-hydroxyphenyl)-propionate. The antioxidant mixtures are useful for polyurethane stabilization.Type: GrantFiled: July 31, 2008Date of Patent: November 2, 2010Assignee: Ciba CorporationInventor: Walid Al-Akhdar
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Publication number: 20100187481Abstract: The invention relates to the use of ionic liquids for improving the lubricating effect of synthetic, mineral and native oils. The invention relates in particular to an improved lubricating composition that is protected from thermal and oxidative attack.Type: ApplicationFiled: May 20, 2008Publication date: July 29, 2010Inventors: Günther Bodesheim, Martin Scgnudt-Amelunxen, Dieter Sohn, Stefan Grundei, Andrea Höpke
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Publication number: 20100163805Abstract: The present invention generally relates to various media for protecting antioxidants contained therein from degradation before use. More particularly, the present invention relates to media which are to be dissolved in a fluid before use and to protect antioxidants contained therein from ultraviolet rays and from degradation caused by a prolonged period of dissolution in the fluid. To this end, such media include various fillers to protect the antioxidants from the ultraviolet rays. The present invention also relates to various media capable of promoting mixing of the antioxidants in the fluid. The present invention also relates to various methods of protecting such antioxidants contained in the media from such rays and various methods of promoting mixing between the fluid and antioxidants and/or fillers.Type: ApplicationFiled: December 31, 2008Publication date: July 1, 2010Inventor: Youngtack Shim
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Publication number: 20100136592Abstract: Compositions, devices, systems and methods for reducing and/or preventing photo-induced damage of one or more reactants in an illuminated analytical reaction by addition of one or more photo-induced damage mitigating agents to the reaction mixture and allowing the reaction to proceed for a period that is less than a photo-induced damage threshold period.Type: ApplicationFiled: November 19, 2009Publication date: June 3, 2010Applicant: Pacific Biosciences of California, Inc.Inventors: Xiangxu Kong, Gene Shen, Andrei Fedorov, John Lyle, Grace Lee, Lubomir Sebo, Duc Do, Robert Weber, Stephen Dudek
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Patent number: 7695643Abstract: The invention relates to novel benzotriazole UV-absorbers having a long wavelength shifted absorption spectrum with significant absorbance up to 410-420 nm. Further aspects of the invention are a process for their preparation, a UV stabilized composition containing the new UV-absorbers and the use of the new compounds as UV-light stabilizers for organic materials.Type: GrantFiled: January 23, 2006Date of Patent: April 13, 2010Assignee: Ciba Specialty Chemicals CorporationInventors: Katharina Fritzsche, Adalbert Braig, Markus Frey, Walter Fischer
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Patent number: 7671118Abstract: A stabilizer system for stabilizing halogen-containing polymers comprising a perchlorate salt and at least one indole compound, a composition comprising such a stabilizer system, process for stabilizing a chlorine-containing polymer using such a stabilizer system, and an article manufacture comprising PVC stabilized by such a stabilizer system.Type: GrantFiled: March 28, 2006Date of Patent: March 2, 2010Assignee: Chemtura Vinyl Additives, GmbHInventors: Wolfgang Wehner, Hans-Helmut Friedrich
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Patent number: 7651635Abstract: The invention provides a composition of matter and a method of its use in preventing unwanted polymerization reactions. The composition comprises an inhibitor and a retarder. The inhibitor is highly effective. The retarder is reliable under extreme and emergency situations. The inhibitor can be an alkylhydroxylamine. The retarder can be a 7-cyano-quinone methide. The combination of the inhibitor and retarder has been found to be far more effective than expected.Type: GrantFiled: February 5, 2009Date of Patent: January 26, 2010Assignee: Nalco CompanyInventor: Vincent E. Lewis
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Publication number: 20090291210Abstract: This disclosure relates to compositions that includes (a) one or more substituted or unsubstituted cyclic alkenes, and (b) an antioxidant composition including at least one compound of Formula (I): R1 through R4 in Formula (I) are described in the specification.Type: ApplicationFiled: July 7, 2009Publication date: November 26, 2009Applicant: Fujifilm Electronic Materials U.S.A., Inc.Inventors: Daniel J. Teff, John L. Chagolla
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Publication number: 20090253608Abstract: Certain substituted phenolic compounds when used with or without 1,2-epoxides as the sole stabilizer components are very effective in stabilizing n-propyl bromide (NPB). In a standard commercially important 60° C. stability test, representative substituted phenolic compounds used pursuant to this invention, can enable NPB to pass the test even though present at levels of about 50 ppm (wt/wt) or less in NPB containing no other stabilizer additive component. In fact, amounts as low as 1 ppm have been found effective with various substituted phenolic compounds. In addition, it has been found that one of the preferred stabilizers of this invention—2,6-di-tert-butyl-p-cresol—even though higher boiling than NPB, left inconsequential amounts of residue at least throughout the range of 1 to 30 ppm (wt/wt). Also, it has been found that certain other preferred stabilizers of this invention can provide synergistically improved stability in passing the 60° C.Type: ApplicationFiled: November 5, 2004Publication date: October 8, 2009Applicant: ALBEMARLE CORPORATIONInventors: Bonnie Gary McKinnie, Joseph H. Miller
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Patent number: 7582317Abstract: The invention concerns blends of a hydroquinone substituted poly unsaturated fatty acid (as present in Kombo nut oil) or a derivative thereof, which blends comprised: (i) 0.1-99.9 wt % of the substituted acid (ii) 0-99.8 wt % of Kombo butter glycerides (iii) 0.1-99.9 wt % of other triglycerides Food products and food supplements comprising such hydroquinone substituted acids are also part of the invention. The substituted acids display many useful health benefits.Type: GrantFiled: August 29, 2002Date of Patent: September 1, 2009Assignee: Loders Croklaan USA LLCInventors: Scott Sinclair Barclay, John Anthony Bosley, Frederick William Cain, Claudia Koenen, Julia Sarah Rogers, Ulrike Schmid
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Patent number: 7560119Abstract: Methods of treating acne include the use of formulations including a benzoyl peroxide solution and an antioxidant.Type: GrantFiled: June 23, 2008Date of Patent: July 14, 2009Assignee: JR Chem, LLCInventors: Joseph R. Faryniarz, Jose E. Ramirez
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Patent number: 7560048Abstract: Liquid stabilizing mixtures for organic polymers comprising: a) a liquid compound belonging to the group of sterically hindered phenols consisting of esters or mixtures of esters having formula (I); b) a solid compound belonging to the group of sterically hindered phenols having formula (II).Type: GrantFiled: July 6, 2005Date of Patent: July 14, 2009Assignee: Great Lakes Chemical (Europe) GmbHInventors: Fabio Broussard, Jose Roncalli
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Patent number: 7556820Abstract: Benzoyl peroxide compositions are stabilized against decomposition by the use of antioxidants, resulting in increased shelf life of products made using the compositions. Treatment of truncal acne vulgaris with a combination of actives, namely benzoyl peroxide and salicylic acid, is provided via regimens that include applying such benzoyl peroxide compositions to an area of the body afflicted with acne, after a waiting period rinsing the benzoyl peroxide-treated area (e.g., by showering), drying the rinsed area, and then applying a topical, at least partially neutralized salicylic acid composition to the afflicted area.Type: GrantFiled: November 4, 2008Date of Patent: July 7, 2009Assignee: JR Chem, LLCInventors: José E. Ramirez, Joseph R. Faryniarz
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Publication number: 20090152502Abstract: The present invention relates to a composition containing a first component selected from the group consisting of at least one polyphenol, at least one phenolic diterpene and mixtures of both, at least one glyceride, at least one hydrophilic emulsifier and at least one hydrophobic emulsifier, and also to the use of this mixture as lipophilic antioxidant.Type: ApplicationFiled: December 11, 2008Publication date: June 18, 2009Applicant: Cognis IP Management GmbHInventors: Michael Muller, Peter Horlacher, Katja Beck
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Publication number: 20090065744Abstract: The use of polycyclic phenolic compounds which have up to 20 benzene rings per molecule and are obtainable by reacting a tetrahydrobenzoxazine I where R1 is a hydrocarbyl radical and R2, R3, R4 and R5 are each independently hydrogen atoms, hydroxyl groups or hydrocarbyl radicals with one or more of the same or different phenols II where R7, R8, R9 and R10 are each independently hydrogen atoms, hydroxyl groups or hydrocarbyl radicals, and/or with one or more of the same or different tetrahydrobenzoxazines I, with the proviso that at least one of the substituents has from 13 to 3000 carbon atoms and the remaining substituents, when they are hydrocarbyl radicals, have in each case from 1 to 20 carbon atoms as stabilizers for stabilizing inanimate organic material against the action of light, oxygen and heat.Type: ApplicationFiled: February 21, 2007Publication date: March 12, 2009Applicant: BASF SEInventors: Arno Lange, Helmut Mach, Hans Peter Rath, Dietmar Posselt
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Publication number: 20090032773Abstract: The present invention provides polymeric compositions comprising an hydrogenated anthraquinone derivative and/or its enol/enolate tautomer. Methods of scavenging oxygen and preventing transmission of oxygen into a package using said compositions are also provided.Type: ApplicationFiled: June 28, 2005Publication date: February 5, 2009Inventors: Mark Andrew Horsham, Andrew David Scully, James Keith Gerard Murphy, Ross Anthony Santangelo, Michael McNally
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Publication number: 20090001322Abstract: Process for preparing an alkoxypolyoxyalkylene (meth)acrylate in which a) a metal alkoxide MetOR10 is initially charged, b) an alkylene oxide of the formula (IV) is added and reacted with the metal alkoxide and c) (meth)acrylic anhydride is added directly and reacted with the reaction product from step b). Appropriately, in step c) , a stabilizer mixture is added which comprises, for example, the following components I. at least one compound of the formula (I) II. at least one compound of the formula (IIa or IIb) or of the formula (IV) III.Type: ApplicationFiled: January 30, 2007Publication date: January 1, 2009Applicant: Evonik Roehm GmbHInventors: Uwe-Martin Wiesler, Joachim Knebel, Brigitte Mess
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Publication number: 20090005478Abstract: Disclosed herein are highly stable styrenated phenolic compositions that are liquids at room temperature, and polymer articles and lubricant compositions containing such styrenated phenolic compositions. Also disclosed are processes for forming such styrenated phenolic compositions, which processes afford distyrenated phenolics assaying at 70% minimum by total GC area, comprising reacting styrene with one or more phenolics, e.g., at least one of phenol, p-cresol and/or o-cresol, in the presence of an acid catalyst, preferably a sulfonic acid catalyst, at elevated temperature, wherein the resulting product mixture comprises one or more monostyrenated phenolics, one or more distyrenated phenolics, and one or more tristyrenated phenolics.Type: ApplicationFiled: July 7, 2008Publication date: January 1, 2009Inventors: Michael E. Gelbin, Jonathan S. Hill, Maurice Power, Jun Dong, Cyril A. Migdal, Gerard Mulqueen, Joseph F. Stieber
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Patent number: 7445729Abstract: Organic peroxide compositions are stabilized against decomposition by the use of antioxidants, resulting in increased shelf life of products made using the compositions.Type: GrantFiled: November 21, 2007Date of Patent: November 4, 2008Assignee: JR Chem, LLCInventors: Joseph R. Faryniarz, Jose E. Ramirez
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Patent number: 7435405Abstract: By suppressing oxidation of sulfide minerals in sulfide ore due to bacteria or the like, this invention prevents the elution of heavy metals from the sulfide ore, and reduces the decrease in flotation performance when processing sulfide ore that is stored in a stockpile. Also, the invention makes it easier to process acidic wastewater from a stockpile or tailings dumpsite. In order to accomplish this, oxidation of sulfide minerals in sulfide ore is suppressed by adding an antioxidant, which contains plant polyphenol and whose main component is an organic acid that contains a carboxyl group, to the sulfide ore stored in a stockpile or tailings dumpsite.Type: GrantFiled: April 14, 2005Date of Patent: October 14, 2008Assignee: Sumitomo Metal Mining Co., Ltd.Inventors: Yoshiyuki Tanaka, Ryoichi Nakayama, Hideyuki Okamoto, Masaki Imamura
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Patent number: 7425290Abstract: A compacted particulate polymer additive composition in a dry granular form formed from a substantially uniform mixture of the following components: (a) at least one particulate sterically-hindered phenolic compound; and (b) one or more particulate polymer additives other than a sterically-hindered phenolic compound; wherein the particles of said composition are held together in compacted dry granular form exclusively or substantially exclusively by contact with dried surfaces of in situ desolvated particles from particles of one or more at least partially solvated components of (a), and optionally by contact with dried surfaces of in situ desolvated particles from particles of one or more at least partially solvated components of (b). Compositions of this type except that there is no component (b) are also described.Type: GrantFiled: August 4, 2004Date of Patent: September 16, 2008Assignee: Albemarle CorporationInventor: John Semen
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Patent number: 7390431Abstract: Organic peroxide compositions are stabilized against decomposition by the use of antioxidants, resulting in increased shelf life of products made using the compositions.Type: GrantFiled: March 10, 2006Date of Patent: June 24, 2008Assignee: JR Chem, LLCInventors: Joseph R. Faryniarz, Jose E. Ramirez
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Patent number: 7332535Abstract: A stabilizer mixture for one or more compounds of the general formula (1) and (1A) but preferably (1), wherein the groups R independently stand for an alkyl-, cycloalkyl-, aralkyl- or aryl-rest whereas the aromatic ring system may be optionally substituted by one or more groups R? which may be identical or different and which groups R? can be an aryl-, a saturated or unsaturated alkyl-, aralkyl- or cycloalkyl-group as well as halogen, an amino-, aminoalkyl-, aminocycloalkyl-, cyano-, thiocyano- or nitrogroup. and a UV-absorber, hindered amine stabilizer, sterically hindered phenol, organophosphite, organophosphonite, organophosphine, or mixtures thereof. The present invention is useful in the protection of various polymeric substrates against the damaging influence of light exposure by the long term storage of polymers. This effect can be observed especially in so-called engineering plastics (such as, for example, PC, PET, PBT, ABS, TPU).Type: GrantFiled: June 8, 2006Date of Patent: February 19, 2008Assignee: Clariant Finance (BVI) LimitedInventors: Christoph Kröhnke, Joseph R. Webster, Ernst Gronmaier, Lajos Avar
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Patent number: 7329772Abstract: A method of making a hindered phenolic antioxidant is disclosed wherein the method comprises: reacting an ester of the formula: wherein R1, R2, and R3 are independently selected alkyl groups and n is 0, 1, or 2, with an aliphatic polyhydroxyl alcohol of the general formula R(OH)n wherein R is an aliphatic group of from 2 to about 12 carbon atoms and n is an integer of from 2 to 7, provided that one hydroxyl is primary and the others are secondary or tertiary, in the presence of a strong acid catalyst; then, neutralizing the strong acid catalyst with an overbased detergent; and isolating the hindered phenolic antioxidant after the neutralization step.Type: GrantFiled: April 29, 2004Date of Patent: February 12, 2008Assignee: Crompton CorporationInventor: John R. Baranski
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Publication number: 20080019860Abstract: The invention provides liquid monophasic antioxidant compositions that are miscible in a lipid material. The monophasic antioxidant compositions may be added to a lipid material to prevent their oxidation. The invention also provides a process for the preparation of the antioxidant compositions.Type: ApplicationFiled: July 3, 2007Publication date: January 24, 2008Applicant: NOVUS INTERNATIONAL INC.Inventors: Ibrahim Abou-Nemeh, Prakash Wadhwa
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Patent number: 7309452Abstract: The present invention discloses an aqueous phenolates-containing liquid formulation having a solidification point of less than or equal to ?10° C. which is characterized by comprising the following components: a) 50-80% by wt. of one or more phenolates; b) 0.1-10% by wt. of at least one crystallization inhibitor; and water and optionally other components forming the balance.Type: GrantFiled: November 18, 2005Date of Patent: December 18, 2007Assignee: OMYA Development AGInventors: Matthias Buri, Patrick Schwarzentruber
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Patent number: 7297746Abstract: A hardener composition for use as a component of a two component polyurethane coating composition, comprising a polyisocyanate, a catalyst for promoting reaction of the polyisocyanate with a reactive hydrogen compound, and one or more antioxidants selected from: a first antioxidant comprising one or more of sterically hindered phenol antioxidants and secondary aryl amine antioxidants, and a second antioxidant comprising one or more organophosphite antioxidant, exhibits improved color stability.Type: GrantFiled: July 14, 2004Date of Patent: November 20, 2007Assignee: Rhodia Inc.Inventors: Richard Rosen, Jean-Marie Bernard, Shiming Wo, Corinne Simone Duffy
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Patent number: 7256214Abstract: Each of an antioxidant, an antimicrobial agent, an antitumor agent, a food and beverage product, cosmetics, a quasi-drug and a pharmaceutical of the present invention contains a new flavanone compound represented by the following structural formula: Alternatively, each of an antioxidant, an antimicrobial agent, an antitumor agent, a food and beverage product, cosmetics, a quasi-drug and a pharmaceutical of the present invention contains at least one flavanone compound selected from the group consisting of nymphaeol-A, nymphaeol-B, and nymphaeol-C.Type: GrantFiled: June 18, 2004Date of Patent: August 14, 2007Assignee: Pokka CorporationInventors: Shigenori Kumazawa, Tsutomu Nakayama, Kayoko Shimoi, Takaki Goto, Syuichi Fukumoto, Tsutomu Arakaki
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Patent number: 7247658Abstract: Surprisingly effective additive formulations for the reduction of highly undesirable yellowing or other discoloration of white, uncolored, polyurethane foam articles are provided. White polyurethane foam exhibits a susceptibility to yellowing and discoloration to a great extent, particularly in relatively short periods of time, than other types of polymeric articles. The inventive additives impart excellent low-discoloration properties over appreciable amounts of time of regular exposure to harmful elements, thereby according the pertinent industry a manner of providing white polyurethane foams for longer periods of time. Methods of producing such reliably white-colored polyurethane foams are also provided.Type: GrantFiled: July 8, 2003Date of Patent: July 24, 2007Assignee: Milliken & CompanyInventors: Mark E. Ragsdale, Philip T. Radford
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Patent number: 7199181Abstract: A stabilizer composition is described and comprises a 2-cyano-3,3-diarylacrylate, a sterically hindered monomeric amine, a sterically hindered phenol and, where appropriate, a chromane derivative and/or an organic phosphite and/or phosphonite. The stabilizer composition is particularly suitable for stabilizing thermoplastic polyurethane with respect to light, oxygen, and heat.Type: GrantFiled: December 13, 2002Date of Patent: April 3, 2007Assignee: BASF AktiengesellschaftInventors: Thomas Heidenfelder, Manfred Appel
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Patent number: 7196135Abstract: A stabilizer composition is described and comprises a 3-arylacrylate, a polymeric compound with molecular weight at least 2000, bearing, on a polymeric framework, side groups having amine functions, where all of the substituents in the ?-position to the amine nitrogen atom are other than hydrogen, and comprises a sterically hindered phenol. The stabilizer composition is particularly suitable for stabilizing thermoplastic polyurethane with respect to light, oxygen, and heat.Type: GrantFiled: December 13, 2002Date of Patent: March 27, 2007Assignee: BASF AktiengesellschaftInventors: Thomas Heidenfelder, Manfred Appel
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Patent number: 7083743Abstract: The invention relates to a synergistic mixture comprising a) at least one compound from the group which consists of the phosphanes of the formula (I), (di/oligo)phosphanes of the formulae (II) and (III) and cyclophosphanes of the formula (IV) and b) at least one 6-hydroxychromane derivative of the general formula (V) and also to a process which stabilizes polymers with respect to thermooxidative degradation by addition and incorporation of this synergistic mixture.Type: GrantFiled: December 18, 2000Date of Patent: August 1, 2006Assignee: Clariant Finance (BVI) LimitedInventors: Christoph Kröhnke, Peter Staniek
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Patent number: 7081213Abstract: A stabilizer mixture for one or more compounds of the general formula (1) and (1A) but preferably (1), wherein the groups R independently stand for an alkyl-, cycloalkyl-, aralkyl- or aryl-rest whereas the aromatic ring system may be optionally substituted by one or more groups R? which may be identical or different and which groups R? can be an aryl-, a saturated or unsaturated alkyl-, aralkyl- or cycloalkyl-group as well as halogen, an amino-, aminoalkyl-, aminocycloalkyl-, cyano-, thiocyano- or nitrogroup. and a UV-absorber, hindered amine stabilizer, sterically hindered phenol, organophosphite, organophosphonite, organophosphine, or mixtures thereof. The present invention is useful in the protection of various polymeric substrates against the damaging influence of light exposure by the long term storage of polymers. This effect can be observed especially in so-called engineering plastics (such as, for example, PC, PET, PBT, ABS, TPU).Type: GrantFiled: May 14, 2002Date of Patent: July 25, 2006Assignee: Clariant Finance (BVI) LimitedInventors: Christoph Krōhnke, Joseph R. Webster, Ernst Gronmaier, Lajos Avar
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Patent number: 7074907Abstract: The compound of the present invention is a component originated from a natural material, camu camu (Myrciaria dubia), has strong antioxidative activity and stable whitening effect, and is represented by the formula (1).Type: GrantFiled: December 24, 2003Date of Patent: July 11, 2006Assignee: Nichirei Biosciences Inc.Inventors: Kenichi Nagamine, Miki Hayashi, Kaori Yamasaki
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Patent number: 7074459Abstract: A method for preserving wood which comprises contacting the wood with a complex of a cationic monomeric or polymeric biocide and an anionic monomeric or polymeric biocide. Insoluble complexes may solubilized in water in the form of an emulsion or microemulsion by adding a nonionic and/or amphoteric surfactant and/or aqueous cosolvent to the complex. Suitable cationic biocides are those that contain functionalities such as amidine, guanidine, biguanide, quaternary, phosphonium, sulfonium and gemini quaternary functionalities. Suitable anionic biocides include: phenolics; saturated, unsaturated or substituted carboxylates; organomercaptide; tetrathiocarbonates; cyanodithioimidocarbamates; dithiodialkylcarbamates; anionic oxides of transition metals; aminocarboxylic acids; aminoorganophosphonic acids; monoalkyl phosphates; dialkylphosphates; and substituted or unsubstituted 2-hydroxy-2,4,6-cycloheptatrianone.Type: GrantFiled: May 23, 2003Date of Patent: July 11, 2006Inventor: Richard F. Stockel
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Patent number: 7026438Abstract: The invention relates to liquid sulphur-containing antioxidants and to compositions comprising them. The novel lubricant compositions comprise the reaction product of a selected group of 5-tert-butyl-4-hydroxy-3-methyl(or tert-butyl)phenyl substituted carboxylic acid esters with thiodiethylene glycol and a mono-hydroxy alcohol with a carbon chain length higher than 4 C-atoms. The novel lubricant compositions are highly resistant to oxidative degradation and are capable of reducing the negative effects of deposits, such as black sludge, in motor combustion engines, particularly spark ignition internal combustion engines.Type: GrantFiled: November 26, 2003Date of Patent: April 11, 2006Assignee: Ciba Specialty Chemicals Corp.Inventors: Hugo Camenzind, Paul Dubs, Roger Martin, David Eliezer Chasan, Gunnar Demme, James Robbins
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Patent number: 6995230Abstract: The invention relates to stabilizers containing at least two phenolic groups bonded to one another via a connecting radical (II) which is a polyol with a number-average molecular weight of from 75×F g/mol to 250×F g/mol, preferably from 100×F g/mol to 200×F g/mol, in particular from 100×F g/mol to 150×F g/mol, where the term F is the number of phenolic groups in the molecule.Type: GrantFiled: July 4, 2001Date of Patent: February 7, 2006Assignee: BASF AktiengesellschaftInventors: Hauke Malz, Thomas Flug, Peter Böhme, Markus Kamieth