Phenol Or Quinone Radical Containing Patents (Class 252/404)
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Patent number: 6024894Abstract: Synergistic composition and method of use are disclosed. The compositions comprise a quinone methide derivative and a hydroxylamine compound. These compositions demonstrate synergism at inhibiting the polymerization of a vinyl aromatic monomer. Preferably the quinone methide derivative is 2,6-di-tert-butyl-4-benzylidene-cyclo-2,5-dienone and the hydroxylamine compound is N,N-bis(hydroxypropyl)hydroxylamine.Type: GrantFiled: March 25, 1998Date of Patent: February 15, 2000Assignee: BetzDearborn Inc.Inventor: Graciela B. Arhancet
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Patent number: 6001786Abstract: The present invention relates generally to substantially liquid, chlorine-free, sulfur-bridged phenols useful as antioxidants and more specifically to the preparation of a substantially liquid, chlorine-free, sulfur-bridged, hindered phenol compositions, using 1-propanol as the reaction solvent, which are effective antioxidant(s) in lubricating oils and liquid organic fuels without causing excessive copper corrosion and which exhibit improved elastomer seal compatibility. The invention also includes lubricating oils and liquid organic fuels containing an antioxidant additive of the present invention, as well as a method of reducing oxidation in the lubricating oil or liquid organic fuel used in a machine such as an internal combustion engine.Type: GrantFiled: February 19, 1997Date of Patent: December 14, 1999Assignee: Ethyl CorporationInventors: Vincent James Gatto, Abbas Kadkhodayan
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Patent number: 6001794Abstract: The present invention relates to the use of a liquid composition comprising a peroxygen bleach and a radical scavenger or mixtures thereof, for pretreating soiled fabrics before said fabrics are washed, for reducing the loss of tensile strength in said fabrics and/or for reducing the color damage of said fabrics. The present invention further encompasses a liquid composition suitable for pretreating soiled fabrics, said composition comprising a peroxygen bleach and a radical scavenging system.Type: GrantFiled: March 26, 1998Date of Patent: December 14, 1999Assignee: The Procter & Gamble CompanyInventors: Valerio Del Duca, Carlo Ricci, Marina Trani
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Patent number: 5998330Abstract: A method of treating vegetation by application of a microbial insecticide in which a quinone has been covalently bonded to the viral occlusion body surface of the microbial insecticide in order to improve the UV stability of the microbial insecticide by forming a protective shield around the pathogen.Type: GrantFiled: February 21, 1997Date of Patent: December 7, 1999Assignee: The Board of Trustees of the University of ArkansasInventor: Gary W. Felton
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Patent number: 5948926Abstract: A method for inhibiting the oxidation of oils and fats or fatty acids which comprises adding an antioxidant and an oxyacid having an average particle size of 200 .mu.m or less to said oils and fats or fatty acids. According to this method, the oxyacid is easily dispersed or dissolved in said oils and fats or fatty acids, and the oxidation inhibiting effect is remarkably improved without deteriorating the quality of the oils and fats or fatty acids.Type: GrantFiled: February 7, 1995Date of Patent: September 7, 1999Assignees: NOF Corporation, Shiseido Company, Ltd.Inventors: Hiroyuki Takeo, Masaaki Sugino, Hideto Yamamoto, Takeshi Matsuo, Yoshihiro Ohhata, Isao Takayanagi
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Patent number: 5944880Abstract: A wood preservative composition comprising a biocide such as a quaternary ammonium compound, e.g., didecyl-dimethyl ammonium chloride (DDAC), an isothiazolone or an isophthalonitrile, in combination with an antioxidant, e.g., a flavone or a phenol, is useful as a cost-effective and environmentally safe wood preservative. The invention also provides a method for the use of such composition and compositions so treated.Type: GrantFiled: January 26, 1998Date of Patent: August 31, 1999Assignee: Mississippi State UniversityInventors: Tor P. Schultz, Darrel D. Nicholas
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Patent number: 5932142Abstract: A process for preparing benzotriazolyl-alkylene bisphenol compounds which comprises reacting a 2-hydroxyphenylbenzotriazole and a 2,4-substituted phenol with an aldehyde in the presence of a basic catalyst and an amine compound; benzotriazolyl-alkylene bisphenol compounds obtained by the process; and stabilized organic materials containing the resulting benzotriazolyl-alkylene bisphenol compounds in an amount of 0.01-10 percent by weight. It is possible to prepare the benzotriazolyl-alkylene bisphenol compounds at a high yield, and organic materials can be effectively stabilized with the resulting compounds.Type: GrantFiled: December 8, 1997Date of Patent: August 3, 1999Assignee: Johoku Chemical Co., Ltd.Inventors: Toshiyuki Yamauchi, Eisuke Kanagawa, Hideo Aoki, Kazuyuki Ishihara
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Patent number: 5914418Abstract: A method for inhibiting polymerization of acrylic-functional silanes comprising forming a mixture comprising an acrylic-functional silane and a polymerization inhibitor described by formula ##STR1## where n is 0 or 1; M is an atom selected from a group consisting of N, P, As, Sb, O, S, Se, Sn, and I; R is an independently selected monovalent hydrocarbon group or hydrogen atom; m is 1, 2, or 3; and X is a conjugate base of an organic acid or inorganic acid.Type: GrantFiled: April 15, 1997Date of Patent: June 22, 1999Assignee: Dow Corning Toray Silicone Co., Ltd.Inventors: Ryuzo Mikami, Tadashi Okawa
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Patent number: 5891905Abstract: Disclosed and claimed are cocoa extracts such as polyphenols or procyanidins, methods for preparing such extracts, as well as uses for them, especially as antineoplastic agents and antioxidants. Disclosed and claimed are antineoplastic compositions containing cocoa polyphenols or procyanidins and methods for treating patients employing the compositions. Additionally disclosed and claimed is a kit for treating a patient in need of treatment with an antineoplastic agent containing cocoa polyphenols or procyanidins as well as a lyophilized antineoplastic composition containing cocoa polyphenols or procyanidins. Further, disclosed and claimed is the use of the invention in antioxidant, preservative and topiosomerase-inhibiting compositions and methods.Type: GrantFiled: April 14, 1997Date of Patent: April 6, 1999Assignee: Mars, IncorporatedInventors: Leo J. Romanczyk, Jr., John F. Hammerstone, Jr., Margaret M. Buck
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Patent number: 5886241Abstract: The polymerization of an ethylenically unsaturated monomer such as isoprene, butadiene and acrylonitrile is inhibited during storage or handling thereof by the addition of a dihydroxycinnamic acid or derivative thereof.Type: GrantFiled: April 21, 1998Date of Patent: March 23, 1999Assignee: BetzDearborn Inc.Inventor: Graciela B. Arhancet
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Patent number: 5846656Abstract: A stabilizing system for stabilizing polymeric materials against ultraviolet light and thermooxidative deterioration is provided in which the stabilizing system is in pellet form. The pellet is formed from a substantially dry homogeneous mixture of at least one stabilizer and an agent which will prevent melting of the stabilizer. The stabilizer compound makes up about 50% to about 98% by weight of the mixture. The stabilizers are antioxidants (such as phosphites and hindered phenols) or hindered amine UV light stabilizers, or combinations thereof. The melt preventing agent may be a compound derived from a fatty acid or a fatty alcohol, or a fatty acid or a fatty alcohol, or a combination of fatty acids or fatty alcohols which makes up about 3%-10% of the homogeneous mixture. The fatty acids, fatty alcohols, and the compounds derived therefrom preferably have a low melting point in the range of 50.degree.-100.degree. C. and preferably between 50.degree. C. and about 80.degree. C.Type: GrantFiled: April 10, 1997Date of Patent: December 8, 1998Assignee: Ciba Specialty Chemicals CorporationInventor: Neil Dunski
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Patent number: 5807503Abstract: A liquid concentrate comprises between about 4 and about 25 wt % of 4,5-dichloro-2-(n-octyl-4-isothiazolin-3-one), between about 25 and about 88 wt % of a plasticizer in which said isothiazolinone compound is soluble and between about 8 and about 50 wt % of benzyl alcohol which stabilizes the concentrate against crystallization and/or freezing at sub-freezing conditions.Type: GrantFiled: September 8, 1997Date of Patent: September 15, 1998Assignee: Morton International, Inc.Inventors: Nuno M. Rei, Roger G. Hamel, Thomas C. McEntee
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Patent number: 5795499Abstract: Polymers are stabilized against degradation by the addition of a liquid composition comprising an organic solvent and at least 40% by weight of a triaryl triazine of the formula (I): ##STR1## wherein X, Y, and Z are each the same or different aromatic carbocyclic radicals, and at least one of X, Y, and Z is substituted by a hydroxy group ortho to the point of attachment to the triazine ring, and at least one of R1 to R9 is an alkoxy radical of the formula, --O-(mixed alkyl) substituted at a point para to the point of attachment to the triazine ring, and the remainder of R1 to R9 are selected from the group consisting of hydrogen, hydroxy, alkyl, alkoxy, sulfonic, carboxy, halo, haloalkyl, and acylamino; with the proviso that --O-(mixed alkyl) is an alkoxy radical formed from an mixture of isomeric C.sub.6 to C.sub.12 alkyl halides containing at least 10% each of at least three different isomers.Type: GrantFiled: May 31, 1995Date of Patent: August 18, 1998Assignee: Cytec Technology Corp.Inventor: Paul Sheldon Waterman
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Patent number: 5772909Abstract: Vanillin is difficult to separate from second organic chemicals produced therewith such as parahydroxybenzaldehyde by conventional distillation or rectification because of the proximity of their boiling points. Vanillin can now be readily separated from such second organic chemicals by azeotropic distillation using as an effective azeotropic distillation agent, dibenzyl ether.Type: GrantFiled: November 2, 1995Date of Patent: June 30, 1998Assignee: International Flavors & Fragrances Inc.Inventors: Thomas Jones, Jeffrey L. Finnan, Joseph Arvizzigno
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Patent number: 5773674Abstract: The polymerization of a vinyl aromatic monomer such as styrene is inhibited by the addition of a composition of a benzoquinone derivative and a hydroxylamine compound.Type: GrantFiled: December 31, 1996Date of Patent: June 30, 1998Assignee: BetzDearborn Inc.Inventors: Graciela B. Arhancet, Inge K. Henrici
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Patent number: 5772921Abstract: The present invention relates to synergistic mixtures of at least one 2,4-dimethyl-6-s-alkyl phenol and at least one selected sterically hindered phenol according to formula II ##STR1## The variable "n" is 1, 2 or 4. X.sub.1 is tert-butyl. X.sub.2 is C.sub.1 -C.sub.4 alkyl. X.sub.3, when n is 1, is C.sub.1 -C.sub.20 alkyl, a triazinylamino group, or a --A.sub.1 --COO--A.sub.2 or --A.sub.1 --CONH--A.sub.2 group. X.sub.3, when n is 2, is a --E.sub.1 --COO--E.sub.2 --OOC--E.sub.3 -- or --E.sub.1 --CONH--E.sub.2 --NHCO--E.sub.3 -- group. X.sub.3, when n is 4, is ?--G.sub.1 --COO!.sub.4 --G.sub.2. The instant synergistic mixtures can be used to stabilize selected organic polymers against thermal, oxidative and/or actinic degradation.Type: GrantFiled: January 29, 1997Date of Patent: June 30, 1998Assignee: Ciba Specialty Chemicals CorporationInventors: Bernard Gilg, Kurt Stinsky
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Patent number: 5767271Abstract: Lignan glycosides having a hydroxy radical scavenging activity and represented by the formula: ##STR1## where R is a glycosyl residue selected from the group consisting of glucose, galactosr and fructose, m is an integer of 1 to 3, and n is 0 or 1.Type: GrantFiled: December 22, 1995Date of Patent: June 16, 1998Assignee: The Nisshin Oil Mills, Ltd.Inventors: Kenichi Kuriyama, Tateo Murui
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Patent number: 5766548Abstract: Control of formation of heat stable amine salts and of corrosion in an amine solvent treating system is accomplished by introduction of N,N-diethylhydroxylamine catalyzed with hydroquinone into the system. The catalyzed N,N-diethylhydroxylamine is effective at the temperature ranges of amine treating systems to effectively reduce formation of heat stable amine salts and to inhibit corrosion. The catalyzed N,N-diethylhydroxylamine is effective in proportions including the range of about 0.5 to about 6 parts N,N-diethylhydroxylamine to 1 part hydroquinone.Type: GrantFiled: March 31, 1997Date of Patent: June 16, 1998Assignee: Cata Chem Inc.Inventor: John Soria
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Patent number: 5756870Abstract: The polymerization of an ethylenically unsaturated monomer such as isoprene and butadiene is inhibited during storage or handling thereof by the addition of a dihydroxycinnamic acid or derivative thereof.Type: GrantFiled: May 3, 1996Date of Patent: May 26, 1998Assignee: BetzDearborn Inc.Inventor: Graciela B. Arhancet
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Patent number: 5730907Abstract: A wood preservative composition comprising a biocide such as a quaternary ammonium compound, e.g., didecyldimethyl ammonium chloride (DDAC), an isothiazolone or an isophthalonitrile, in combination with an antioxidant, which is a flavone or a phenol, is useful as a cost-effective and environmentally safe wood preservative. The invention also provides a method for the use of such composition and compositions so treated.Type: GrantFiled: August 27, 1996Date of Patent: March 24, 1998Assignee: Mississippi State UniversityInventors: Tor P. Schultz, Darrel D. Nicholas
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Patent number: 5726034Abstract: An aglucone is isoflavone enriched vegetable protein extract and protein material are provided, as well as a high genistein content material and a high daidzein content material. Isoflavone conjugates in a vegetable material are converted to isoflavone glucosides by treating the vegetable material at a temperature and a pH for a period of time sufficient to effect the conversion. The isoflavone glycosides are converted to glucose isoflavones by enzymatic reaction. The vegetable material is extracted with an aqueous extractant having a pH above about the isoelectric point of protein in the vegetable material to extract protein and the isoflavones either before or after conversion of the isoflavone conjugates to isoflavone glucosides or the conversion of the isoflavone glucosides to aglucone isoflavones. An aglucone isoflavone enriched protein material is produced by precipitating the protein and aglucone isoflavones from the extract.Type: GrantFiled: September 6, 1996Date of Patent: March 10, 1998Assignee: Protein Technologies International, Inc.Inventors: Barbara A. Bryan, Maryann C. Allred
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Patent number: 5714094Abstract: An antioxidant composition and a process of recovering the same from a gelatinous retentate of spent ground coffee oil, comprising from 20 to 60% wt of complex lipids and from 10 to 75% wt of carboxylic acids 5-hydroxytryptamides, in which the 5-HT are for example those of behenic, arachidic and/or lignoceric acids, and the complex lipids are phospholipids and glycolipids. This composition may be advantageously used in food products.Type: GrantFiled: July 11, 1995Date of Patent: February 3, 1998Assignee: Nestec S.A.Inventors: Raymond Bertholet, Ladislas Colarow, Andrej Kusy, Vincent Rivier
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Patent number: 5663128Abstract: Products are described which can be obtained by reacting components a), b), c) and d), where component a) is a compound of the formula I or a mixture of compounds of the formula I, component b) is a compound of the formula II or a mixture of compounds of the formula II, component c) is a compound of the formula III or a mixture of compounds of the formula III and component d) is a compound of the formula IV or a mixture of compounds of the formula IV, ##STR1## in which the general symbols are as defined in claim 1, the compound of the formula I being, for example, pentaerythritol, thiodiethylene glycol, 1,4-butanediol, 1,2-propanediol, diethylene glycol, triethylene glycol, diethanolamine or glycerol, the compound of the formula II being, for example, sunflower oil or coconut fat, the compound of the formula III being, for example, methyl 3-(3',5'-di-tert-butyl-4'-hydroxyphenyl)propionate and the compound of the formula IV, being for example, sulfur or diisopropyl dithiophosphate.Type: GrantFiled: September 19, 1994Date of Patent: September 2, 1997Assignee: Ciba-Geigy CorporationInventors: Samuel Evans, Paul Dubs, Hugo Camenzind
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Patent number: 5641475Abstract: Therapeutic treatment as well as prophylactic measures are provided by topical application of compositions containing an aryl 2-acetoxyethanoic acid to eradicate or prevent the development of axillary foul odor, foot malodor and other body odors, e.g. scalp, and skin, nail and follicular infections caused by microorganisms. The compositions are antimicrobial against several organisms that infect the skin and are specifically effective against P. acnes. The compositions are therapeutically effective against folliculitis and perifolliculitis and are useful for other skin lesions, nail and mucosal infections such as impetigo, seborrheic dermatitis, erythrasma and trichomycosis axillaris, associated with or caused by microorganisms. The therapeutic effect of the composition may be synergized or amplified by incorporating a cosmetic or dermatologic agent into the formulation for topical treatment of cosmetic and dermatologic indications.Type: GrantFiled: November 1, 1994Date of Patent: June 24, 1997Assignee: TriStrata, Inc.Inventors: Ruey J. Yu, Eugene J. Van Scott
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Patent number: 5616780Abstract: The novel compounds of the formula I ##STR1## in which A is a group of the formula IIa or IIb, ##STR2## Y is oxygen, methylene, ethylidene or a >C.dbd.C(CH.sub.3).sub.2 group, Z is nitrogen, ##STR3## R.sub.1 and R.sub.2 are, for example C.sub.1 -C.sub.5 alkyl, R.sub.3 and R.sub.4 are, for example, hydrogen or methyl, and R.sub.5, R.sub.6, R.sub.7, R.sub.8, R.sub.9, R.sub.10, R.sub.11, R.sub.12, R.sub.13 and R.sub.14 are, for example, hydrogen, are suitable for stabilizing organic material against oxidative, thermal or light-induced degradation.Type: GrantFiled: January 31, 1996Date of Patent: April 1, 1997Assignee: Ciba-Geigy CorporationInventors: Rita Pitteloud, Bernard Gilg
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Patent number: 5614648Abstract: A method of producing an antioxidant containing derivatives of an organic compound, and in particular, an antioxidant glyceride derivative, comprises reacting a first compound with a second medium. By this reaction, a product is formed whereby an active component of the first compound, e.g., an antioxidant moiety, is covalently incorporated into the second medium.The second medium comprises glyceride derivatives, silicones, fluorocarbons and alkoxylates containing reactive groups such as hydroxy, amino, carboxyl, ester, or amides.Type: GrantFiled: January 10, 1995Date of Patent: March 25, 1997Inventors: George H. Greene, Robert Miller, James L. Williams, James C. Phillips, Jerry F. Stults, Jan P. E. Tellings
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Patent number: 5612142Abstract: Wood and other cellulose-based products are preserved with a water-based treating solution containing a phenolic resin prepolymer such as phenol formaldehyde resin prepolymer, a resorcinol formaldehyde resin prepolymer and water. The treatment is carried out by exposing the wood or other cellulose-based product, while submerged in the treating solution, to one or more cycles of reduced pressure (i.e. vacuum) and elevated pressure.Type: GrantFiled: October 23, 1995Date of Patent: March 18, 1997Assignee: Polymer Wood Processors, Inc.Inventor: Jean Lewis, deceased
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Patent number: 5603866Abstract: A composition comprising A) an aqueous solution wherein the total content of 3-isothiazolinones is below 8 wt/%, and B) a stabilizing compound of the formula:[R.sub.x A--C.sub.6 H.sub.2 R.sup.1 R.sup.2 ].sub.y --Zwherein:R, R.sup.1 and R.sup.2 each independently represents hydrogen, a straight-chained or branched or cyclic alkyl radical, aralkyl or aryl;A is oxygen or nitrogen;Z represents AR.sub.x, R.sup.1, R.sup.2, alkoxy methylene, methylene or alkylidene;provided that when A is oxygen, x is 0 or 1 and when A is nitrogen, x is 1 or 2; and y is 1 or 2;exhibits improved stability.Type: GrantFiled: May 17, 1995Date of Patent: February 18, 1997Assignee: Bromine Compounds, Ltd.Inventors: Jeane Segall, Leonard M. Shorr
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Patent number: 5601756Abstract: Liquid UV stabilizers which are stable at room temperatures or below made from di-substituted and tri-substituted benzophenone compositions. A process to render di-substituted and tri-substituted benzophenone admixtures stable liquids at room temperatures or below involving heating the admixture to a temperature in the range of 80.degree.-175.degree. C. for a period of time sufficient that when the admixture is cooled to room temperature the admixture remains liquid.Type: GrantFiled: August 23, 1995Date of Patent: February 11, 1997Inventor: John V. Swearengin
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Patent number: 5594055Abstract: A phosph(on)ite free antioxidant system based on an .alpha.-tocopherol formulation and a compound selected from tetrakis[methylene(3,5-di-tert.-4-hydroxyhydrocinnamate]methane or octadecyl 3,5-di-tert.-4-hydroxyhydrocinnamate is disclosed. This system can replace phenolic/phosphite combinations as the primary system, or simply replace the phosphite portion, to achieve certain optimum performance requirements. In either case, the problems associated with phosph(on)ites can be eliminated or minimized.Type: GrantFiled: February 22, 1995Date of Patent: January 14, 1997Assignee: Hoffmann-La Roche Inc.Inventor: Sai-Shek Young
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Patent number: 5575952Abstract: An article of manufacture comprising (i) a plurality of electrical conductors, each surrounded by one or more layers of a composition comprising (a) one or more polyolefins and, blended therewith, (b) a mixture containing one or more alkylhydroxyphenylalkanoyl hydrazines and one or more functionalized hindered amines; and (ii) hydrocarbon cable filler grease within the interstices between said surrounded conductors.Type: GrantFiled: October 28, 1994Date of Patent: November 19, 1996Assignee: Union Carbide Chemicals & Plastics Technology CorporationInventors: Michael J. Keogh, Geoffrey D. Brown
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Patent number: 5571453Abstract: A stabilizer composition useful as an additive for polyether polyols, particularly those employed in the manufacture of polyurethane foams, is provided which comprises a diphenylamine:isobutylene:diisobutylene reaction product, a sterically hindered phenol and a trihydrocarbyl phosphite.Type: GrantFiled: October 25, 1994Date of Patent: November 5, 1996Assignee: Uniroyal Chemical Company, Inc.Inventors: Lawrence B. Barry, Mark C. Richardson
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Patent number: 5567751Abstract: Disclosed are homogeneous liquid stabilizer for polyvinyl chloride formulations and which exhibit a reduced tendency to form precipitates, comprising an aromatic ether alcohol, an alkyl or dialkyl phenol, and an admixture of alkyl tin compounds including butyltin alkyl mercaptides, butyltin hydroxyethyl mercaptides and compounds which are dibutyltin sulfides and/or monobutyltin sulfides.Type: GrantFiled: June 1, 1995Date of Patent: October 22, 1996Assignee: Witco CorporationInventor: Samuel Hoch
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Patent number: 5562863Abstract: Vinyl aromatic monomer polymerization methods utilizing a composition of 2,6-di-tert-butyl-4-methylphenol and a substituted benzoquinonediimide compound are disclosed. Preferably, the composition is employed in an amount of 1 part to 10,000 parts per million parts monomer during distillation of styrene.Type: GrantFiled: July 18, 1995Date of Patent: October 8, 1996Assignee: Betz Laboratories, Inc.Inventor: Graciela B. Arhancet
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Patent number: 5543083Abstract: The present invention relates to non-surface staining, light stable antioxidant compounds which reduce the fading, decoloration and degradation of various surfaces, ie., fabrics, from sunlight. These antioxidant compounds are butylated hydroxytoluene and sorbic acid derivatives, containing at least one C.sub.8 -C.sub.22 hydrocarbon fatty amine organic moiety and are either solid materials having a melting point of less than about 80.degree. Celsius, or are liquids at a temperature of less than about 40.degree. Celsius.Type: GrantFiled: July 26, 1994Date of Patent: August 6, 1996Assignee: The Procter & Gamble CompanyInventors: Mark R. Sivik, John C. Severns
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Patent number: 5540861Abstract: This invention relates to a blend of different isomers of a compound represented by structure I ##STR1## wherein R is C.sub.9 -C.sub.20 alkyl; wherein Y is NO.sub.2 or SO.sub.3 R' or H; wherein R' is C.sub.1 -C.sub.20 alkyl; wherein X is NO.sub.2 or C.sub.1 -C.sub.20 alkyl; and wherein R" is H or C.sub.1 -C.sub.20 alkyl, m is 2 or 3, and n is 0, 1, 2, 3, with the provisos: (1) that Y may not be H and X may not be NO.sub.2 when n=0 and (2) that when R is C.sub.9 and n=0, X and Y may not both be NO.sub.2.Type: GrantFiled: February 14, 1994Date of Patent: July 30, 1996Assignee: Uniroyal Chemical Company, Inc.Inventors: Anthony V. Grossi, Paul E. Stott, John M. DeMassa, Howard S. Friedman, Gerald J. Abruscato
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Patent number: 5534487Abstract: The present invention provides a method of stabilizing solutions of 3-isothiazolone compounds using a stabilizing compound of the formula: ##STR1## wherein R is C.sub.1 -C.sub.6 alkyl; and compositions which comprise 3-isothiazolone compound, solvent and stabilizing compound.Type: GrantFiled: May 16, 1995Date of Patent: July 9, 1996Assignee: Rohm and Haas CompanyInventor: Kevin F. Gironda
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Patent number: 5523020Abstract: A clathrate compound composed of a water-soluble microbicide and a phenolic compound of formula (1) or (2): ##STR1##Type: GrantFiled: September 20, 1994Date of Patent: June 4, 1996Assignee: Kurita Water Industries Ltd.Inventors: Minoru Yagi, Kazumi Nakane, Yuriko Hiyane
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Patent number: 5514727Abstract: This invention relates to vinyl ether-based coatings for which properties such as color stability, thermal stability, mechanical stability, hydrolyric stability, and resistance to embrittlement may be maintained and properties hydrogen generation and blocking are minimized. The invention also relates to stabilizers which control these properties in the coatings.Type: GrantFiled: July 13, 1994Date of Patent: May 7, 1996Assignee: AlliedSignal Inc.Inventors: George D. Green, James R. Snyder, Raymond J. Swedo
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Patent number: 5498344Abstract: A liquid concentrate comprises between about 4 and about 25 wt % of an isothiazolinone compound or mixture of isothiazolinone compounds between about 25 and about 88 wt % of a plasticizer in which said isothiazolinone compound is soluble and between about 8 and about 50 wt % of a C.sub.6 -C.sub.12 monoalkylphenol(s) which stabilizes the concentrate against crystallization and/or freezing at sub-freezing conditions.Type: GrantFiled: February 2, 1995Date of Patent: March 12, 1996Assignee: Morton International, Inc.Inventors: Nuno M. Rei, Roger G. Hamel
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Patent number: 5491178Abstract: This invention relates to vinyl ether-based coatings for which properties such as color stability, thermal stability, mechanical stability, hydrolytic stability, and resistance to embrittlement may be maintained and properties hydrogen generation and blocking are minimized.Type: GrantFiled: August 19, 1994Date of Patent: February 13, 1996Assignee: AlliedSignal Inc.Inventors: Raymond J. Swedo, George D. Green, James R. Snyder
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Patent number: 5478875Abstract: Products are described which can be obtained by reacting components a), b) and c), where component a) is a compound of the formula I or a mixture of compounds of the formula I, component b) is a compound of the formula II or a mixture of compounds of the formula II and component c) is a compound of the formula III or a mixture of compounds of the formula III, ##STR1## in which the general symbols are as defined in claim 1, the compound of the formula I being, for example, pentaerythritol, thiodiethylene glycol, 1,4-butanediol, 1,4-propanediol, diethylene glycol, triethylene glycol, diethanolamine or glycerol, the compound of the formula II being, for example, sunflower oil or coconut fat, and the compound of the formula III being, for example, methyl 3-(3',5'-di-tert-butyl-4'-hydroxyphenyl)propionate. The abovementioned products can be used as liquid antioxidants in polymers and lubricants.Type: GrantFiled: April 1, 1993Date of Patent: December 26, 1995Assignee: Ciba-Geigy CorporationInventors: Paul Dubs, Roger Martin, Samuel Evans
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Patent number: 5427701Abstract: Novel compositions are described which comprises an elastomer or a lubricant and at least one compound of the formulae I or II ##STR1## The symbols R.sub.1, R.sub.2, R.sub.3, Z.sub.1 and Z.sub.2 are as defined in claim 1.The compounds of the formula II and some of the compounds of the formula I are novel, and they are used especially as antioxidants.Type: GrantFiled: July 14, 1994Date of Patent: June 27, 1995Assignee: Ciba-Geigy CorporationInventors: Hans R. Meier, Samuel Evans, Paul Dubs
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Patent number: 5417888Abstract: A method for producing a relatively low viscosity tannin extract from bark and/or wood and suitable for use in formaldehyde-condensation adhesives comprises providing tannin extract obtained from bark and/or wood, separating from the tannin extract the high molecular weight material, subjecting the high molecular weight material to treatment with one or more sulphite compounds to reduce the molecular weight and recombining the sulphited material with the tannin extract. The tannin extract may be recovered by subjecting bark and/or wood to a first stage hot aqueous tannin extraction process, thereby obtaining a first stage tannin extract, subjecting the extracted bark and/or wood to a second stage hot aqueous extraction process at a higher pH than the first stage, thereby obtaining a second stage tannin extract, and optionally recombining the first and second stage tannin extracts.Type: GrantFiled: January 24, 1994Date of Patent: May 23, 1995Assignee: Commonwealth Scientific and Industrial ResearchInventors: Peter J. Collins, Yoshikazu Yazaki
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Patent number: 5380890Abstract: A method of producing an antioxidant containing compound, and in particular, an antioxidant glyceride derivative, comprises reacting a first compound with a second medium. By this reaction, a product is formed whereby an active component of the first compound, e.g., the antioxidant, is covalently incorporated into the second medium.The second medium comprises glyceride derivatives, silicones, fluorocarbons and alkoxylates containing reactive groups such as hydroxy, amino, carboxyl, ester, or amides.Type: GrantFiled: November 27, 1991Date of Patent: January 10, 1995Inventors: George H. Greene, Robert Miller, James L. Williams, James C. Phillips, Jerry F. Stults, Jan P. E. Tellings
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Patent number: 5376290Abstract: Novel compositions are described which comprise an elastomer or a lubricant and at least one compound of the formulae I or II ##STR1## The symbols R.sub.1, R.sub.2, R.sub.3, Z.sub.1 and Z.sub.2 are as defined in claim 1.The compounds of the formula II and some of the compounds of the formula I are novel, and they are used especially as antioxidants.Type: GrantFiled: October 18, 1991Date of Patent: December 27, 1994Assignee: Ciba-Geigy CorporationInventors: Hans R. Meier, Samuel Evans, Paul Dubs
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Patent number: 5356976Abstract: Compounds of formula I ##STR1## wherein R.sub.1 is C.sub.1 -C.sub.4 n-alkyl, isopropyl, s-butyl, cyclopentyl, cyclohexyl or .alpha.-methylbenzyl, R.sub.2 is C.sub.4 -C.sub.18 tert-alkyl or .alpha.,.alpha.-dimethylbenzyl, R.sub.3 is C.sub.1 -C.sub.28 alkyl, and R.sub.4 s methyl or ethyl, with the proviso that the --CHR.sub.3 R.sub.4 group contains at least 4 carbon atoms, are suitable for stabilizing organic material which is susceptible to degradation induced by heat, oxidation or actinic light.Type: GrantFiled: July 12, 1993Date of Patent: October 18, 1994Assignee: Ciba-Geigy CorporationInventors: Paul Dubs, Rita Pitteloud
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Patent number: 5338478Abstract: A stabilizer composition useful as an additive for polyether polyols, particularly those employed in the manufacture of polyurethane foams, is provided which comprises a diarylamine, a sterically hindered phenol and a pentaerythritol diphosphite.Type: GrantFiled: July 27, 1993Date of Patent: August 16, 1994Assignee: Uniroyal Chemical Company, Inc.Inventors: Lawrence B. Barry, Mark C. Richardson
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Patent number: 5322872Abstract: Compositions of (a) a salt of a metal and a carboxylic acid having at least 6 carbon atoms and (b) at least one salt of a metal other than the metal of (a) and a carboxylic acid having at least 6 carbon atoms in a fluid medium are stabilized towards storage decomposition and precipitation by incorporating in the composition (c) a complexing agent such as a ketoxime.Type: GrantFiled: April 14, 1993Date of Patent: June 21, 1994Assignee: The Lubrizol CorporationInventor: Kevin J. Quinn
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Patent number: 5320949Abstract: The present invention relates to an aglucone isoflavone enriched vegetable protein fiber wherein a vegetable protein material is extracted to form a slurry of protein, fiber and glucone isoflavones. The pH of the slurry is adjusted to about 6 to 8 and the slurry reacted with a beta glucosidase to convert the glucone isoflavones in said slurry to aglucone isoflavones. The fiber fraction is then recovered from the slurry by centrifugation or similar means to provide an aglucone enriched fiber.Type: GrantFiled: October 12, 1993Date of Patent: June 14, 1994Assignee: Protein Technologies International, Inc.Inventor: Jerome L. Shen