Titanium Or Zirconium Compound Patents (Class 252/507)
-
Patent number: 11811064Abstract: Provided are processes of preventing or eliminating caking of particulate materials during milling operations. Processes include the addition of an anti-caking additive such as a rosin, abietic acid, fatty acid, or derivative of any of the foregoing to a mill prior to or along with a particulate chemical, and milling the combination. The addition of the anti-caking additive prevents or reduces the amount of caking observed thereby increasing yields and maintaining or enhancing the resulting properties of the milled product.Type: GrantFiled: July 24, 2018Date of Patent: November 7, 2023Assignee: CAMX Power LLCInventor: Jack Treger
-
Patent number: 11616232Abstract: Disclosed is a doped lithium manganese iron phosphate-based particulate for a cathode of a lithium-ion battery. The particulate includes a composition represented by a formula of Mm-LixMn1-y-zFeyM?z(PO4)n/C, wherein M, M?, x, y, z, m, and n are as defined herein. Also disclosed is a powdery material including the particulate, and a method for preparing the powdery material.Type: GrantFiled: December 16, 2019Date of Patent: March 28, 2023Assignee: HCM CO., LTD.Inventors: Chien-Wen Jen, Hsin-Ta Huang, Chih-Tsung Hsu, Yi-Hsuan Wang
-
Patent number: 11575181Abstract: According to one embodiment, a battery includes a container member, a separator, a first electrode, a first electrolyte, a second electrode and a second electrolyte. The container member has a housing space in the interior, and the separator is housed in the housing space of the container member. The separator includes a bag, and the first electrode is housed in an interior of the bag. The first electrolyte is retained on the first electrode in the interior of the bag. The second electrode is located outside the bag in the housing space. The second electrolyte is retained by the second electrode outside the bag in the housing space.Type: GrantFiled: August 26, 2019Date of Patent: February 7, 2023Assignee: KABUSHIKI KAISHA TOSHIBAInventors: Hayato Seki, Yasuyuki Hotta, Shinsuke Matsuno
-
Patent number: 11108042Abstract: A positive electrode composite material for a lithium ion secondary battery that makes it possible to appropriately reduce the electric resistance in a positive electrode and to realize a high-performance lithium ion secondary battery. The positive electrode composite material to be used in the positive electrode of the lithium ion secondary battery includes a particulate positive electrode active material composed of a lithium composite oxide having a layered crystal structure including at least lithium, and a conductive oxide. Here, a particulate region where primary particles of the conductive oxide are aggregated, and a film-shaped region where the conductive oxide is formed in a film shape adhere to at least a part of the surface of the positive electrode active material. The average particle diameter based on cross-sectional TEM observation of primary particles in the particulate region is equal to or greater than 0.Type: GrantFiled: February 8, 2018Date of Patent: August 31, 2021Assignees: TOYOTA JIDOSHA KABUSHIKI KAISHA, SUMITOMO METAL MINING CO., LTD.Inventors: Daisuke Horikawa, Ryuta Sugiura, Taira Aida, Satoshi Kanada
-
Patent number: 10549996Abstract: Polypropylene-coated functionalized multiwall carbon nanotubes (PP/f-MWNT) comprising functionalized multiwall carbon nanotubes (f-MWNT) in an amount of from about 0.5 wt. % to about 80 wt. %, based on the total weight of the PP/f-MWNT; and polypropylene (PP) in an amount of from about 20 wt. % to about 99.5 wt. %, based on the total weight of the PP/f-MWNT. A method of making PP/f-MWNT comprising (a) contacting pristine multiwall carbon nanotubes (p-MWNT) with nitric acid to produce f-MWNT; (b) contacting at least a portion of the f-MWNT with a first solvent to form a f-MWNT dispersion; (c) contacting PP with a second solvent to form a PP solution; (d) contacting at least a portion of the f-MWNT dispersion with at least a portion of the PP solution to form a PP and f-MWNT suspension; and (e) drying at least a portion of the PP and f-MWNT suspension to form the PP/f-MWNT.Type: GrantFiled: November 29, 2016Date of Patent: February 4, 2020Assignees: GEORGIA TECH RESEARCH CORPORATION, SABIC GLOBAL TECHNOLOGIES B.V.Inventors: Po-Hsiang Wang, Sushanta Ghoshal, Nikhil Verghese, Satish Kumar
-
Patent number: 10205158Abstract: Particulate LMFP cathode materials having high manganese contents and small amounts of dopant metals are disclosed. These cathode materials are made by milling a mixture of precursor materials in a wet or dry milling process. Preferably, off-stoichiometric amounts of starting materials are used to make the cathode materials. Unlike other high manganese LMFP materials, these cathode materials provide high specific capacities, very good cycle life and high energies even at high discharge rates.Type: GrantFiled: October 10, 2017Date of Patent: February 12, 2019Assignee: Dow Global Technologies LLCInventors: Shrikant N. Khot, Deidre A. Strand, Jamie L. Cohen, Thierry Drezen, Steven S. Kaye, Bin Li
-
Patent number: 10149862Abstract: A facile approach is described to prepare monodisperse Fe3O4 and Co3O4 nanoparticles on chemically reduced graphene oxide (rGO) to form nanocomposites by low temperature solution route and MWI method, respectively. These processes are environmentally friendly and convenient compared with previously reported methods. The synthesized nanocomposites were characterized using x-ray diffraction spectroscopy (XRD), raman spectroscopy, scanning electron microscopy (SEM) measurements and UV/Vis absorption spectroscopy. XRD patterns revealed the high crystalline quality of the nanocomposites. SEM micrographs showed the morphology of the rGO nanosheets decorated by Co3O4 and Fe3O4 nanoparticles. UV/Vis study revealed the formation of Fe3O4/rGO and Co3O4/rGO nanocomposites with characteristics absorption maxima. Finally, preliminary results of using the Fe3O4/rGO and Co3O4/rGO composites for efficient killing of Human hepatocytes cancer (HepG2) cell are reported.Type: GrantFiled: November 17, 2015Date of Patent: December 11, 2018Assignee: Alfaisal UniversityInventors: Edreese H Alsharaeh, Faheem Ahmed, Nishat Arshi, Yasmin Mussa, Meshael Alturki, Yazeed Aldawsari, Azmat Khan
-
Patent number: 9786915Abstract: A solid state lithium carbon monofluoride battery includes an anode comprising Li, a solid electrolyte, and a cathode including CFx and LPS. The cathode can also include a carbon compound. The solid electrolyte can include LPS. The LPS can include ?-Li3PS4. The cathode LPS can include ?-Li3PS4. A method of making a battery is also disclosed.Type: GrantFiled: February 27, 2015Date of Patent: October 10, 2017Assignee: UT-BATTELLE, LLCInventors: Chengdu Liang, Ezhiylmurugan Rangasamy
-
Patent number: 9748600Abstract: The present invention relates to a novel phosphate based composite anode material, preparation method and uses thereof. Specifically disclosed is a phosphate based composite cell anode material, the material having monoclinic and orthorhombic crystal lattice structures with the chemical formula of A3?xV2?yMY(PO4)3, wherein A is Li+, Na+ or the mixture thereof, M is Mg, Al, Sc, Ti, Cr, Mn, Fe, Co, Ni, Cu, Zn or Nb, 0?x?3.0, 0?y?2.0, and C is the carbon layer. Also disclosed are a preparation method and uses of the composite material. Unlike simple physical mixing, the composite material of the present invention has the advantages of an adjustable electric potential plateau, high reversible capacity, good cycle stability, power consumption early warning and the like.Type: GrantFiled: September 12, 2012Date of Patent: August 29, 2017Assignee: Ningbo Institute of Materials Technology & Engineering, Chinese Academy of SciencesInventors: Yuanhao Tang, Chenyun Wang, Deyu Wang, Jun Li
-
Patent number: 9692054Abstract: There are provided an electrode material for a lithium ion secondary battery having a high discharge capacity and a high mass energy density at a low temperature or at a high-speed charge and discharge, an electrode for a lithium ion secondary battery, and a lithium ion secondary battery. An electrode material for a lithium ion secondary battery of the present invention includes an electrode active material made of LiFexMn1?x?yMyPO4 (0.220?x?0.350, 0.0050?y?0.018) in which the M is either or both of Co and Zn, the electrode material has an orthorhombic crystal structure, a space group is Pnma, values of crystal lattice constants a, b, and c satisfy 10.28 ??a?10.42 ?, 6.000 ??b?6.069 ?, and 4.710 ??c?4.728 ?, and lattice volume V satisfies 289.00 ?3?V?298.23 ?3.Type: GrantFiled: August 13, 2015Date of Patent: June 27, 2017Assignee: SUMITOMO OSAKA CEMENT CO., LTD.Inventors: Satoru Oshitari, Masataka Oyama, Ryuuta Yamaya
-
Patent number: 9614354Abstract: A resistor element of a spark plug containing ZrO2, wherein a target region is defined by a rectangular region where the size in the direction perpendicular to an axial line is 1800 ?m and the size in the direction of the axial line is 2400 ?m. In the case where the target region is divided into a plurality of square regions having lengths of 200 ?m on a side, a transverse line-shaped region is defined by a region in a line shape that is constituted of nine square regions arranged in the direction perpendicular to the axial line. A first type region is defined by the square region where a proportion of an area of ZrO2 is 25% or more, and a second type region is defined by the square region where a proportion of an area of ZrO2 is less than 25%.Type: GrantFiled: June 2, 2014Date of Patent: April 4, 2017Assignee: NGK SPARK PLUG CO., LTD.Inventors: Haruki Yoshida, Jumpei Kita, Yoshitomo Iwasaki, Toshitaka Honda
-
Patent number: 9576706Abstract: Disclosed is a method for preparing a carbon nanomaterial/polymer composite. More particularly, it relates to an improved method for preparing a carbon nanomaterial/polymer composite capable of solving a dust problem of a carbon nanomaterial powder and a layer separation problem due to large density difference between the carbon nanomaterial powder and a polymer pellet and providing superior physical properties of the composite, whereby an additive used to prepare the carbon nanomaterial/polymer composite is mixed with the carbon nanomaterial powder and prepared into a pellet, which is then mixed with the polymer pellet.Type: GrantFiled: December 21, 2012Date of Patent: February 21, 2017Assignee: KOREA KUMHO PETROCHEMICAL CO., LTD.Inventors: Sang Hyo Ryu, Kwon Ju, Nam Sun Choi, Sang Kyu Choi, Myung Wook Jung, Yu Hyun Song, Young Chan Jang
-
Patent number: 9460827Abstract: Certain exemplary embodiments can provide a graphene hybrid composite (GHC). The GHC can be formed between specific nano carbon materials and graphene generated via pyrolysis of solid carbon sources. A Raman spectrum of the GHC can show a major 2D band at approximately 2650 cm?1, a minor D and G band at approximately 1350 cm?1 and approximately 1575 cm?1, and an intensity ratio of 2D band over D band and G band greater than 1.Type: GrantFiled: October 7, 2013Date of Patent: October 4, 2016Inventors: Nguyen C. Khe, Hieu Dinh, Dien Dinh
-
Patent number: 9238872Abstract: Disclosed is an electrode for electrolytic synthesis of a fluorine compound, including: an electrode substrate having at least a surface thereof formed of a conductive carbon material; a conducting diamond layer formed on a part of the surface of the electrode substrate; and a metal fluoride-containing coating layer formed on an exposed part of the electrode substrate that is uncovered by the conducting diamond layer. It is possible for the electrolytic synthesis electrode to limit the growth of a graphite fluoride layer on the electrode surface, prevent decrease in effective electrolysis area and allow stable electrolysis in an electrolytic bath of a hydrogen fluoride-containing molten salt.Type: GrantFiled: January 27, 2012Date of Patent: January 19, 2016Assignee: Central Glass Company, LimitedInventors: Isamu Mori, Akifumi Yao, Akiou Kikuchi, Masaaki Yonekura, Hiroshi Horiuchi
-
Patent number: 9228100Abstract: There is provided a liquid composition that can form a resistor exhibiting a stable resistance value. One mode of the liquid composition of the invention is a liquid composition comprising (a) an epoxy resin, (b) carbon black particles, (c) carbon nanotubes and (d) a solvent with a vapor pressure of less than 1.34×103 Pa at 25° C.Type: GrantFiled: August 4, 2011Date of Patent: January 5, 2016Assignee: HITACHI CHEMICAL COMPANY, LTD.Inventors: Yasushi Kumashiro, Naoki Maruyama, Maki Inada
-
Publication number: 20150137047Abstract: Provided is a composition comprising a polymeric material, a filler material dispersed in the polymeric material, the filler material comprising inorganic particles and a discontinuous arrangement of conductive material wherein at least a portion of the conductive material is in durable electrical contact with the inorganic particles, and conductive material dispersed in the polymeric material.Type: ApplicationFiled: December 23, 2014Publication date: May 21, 2015Inventors: Andrew C. Lottes, Nanayakkara L.D. Somasiri, Jimmie R. Baran, JR., Badri Veeraraghavan, Paul V. Huynh, Dipankar Ghosh
-
Publication number: 20150132647Abstract: [Problem] Provided is a slurry composition which has an excellent viscosity stability and thus, after being applied to a current collector for an electrode and drying, has an excellent adhesion with the current collector. [Solving Means] A slurry composition which is used for manufacturing an electrode for an electrochemical cell contains a lithium ion, comprising a polymer binder resin, a pH adjusting agent, and an active material, wherein the pH is from 2.0 to 9.0.Type: ApplicationFiled: November 12, 2014Publication date: May 14, 2015Applicant: TAIYO INK MFG. CO., LTD.Inventor: Fumitaka KATO
-
Publication number: 20150132660Abstract: The present invention concerns electrode materials capable of redox reactions by electron and alkali-ion exchange with an electrolyte. The applications are in the field of primary (batteries) or secondary electrochemical generators, supercapacitors and light modulating systems of the electrochromic type.Type: ApplicationFiled: January 22, 2015Publication date: May 14, 2015Inventors: Nathalie Ravet, Simon Besner, Martin Simoneau, Alain Vallee, Michel Armand, Jean-Francois Magnan, Karim Zaghib
-
Publication number: 20150104709Abstract: A cathode active material of the present invention is a cathode active material having a composition represented by General Formula (1) below, LiFe1-xMxP1-ySiyO4??(1), where: an average valence of Fe is +2 or more; M is an element having a valence of +2 or more and is at least one type of element selected from the group consisting of Zr, Sn, Y, and Al; the valence of M is different from the average valence of Fe; 0<x?0.5; and y=x×({valence of M}?2)+(1?x)×({average valence of Fe}?2). This provides a cathode active material that not only excels in terms of safety and cost but also can provide a long-life battery.Type: ApplicationFiled: December 18, 2014Publication date: April 16, 2015Inventors: Koji OHIRA, Motoaki NISHIJIMA, Toshitsugu SUEKI, Shogo ESAKI, Isao TANAKA, Yukinori KOYAMA, Katsuhisa TANAKA, Koji FUJITA, Shunsuke MURAI
-
Publication number: 20150083976Abstract: A composition includes an active material, a conductive agent, lithium dodecyl sulfate, a solvent, and an organic binder. Another composition includes an active compound containing lithium, a conductive agent, lithium dodecyl sulfate, a solvent and an organic binder. Another composition includes an anode active material, a conductive agent, lithium dodecyl sulfate, a solvent and an organic binder.Type: ApplicationFiled: September 24, 2013Publication date: March 26, 2015Applicant: PALO ALTO RESEARCH CENTER INCORPORATEDInventors: RANJEET RAO, CHANG-JUN BAE
-
Patent number: 8987164Abstract: A semiconductor of which a substance such as a semiconductor photocatalyst is uniformly coated on the surface thereof with a graphitic carbon film and a method of fabricating the same are disclosed. According to the inventive method, a graphitic carbon film having a thickness of 1 nm or less is uniformly formed on the surface of the semiconductor by performing hydrothermal synthesis and pyrolysis on glucose, so as to keep the original structure crystallinity of the semiconductor photocatalyst to be a support of the carbon film.Type: GrantFiled: December 7, 2012Date of Patent: March 24, 2015Assignee: Korea Advanced Institute of Science and TechnologyInventors: Jeung-Ku Kang, Dong-Ki Lee, Kyu-Sung Han, Weon-Ho Shin, Jung-Woo Lee, Jung-Hoon Choi, Kyung-Min Choi, Yeob Lee
-
Patent number: 8961833Abstract: A lithium/fluorinated carbon (Li/CFx) battery having a composite cathode including an electroactive cathode material, a non-electroactive additive, a conductive agent, and a binder. The electroactive cathode material is a single fluorinated carbon having a general formula of CFx, whereby x is an averaged value ranging from about 0.5 to about 1.2. The non-electroactive additive is at least one or a mixture of two or more oxides selected from the group comprising Mg, B, Al, Si, Cu, Zn, Y, Ti, Zr, Fe, Co, or Ni. The conductive agent is selected from the group comprising carbon, metals, and mixtures thereof. Finally, the binder is an amorphous polymer selected from the group comprising fluorinated polymers, ethylene-propylene-diene (EPDM) rubbers, styrene butadiene rubbers (SBR), poly (acrylonitrile-methyl methacrylate), carboxymethyl celluloses (CMC), and polyvinyl alcohol (PVA).Type: GrantFiled: August 10, 2011Date of Patent: February 24, 2015Assignee: The United States of America as represented by the Secretary of the ArmyInventors: Shengshui Zhang, Donald L. Foster, Jeffery Wolfenstine, Jeffery A. Read
-
Patent number: 8962504Abstract: The disclosure provides novel graphene-reinforced ceramic composites and methods for making such composite materials.Type: GrantFiled: July 27, 2012Date of Patent: February 24, 2015Assignee: Arizona Board of Regents on Behalf of The University of ArizonaInventors: Erica L. Corral, Luke S. Walker, Victoria R. Marotto, Mohammad A. Rafiee, Nikhil Koratkar
-
Publication number: 20150044542Abstract: An isolated salt comprising a compound of formula (H2X)(TiO(Y)2) or a hydrate thereof, wherein X is 1,4-diazabicyclo[2.2.2]octane (DABCO), and Y is oxalate anion (C2O4?2), when heated in an oxygen-containing atmosphere at a temperature in the range of at least about 275° C. to less than about 400° C., decomposes to form an amorphous titania/carbon composite material comprising about 40 to about 50 percent by weight titania and about 50 to about 60 percent by weight of a carbonaceous material coating the titania. Heating the composite material at a temperature of about 400 to 500° C. crystallizes the titania component to anatase. The titania materials of the invention are useful as components of the cathode or anode of a lithium or lithium ion electrochemical cell.Type: ApplicationFiled: October 24, 2014Publication date: February 12, 2015Applicant: UCHICAGO ARGONNE, LLCInventors: John T. Vaughey, Andrew Jansen, Christopher D. Joyce
-
Patent number: 8945501Abstract: A method for preparing a carbon nanotube, including: a) preparing an LPAN solution, stirring the LPAN solution at between 100 and 200° C. for between 100 and 200 hours to yield a cyclized LPAN solution; b) heating the cyclized LPAN solution at between 200 and 300° C. for between 1 and 10 hours to yield an OPAN; c) grinding, screening, and drying at room temperature the OPAN to yield a thermal oxidative precursor; d) calcining the thermal oxidative precursor at between 400 and 1000° C. for between 1 and 24 h in the presence of inert gas having a flow rate of between 10 and 500 mL/min to yield a carbonated precursor; and e) calcining the carbonated precursor at between 1000 and 1500° C. for between 1 and 10 hours in the presence of the inert gas having a flow rate of between 10 and 500 mL/min to yield a carbon nanotube material.Type: GrantFiled: September 30, 2013Date of Patent: February 3, 2015Inventors: Jianhong Liu, Jian Xu, Shuangquan Wu
-
Patent number: 8940193Abstract: One or more embodiments provide for a device that utilizes voltage switchable dielectric material having semi-conductive or conductive materials that have a relatively high aspect ratio for purpose of enhancing mechanical and electrical characteristics of the VSD material on the device.Type: GrantFiled: June 10, 2011Date of Patent: January 27, 2015Assignee: Littelfuse, Inc.Inventors: Lex Kosowsky, Robert Fleming
-
Publication number: 20150017538Abstract: Provided is a cathode active material which is superior in safety and cost and makes it possible to provide a nonaqueous secondary battery having a long life. The cathode active material has a composition represented by the following formula (1): LiMn1-xMxP1-yAlyO4 ??(1) (wherein M is at least one selected from the group consisting of Ti, V, Zr, Sn and Y, x is in a range of 0<x?0.5, and y is in a range of 0<y?0.25).Type: ApplicationFiled: December 28, 2012Publication date: January 15, 2015Inventors: Koji Ohira, Motoaki Nishijima, Yuichi Kamimura
-
Patent number: 8932720Abstract: The present invention describes the use of a composition which can be cured below 40° C., a method of coating fiber/polymer composites, the preparation of curable compositions, and a modular system for preparing said compositions.Type: GrantFiled: September 14, 2009Date of Patent: January 13, 2015Assignee: BASF Coatings GmbHInventors: Michael Dornbusch, Hendrik Narjes, Doris Austermann
-
Publication number: 20140377790Abstract: Methods of forming metal nanoparticle decorated carbon nanotubes are provided. The methods include mixing a metal precursor with a plurality of carbon nanotubes to form a metal precursor-carbon nanotubes mixture. The methods also include exposing the metal precursor-carbon nanotubes mixture to electromagnetic radiation to deposit metal nanoparticles on a major surface of the carbon nanotubes.Type: ApplicationFiled: November 12, 2013Publication date: December 25, 2014Applicant: INDIAN INSTITUTE OF TECHNOLOGY MADRASInventors: Sundara RAMAPRABHU, Mridula BARO, Pranati NAYAK, Tessy THERES BABY
-
Patent number: 8906557Abstract: Anode active materials and methods of preparing the same are provided. One anode active material includes a carbonaceous material capable of improving battery cycle characteristics. The carbonaceous material bonds to and coats metal active material particles and fibrous metallic particles to suppress volumetric changes.Type: GrantFiled: March 22, 2007Date of Patent: December 9, 2014Assignee: Samsung SDI Co., Ltd.Inventors: Gue-sung Kim, Yong-nam Ham, Han-su Kim, Dong-min Im
-
Publication number: 20140356725Abstract: Synthesis process for new particles of Li4Ti5O12, Li(4-?)Z?Ti5O12 or Li4Z?Ti(5-?)O12, preferably having a spinel structure, wherein ? is greater than 0 and less than or equal to 0.5 (preferably having a spinel structure), ? representing a number greater than zero and less than or equal to 0.33, Z representing a source of at least one metal, preferably chosen from the group made up of Mg, Nb, Al, Zr, Ni, Co. These particles coated with a layer of carbon notably exhibit electrochemical properties that are particularly interesting as components of anodes and/or cathodes in electrochemical generators.Type: ApplicationFiled: August 18, 2014Publication date: December 4, 2014Applicant: HYDRO-QUEBECInventors: Karim ZAGHIB, Michel GAUTHIER, Fernand BROCHU, Abdelbast GUERFI, Monique MASSE, Michel ARMAND
-
Publication number: 20140346408Abstract: This invention relates to a method of manufacturing a graphene or graphene oxide/nanoparticle hybrid material and a graphene/nanoparticle hybrid material manufactured thereby, wherein the hybrid material can be easily, rapidly and eco-friendly synthesized while minimizing the use of chemicals and thermal treatment because of electrostatic self-assembly properties of a biomaterial. This method includes preparing nanoparticles, a biomaterial solution and a graphene oxide solution, mixing the nanoparticles with the biomaterial solution to form biomaterial-coated nanoparticles, mixing the biomaterial-coated nanoparticles with the graphene oxide solution to obtain a graphene oxide/nanoparticle hybrid material, and reducing the graphene oxide/nanoparticle hybrid material to obtain a graphene/nanoparticle hybrid material.Type: ApplicationFiled: January 24, 2014Publication date: November 27, 2014Applicant: ELECTRONICS AND TELECOMMUNICATIONS RESEARCH INSTITUTEInventors: Yong-Ju YUN, Ki-Bong SONG
-
Publication number: 20140328005Abstract: A lithium titanium oxide (LTO)/carbon composite, a preparation method for the LTO/carbon composite, a negative electrode material using the LTO/carbon composite, and a hybrid super capacitor using the negative electrode material are disclosed. The lithium titanium oxide (LTO)/carbon composite is formed to insert a carbon-based additive into a plurality of voids formed on the LTO granules, thereby improving the electrical conductivity.Type: ApplicationFiled: April 25, 2014Publication date: November 6, 2014Applicant: SAMHWA CAPACITOR CO., LTD.Inventors: Young Joo OH, Jung Rag YOON, Kyung Min LEE, Byung Gwan LEE
-
Publication number: 20140295231Abstract: According to one embodiment, there is provided an active substance. The active substance contains active material particles. The active material particles comprise a compound represented by the formula: Ti1-xM1xNb2-yM2yO7. The active material particles has a peak A attributed to a (110) plane which appears at 2? ranging from 23.74 to 24.14°, a peak B attributed to a (003) plane which appears at 2? ranging from 25.81 to 26.21° and a peak C attributed to a (?602) plane which appears at 2? ranging from 26.14 to 26.54° in an X-ray diffraction pattern of the active material particles. An intensity IA of the peak A, an intensity IB of the peak B, and an intensity IC of the peak C satisfy the relation (1): 0.80?IB/IA?1.12; and the relation (2) IC/IB?0.80.Type: ApplicationFiled: March 10, 2014Publication date: October 2, 2014Applicant: KABUSHIKI KAISHA TOSHIBAInventors: Kazuki ISE, Yasuhiro HARADA, Hiroki INAGAKI, Norio TAKAMI
-
Publication number: 20140291588Abstract: Provided are a mixed cathode active material having improved power characteristics and safety, and a lithium secondary battery including the same. More particularly, the present invention relates to a mixed cathode active material which may assist power in a low SOC range to widen an available state of charge (SOC) range and may simultaneously provide improved safety by blending substituted LFP, in which operating voltage is adjusted by substituting a portion of iron (Fe) with other elements such as titanium (Ti), in order to prevent a rapid increase in resistance of manganese (Mn)-rich having high capacity but low operating voltage in a low SOC range (e.g., a SOC range of 10% to 40%), and a lithium secondary battery including the mixed cathode active material.Type: ApplicationFiled: June 18, 2014Publication date: October 2, 2014Inventors: Song Taek Oh, Sang Uck Lee, Su Rim Lee, Geun Chang Chung, Jae Kook Kim, Jin Sub Lim
-
Publication number: 20140248537Abstract: There is provided a novel slurry composition for forming a lithium secondary battery electrode which can improve homogeneity of an electrode active material and a conductive assistant even without using an organic solvent and can improve the binding of an electrode active material and a conductive assistant with an electrode collector, and a lithium secondary battery with improved charge/discharge cycle characteristics and battery capacity. A slurry composition for forming a lithium secondary battery electrode, characterized by comprising an electrode active material (A), a conductive assistant (B), and a pulverized cellulose fiber (C) as an aqueous binder, and a lithium secondary battery electrode and a lithium secondary battery which are obtained using the composition, and an aqueous binder used for the composition.Type: ApplicationFiled: September 20, 2012Publication date: September 4, 2014Inventors: Hisato Hayashi, Masaaki Ozawa, Osamu Uesugi, Yoshihiro Kadoma
-
Publication number: 20140248531Abstract: The described embodiments provide an energy storage device that includes a positive electrode including a material that stores and releases ion, a negative electrode including Nb-doped TiO2(B), and a non-aqueous electrolyte containing lithium ions. The described embodiments provide a method including the steps of combining at least one titanium compound and at least one niobium compound in ethylene glycol to form a precursor solution, adding water into the precursor solution to induce hydrolysis and condensation reactions, thereby forming a reaction solution, heating the reaction solution to form crystallized particles, collecting the particles, drying the collected particles, and applying a thermal treatment at a temperature >350° C. to the dried particles to obtain Nb-doped TiO2(B) particles.Type: ApplicationFiled: February 12, 2014Publication date: September 4, 2014Applicant: IMRA AMERICA, INC.Inventors: Bing TAN, Zhendong HU, Guanghui HE, Yong CHE
-
Publication number: 20140234700Abstract: With a small amount of a conductive additive, an electrode for a storage battery including an active material layer which is highly filled with an active material is provided. The use of the electrode enables fabrication of a storage battery having high capacity per unit volume of the electrode. By using graphene as a conductive additive in an electrode for a storage battery including a positive electrode active material, a network for electron conduction through graphene is formed. Consequently, the electrode can include an active material layer in which particles of an active material are electrically connected to each other by graphene. Therefore, graphene is used as a conductive additive in an electrode for a sodium-ion secondary battery including an active material with low electric conductivity, for example, an active material with a band gap of 3.0 eV or more.Type: ApplicationFiled: February 14, 2014Publication date: August 21, 2014Applicant: SEMICONDUCTOR ENERGY LABORATORY CO., LTD.Inventors: Tamae Moriwaka, Satoshi Seo, Takuya Hirohashi, Kunio Hosoya, Shunsuke Adachi
-
Patent number: 8808576Abstract: The present invention relates to a process for the preparation of compounds of general formula (I) Lia-bM1bV2-cM2c(PO4)x??(I) wherein M1, M2, a, b, c and x have the following meanings: M1: Na, K, Rb and/or Cs, M2: Ti, Zr, Nb, Cr, Mn, Fe, Co, Ni, Al, Mg and/or Sc, a: 1.5-4.5, b: 0-0.6, c: 0-1.98 and x: number to equalize the charge of Li and V and M1 and/or M2, if present, wherein a-b is >0, to a compound according to general formula (I) as defined above, to spherical agglomerates and/or particles comprising at least one compound of general formula (I) as defined above, to the use of such a compound for the preparation of a cathode of a lithium ion battery or an electrochemical cell, and to a cathode for a lithium ion battery, comprising at least one compound as defined above.Type: GrantFiled: April 2, 2013Date of Patent: August 19, 2014Assignee: BASF SEInventors: Hartmut Hibst, Brian Roberts, Jordan Keith Lampert, Kirill Bramnik
-
Patent number: 8808575Abstract: The present invention relates to a process for the preparation of compounds of general formula (I) Lia-bM1bV2-cM2c(PO4)x??(I) wherein M1, M2, a, b, c and x have the following meanings: M1: Na, K, Rb and/or Cs, M2: Ti, Zr, Nb, Cr, Mn, Fe, Co, Ni, Al, Mg and/or Sc, a: 1.5-4.5, b: 0-0.6, c: 0-1.98 and x: number to equalize the charge of Li and V and M1 and/or M2, if present, wherein a-b is >0, to a compound according to general formula (I) as defined above, to spherical agglomerates and/or particles comprising at least one compound of general formula (I) as defined above, to the use of such a compound for the preparation of a cathode of a lithium ion battery or an electrochemical cell, and to a cathode for a lithium ion battery, comprising at least one compound as defined above.Type: GrantFiled: April 2, 2013Date of Patent: August 19, 2014Assignee: BASF SEInventors: Hartmut Hibst, Brian Roberts, Jordan Keith Lampert, Kirill Bramnik
-
Publication number: 20140217330Abstract: A metal oxide-carbon composite includes a carbon aerogel with an oxide overcoat. The metal oxide-carbon composite is made by providing a carbon aerogel, immersing the carbon aerogel in a metal oxide sol under a vacuum, raising the carbon aerogel with the metal oxide sol to atmospheric pressure, curing the carbon aerogel with the metal oxide sol at room temperature, and drying the carbon aerogel with the metal oxide sol to produce the metal oxide-carbon composite. The step of providing a carbon aerogel can provide an activated carbon aerogel or provide a carbon aerogel with carbon nanotubes that make the carbon aerogel mechanically robust.Type: ApplicationFiled: January 15, 2014Publication date: August 7, 2014Inventors: Marcus A. WORSLEY, Thomas Yong-Jin HAN, Joshua D. KUNTZ, Octavio CERVANTES, Alexander E. GASH, Theodore F. BAUMANN, Joe H. SATCHER, Jr.
-
Patent number: 8790551Abstract: An electrolyte composition containing an ionic liquid and conductive particles, an electrolyte composition containing an ionic liquid and oxide semiconductor particles and optionally containing conductive particles, and an electrolyte composition containing an ionic liquid and insulating particles are provided. Furthermore, a photoelectric conversion element comprising: a working electrode, the working electrode comprising an electrode substrate and an oxide semiconductor porous film formed on the electrode substrate and sensitized with a dye; a counter electrode disposed opposing the working electrode; and an electrolyte layer made of these electrolyte compositions is provided.Type: GrantFiled: June 16, 2009Date of Patent: July 29, 2014Assignee: Fujikura Ltd.Inventors: Hiroki Usui, Nobuo Tanabe, Hiroshi Matsui, Tetsuya Ezure, Shozo Yanagida
-
Patent number: 8784694Abstract: The invention relates to a lithium manganese phosphate/carbon nanocomposite as cathode material for rechargeable electrochemical cells with the general formula LixMnyM1-y(PO4)z/C where M is at least one other metal such as Fe, Ni, Co, Cr, V, Mg, Ca, Al, B, Zn, Cu, Nb, Ti, Zr, La, Ce, Y, x=0.8-1.1, y=0.5-1.0, 0.9<z<1.1, with a carbon content of 0.5 to 20% by weight, characterized by the fact that it is obtained by milling of suitable precursors of LixMnyM1-y(PO4)Z with electro-conductive carbon black having a specific surface area of at least 80 m2/g or with graphite having a specific surface area of at least 9.5 m2/g or with activated carbon having a specific surface area of at least 200 m2/g. The invention also concerns a process for manufacturing said nanocomposite.Type: GrantFiled: April 14, 2009Date of Patent: July 22, 2014Assignee: Dow Global Technologies LLCInventor: Andreas Kay
-
Publication number: 20140199579Abstract: A negative electrode active material for a nonaqueous electrolyte secondary battery has a carbonaceous substance, a silicon oxide phase in the carbonaceous substance, a silicon phase in the silicon oxide phase, and a zirconia phase in the carbonaceous substance. The negative electrode active material has a diffraction peak at 2?=30±1° in powder X-ray diffraction measurement.Type: ApplicationFiled: March 17, 2014Publication date: July 17, 2014Applicant: KABUSHIKI KAISHA TOSHIBAInventors: Tomokazu MORITA, Takashi KUBOKI, Takayuki FUKASAWA, Yasuyuki HOTTA, Kenji ESSAKI, Norikazu OSADA
-
Publication number: 20140186714Abstract: A cathodic active material for a nonaqueous electrolyte secondary battery according to the invention includes a lithium-containing transition metal phosphate containing Li and a transition metal. A transition metal site and P site of the lithium-containing transition metal phosphate are replaced by elements other than elements contained in the lithium-containing transition metal phosphate, and the quantity of P site is excessive with respect to a stoichiometric proportion of the lithium-containing transition metal phosphate. With this cathodic active material, a high-power and high-capacity secondary battery which is superior in safety and cost and has superior rate performance can be provided.Type: ApplicationFiled: June 5, 2013Publication date: July 3, 2014Applicant: SHARP KABUSHIKI KAISHAInventors: Yuichi Kamimura, Motoaki Nishijima, Tomohisa Yoshie, Koji Ohira
-
Publication number: 20140175338Abstract: An electrically conductive polymer compound is disclosed. The compound comprises a matrix comprising polyphenylene sulfide and carbon nanotubes and glass fibers dispersed in the matrix. The carbon nanotubes are disaggregated and disagglomerated within the polyphenylene sulfide, when the compound is viewed at 20,000× magnification. The compound is useful for making extruded or molded plastic articles that need electrical properties.Type: ApplicationFiled: March 12, 2013Publication date: June 26, 2014Applicant: POLYONE CORPORATIONInventors: Joseph C GOLBA, Jane M SPIKOWSKI, Brad J DAVISON, Kebin GENG
-
Publication number: 20140159668Abstract: An anode electrode for an energy storage device includes both an ion intercalation material and a pseudocapacitive material. The ion intercalation material may be a NASICON material, such as NaTi2(PO4)3 and the pseudocapacitive material may be an activated carbon material. The energy storage device also includes a cathode, an electrolyte and a separator.Type: ApplicationFiled: August 21, 2013Publication date: June 12, 2014Applicant: Aquion Energy Inc.Inventors: Jay Whitacre, Alex Mohamed, Andrew Polonsky, Sneha Shanbhag, Kristen Carlisle
-
Publication number: 20140147738Abstract: An electrode composite material is disclosed in the invention. The electrode composite material comprises ABxCyDz, wherein A is selected from at least one of polypyrrole, polyacrylonitrile, and polyacrylonitrile copolymer; B comprises sulfur; C is selected from carbon material; D is selected from metal oxides, l?x?20, 0?y<l, and 0?z<1. Comparing to the prior art, the conductivity of the electrode composite material is obviously increased, the material is dispersed uniformly and the size of the material is small. The electrochemical performance of the electrode composite material is improved. It has a good cycle life and high discharging capacity efficiency. A method for manufacturing the electrode composite material, a positive electrode using the electrode composite material and a battery including the same are also disclosed in the invention.Type: ApplicationFiled: December 11, 2013Publication date: May 29, 2014Applicant: POSITEC POWER TOOLS (SUZHOU) CO., LTDInventors: Pu Chen, Yongguang Zhang, Zhumabay Bakenov, Aishuak Konarov, The Nam Long Doan
-
Publication number: 20140139973Abstract: A titanium oxide composite, a titanium oxide composite manufacturing method, and a super capacitor using the same are provided. The titanium oxide composite is prepared to surround graphene on a surface of granule type titanium oxide. One of a granule type LixTiyOz and a granule type HxTiyOz is selected and thereby used for the granule type titanium oxide, the granule type LixTiyOz satisfies 1?x?4, 1?y?5, and 1?z?12, and the granule type HxTiyOz satisfies 1?x?2, 1?y?12, and 1?z?25.Type: ApplicationFiled: November 12, 2013Publication date: May 22, 2014Applicant: SAMHWA CAPACITOR CO., LTD.Inventors: Young Joo OH, Jung Rag YOON, Kyung Min LEE, Byung Gwan LEE
-
Publication number: 20140117290Abstract: Epoxidised natural rubber [ENR] based vulcanised-blends with two different types of electrical conductive filler (i.e. conductive grade-carbon black and intrinsically electrical conductive polymer) may be produced respectively by using either internal mechanical mixing method or open milling method or the combination of the two methods. All these ENR based vulcanised-blends show high consistent reversible electrical behaviour under the tensile straining process. They also exhibit useful mechanical property ties with tensile strengths up to 28.0 MPa, elongations at break up to 800.0% and Dunlop rebound resiliencies up to 55.0%. The lower the rebound resilience, the better the damping property and shock absorption ability for the ENR based vulcanised-blends. As a result, these ENR based vulcanised-blends are ideal to be used for manufacturing flexible sensors that may correspond to the tensile straining process.Type: ApplicationFiled: June 8, 2012Publication date: May 1, 2014Applicant: LEMBAGA GETAH MALAYSIAInventor: Yong Kok Chong