Abstract: The present invention relates to a process for the synthesis of a carbon-deposited alkali metal oxyanion cathode material comprising particles, wherein said particles carry, on at least a portion of the particle surface, carbon deposited by pyrolysis, said process comprising a dry high-energy milling step performed on precursors of said carbon-deposited alkali metal oxyanion prior to a solid-state thermal reaction.

Abstract: Provided are an insulated ultrafine powder obtained by adding liquid metal alkoxide to a methanol-containing organic solvent in which a conductive ultrafine powder comprising a carbon material is dispersed and further adding water thereto and a method for producing the same. Also, provided are an insulated ultrafine powder obtained by adding liquid metal alkoxide to a methanol-containing organic solvent in which a conductive ultrafine powder comprising a carbon material is dispersed, further adding a coupling agent having an alkoxide group and then adding water thereto and a method for producing the same. Further, provided is a high dielectric constant resin composite material obtained by blending the insulated ultrafine powder of the present invention with a resin in a volume ratio (insulated ultrafine powder/resin) falling in a range of 5/95 to 50/50.

Abstract: The electrode material includes metal oxide nanoparticles formed by applying shear force and centrifugal force to reactants containing a reaction inhibitor in a rotating reaction vessel during a chemical reaction; and carbon nanotubes with a specific area of 600 to 2600 m2/g to which shear force and centrifugal force are applied for dispersion in the rotating reaction vessel during the chemical reaction. The metal oxide particles are highly dispersed and carried on the carbon nanotubes. Preferably, the metal oxide is lithium titanate.

Abstract: A lithium/fluorinated carbon (Li/CFx) battery having a composite cathode including an electroactive cathode material, a non-electroactive additive, a conductive agent, and a binder. The electroactive cathode material is a single fluorinated carbon having a general formula of CFx, whereby x is an averaged value ranging from about 0.5 to about 1.2. The non-electroactive additive is at least one or a mixture of two or more oxides selected from the group comprising Mg, B, Al, Si, Cu, Zn, Y, Ti, Zr, Fe, Co, or Ni. The conductive agent is selected from the group comprising carbon, metals, and mixtures thereof. Finally, the binder is an amorphous polymer selected from the group comprising fluorinated polymers, ethylene-propylene-diene (EPDM) rubbers, styrene butadiene rubbers (SBR), poly (acrylonitrile-methyl methacrylate), carboxymethyl celluloses (CMC), and polyvinyl alcohol (PVA).

Abstract: An anode includes an anode active material including a lithium titanium oxide, a binder, and 0 to about 2 parts by weight of a carbon-based conductive agent based on 100 parts by weight of the lithium titanium oxide.

Abstract: A composite of electrode active material including aggregates formed by self-assembly of electrode active material nanoparticles and carbon nanotubes, and a fabrication method thereof are disclosed. This composite is in the form of a network in which at least some of the carbon nanotubes connect two or more aggregates that are not directly contacting each other, creating an entangled structure in which a plurality of aggregates and a plurality of carbon nanotube strands are intertwined. Due to the highly conductive properties of the carbon nanotubes in this composite, charge carriers can be rapidly transferred between the self-assembled aggregates. This composite may be prepared by preparing a dispersion in which the nanoparticles and/or carbon nanotubes are dispersed without any organic binders, simultaneously spraying the nanoparticles and the carbon nanotubes on a current collector through electrospray, and then subjecting the composite material formed on the current collector to a heat treatment.

Abstract: A spinel-type lithium titanium oxide/graphene composite and a method of preparing the same are provided. The method can be useful in simplifying a manufacturing process and shortening a manufacturing time using microwave associated solvothermal reaction and post heat treatment, and the spinel-type lithium titanium oxide/graphene composite may have high electrochemical performances due to its excellent capacity and rate capability and long lifespan, and thus be used as an electrode material of the lithium secondary battery.

Abstract: A nano graphene-enhanced particulate for use as a lithium-ion battery anode active material, wherein the particulate is formed of a single sheet of graphene or a plurality of graphene sheets and a plurality of fine anode active material particles with a size smaller than 10 ?m. The graphene sheets and the particles are mutually bonded or agglomerated into the particulate with at least a graphene sheet embracing the anode active material particles. The amount of graphene is at least 0.01% by weight and the amount of the anode active material is at least 0.1% by weight, all based on the total weight of the particulate. A lithium-ion battery having an anode containing these graphene-enhanced particulates exhibits a stable charge and discharge cycling response, a high specific capacity per unit mass, a high first-cycle efficiency, a high capacity per electrode volume, and a long cycle life.

Abstract: The disclosure relates a niobium oxide useful in anodes of secondary lithium ion batteries. Such niobium oxide has formula LixM1?yNbyNb2O7, wherein 0?x?3, 0?y?1, and M represents Ti or Zr. The niobium oxide may be in the form of particles, which may be carbon coated. The disclosure also relates to an electrode composition containing at least one or more niobium oxides of formula LixM1?yNbyNb2O7. The disclosure further relates to electrodes, such as anodes, and batteries containing at least one or more niobium oxides of formula LixM1?yNbyNb2O7. Furthermore, the disclosure relates to methods of forming the above.

Abstract: A positive electrode material is disclosed which contains an iron lithium phosphate as a positive electrode active material and has a large charge/discharge capacity, high-rate adaptability, and good charge/discharge cycle characteristics at the same time. Also disclosed are a simple method for producing such a positive electrode material and a high-performance secondary battery employing such a positive electrode material. Specifically, disclosed is a positive electrode material for secondary battery characterized by mainly containing a positive electrode active material represented by the general formula: LinFePO4 (wherein n is a number of 0-1) and further containing at least one different metal element selected from the group consisting of vanadium (V), chromium (Cr), copper (Cu), zinc (Zn), indium (In) and tin (Sn). This positive electrode material can be produced using a halide of such a metal element as the raw material.

Abstract: An anode composition for a lithium secondary battery includes an anode active material, a binder, and a conductive material. The active material includes a plurality of anode active material particles, each of which includes a core made of metal or metalloid allowing alloying or dealloying with lithium, or a compound containing the metal or metalloid; and a shell formed at an outer portion of the core and having Ketjen black. The conductive material includes carbon nano fiber. The anode composition uses a metal-based anode active material that may controls the volume expansion, and also uses conductive material with excellent dispersion so that the life characteristic of the battery may be improved.

Abstract: The present invention relates to a positive electrode composite material for Li-ion battery, to the preparation method thereof, and to the use thereof in a Li-ion battery. The composite material according to the invention includes: a) at least one conductive additive including carbon nanotubes at a content between 1 and 2.5 wt %, preferably between 1.5 and 2.2 wt %, relative to the total weight of the composite material; b) an active electrode material capable of reversibly forming an insertion compound with lithium, having an electrochemical potential greater than 2V relative to the Li/Li+ couple, and selected from among compounds having LiMv(XOz)n polyanionic framework; and c) a polymer binder. The positive electrode composite material according to the invention imparts, to the Li-ion battery incorporating said electrode, high support for the cycling capacity, weak internal resistance, and strong charge and discharge kinetics for the moderate cost of the stored KW.

Abstract: An electrode comprises graphene, titanium dioxide and a binder, the binder configured to facilitate the binding together of the graphene and titanium dioxide to form the electrode.

Abstract: Disclosed herein are an electrically conductive thermoplastic resin composition and a plastic article including the same. The electrically conductive thermoplastic resin composition comprises about 80 to about 99.9 parts by weight of a thermoplastic resin, about 0.1 to about 10 parts by weight of carbon nanotubes, about 0.1 to about 10 parts by weight of an impact modifier, based on a total of about 100 parts by weight of the thermoplastic resin and the carbon nanotubes, and about 0.1 to about 10 parts by weight of conductive metal oxide, based on a total of about 100 parts by weight of the thermoplastic resin and the carbon nanotubes.

Abstract: A high capacity lithium secondary battery includes a lithium manganese oxide having a layered structure exhibiting a great irreversible capacity in the event of overcharging at a high voltage and a spinel-based lithium manganese oxide. Because it is activated at a high voltage of 4.45 V or higher based on a positive electrode potential, additional lithium for utilizing a 3V range of the spinel-based lithium manganese oxide can be provided and an even profile in the entire SOC area can be obtained. Because the lithium secondary battery includes the mixed positive electrode active material including the spinel-based lithium manganese oxide and the lithium manganese oxide having a layered structure, and is charged at a high voltage, its stability can be improved. Also, the high capacity battery having a large available SOC area and improved stability without causing an output shortage due to a rapid voltage drop in the SOC area can be implemented.

Abstract: The invention relates to a process for coating nanoparticles with graphene, comprising the steps of (a) providing a suspension comprising a suspension medium and nanoparticles with positive surface charge, (b) adding graphene oxide particles to the suspension from step (a), the graphene oxide particles accumulating on the nanoparticles, and (c) converting the graphene oxide particles accumulated on the nanoparticles to graphene, to graphene-coated nanoparticles comprising at least one metal, a semimetal, a metal compound and/or a semimetal compound, and to the use of these graphene-coated nanoparticles in electrochemical cells and supercapacitors, and to supercapacitors and electrochemical cells comprising these nanoparticles.

Abstract: The invention relates generally to carbon nano-tube composites and particularly to carbon nano-tube compositions for electrochemical energy storage devices and a method for making the same.

Abstract: An electrode material is created by forming a thin coating or small deposits of metal oxide as an intercalation host on a carbon powder. The carbon powder performs a role in the synthesis of the oxide coating, in providing a three-dimensional, electronically conductive substrate supporting the metal oxide, and as an energy storage contribution material through ion adsorption or intercalation. The metal oxide includes one or more metal oxides. The electrode material, a process for producing said electrode material, an electrochemical capacitor and an electrochemical secondary (rechargeable) battery using said electrode material is disclosed.

Abstract: The present invention provides an electrode mixture, an electrode and a nonaqueous electrolyte secondary battery. The electrode mixture includes a lithium mixed metal oxide represented by formula (1): Liz(Ni1-x-yMnxMy)O2??(1), an electrically conductive material, and a water-dispersible polymeric binder, wherein x is 0.30 or more and less than 1, y is 0 or more and less than 1, x+y is 0.30 or more and less than 1, z is 0.5 or more and 1.5 or less, and M represents one or more members selected from the group consisting of Co, Al, Ti, Mg and Fe.

Abstract: Provided is a lithium secondary battery which has excellent low-temperature power output characteristics by the inclusion of a given amount of a lithium metal oxide and/or a lithium metal sulfide in an anode mix for a lithium secondary battery containing a carbon-based anode active material and is thereby capable of being used as a power source for electric vehicles (EVs) and hybrid electric vehicles (HEVs) that must provide high-power output at low temperatures as well as at room temperature.

Abstract: One or more embodiments provide for a device that utilizes voltage switchable dielectric material having semi-conductive or conductive materials that have a relatively high aspect ratio for purpose of enhancing mechanical and electrical characteristics of the VSD material on the device.

Abstract: An electrode material comprising at least one compound of the general formula (I) LiaMbFcOd??(I) in which the variables are each defined as follows: M is at least one transition metal selected from Ti, Cr, V and Mn, where Ti, Cr, V and Mn may be replaced partially by Al, Ga, Ni, Fe or Co, a is in the range from 2.5 to 3.5, b is in the range from 0.8 to 1.2, c is in the range from 5.0 to 6.5 and d is in the range from zero to 1.0.

Abstract: A method of dispersing nanotubes and/or nanoplatelets in a polyolefin is provided, involving A) preparing a solution comprising nanotubes or nanoplatelets or both; B) stirring the resulting solution from step (A); C) dissolving at least one polymeric material in the stirred solution from step (B) and isolating precipitates from the solution; and D) melt-blending the precipitates with at least one polyolefin, along with the nanocomposites prepared thereby, and articles formed from the nanocomposites.

Abstract: The present invention relates to a process for the preparation of compounds of general Formula (I) La?bM1bFe1?cM2cPd?eM3eOx (I), wherein Fe has the oxidation state +2 and M1, M2, M3, a, b, c, d, e and x are: M1: Na, K, Rb and/or Cs, M2: Mn, Mg, Al Ca, Ti Co, Ni, Cr, V, M3: Si, S, F a: 0.8-1.9, b: 0-0.3, c: 0-0.9, 15 d: 0.8-1.9, e: 0-0.5, x: 1.

Abstract: An object of the present invention is to provide a transparent electroconductive film, which in addition to satisfying each of the requirements of favorable phototransmittance, high electrical conductivity, low refractive index and the like required when using in a multi-junction solar cell, enables running costs to be reduced since the transparent electroconductive film is produced without using a vacuum deposition method. The transparent electroconductive film for a solar cell of the present invention is provided between photoelectric conversion layers of a multi-junction solar cell, a coated film of fine particles formed by coating using a wet coating method is baked, the electroconductive component in the base material that composes the electroconductive film is present within the range of 5 to 95% by weight, and the thickness of the electroconductive film is within the range of 5 to 200 nm.

Abstract: A mesoporous carbon material, a fabrication method thereof and a supercapacitor containing the mesoporous carbon material are provided. The mesoporous carbon material includes a plurality of carbon nanotubes (CNTs) and/or metal particles and/or metal oxide particles, and a carbon matrix. The mesoporous carbon material has a plurality of mesopores formed by the carbon matrix and the carbon nanotubes and/or the metal particles and/or the metal oxide particles. The plurality of carbon nanotubes, and/or the metal particles and/or the metal oxide particles are formed substantially adjacent to the plurality of mesopores.

Abstract: An electrically conductive composition and a fabrication method thereof are provided. The electrically conductive structure includes a major conductive material and an electrically conductive filler of an energy delivery character dispersed around the major conductive material. The method includes mixing a major conductive material with an electrically conductive filler of an energy delivery character to form a mixture, coating the mixture on a substrate, applying a second energy source to the mixture while simultaneously applying a first energy source for sintering the major conductive material to form an electrically conductive composition with a resistivity smaller than 10×10?3?·cm.

Abstract: The present invention provides an insulated ultrafine powder containing electrically conductive ultrafine particles coated with an insulation coating, characterized in that the electrically conductive ultrafine particles are formed of a carbon material which is in the form of spherical particles having a diameter of 1 nm or more and 500 nm or less, fibers having a cross-sectional diameter of 1 nm or more and 500 nm or less, or plate-like particles having a thickness of 1 nm or more and 500 nm or less; the insulation coating is formed of an insulating metal oxide or a hydrate thereof; and the thickness of the insulation coating is 0.

Abstract: The invention relates to a metal boride precursor mixture comprising a metal oxide and a boric oxide combined in such a manner so as to produce intimately linked clusters wherein the boric oxide is found within the metal oxide. Furthermore, the invention discloses a carbon composite material made with the metal boride precursor mixture and a carbonaceous component. Finally, the invention also teaches the process for preparing the metal boride precursor mixture comprising steps of providing a metal oxide and a boron oxide, mechanically mixing the metal oxide and the boron oxide at a temperature that liquefies the boron oxide and may impregnate the metal oxide to produce an intimately linked cluster of metal oxide and boric oxide.

Abstract: The present invention relates to a Process for the preparation of compounds of general formula (I), Lia-bM1bFe1-cM2cPd-eM3eOx, wherein M1, M2, M3, a, b, c, d and e: M1: Na, K, Rb and/or Cs, M2: Mn, Mg, Ca, Ti, Co, Ni, Cr, V, M3: Si, S, a: 0.8-1.9, b: 0-0.3, c: 0-0.9, d: 0.8-1.9, e: 0-0.5, x: 1.

Abstract: The invention relates to materials for use as electrodes in an alkali-ion secondary (rechargeable) battery, particularly a lithium-ion battery. The invention provides transition-metal compounds having the ordered-olivine, a modified olivine, or the rhombohedral NASICON structure and the polyanion (PO4)3? as at least one constituent for use as electrode material for alkali-ion rechargeable batteries.

Abstract: The present invention relates to a nanoparticulate composition comprising nanoparticles with a particle-size distribution of d90?10 ?m, and optionally a surface-active agent. The present invention further relates to a method for the production of such a nanoparticulate composition.

Abstract: A composition comprising: a metal oxide of a first metal ions and second metal ions; an electrically conductive material; and a binder material. The second metal ions have a higher oxidation state than the first metal ions. The presence of the second metal ion increases the number of metal cation vacancies. A method of: dissolving salts of a first metal ion and a second metal ion in water to form a solution; heating the solution to a temperature of about 80-90° C.; and adding a base to the solution to precipitate nanoparticles of a metal oxide of the first metal ion and the second metal ion.

Abstract: The invention relates to a lithium manganese phosphate/carbon nanocomposite as cathode material for rechargeable electrochemical cells with the general formula LixMnyM1-y(PO4)z/C where M is at least one other metal such as Fe, Ni, Co, Cr, V, Mg, Ca, Al, B, Zn, Cu, Nb, Ti, Zr, La, Ce, Y, x=0.8-1.1, y=0.5-1.0, 0.9<z<1.1, with a carbon content of 0.5 to 20% by weight, characterized by the fact that it is obtained by milling of suitable precursors of LixMnyM1-y(PO4)Z with electro-conductive carbon black having a specific surface area of at least 80 m2/g or with graphite having a specific surface area of at least 9.5 m2/g or with activated carbon having a specific surface area of at least 200 m2/g. The invention also concerns a process for manufacturing said nanocomposite.

Abstract: The disclosure of the present application provides various compositions, and methods for preparing the same, which may be useful, for example, to prepare one or more anodes of the present disclosure. Such anodes may be useful, for example, to prepare one or more batteries which themselves, for example, may be useful in connection with a vehicle as referenced herein. In at least one embodiment of an anode of the present disclosure, the anode comprises lithium-based compound having the formula Li4?Ti5-yMyO12-zXz, wherein M comprises a dopant material selected from the group consisting of molybdenum, tungsten, zirconium, and hafnium, wherein X comprises a chalcogen selected from the group consisting of sulfur, selenium, and tellurium, wherein 0<y?1, and wherein 0<z?2y.

Abstract: The invention relates to materials for use as electrodes in an alkali-ion secondary (rechargeable) battery, particularly a lithium-ion battery. The invention provides transition-metal compounds having the ordered-olivine, a modified olivine, or the rhombohedral NASICON structure and the polyanion (PO4)3? as at least one constituent for use as electrode material for alkali-ion rechargeable batteries.

Abstract: The present invention relates to a process for the preparation of compounds of general formula (I): Lia?bM1bV2-cM2c(PO4)x; wherein M1, M2, a, b, c and x have the following meanings: M1: Na, K, Rb and/or Cs, M2: Ti, Zr, Nb, Cr, Mn, Fe, Co, Ni, Al, Mg and/or Sc, a: 1.5-4.5, b: 0-0.6, c: 0-1.98 and x: number to equalize the charge of Li and V and M1 and/or M2, if present, wherein a?b is >0, to a compound according to general formula (I) as defined above, to spherical agglomerates and/or particles comprising at least one compound of general formula (I) as defined above, to the use of such a compound for the preparation of a cathode of a lithium ion battery or an electrochemical cell, and to a cathode for a lithium ion battery, comprising at least one compound as defined above.

Abstract: This invention relates to a composition comprising carbon nanotubes and a protective material that protects the carbon nanotubes from damage or degradation such as by oxidation upon exposure to high temperature.

Abstract: The present invention relates to a process for the preparation of compounds of general formula (I) Lia-bM1bV2-cM2c(PO4)x (I) with M1: Na, K, Rb and/or Cs, M2: Ti, Zr, Nb, Cr, Mn, Fe, Co, Ni, Al, Mg and/or Sc, a: 1.5-4.5, b: 0-0.6, c: 0-1.98 and x: number to equalize the charge of Li and V and M1 and/or M2, if present, wherein a?b is >0, by providing an essentially aqueous mixture comprising at least one lithium-comprising compound, at least one vanadium-comprising compound in which vanadium has the oxidation state +5 and/or +4, and at least one M1-comprising compound, if present, and/or at least one M2-comprising compound, if present, and at least one reducing agent which is oxidized to at least one compound comprising at least one phosphorous atom in oxidation state +5, drying and calcining.

Abstract: Combustion flame-plasma hybrid reactor systems, chemical reactant sources, and related methods are disclosed. In one embodiment, a combustion flame-plasma hybrid reactor system comprising a reaction chamber, a combustion torch positioned to direct a flame into the reaction chamber, and one or more reactant feed assemblies configured to electrically energize at least one electrically conductive solid reactant structure to form a plasma and feed each electrically conductive solid reactant structure into the plasma to form at least one product is disclosed. In an additional embodiment, a chemical reactant source for a combustion flame-plasma hybrid reactor comprising an elongated electrically conductive reactant structure consisting essentially of at least one chemical reactant is disclosed. In further embodiments, methods of forming a chemical reactant source and methods of chemically converting at least one reactant into at least one product are disclosed.

Abstract: The invention relates to a method for producing carbon or HV graphite electrodes, in which a carbon carrier is mixed with a hydrocarbon-containing binder, and the mixture is subjected to a coking process and/or graphitization process, and one or more synthetic titanium compounds are additionally added to the raw materials. The titanium compound is preferably comprised of TiO2. Iron oxide can be added as an accompanying substance.

Abstract: A chip-shaped electronic component includes a substrate and an end face electrode layer provided on an end face of the substrate, in which the end face electrode layer contains a mixed material. The mixed material includes as a conductive particle, a carbon powder, a whisker-like inorganic filler coated with a conductive film, and a flake-like conductive powder. Additionally, an epoxy resin has a weight-average molecular weight between 1,000 and 80,000.

Abstract: A new ramming paste for aluminum reduction cell cathodes is a high swelling cold ramming paste made of a blend of pitch, light oil diluent and an aggregate comprising a mixture of anthracite and crushed anode butts or calcined coke. The presence of the crushed anode butts or calcined coke increases the sodium swelling index of the paste by about four times higher than that of regular ramming pastes. This new high swelling cold ramming paste may also contain an amount of a refractory hard material, such as TiB2.

Abstract: A semiconductor structure and fabrication method is provided for integrating wide bandgap nitrides with silicon. The structure includes a substrate, a single crystal buffer layer formed by epitaxy over the substrate and a group III nitride film formed by epitaxy over the buffer layer. The buffer layer is reflective and conductive. The buffer layer may comprise B an element selected from the group consisting of Zr, Hf, Al. For example, the buffer layer may comprise ZrB2, AlB2 or HfB2. The buffer layer provides a lattice match with the group III nitride layer. The substrate can comprise silicon, silicon carbide (SiC), gallium arsenide (GaAs), sapphire or Al2O3. The group III nitride material includes GaN, AlN, InN, AlGaN, InGaN or AlInGaN and can form an active region. In a presently preferred embodiment, the buffer layer is ZrB2 and the substrate is Si(111) or Si(100) and the group III nitride layer comprises GaN.

Abstract: A negative active material for a rechargeable lithium battery, a method of preparing the negative active material, and a rechargeable lithium battery including the negative active material. The negative active material for a rechargeable lithium battery includes lithium titanium oxide (Li4Ti5O12) having a tap density of about 1.2 g/cc to 2.2 g/cc. The lithium titanium oxide is prepared by a mechano-chemical treatment and a heat treatment at a low temperature of about 650° C. to 775° C. According to the present invention, lithium titanium oxide having high crystallinity and tap density can be prepared through a simple and low-cost solid-phase method, e.g., a mechano-chemical treatment, and thus an electrode with excellent electrochemical reactivity and high energy density per volume can be fabricated.

Abstract: One or more embodiments provide for a composition that includes (i) organic material that is conductive or semi-conductive, and (ii) conductor and/or semiconductor particles other than the organic material. The organic material and the conductor and/or semiconductor particles are combined to provide the composition with a characteristic of being (i) dielectric in absence of a voltage that exceeds a characteristic voltage level, and (ii) conductive with application of the voltage exceeding the characteristic voltage level.

Abstract: Deposition of an electrode active material printing suspension onto a conductive substrate by various pad-printing techniques is described. After heat-treating to evaporate the solvent and decompose a printing binder, an electrode active coating suitable for incorporation into an electrochemical cell is provided.

Abstract: A material in particular for use in electrochemical cells or supercapacitors comprises a poorly conducting active material of relatively low conductivity having regular or irregular passages having average cross-sectional dimensions generally in the size range from 5 ?m to 200 nm and interconnected mesopores having average cross-sectional dimensions in the size range from 2 to 50 nm. The active material is covered with a network of an electronically conductive metal oxide of relatively high conductivity extending into said mesopores. Also claimed is a method of manufacturing such a material.

Abstract: This invention relates generally to organized assemblies of carbon and non-carbon compounds and methods of making such organized structures. In preferred embodiments, the organized structures of the instant invention take the form of nanorods or their aggregate forms. More preferably, a nanorod is made up of a carbon nanotube filled, coated, or both filled and coated by a non-carbon material. This invention is further drawn to the separation of single-wall carbon nanotubes. In particular, it relates to the separation of semiconducting single-wall carbon nanotubes from conducting (or metallic) single-wall carbon nanotubes. It also relates to the separation of single-wall carbon nanotubes according to their chirality and/or diameter.

Abstract: The invention provides an electrode comprising an electrically conductive material having a surface capable of producing surface enhanced Raman scattering of incident light from an adsorbate material adsorbed on the surface of the electrode. The adsorbate is substantially reducible and not substantially oxidizable. The surface of the electrode can be microroughened and include, for example, a plurality of adatoms or clusters of adatoms of a metallic material. The adatoms or clusters of adatoms form sites for photocatalysis of electroreduction when the electrode is irradiated with a light source. The invention also includes a method for making the electrode, and a method of generating electricity using the electrode. In accordance with a further aspect of the invention, a fuel cell is provided including the electrode of the invention.