Titanium Or Zirconium Compound Patents (Class 252/507)
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Patent number: 4438059Abstract: This application discloses a process of making electrically conductive fiber glass articles whereby carbon black is mixed with the resin to provide the desired value of electrical conductivity. A large amount of titanium dioxide is added to counteract the black color resulting from the carbon black addition. The resulting paste is added to fiber glass and the resin is cured thus resulting in a light gray or other gray tones. It is important that the carbon black, titanium and resin be thoroughly mixed to disperse the carbon and other pigments, and the mixing may be accomplished by means of a high intensity mixer or ball mill.Type: GrantFiled: September 22, 1982Date of Patent: March 20, 1984Assignee: Molded Fiber Glass CompaniesInventors: Robert E. Mollman, Ralph Silva
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Patent number: 4382882Abstract: Electrically conductive carbon compositions are disclosed which are formed from carbon having a graphite-like structure and a nitrosyl or nitronium salt or salts. The nitrosyl or nitronium salt reacts with the carbon to intercalate it with charge-exchange atoms or molecules. Binary, ternary and multi-intercalated lamellar compositions are produced according to the particular reaction process selected. The compositions may be used alone as electrical conductors or may be combined in a matrix to form composite conductors.Type: GrantFiled: December 29, 1980Date of Patent: May 10, 1983Inventors: F. Lincoln Vogel, William C. Forsman
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Patent number: 4382024Abstract: An electrically conductive silicone rubber composition having a positive, non-linear, temperature coefficient of resistance and which is substantially non-conductive at a temperature above a predetermined transition temperature, the composition comprising up to 25% based on total material weight of conducting carbon black, from 29% to 62% based on total material weight of at least one additive having a particle size between 0.005 microns and 100 microns, being compatible with the rubber, and having a melting point above the curing temperature of the rubber.Type: GrantFiled: December 14, 1979Date of Patent: May 3, 1983Assignee: Hotfoil LimitedInventors: Peter H. Seaman, Frederick W. Bloore
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Patent number: 4379762Abstract: A method of producing a graphite-based conductive coating composition to be applied to the interior wall of a color picture (cathode-ray) tube, which method comprises the steps of preparing a mixed solution of electroconductive materials by mixing graphite particles, a metal oxide and a surface treating agent with water, producing an electroconductive powder by instantaneously drying said mixed solution, and mixing said electroconductive powder with a silicate and a dispersant in water and stirring the mixture. Said metal oxide, which is a component of said mixed solution, is preferably titanium oxide and the like and said surface treating agent is preferably silicon oxide. It is also desirable that said mixed solution of electroconductive materials be dried instantaneously by spray drying.Type: GrantFiled: March 25, 1980Date of Patent: April 12, 1983Assignee: Hitachi Powdered Metals Company, Ltd.Inventors: Hironobu Chiyoda, Hisayuki Yamazaki, Reiichiro Takabe
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Patent number: 4376029Abstract: A cathode component for a Hall aluminum cell is economically produced from a mixture of a carbon source, preferably calcined petroleum coke, and optionally calcined acicular needle petroleum coke, calcined anthracite coal; a binder such as pitch including the various petroleum and coal tar pitches; titanium dioxide, TiO.sub.2 ; and boric acid, B.sub.2 O.sub.3 or boron carbide, B.sub.4 C; forming said mixture into shapes and heating to a TiB.sub.2 -forming temperature.Type: GrantFiled: September 11, 1980Date of Patent: March 8, 1983Assignee: Great Lakes Carbon CorporationInventors: Louis A. Joo', Kenneth W. Tucker, Frank E. McCown
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Patent number: 4374760Abstract: Preparation of new, useful and novel highly electro-conductive polymer compositions via the dispersion of electrically conductive particulates in conjunction with small proportions of certain organo aluminates, titanates and/or zirconates in polymeric substrates is hereinafter described. Further the production of heretofore unknown classes of organo aluminates, titanates and zirconates useful in the practice of this invention is disclosed and generically useful subclasses of these compounds defined. Advantages other than improved electrical conductivity of the resultant composites, i.e., process and physical property improvements are also documented for compositions containing said additives and particulate materials and/or composites in polymeric dispersions, and/or compositions of said particulates with said organic aluminates, titanates and zirconates.Type: GrantFiled: September 12, 1980Date of Patent: February 22, 1983Inventor: Harold Charles
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Patent number: 4308177Abstract: Chloro-hydrocarbons are used as pitch binder modifiers to improve the strength, density and electrical properties of carbon and graphite articles produced from carbonaceous particles, binders, and additives, and are particularly useful in manufacture of electrodes used in ultra high powered electric arc steel furnaces.Type: GrantFiled: August 27, 1979Date of Patent: December 29, 1981Assignee: Great Lakes Carbon CorporationInventor: Kenneth W. Tucker
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Patent number: 4302361Abstract: A pressure sensitive conductor consists essentially of (I) an electrically insulating rubber (excluding addition reaction type liquid silicone rubber), (II) 25 to 50% by volume of electrically conductive metal particles (preferably 40 to 200.mu. in particle size) and (III) 5 to 20% by volume of carbon black, and having a JIS A hardness of at least 40. Said conductor may optionally contain (IV) 0.1 to 5% by volume of a mono-, di- or trialkyl titanate. This pressure sensitive conductor has high mechanical strength, a rapid electrical response to deformations, a low hysteresis of the electrical resistance variation on application and release of pressure, and minimized change of the pressure-resistivity curve under repeated deformations.Type: GrantFiled: February 26, 1979Date of Patent: November 24, 1981Assignee: Japan Synthetic Rubber Co., Ltd.Inventors: Teizo Kotani, Masaki Nagato, Kozo Arai
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Patent number: 4293838Abstract: A vitreous enamel resistor material comprising a mixture of a vitreous glass frit, an insulating material containing an oxide of zirconium, and a conductive phase of fine particles of tin oxide. The insulating material is selected from the group consisting of zirconia (ZrO.sub.2), calcium zirconate (CaZrO.sub.2), barium zirconate (BaZrO.sub.3) and strontium zirconate (SrZrO.sub.3), and the conductive phase may also contain an additive such as tantalum oxide. An electrical resistor is made from the resistor material by applying the material to a substrate and firing the coated substrate to a temperature at which the glass softens. Upon cooling, the substrate has on the surface thereof a film of glass and insulating material having the particles of the conductive phase embedded therein and dispersed therethroughout. The resistor material provides a resistor having relatively high resistivity as well as rugged physical characteristics.Type: GrantFiled: January 29, 1979Date of Patent: October 6, 1981Assignee: TRW, Inc.Inventors: Richard L. Wahlers, Vernon E. Osborne
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Patent number: 4293450Abstract: An electrically conductive composition is provided which comprises an intercalation compound of (1) graphite, (2) fluorosulfonic acid, chlorosulfonic acid, or mixtures thereof, and (3) a boron trihalide, a tetrahalide of a Group IV element, a pentahalide of a Group V element, or mixtures thereof. The graphite may be in any one of a variety of physical configurations, e.g. as particulate crystals or present in a carbonaceous fibrous material, at the time of the intercalation reaction. The resulting graphite intercalation compound possesses advantageous electrical conductivity characteristics not possessed by plain graphite and is capable of utilization as a light weight electrical conductor. The graphite intercalation compound may optionally be provided within a metal matrix (e.g. within elemental copper) to form an electrically conductive composite article.Type: GrantFiled: April 18, 1978Date of Patent: October 6, 1981Inventor: F. Lincoln Vogel
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Patent number: 4292345Abstract: A method of protecting carbon-containing component parts of metallurgical units from oxidation comprises impregnating a component part with orthophosphoric acid to form a glassy mass in the pores of the component part when the latter is heated, drying the component part until the moisture is removed from the pores thereof, additionally impregnating the component part with an elemental organic compound comprising an element: Si, or Ti, or Al and capable of forming a phosphate, and heating the impregnated component part to the temperature at which phosphates are formed.Type: GrantFiled: February 4, 1980Date of Patent: September 29, 1981Inventors: Mikhail I. Kolesnik, Anatoly P. Egorov, Anatoly A. Kuznetsov, Anatoly P. Gobov, Jury M. Ryabukhin, Viktor A. Rudakov, Gennady V. Pisarev, Jury M. Zheleznov, Alexei V. Vasiliev
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Patent number: 4271045Abstract: An electrically conductive composition and method for making same is disclosed. The composition includes a uniform mixture of electrically conductive particles comprising pyrolytic carbon doped or coated with a component taken from Group III-VIII elements of the Periodic Table and a curable, non-conducting polymer binder.Type: GrantFiled: June 13, 1978Date of Patent: June 2, 1981Inventors: Wolf-Erhard Steigerwald, Peter Ambros, Hermann Geyer
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Patent number: 4235241Abstract: An improved electrode for living body is proposed which is excellent in the stability and reliability in detecting and transmitting the electric signals generated in a living body by the physiological electric phenomena such as electrocardiographic, electromyographic and electroencephalographic signals.The electrode of the invention is characterized by the material which is mainly a titanium hydride or a mixture of a titanium hydride with silver chloride optionally combined with a metal salt with basicity and a carbon powder, e.g. graphite.Type: GrantFiled: September 5, 1978Date of Patent: November 25, 1980Assignee: TDK Electronics Co., Ltd.Inventors: Katsuhiko Tabuchi, Toshiaki Kato
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Patent number: 4182608Abstract: A photoflash lamp unit is described having a plurality of flash lamps fired individually and in sequence to include a plurality of solid state switching devices each capable of being converted from a high electrical resistance to a low electrical resistance upon activation by either radiant energy or a high voltage pulse. The switch material composition comprises an admixture of a metallic silver source with a sufficient amount of a metal containing material to convert the switch to said low electrical resistance state by the high voltage pulse customarily employed to flash the individual lamps. In this manner, the switch device can be more reliably converted to the conductive state if not already completely converted by radiant energy supplied from an adjacent flash lamp and so provide a conductive path in the electrical circuit.Type: GrantFiled: December 1, 1977Date of Patent: January 8, 1980Assignee: General Electric CompanyInventors: Harihar D. Chevali, Thomas A. Evans
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Patent number: 4173731Abstract: A resistor composition for use in producing a resistor used in a spark plug comprising(1) 100 parts by weight of(a) a glass; and(b) an inorganic filler;with the glass (a) being present in a proportion of about 30 to about 70% by weight and the inorganic filler (b) being present in a proportion of about 70% to about 30% by weight;and wherein at least about 0.1% by weight of the inorganic filler (b) is replaced by at least one non-oxide compound;(2) about 0.5 to about 7 parts by weight of carbon; and(3) 0 to about 20 parts by weight of at least one of a metal oxide, a transition metal carbide, SiC having a low electrical resistivity and B.sub.4 C.Type: GrantFiled: March 2, 1978Date of Patent: November 6, 1979Assignee: NGK Spark Plug Co., Ltd.Inventors: Shunichi Takagi, Masaru Fukuoka
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Patent number: 4161433Abstract: A novel polyphase packing for alkali metal mercury amalgam denuders comprised of a sintered mixture of powdered valve metal borides and valve metal carbides, a novel amalgam denuder containing the said polyphase packing and a novel process of decomposing alkali metal mercury amalgam by contacting the amalgam with an aqueous media in the presence of the said polyphase packing.Type: GrantFiled: February 17, 1978Date of Patent: July 17, 1979Assignee: Oronzio De Nora Impianti Elettrochimici S.p.A.Inventors: Oronzio De Nora, Antonio Nidola, Placido M. Spaziante
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Patent number: 4151126Abstract: Shaped polyolefin objects having decorative metal coatings are obtained by (1) cold compressing a solid, substantially homogeneous, particulate, highly-filled polyolefin composite containing polyolefin, particularly polyethylene, and at least 33% by weight of filler including at least 10% of conductive carbon and, optionally, an inorganic filler compound, in which the polyolefin is polymerized onto the surface of the filler, (2) sintering the compressed shaped object, and (3) electroplating the sintered object.Type: GrantFiled: April 25, 1977Date of Patent: April 24, 1979Assignee: E. I. Du Pont de Nemours and CompanyInventors: Robert L. Adelman, Edward G. Howard, Jr.
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Patent number: 4119655Abstract: Novel intercalates of graphite are prepared by reacting graphite with a Lewis acid fluoride and ClF.sub.3 in the presence of HF. These compounds are particularly useful as battery cathodes.Type: GrantFiled: January 17, 1977Date of Patent: October 10, 1978Assignee: Exxon Research & Engineering Co.Inventor: Roger Hulme
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Patent number: 4110260Abstract: The electroconductive composite ceramics composed of an independent phase conglomerates having a particle diameter of at least 20.mu. and a continuous phase connecting mutually the independent phase of conglomerates. Particularly, electroconductive composite ceramics composed of (A) 50-98% by weight of an independent phase of conglomerates having a particle diameter of at least 20 which consists essentially of a phase of insulating or semiconductive ceramics having a high melting point or a mixture thereof and (B) 50-2% by weight of a continuous phase of an electroconductive substance connecting mutually the independent phase of conglomerates. The electroconductive composite ceramics exhibit stable electroconductivity-temperature characteristics at a temperature of 1000.degree. C. or higher and have excellent thermal shock resistance, mechanical strength and chemical resistance.Type: GrantFiled: September 22, 1976Date of Patent: August 29, 1978Assignee: Tokyo Denki Kagaku Kogyo Kabushiki Kaisha (TDK Electronics Co., Ltd.)Inventors: Hirotaka Yamamoto, Satoshi Sendai, Hideaki Ninomiya
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Patent number: 4098725Abstract: Low thermally expansive, electroconductive composite sintered ceramics comprised of a phase of at least one ceramics selected from the group consisting of low thermally expansive ceramics and negatively thermally expansive ceramics, having dispersed thereinto substantially in a continuous state a phase of an electroconductive substance such as a metal.Type: GrantFiled: November 21, 1975Date of Patent: July 4, 1978Assignee: Tokyo Denki Kagaku Kogyo Kabushiki KaishaInventors: Hirotaka Yamamoto, Hideaki Ninomiya, Makoto Kobayashi
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Patent number: 4076652Abstract: Elastic resistor compositions comprising metallic-conductive particles and solid conductive lubricant particles codistributed in a matrix of a curable, elastomer-forming polymer and the cured compositions formed therefrom. Elastic resistors made from said compositions are also disclosed.Type: GrantFiled: May 24, 1976Date of Patent: February 28, 1978Assignee: E. I. Du Pont de Nemours and CompanyInventors: James Barry Ganci, Sebastian V. R. Mastrangelo
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Patent number: 4042656Abstract: A graphite-base filling material for the decomposition of alkali metal amalgams, said material containing titanium carbide and incorporating the ingredients in an amount between 69 and 35 wt % for the graphite and between 31 and 65 wt % for the titanium carbide.The method of producing the material disclosed consists in that a carbon filler, a carbon-containing binding agent and titanium or titanium carbide or titanium oxide are intermixed. The titanium or said titanium compounds is used in an amount between 24.8 and 52 wt %, the titanium carbide or titanium oxide being taken in terms of titanium. The mixture obtained is moulded and the blanks moulded are fired at a temperature between 500.degree. and 1200.degree. C. Next, the blanks fired are graphitized at a temperature between 1700.degree. and 1800.degree. C.Type: GrantFiled: April 21, 1975Date of Patent: August 16, 1977Inventors: Vladimir Petrovich Chviruk, Nina Vasilievna Koneva, Alexandr Afanasievich Kilkinov, Alexandr Viktorovich Demin, Nikolai Nikolaevich Shipkov, Konstantin Alexeevich Kosinsky, Georgy Mikirtychevich Kamarian, Ernest Elizarovich Nemirovsky, Igor Nikolaevich Samokhin
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Patent number: 3956194Abstract: New mixed conductors resulting from the insertion of an alkali element in the lattice of an intercalation compound of graphite and of a product M'.sub.y X.sub.z : M' is a transition metal such as Ti, V, Cr, Mn, Fe, Mo; X is a nonmetallic electronegative atom such as O, S, F, Cl or Br; y and z have the values of the indices in said product M'.sub.y X.sub.z. These mixed compounds are useful for the manufacture of positive electrodes of electrochemical generators.Type: GrantFiled: August 17, 1973Date of Patent: May 11, 1976Inventor: Michel B. Armand
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Patent number: 3947277Abstract: Electrical resistor inks comprising a mixture of a semi-conducting pyropolymeric inorganic material and a transition metal oxide along with a vehicle consisting of a binder such as a synthetic resin or a varnish and a suitable solvent or oil, etc. are useful in forming resistors in electrical circuits, the resistor ink possessing a temperature coefficient of resistance of less than about 500 ppm/.degree. C.Type: GrantFiled: December 19, 1973Date of Patent: March 30, 1976Assignee: Universal Oil Products CompanyInventors: Robert D. Carnahan, Karl J. Youtsey
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Patent number: 3947278Abstract: Electrical resistor inks comprising a mixture of carbon black and a semi-conducting pyropolymeric inorganic material along with a vehicle consisting of a binder such as a synthetic resin or a varnish and a suitable solvent or oil, etc. are useful in forming resistors in electrical circuits, the resistor ink possessing a temperature coefficient of resistance of less than 500 ppm/.degree. C.Type: GrantFiled: December 19, 1973Date of Patent: March 30, 1976Assignee: Universal Oil Products CompanyInventor: Karl J. Youtsey
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Patent number: 3931055Abstract: Glass powder is wetted with an aqueous solution or emulsion of an organic binder and mixed with carbon black in the form of soot or lampblack. The resulting material is packed between the parts of the central electrode of a sparkplug and fired at a temperature sufficient to fuse the glass to produce a gas-tight seal with electrically conducting properties. Up to 5% of metal powders may be included in the material if it is desired to prevent the resistance from rising during service. Oxides or carbides and certain other metal powders may be added to bring the thermal expansion coefficient to a desired average value.Type: GrantFiled: August 29, 1973Date of Patent: January 6, 1976Assignee: Robert Bosch G.m.b.H.Inventor: Karl-Hermann Friese