Abstract: Ionic colloidal crystals (ordered multicomponent colloids formed by attractive electrostatic interactions) may be produced by controlling the surface potential and relative size of multiple populations of colloidal particles in suspension. Such suspensions are dried or otherwise caused to precipitate out the particles in ordered arrays. The crystal structure of the arrays may be controlled by appropriate choices of particle materials, sizes, and charge ratios.

Abstract: The invention relates to zinc oxide nanoparticles having an average particle size in the range from 3 to 50 nm, dispersed in an organic solvent, according to one or more of claims 1 to 6, characterised in that in a step a) one or more precursors of the nanoparticles are converted into the nanoparticles in an alcohol, in a step b) the growth of the nanoparticles is terminated by addition of at least one modifier, which is a precursor of silica, when the absorption edge in the UV/VIS spectrum of the reaction solution has reached the desired value, in a step c) the silica coating is modified by addition of at least one further surface modifier selected from the group consisting of organofunctional silanes, quaternary ammonium compounds, phosphonates, phosphonium and sulfonium compounds or mixtures thereof, and optionally, in step d), the alcohol from step a) is removed and replaced by another organic solvent, to isolated nanoparticles, and to the use thereof for UV protection in polymers.

Abstract: A UV-bandpass filter for transmitting therethrough light having a wavelength included in a UV-region. The bandpass filter is an optical filter including a thin silver film; wherein the thin silver film includes an entrance face and an exit face opposing the entrance face, for emitting light having a wavelength included in a specific UV-region whose wavelength ranges from 250 nm to 400 nm in the light having reached the entrance face, and has such a thickness as to yield a transmittance of 10% or less with respect to light having a wavelength excluding the specific UV-region.

Abstract: The invention relates to a security marking whose level of proof against forgery is greater than that of known security markings, comprising liquid-crystalline material with chiral phase, wherein the security marking is imperceptible to the eye and the properties of the liquid-crystalline material with chiral phase can be detected with the aid of detection systems.

Abstract: An article of manufacture marked with compositions comprising rare earth metal compounds which, due to their luminescence when irradiated with UV light, are suitable in particular for the marking of security-relevant items, such as documents or data carriers.

Abstract: Disclosed herein is an ultraviolet (UV) light-blocking composition comprising a metal nanoparticle that absorbs and blocks a UV light wavelength using a surface plasmon-absorbing wavelength, and a dielectric. The UV light-blocking composition is capable of absorbing and blocking a UV light wavelength or, a specific wavelength, using the surface plasmon-absorbing wavelength of the metal nanoparticle or, the plasmon-absorbing wavelength transited by the dielectric, thereby demonstrating increased visibility when applied to an image display apparatus such as a mobile phone, and the like.

Abstract: A near-infrared ray shielding paint capable of forming a coating that exhibits high light transmission coefficient in visible light region while having high shielding capability in near-infrared region and exhibits little chromaticity change even in harsh environment, which near-infrared ray shielding paint comprises a first near-infrared ray-absorption coloring matter containing a compound composed of a diimonium compound cation and an anion of the formula (1), a second near-infrared ray-absorbing coloring matter of different type and a transparent resin in which a compound of the formula (2) is polymerized in an amount of 30% by mass or more. A near-infrared ray shielding laminate having a near-infrared ray shielding layer is produced with the use of this paint. (CF3SO2)2N? ??(1) [R is H or a —CH3 group, and X is a C6-C25 cyclohydrocarbon group].

Abstract: One embodiment of the invention provides a method including molding composite panels that are UV resistant, substantially free of fiber readout, and have visible fibers from epoxy compositions comprising resins having aromatic rings.

Abstract: Methods of forming UV-absorbent transparent coatings and transparent substrates coated with the same allow for a relatively lower temperature cross-linkage reaction between a UV-absorbent compound and an epoxy-alkoxysilane. More specifically, UV-absorbent coatings on transparent substrates are formed by prepolymerizing a mixture consisting essentially of a benzophenone, an epoxy alkoxysilane and an organic catalyst at a temperature of between about 40° C. to about 130° C. and for a time sufficient such that between about 30% to about 70% of the epoxy alkoxysilane has been converted to a ring-opened oligomer or polymer. Such prepolymerized mixture may then be hydrolyzed and coated onto the surface of a transparent substrate, and thereafter cured at a temperature of less than about 200° C. for a time sufficient to cross-link the hydrolyzed alkoxysilane with itself and the glass surface.

Abstract: The present invention relates to particles or powders of a compound of formula Zn1?yMyO1?xSx, wherein x has a value in the range from 0.01 to 0.08, M represents a divalent metal and y has a value in the range from 0 to 0.2, the compound having a wurtzite structure.

Abstract: A plastic lens which absorbs ultraviolet light having wavelength of about 400 nm and suppresses coloring and a process for producing the lens. A plastic lens may be made from a composition which comprises (A) a lens material monomer comprising diethylene glycol bisallylcarbonate, (B) an organic peroxide-based polymerization initiator, (C) a cobalt compound represented by at least one of CoO.Al2O3 and Co.Al2O4, and (D) at least one ultraviolet light absorbent selected from 2-hydroxy-4-octyloxy-benzophenone, 2,2?,4,4?-tetrahydroxy-4-octyloxybenzophenone and 2,2?,4?-trihydroxy-4-octyloxybenzophenone. A process for producing a plastic lens comprises mixing component (A), component (B), a cobalt fluid comprising component (C) in a dispersant and component (D) and a step of casting the mixed fluid into a mold and polymerizing the fluid to obtain a plastic lens.

Abstract: Photochromatic compounds belonging to the groups of chromenes and spiro-pyrans having general formula (I)

Abstract: A resin composition which can enhance the heat resistance and the humidity resistance of a dye possessing the maximum absorption at wavelengths in the range of 380–780 nm is provided. It is obtained by polymerizing a monomer mixture containing 5–100 wt. % of a monomer represented by the formula: CH2?CR—COOX (wherein R denotes a hydrogen atom or a methyl group and X denotes a hydrocarbon group of 4–25 carbon atoms) and/or a fluorine atom-containing unsaturated monomer and containing a dye possessing the maximum absorption at wavelengths in the range of 380–780 nm in an acryl type resin having an acid value in the range of 0–30 mgKOH/g and a hydroxyl value in the range of 0–30 mgKOH/g.

Abstract: Disclosed is a photochromic golf ball with a one- or multi-piece structure, which comprises a photochromic compound. The photochromic golf ball reversibly changes between two different color states according to exposure to U.V. radiation associated with direct sunlight. The photochromic golf ball is white when it is shielded from direct sunlight, but changes in color when it is directly exposed to direct sunlight. In a golf ball structure having a core, an outer cover, and a transparent coating, the photochromic compound is present either in the outer cover or the transparent coating.

Abstract: A composition formed from Group II fluorides in which the composition has little or no intrinsic birefringence at a selected wavelength. The composition is a mixed solid solution of CaF2 with a second crystal of SrF2 or BaF2. The resulting composition is in the form of Ca1?xSrxF2 or Ca1?xBaxF2, or a combination of SrF2 and BaF2, in the form of Ca1?x?ySrxBayF2. The specific form of the composition that effectively nulls out the intrinsic birefringence at a selected wavelength within the UV range is determined in one preferred method from the magnitudes of the intrinsic birefringences of the components, CaF2, SrF2, and BaF2.

Abstract: An optical filter comprises a transparent support and a filter layer. The filter layer contains a dye and a binder polymer. The dye is in an aggregated form exhibiting an absorption maximum in the wavelength region of 750 to 1,100 nm. The support, the filter layer or an optional layer contains an ultraviolet absorbing agent represented by the formula (I), (II), (III) or the like.

Abstract: A photochromic film includes a laminated film including a composite oxide film composed of at least two elements, one of the two elements selected from the group consisting of Ti, Mn, Co, Ni, Zn, and Sn, and the other of the two elements selected from the group consisting of Mg and Al, respectively, and a transparent conductive film, wherein the light transmission property is changed by UV irradiation.

Abstract: The present invention relates to the use of water soluble melanin in solid plastic films of polyvinyl alcohol to be used in conjunction with other plastics to make laminated sheets or lenses. Such laminates will be used as filters to protect against photochemical damage from electromagnetic radiation.

Abstract: The present invention is directed to an ultraviolet absorber composition which is formed by melt-mixing a compound (A) represented by formula (I): and a resin stabilizer (B) selected from the group consisting of a phenolic antioxidant (b-1), a phosphorus-containing antioxidant (b-2), a hindered amine stabilizer (b-3), and an ultraviolet absorber (b-4) other than the compound (A), at a mass ratio (A)/(B) of 95/5 to 50/50. The composition has excellent compatibility with synthetic resins and provides a stabilized synthetic resin molding.

Abstract: The invention relates to a mixture, comprising (A) 10 to 90 wt. % of at least one C6 to C18 alkyl ester, or C5 to C8 cycloalkyl ester of 2-cyano-3,3-diphenylacrylic acid and (B) 90 to 10 wt. % of at least one further compound, with at least one UV absorption maximum in the range 280 to 450 nm and structurally different from compound (A). Said mixture is suitable for the protection of human skin from damaging UV radiation and for the protection of coloured textile materials from colour fading.

Abstract: An optical adhesive polyester film comprising (A) a polyester film layer containing an aromatic polyester and an ultraviolet absorber and (B) a coating formed on at least one surface of the polyester film (A). The coating (B) contains at least one polymer selected from the group consisting of a coating polyester having a glass transition point of 40 to 100° C. and an acryl polymer having a glass transition point of 20 to 80° C. in an amount of 50 to 95% by weight based on the coating. The optical adhesive polyester film is disposed on the front of a plasma display so as to block externally incoming ultraviolet light.

Abstract: A high refractive index, curable, synthetic resin composition comprising a core resin composition composed of a mixture of ethylenically unsaturated compounds, and an initiation system containing both photo and thermal initiators, particularly a photochromic resin composition which further includes at least one photochromic dye. Also a curing process, which includes a combination of multi-step radiation curing and thermal annealing. Articles produced of cured composition exhibit superior physical and, in appropriate cases, photochromic properties and can be easily mass produced on a commercial scale due to short processing time and use of readily available chemicals.

Abstract: A UV-protective composition comprising a water-soluble polyaminoamide containing 1,3-diimine groups, wherein the polyaminoamide containing 1,3-diimine groups absorbs ultraviolet light radiation having a wavelength of about 200 nm to about 420 nm, and methods of treating substrates with the UV-protective polyaminoamide containing 1,3-diimine groups.

Abstract: An ultraviolet-absorbing film comprising a fluorescent brightening agent and having a transmission of the rays of 410 nm or less of 90% or less, wherein the fluorescent brightening agent is represented by the following formula (I): wherein R1 and R4 each represents a hydrogen atom, an alkyl group or an alkoxyl group; R2 and R3 each represents an alkyl group; and [A] represents a substituted aryl or substituted ethenyl group.

Abstract: The invention provides an optical filter comprising: a. an organic, solar blind filter dye; and b. a UV-transparent, non-scattering and chemically stable substrate. The substrate may be a UV-transparent nanoporous silica glass solid having pores that are substantially filled with a UV-transparent solvent, which has been selected to dissolve said dye and also to match the refractive index of the nanoporous silica glass solid. Alternatively, the substrate may be a UV-transparent inorganic salt compressed to form a solid body. The invention also provides for methods of making these embodiments and an optical device comprising such an optical filter. The filter provides an efficient solar blind filter that is chemically and dimensionally stable.

Abstract: The invention features an optical medium for calibrating UV absorbance detectors, methods for making such an optical medium, and methods for calibrating UV absorbance detectors using such a medium. The optical calibration medium includes a gel-sol silica glass monolith with a rare-earth dopant therein. The rare-earth dopant exhibits at least one spectral feature in at least the far UV range. The constituents of the gel-sol silica glass monolith are selected so the rare-earth doped sol-gel glass monolith exhibits a transmittance in the far UV range so each distinct spectral feature of the rare-earth dopant in the far UV range is discernable. The transmittance in a particular embodiment is at least about 50% at about 250 nm. The rare earth materials selected for use as dopants are those exhibiting a wide range of spectral features, preferably over a range from about 190 nm to about 700 nm and more particularly exhibit at least one distinct spectral feature in the range from about 190 nm to about 300 nm.

Abstract: A fluorescent lamp cover which comprises a transparent resin containing a fluorescent brightening agent so as to cut off 90% or more of the rays of 410 nm or less, wherein the fluorescent brightening agent is represented by the following formula (I): 1

Abstract: The present invention relates to an ultraviolet absorber for synthetic resins composed of a triazine compound represented by the general formula (I) shown below 1

Abstract: There is disclosed an optically active polysilane represented by the following general formula: wherein R1 and R2 are a combination of (R)-3,7-dimethyloctyl group and (S)-3-methylpentyl group, R3 is an alkyl group having 3 to 20 carbon atoms and formed of a branched structure which is branched at any one of the first to fourth carbon atoms positioned away from the backbone chain, R4 is a straight-chain alkyl ether group having 2 to 22 carbon atoms, or a straight-chain alkyl group having 2 to 22 carbon atoms, x is a number ranging from 0.01 to 0.99, and n is a number ranging from 10 to 100,000.

Abstract: Improved compounds and base precursors that undergo thermal decomposition are disclosed. Thermal-dye-bleach agents, and in particular, a novel class of salts of arylsulfonylacetic acids as bleaching agents for photothermographic use are disclosed. Photothermographic elements employing these thermal-dye-bleach agents are suitable for use as acutance and antihalation systems, bleachable filter dye materials, and in promoting unblocking of various components such as blocked developers, especially in in photothermographic elements.

Abstract: The present invention relates to an epoxy resin composition comprising at least (A) an epoxy resin having a cycloalkane ring or cyclohexene ring but having neither aromatic ring nor aminic nitrogen atom, (B) a carboxylic anhydride having no aromatic ring, and (C) an ultraviolet absorbent, wherein a content of component (A) is from 70 to 100 percents by weight based on the total weight of epoxy resins, and a content of component (B) is from 70 to 100 percents by weight based on the total weight of carboxylic anhydrides.

Abstract: Use of a semi-crystalline polymer in a composition containing at least one organic UV screening agent. The polymer makes it possible to increase the sun protection factor (SPF). In addition, the semi-crystalline polymer makes it possible to introduce better dispersion of screening agents and confers, on the composition, good resistance to water (waterproof effect) and better spreading qualities. Composition for the photoprotection of keratinous substances, in particular for the protection of the skin and/or hair against solar radiation.

Abstract: A crystal filter and a method of making a crystal filter capable of transmitting radiation within a particular pass band is disclosed. The crystal filter is particularly appropriate for a UV detection system, where the pass band is between about 200 to about 350 nm. A UV detection system incorporating the crystal filter is also described. One embodiment of crystal filter is formed from a single-crystal transparent host, such as a fluoride host, codoped with lanthanide or actinide fluorides and lanthanide or actinide nitrides, oxides, borides, carbides or hydroxides. Filter crystals according to the present invention can be grown by various crystal growth methods, including Czochralski and Bridgeman crystal growth methods.

Abstract: Materials for, and methods of protecting yarns, fibers, fabrics and finished textiles from the deleterious effects of ultraviolet radiation. The materials include at least one physical UVR attenuator, having an average particle size below 1000 nanometers, and at least one flexible, film-forming polymeric binder for bonding the material to a fabric surface, wherein the physical UVR attenuator is dispersed within said binder to form an aqueous dispersion. Also disclosed are materials including both physical and chemical UVR attenuators, in which a synergistic protection effect is achieved.

Abstract: A heat-sensitive recording material including a support having succesively disposed thereon a heat-sensitive recording layer, a light transmittance adjusting layer and a protective layer, wherein the light transmittance adjusting layer contains a UV absorbent precursor represented by the general formula (1): 1

Abstract: Novel ultraviolet absorbing compounds that are liquid in nature, are extremely low in color (and thus permit use without the concomitant necessity of adding large amounts of other coloring agents to combat such discoloring), and are highly effective in providing protection in wavelength ranges for which previous attempts at low-color ultraviolet absorbers have failed are provided herein. Such compounds provide such excellent, inexpensive, and beneficial protection from ultraviolet exposure within various media, including, but not limited to, clear thermoplastics. The particular compounds are generally polymeric in nature including various chain lengths of polyoxyalkylenes thereon and are liquid in nature to facilitate handling and introduction within the target media. In addition, such ultraviolet absorbers also exhibit extremely low migratory properties thereby providing long-term protective benefits to the target media as well.

Abstract: The present invention relates to a material comprising a matrix, apatite and at least one europium composite compound of the general formula MexmMy3Rzn, wherein mx+3y=nz; Mexm=Mex′m′+Mex″m″+ . . . ; Rzn=Rz′n′+Rz″n″+ . . . ; mx=m′x′+m″x″+ . . . ; nz=n′z′+n″z″+ . . . ; x≧1.0 ≧y≧0.01. Me represents yttrium, lanthanum, cerium, praseodymium, neodymium, samarium, europium, gadolinium, dysprosium, holmium, erbium, ytterbium, aluminum, bismuth, tin, titanium, manganese, calcium, barium, zinc, cadmium, sodium, potassium, rubidium, cesium, R represents oxygen, sulfur, fluorine, bromine, phosphorus, boron, vanadium, molybdenum, tungsten, germanium or compounds thereof, and m and n represent the charge of a Me or R ion, respectively. The composition for the production of the material comprises (wt. % ) apatite 0.01-10.

Abstract: This invention provides a synthetic silica glass optical member used together with light having a specific wavelength of 250 nm or less, in which the difference between the maximum value and the minimum value of transmittance [%/cm] per cm in thickness for the light in a predetermined direction within a plane perpendicular to the optical axis is 2.0%/cm or less.

Abstract: Novel ultraviolet absorbing compounds that are liquid in nature, are extremely low in color (and thus permit use without the concomitant necessity of adding large amounts of other coloring agents to combat such discoloring), and are highly effective in providing protection in wavelength ranges for which previous attempts at low-color ultraviolet absorbers have failed are provided herein. Such compounds provide such excellent, inexpensive, and beneficial protection from ultraviolet exposure within various media, including, but not limited to, clear thermoplastics. The particular compounds are generally polymeric in nature including various chain lengths of polyoxyalkylenes thereon and are liquid in nature to facilitate handling and introduction within the target media. In addition, such ultraviolet absorbers also exhibit extremely low migratory properties thereby providing long-term protective benefits to the target media as well.

Abstract: The present invention provides indolinospiropyran compounds and methods for their manufacture, which compounds are useful as photochromic compounds. The compounds of the invention are substituted on the indole ring with succinimide, which substitution permits ring opening of the succinimide and modulation of the bulk and photochromic properties of the compounds. The compounds may be conveniently prepared using the solid phase organic synthesis of the invention.

Abstract: The present invention relates to methods for using a maleimide of formula (I) with the proviso that R1 and R2 do not simultaneously stand for phenyl or a maleimide of formula Ia as UV fluorescent material for void detection and for the preparation of scintillators films, luminescent solar energy collectors, organic electroluminescent devices, printing inks, non-impact printing inks, electrophotographic toners, color filters, and colored high molecular organic material.

Abstract: The present invention relates to a process for protecting hair and skin from the deleterious effects of ultra violet radiation using topical applications of a novel dimethicone copolyol compounds bearing ultra violet absorbing substituents.

Abstract: A class of molecules suitable for linear and nonlinear optical applications which include charged aromatic groups which function as electronic donors and acceptors connected through polyhedral and &pgr;-organic and inorganic groups. The polyhedral and &pgr;-organic and inorganic groups function as structural and electronic bridges for the charged donors and acceptors.

Abstract: An ultraviolet light absorber containing, as an active ingredient, a zinc oxide type solid solution which is represented by the formula (1), (Zn)1−xM3+x−&dgr;O   (1) wherein M3+ is a trivalent metal such as Al, Fe, Ce or Ti, x is a number in the range of 0<x<=0.2, and &dgr; is a cationic lattice defect, and has an average secondary particle diameter of from 0.1 to 1.5 &mgr;m in a plate form and a BET specific surface area of at least 5 m2/g, an ultraviolet light resistant resin composition containing a resin and the above zinc oxide type solid solution and a sun block cosmetic material containing the above zinc oxide type solid solution.

Abstract: UV-absorbers of the 4-alkoxy-2-hydroxyphenyl-s-triazine type are incorporated in a cellulose triacetate film. Such an UV-cut off film can be used advantageously, amongst others, as protective sheet for a polarizer in a Liquid Crystal Display.

Abstract: The invention features an optical medium for calibrating UV absorbance detectors, methods for making such an optical medium, and methods for calibrating UV absorbance detectors using such a medium. The optical calibration medium includes a gel-sol silica glass monolith with a rare-earth dopant therein. The rare-earth dopant exhibits at least one spectral feature in at least the far UV range. The constituents of the gel-sol silica glass monolith are selected so the rare-earth doped sol-gel glass monolith exhibits a transmittance in the far UV range so each distinct spectral feature of the rare-earth dopant in the far UV range is discernable. The transmittance in a particular embodiment is at least about 50% at about 250 nm. The rare earth materials selected for use as dopants are those exhibiting a wide range of spectral features, preferably over a range from about 190 nm to about 700 nm and more particularly exhibit at least one distinct spectral feature in the range from about 190 nm to about 300 nm.

Abstract: The invention features an optical medium for calibrating UV absorbance detectors, methods for making such an optical medium, and methods for calibrating UV absorbance detectors using such a medium. The optical calibration medium includes a gel-sol silica glass monolith with a rare-earth dopant therein. The rare-earth dopant exhibits at least one spectral feature in at least the far UV range. The constituents of the gel-sol silica glass monolith are selected so the rare-earth doped sol-gel glass monolith exhibits a transmittance in the far UV range so each distinct spectral feature of the rare-earth dopant in the far UV range is discernable.

Abstract: A neutral titanium dioxide colloid sol having a high stability in a neutral range and capable of forming a colorless transparent coating even when dried at room temperature is produced by mixing an acid titanium dioxide sol comprising 50 to 100 parts by weight of titanium dioxide colloidal particles and 5 to 50 parts by weight of a chelating agent for titanium ions with 1 to 50 parts by weight of an alkaline substance comprising at least one of alkali metal compounds and amine compounds, and optionally by adjusting the pH value of the liquid mixture to 5 to 10, or adjusting the pH value of the liquid mixture to 6 to 10, and then applying a deionization treatment to the mixture to thereby charge the titanium dioxide colloidal particles with negative electricity.

Abstract: A two-layer coating system blocks ultraviolet radiation up to and including 400 nanometers, the upper end of ultra violet light. An inner layer blocks radiation from about 375 nanometers to 400 nanometers. An outer layer absorbs radiation up to 375 nanometers.

Abstract: A crystal having good optical transmission between 260 nm and 280 nm and strongly absorbing at 285 nm and higher, which is nonhydroscopic and stable at temperatures to 250° C. An example of such a crystal is Cerium doped YLiF4. These properties make YLiF4 crystals doped with Ce3+ excellent materials for use as UV filters in the missile early warning spectral band. Optical devices including missile detection systems are also provided.