With Scandium, Yttrium, Gallium, Rare Earth, Or Actinide Patents (Class 252/62.57)
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Patent number: 12183493Abstract: Provided is a ferrite sintered magnet including a ferrite phase having a magnetoplumbite-type crystal structure. x, y, and m satisfy the following Equations (1), (2), and (3) when composition of the ferrite sintered magnet is represented by R1-xAxFem-yCoy, where R denotes at least one kind of element selected from rare earth elements including Y and A denotes Ca or Ca and elements including at least one kind selected from Sr or Ba. The content of B in the ferrite sintered magnet is from 0.1% to 0.6% by mass in terms of B2O3. 0.2?x?0.8??(1) 0.1?y?0.Type: GrantFiled: May 19, 2023Date of Patent: December 31, 2024Assignee: TDK CorporationInventors: Junnichi Nagaoka, Hitoshi Taguchi, Yuichi Sugawara, Jo Sato
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Patent number: 11569013Abstract: This ferrite magnet has a magnetoplumbite structure and is characterized in that, when representing the composition ratios of the total of each metal element A, R, Fe and Me with expression (1) A1-xRx(Fe12-yMey)z, the Fe2+ content (m) in the ferrite magnet is greater than 0.1 mass % and less than 5.4 mass % (in expression (1), A is at least one element selected from Sr, Ba, Ca and Pb; R is at least one element selected from the rare-earth elements (including Y) and Bi, and includes at least La, and Me is Co, or Co and Zn). The invention makes it possible to achieve a ferrite magnet with increased Br.Type: GrantFiled: May 19, 2017Date of Patent: January 31, 2023Assignee: TDK CORPORATIONInventors: Junnichi Nagaoka, Hitoshi Taguchi
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Patent number: 11562839Abstract: A core-shell particle includes: a core including an iron oxyhydroxide compound represented by Formula A3a3Fe1?a3OOH (in which A3 represents at least one metal element other than Fe, and a3 satisfies 0<a3<1) or at least one iron oxide compound selected from the group consisting of Fe2O3, a compound represented by Formula A1a1Fe2?a1O3 (in which A1 represents at least one metal element other than Fe, and a1 satisfies 0<a1<2), Fe3O4, and a compound represented by Formula A2a2Fe3?a2O4 (in which A2 represents at least one metal element other than Fe, and a2 satisfies 0<a2<2); and a shell which covers the core and includes a polycondensate of a metal alkoxide.Type: GrantFiled: May 9, 2018Date of Patent: January 24, 2023Assignee: FUJIFILM CorporationInventors: Kenji Naoi, Takashi Fujimoto, Masashi Shirata
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Patent number: 11450344Abstract: The magnetic recording medium includes a non-magnetic support; and a magnetic layer including a ferromagnetic powder, in which the ferromagnetic powder is an ?-iron oxide powder having an average particle size of 9.0 nm to 20.0 nm, and in the ?-iron oxide powder, a content of particles having a particle size smaller than 8.0 nm is less than 20.0% by mass, a content of particles having a particle size smaller than 6.0 nm is less than 5.0% by mass, and a content of particles having a particle size greater than 25.0 nm is less than 20.0% by mass.Type: GrantFiled: August 6, 2020Date of Patent: September 20, 2022Assignee: FUJIFILM CorporationInventors: Kenji Naoi, Koichi Yagishita
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Patent number: 11373788Abstract: Disclosed are embodiments of synthetic garnet materials for use in radiofrequency applications. In some embodiments, increased amounts of gadolinium can be added into specific sites in the crystal structure of the synthetic garnet by incorporating indium, a trivalent element. By including both indium and increased amounts of gadolinium, the dielectric constant can be improved. Thus, embodiments of the disclosed material can be advantageous in both above and below resonance applications, such as for isolators and circulators.Type: GrantFiled: May 7, 2018Date of Patent: June 28, 2022Assignee: Skyworks Solutions, Inc.Inventors: Michael David Hill, David Bowie Cruickshank
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Patent number: 11289250Abstract: A sintered ferrite magnet represented by the general formula of Ca1-xLaxFe2n-y-zCoyZnz expressing the atomic ratios of metal elements of Ca, La, Fe, Co and Zn, wherein x, y, z, and n [2n is a molar ratio represented by 2n=(Fe+Co+Zn)/(Ca+La)] meet 0.4<x<0.75, 0.15?y<0.4, 0.11?z<0.4, 0.26?(y+z)<0.65, and 3?n?6.Type: GrantFiled: May 17, 2018Date of Patent: March 29, 2022Assignee: HITACHI METALS, LTD.Inventors: Masaki Yamamoto, Yoshinori Kobayashi
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Patent number: 11264155Abstract: An object of the present invention is to provide a magnetic powder having a narrow particle size distribution of epsilon-type iron oxide particles, and another object is to provide magnetic powder suitable for magnetic recording medium by improving particle size distribution, and provide epsilon-type iron oxide magnetic particles and related technologies in which a number average particle diameter of major diameters (D50) is 10 to 20 nm, a 90% cumulative particle diameter (D90) is 30 nm or less, and a geometric standard deviation (?g) of major diameters is 1.45 or less, which are obtained by TEM observation.Type: GrantFiled: September 29, 2017Date of Patent: March 1, 2022Assignee: DOWA ELECTRONICS MATERIALS CO., LTD.Inventors: Kazuhiro Yamaga, Tetsuya Kawahito, Toshihiko Ueyama, Kenji Sakane
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Patent number: 10875095Abstract: An electronic component includes a body made of an insulator, a coating film covering the body, a conductor located in the body, and outer electrodes each of which is connected to the conductor. The insulator contains a magnetic metal powder. The coating film is composed of resin and cations of a metal which is a cationic element contained in the insulator and which has a standard electrode potential E0 of less than about 0 V.Type: GrantFiled: March 15, 2016Date of Patent: December 29, 2020Assignee: Murata Manufacturing Co., Ltd.Inventors: Mitsunori Inoue, Hironobu Kubota
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Patent number: 10720272Abstract: The present invention produces a ferrite magnetic material having a remarkably higher maximum energy product ((BH)max) than a conventional ferrite magnetic material through the induction of a high saturation magnetization and a high anisotropic magnetic field by simultaneously adding Co and Zn to substitute some of Fe and adjusting the content ratio of Zn/Co. In addition, the present invention can produce a desired magnetic material at a lower cost than a conventional CaLaCo-based ferrite magnetic material substituted with only Co by using Zn, which is relatively at least seven times cheaper than Co, together with Co.Type: GrantFiled: September 1, 2016Date of Patent: July 21, 2020Assignee: UNION MATERIALS CORPORATIONInventors: Min-Ho Kim, Dong-Young Lee, Jung-Hwan Lee
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Patent number: 10714247Abstract: The present invention relates to a ferrite sintered plate having a composition comprising 47 to 50 mol % of Fe2O3, 7 to 26 mol % of NiO, 13 to 36 mol % of ZnO, 7 to 12 mol % of CuO and 0 to 1.5 mol % of CoO, as calculated in terms of the respective oxides, in which the ferrite sintered plate has a volume resistivity of 1×108 to 1×1012·cm and a thickness of 10 to 60 ?m; and a ferrite sintered sheet comprising the ferrite sintered plate on a surface of which a groove or grooves are formed, and an adhesive layer and/or a protective layer formed on the ferrite sintered plate, in which the ferrite sintered sheet has a magnetic permeability at 500 kHz a real part of which is 120 to 800 and an imaginary part of which is 0 to 30, and a product (?m) of the real part of the magnetic permeability at 500 kHz of the ferrite sintered sheet and a thickness of the ferrite sintered plate is 5000 to 48000.Type: GrantFiled: May 21, 2015Date of Patent: July 14, 2020Assignee: TODA KOGYO CORP.Inventors: Yoji Okano, Makoto Sadai, Shingo Honda, Mitsunori Kurumada, Akihiro Yoshida, Kazuyoshi Kawato
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Patent number: 10688201Abstract: A method of synthesizing a radiolabeled nanoparticle. The method includes heating a solution including an iron oxide nanoparticle and at least one radioactive metal ion to bind the iron oxide nanoparticle and the at least one radioactive metal ion, thereby forming the radiolabeled nanoparticle. The method further includes adding a quenching agent to the solution to complex with non-bound radioactive metal ions remaining in the solution. The method further includes separating the complexed quenching agent from the radiolabeled nanoparticle.Type: GrantFiled: October 9, 2014Date of Patent: June 23, 2020Assignee: The General Hospital CorporationInventors: Jason Philip Holland, Lee Josephson
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Patent number: 10141091Abstract: A ferrite magnetic material comprising a primary phase of a magnetoplumbite-type hexagonal ferrite, the primary phase having a composition represented by formula (I), can provide improved magnetic properties in terms of the residual magnetic flux density (Br), intrinsic coercive force (iHc), squareness (Hk/iHc), and maximum energy product (B.Hmax). Therefore, a segment-type permanent magnet derived therefrom can be used in the manufacture of small type motors for automobiles, motors for electric equipments as well as for home appliances, and other devices.Type: GrantFiled: May 16, 2012Date of Patent: November 27, 2018Assignee: UNION MATERIALS CORPORATIONInventors: Kilsoo Park, Minho Kim, Dongyoung Lee
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Patent number: 10096412Abstract: The present invention provides a rare earth based magnet including R2T14B main-phase crystal grains, and two-grain boundary phases between adjacent two R2T14B main-phase crystal grains, the two-grain boundary phases are controlled such that the thickness thereof is 5 nm or more and 500 nm or less, and it is composed of a phase with a magnetism different from that of a ferromagnet.Type: GrantFiled: March 28, 2014Date of Patent: October 9, 2018Assignee: TDK CORPORATIONInventors: Eiji Kato, Yoshinori Fujikawa, Taeko Tsubokura, Chikara Ishizaka, Katsuo Sato
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Patent number: 9808543Abstract: Iron garnet nanoparticles and or iron garnet particles containing various activatable nuclides, such as holmium-165 (165Ho) and dysprosium-164 (164Dy), are disclosed in this application. The iron garnet (e.g., HoIG and DyIG) nanoparticles and iron garnet particles can prepared using hydroxide co-precipitation methods. In some embodiments, radiosensitizers can be loaded on radioactive magnetic nanoparticles or radioactive iron garnet particles and, optionally, coated with suitable lipid bilayers. Methods of using the disclosed nanoparticles and particles for mediating therapeutic benefit in diseases responsive to radiation therapy are also provided. Another aspect of the invention provides films, electrospun fabrics or bandage coverings for the delivery of radiation to the site of a skin lesion amenable to treatment with radiation (e.g., skin cancers or psoriasis).Type: GrantFiled: January 20, 2015Date of Patent: November 7, 2017Assignees: UNIVERSITY OF NORTH TEXAS HEALTH SCIENCE CENTER AT FORT WORTH, THE BOARD OF REGENTS OF THE UNIVERSITY OF TEXAS SYSTEMInventors: Anthony J. Di Pasqua, Kenneth J. Balkus, Jr., Imalka S. Munaweera, Yi Shi
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Patent number: 9697937Abstract: An object of the present invention is to provide a ferrite material that is excellent in temperature characteristic and DC superimposition characteristic. The present invention relates to Ni—Zn—Cu-based ferrite particles comprising 70 to 95% by weight of an Ni—Zn—Cu ferrite having a specific composition, 1 to 20% by weight of nickel oxide, 0 to 20% by weight of zinc oxide and 1 to 10% by weight of copper oxide, and a ferrite sintered ceramics obtained by sintering the ferrite particles.Type: GrantFiled: February 7, 2013Date of Patent: July 4, 2017Assignee: TODA KOGYO CORP.Inventors: Yoji Okano, Tomohiro Dote, Takanori Doi
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Patent number: 9630172Abstract: Provided are a titanium dioxide-coated upconverting nanoparticle (UCNP) and a photocatalyst complex containing a gold nanorod (GNR) combined with the titanium dioxide-coated UCNP.Type: GrantFiled: July 3, 2014Date of Patent: April 25, 2017Assignee: GWANGJU INSTITUTE OF SCIENCE AND TECHNOLOGYInventors: Min-Gon Kim, Hyo-Young Mun, Ju-Young Byun, Taihua Li, Jin-Ho Park
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Patent number: 9627112Abstract: A sintered ferrite magnet comprises a main phase of an M type Sr ferrite having a hexagonal crystal structure. An amount of Zn is 0.05 to 1.35 mass % in terms of ZnO and M1/M2 is 0.43 or less when an amount of a rare-earth element (R) is M1 in terms of mol and the amount of Zn is M2 in terms of mol.Type: GrantFiled: March 4, 2015Date of Patent: April 18, 2017Assignee: TDK CORPORATIONInventors: Yoshitaka Murakawa, Naoharu Tanigawa, Yoshihiko Minachi, Hitoshi Taguchi
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Patent number: 9552914Abstract: This application relates to devices in which magnets are arranged so that an intensity of a magnetic field emitted by the magnets is substantially the same at a position of interest for at least two discrete positions of the magnets. The application describes how this can be achieved even when the discrete positions are different distances from the position of interest by identifying locations at which magnetic material can be added to balance the field intensity for both discrete locations. In some embodiments, this type of configuration can be helpful in accommodating movement of magnets between two common positions. When the magnetic field intensity for the position of interest is set near zero a magnetically sensitive component can be positioned at the point of interest with little or no effect from the magnetic field when the magnets are in any of the discrete positions.Type: GrantFiled: May 19, 2015Date of Patent: January 24, 2017Assignee: Apple Inc.Inventor: James A. Stryker
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Patent number: 9527776Abstract: Embodiments disclosed herein include methods of modifying synthetic garnets used in RF applications to reduce or eliminate Yttrium or other rare earth metals in the garnets without adversely affecting the magnetic properties of the material. Some embodiments include substituting Bismuth for some of the Yttrium on the dodecahedral sites and introducing one or more high valency ions to the octahedral and tetrahedral sites. Calcium may also be added to the dodecahedral sites for valency compensation induced by the high valency ions, which could effectively displace all or most of the Yttrium (Y) in microwave device garnets. The modified synthetic garnets with substituted Yttrium (Y) can be used in various microwave magnetic devices such as circulators, isolators and resonators.Type: GrantFiled: February 26, 2014Date of Patent: December 27, 2016Assignee: Skyworks Solutions, Inc.Inventors: David Bowie Cruickshank, Michael David Hill
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Patent number: 9487411Abstract: The method of manufacturing magnetic particles, wherein the magnetic particles are magnetic particles for magnetic recording, and includes subjecting starting material magnetic particles to glass component-adhering treatment to be adhered with a glass component, and subjecting the magnetic particles after the glass component-adhering treatment to coercive force-reducing treatment with heating, to provide magnetic particles having lower coercive force than the starting material magnetic particles.Type: GrantFiled: April 22, 2014Date of Patent: November 8, 2016Assignee: FUJIFILM CorporationInventor: Yasushi Hattori
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Patent number: 9458026Abstract: To provide a method for improving a coercive force of epsilon-type iron oxide particles, and an epsilon-type iron oxide. Specifically, to provide a method for improving the coercive force of an epsilon-type iron oxide comprising: substituting Fe-site of the epsilon-type iron oxide with other element, while not substituting Fe of D-site in the epsilon-type iron oxide with other element, and the epsilon type iron oxide.Type: GrantFiled: September 30, 2010Date of Patent: October 4, 2016Assignees: THE UNIVERSITY OF TOKYO, DOWA ELECTRONICS MATERIALS CO., LTD.Inventors: Shin-ichi Ohkoshi, Shunsuke Sakurai, Asuka Namai, Sayaka Umeda, Hiroshi Hachiya, Kazuyuki Matsumoto, Takashi Gotoh
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Patent number: 9460837Abstract: Disclosed are a multilayered power inductor, including: a body in which a plurality of magnetic layers formed with inner electrodes are stacked; and a plurality of gap layers, wherein the plurality of gap layers are formed so as not to contact external electrodes formed at both sides of the body, and a gap composition of the multilayered power inductor. In addition, as the gap composition, the exemplary embodiment of present invention can prepare tetravalent or tetravalent dielectric oxide into the paste type and applies the gap layer structure thereto, thereby facilitating the structural design and the thickness control of the gap layer as compared with the case of forming the gap layer in the sheet shape of the related art and improving the DC-bias characteristics by maximally suppressing the diffusion with the body.Type: GrantFiled: June 28, 2012Date of Patent: October 4, 2016Assignee: SAMSUNG ELECTRO-MECHANICS CO., LTD.Inventors: Soo Hwan Son, Sung Yong An, Myeong Gi Kim, So Yeon Song, Byeong Cheol Moon
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Patent number: 9401235Abstract: A sintered ferrite magnet having a main phase composed of ferrite having a hexagonal, M-type magnetoplumbite structure, a grain boundary phase containing Si and Ca with a lower atomic ratio of La than in said main phase, and a third phase containing La at a higher atomic ratio than in said main phase, and a method for producing a sintered ferrite magnet having said third phase by calcining starting materials with more La than Ca, adding more than 1% and 1.8% or less by mass of SiO2 and 1-2% by mass (calculated as CaO) of CaCO3 to the calcined body, and pulverizing, molding and sintering it.Type: GrantFiled: December 26, 2011Date of Patent: July 26, 2016Assignee: HITACHI METALS, LTD.Inventors: Yoshinori Kobayashi, Tsunehiro Kawata
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Patent number: 9263175Abstract: Disclosed are synthetic garnets and related devices that can be used in radio-frequency (RF) applications. In some embodiments, such RF devices can include garnets having reduced or substantially nil Yttrium or other rare earth metals. Such garnets can be configured to yield high dielectric constants, and ferrite devices, such as TM-mode circulators/isolators, formed from such garnets can benefit from reduced dimensions. Further, reduced or nil rare earth content of such garnets can allow cost-effective fabrication of ferrite-based RF devices. In some embodiments, such ferrite devices can include other desirable properties such as low magnetic resonance linewidths. Examples of fabrication methods and RF-related properties are also disclosed.Type: GrantFiled: May 30, 2012Date of Patent: February 16, 2016Assignee: Skyworks Solutions, Inc.Inventors: David Bowie Cruickshank, Rickard Paul O'donovan, Iain Alexander MacFarlane, Brian Murray, Michael David Hill
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Publication number: 20150130550Abstract: Materials, devices and methods related to below-resonance radio-frequency (RF) circulators and isolators. In some embodiments, a circulator can include a conductor having a plurality of signal ports, and one or more magnets configured to provide a magnetic field. The circulator can further include one or more ferrite disks implemented relative to the conductor and the one or more magnets so that an RF signal can be routed selectively among the signal ports due to the magnetic field. Each of the one or more ferrite disks can include synthetic garnet material having dodecahedral sites, octahedral sites and tetrahedral sites, with bismuth (Bi) occupying at least some of the dodecahedral sites, and aluminum (Al) occupying at least some of the tetrahedral sites. Such synthetic garnet material can be represented by a formula Y3-x-2y?zBixCa2y+zFe5-y-z-aVyZrzAlaO12. In some embodiments, x?1.4, y?0.7, z?0.7, and a?0.75.Type: ApplicationFiled: September 16, 2014Publication date: May 14, 2015Inventors: David Bowie CRUICKSHANK, Iain Alexander MACFARLANE, Michael David HILL
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Patent number: 9028705Abstract: A capsule having a solid core, a primary shell of liquid encapsulating the solid core and a secondary shell of particles encapsulating the primary shell. The primary and secondary shells are generally repulsive to each other. Also provided is a process for the manufacture of capsules and a process for the manufacture of a magnetic body.Type: GrantFiled: May 31, 2012Date of Patent: May 12, 2015Assignee: Magnequench LimitedInventors: Zhao Wei, Han Zhisan, David Miller
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Patent number: 8980116Abstract: A sintered ferrite magnet having a ferrite phase with a hexagonal structure as the main phase, wherein the composition of the metal elements composing the main phase is represented by the following general formula (1): RxCamA1?x?m(Fe12?yMy)z: ??(1), x, m, y and z in formula (1) satisfying all of the conditions represented by the following formulas (2)-(6): 0.2?x?0.5: ??(2) 0.13?m?0.41: ??(3) 0.7x?m?0.15: ??(4) 0.18?yz?0.31: ??(5) 9.6?12z?11.8: ??(6), and wherein the density of the sintered ferrite magnet is at least 5.05 g/cm3, and the crystal grains of the sintered ferrite magnet satisfy all of the conditions represented by the following formulas (7) and (8), where L ?m is the average for the maximum value and S ?m is the average for the minimum value among the diameters passing through the center of gravity of each grains in the crystal cross-section parallel to the c-axis direction of hexagonal structures. L?0.95: ??(7) 1.8?L/S?2.5: ??(8).Type: GrantFiled: February 27, 2008Date of Patent: March 17, 2015Assignee: TDK CorporationInventors: Shigeki Yanagida, Noboru Ito, Yuuki Aburakawa, Naoki Mori, Yoshihiko Minachi
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Publication number: 20150069286Abstract: The present invention relates generally to a magnetic catalyst for wet oxidation of organic waste and the preparation method thereof. According to the present invention, after the raw materials are dissolved and mixed in water, the pH value is adjusted for producing precipitates. Then after heating, filtering, drying, grinding, sifting, and calcinations are performed, the given magnetic catalyst can be reused without losing its activity. In addition, during treating organic waste by using wet oxidation method, no secondary waste is produced. Besides, the magnetic catalyst can be recycled by magnetic devices, making it excellent in terms of performance and convenience.Type: ApplicationFiled: September 12, 2013Publication date: March 12, 2015Applicant: ATOMIC ENERGY COUNCIL - INSTITUTE OF NUCLEAR ENERGY RESEARCHInventors: YIH-PING CHEN, CHAO-RUI CHEN, YIN-MAO HSU
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Patent number: 8920670Abstract: A magnetic material of an embodiment includes: first magnetic particles that contain at least one magnetic metal selected from the group including Fe, Co, and Ni, are 1 ?m or greater in particle size, and are 5 to 50 ?m in average particle size; second magnetic particles that contain at least one magnetic metal selected from the group including Fe, Co, and Ni, are smaller than 1 ?m in particle size, and are 5 to 50 nm in average particle size; and an intermediate phase that exists between the first magnetic particles and the second magnetic particles.Type: GrantFiled: August 29, 2012Date of Patent: December 30, 2014Assignee: Kabushiki Kaisha ToshibaInventors: Koichi Harada, Tomohiro Suetsuna, Toshihide Takahashi, Seiichi Suenaga
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Publication number: 20140361214Abstract: An object of the present invention is to provide a ferrite magnetic material which can provide a permanent magnet retaining high Br and HcJ as well as having high Hk/HcJ. The ferrite magnetic material according to a preferred embodiment is a ferrite magnetic material formed of hard ferrite, wherein a P content in terms of P2O5 is 0.001% by mass or more.Type: ApplicationFiled: August 11, 2014Publication date: December 11, 2014Inventors: Junichi NAGAOKA, Takahiro MORI, Hiroyuki MORITA, Yoshihiko MINACHI
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Publication number: 20140291571Abstract: An object of the present invention is to provide, in order to deal with a high frequency band in which radio waves are expected to be increasingly used hereafter, a magnetoplumbite-type hexagonal ferrite material having significantly improved high-frequency property of magnetic permeability. Specifically, a magnetoplumbite-type hexagonal ferrite is represented by a composition formula: A(1-X)BxCx(D1yD2y)Fe(12-x-2y)O19 (where x: 0.1 to 0.3, y:0.1 to 0.5), wherein A is any one of Ba2+, Sr2+ and Ca2+, B is any one of La3+ and Nd3+, C and D1 are any one or more of Co2+, Mn2+, Mg2+, Zn2+, Cu2+ and Ni2+, and D2 is any one of Ti4+ and Zr4+.Type: ApplicationFiled: March 14, 2014Publication date: October 2, 2014Applicant: KABUSHIKI KAISHA RIKENInventor: Keita HIROSE
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Patent number: 8828265Abstract: The invention relates to a modified strontium ferrite of the general chemical formula: Sr1-xLaxFe12-yCoyO19; in which x=y=0.01-1.00 or x=0.15 and y=x/1.6n to =x/2.6n, where n is the Fe2O3:SrO ratio used and may be 5-6. According to the invention, lanthanum and cobalt are added in an amount such that 0.14?x?0.145 and 0.14?y?0.145. The modified strontium ferrite thus prepared has excellent magnetic properties with regard to the remanence BR, the coercive force HCJ and the ratio of HK to HCJ.Type: GrantFiled: December 17, 2009Date of Patent: September 9, 2014Assignee: TRIDELTA Hartferrite GmbHInventor: Kevin Mikenda
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Patent number: 8821650Abstract: A process for mechanically strengthening a permanent magnet includes providing nanofibers or nanotubes, providing a ferromagnetic metal, defining a mixture by mixing the ferromagnetic metal with the nanofibers or nanotubes and sintering the mixture.Type: GrantFiled: August 4, 2009Date of Patent: September 2, 2014Assignee: The Boeing CompanyInventor: Michael Strasik
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Patent number: 8801956Abstract: A hexagonal crystal ferrite magnetic powder having high magnetic characteristics while having a small particle volume and a high specific surface area is provided, and a high-density magnetic recording medium using the powder. A method for producing a hexagonal crystal ferrite formed using a glass crystallization method includes the steps of: mixing a glass matrix with raw materials including iron, bismuth, a divalent metal (M1), a tetravalent metal (M2), any one kind (A) of barium, strontium, calcium, and lead, and at least one kind of rare earth element (represented by R) having a mole equal to or less than that of the iron; heating the mixed raw material to obtain a glass body; quenching the glass body, pulverizing the glass body, and performing a heat treatment, and washing the glass body after the heat treatment with an acid solution.Type: GrantFiled: January 29, 2010Date of Patent: August 12, 2014Assignee: Dowa Electronics Materials Co., Ltd.Inventors: Kenji Masada, Tomoyuki Ishiyama, Gousuke Iwasaki
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Patent number: 8769965Abstract: A magnetic refrigeration material includes: at least one selected from the group consisting of Y, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm and Tb by a range of 4 to 15 atomic percentages; at least one selected from the group consisting of Fe, Co, Ni, Mn and Cr by a range of 60 to 93 atomic percentages; at least one selected from the group consisting of Si, C, Ge, Al, Ga and In by a range of 2.9 to 23.5 atomic percentages; and at least one selected from the group consisting of Ta, Nb and W by a range of 1.5 atomic percentages or less, wherein the magnetic refrigeration material includes a NaZn13 type crystal structure as a main phase.Type: GrantFiled: January 17, 2008Date of Patent: July 8, 2014Assignee: Kabushiki Kaisha ToshibaInventors: Hideyuki Tsuji, Akiko Saito, Tadahiko Kobayashi
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Publication number: 20140175327Abstract: Embodiments disclosed herein include methods of modifying synthetic garnets used in RF applications to reduce or eliminate Yttrium or other rare earth metals in the garnets without adversely affecting the magnetic properties of the material. Some embodiments include substituting Bismuth for some of the Yttrium on the dodecahedral sites and introducing one or more high valency ions to the octahedral and tetrahedral sites. Calcium may also be added to the dodecahedral sites for valency compensation induced by the high valency ions, which could effectively displace all or most of the Yttrium (Y) in microwave device garnets. The modified synthetic garnets with substituted Yttrium (Y) can be used in various microwave magnetic devices such as circulators, isolators and resonators.Type: ApplicationFiled: February 26, 2014Publication date: June 26, 2014Applicant: Skyworks Solutions, Inc.Inventors: David Bowie Cruickshank, Michael David Hill
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Patent number: 8696925Abstract: Embodiments disclosed herein include methods of modifying synthetic garnets used in RF applications to reduce or eliminate Yttrium or other rare earth metals in the garnets without adversely affecting the magnetic properties of the material. Some embodiments include substituting Bismuth for some of the Yttrium on the dodecahedral sites and introducing one or more high valency ions to the octahedral and tetrahedral sites. Calcium may also be added to the dodecahedral sites for valency compensation induced by the high valency ions, which could effectively displace all or most of the Yttrium (Y) in microwave device garnets. The modified synthetic garnets with substituted Yttrium (Y) can be used in various microwave magnetic devices such as circulators, isolators and resonators.Type: GrantFiled: July 14, 2011Date of Patent: April 15, 2014Assignee: Skyworks Solutions, Inc.Inventors: David Bowie Cruickshank, Michael D. Hill
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Publication number: 20140097378Abstract: A ferrite magnet and a ferrite sintered magnet including a ferrite magnetic material are provided. A main phase of the ferrite magnetic material includes a ferrite phase having a hexagonal crystal structure, and metal element composition expressed by Ca1-w-x-yR wSr xBayFezMm wherein 0.25<w<0.5, 0.01<x<0.35, 0.0001<y<0.013, y<x, 8.7<z<9.9, 1.0<w/m<2.1, 0.017<m/z<0.055 and Si component is at least included as a sub-component, and wherein; when content y1 mass % of the Si component in the ferrite magnetic material, with respect to SiO2, is shown on Y-axis and a total content x1 of z and m is shown on X-axis, a relation between x1 and y1 is within a range surrounded by 4 points placed on X-Y coordinate having the X and Y axes.Type: ApplicationFiled: November 4, 2013Publication date: April 10, 2014Applicant: TDK CORPORATIONInventors: Shigeki YANAGIDA, Takahiro MORI, Hiroyuki MORITA, Nobuhiro SUTO, Tatsuya KATOH, Yoshihiko MINACHI
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Patent number: 8679362Abstract: Disclosed herein are a nickel-zinc-copper (NiZnCu) based ferrite composition containing 0.001 to 0.3 parts by weight of bivalent metal, 0.001 to 0.3 parts by weight of trivalent metal, and 0.001 to 0.5 parts by weight of tetravalent metal based on 100 parts by weight of main component containing 47.0 to 50.0 mol % of Fe2O3, 15.0 to 27.0 mol % of NiO, 18.0 to 25.0 mol % of ZnO, and 7.0 to 13.0 mol % of CuO, and a multilayered chip device and a toroidal core using the same. According to exemplary embodiments of the present invention, a bivalent metal, a trivalent metal, and a tetravalent are contained in a NiZuCu ferrite, thereby making it possible to provide a ferrite composition having excellent quality factor (Q) characteristics. Moreover, it is possible to provide a toroidal core and a multilayered chip device having excellent sinterability, permittivity, and quality factor (Q) characteristics using the ferrite composition.Type: GrantFiled: September 6, 2012Date of Patent: March 25, 2014Assignee: Samsung Electro-Mechanics Co., Ltd.Inventors: Myeong Gi Kim, Sung Yong An, Ic Seob Kim
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Patent number: 8652347Abstract: Provided are new compositions of ruthenates in the pervoskite and layered pervoskite family, wherein the ruthenate compositions exhibit large magnetoresistance (MR) and electric-pulse-induced resistance (EPIR) switching effects, the latter observable at room temperature. This is the first time large MR and EPIR effects have been shown together in ruthenate compositions. Further provided are methods for synthesizing the class of ruthenates that exhibits such properties, as well as methods of use therefor in electromagnetic devices, thin films, sensors, semiconductors, insulators and the like.Type: GrantFiled: April 23, 2007Date of Patent: February 18, 2014Assignee: The Trustees of the University of PennsylvaniaInventors: I-Wei Chen, Alexander Mamchik
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Publication number: 20130307653Abstract: A ferrite magnetic material comprising a primary phase of a magnetoplumbite-type hexagonal ferrite, the primary phase having a composition represented by formula (I), can provide improved magnetic properties in terms of the residual magnetic flux density (Br), intrinsic coercive force (iHc), squareness (Hk/iHc), and maximum energy product (B.Hmax). Therefore, a segment-type permanent magnet derived therefrom can be used in the manufacture of small type motors for automobiles, motors for electric equipments as well as for home appliances, and other devices.Type: ApplicationFiled: May 16, 2012Publication date: November 21, 2013Applicant: SSANGYONG MATERIALS CORPORATIONInventors: Kilsoo Park, Minho Kim, Dongyoung Lee
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Publication number: 20130284969Abstract: Disclosed are an R—Fe—B sintered magnet and a method for producing the same. More specifically, provided is an R—Fe—B (R=Nd, Dy, Pr, Tb, Ho, La, Ce, Sm, Gd, Er, Tm, Yb, Lu or Th) sintered magnet having a structure in which R2Fe14B crystal grains as major phases are surrounded with R-rich phases, wherein a dihedral angle between two adjacent R2Fe14B crystal grains and the R-rich phase contacting the R2Fe14B crystal grains is 70° or less in a triple junction formed by the R2Fe14B crystal grains. The sintered magnet maintains a high coercive force and exhibits improved mechanical properties and is thus applicable to motors or permanent magnets used at high temperatures.Type: ApplicationFiled: January 6, 2012Publication date: October 31, 2013Applicant: INDUSTRY-UNIVERSITY COOPERATION FOUNDATION, HANYANG UNIVERSITYInventors: Young-Do Kim, Se-Hoon Kim, Jin-Woo Kim
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Publication number: 20130256583Abstract: A method of preparing a dispersion of stabilized iron oxide nanoparticles that comprise cores and coatings on the cores, which comprise zwitterionic functional groups chemically bound to the cores, using a single solution that comprises dissolved iron ions and a zwitterion silane and/or a hydrolyzed product of the zwitterion silane.Type: ApplicationFiled: April 3, 2013Publication date: October 3, 2013Inventors: Joseph B. Schlenoff, Zaki G. Estephan
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Publication number: 20130169488Abstract: A new magnetic substance having a high magnetic permeability and a low magnetic permeability loss over a wide frequency bandwidth, a composite material for antennas using the new magnetic substance and a polymer, and an antenna using the composite material for antennas.Type: ApplicationFiled: September 6, 2012Publication date: July 4, 2013Applicant: SAMSUNG ELECTRONICS CO., LTD.Inventors: Jun-sig KUM, Nak-hyun KIM, Hyun-jin KIM, Seung-kee YANG, Joong-hee LEE
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Patent number: 8444872Abstract: Disclosed is a magnetic material having high Hc and High Curie point, which is capable of controlling such magnetic characteristics without requiring rare or expensive raw materials. Specifically disclosed is a magnetic material composed of particles of a magnetic iron oxide which is represented by the following general formula: ?-AxByFe2?x?yO3 or ?-AxByCzFe2?x?y?zO3 (wherein A, B and C each represents a metal excluding Fe and different from each other, satisfying 0<x, y, z<1), with ?-Fe2O3 as a main phase.Type: GrantFiled: May 30, 2008Date of Patent: May 21, 2013Assignees: The University of Tokyo, Dowa Electronics Materials Co., Ltd.Inventors: Shin-ichi Ohkoshi, Shunsuke Sakurai, Takenori Yorinaga, Kazuyuki Matsumoto, Shinya Sasaki
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Publication number: 20130062553Abstract: Disclosed herein are a nickel-zinc-copper (NiZnCu) based ferrite composition containing 0.001 to 0.3 parts by weight of bivalent metal, 0.001 to 0.3 parts by weight of trivalent metal, and 0.001 to 0.5 parts by weight of tetravalent metal based on 100 parts by weight of main component containing 47.0 to 50.0 mol % of Fe2O3, 15.0 to 27.0 mol % of NiO, 18.0 to 25.0 mol % of ZnO, and 7.0 to 13.0 mol % of CuO, and a multilayered chip device and a toroidal core using the same. According to exemplary embodiments of the present invention, a bivalent metal, a trivalent metal, and a tetravalent are contained in a NiZuCu ferrite, thereby making it possible to provide a ferrite composition having excellent quality factor (Q) characteristics. Moreover, it is possible to provide a toroidal core and a multilayered chip device having excellent sinterability, permittivity, and quality factor (Q) characteristics using the ferrite composition.Type: ApplicationFiled: September 6, 2012Publication date: March 14, 2013Applicant: Samsung Electro-Mechanics Co., Ltd.Inventors: Myeong Gi Kim, Sung Yong An, Ic Seob Kim
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Publication number: 20130050041Abstract: Disclosed are synthetic garnets and related devices that can be used in radio-frequency (RF) applications. In some embodiments, such RF devices can include garnets having reduced or substantially nil Yttrium or other rare earth metals. Such garnets can be configured to yield high dielectric constants, and ferrite devices, such as TM-mode circulators/isolators, formed from such garnets can benefit from reduced dimensions. Further, reduced or nil rare earth content of such garnets can allow cost-effective fabrication of ferrite-based RF devices. In some embodiments, such ferrite devices can include other desirable properties such as low magnetic resonance linewidths. Examples of fabrication methods and RF-related properties are also disclosed.Type: ApplicationFiled: May 30, 2012Publication date: February 28, 2013Applicant: SKYWORKS SOLUTIONS, INC.Inventors: David Bowie CRUICKSHANK, Rickard Paul O'DONOVAN, Iain Alexander MACFARLANE, Brian MURRAY, Michael David HILL
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Publication number: 20120326074Abstract: A sintered ferrite magnet comprising a first granular ferrite compound phase containing Ca, La, Fe and Co and having a Curie temperature Tc1 between 415° C. and 430° C., and a second granular ferrite compound phase containing Sr, La, Fe and Co and having a Curie temperature Tc2 between 437° C. and 455° C., the volume ratio of the first ferrite compound phase being 50-90%, and the volume ratio of the second ferrite compound phase being 10-50%, with their total volume ratio being 95% or more.Type: ApplicationFiled: March 9, 2011Publication date: December 27, 2012Applicant: HITACHI METALS, LTD.Inventors: Seiichi Hosokawa, Etsushi Oda, Hiroshi Iwasaki
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Patent number: 8335037Abstract: [Problem] When a nonreciprocal device operating at 100 GHz to 300 GHz is to be realized by using a conventional magnetic material of garnet-type ferrite or spinel-type ferrite, a huge permanent magnet is required and, therefore, it is very difficult to achieve a millimeter-wave band nonreciprocal device for practical use. [Solving means] To solve this problem, there is provided a millimeter-wave band nonreciprocal device composed of a magnetic material represented by a formula ?-MxFe2-xO3 (0<x<2), wherein M is at least one of elements In, Ga, Al, Sc, Cr, Sm, Yb, Ce, Ru, Rh, Ti, Co, Ni, Mn, Zn, Zr, and Y and the magnetic material having ?-phase hematite as a principal phase exhibits strong coercive force and anisotropic magnetic field at room temperature. Dimensions of a magnetic circuit containing a permanent magnet for operations of the nonreciprocal device can be made remarkably small and, by optimum design, the use of the magnetic circuit can be made unnecessary.Type: GrantFiled: October 17, 2008Date of Patent: December 18, 2012Assignees: The University of Tokyo, Dowa Electronics Materials Co., Ltd.Inventors: Shigeru Takeda, Shin-Ichi Ohkoshi
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Patent number: 8303837Abstract: A rotating machine comprising a sintered ferrite magnet having an M-type ferrite structure, comprising Ca, an R element that is at least one of rare earth elements and indispensably includes La, Ba, Fe and Co as indispensable elements, and having a composition represented by the formula: Ca1-x-yRxBayFe2n-zCoz, wherein (1?x?y), x, y, z and n represent the contents of Ca, the R element, Ba and Co, and a molar ratio, meeting 0.3?1?x?y?0.65, 0.2?x?0.65, 0.001?y?0.2, 0.03?z?0.65, 4?n?7, and 1?x?y>y; a bonded magnet comprising ferrite powder having the above composition and a binder, and a magnet roll, at least one magnetic pole portion of which is made of the above bonded magnet.Type: GrantFiled: February 13, 2007Date of Patent: November 6, 2012Assignee: Hitachi Metals, Ltd.Inventors: Takashi Takami, Hiroshi Iwasaki, Yoshinori Kobayashi, Naoki Mochi, Ryuji Gotoh