With Scandium, Yttrium, Gallium, Rare Earth, Or Actinide Patents (Class 252/62.57)
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Patent number: 6929758Abstract: A ferrite magnet obtained by adding either an oxide of Mn or oxides of Mn and Co to a ferrite having a hexagonal M-type magnetoplumbite structure, in which a portion of Sr, Ba, Pb or Ca is replaced with at least one element that is selected from the group consisting of the rare earth elements (including Y) and Bi and that always includes La, during the fine pulverization process thereof, and then subjecting the mixture to re-calcining and/or sintering process(es). By adding a small amount of the element Mn or elements Mn and Co to the ferrite already having the hexagonal M-type magnetoplumbite structure during the fine pulverization process thereof, the magnetic properties can be improved.Type: GrantFiled: December 6, 2001Date of Patent: August 16, 2005Assignee: Neomax Co., Ltd.Inventors: Etsushi Oda, Sachio Toyota, Seiichi Hosokawa
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Patent number: 6908568Abstract: An oxide magnetic material is prepared by wet molding in a magnetic field a slurry containing a particulate oxide magnetic material, water and a polyhydric alcohol having the formula: Cn(OH)nHn+2 wherein n is from 4 to 100 as a dispersant. By improving the orientation in a magnetic field upon wet molding using water, an oxide magnetic material having a high degree of orientation, typically an anisotropic ferrite magnet, is obtained at a high rate of productivity. The method is advantageous from the environmental and economical standpoints.Type: GrantFiled: June 17, 2002Date of Patent: June 21, 2005Assignee: TDK CorporationInventors: Kiyoyuki Masuzawa, Hitoshi Taguchi
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Patent number: 6902685Abstract: A ferrite magnet powder and a ferrite magnet exhibiting improved magnetic properties are provided at a reduced manufacturing cost. An application product and manufacturing methods thereof are also provided. An oxide magnetic material includes, as a main phase, a ferrite having a hexagonal M-type magnetoplumbite structure. The material includes: A, which is at least one element selected from the group consisting of Sr, Ba, Pb and Ca; R, which is at least one element selected from the group consisting of Y (yttrium), the rare earth elements and Bi; Fe; and B (boron). The constituents A, R, Fe and B of the material satisfy the inequalities of 7.04 at %?A?8.68 at %, 0.07 at %?R?0.44 at %, 90.4 at %?Fe?92.5 at % and 0.015 at %?B?0.87 at % to the sum of the elements A, R, Fe and B.Type: GrantFiled: May 21, 2002Date of Patent: June 7, 2005Assignee: Neomax Co., Ltd.Inventors: Sachio Toyota, Isamu Furuchi, Yoshinori Kobayashi
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Patent number: 6899819Abstract: The present research provides a high-density magnetic ceramic composition for microwave application and a preparation method thereof. The magnetic ceramic composition of this research includes Yttrium iron garnet (YIG, Y3Fe5O12) as its basic element and a little amount of additional element, silicon oxide (SiO2), which is expressed as: Y3Fe5O12+x SiO2 (0.05?x?5 mol %). The magnetic ceramic composition is prepared by measuring proper amounts of ferric oxide (Fe2O3), yttrium oxide (Y2O3) and SiO2, mixing them, calcining the mixture, and molding and sintering them. Since the magnetic ceramic composition of the present research has very little magnetic loss, it can be used in components for communication in a microwave band, usefully.Type: GrantFiled: November 18, 2003Date of Patent: May 31, 2005Assignees: Electronics and Telecommunications Research Institute, EG Co., Ltd.Inventors: Dong-Young Kim, Jin Woo Hahn, Dong Suk Jun, Sang Seok Lee
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Patent number: 6893581Abstract: A composite magnetic material contains first magnetic particles made of a first magnetic material and second magnetic particles made of a second magnetic material, the first and second magnetic particles being mixed with each other. A frequency characteristic of the first magnetic material is different from that of the second magnetic material. The first and second magnetic particles are mixed so that, at a frequency of an intersecting point between a first curve representing a frequency characteristic of a real part of a complex magnetic permeability of the first magnetic material and a second curve representing a frequency characteristic of a real part of a complex magnetic permeability of the second magnetic material, a value of a real part of a complex magnetic permeability of the composite magnetic material is larger than a value of the intersecting point.Type: GrantFiled: January 28, 2003Date of Patent: May 17, 2005Assignee: Sanyo Electric Co., Ltd.Inventors: Takashi Umemoto, Hideki Yoshikawa, Keiichi Kuramoto, Hitoshi Hirano
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Patent number: 6872251Abstract: A method for manufacturing single crystal ceramic powder is provided. The method includes a powder supply step for supplying powder consisting essentially of ceramic ingredients to a heat treatment area with a carrier gas, a heat treatment step for heating the powder supplied to the heat treatment area at temperatures required for single-crystallization of the powder to form a product, and a cooling step for cooling the product obtained in the heat treatment step to form single crystal ceramic powder. The method provides single crystal ceramic powder consisting of particles with a very small particle size and a sphericity being 0.9 or higher.Type: GrantFiled: May 29, 2002Date of Patent: March 29, 2005Assignee: TDK CorporationInventors: Minoru Takaya, Yoshiaki Akachi, Hiroyuki Uematsu, Hisashi Kobuke
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Patent number: 6852245Abstract: A composition for producing granules for molding ferrite, which comprises a ferrite slurry at least having raw ferrite powders; an ethylene-modified polyvinyl alcohol whose ethylene modified amount is from 4 to 10 mol %, average polymerization degree is from 500 to 1700, and average saponification degree is from 90.0 to 99.5 mol %; and water mixed therewith, ferrite granules produced from the composition, ferrite green body produced from the granules and ferrite sintered body produced from the sintered body are disclosed.Type: GrantFiled: April 26, 2002Date of Patent: February 8, 2005Assignee: TDK CorporationInventor: Hiroshi Harada
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Patent number: 6846429Abstract: This invention provides a transparent, paramagnetic polymer composition in which a polymer is completed with sufficient rare earth ions, particularly ions selected from ions in the group of elements 64-69, to provide a polymer with a magnetic mass susceptibility greater than 20×10?6 emu/g measured at 298° K. This invention provides optically responsive devices that employ these transparent, paramagnetic polymers as an element that is responsive to a magnetic field and a means for providing magnetic field. This invention provides transparent labels or markings employing these transparent, paramagnetic polymers.Type: GrantFiled: January 16, 2002Date of Patent: January 25, 2005Assignee: E. I. du Pont de Nemours and CompanyInventor: David M. Dean
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Patent number: 6811718Abstract: In the method for manufacturing ferrite type permanent magnets according to the formula M1-xRxFe12-yTyO19: a) a mixture of the raw materials PM, PF, PR and PT of elements M, Fe, R and T, respectively, is formed, Fe and M being the main raw materials and R and T being substitute raw materials; b) the mixture is roasted to form a clinker; c) wet grinding of said clinker is carried out; d) the particles are concentrated and compressed in an orientation magnetic field to form an anisotropic, easy to handle green compact of a predetermined shape; and e) the anisotropic green compact D is sintered to obtain a sintered element. The surface are GS and percentage of at least one of the substitute raw materials is selected according to the surface area and percentage of the iron raw material to obtain magnets with high squareness and overall performance index properties.Type: GrantFiled: April 9, 2002Date of Patent: November 2, 2004Assignee: Ugimag SAInventors: Antoine Morel, Philippe Tenaud
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Patent number: 6803140Abstract: A solid electrolyte material contains an A site-deficient complex oxide represented by a chemical formula A1-&agr;BO3-&dgr;, in which a B site contains at least Ga. This solid electrolyte material has stability, high oxide-ion conductivity at low temperature and high toughness. A method of manufacturing the solid electrolyte material, comprises: mixing oxide materials of respective constituent elements; baking temporarily the mixed materials at 1100 to 1200° C. for 2 to 10 hours; grinding the temporarily baked materials to powder; molding the powder; and sintering the molded powder. A solid oxide fuel cell, has: the solid electrolyte material; a cathode electrode formed on one surface of the solid electrolyte material; and an anode electrode formed on the other surface of the solid electrolyte material. The solid oxide fuel cell has a stable and long operation at low temperature.Type: GrantFiled: August 28, 2001Date of Patent: October 12, 2004Assignee: Nissan Motor Co., Ltd.Inventors: Tatsuo Sugiyama, Kazuo Matsuo, Fumio Munakata, Yoshio Akimune
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Patent number: 6793842Abstract: A ferrite fine powder having a mean particle size of 0.1 to 30 &mgr;m and made of spherical single-crystal particles. The ferrite fine powder has superior physical properties and excellent magnetic properties desirable for use as a raw material for a dust core of coils, transformers, etc. The powder is prepared by forming a solution or suspension containing a compound or compounds of at least one of the metals forming the ferrite into fine droplets, and thermally decomposing the droplets at elevated temperatures.Type: GrantFiled: July 6, 2001Date of Patent: September 21, 2004Assignees: Shoei Chemical Inc., TDK CorporationInventors: Yuji Akimoto, Kazuro Nagashima, Masahiro Ikemoto, Minoru Takaya, Yoshiaki Akachi, Hisashi Kobuke
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Patent number: 6780344Abstract: A garnet ferrite used for a non-reciprocal circuit device contains Fe in an amount lower than the value derived from stoichiometry by 0.5% to 5%, and more preferably by 1% to 3%. The garnet ferrite can exhibit a low insertion loss in a high-frequency band of more than 5 MHz.Type: GrantFiled: October 23, 2002Date of Patent: August 24, 2004Assignee: Alps Electric Co., Ltd.Inventors: Yutaka Yamamoto, Tomoo Kato, Toshio Takahashi, Hitoshi Onishi
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Patent number: 6761747Abstract: An aqueous dispersion containing abrasive particles comprises abrasive particles having superparamagnetic metal oxide domains in a non-magnetic metal oxide or non-metal oxide matrix. The abrasive particles of the aqueous dispersion can have an average particle size of below 400 nm and a BET surface area of 50 to 600 m2/g. The dispersion can be produced by dispersing the abrasive particles with an energy of at least 200 kJ/m3 using a device in which the abrasive particles are first subjected to high pressure, then decompressed through a nozzle so that the abrasive particles collide with one another or against sections of wall in the device. The aqueous dispersion can be used for chemical mechanical polishing (CMP).Type: GrantFiled: October 24, 2002Date of Patent: July 13, 2004Assignee: Degussa AGInventors: Heiko Gottfried, Markus Pridoehl, Berthold Trageser, Guido Zimmermann, Stefan Heberer, Heike Muehlenweg
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Patent number: 6761830Abstract: A method for manufacturing type M hexaferrite powders fo the formula AFe12O19 where A is Ba, Sr, Ca, Pb or a mixture thereof. An iron oxide Fe2O3 and a compound A are mixed with a molar ratio n=Fe2O3/AO, formed and calcined, and the agglomerates which result from the calcining are ground to obtain a fine ferrite powder. The mixture is formed with a ratio n ranging between 5.7 and 6.1, and with a predetermined degree of homogeneity, and before or during the grinding process, an agent controlling the microstructure is introduced.Type: GrantFiled: February 15, 2002Date of Patent: July 13, 2004Assignee: Ugimag S.A.Inventors: Antoine Morel, Eric Brando, Philippe Tenaud
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Patent number: 6758986Abstract: The production is performed by calcining ferrite magnetic powder in which La is substituted for part of Sr and Ti, Zn, and Co are substituted for part of Fe at temperatures of 1100° C. to 1450° C. The magnetization is improved by substituting Zn for part of Fe, and by substituting Ti for part of Fe for the purpose of charge compensation. In addition, the coercive force is improved by substituting Co for part of Fe, and by substituting La for part of Sr for the purpose of charge compensation. Ti is used for the charge compensation, so that it is possible to reduce the cost.Type: GrantFiled: April 30, 2001Date of Patent: July 6, 2004Assignee: Sumitomo Special Metals Co., Ltd.Inventors: Seiichi Hosokawa, Sachio Toyota
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Patent number: 6755988Abstract: A method for making ferrite magnets of formula M1−xRxFe12−yTyO19 including: a1) forming a powder mixture MP of related raw materials, a2) transforming into granules in green state A, b) calcining the granules in green state to form clinker B, c) wet grinding clinker B to obtain a homogeneous dispersion of fine particles C, d) concentrating and compressing the particles under an orienting magnetic field to form an anisotropic green compact D, and e) sintering the green compact to obtain a sintered element E. In step a1), MP is formed from a dry mixture MS of M and Fe powder elements and a dispersion DF of raw materials related to elements R and T, and in step b) the granules in green state are calcined to obtain a clinker B which is homogeneous in chemical composition and size and with apparent low density, between 2.5 and 3.5.Type: GrantFiled: July 10, 2002Date of Patent: June 29, 2004Assignee: Ugimac, S.A.Inventors: Philippe Tenaud, Eric Brando
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Publication number: 20040121188Abstract: A ferrite magnet obtained by adding at least one element selected from the group consisting of Co, Ni, Mn and Zn to a ferrite having a hexagonal M-type magnetoplumbite structure, in which a portion of Sr, Ba, Pb or Ca is replaced with at least one element that is selected from the group consisting of the rare-earth elements (including Y) and Bi and that always includes La, during the fine pulverization process thereof, and then subjecting the mixture to re-calcining and/or sintering process(es). By adding a small amount of the element such as Co, Ni, Mn or Zn to the ferrite already having the hexagonal M-type magnetoplumbite structure during the fine pulverization process thereof, the magnetic properties can be improved.Type: ApplicationFiled: July 24, 2003Publication date: June 24, 2004Inventors: Etsushi Oda, Sachio Toyota, Seiichi Hosokawa
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Publication number: 20040099837Abstract: The present research provides a high-density magnetic ceramic composition for microwave application and a preparation method thereof. The magnetic ceramic composition of this research includes Yttrium iron garnet (YIG, Y3Fe5O12) as its basic element and a little amount of additional element, silicon oxide (SiO2), which is expressed as: Y3Fe5O12+x SiO2 (0.05≦x≦5 mol %). The magnetic ceramic composition is prepared by measuring proper amounts of ferric oxide (Fe2O3), yttrium oxide (Y2O3) and SiO2, mixing them, calcining the mixture, and molding and sintering them. Since the magnetic ceramic composition of the present research has very little magnetic loss, it can be used in components for communication in a microwave band, usefully.Type: ApplicationFiled: November 18, 2003Publication date: May 27, 2004Inventors: Dong-Young Kim, Jin Woo Hahn, Dong Suk Jun, Sang Seok Lee
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Patent number: 6737011Abstract: A ferrite magnet having a basic composition represented by the following general formula: (A1−xRx)O.n[(Fe1−yMy)2O3] by atomic ratio, wherein A is Sr and/or Ba, R is at least one of rare earth elements including Y, M is at least one element selected from the group consisting of Co, Mn, Ni and Zn, and x, y and n are numbers meeting the conditions of 0.01≦x≦0.4, [x/(2.6n)]≦y≦[x/(1.6n)], and 5≦n≦6, and substantially having a magnetoplumbite crystal structure, is obtained by uniformly mixing a compound of Sr and/or Ba with an iron compound; calcining the resultant uniform mixture; adding a compound of the R element and/or the M element to the resultant calcined powder at a pulverization step thereof; and sintering the resultant mixture. The compound of the R element and/or the M element may be added at a percentage of more than 0 atomic % and 80 atomic % or less, on an element basis, at a mixing step before calcination.Type: GrantFiled: November 9, 1999Date of Patent: May 18, 2004Assignee: Hitachi Metals, Ltd.Inventors: Takashi Takami, Yutaka Kubota, Yasunobu Ogata
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Publication number: 20040061090Abstract: A ferrite magnet obtained by adding a ferrite having a spinel-type structure to a ferrite having a hexagonal M-type magnetoplumbite structure, in which a portion of Sr, Ba, Pb or Ca is replaced with at least one element that is selected from the group consisting of the rare-earth elements (including Y) and Bi and that always includes La, during the fine pulverization process thereof. By adding a small amount of the element such as Co, Ni, Mn or Zn to the ferrite already having the hexagonal M-type magnetoplumbite structure during the fine pulverization process thereof, the magnetic properties can be improved.Type: ApplicationFiled: July 22, 2003Publication date: April 1, 2004Inventors: Etsushi Oda, Seiichi Hosokawa, Sachio Toyota
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Patent number: 6699332Abstract: A method of producing a magnetic recording medium comprising the steps of providing a substrate having a layer of a non-magnetic material that can be converted into a magnetic state by annealing, and then converting selected portions of the non-magnetic layer to a magnetic state by subjecting them to annealing by directing a focussed beam of radiation onto the substrate to form a patterned magnetic layer comprising an ordered array of magnetic regions separated by non-magnetic regions.Type: GrantFiled: November 13, 2000Date of Patent: March 2, 2004Assignee: Data Storage InstituteInventors: Seidikkurippu N. Piramanayagam, Jian Ping Wang
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Publication number: 20040026654Abstract: A ferrite magnet powder and a ferrite magnet exhibiting improved magnetic properties are provided at a reduced manufacturing cost. An application product and manufacturing methods thereof are also provided. An oxide magnetic material includes, as a main phase, a ferrite having a hexagonal M-type magnetoplumbite structure. The material includes: A, which is at least one element selected from the group consisting of Sr, Ba, Pb and Ca; R, which is at least one element selected from the group consisting of Y (yttrium), the rare earth elements and Bi; Fe; and B (boron). The constituents A, R, Fe and B of the material satisfy the inequalities of 7.04 at %≦A=8.68 at %, 0.07 at %≦R≦0.44 at %, 90.4 at %≦Fe≦92.5 at % and 0.015 at %≦B≦0.87 at % to the sum of the elements A, R, Fe and B.Type: ApplicationFiled: March 24, 2003Publication date: February 12, 2004Inventors: Sachio Toyota, Isamu Furuchi, Yoshinori Kobayashi
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Patent number: 6689287Abstract: The subject invention includes a composite material comprising a ferroelectric material and a ferromagnetic material having a loss factor (tan &dgr;) for the composite material which includes a dielectric loss factor of the ferroelectric material and a magnetic loss factor of the ferromagnetic material. The composite material achieves the loss factor of from 0 to about 1.0 for a predetermined frequency range greater than 1 MHz. The ferroelectric material has a dielectric loss factor of from 0 to about 0.5 and the ferromagnetic material has a magnetic loss factor of from 0 to about 0.5 for the predetermined frequency range. The ferroelectric material is present in an amount from 10 to 90 parts by volume based on 100 parts by volume of the composite material and the ferromagnetic material is present in an amount from 10 to 90 parts by volume based upon 100 parts by volume of the composite material such that the amount of the ferroelectric material and the ferromagnetic material equals 100 parts by volume.Type: GrantFiled: November 1, 2001Date of Patent: February 10, 2004Assignee: Delphi Technologies, Inc.Inventors: Norman W. Schubring, Joseph V. Mantese, Adolph L. Micheli
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Patent number: 6666991Abstract: A fluorescent or luminous composition, comprising a multilayered film-coated powder having at least two coating films on a base particle, and a fluorescent or luminous substance; the composition, wherein at least one layer of the coating films contains the fluorescent or luminous substance; a genuine/counterfeit discrimination object, in which the fluorescent or luminous composition; and a genuine/counterfeit discrimination method, comprising recognizing fluorescence or luminescence by irradiating, with a light, the genuine/counterfeit discrimination object.Type: GrantFiled: May 29, 2001Date of Patent: December 23, 2003Assignees: Nittetsu Mining Co., Ltd.Inventors: Takafumi Atarashi, Kiyoshi Hoshino, Katsuto Nakatsuka
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Patent number: 6653548Abstract: A cuboid p-type and an n-type thermoelectric conversion material having a composite of an alloy powder for a rare earth magnet and a bismuth-based thermoelectric conversion material that has been rendered a p-type semiconductor or an n-type semiconductor by the addition of the required dopant, are arranged alternately with a material with low thermal conductivity and high electrical resistivity interposed between them. The low- and the high-temperature sides of these thermoelectric conversion materials are connected with wires, a magnetic field is applied in the x axis direction, a temperature gradient ∇T is imparted in the z axis direction a p-n junction is created, and thermoelectromotive force is extracted from the connection end in a plane in the y axis direction. There is a marked increase in the Seebeck coefficient even though no magnetic field is applied externally.Type: GrantFiled: October 10, 2001Date of Patent: November 25, 2003Assignee: Sumitomo Special Metals Co., Ltd.Inventor: Osamu Yamashita
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Patent number: 6652767Abstract: In a composition for a plastic magnet, containing an Nd—Fe—B based alloy powder and a ferrite magnetic material powder mixed to a resin material, the Nd—Fe—B based alloy powder has particle sizes distributed in a range of 100 to 400 &mgr;m, and the ferrite magnetic material powder has an average particle size of approximately 1 &mgr;m. The weight ratio of the Nd—Fe—B based alloy powder to the ferrite magnetic material powder is in a range of 30:70 to 70:30. Further, the ratio of the total weight of the Nd—Fe—B based alloy powder 2 and the ferrite magnetic material powder 3 to the weight of the resin material is in a range of 90:10 to 80:20. Thus, in a plastic magnet 1 formed using the composition, peripheries of particles of the Nd—Fe—B based alloy powder 2 are surrounded by particles of the ferrite magnetic material powder 3 and the resin material.Type: GrantFiled: April 9, 2002Date of Patent: November 25, 2003Assignee: Enplas CorporationInventor: Satoshi Kazamaturi
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Patent number: 6645394Abstract: A high frequency magnetic material ceramic composition including materials having the general formula (Ca, A)zCuxB8−x−zO12 is prepared. A represents Y and/or at least one element selected from the rare earth elements excluding Y; B represents metal elements which are different from A and include at least Fe and V. x has a value of 0.002<x<0.2; and z is a value of 3.0<z≦3.09. The Ca/V ratio is 2.0<Ca/V≦2.4. A irreversible circuit component containing center electrodes electrically insulated from each other in a ferrite member made of the high frequency magnetic material ceramic is provided.Type: GrantFiled: May 17, 2002Date of Patent: November 11, 2003Assignee: Murata Manufacturing Co., Ltd.Inventors: Yuko Fujita, Tatsuya Matsunaga
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Patent number: 6641751Abstract: The present invention relates to a magnetic garnet single crystal and a Faraday rotator using the magnetic garnet single crystal and the object of the present invention is to provide a magnetic garnet single crystal which suppresses a generation of crystal defects and a Faraday rotator which improves an extinction ratio. A magnetic garnet single crystal grown by a liquid-phase epitaxial growth method and having the general formula represented by BiaPbbA3−a−bFe5−c−dBcPtdO12 is used, wherein A is at least one kind of element selected from Y, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb and Lu, B is at least one kind of element selected from Ga, Al, Sc, Ge and Si, and a, b, c and d are represented by 0.8<a<1.4, 0<b≦20, 0≦c≦0.9 and 0<d≦2.0 respectively.Type: GrantFiled: July 25, 2000Date of Patent: November 4, 2003Assignee: TKD CorporationInventors: Atsushi Ooido, Kazuhito Yamasawa
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Patent number: 6624713Abstract: As a magnetic material for high frequencies provided in a high-frequency circuit component used as a high-frequency nonreciprocal circuit device, for example, a circulator and an isolator, a magnetic material which can be densely sintered at a relatively low temperature and has a reduced ferromagnetic resonance half width is provided. The magnetic material for high frequencies is primarily composed of yttrium iron-based garnet in which Ca substitutes for a part of Y site, and V substitutes for a part of Fe site, and does not substantially contain tetravalent nor pentavalent elements, other than V, or contains about 0.5% by weight or less of oxide of this element, and the ratio of Ca atoms to V atoms, Ca/V, falls within the range of 2.0<Ca≦2.4.Type: GrantFiled: August 16, 2001Date of Patent: September 23, 2003Assignee: Murata Manufacturing Co., Ltd.Inventors: Tatsuya Matsunaga, Hiroshi Marusawa
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Publication number: 20030168785Abstract: A ferrite magnet having a basic composition represented by the following general formula: (A1-xRx)O.n[(Fe1-yMy)2O3] by atomic ratio, wherein A is Sr and/or Ba, R is at least one of rare earth elements including Y, M is at least one element selected from the group consisting of Co, Mn, Ni and Zn, and x, y and n are numbers meeting the conditions of 0.01≦x≦0.4, [x/(2.6n)]≦y≦[x/(1.6n)], and 5≦n≦6, and substantially having a magnetoplumbite-type crystal structure, is obtained by uniformly mixing a compound of Sr and/or Ba with an iron compound; calcining the resultant uniform mixture; adding a compound of the R element and/or the M element to the resultant calcined powder at a pulverization step thereof; and sintering the resultant mixture. The compound of the R element and/or the M element may be added at a percentage of more than 0 atomic % and 80 atomic % or less, on an element basis, at a mixing step before calcination.Type: ApplicationFiled: January 16, 2003Publication date: September 11, 2003Applicant: HITACHI METALS, LTD.Inventors: Takashi Takami, Yutaka Kubota, Yasunobu Ogata
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Publication number: 20030085375Abstract: The subject invention includes a composite material comprising a ferroelectric material and a ferromagnetic material having a loss factor (tan &dgr;) for the composite material which includes a dielectric loss factor of the ferroelectric material and a magnetic loss factor of the ferromagnetic material. The composite material achieves the loss factor of from 0 to about 1.0 for a predetermined frequency range greater than 1 MHz. The ferroelectric material has a dielectric loss factor of from 0 to about 0.5 and the ferromagnetic material has a magnetic loss factor of from 0 to about 0.5 for the predetermined frequency range. The ferroelectric material is present in an amount from 10 to 90 parts by volume based on 100 parts by volume of the composite material and the ferromagnetic material is present in an amount from 10 to 90 parts by volume based upon 100 parts by volume of the composite material such that the amount of the ferroelectric material and the ferromagnetic material equals 100 parts by volume.Type: ApplicationFiled: November 1, 2001Publication date: May 8, 2003Applicant: Delphi Technologies Inc.Inventors: Norman W. Schubring, Joseph V. Mantese, Adolph L. Micheli
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Patent number: 6558807Abstract: To use a media agitating mill of a wet internal circulation type when grinding materials, and offer oxide magnetic materials and coils in which influences of ZrO2 and Y2O3 mixing when using partially stabilized zirconia as media beads are improved. The magnetic materials and coils are characterized in that Fe2O3, ZnO, NiO and CuO are main components, and Y2O3, ZrO2 and Bi2O3 are contained with respect to these main components, where an amount of Y2O3 is 0.007 to 0.028 wt % for the total amount, an amount of ZrO2 is 0.12 to 0.55 wt % therefor and an amount of Bi2O3 is 0.03 to 10.12 wt % for the same.Type: GrantFiled: January 19, 2001Date of Patent: May 6, 2003Assignee: TDK CorporationInventors: Ko Ito, Yukio Takahashi
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Publication number: 20030080315Abstract: A garnet ferrite used for a non-reciprocal circuit device contains Fe in an amount lower than the value derived from stoichiometry by 0.5% to 5%, and more preferably by 1% to 3%. The garnet ferrite can exhibit a low insertion loss in a high-frequency band of more than 5 MHz.Type: ApplicationFiled: October 23, 2002Publication date: May 1, 2003Applicant: Alps Electric Co., Ltd.Inventors: Yutaka Yamamoto, Tomoo Kato, Toshio Takahashi, Hitoshi Onishi
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Patent number: 6537463Abstract: A resin-bonded magnet composed substantially of (a) an R—T—N-based magnetic powder having a basic composition of R&agr;T100−&agr;−&bgr;N&bgr;, wherein R is at least one selected form the group consisting of rare earth elements including Y, T is Fe or Fe and Co, 5≦&agr;≦20, and 5≦&bgr;≦30, (b) a ferrite magnetic powder having a substantially magnetoplumbite-type crystal structure and a basic composition represented by (A1−xR′x) O[(Fe1−yMy)2O3] by atomic ratio, wherein A is Sr and/or Ba, R′ is at least one selected from the group consisting of rare earth elements including Y, La being indispensable, M is Co or Co and Zn, 0.01≦x<0.4, 0.005≦y≦0.04, and 5.0≦n≦6.4, and (c) a binder. The ferrite magnet powder is preferably an anisotropic, granulated powder or an anisotropic, sintered ferrite magnet powder.Type: GrantFiled: December 11, 2000Date of Patent: March 25, 2003Assignee: Hitachi Metals, Ltd.Inventors: Katsunori Iwasaki, Masahiro Tobise, Yasunobu Ogata, Mikio Shindo, Hiroshi Okajima
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Publication number: 20030052300Abstract: In the method for manufacturing ferrite type permanent magnets according to the formula M1-xRxF12-yTyO19:Type: ApplicationFiled: April 9, 2002Publication date: March 20, 2003Inventors: Antoine Morel, Philippe Tenaud
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Patent number: 6527973Abstract: A magnetooptical device which defines a Faraday rotation angle &thgr; expressed by 44 deg.≦&thgr;≦46 deg. when light having a wavelength &lgr; (1570 nm≦&lgr;≦1620 nm) impinges thereupon. A magnetic garnet material expressed by a general formula: BiaM13−a Fe5−bM2bO12 is used. M1 is at least one kind of element that is selected from among Y, La, Eu, Gd, Ho, Yb, Lu and Pb; M2 is at least one kind of element that is selected from among Ga, Al, Ti, Ge, Si and Pt; and a and b satisfy 1.0≦a≦1.5 and 0≦b≦0.5, respectively.Type: GrantFiled: December 11, 2000Date of Patent: March 4, 2003Assignee: TDK CorporationInventors: Atsushi Ohido, Kazuhito Yamasawa
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Publication number: 20030024605Abstract: A magnetic substance having the maximum value of complex permeability in quasi-microwave range is provided for suppressing a high frequency noise in a small-sized (electronic apparatus. The magnetic substance is of a magnetic composition comprising M, X and Y, where M is a metallic magnetic material consisting of Fe, Co, and/or Ni, X being element or elements other than M and Y, and Y being F, N, and/or O. The M-X-Y magnetic composition has a concentration of M in the composition so that said M-X-Y magnetic composition has a saturation magnetization of 35-80% of that of the metallic bulk of magnetic material comprising M alone. The magnetic composition has the maximum &mgr;″max of complex.Type: ApplicationFiled: September 4, 2001Publication date: February 6, 2003Inventors: Shigeyoshi Yoshida, Hiroshi Ono, Shinsuke Andoh, Wei-Dong Li, Yutaka Shimada
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Patent number: 6485840Abstract: An oxide magnetic material comprising main constituents including Fe2O3, ZnO, CuO and NiO. Y2O3 of 0.003 to 0.021 wt % and ZrO2 of 0.06 to 0.37 wt % are included in said main constituents with respect to all amounts. It is also preferable that Si of 0.010 to 0.0112 wt % is included in said main constituents with respect to all amounts. Further, it is also preferable that Y2O3 of 0.001 to 0.011 wt %, ZrO2 of 0.031 to 0.194 wt %, and Si of 0.010 to 0.056 wt % are included in said main constituents with respect to all amounts.Type: GrantFiled: August 18, 2000Date of Patent: November 26, 2002Assignee: TDK CorporationInventors: Ko Ito, Yukio Takahashi, Takuya Ono, Hiroshi Harada
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Patent number: 6483645Abstract: An optical isolator comprsing at least two parts of a Faraday rotator obtained from a garnet crystal and an analyzer, which is small in size, can be mounted directly to a semiconductor laser. The garnet crystal is grown, by a liquid-phase epitaxial growth technique, on the substrate of a garnet with a lattice constant of 12.514±0.015 Å, and consists of the following composition formula: (Tb1−(a+b+c+d)LnaBibM1cEud)3(Fe1−eM2e)5O12 where Ln is an element selected from rare-earth elements excluding Tb and Eu, and Y; M1 is an element selected from elements Ca, Mg, and Sr; M2 is an element selected from elements of Al, Ga, Sc, In, Ti, Si, and Ge; a, b, c, d, and e are defined as 0≦a≦0.5, 0.3<b≦0.6, 0≦c≦0.02, 0<d≦0.3, and 0.01<e≦0.3, respectively.Type: GrantFiled: October 11, 2000Date of Patent: November 19, 2002Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Masayuki Tanno, Satoru Fukuda
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Publication number: 20020153065Abstract: Spindle-shaped goethite particles of the present invention contain Co of 8 to 45 atm %, calculated as Co, based on whole Fe, Al of 5 to 20 atm %, calculated as Al, based on whole Fe, and have an average major axial diameter of 0.05 to 0.18 &mgr;m, each of said spindle-shaped goethite particles comprising a seed portion and a surface layer portion, the weight ratio of said seed portion to said surface layer portion being 30:70 to 80:20 and the relationship of the Co concentration of the seed portion with that of the hematite particle being 50 to 95:100 when the Co concentration of the hematite particle is 100, and said Al existing in said surface layer portion. Such spindle-shaped goethite particles are fine particles and exhibit a good particle size distribution.Type: ApplicationFiled: August 3, 2001Publication date: October 24, 2002Applicant: Toda Kogyo CorporationInventors: Kenji Okinaka, Masaaki Maekawa
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Patent number: 6451220Abstract: A magnetic composition comprised of cobalt ferrite nanoparticles dispersed in an ionic exchange resin.Type: GrantFiled: January 21, 1997Date of Patent: September 17, 2002Assignee: Xerox CorporationInventors: Ronald F. Ziolo, Javier Tejada Palacios, Elizabeth C. Kroll, Xixiang Zhang, Rachel Pieczynski
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Patent number: 6426156Abstract: A magnetic garnet single crystal film used for a magnetostatic wave device has a Pb content in the range of from more than zero to about 4,000 ppm by weight.Type: GrantFiled: January 30, 2001Date of Patent: July 30, 2002Assignee: Murata Manufacturing Co., Ltd.Inventor: Masaru Fujino
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Patent number: 6419847Abstract: An La—Co ferrite magnet powder, in which Sr and Fe are replaced with La and Co, respectively, is made by carrying out a calcination process at a temperature higher than 1300° C. and equal to or lower than 1450° C. Fe has a magnetic moment oriented upwardly with respect to a crystal c-axis at a number of sites thereof, and also has an opposite magnetic moment oriented downwardly with respect to the crystal c-axis at another number of sites thereof. And Fe is replaced with Co at the greater number of sites thereof. As a result, high coercivity is attained. In this manner, coercivity can be increased while suppressing decrease in saturation magnetization &sgr;s.Type: GrantFiled: July 19, 2000Date of Patent: July 16, 2002Assignee: Sumitomo Special Metals Co., Ltd.Inventors: Sachio Toyota, Seiichi Hosokawa, Shuji Anamoto, Isamu Furuchi
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Patent number: 6416682Abstract: The present invention relates to methods of producing synthetic crystals (typically minerals) or comparable inorganic compounds by reactions of metal salts and metal oxyhydroxides under near-critical, critical or supercritical solvent conditions, avoiding thereby many of the difficulties associated with conventional solid state or wet chemistry synthesis. The metal oxyhydroxides are typically divalent or trivalent metals and the preferred solvent is typically (but not exclusively) water under near-critical, critical or supercritical conditions. The crystals so produced have a controlled particle size distribution. The crystals produced by the present invention also have morphologies with favorable properties for compaction into green bodies for subsequent sintering into near-net-shapes, approaching maximum theoretical densities. Avoidance of noxious by-products is another advantage of the present synthetic methods.Type: GrantFiled: November 4, 1999Date of Patent: July 9, 2002Assignee: Ceramic Oxides International B.V.Inventors: Pieter Krijgsman, Daniel J. W. Ijdo
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Patent number: 6416681Abstract: Granule for forming ferrite is provided by mixing powders of ferrite raw material, polyvinyl alcohol as a binder and polyethylene glycol added as plasticizer and having molecular weight being 1000 to 6000, and forming granules.Type: GrantFiled: August 23, 2000Date of Patent: July 9, 2002Assignee: TDK CorporationInventor: Hiroshi Harada
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Patent number: 6402980Abstract: The present invention provides an oxide magnetic material, which includes a primary phase of a hexagonal ferrite containing metallic elements Ca, R, Fe and M, where M represents at least one element selected from the group including Co, Ni and Zn, and R represents at least one element selected from the group including Bi and rare earth elements including Y, with La being essentially included in R; wherein the proportions of the metallic elements Ca, R, Fe and M with respect to the total amount of the metallic elements are from 1 to 13 atomic % for Ca, from 0.05 to 10 atomic % for R, from 80 to 95 atomic % for Fe, and from 1 to 7 atomic % for M. The present invention also provides ferrite particles, a bonded magnet, a sintered magnet, a process for producing them, and a magnetic recording medium, which contain the oxide magnetic material.Type: GrantFiled: May 19, 1999Date of Patent: June 11, 2002Assignee: TDK CorporationInventors: Hitoshi Taguchi, Kiyoyuki Masuzawa, Yoshihiko Minachi, Kazumasa Iida, Miyuki Kawakami
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Patent number: 6383407Abstract: A ferrite powder for bonded magnets having a substantially magnetoplumbite-type crystal structure and an average diameter of 0.9-2 &mgr;m, the ferrite powder having a basic composition represented by the following general formula: (A1−xRx)O.n[(Fe1−yMy)2O3] by atomic ratio, wherein A is Sr and/or Ba; R is at least one of rare earth elements including Y, La being indispensable; M is at least one element selected from the group consisting of Co, Mn, Ni and Zn; and x, y and n are numbers meeting the conditions of 0.01≦x≦0.4, [x/(2.6n)]≦y≦[x/(1.6n)], and 5≦n≦6, (Si+Ca) being 0.2 weight % or less, and (Al+Cr) being 0.13 weight % or less, can be produced by mixing iron oxide containing 0.06 weight % or less of (Si+Ca) and 0.Type: GrantFiled: February 16, 2001Date of Patent: May 7, 2002Assignee: Hitachi Metals, Ltd.Inventors: Yasunobu Ogata, Yutaka Kubota, Takashi Takami, Shuichi Shiina
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Patent number: 6379810Abstract: The present invention provides a magnetic film expressed by a composition formula TaMbXcNdOe (T is a magnetic metal such as Fe, M is an alkaline earth metal such as Be, Mg, and Ca, and X is at least one selected from the group consisting of Y, Ti, Zr, Hf, V, Nb, Ta and lanthanoid), where a+b+c+d+e=100, 45 ≦a≦85, 5.5≦b≦28, 0.5≦c≦16, 6≦b+c≦28.5, 0.4 <b/c ≦56, 0≦d≦10, and 8≦d+e≦40. The magnetic film comprises mainly metal magnetic crystal grains having an average crystal grain diameter of not more than 15 nm and a grain boundary product. The grain boundary product substantially separates the metal magnetic crystal grains. The main component of the metal magnetic crystal grains is the T. The grain boundary product contains at least an oxide or a nitride of the M and the X. The magnetic film has a saturation magnetic flux density of not less than 0.8 T and an electric resistivity of not less than 80 &mgr;&OHgr;cm.Type: GrantFiled: January 18, 2000Date of Patent: April 30, 2002Assignee: Matsushita Electric Industrial Co., Ltd.Inventors: Masayoshi Hiramoto, Yasuhiro Iwano, Hirosuke Mikami, Hiroyasu Tsuji, Hiroshi Sakakima
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Patent number: 6352649Abstract: The present invention provides magnetostrictive composites that include an oxide ferrite and metallic binders which provides mechanical properties that make the magnetostrictive compositions effective for use as sensors and actuators.Type: GrantFiled: April 17, 2000Date of Patent: March 5, 2002Assignee: Iowa State University Research Foundation Inc.Inventors: R. William McCallum, John E. Snyder, Kevin W. Dennis, Carl R. Schwichtenberg, David C. Jiles
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Publication number: 20020014612Abstract: The present invention relates to a magnetooptical device utilizing a magnetooptical effect provided by using a magnetic garnet material, and provides a magnetic garnet material which is less likely to crack during the growth and lapping of the single crystal film. It is an object of the invention to provide a magnetooptical device which defines a Faraday rotation angle &thgr; expressed by 44 deg.≦&thgr;≦46 deg. when light having a wavelength &lgr; (1570 nm≦&lgr;≦1620 nm) impinges thereupon, in order to permit the suppression of and which is less likely to crack during processing to allow any reduction of yield. A magnetic garnet material expressed by a general formula: BiaM13-aFe5-bM2bO12 is used. M1 is at least one kind of element that is selected from among Y, La, Eu, Gd, Ho, Yb, Lu and Pb; M2 is at least one kind of element that is selected from among Ga, Al, Ti, Ge, Si and Pt; and a and b satisfy 1.0≦a≦1.5 and 0≦b≦0.5, respectively.Type: ApplicationFiled: December 11, 2000Publication date: February 7, 2002Applicant: TDK CorporationInventors: Atsushi Ohido, Kazuhito Yamasawa