Abstract: Described herein are chemiluminescent powders that can be applied to a variety of substrates that are generally sensitive to existing chemiluminescent compositions. Methods for producing the chemiluminescent compositions are also provided.

Abstract: This invention is directed towards chemiluminescent systems useful in the practice of methods of intrusion detection, compositions useful for intrusion detection and methods for their formation, and to covert intrusion detection techniques and compositions therefore containing an infrared light generating chemiluminescent system, blended into an earthen-like carrier that enable one to detect whether any movement has breached an area during a certain time frame.

Abstract: Chemical light producing systems and the chemiluminescent formulations contained therein are taught which exhibit reduced hydrolysis and thereby are characterized by an inherently long shelf-life and commercial viability. By replacing the typical oxalate ester, e.g. (bis{3,4,6-trichloro-2-[(pentoxy)carbonyl]phenyl}oxalate) with a branched chain oxalic acid ester represented by the general formula: wherein the group designated as R contains from 4-15 carbons, wherein the carbon of attachment of R to the oxygen is via a primary carbon, and wherein substructure A is composed of substituents selected from the group including alkyl chains, alkyl rings, aromatic rings and combinations thereof such that R is nonlinear, water hydrolysis of the oxalate ester is retarded. This retardation of the hydrolysis changes the storage constraints of the oxalate ester.

Abstract: The present invention relates to nanostructures for use in luminescent devices.

Abstract: The present invention relates to polyacene derivatives represented by general formula (I) below: (wherein R1 to R10, etc. each represents hydrogen atom, hydrocarbon group, or an alkoxy group; A1 and A2 are hydrogen atom, a halogen atom, a hydrocarbon group, an alkoxy group, cyano group, etc.; n is an integer of not less than 1; R6 and R7 may be linked to each other to form a ring); and a process for preparing the polyacene derivatives from polyhydro compounds as well as electrically conductive materials comprising the polyacene derivatives. According to the process for preparing the polyacene derivatives of the present invention, optional substituents can be introduced into any carbon atoms of the polyacene, and the number of aromatic rings can be increased.

Abstract: A polymer for use in an optical device comprising one or more regions, where each region comprises (i) a first structural unit having general formula I: where m=1 or 2 and which contains at least one substituent selected from the group consisting of alkyl, alkoxy, aryl, aryloxy, heteroaryl, and heteroaryloxy groups, each of which may be further substituted; and (ii) a second structural unit Ar selected from the group consisting of heteroaryl, triarylamine and 2,7-fluorenyl; such that where m=1 each region comprises a unit having general formula II: wherein, the substituent has a molecular weight of less than 300.

Abstract: The thixotropic composition of the instant invention may be cured to a more or less rigid form without the use of a mold. The shaped thixotropic composition includes one of the two components which when combined result in chemiluminescent light. The cured solid is useful in a variety of environments and will emit chemiluminescent light upon addition of a second chemiluminescent component.

Abstract: A multiple-part marking system that comprises at least one first part comprising at least one oxalate ester, at least one fluorescer, and at least one inorganic salt; and at least one second part comprising at least one peroxide and at least one catalyst, wherein the at least one inorganic salt is chosen from sodium thiosulphate, potassium thiosulphate, cobalt acetate, copper acetate, lead acetate, cupric chloride, ferric chloride, calcium iodide, potassium iodide, and silver nitrate. Light and heat are emitted when the two parts interact.

Abstract: Compounds are disclosed for the production of chemiluminescent light, particularly for the production of blue/violet light within the range of about 390 nm to less than 438 nm, and most particularly to the use of compounds composed of symmetrically and asymmetrically substituted anthracenes which are effective for increasing the production of such blue/violet light when used as fluorescers in conjunction with chemiluminescent systems. These systems utilize derivatives of 9,10-diphenylanthracene containing one or more fluorines As shown in General Formulae 1-3. The variables shown in Formulae 1-3 are defined in the specification.

Abstract: Described herein are chemiluminescent powders that can be applied to a variety of substrates that are generally sensitive to existing chemiluminescent compositions. Methods for producing the chemiluminescent compositions are also provided.

Abstract: A gene detection method for detecting a gene having a specific sequence with high sensitivity is provided.

Abstract: Described is an illumination unit for a field-device display module. The illumination unit generates luminescence light as background illumination for the display. In this arrangement, the illumination element comprises a chemiluminescence element or a radioactive element that generates ionising radiation for exciting a phosphorescence layer.

Abstract: A therapeutic device has a first chamber that retains an oxalic ester solution, and a second chamber that retains a hydrogen peroxide and fluorescer solution. The therapeutic device is activated by causing the oxalic ester solution to mix with the hydrogen peroxide and fluorescer solution, which produces chemiluminescent light for treating a wound.

Abstract: The present invention relates to electroluminescent polymers which contain structural units of the formula (1) and to the use thereof. The polymers according to the invention exhibit improved efficiency and a longer lifetime, in particular on use in polymeric organic light-emitting diodes.

Abstract: A chemiluminescent system and device is disclosed wherein a first polymeric sheet having a shaped cavity therein is sealed around its periphery to a second polymeric sheet and the cavity contains a cured PVC plastisol having admixed an oxalate solution and finely divided semiconductor laser crystals and a sealed receptacle containing a liquid component of a chemiluminescent activator. Placed over the plastisol or container is a light filter having a dye or dyes, pigment or pigments compounded into the filter, the dyes or pigments are chosen from those that absorb certain parts of the spectrum such that all light emissions up to 1050 nm are absorbed and anything beyond 1050 nm is transmitted. The devices generate a chemiluminescent light at wavelengths chosen to stimulate the semiconductor laser crystals. The semiconductor laser crystals absorb the chemiluminescent light and re-emit energy at wavelengths in the IR.

Abstract: This invention publishes new usages of kinds of carbonic ester compounds. The new usage described in this invention is related to the application of carbonic ester compounds in the preparation of solvents for chemiluminescent systems. This invention also provides luminescent compositions, luminescent liquids and oxidized liquids that contain carbonic ester compounds. Chemiluminescent compositions containing carbonic ester compounds can decrease reaction pressure effectively, facilitate reaction balance heading to luminescence reaction, generate larger luminescent output without adding catalyst, decrease the dosage of catalyst or not need adding catalyst, decrease influences of over-high output at the reaction start caused by catalyst on whole luminescent time, and ensure stable light output from luminescent compositions. Carbonic ester compounds, especially long carbon chain carbonic ester, have the characters of non-toxic and high flash point, and have suitable solubility on ordinary bis oxalate ester.

Abstract: The method for making an active material according to the invention comprises a step of contacting an aqueous solution containing a metal-fluoro complex with a carbon material. The active material comprises a carbon material and a metal oxide particle group supported directly on the surface of the carbon material.

Abstract: The present invention relates to heptarylene- and octarylenetetracarboximides of the general formula (I) to precursors thereof or mixtures thereof, and to processes for their preparation and to their use.

Abstract: Described herein are chemiluminescent compositions that can be applied to a variety of substrates that are generally sensitive to existing chemiluminescent compositions. Methods for producing the chemiluminescent compositions are also provided.

Abstract: The present invention is directed to compositions and methods for improving a chemiluminescent signal. In particular, a reaction buffer with an alkaline pH range of about 9 to 10 provides a maximal chemiluminescent intensity and longevity of luminol that is catalyzed by superoxide anions. The addition of carbonate to the reaction buffer provides an optimal signal to background ratio and stability of a chemiluminescent signal from luminol catalyzed by superoxide anions. The method includes preparing a buffer with an alkaline pH, combining the buffer with a working reagent to produce and detect a chemiluminescent signal. The working reagent includes luminol, a coumaric acid and a peroxide. The composition includes a buffer having a pH from about 9 to about 10, a stock reagent comprising luminol, a coumaric acid, a peroxide, and a second buffer having a pH of about 8.5.

Abstract: Compositions are provided, comprising a host and a dopant, wherein the weight:weight ratio of host:dopant is about 10:1 to about 40:1, and a solvent, and methods for making the same, as well as devices and sub-assemblies including the same.

Abstract: A formable, porous chemiluminescent reactant composition, device therefore, and a process for production thereof is disclosed. The fluidizable solid admixture of the instant invention may be cured to a more or less rigid form with or without the use of a mold. The cured solid is useful as a chemiluminescent reactant component and is useful in a variety of environments.

Abstract: This invention is directed towards chemiluminescent systems useful in the practice of methods of intrusion detection, compositions useful for intrusion detection and methods for their formation, and to covert intrusion detection techniques and compositions therefore containing an infrared light generating chemiluminescent system, blended into an earthen-like carrier that enable one to detect whether any movement has breached an area during a certain time frame.

Abstract: A therapeutic device has a first chamber that retains an oxalic ester solution, and a second chamber that retains a hydrogen peroxide and fluorescer solution. The therapeutic device is activated by causing the oxalic ester solution to mix with the hydrogen peroxide and fluorescer solution, which produces chemiluminescent light for treating a wound.

Abstract: The present invention teaches a chemiluminescent device along with a process for its production. The invention specifically relates to a chemiluminescent article of manufacture (FIG. 1), which includes a containment device (12) having polymeric outer containment (18, 20), and chemical system of oxalate solution inside frangible vial (14), and activator inside frangible vial (16), both the containment device and chemical system may be selected to be particularly susceptible to environmental degradation subsequent to their use. In a preferred embodiment, the chemiluminescent device is designed for an enhanced shelf life prior to use while remaining capable of losing its physical form and re-entering the environment after use.

Abstract: A formable, porous chemiluminescent reactant composition, device therefore, and a process for production thereof is disclosed. The fluidizable solid admixture of the instant invention may be cured to a more or less rigid form with or without the use of a mold. The cured solid is useful as a chemiluminescent reactant component and is useful in a variety of environments.

Abstract: Methods for generating chemiluminescence rapidly by reaction of at least one compound comprising a C—C double bond substituted at one carbon with two sulfur atom-containing groups with a peroxidase enzyme and a peroxide are disclosed. The chemiluminescence thus produced can be used as a detectable signal in assays for peroxidase enzymes or peroxide-producing enzymes and in assays employing enzyme-labeled specific binding pairs. Use of the methods provides rapid signal generation, achieving a plateau intensity in under one minute. The substrate can be provided in a composition which demonstrates unexpectedly long storage stability.

Abstract: A chemiluminescent formulation includes an oxalate solution including a dye and an activator solution including polyethylene oxide. The oxalate solution and the activator solution are mixed to form a chemiluminescent mixture. Chemiluminescent energy in the form of light is emitted after mixing. The polyethylene oxide substantially increases the light output from the chemiluminescent mixture compared to a non-polyethylene oxide containing formulation.

Abstract: A luminescent composition, with a luminescent marker and a ionizing agent exhibiting luminescence for an indicatory period once intermixed, and with luminance intensity remaining at a threshold intensity during indicatory period. Luminescence also can be exhibited responsive to responsive to excitatory light applied to the composition. The luminescent marker includes a coumarinic compound and the ionizing agent includes an ammonium base. Antimicrobial agents are included. A luminescence measuring apparatus includes a photoemitter and a photodetector responsive to an emissive light induced by photoemitter. An optical filter can be used with the photodetector. A two-phase composition dispensing apparatus includes a first phase reservoir, a second phase reservoir, a mixing nozzle, and a dispensing mechanism.

Abstract: Described herein are chemiluminescent compositions that can be applied to a variety of substrates that are generally sensitive to existing chemiluminescent compositions. Methods for producing the chemiluminescent compositions are also provided.

Abstract: A chemiluminescent glow spike includes a hand tool having a transparent plastic tube portion as a shell container for a first agent of a liquid chemiluminescent material and for a glass vial containing a second agent of the liquid chemiluminescent material. A distal end of the transparent plastic tube portion is formed with a penetrating spike portion to mount a comestible article by a user. Application of an external force to the transparent plastic tube containing the glass vial breaks the glass vial to cause the first and second agents to intermix to activate the liquid chemiluminescent material to provide a fluorescent/luminescent effect.

Abstract: A composition exhibiting significantly increased luminance as compared with that of a known luminescent composition is provided. The composition constitutes a system in which chemiluminescence is effected by mixing two types of compositions and includes a composition A in which an oxalic ester is present in a solid state in a solution containing the oxalic ester and a luminescent substance both dissolved therein and a composition B in which aqueous hydrogen peroxide and a catalyst is dissolved in a solution.

Abstract: The present invention provides a chemiluminescent composition including an oxalate and a fluorescent material wherein the chemiluminescent composition is mixed with a composition including hydrogen peroxide to induce chemiluminescence. The chemiluminescent composition comprises a solvent for the oxalate and the fluorescent material, which includes an acetyl citrate ester or an organic solvent containing an acetyl citrate ester. As an alternative to dibutyl phthalate which is suspected to be one of endocrine disrupting chemicals, the solvent of the present invention can assure safety to human body while maintaining excellent storage stability and luminescent performance.

Abstract: An embodiment of an oxalate ester chemiluminescent light system comprises two components. One component is an oxalate ester, containing at least 0.01M oxalate ester and 0.001M fluorescer in a suitable solvent; the other component contains 0.01M to 3M of hydrogen peroxide in a polyethylene glycol mixed solvent, where the amount of polyethylene glycol in the mixture is from 1%-99% and the balance of the mixed solvent may be an ester. In comparison to chemiluminescent light systems comprising tertiary alcohols, the light emitting system with the polyethylene glycol has lower toxicity, higher flash point and lower vapor pressure; the energy of the chemical light produced is about 15% higher; and storage stability is better.

Abstract: The present invention provides luminescent lanthanide metal chelates comprising a metal ion of the lanthanide series and a complexing agent comprising at least one salicylamidyl moiety. Also provided are probes incorporating the salicylamidyl ligands of the invention and methods utilizing the ligands of the invention and probes comprising the ligands of the invention.

Abstract: The present invention is a method for making a chemiluminescent paint whose chemo-fluorescent reaction's active period is controllable as a first-order function of humidity, thus reducing to a second order function the prior art's dependency on ambient temperature, through encapsulating a key reactant in a moisture-sensitive, nano-polymeric structure and combining that encapsulating structure and encapsulated reactant with the other elements necessary for both the excitative and fluorescing reactions of the chemiluminescent paint.

Abstract: A chemiluminescent reactant solution and a layer containing a solid oxidizer. An embodiment of the invention has the layer containing a solid oxidizer supported by a substrate such as paper. The reactant solution includes an oxalate and a fluorescer and reacts with the oxidizer after it is applied to the oxidizer layer. A preferred embodiment of the invention includes the presence of an oxidizer activator layer. A chemiluminescent marking system including a chemiluminescent reactant solution in at least one first delivery applicator and an oxidizer solution in a second delivery applicator. The oxidizer solution reacts with the chemiluminescent reactant solution to cause the chemiluminescent reactant solution to glow. A stabilizer may also be included in the oxidizer solution.

Abstract: Compounds of formula (I): [where: R1 is a direct bond, oxygen, a group >CH2, sulphur, a group >C?O, a group-(CH2)2— or a group-N—Ra, where Ra is hydrogen or alkyl; R3, R4, R5 and R6 are hydrogen or substituents?; R8, R9, R10 and R11 are hydrogen, hydroxy or alkyl; or R9 and R11 are joined to form a fused ring system with the benzene rings to which they are attached; R7 is a direct bond, oxygen or a —CH2-group; p is 0 or 1 ; substituents? are: alkyl, alkoxy, alkenyl, halogen, nitrile, hydroxyl, aryl, aralkyl, aryloxy, aralkyloxy, arylalkenyl, cycloalkyl, carboxy, carboxyalkoxy, alkoxycarbonyl, aryloxycarbonyl, alkylcarbonyloxy, alkanesulphonyl, arenesulphonyl, alkanoyl or arylcarbonyl; n is 1 to 12; R12 is hydrogen, methyl or ethyl; A is a group —[O(CHR13CHR14)a]y—, —[O(CH2)bCO]y-, or —[O(CH2)bCO](y-1)-[O(CHR13CHR14)a]—, where: one of R13 and R14 is hydrogen and the other is hydrogen, methyl or ethyl; a is 1 to 2 ; b is 4 to 5 ; Q is a residue of a polyhydroxy compound having from 2 to 6 hydroxy groups;

Abstract: The present invention provides a chemiluminescence enhancer treated to retain favorable dispersibility of fine solid carriers and stably exert a chemiluminescence enhancing action. The invention provides a chemiluminescence enhancer used for signal detection in a solid phase immunoassay using antigen or/and antibody immobilized onto fine solid carriers dispersible in a liquid medium, consisting of a water soluble macromolecular quaternary ammonium salt, a quaternary sulfonium salt or a quaternary phosphonium salt in order to enhance emission of light caused by an enzymatic reaction of a chemiluminescent substrate having dioxetane, wherein the chemiluminescence enhancer is given an aggregation inhibition treatment of the fine solid carriers by the treatment with an oxidizing agent or a reducing agent, and a chemiluminescence method and a kit using the chemiluminescence enhancer.

Abstract: Novel compounds comprising a C—C double bond substituted at one carbon with two sulfur atom-containing groups are disclosed. The compounds are useful in methods and compositions for generating chemiluminescence rapidly by reaction with a peroxidase enzyme and a peroxide. The chemiluminescence thus produced can be used as a detectable signal in assays for peroxidase enzymes or peroxide-producing enzymes and in assays employing enzyme-labeled specific binding pairs.

Abstract: A first object is to prevent the leakage of chemiluminescent liquid during chemiluminescence. A second object is to provide enhanced shock resistance. A third object is to provide enhanced hydraulic-pressure resistance and a product at a low cost. A chemiluminescent device comprises a container, and a synthetic-resin ampoule contained in the flexible container. The ampoule has a surface formed with a groove extending along the circumferential direction thereof.

Abstract: Disclosed is an ink composition suitable for ink jet printing comprising a luminescent compound, a solvent, and an energy active compound, and optionally a non-luminescent colorant. The energy active compound, when exposed to energy, generates one or more active species that can react with the luminescent compound to alter one or more of the characteristics of the luminescent compound. The luminescent compound can be colored or colorless. Also disclosed is a method for marking substrates comprising providing a mark comprising a luminescent compound and an energy active compound. Further disclosed is a jet ink composition suitable for printing on substrates authentication or security marks which can be rendered unreadable. The luminescence of the mark is quenched and the visible color is changed when irradiated with a light.

Abstract: Disclosed herein is a chemiluminescent composition that can produce bight pure white light even at a low temperature. The chemiluminescent composition producing white light comprises a blue or green fluorescer or a mixture thereof as a fluorescer, and a 1,6,7,12-tetrahaloperylenedicarboximide represented by Formula 3 wherein R is an alkyl or aryl group and X is Cl or Br.

Abstract: The present invention teaches a chemiluminescent device along with a process for its production. The invention specifically relates to a chemiluminescent article of manufacture which includes a containment device and chemical system, both of which may be selected so as to be particularly susceptible to environmental degradation subsequent to their use. In a preferred embodiment the chemiluminescent device is categorized as being biodegradable, i.e. designed to be capable of losing its physical form and re-entering the environment.

Abstract: Electrochemiluminescent-labels and enzyme substrates, which preferably are conjugated, are used in immunoassays and electrochemiluminescence is generated catalytically. In conventional electrochemiluminescence immunoassays, an anti-analyte antibody molecule can give rise to typically 6–8 electrochemiluminescence-active ruthenium atoms, while in the present invention, each enzyme-labeled anti-analyte molecule can give rise to thousands of electrochemiluminescence-active ruthenium atoms per second. An exemplary immunoassay is based on a catalytic process employing ?-lactamase-conjugated anti-analytes which enzymatically hydrolyze electrochemiluminescent-labeled substrates, making them strongly electrochemiluminescent. The electrochemiluminescence signal generated by each anti-analyte molecule (i.e., each analyte molecule) is much greater than with the conventional method. Accordingly, greater sensitivity can be gained in the measurement of low concentrations of a given immunoassay analyte.

Abstract: The present invention relates to the use of functionalized perylene-3,4,9,10-tetracarboxylic acid diimides as initiator and/or co-reactant for polymerization reactions, to polymers prepared using the perylene-3,4,9,10-tetracarboxylic acid diimide compounds, to the use of these colored and/or fluorescent polymers, and to novel functionalized perylenetetracarboxylic acid diimides.

Abstract: Novel compounds comprising a C—C double bond substituted at one carbon with two sulfur atom-containing groups are disclosed. The compounds are useful in methods and compositions for generating chemiluminescence rapidly by reaction with a peroxidase enzyme and a peroxide. The chemiluminescence thus produced can be used as a detectable signal in assays for peroxidase enzymes or peroxide-producing enzymes and in assays employing enzyme-labeled specific binding pairs.

Abstract: Novel compounds comprising a C—C double bond substituted at one carbon with two sulfur atom-containing groups are disclosed. The compounds are useful in methods and compositions for generating chemiluminescence rapidly by reaction with a peroxidase enzyme and a peroxide. The chemiluminescence thus produced can be used as a detectable signal in assays for peroxidase enzymes or peroxide-producing enzymes and in assays employing enzyme-labeled specific binding pairs.

Abstract: A dual enzyme chemiluminescent substrate formulation useful for the independent or simultaneous analysis of the enzymes is disclosed, the formulation includes, as one substrate component, dihydrophthalazinedione, such as luminol or isoluminol, and a peroxide source and, as the other substrate component, a 1,2-dioxetane. The formulation further includes a polymeric quaternary onium salt as an isolating agent to defeat adverse interactions between the substrate pairs.

Abstract: A two and three dimensional display medium having a novel transparent polymer composite containing particles of crystals doped with Yb3+ and other rare earth ions. The polymer composite creates homogeneously dispersed compositions without cracking or delamination of the film and can be used for various optical applications.