Volatile Or Gas Charged Liquids Containing Patents (Class 252/8)
  • Patent number: 6402975
    Abstract: Fire flooding and extinguishing agents and detoxifiers which are environmentally safe and non-toxic in both natural form and in fire exposed degraded forms are disclosed. The flooding and streaming-type fire extinguishing agents are rich in low boiling, unsaturated fluorocarbon compounds having low liquid viscosities, and low boiling alkenes as detoxifying agents. The detoxifiers are conjugated double bond hydrocarbons.
    Type: Grant
    Filed: September 21, 2000
    Date of Patent: June 11, 2002
    Assignee: Lacovia N.V.
    Inventors: Elio F. Guglielmi, Lorne D. MacGregor
  • Patent number: 6352648
    Abstract: Fire flooding and extinguishing agents and detoxifiers which are environmentally safe and non-toxic in both natural form and in fire exposed degraded forms are disclosed. The flooding and streaming-type fire extinguishing agents are rich in low boiling, unsaturated halocarbon compounds having low liquid viscosities, and low boiling alkenes as detoxifying agents. The detoxifiers are conjugated double bond hydrocarbons.
    Type: Grant
    Filed: July 24, 2000
    Date of Patent: March 5, 2002
    Assignee: Lacovia N.V.
    Inventors: Elio F. Guglielmi, Lorne D. MacGregor
  • Patent number: 6346203
    Abstract: A method for suppressing a fire at a burning material comprising delivering to said burning material (a) an inert gas and (b) a gaseous compound selected from the group consisting of a hydrofluorocarbon, an iodofluorocarbon, and a mixture thereof, gases (a) and (b) being delivered in a combined concentration sufficient to extinguish the fire.
    Type: Grant
    Filed: February 15, 2000
    Date of Patent: February 12, 2002
    Assignee: PCBU Services, Inc.
    Inventors: Mark L. Robin, W. Douglas Register, Thomas F. Rowland
  • Publication number: 20010032960
    Abstract: Unsaturated C3 and C4 perfluorocarbons are used to extinguish fires. These compounds have been found to extinguish fires as effectively as Halons with similar volatility, residue levels, materials compatibility and safety but with enhanced environmental acceptability.
    Type: Application
    Filed: February 9, 2000
    Publication date: October 25, 2001
    Inventors: Lawrence Robert Grzyll, Dwight Douglas Back, Charlie Ramos, Nidal Abdul Samad
  • Patent number: 6267788
    Abstract: The present invention relates to a fire extinguishing unit containing a gas-liquid mixture especially for use as a fire extinguishing agent. The mixture contains a) at least one halogenated carbon or C1-C10 hydrocarbon, b) a chemical compound having a high stream pressure and a low boiling point, high solubility in the halogenated compound and a capacity of dispersing the halogenated compound, and/or an inert gas.
    Type: Grant
    Filed: October 16, 2000
    Date of Patent: July 31, 2001
    Assignee: Halotron, Inc.
    Inventor: Jan Andersson
  • Patent number: 6182768
    Abstract: The present invention relates to a gas-liquid mixture especially for use as a fire extinguishing agent. The mixture contains a) at least one halogenated carbon or C1-C10 hydrocarbon, b) a chemical compound having a high steam pressure and a low boiling point, high solubility in the halogenated compound and a capacity of dispersing the halogenated compound, and/or an inert gas. The invention also relates to a fire extinguishing unit and a method for using the mixture.
    Type: Grant
    Filed: April 29, 1999
    Date of Patent: February 6, 2001
    Assignee: Halotron, Inc.
    Inventor: Jan Andersson
  • Patent number: 6146544
    Abstract: Fire flooding and extinguishing agents and detoxifiers which are environmentally safe and non-toxic in both natural form and in fire exposed degraded forms are disclosed. The flooding and streaming-type fire extinguishing agents are rich in low boiling, unsaturated halocarbon compounds having low liquid viscosities, and low boiling alkenes as detoxifying agents. The detoxifiers are conjugated double bond hydrocarbons.
    Type: Grant
    Filed: March 9, 1998
    Date of Patent: November 14, 2000
    Assignee: Lacovia N.V.
    Inventors: Elio F. Guglielmi, Lorne D. MacGregor
  • Patent number: 6001270
    Abstract: Sticky high water content gelled fire extinguisher compositions hold the antage of providing a high water content, slightly viscous (sticky) gel with flow properties similar to water. The ability of this material to stick to burning surfaces is what sets it apart from water extinguishers. Not only are fires extinguished, but also surfaces are cooled by the sticky gel as the water evaporates. The basic gelled fire extinguisher composition is comprised of about 88 weight percent water and about 12 weight percent of a 7 nanometer particle size silicon dioxide gellant. The silicon dioxide gellant is available as EH5 tradename by Cabot for this silicon dioxide gellant. Other ingredients such as dispersants, wetting agents and flame retardants can be used as additives in combination with the gelling agent. The actual gel system is inexpensive, made from readily available ingredients and easily prepared.
    Type: Grant
    Filed: March 16, 1998
    Date of Patent: December 14, 1999
    Assignee: The United States of America as represented by the Secretary of the Army
    Inventors: William D. Stephens, Leo K. Asaoka, Christi L. Salter
  • Patent number: 5993682
    Abstract: A set of blends for extinguishment of fires, suppression of explosions, and inertion against fires and explosions is disclosed. The blends are comprised of a bromine-containing component and a fluorine-containing component. The bromine-containing component is comprised of one or more hydrobromoalkanes, hydrobromoalkenes, and/or hydrobromoarenes. The fluorine-containing component is comprised of one or more fluorine-containing halocarbons, which may also contain chlorine. Specifically provided as fluorine-containing halocarbons are saturated and unsaturated hydrochlorofluorocarbons, hydrofluorocarbons, perfluorocarbons, perfluoroethers, hydrofluoroethers, and/or hydrofluoropolyethers. This provides a blend that mimics the fire and explosion protection action of halons and hydrobromofluorocarbons without the environmental impact associated with these compounds, which contain bromine and fluorine in the same molecule.
    Type: Grant
    Filed: September 9, 1997
    Date of Patent: November 30, 1999
    Assignee: University of New Mexico
    Inventors: Robert E. Tapscott, Ted A. Moore, Joseph L. Lifke
  • Patent number: 5948323
    Abstract: The present invention concerns finely divided particles of compounds that provide flame retardancy and/or smoke suppressant properties to fibers, textiles, polymeric articles, paper, paint, coating and insulation. More particularly, the present invention concerns colloidal-sized particles of hydrated salts, organic phosphates, metal borates, polyamides, solid halogenated flame retardants with a melting point greater than 250.degree. C., molybdenum compounds, metallocenes, antimony compounds, zinc compounds, bismuth compounds and other solid chemicals which act as flame retardants or smoke suppressants. The present invention also concerns various milling processes to reduce these materials to colloidal sizes and to disperse them in water, organic liquids and meltable solids.
    Type: Grant
    Filed: November 26, 1997
    Date of Patent: September 7, 1999
    Assignee: GLCC Technologies, Inc.
    Inventors: John McLaughlin, Philip S. Podwirny, John C. Morley
  • Patent number: 5919393
    Abstract: A process for controlling or extinguishing fires comprises introducing to a fire or flame (e.g., by streaming or by flooding) a non-flammable extinguishment composition comprising at least one mono- or dialkoxy-substituted perfluoroalkane, perfluorocycloalkane, perfluorocycloalkyl-containing perfluoroalkane, or perfluorocycloalkylene-containing perfluoroalkane compound, the compound optionally containing additional catenary heteroatoms in its perfluorinated portion and preferably having a boiling point in the range of from about 0.degree. C. to about 150.degree. C. The compounds exhibit good extinguishment capabilities while being environmentally acceptable.
    Type: Grant
    Filed: November 25, 1997
    Date of Patent: July 6, 1999
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Richard M. Flynn, Scott D. Thomas
  • Patent number: 5862867
    Abstract: The present invention relates to a gas-liquid mixture especially for use as a fire extinguishing agent. The mixture containsa) at least one halogenated carbon or C.sub.1 -C.sub.10 hydrocarbon,b) a chemical compound having a high stream pressure and a low boiling point, high solubility in the halogenated compound and a capacity of dispersing the halogenated compound, and/or an inert gas.The invention also relates to a fire extinguishing unit and a method for using the mixture.
    Type: Grant
    Filed: October 16, 1997
    Date of Patent: January 26, 1999
    Assignee: Halotron, Inc.
    Inventor: Jan Andersson
  • Patent number: 5856587
    Abstract: Extinguishing compositions comprising a liquid extinguishing agent constituted by hydrofluoropolyethers having general formulaHF.sub.2 CO(CF.sub.2 O).sub.n (CF.sub.2 CF.sub.2 O).sub.m CF.sub.2 Hwherein n and m are integers comprised between 0 and 20, excluding when m and m are contemporaneously 0 and having boiling point between 30.degree. and 200.degree. C. and having an O/C molar ratio between 0.5-1.
    Type: Grant
    Filed: March 5, 1997
    Date of Patent: January 5, 1999
    Assignee: Ausimot SpA
    Inventors: Mario Visca, Gianfranco Spataro, Giuseppe Marchionni
  • Patent number: 5853607
    Abstract: A process chamber is disclosed which provides a 360.degree. circular gas/vacuum distribution over a substrate being processed. The substrate being processed is supported on a heated and optionally cooled pedestal assembly. The substrate faces a one-piece gas distribution faceplate being connected to an RF power supply outside the vacuum environment of the processing chamber. A pumping channel view port is provided to verify and confirm instrumentation readings concerning the degree of surface deposition on process chamber internal surfaces. All process chamber wall surfaces facing the region where plasma will be present during processing (except the gas distribution faceplate) are ceramic and therefore highly resistant to corrosion. The pedestal an un-anodized metal is also covered with a loosely fitting ceramic surface having alignment features to maintain concentricity between the wafer support surface of the pedestal and the wafer being processed.
    Type: Grant
    Filed: October 11, 1995
    Date of Patent: December 29, 1998
    Assignee: Applied Materials, Inc.
    Inventors: Jun Zhao, Tom Cho, Charles Dornfest, Stefan Wolff, Kevin Fairbairn, Xin Sheng Guo, Alex Schreiber, John M. White
  • Patent number: 5833874
    Abstract: Fire-extinguishing compositions of low ozone depletion potential comprise dry particles of fire-extinguishing agents dispersed in a gel of liquified volatile perfluorocarbons, chlorofluorocarbons or hydrofluorocarbons. The dry particles are compatibilized with the carrier gel by the presence of a surfactant system composed of a non-ionic surfactant, a film forming fluorocarbon surfactant and a phosphorus containing antiflocculent.
    Type: Grant
    Filed: December 5, 1995
    Date of Patent: November 10, 1998
    Assignee: Powsus Inc.
    Inventors: Harry E. Stewart, Donald B. MacElwee
  • Patent number: 5759430
    Abstract: A set of tropodegradable agents for extinguishment of fires, suppression of explosions, and inertion against fires and explosions is disclosed. The agents are characterized by high efficiency, cleanliness, and short atmospheric lifetimes. The latter property is essential and results in a low ozone depletion potential (ODP) and a low global warming potential (GWP). The agents are halocarbons or mixtures comprised of halocarbons that have at least one of the following features: carbon-to-carbon double bonds and/or carbon-to-iodine bonds. Specifically disclosed are the two families of agents: (I) bromine-containing alkenes and (2) iodocarbons.
    Type: Grant
    Filed: June 1, 1995
    Date of Patent: June 2, 1998
    Inventors: Robert E. Tapscott, Stephanie R. Skaggs, Jonathan S. Nimitz
  • Patent number: 5718293
    Abstract: A process for controlling or extinguishing fires comprises introducing to a fire or flame (e.g., by streaming or by flooding) a non-flammable extinguishment composition comprising at least one mono- or dialkoxy-substituted perfluoroalkane, perfluorocycloalkane, perfluorocycloalkyl-containing perfluoroalkane, or perfluorocycloalkylene-containing perfluoroalkane compound, the compound optionally containing additional catenary heteroatoms in its perfluorinated portion and preferably having a boiling point in the range of from about 0.degree. C. to about 150.degree. C. The compounds exhibit good extinguishment capabilities while being environmentally acceptable.
    Type: Grant
    Filed: December 15, 1995
    Date of Patent: February 17, 1998
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Richard M. Flynn, Scott D. Thomas
  • Patent number: 5716549
    Abstract: A new set of effective, environmentally safe, nonflammable, low-toxicity refrigerants, solvents, foam blowing agents, propellants, and firefighting agents is disclosed. The agents are clean, electrically nonconductive, and have short atmospheric lifetimes, zero ozone-depletion potential, and low global warming potentials. The agents comprise at least one fluoroiodocarbon agent satisfying the general formula C.sub.a H.sub.b Br.sub.c Cl.sub.d F.sub.e I.sub.f N.sub.g O.sub.h, wherein a is between and including 1 and 8; b is between and including 0 and 2; c, d, g, and h are each between and including 0 and 1; e is between and including 1 and 18; and f is between and including 1 and 2, either neat or mixed with additives selected from the group consisting of: alcohols, esters, ethers, fluoroethers, hydrocarbons, hydrofluorocarbons, and perfluorocarbons.
    Type: Grant
    Filed: August 22, 1996
    Date of Patent: February 10, 1998
    Assignee: Ikon Corporation
    Inventors: Jonathan Shelley Nimitz, Lance Harrell Lankford
  • Patent number: 5705663
    Abstract: The invention relates to quaternized triethanolamine difatty acid esters prepared from triethanolamine, fatty acid, fatty acid ester and a quaternizing agent and to a process for their preparation and to their use. The quaternized triethanolamine difatty acid esters thus prepared can be used to produce particularly storage-, temperature- and viscosity-stable rinse cycle laundry softeners having a high active content.
    Type: Grant
    Filed: December 7, 1995
    Date of Patent: January 6, 1998
    Assignee: Servo Delden B.V.
    Inventors: Michael Brock, Meinolf Enneking, Kurt Kosswig
  • Patent number: 5698630
    Abstract: The present invention relates to a gas-liquid mixture especially for use as a fire extinguishing agent. The mixture containsa) at least one halogenated carbon or C.sub.1 -C.sub.10 hydrocarbon,b) a chemical compound having a high steam pressure and a low boiling point, high solubility in the halogenated compound and a capacity of dispersing the halogenated compound, and/or an inert gas.The invention also relates to a fire extinguishing unit and a method for using the mixture.
    Type: Grant
    Filed: November 13, 1995
    Date of Patent: December 16, 1997
    Assignee: Halotron, Inc.
    Inventor: Jan Andersson
  • Patent number: 5695691
    Abstract: The present invention concerns finely divided particles of compounds that provide flame retardancy and/or smoke suppressant properties to fibers, textiles, polymeric articles, paper, paint, coating and insulation. More particularly, the present invention concerns colloidal-sized particles of hydrated salts, organic phosphates, metal borates, polyamides, solid halogenated flame retardants with a melting point greater than 250.degree. C., molybdenum compounds, metallocenes, antimony compounds, zinc compounds, bismuth compounds and other solid chemicals which act as flame retardants or smoke suppressants. The present invention also concerns various milling processes to reduce these materials to colloidal sizes and to disperse them in water, organic liquids and meltable solids.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: December 9, 1997
    Assignee: Anzon, Inc.
    Inventors: John McLaughlin, Philip S. Podwirny, John C. Morley
  • Patent number: 5695688
    Abstract: A new set of effective, environmentally safe, nonflammable, low-toxicity refrigerants, solvents, foam blowing agents, propellants, and firefighting agents is disclosed. The agents are clean, electrically nonconductive, and have short atmospheric lifetimes, zero ozone-depletion potential, and low global warming potentials. The agents comprise at least one fluoroiodocarbon agent satisfying the general formula C.sub.a H.sub.b Br.sub.c Cl.sub.d F.sub.e I.sub.f N.sub.g O.sub.h, wherein a is between and including 1 and 8; b is between and including 0 and 2; c, d, g, and h are each between and including 0 and 1; e is between and including 1 and 18; and f is between and including 1 and 2, either neat or mixed with additives selected from the group consisting of: alcohols, esters, ethers, fluoroethers, hydrocarbons, hydrofluorocarbons, and perfluorocarbons.
    Type: Grant
    Filed: September 10, 1996
    Date of Patent: December 9, 1997
    Assignee: Ikon Corporation
    Inventors: Jonathan Shelly Nimitz, Lance Harrell Lankford
  • Patent number: 5626786
    Abstract: A class of fire suppressant compounds which have labile bromine atoms bound to atoms other than carbon have been discovered to be more effective at suppressing fires than Halon 1211 and Halon 1301. Moreover, this class of fire suppressant compounds hydrolyze or oxidize rapidly in the troposphere and as a consequence thereof, they have minimal ozone depletion potential.
    Type: Grant
    Filed: April 17, 1995
    Date of Patent: May 6, 1997
    Inventors: John H. Huntington, Peter D. Haaland
  • Patent number: 5615742
    Abstract: A method for extinguishing hydrogen fires comprises introducing to the hydrogen fire a fire extinguishing concentration of 1,1,1,2,3,3,3-heptafluoropropane and maintaining the concentration until the fire is extinguished. The method includes heptafluoropropane at a range of 13-30% volume/volume in the air. The fire extinguishing methods also include the use of heptafluoropropane in blend with other fire extinguishing compounds. Also disclosed are atmospheres of hydrogen, an oxidizer, and a sufficient amount of 1,1,1,2,3,3,3-heptafluoropropane to render the atmosphere incapable of supporting combustion of the hydrogen, as well as related methods for preparing such atmospheres.
    Type: Grant
    Filed: September 15, 1995
    Date of Patent: April 1, 1997
    Assignee: Great Lakes Chemical Corporation
    Inventors: Mark L. Robin, Charles J. Mazac, John S. Rubacha
  • Patent number: 5609787
    Abstract: A method for extinguishing fire uses a gaseous fire-extinguishing agent having as an active component thereof a polyfluoro-tertiary amine represented by the following formula:(CF.sub.3).sub.2 NRfwherein Rf stands for a polyfluoroalkyl group of 1-4 carbon atoms or a polyfluoroalkenyl group of 1-4 carbon atoms.
    Type: Grant
    Filed: November 17, 1994
    Date of Patent: March 11, 1997
    Assignee: Agency of Industrial Science & Technology, Ministry of International Trade & Industry
    Inventors: Takashi Abe, Haruhiko Fukaya, Eiji Hayashi, Yoshio Hayakawa
  • Patent number: 5605647
    Abstract: A new set of effective, environmentally safe, nonflammable, low-toxicity refrigerants, solvents, foam blowing agents, propellants, and firefighting agents is disclosed. The agents are clean, electrically nonconductive, and have short atmospheric lifetimes, zero ozone-depletion potential, and low global warming potentials. The agents comprise at least one fluoroiodocarbon agent satisfying the general formula C.sub.a H.sub.b Br.sub.c Cl.sub.d F.sub.e I.sub.f N.sub.g O.sub.h, wherein a is between and including 1 and 8; b is between and including 0 and 2; c, d, g, and h are each between and including 0 and 1; e is between and including 1 and 18; and f is between and including 1 and 2, either neat or mixed with additives selected from the group consisting of: alcohols, esters, ethers, fluoroethers, hydrocarbons, hydrofluorocarbons, and perfluorocarbons.
    Type: Grant
    Filed: June 30, 1994
    Date of Patent: February 25, 1997
    Assignee: Ikon Corporation
    Inventors: Jonathan S. Nimitz, Lance H. Lankford
  • Patent number: 5562861
    Abstract: A new set of effective, environmentally safe, nonflammable, low-toxicity refrigerants, solvents, foam blowing agents, propellants, and firefighting agents is disclosed. The agents are clean, electrically nonconductive, and have short atmospheric lifetimes, zero ozone-depletion potential, and low global warming potentials. The agents comprise at least one fluoroiodocarbon agent satisfying the general formula C.sub.a H.sub.b Br.sub.c Cl.sub.d F.sub.e I.sub.f N.sub.g O.sub.h, wherein a is between and including 1 and 8; b is between and including 0 and 2; c, d, g, and h are each between and including 0 and 1; e is between and including 1 and 18; and f is between and including 1 and 2, either neat or mixed with additives selected from the group consisting of: alcohols, esters, ethers, fluoroethers, hydrocarbons, hydrofluorocarbons, and perfluorocarbons.
    Type: Grant
    Filed: March 31, 1995
    Date of Patent: October 8, 1996
    Assignee: IKON Corporation
    Inventors: Jonathan S. Nimitz, Lance H. Lankford
  • Patent number: 5558810
    Abstract: The present invention relates to compositions of pentafluoropropane and a fluorinated propane having from 1 to 5 fluorine atoms; a hydrocarbon having from 1 to 5 carbon atoms; 1,1,1,4,4,4-hexafluorobutane, (CF.sub.3).sub.2 CHCH.sub.3, dimethyl ether; or 1,1,1,2,3,4,4,5,5,5-decafluoropentane. The compositions, which may be azeotropic or azeotrope-like, may be used as refrigerants, cleaning agents, expansion agents for polyolefins and polyurethanes, aerosol propellants, refrigerants, heat transfer media, gaseous dielectrics, fire extinguishing agents, power cycle working fluids, polymerization media, particulate removal fluids, carrier fluids, buffing abrasive agents or displacement drying agents.
    Type: Grant
    Filed: November 16, 1994
    Date of Patent: September 24, 1996
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Barbara H. Minor, Tuneen E. C. Chisolm
  • Patent number: 5534164
    Abstract: Flooding fire extinguishing agents which are non-toxic and environmentally safe in both natural form and in degraded form which may occur as a result of exposure to fire are disclosed. The flooding fire extinguishing agents are rich in low boiling unsaturated chlorofluorocarbon compounds and have low liquid viscosities.
    Type: Grant
    Filed: November 18, 1994
    Date of Patent: July 9, 1996
    Inventor: Elio Guglielmi
  • Patent number: 5534035
    Abstract: A copolymer for use in rendering leather water repellant is formed from ethylenically unsaturated monomer and ethylenically unsaturated monofunctional monomer, wherein the monomers include mono- or di- fatty alkyl ester of dicarboxylic acid and a free carboxylic acid monomer and provide a carboxylic acid equivalent weight of 100 to 1000 and at least 20% by weight of fatty alkyl groups.
    Type: Grant
    Filed: August 18, 1993
    Date of Patent: July 9, 1996
    Assignee: Allied Colloids Limited
    Inventors: Adrian S. Allen, Finlay D. Aiston
  • Patent number: 5484546
    Abstract: Refrigerant compositions include mixtures of hexafluorodimethyl ether and cyclopropane, dimethylether or propylene; bis(difluoromethyl) ether and 2,2,3,4,4-pentafluorooxetane; fluoromethyl trifluoromethyl ether and 2,2,4,4,5,5-hexafluoro-1,3-dioxolane, 1-trifluoromethoxy-1,2,2,2-tetrafluoroethane, dimethylether or tris(trifluoromethyl)amine; trifluoromethyl methyl ether and perfluorooxetane, 2,2,4,4,5,5-hexafluoro-1,3-dioxolane, perfluoromethyl ethyl ether, perfluorodinethoxymethane, 1-trifluoromethoxy-1,2,2,2-tetrafluoroethane, dimethylether or tris(trifluoromethyl)amine; perfluoromethyl ethyl ether and dimethylether, propylene or 1-trifluoromethoxy-1,2,2,2-tetrafluoroethane; perfluorodirnethoxymethane and dimethylether or isobutane; 1-trifluoromethoxy-1,1,2,2-tetrafluoroethane and tris(trifluoromethyl)amine or dimethylether; difluoromethoxy pentafluoroethane and dimethylether, isobutane or tris(trifluoromethyl)amine; 1-trifluoromethoxy-1,2,2,2-tetrafluoroethane and dimethylether or isobutane; 1-difluorometh
    Type: Grant
    Filed: May 13, 1994
    Date of Patent: January 16, 1996
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Barbara H. Minor, Tuneen E. C. Chisolm, Glenn S. Shealy
  • Patent number: 5480572
    Abstract: Refrigerant compositions include mixtures of perfluorooxetane and perfluoromethyl ethyl ether or dimethyl ether; 2,2,4,4,5,5-hexafluoro-1,3-dioxolane and cyclopropane or dimethyl ether; 2,2,3,4,4-pentafluorooxetane and difluoromethyl(trifluoromethyl)sulfide or 1-trifluoromethoxy-2,2,2-trifluoroethane; 2,2,4,4-tetrafluorooxetane and 1-difluoromethoxy-1,1,2,2-tetrafluoroethane or 1-difluoromethoxy-1,2,2,2-tetrafluoroethane; 2,2,3,3-tetrafluorooxetane and 1-difluoromethoxy-1,1,2,2-tetrafluoroethane or 1-difluoromethoxy-1,2,2,2-tetrafluoroethane.
    Type: Grant
    Filed: May 13, 1994
    Date of Patent: January 2, 1996
    Assignee: E. I. du Pont de Nemours and Company
    Inventor: Barbara H. Minor
  • Patent number: 5466386
    Abstract: Fire-extinguishing compositions of low ozone depletion potential comprise dry particles of ammonium bromide coated with an abherent such as zinc stearate to improve flowability. The coated particles enhance the fire-extinguishing properties of chlorofluorocarbons and halogenated paraffins having low ozone depletion properties, when dispersed therein.
    Type: Grant
    Filed: May 3, 1993
    Date of Patent: November 14, 1995
    Assignee: POWSUS, Inc.
    Inventors: Harry E. Stewart, Donald B. MacElwee
  • Patent number: 5433880
    Abstract: Refrigerant compositions are disclosed which include a first component of bis(trifluoromethyl)sulfide, difluoromethyl(trifluoromethyl)sulfide, pentafluoroethyl sulfur pentafluoride, difluoromethyl sulfur pentafluoride, trifluoromethylsulfur pentafluoride bis(pentafluoroethyl)sulfide and a second component of difluoromethane, 1,1,2,2-tetrafluoroethane, 1,1,1,2-tetrafluoroethane, 1,1,2-trifluoroethane, 1,1-difluoroethane, fluoroethane, dimethyl ether, ammonia, fluoromethyl trifluoromethyl ether, trifluoromethyl methyl ether, 1,1,1,2,2-pentafluoropropane, 2-fluoropropane, cyclopropane, bis(difluoromethyl)ether, 1,1,2,2-tetrafluoropropane, 1,1,1,2-tetrafluoropropane, 1-fluoropropane, 1,1,1,3,3-pentafluoropropane, 1,2,2-trifluoropropane, 2,2-difluoropropane, 1,2-difluoropropane, 1,1-difluoropropane, 1-trifluoromethoxy-2,2,2-trifluoroethane, tris(trifluoromethyl)amine or 1,1,2,2,3-pentafluoropropane.
    Type: Grant
    Filed: March 30, 1994
    Date of Patent: July 18, 1995
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Barbara H. Minor, Glenn S. Shealy
  • Patent number: 5417871
    Abstract: Refrigerant compositions include mixtures of difluoromethane and isobutane, butane, propylene or cyclopropane; pentafluoroethane and propylene or cyclopropane; 1,1,2,2-tetrafluoroethane and propane; 1,1,1,2-tetrafluoroethane and cyclopropane; 1,1,1-trifluoroethane and DME or propylene; 1,1-difluoroethane and propane, isobutane, butane or cyclopropane; fluoroethane and propane or cyclopropane; 1,1,1,2,2,3,3-heptafluoropropane and butane, cyclopropane, DME, isobutane or propane; or 1,1,1,2,3,3,3-heptafluoropropane and butane, cyclopropane, isobutane or propane.
    Type: Grant
    Filed: March 11, 1994
    Date of Patent: May 23, 1995
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Barbara H. Minor, Donald B. Bivens, Brooks S. Lunger
  • Patent number: 5393438
    Abstract: A process for extinguishing, preventing and controlling fires using a composition containing at least one fluoro-substituted propane selected from the group of 2,2-dichloro-1,1,1-trifluoroethane (CHCl.sub.2 CF.sub.3), 2-chloro-1,1,1,2-tetrafluoroethane (CHClFCF.sub.3), and 1,1,1,2-tetrafluoroethane (CH.sub.2 FCF.sub.3), and mixtures thereof is disclosed. The fluoropropanes can be used in open or enclosed areas with little or no effect on the ozone in the stratosphere and with little effect on the global warming process.
    Type: Grant
    Filed: June 16, 1992
    Date of Patent: February 28, 1995
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Richard E. Fernandez
  • Patent number: 5368105
    Abstract: A cryogenic slurry comprising a mixture of solid carbon dioxide particles suspended in liquid nitrogen is provided which is useful in extinguishing underground fires.
    Type: Grant
    Filed: December 11, 1991
    Date of Patent: November 29, 1994
    Assignee: The United States of America as represented by the Secretary of the Interior
    Inventors: Robert F. Chaiken, Ann G. Kim, Andrew M. Kociban, Joseph P. Slivon, Jr.
  • Patent number: 5340490
    Abstract: Azeotrope-like compositions comprising trifluoromethane and carbon dioxide or trifluromethane, hexafluoroethane and carbon dioxide are stable and have utility as refrigerants for heating and cooling as well as fire extinguishing compositions.
    Type: Grant
    Filed: July 14, 1993
    Date of Patent: August 23, 1994
    Assignee: AlliedSignal Inc.
    Inventors: Barbara R. Decaire, Peter B. Logsdon, Earl A. E. Lund, Ian R. Shankland, Rajiv R. Singh, David P. Wilson, Raymond H. P. Thomas
  • Patent number: 5262077
    Abstract: Azeotrope-like blends are disclosed comprising effective amounts of 1,1,1,2-tetrafluoroethane (HFC-134a), 1,1-difluoroethane (HFC-152a) and a halocarbon selected from the group consisting of 2-chloro-1,1,1,2-tetrafluoroethane (HCFC-124), 2-chloro-1,1,2,2-tetrafluoroethane (HCFC-124a), 1-hydroperfluoropropane (HFC-227ca), 2-hydroperfluoropropane (HFC-227ea), and mixtures thereof.
    Type: Grant
    Filed: July 3, 1991
    Date of Patent: November 16, 1993
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Donald B. Bivens, Brooks S. Lunger
  • Patent number: 5250208
    Abstract: Azeotropic or azeotrope-like compositions of effective amounts of 1,1,2,2,3,3,4,4,-octofluorobutane; trans-1,2-dichloroethylene, cis-1,2-dichloroethylene, 1,1-dichloroethane, or 1,3-dichloro-1,2,2,3,3-HCFC-225cb; and an alcohol such as methanol, ethanol, or isopropanol, to form an azeotropic or azeotrope-like composition are disclosed that are useful as cleaning agents, refrigerants, aerosol propellants, heat transfer media, gaseous dielectrics, fire extinguishing agents, expansion agents for polyolefins and polyurethanes and as power cycle working fluids.
    Type: Grant
    Filed: April 2, 1992
    Date of Patent: October 5, 1993
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Abid N. Merchant, Janet C. Sung
  • Patent number: 5250200
    Abstract: An environmentally safe fire fighting technique comprises directing a fire/flame extinguishing amount of an essentially zero ODP hydrofluoroalkane compound (other than a tetrafluoroethane or pentafluoroethane) onto a burning fire or flame, e.g., by total flooding.
    Type: Grant
    Filed: June 10, 1991
    Date of Patent: October 5, 1993
    Assignee: Atochem
    Inventor: Daniel Sallet
  • Patent number: 5248433
    Abstract: Constant boiling azeotropic or azeotrope-like mixtures of octafluoropropane and fluoroethane are useful as refrigerants, aerosol propellants, heat transfer media, gaseous dielectrics, fire extinguishing agents, expansion agents for polyolefins and polyurethanes and as power cycle working fluids.
    Type: Grant
    Filed: April 30, 1992
    Date of Patent: September 28, 1993
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Vinci M. Felix, Mark B. Shiflett
  • Patent number: 5236611
    Abstract: Constant boiling compositions of perfluoropropane and trifluoroethane that are useful as refrigerants, aerosol propellants, heat transfer media, gaseous dielectrics, fire extinguishing agents, expansion agents for polyolefins and polyurethanes and as power cycle working fluids.
    Type: Grant
    Filed: October 28, 1991
    Date of Patent: August 17, 1993
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Mark B. Shiflett
  • Patent number: 5234613
    Abstract: Substantially constant boiling compositions that are mixtures of difluoromethane and propane that are useful as refrigerants, aerosol propellants, heat transfer media, gaseous dielectrics, fire extinguishing agents, and expansion agents for polymers.
    Type: Grant
    Filed: September 30, 1991
    Date of Patent: August 10, 1993
    Assignee: E.I. Du Pont de Nemours and Company
    Inventor: Mark B. Shiflett
  • Patent number: 5232618
    Abstract: Substantially constant boiling mixtures of difluoromethane and 1,1,1-trifluoroethane or perfluoroethane are useful as refrigerants, aerosol propellants, heat transfer media, gaseous dielectrics, fire extinguishing agents, and expansion agents for polymers.
    Type: Grant
    Filed: September 30, 1991
    Date of Patent: August 3, 1993
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Mark B. Shiflett
  • Patent number: 5221493
    Abstract: Azeotropic mixtures of HFC-338pcc and an alcohol such as methanol, ethanol, isopropanol or N-propanol, or a ketone such as acetone, are disclosed that are useful as cleaning agents, refrigerants, aerosol propellants, heat transfer media, gaseous dielectrics, fire extinguishing agents, expansion agents for polyolefins and polyurethanes, power cycle working fluids, polymerization media, particulate removal fluids, carrier fluids, and displacement drying agents.
    Type: Grant
    Filed: October 18, 1991
    Date of Patent: June 22, 1993
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Abid N. Merchant, Allen C. Sievert, Akimichi Yokozeki, Janet C. Sung
  • Patent number: 5219474
    Abstract: A liquid fire extinguishing composition is obtained by mixing a C.sub.1 -C.sub.5 halogenated alkane such as Halone 1301 (CF.sub.3 Br), Halone 1211 (CF.sub.2 ClBr), or a mixture thereof with an organophosphorus compound, or the mixture thereof for a wide variety of a fire extinguishment and no residues after fire extinguishing.
    Type: Grant
    Filed: August 8, 1990
    Date of Patent: June 15, 1993
    Assignee: Korea Institute of Science and Technology
    Inventors: Choong E. Song, In O. Kim, Jae K. Lee, Tae K. Kim, Sang G. Lee
  • Patent number: 5196137
    Abstract: Azeotropic mixtures of 1,1,1,2,3,4,4,5,5,5-decafluoropentane (HFC-43-10mee) and trans-1,2-dichloroethylene, cis-1,2-dichloroethylene or 1,1-dichloroethane are useful as cleaning agents, expansion agents for polyolefins and polyurethanes, refrigerants, aerosol propellants, heat transfer media, gaseous dielectrics, fire extinguishing agents, power cycle working fluids, polymerization media, particulate removal fluids, carrier fluids, buffing abrasive agents, and displacement drying agents.
    Type: Grant
    Filed: October 1, 1991
    Date of Patent: March 23, 1993
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Abid N. Merchant
  • Patent number: 5194170
    Abstract: Azeotropic or azeotrope-like compositions of effective amounts of 1,1,2,2,3,3,4,4-octafluorobutane and trans-1,2-dichloroethylene; cis-1,2-dichloroethylene; or 1,1-dichloroethane to form an azeotropic or azeotrope-like composition are disclosed that are useful as cleaning agents, refrigerants, aerosol propellants, heat transfer media, gaseous dielectrics, fire extinguishing agents, expansion agents for polyolefins and polyurethanes and as power cycle working fluids.
    Type: Grant
    Filed: April 2, 1992
    Date of Patent: March 16, 1993
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Abid N. Merchant, Janet C. Sung
  • Patent number: 5185094
    Abstract: Ternary mixtures of pentafluoroethane, difluoromethane and tetrafluoroethane are useful as refrigerants, aerosol propellants, heat transfer media, gaseous dielectrics, fire extinguishing agents, expansion agents for polyolefins and polyurethanes, and as power cycle working fluids.
    Type: Grant
    Filed: February 1, 1991
    Date of Patent: February 9, 1993
    Assignee: E. I. du Pont de Nemours and Company
    Inventor: Mark B. Shiflett