With Stretching Of Formed Article Patents (Class 264/208)
  • Patent number: 8617445
    Abstract: The present invention provides a process for producing an oriented thermoplastic polyester resin sheet which is excellent in tensile strength, tencile modulas and heat resistance, and a light laminate-molded body using the same, which has a low linear expansion coefficient and is excellent in impact resistance, durability, easiness of handling, productivity, and others. A process for producing an oriented thermoplastic polyester resin sheet, which includes: pultrusion-drawing a thermoplastic polyester resin sheet in an amorphous state at a temperature from the glass transition temperature of the thermoplastic polyester resin ?20° C. to the glass transition temperature of the thermoplastic polyester resin +20° C.; and then drawing the resultant uniaxially at a temperature higher than the temperature for the pultrusion-drawing. A laminate-molded body, wherein a thermoplastic resin layer is laminated on each of the surfaces of the resultant oriented thermoplastic polyester resin sheet.
    Type: Grant
    Filed: February 17, 2006
    Date of Patent: December 31, 2013
    Assignee: Sekisui Chemical Co., Ltd.
    Inventors: Shigeru Ogasawara, Hirotsugu Yoshida, Hisashi Eguchi, Ryuichi Matsuo
  • Patent number: 8308862
    Abstract: An optical cellulose acylate film comprising a polymer component which is a cellulose acylate obtained by substituting hydroxyl groups of a cellulose by an acetyl group and an acyl group having 3 or more carbon atoms, wherein a substitution degree A of the acetyl group and a substitution degree B of the acyl group having 3 or more carbon atoms satisfy the following formulae (I) and (II): 2.0?A+B?3.0 (I), 0<B (II), and the optical cellulose acylate film comprises a retardation-expressing agent which is at least one of a rod-like compound and a discotic compound or an elastic modulus E(MD) in a casting direction and an elastic modulus E(TD) in a casting width direction satisfy the following formulae (III) and (IV): 1,500 MPa?E(MD)?3,400 Mpa (III) and 1,200 MPa?E(TD)?3,400 Mpa (IV).
    Type: Grant
    Filed: May 13, 2005
    Date of Patent: November 13, 2012
    Assignee: FUJIFILM Corporation
    Inventors: Hiroyuki Kawanishi, Yosuke Nishiura, Takako Nishiura, legal representative
  • Patent number: 8304040
    Abstract: A polymer is swollen in a first tank. The swelling temperature is in the range of ?10 to 50° C. The mixture is cooled in a first cooling vessel to the range of ?100 to ?10° C., and thereafter heated in a heating device to the range of 0 to 57° C. The polymer is cellulose acylate in which a degree of substitution of the acyl group for hydroxyl group is at least 2.87. A film obtained from the cellulose acylate has a negative value of ?Re and a positive value of ?Rth, and |?Rth| is at least 10 nm. ?Re and ?Rth are respective difference of Re and Rth at the measurement thereof with use of wavelengths between 700 nm and 400 nm. The film is used adequately as a birefringence film, a protective film for a polarizing filter in a liquid crystal display.
    Type: Grant
    Filed: January 26, 2005
    Date of Patent: November 6, 2012
    Assignee: FUJIFILM Corporation
    Inventor: Yasuyuki Sasada
  • Patent number: 8246886
    Abstract: A method and system for aligning nanotubes within an extensible structure such as a yarn or non-woven sheet. The method includes providing an extensible structure having non-aligned nanotubes, adding a chemical mixture to the extensible structure so as to wet the extensible structure, and stretching the extensible structure so as to substantially align the nanotubes within the extensible structure. The system can include opposing rollers around which an extensible structure may be wrapped, mechanisms to rotate the rollers independently or away from one another as they rotate to stretch the extensible structure, and a reservoir from which a chemical mixture may be dispensed to wet the extensible structure to help in the stretching process.
    Type: Grant
    Filed: July 9, 2008
    Date of Patent: August 21, 2012
    Assignee: Nanocomp Technologies, Inc.
    Inventors: David S. Lashmore, Robert Braden, Anastasios John Hart, John Welch
  • Patent number: 7998575
    Abstract: The invention relates to a continuous dry spinning process for preparing a fiber from a polymer solution having concentrations of polymer, salt, solvent and water. After the fiber is extruded and quenched, the fiber is placed in contact with a conditioning solution comprising concentrations of solvent, salt, and water. The conditioning solution acts upon the fiber to plasticize the fiber prior to being drawn. The conditioning solution has concentrations of solvent, salt, and water so that the fiber is plasticized to the extent necessary for drawing but does not plasticize the fiber to such an extent as to re-dissolve the fiber into a polymeric solution. A heat-treated fiber manufactured from this process has improved shrinkage and can be colored to darker shades.
    Type: Grant
    Filed: December 19, 2007
    Date of Patent: August 16, 2011
    Assignee: E.I. du Pont de Nemours and Company
    Inventors: Mark H. Headinger, Edgar N. Rudisill, David W. Luckey
  • Patent number: 7964127
    Abstract: A method for producing an optical film comprising the steps of: (i) melt casting a cellulose ester resin or a cycloolefin resin by extruding melt of the cellulose ester resin or the cycloolefin resin from a die onto a roll-shaped cooling drum; (ii) cooling and solidifying the extruded melt to form a film; (iii) stretching the film in a lateral direction of the film; and (iv) winding the film in a roll, wherein the cooling drum has plural regions divided predeterminedly in an axis direction of the cooling drum, a temperature of each region being independently controlled.
    Type: Grant
    Filed: August 26, 2010
    Date of Patent: June 21, 2011
    Assignee: Konica Minolta Opto, Inc.
    Inventor: Kenichi Kazama
  • Patent number: 7914712
    Abstract: A cellulose acylate film characterized in that it has a shear rate dependency of melt viscosity of 0.1 to 2 and/or a temperature dependency of melt viscosity of 0.1 to 3. The cellulose acylate film is capable of suppressing generation of cutting wastage at the time of cutting.
    Type: Grant
    Filed: May 24, 2006
    Date of Patent: March 29, 2011
    Assignee: Fujifilm Corporation
    Inventor: Kiyokazu Hashimoto
  • Patent number: 7780889
    Abstract: The invention relates to a continuous dry spinning process for preparing a fiber from a polymer solution having concentrations of polymer, salt, solvent and water. After the fiber is extruded and quenched, the fiber is placed in contact with a conditioning solution comprising concentrations of solvent, salt, and water. The conditioning solution acts upon the fiber to plasticize the fiber prior to being drawn. The conditioning solution has concentrations of solvent, salt, and water so that the fiber is plasticized to the extent necessary for drawing but does not plasticize the fiber to such an extent as to re-dissolve the fiber into a polymeric solution. A heat-treated fiber manufactured from this process has improved shrinkage and can be colored to darker shades.
    Type: Grant
    Filed: December 19, 2007
    Date of Patent: August 24, 2010
    Assignee: E.I. du Pont de Nemours and Company
    Inventors: Mark H. Headinger, Edgar N. Rudisill, David W. Luckey
  • Patent number: 7771636
    Abstract: The invention relates to a continuous dry spinning process for preparing a fiber from a polymer solution having concentrations of polymer, salt, solvent and water. After the fiber is extruded and quenched, the fiber is placed in contact with a conditioning solution comprising concentrations of solvent, salt, and water. The conditioning solution acts upon the fiber to plasticize the fiber prior to being drawn. The conditioning solution has concentrations of solvent, salt, and water so that the fiber is plasticized to the extent necessary for drawing but does not plasticize the fiber to such an extent as to re-dissolve the fiber into a polymeric solution. A heat-treated fiber manufactured from this process has improved shrinkage and can be colored to darker shades.
    Type: Grant
    Filed: December 19, 2007
    Date of Patent: August 10, 2010
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Mark H. Headinger, Edgar N. Rudisill, David W. Luckey
  • Patent number: 7771637
    Abstract: The invention relates to a continuous dry spinning process for preparing a fiber from a polymer solution having concentrations of polymer, salt, solvent and water. After the fiber is extruded and quenched, the fiber is placed in contact with a conditioning solution comprising concentrations of solvent, salt, and water. The conditioning solution acts upon the fiber to plasticize the fiber prior to being drawn. The conditioning solution has concentrations of solvent, salt, and water so that the fiber is plasticized to the extent necessary for drawing but does not plasticize the fiber to such an extent as to re-dissolve the fiber into a polymeric solution. A heat-treated fiber manufactured from this process has improved shrinkage and can be colored to darker shades.
    Type: Grant
    Filed: December 19, 2007
    Date of Patent: August 10, 2010
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Mark H. Headinger, Edgar N. Rudisill, David W. Luckey
  • Patent number: 7771638
    Abstract: The invention relates to a continuous dry spinning process for preparing a fiber from a polymer solution having concentrations of polymer, salt, solvent and water. After the fiber is extruded and quenched, the fiber is placed in contact with a conditioning solution comprising concentrations of solvent, salt, and water. The conditioning solution acts upon the fiber to plasticize the fiber prior to being drawn. The conditioning solution has concentrations of solvent, salt, and water so that the fiber is plasticized to the extent necessary for drawing but does not plasticize the fiber to such an extent as to re-dissolve the fiber into a polymeric solution. A heat-treated fiber manufactured from this process has improved shrinkage and can be colored to darker shades.
    Type: Grant
    Filed: December 19, 2007
    Date of Patent: August 10, 2010
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Mark H. Headinger, David W. Luckey, Edgar N. Rudisill
  • Patent number: 7651743
    Abstract: A cellulose acylate film that has a crystallization index expressed by expression (A) as defined in the specification of from 0.70 to 1.02 and a modulus of elasticity in every arbitrary direction of an in-plane of the cellulose acylate film of from 3,800 MPa to 6,000 MPa; a manufacturing method of a cellulose acylate film comprising: casting a dope on a support; drying the dope on the support, so as to form a film; peeling the film from the support; and subjecting the film to a stretching treatment, wherein a crystallization index expressed by expression (A) of the film after peeling and before stretching is from 0.70 to 1.00; an optically compensatory sheet comprising the cellulose acylate film; and a polarizing plate and a liquid crystal display device using the optically compensatory sheet.
    Type: Grant
    Filed: June 2, 2006
    Date of Patent: January 26, 2010
    Assignee: Fujifilm Corporation
    Inventors: Nobutaka Fukagawa, Mitsuo Yoshikane
  • Patent number: 7354633
    Abstract: A retardation film containing a polyalcohol ester, a polycarboxylic acid ester, and a cellulose ester, wherein a total acylation degree of the cellulose ester is in the range of 2.4-2.8; and a Mw/Mn value of the cellulose ester is in the range of 1.4-3.0, provided that Mw represents a weight average molecular weight and Mn represent a number average molecular weight of the cellulose ester.
    Type: Grant
    Filed: November 18, 2005
    Date of Patent: April 8, 2008
    Assignee: Konica Minolta Opto, Inc.
    Inventors: Koichi Saito, Kunio Shimizu, Isamu Michihata
  • Patent number: 7306832
    Abstract: A manufacturing method of a cellulose ester film satisfying the relationships, Nx>Ny>Nz, and 0.8?Rt/R0?3.5, the method comprising casting a cellulose ester dope containing a solvent of a good solvent and a poor solvent on a support to form a web; peeling the web from the support; transporting the peeled web (step D0); holding the edges in the transverse direction of the web (step A); stretching the resulting web in the transverse direction while applying a tension; reducing the tension in the transverse direction of the web; and drying the stretched web, wherein the residual solvent content of the web is 5 to 90% by weight at the beginning in the step A, and the residual poor solvent content in the residual solvent content of the web is from 15 to 95% by weight at the terminal point in the Step D0.
    Type: Grant
    Filed: October 14, 2004
    Date of Patent: December 11, 2007
    Assignee: Konica Corporation
    Inventors: Koji Tasaka, Hiroki Umeda, Noriyasu Kuzuhara, Takatoshi Yajima
  • Patent number: 7273917
    Abstract: A reaction product comprises a polyester-polycarbonate comprising a polyester unit and a polycarbonate unit, a polycarbonate polymer, and a transesterification catalyst. The reaction product has a haze of less than 1.7% as measured at a thickness of 3.2 mm according to ASTM D1003-00. A thermoplastic composition comprising the reaction product and articles formed from therefrom are disclosed. A method of forming the reaction product is also disclosed.
    Type: Grant
    Filed: May 20, 2005
    Date of Patent: September 25, 2007
    Assignee: General Electric Company
    Inventor: Brian Mullen
  • Patent number: 6235869
    Abstract: Synthetic absorbable medical devices made totally or in part from a random polymer comprising glycolide, lactide, trimethylene carbonate, and caprolactone are provided. The polymer can be fabricated into a monofilament which exhibits physical characteristics equivalent to or superior than gut sutures.
    Type: Grant
    Filed: October 9, 1999
    Date of Patent: May 22, 2001
    Assignee: United States Surgical Corporation
    Inventors: Mark S. Roby, Lydmilla K. Kokish, Rooma M. Mehta, Jerry Y. Jonn
  • Patent number: 5779736
    Abstract: The present invention discloses a process for producing a fibrillated cellulose acetate fiber comprising contacting cellulose acetate fiber with a strong base solution at conditions sufficient to remove greater than about 5% of bulk acetyl groups from said cellulose acetate fiber. Modified cellulose acetate staple fiber comprising an outer layer of regenerated cellulose in which at least about 5% of the acetyl groups are removed on an overall fiber basis are also disclosed. Paper products incorporating said fibers are also disclosed.
    Type: Grant
    Filed: January 19, 1995
    Date of Patent: July 14, 1998
    Assignee: Eastman Chemical Company
    Inventors: Tim J. Frederick, Melvin G. Mitchell, Lee R. Partin, Alan K. Wilson, Richard D. Neal
  • Patent number: 5374708
    Abstract: Polyimide filaments and polyimide films having great strength, high elastic modulus and high crystallinity and comprising a novel polyimide which can be melt-processed without impairing high crystallinity and which essentially consists of recurring structural units represented by the formula (I): ##STR1## more than 85 mol % the polyimide consists of recurring structural units of the formula (II): ##STR2## and from 0.5 to 15 mol % of the polyimide consists of recurring structural units represented by the formula (III), the formula (II) exclusive, the formula (IV) and/or the formula (V).
    Type: Grant
    Filed: August 8, 1991
    Date of Patent: December 20, 1994
    Assignee: Mitsui Toatsu Chemicals, Incorporated
    Inventors: Shoji Tamai, Masahiro Ohta, Akihiro Yamaguchi, Masumi Saruwatari
  • Patent number: 5367042
    Abstract: Films containing polybenzazole polymer dissolved in a solvent can be mechanically stretched to provide biaxial orientation. The resulting dope film can be coagulated. The polymer film has improved properties in the direction in which stretching occurs.
    Type: Grant
    Filed: August 27, 1992
    Date of Patent: November 22, 1994
    Assignee: The Dow Chemical Company
    Inventors: Peter E. Pierini, Robbert M. Vermeulen, Susan E. Dollinger
  • Patent number: 5269996
    Abstract: A method for producing ultra fine denier cellulose acetate fibers that entails spinning a spinning solution containing adequately high amounts of cellulose acetate in acetone wherein the cellulose acetate has a falling ball viscosity of 15 to 70 seconds wherein the spinning is conducted through spinnerettes having holes that have a diameter of less than 36 microns followed by drying at a temperature of about 50.degree. to 80.degree. C. at a draw ratio of 0.9 to 1.7.
    Type: Grant
    Filed: September 14, 1992
    Date of Patent: December 14, 1993
    Assignee: Eastman Kodak Company
    Inventors: Benedict M. Lee, Charles S. Winebarger
  • Patent number: 5252396
    Abstract: The present invention relates to a shaped material consisting of a layer having open microvoids (hereinafter referred to as light-scattering layer) and a layer having a hue different from that of the light-scattering layer (hereinafter referred to as color-developing layer), the light-scattering layer constituting at least part of the outer surface of the shaped material and the color-developing layer constituting the rest of the shaped material, which shaped material changes its color reversibly depending upon its moist or dry condition, as well as to a process for producing said shaped material.
    Type: Grant
    Filed: December 19, 1991
    Date of Patent: October 12, 1993
    Assignee: Mitsubishi Rayon Co., Ltd.
    Inventors: Yuichi Fukui, Hajime Itoh, Shigeki Hagura, Itsumi Muraoka
  • Patent number: 4975315
    Abstract: A metallizable, sealable, biaxially stretch-oriented multi-ply film comprises a base layer essentially of polypropylene, a first polyolefinic facing layer and a second polyolefinic facing layer. All of the layers contain a neutralizing agent and a stabilizer against thermal degradation. The neutralizing agent is a calcium carbonate having an absolute particle size of less than 10.0 .mu.m, a mean particle size of less than 0.1 .mu.m, a specific surface area of more than 40 m.sup.2 /g and a whiteness of more than 90% and, the stabilizer comprises a phenolic stabilizer having a molecular weight of more than 1,000 g/mol. One polyolefinic facing layer contains an anti-blocking agent. In addition, a process for producing the metallizable multi-ply film is described, and its use as a packaging material is indicated.
    Type: Grant
    Filed: March 15, 1988
    Date of Patent: December 4, 1990
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Lothar Bothe, Gunter Schloegl, Guenther Crass, Thomas Wilhelm
  • Patent number: 4328838
    Abstract: Thick and tough cellophane for casings is provided wherein viscose is passed through an aqueous coagulation solution containing 15 to 30 weight percent of middle or higher alcohol and/or polyhydric alcohol, the coagulated viscose film being subjected to tension in its horizontal direction in the process of coagulation during passage in the coagulation solution. Thicker and tougher casing cellophane is provided wherein the coagulated viscose film exiting from the coagulation solution is further passed through a second aqueous coagulation solution containing inorganic acid and metallic salt thereof, the coagulated viscose film being subjected to tension in its horizontal direction during passage in the coagulation solution.
    Type: Grant
    Filed: May 30, 1979
    Date of Patent: May 11, 1982
    Assignee: Kanegafuchi Kagaku Kogyo Kabushiki Kaisha
    Inventors: Kosaku Asada, Hiroo Maeno
  • Patent number: 4276173
    Abstract: An improved cellulose acetate semi-permeable hollow fiber suitable for use in artificial kidneys and a process for making same.
    Type: Grant
    Filed: December 21, 1978
    Date of Patent: June 30, 1981
    Assignee: Cordis Dow Corp.
    Inventors: Michael J. Kell, Robert D. Mahoney
  • Patent number: 4246221
    Abstract: A solution containing cellulose dissolved in a tertiary amine N-oxide solvent containing a nonsolvent for cellulose such as water is shaped by extrusion or other shaping process to form a shaped cellulose fiber, rod, plate, tubing or film. The extruded shaped article is stretched in air while still a solution to impart improved physical properties thereto and the cellulose is precipitated from the shaped solution to set the properties without additional drawing. The solution may be prepared by dissolving cellulose in the tertiary amine N-oxide solvent in the barrel of an extrusion apparatus, extruding the solution, orienting by stretching the resulting product in air while still a solution and then precipitating the cellulose from the shaped article before significant degradation of the cellulose. The cellulose and tertiary amine N-oxide may be ground to substantially the same particle size before charging the extruder barrel.
    Type: Grant
    Filed: March 2, 1979
    Date of Patent: January 20, 1981
    Assignee: Akzona Incorporated
    Inventor: Clarence C. McCorsley, III