With Stretching Of Formed Article Patents (Class 264/208)
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Patent number: 8617445Abstract: The present invention provides a process for producing an oriented thermoplastic polyester resin sheet which is excellent in tensile strength, tencile modulas and heat resistance, and a light laminate-molded body using the same, which has a low linear expansion coefficient and is excellent in impact resistance, durability, easiness of handling, productivity, and others. A process for producing an oriented thermoplastic polyester resin sheet, which includes: pultrusion-drawing a thermoplastic polyester resin sheet in an amorphous state at a temperature from the glass transition temperature of the thermoplastic polyester resin ?20° C. to the glass transition temperature of the thermoplastic polyester resin +20° C.; and then drawing the resultant uniaxially at a temperature higher than the temperature for the pultrusion-drawing. A laminate-molded body, wherein a thermoplastic resin layer is laminated on each of the surfaces of the resultant oriented thermoplastic polyester resin sheet.Type: GrantFiled: February 17, 2006Date of Patent: December 31, 2013Assignee: Sekisui Chemical Co., Ltd.Inventors: Shigeru Ogasawara, Hirotsugu Yoshida, Hisashi Eguchi, Ryuichi Matsuo
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Patent number: 8308862Abstract: An optical cellulose acylate film comprising a polymer component which is a cellulose acylate obtained by substituting hydroxyl groups of a cellulose by an acetyl group and an acyl group having 3 or more carbon atoms, wherein a substitution degree A of the acetyl group and a substitution degree B of the acyl group having 3 or more carbon atoms satisfy the following formulae (I) and (II): 2.0?A+B?3.0 (I), 0<B (II), and the optical cellulose acylate film comprises a retardation-expressing agent which is at least one of a rod-like compound and a discotic compound or an elastic modulus E(MD) in a casting direction and an elastic modulus E(TD) in a casting width direction satisfy the following formulae (III) and (IV): 1,500 MPa?E(MD)?3,400 Mpa (III) and 1,200 MPa?E(TD)?3,400 Mpa (IV).Type: GrantFiled: May 13, 2005Date of Patent: November 13, 2012Assignee: FUJIFILM CorporationInventors: Hiroyuki Kawanishi, Yosuke Nishiura, Takako Nishiura, legal representative
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Patent number: 8304040Abstract: A polymer is swollen in a first tank. The swelling temperature is in the range of ?10 to 50° C. The mixture is cooled in a first cooling vessel to the range of ?100 to ?10° C., and thereafter heated in a heating device to the range of 0 to 57° C. The polymer is cellulose acylate in which a degree of substitution of the acyl group for hydroxyl group is at least 2.87. A film obtained from the cellulose acylate has a negative value of ?Re and a positive value of ?Rth, and |?Rth| is at least 10 nm. ?Re and ?Rth are respective difference of Re and Rth at the measurement thereof with use of wavelengths between 700 nm and 400 nm. The film is used adequately as a birefringence film, a protective film for a polarizing filter in a liquid crystal display.Type: GrantFiled: January 26, 2005Date of Patent: November 6, 2012Assignee: FUJIFILM CorporationInventor: Yasuyuki Sasada
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Patent number: 8246886Abstract: A method and system for aligning nanotubes within an extensible structure such as a yarn or non-woven sheet. The method includes providing an extensible structure having non-aligned nanotubes, adding a chemical mixture to the extensible structure so as to wet the extensible structure, and stretching the extensible structure so as to substantially align the nanotubes within the extensible structure. The system can include opposing rollers around which an extensible structure may be wrapped, mechanisms to rotate the rollers independently or away from one another as they rotate to stretch the extensible structure, and a reservoir from which a chemical mixture may be dispensed to wet the extensible structure to help in the stretching process.Type: GrantFiled: July 9, 2008Date of Patent: August 21, 2012Assignee: Nanocomp Technologies, Inc.Inventors: David S. Lashmore, Robert Braden, Anastasios John Hart, John Welch
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Patent number: 7998575Abstract: The invention relates to a continuous dry spinning process for preparing a fiber from a polymer solution having concentrations of polymer, salt, solvent and water. After the fiber is extruded and quenched, the fiber is placed in contact with a conditioning solution comprising concentrations of solvent, salt, and water. The conditioning solution acts upon the fiber to plasticize the fiber prior to being drawn. The conditioning solution has concentrations of solvent, salt, and water so that the fiber is plasticized to the extent necessary for drawing but does not plasticize the fiber to such an extent as to re-dissolve the fiber into a polymeric solution. A heat-treated fiber manufactured from this process has improved shrinkage and can be colored to darker shades.Type: GrantFiled: December 19, 2007Date of Patent: August 16, 2011Assignee: E.I. du Pont de Nemours and CompanyInventors: Mark H. Headinger, Edgar N. Rudisill, David W. Luckey
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Patent number: 7964127Abstract: A method for producing an optical film comprising the steps of: (i) melt casting a cellulose ester resin or a cycloolefin resin by extruding melt of the cellulose ester resin or the cycloolefin resin from a die onto a roll-shaped cooling drum; (ii) cooling and solidifying the extruded melt to form a film; (iii) stretching the film in a lateral direction of the film; and (iv) winding the film in a roll, wherein the cooling drum has plural regions divided predeterminedly in an axis direction of the cooling drum, a temperature of each region being independently controlled.Type: GrantFiled: August 26, 2010Date of Patent: June 21, 2011Assignee: Konica Minolta Opto, Inc.Inventor: Kenichi Kazama
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Patent number: 7914712Abstract: A cellulose acylate film characterized in that it has a shear rate dependency of melt viscosity of 0.1 to 2 and/or a temperature dependency of melt viscosity of 0.1 to 3. The cellulose acylate film is capable of suppressing generation of cutting wastage at the time of cutting.Type: GrantFiled: May 24, 2006Date of Patent: March 29, 2011Assignee: Fujifilm CorporationInventor: Kiyokazu Hashimoto
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Patent number: 7780889Abstract: The invention relates to a continuous dry spinning process for preparing a fiber from a polymer solution having concentrations of polymer, salt, solvent and water. After the fiber is extruded and quenched, the fiber is placed in contact with a conditioning solution comprising concentrations of solvent, salt, and water. The conditioning solution acts upon the fiber to plasticize the fiber prior to being drawn. The conditioning solution has concentrations of solvent, salt, and water so that the fiber is plasticized to the extent necessary for drawing but does not plasticize the fiber to such an extent as to re-dissolve the fiber into a polymeric solution. A heat-treated fiber manufactured from this process has improved shrinkage and can be colored to darker shades.Type: GrantFiled: December 19, 2007Date of Patent: August 24, 2010Assignee: E.I. du Pont de Nemours and CompanyInventors: Mark H. Headinger, Edgar N. Rudisill, David W. Luckey
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Patent number: 7771636Abstract: The invention relates to a continuous dry spinning process for preparing a fiber from a polymer solution having concentrations of polymer, salt, solvent and water. After the fiber is extruded and quenched, the fiber is placed in contact with a conditioning solution comprising concentrations of solvent, salt, and water. The conditioning solution acts upon the fiber to plasticize the fiber prior to being drawn. The conditioning solution has concentrations of solvent, salt, and water so that the fiber is plasticized to the extent necessary for drawing but does not plasticize the fiber to such an extent as to re-dissolve the fiber into a polymeric solution. A heat-treated fiber manufactured from this process has improved shrinkage and can be colored to darker shades.Type: GrantFiled: December 19, 2007Date of Patent: August 10, 2010Assignee: E. I. du Pont de Nemours and CompanyInventors: Mark H. Headinger, Edgar N. Rudisill, David W. Luckey
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Patent number: 7771637Abstract: The invention relates to a continuous dry spinning process for preparing a fiber from a polymer solution having concentrations of polymer, salt, solvent and water. After the fiber is extruded and quenched, the fiber is placed in contact with a conditioning solution comprising concentrations of solvent, salt, and water. The conditioning solution acts upon the fiber to plasticize the fiber prior to being drawn. The conditioning solution has concentrations of solvent, salt, and water so that the fiber is plasticized to the extent necessary for drawing but does not plasticize the fiber to such an extent as to re-dissolve the fiber into a polymeric solution. A heat-treated fiber manufactured from this process has improved shrinkage and can be colored to darker shades.Type: GrantFiled: December 19, 2007Date of Patent: August 10, 2010Assignee: E. I. du Pont de Nemours and CompanyInventors: Mark H. Headinger, Edgar N. Rudisill, David W. Luckey
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Patent number: 7771638Abstract: The invention relates to a continuous dry spinning process for preparing a fiber from a polymer solution having concentrations of polymer, salt, solvent and water. After the fiber is extruded and quenched, the fiber is placed in contact with a conditioning solution comprising concentrations of solvent, salt, and water. The conditioning solution acts upon the fiber to plasticize the fiber prior to being drawn. The conditioning solution has concentrations of solvent, salt, and water so that the fiber is plasticized to the extent necessary for drawing but does not plasticize the fiber to such an extent as to re-dissolve the fiber into a polymeric solution. A heat-treated fiber manufactured from this process has improved shrinkage and can be colored to darker shades.Type: GrantFiled: December 19, 2007Date of Patent: August 10, 2010Assignee: E. I. du Pont de Nemours and CompanyInventors: Mark H. Headinger, David W. Luckey, Edgar N. Rudisill
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Patent number: 7651743Abstract: A cellulose acylate film that has a crystallization index expressed by expression (A) as defined in the specification of from 0.70 to 1.02 and a modulus of elasticity in every arbitrary direction of an in-plane of the cellulose acylate film of from 3,800 MPa to 6,000 MPa; a manufacturing method of a cellulose acylate film comprising: casting a dope on a support; drying the dope on the support, so as to form a film; peeling the film from the support; and subjecting the film to a stretching treatment, wherein a crystallization index expressed by expression (A) of the film after peeling and before stretching is from 0.70 to 1.00; an optically compensatory sheet comprising the cellulose acylate film; and a polarizing plate and a liquid crystal display device using the optically compensatory sheet.Type: GrantFiled: June 2, 2006Date of Patent: January 26, 2010Assignee: Fujifilm CorporationInventors: Nobutaka Fukagawa, Mitsuo Yoshikane
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Patent number: 7354633Abstract: A retardation film containing a polyalcohol ester, a polycarboxylic acid ester, and a cellulose ester, wherein a total acylation degree of the cellulose ester is in the range of 2.4-2.8; and a Mw/Mn value of the cellulose ester is in the range of 1.4-3.0, provided that Mw represents a weight average molecular weight and Mn represent a number average molecular weight of the cellulose ester.Type: GrantFiled: November 18, 2005Date of Patent: April 8, 2008Assignee: Konica Minolta Opto, Inc.Inventors: Koichi Saito, Kunio Shimizu, Isamu Michihata
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Patent number: 7306832Abstract: A manufacturing method of a cellulose ester film satisfying the relationships, Nx>Ny>Nz, and 0.8?Rt/R0?3.5, the method comprising casting a cellulose ester dope containing a solvent of a good solvent and a poor solvent on a support to form a web; peeling the web from the support; transporting the peeled web (step D0); holding the edges in the transverse direction of the web (step A); stretching the resulting web in the transverse direction while applying a tension; reducing the tension in the transverse direction of the web; and drying the stretched web, wherein the residual solvent content of the web is 5 to 90% by weight at the beginning in the step A, and the residual poor solvent content in the residual solvent content of the web is from 15 to 95% by weight at the terminal point in the Step D0.Type: GrantFiled: October 14, 2004Date of Patent: December 11, 2007Assignee: Konica CorporationInventors: Koji Tasaka, Hiroki Umeda, Noriyasu Kuzuhara, Takatoshi Yajima
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Patent number: 7273917Abstract: A reaction product comprises a polyester-polycarbonate comprising a polyester unit and a polycarbonate unit, a polycarbonate polymer, and a transesterification catalyst. The reaction product has a haze of less than 1.7% as measured at a thickness of 3.2 mm according to ASTM D1003-00. A thermoplastic composition comprising the reaction product and articles formed from therefrom are disclosed. A method of forming the reaction product is also disclosed.Type: GrantFiled: May 20, 2005Date of Patent: September 25, 2007Assignee: General Electric CompanyInventor: Brian Mullen
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Patent number: 6235869Abstract: Synthetic absorbable medical devices made totally or in part from a random polymer comprising glycolide, lactide, trimethylene carbonate, and caprolactone are provided. The polymer can be fabricated into a monofilament which exhibits physical characteristics equivalent to or superior than gut sutures.Type: GrantFiled: October 9, 1999Date of Patent: May 22, 2001Assignee: United States Surgical CorporationInventors: Mark S. Roby, Lydmilla K. Kokish, Rooma M. Mehta, Jerry Y. Jonn
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Patent number: 5779736Abstract: The present invention discloses a process for producing a fibrillated cellulose acetate fiber comprising contacting cellulose acetate fiber with a strong base solution at conditions sufficient to remove greater than about 5% of bulk acetyl groups from said cellulose acetate fiber. Modified cellulose acetate staple fiber comprising an outer layer of regenerated cellulose in which at least about 5% of the acetyl groups are removed on an overall fiber basis are also disclosed. Paper products incorporating said fibers are also disclosed.Type: GrantFiled: January 19, 1995Date of Patent: July 14, 1998Assignee: Eastman Chemical CompanyInventors: Tim J. Frederick, Melvin G. Mitchell, Lee R. Partin, Alan K. Wilson, Richard D. Neal
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Patent number: 5374708Abstract: Polyimide filaments and polyimide films having great strength, high elastic modulus and high crystallinity and comprising a novel polyimide which can be melt-processed without impairing high crystallinity and which essentially consists of recurring structural units represented by the formula (I): ##STR1## more than 85 mol % the polyimide consists of recurring structural units of the formula (II): ##STR2## and from 0.5 to 15 mol % of the polyimide consists of recurring structural units represented by the formula (III), the formula (II) exclusive, the formula (IV) and/or the formula (V).Type: GrantFiled: August 8, 1991Date of Patent: December 20, 1994Assignee: Mitsui Toatsu Chemicals, IncorporatedInventors: Shoji Tamai, Masahiro Ohta, Akihiro Yamaguchi, Masumi Saruwatari
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Patent number: 5367042Abstract: Films containing polybenzazole polymer dissolved in a solvent can be mechanically stretched to provide biaxial orientation. The resulting dope film can be coagulated. The polymer film has improved properties in the direction in which stretching occurs.Type: GrantFiled: August 27, 1992Date of Patent: November 22, 1994Assignee: The Dow Chemical CompanyInventors: Peter E. Pierini, Robbert M. Vermeulen, Susan E. Dollinger
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Patent number: 5269996Abstract: A method for producing ultra fine denier cellulose acetate fibers that entails spinning a spinning solution containing adequately high amounts of cellulose acetate in acetone wherein the cellulose acetate has a falling ball viscosity of 15 to 70 seconds wherein the spinning is conducted through spinnerettes having holes that have a diameter of less than 36 microns followed by drying at a temperature of about 50.degree. to 80.degree. C. at a draw ratio of 0.9 to 1.7.Type: GrantFiled: September 14, 1992Date of Patent: December 14, 1993Assignee: Eastman Kodak CompanyInventors: Benedict M. Lee, Charles S. Winebarger
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Patent number: 5252396Abstract: The present invention relates to a shaped material consisting of a layer having open microvoids (hereinafter referred to as light-scattering layer) and a layer having a hue different from that of the light-scattering layer (hereinafter referred to as color-developing layer), the light-scattering layer constituting at least part of the outer surface of the shaped material and the color-developing layer constituting the rest of the shaped material, which shaped material changes its color reversibly depending upon its moist or dry condition, as well as to a process for producing said shaped material.Type: GrantFiled: December 19, 1991Date of Patent: October 12, 1993Assignee: Mitsubishi Rayon Co., Ltd.Inventors: Yuichi Fukui, Hajime Itoh, Shigeki Hagura, Itsumi Muraoka
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Patent number: 4975315Abstract: A metallizable, sealable, biaxially stretch-oriented multi-ply film comprises a base layer essentially of polypropylene, a first polyolefinic facing layer and a second polyolefinic facing layer. All of the layers contain a neutralizing agent and a stabilizer against thermal degradation. The neutralizing agent is a calcium carbonate having an absolute particle size of less than 10.0 .mu.m, a mean particle size of less than 0.1 .mu.m, a specific surface area of more than 40 m.sup.2 /g and a whiteness of more than 90% and, the stabilizer comprises a phenolic stabilizer having a molecular weight of more than 1,000 g/mol. One polyolefinic facing layer contains an anti-blocking agent. In addition, a process for producing the metallizable multi-ply film is described, and its use as a packaging material is indicated.Type: GrantFiled: March 15, 1988Date of Patent: December 4, 1990Assignee: Hoechst AktiengesellschaftInventors: Lothar Bothe, Gunter Schloegl, Guenther Crass, Thomas Wilhelm
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Patent number: 4328838Abstract: Thick and tough cellophane for casings is provided wherein viscose is passed through an aqueous coagulation solution containing 15 to 30 weight percent of middle or higher alcohol and/or polyhydric alcohol, the coagulated viscose film being subjected to tension in its horizontal direction in the process of coagulation during passage in the coagulation solution. Thicker and tougher casing cellophane is provided wherein the coagulated viscose film exiting from the coagulation solution is further passed through a second aqueous coagulation solution containing inorganic acid and metallic salt thereof, the coagulated viscose film being subjected to tension in its horizontal direction during passage in the coagulation solution.Type: GrantFiled: May 30, 1979Date of Patent: May 11, 1982Assignee: Kanegafuchi Kagaku Kogyo Kabushiki KaishaInventors: Kosaku Asada, Hiroo Maeno
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Patent number: 4276173Abstract: An improved cellulose acetate semi-permeable hollow fiber suitable for use in artificial kidneys and a process for making same.Type: GrantFiled: December 21, 1978Date of Patent: June 30, 1981Assignee: Cordis Dow Corp.Inventors: Michael J. Kell, Robert D. Mahoney
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Patent number: 4246221Abstract: A solution containing cellulose dissolved in a tertiary amine N-oxide solvent containing a nonsolvent for cellulose such as water is shaped by extrusion or other shaping process to form a shaped cellulose fiber, rod, plate, tubing or film. The extruded shaped article is stretched in air while still a solution to impart improved physical properties thereto and the cellulose is precipitated from the shaped solution to set the properties without additional drawing. The solution may be prepared by dissolving cellulose in the tertiary amine N-oxide solvent in the barrel of an extrusion apparatus, extruding the solution, orienting by stretching the resulting product in air while still a solution and then precipitating the cellulose from the shaped article before significant degradation of the cellulose. The cellulose and tertiary amine N-oxide may be ground to substantially the same particle size before charging the extruder barrel.Type: GrantFiled: March 2, 1979Date of Patent: January 20, 1981Assignee: Akzona IncorporatedInventor: Clarence C. McCorsley, III