Abstract: A method for annealing a structure formed by electrodeposition is provided, the method comprising providing the electrodeposition structure, the electrodeposition structure comprising an electroformed mold, the electroformed mold having a nominal thickness between and including 0.5 mm to 8.0 mm and having a melting temperature; heating the electrodeposition structure to a temperature between ambient temperature and the melting temperature of the electrodeposition structure; isostatically pressurizing the electrodeposition structure to a pressure above ambient pressure; cooling the electrodeposition structure to ambient temperature; and depressurizing the electrodeposition structure to ambient pressure.

Abstract: The invention provides new methods for recycling thermoset materials such as natural rubbers, synthetic rubbers, silicone rubbers, and other elastomers and cross-linked polymers (e.g., isoprene rubbers; butyl rubbers; ethylene-propylene-diene-rubbers, “EPDM”; nitrile, or acrylonitrile butadiene rubbers, “NBR”; styrene-butadiene rubbers, “SBR”; hard rubbers such as EBONITE®; mixtures of vulcanized rubbers from discarded tires). The invention is based on the discovery that by combining powdered or particulate thermoset materials with lubricants such as aromatic or paraffinic rubber processing oils or volatile solvents, the thermoset materials can be recycled under moderate temperature and pressure conditions to rapidly produce materials having physical properties comparable to those of virgin thermoset materials. The resulting materials can, for example, be extruded or compaction molded into new shapes such as panels.

Abstract: In a method of making an electrically conductive electrode member, a compound material, containing a binder made of polymer plastic and 80 weight % of a powdery electrically conductive material as filler, is introduced into a plasticizing screw of an injection molding machine for transforming the compound material to a plasticized material and discharging the plasticized material via a nozzle having a length of less than 15 mm for subsequent injection molding. The injection molding machine is constructed throughout a material flow passage from a point of introduction of the compound material to the injection mold to have only tapered portions which narrow a flow cross section by not more than 10:1.

Abstract: The present invention relates to the prevention and decrease of osteolysis produced by wear of the ultrahigh molecular weight polyethylene (UHMWPE). Methods are disclosed for the isolation of wear particles, preparation of implants exhibiting decreased wear in comparison to conventional UHMWPE and preparation of implants that cause decreased biological response in comparison to conventional UHMWPE. The implants created by these methods are also included in the present invention.

Abstract: A method of tempering composite fiber panels eliminates a need for a bake oven during the tempering step. Both the front and back surfaces of the panels are sprayed with a tempering oil including a mixture of a drying oil and a dryer or catalyst. The drying oil may include a linseed oil refined to minimize low molecular weight and a conjugated oil. Sometimes the drying oil is further mixed with either a conjugated oil, a catalyst, a low molecular weight isocyanate resin (Imw-MDI) or another additive. The sprayed panels are stacked preferably in face-to-face contact inside a curing chamber heated only by the residual heat in the hot panels. A number of additives to the tempering oil are considered. A number of different forms of commercial panels are considered, such as: hardboard, oriented strandboard, fiber board siding, wafer board, medium density fiber board, particle board, and other similar boards.

Abstract: A method of forming a crystalline phase material includes, a) providing a stress inducing material within or operatively adjacent a crystalline material of a first crystalline phase; and b) annealing the crystalline material of the first crystalline phase under conditions effective to transform it to a second crystalline phase. The stress inducing material preferably induces compressive stress within the first crystalline phase during the anneal to the second crystalline phase to lower the required activation energy to produce a more dense second crystalline phase. Example compressive stress inducing layers include SiO2 and Si3N4, while example stress inducing materials for providing into layers are Ge, W and Co. Where the compressive stress inducing material is provided on the same side of a wafer over which the crystalline phase material is provided, it is provided to have a thermal coefficient of expansion which is less than the first phase crystalline material.

Abstract: A method for producing open-ended biaxially oriented containers includes forming a biaxially oriented intermediate by blow forming, without plug assist, a sheet of unoriented thermoplastic material into a forming tube to a depth of draw sufficient for full orientation of the side walls. The blow formed intermediate is placed on a male form a predetermined size, shape, and texture. The intermediate is heated above the orientation temperature of the thermoplastic material to heat shrink the intermediate onto the surface of the male form. The formed container is then removed from the male form.

Abstract: A method of producing a microporous membrane comprising the steps of: extruding a polymer at a temperature of from (polymer melting point +10° C.) to (polymer melting point +100° C.); drawing the extruded polymer at a rate of 5˜120 m/min in 10˜150° C. to obtain a polymer film; annealing the polymer film at a temperature of from (polymer melting point −100° C.) to (polymer melting point −5° C.) for 10 seconds to 1 hour; irradiating both surfaces of the annealed polymer film with an ion-particle amount of 102˜1020 ion/cm2 energized at 10−2˜107 KeV, at an irradiating distance of 5˜100 cm under a vacuum of 10−2˜10−[torr; cold stretching the irradiated polymer film at a temperature of from −20° C. to (polymer melting point −40° C.); hot stretching the cold stretched polymer film at a temperature of from (polymer melting point −40° C.) to (polymer melting point −5° C.

Abstract: A method of making a polyurea-polyurethane composite structure that is substantially free from emission of volatile organic compounds is disclosed. The composite structure produced according to the method of the subject invention has a flexural modulus of at least 200,000 lb/in2. The composite structure includes first and second layers. A mold substrate is provided and a first-layer polyisocyanate component and a first-layer resin component are reacted and sprayed onto the mold substrate to form the first-layer. The first-layer polyisocyanate component includes an aliphatic polyisocyanate, and the first-layer resin component includes a polyamine thereby forming a polyurea show surface having a Shore D hardness of at least 65. After application of the first-layer, a second-layer polyisocyanate component and a second-layer resin component are reacted and sprayed behind the first-layer to form the second-layer of the composite structure.

Abstract: A process for producing a lens comprising polymerizing bis(&bgr;-epithiopropyl)ether to form a lens.

Abstract: A resin molded article and a production method thereof, including the processes of heat-molding a molding material containing a biodegradable resin and a reinforcing fiber or a biodegradable resin, a reinforcing fiber after controlling a water content thereof, or non-controlling. The resin molded article according to the present invention has sufficient heat resistance so that they are not deformed even after being temporarily left in a high temperature environment such as that in an automobile in the daytime in summer seasons and being heated to a high temperature, without deteriorating the properties thereof as members for recording materials, and therefore cause no environmental problems when left in nature since they can be finally decomposed by microorganisms.

Abstract: A method for improving adhesion between two adjacent layers of a laminate membrane includes annealing the laminate membrane at a temperature between an alpha-transition temperature and a beta-transition temperature of at least one polymeric component of at least one of two adjacent layers for a time sufficient for the at least one polymeric component of at least one of the adjacent layers to partially diffuse into the other adjacent layer. A sealed, inflated bladder of the invention prepared from the laminate membrane can experience high strains without layer separation or peeling of the laminate layers, even at a seam.

Abstract: The invention provides a highly heat-stable polyester container and a method of manufacturing the polyester container, which can be treated by retort sterilization at a high temperature after filling food, a drink or the like in the container and sealing off it, and which has superior heat stability enough to prevent deformation and whitening due to heat shrinkage in a bottom portion of the container even when treated by the retort sterilization. In the polyester container, a barrel portion and a bottom portion of the container are heat-set, and at least the bottom portion of the container has an endothermic peak on a DSC curve in the range of not lower than about 150° C. but not higher than a melting start point.

Abstract: In the production of spiral-shaped heating elements, a device winds an oblong base material onto a mandrel while forming a spiral with the base material and equips the ends of the spiral with contacts for electrical connection. The device includes a feeding device for supplying the mandrel, onto whose casing surface the base material is wound in a spiral shape, with the oblong base material. In order to carry out a method for the production of a spiral-shaped heating element made of material containing carbon fibers, the method is as follows: utilize a base material that comprises carbon fibers which have been embedded into IBM a thermoplastic embedding compound, heat the base material to a temperature at which the embedding compound softens, wind the softened base material onto the mandrel while forming the spiral, and set the spiral shape by removing the embedding compound.

Abstract: The present invention can provide particles for electro-rheological fluid for providing a high electro-rheological effect over a wide temperature range at low electric power consumption, and having high strength and excellent durability, not being susceptible to break-up due to the load of stress. Particles for an electro-rheological fluid of the present invention comprise spherical carbonaceous particles, obtained substantially from a solvent and a condensation product of a methylene type bond of aromatic sulfonic acid or a salt thereof.

Abstract: A plastic container for retaining a commodity during a high temperature pasteurization or retort process. The container includes a finish defining an aperture for receiving the commodity, a body portion generally extending downward from the finish portion, and a base portion generally extending inward from the body portion and closing off the bottom of the container. The body portion itself includes a sidewall having a crystallinity of greater than 30% and a shoulder portion flaring outward, from a generally transverse plane defined by the mouth of the container, at an angle of about 15° or less.

Abstract: Coagulation spinning produces structures such as fibers, ribbons, and yarns of carbon nanotubes. Stabilization, orientation, and shaping of spun materials are achieved by post-spinning processes. Advantages include the elimination of core-sheath effects due to carbonaceous contaminants, increasing mechanical properties, and eliminating dimensional instabilities in liquid electrolytes that previously prohibited the application of these spun materials in electrochemical devices. These advances enable the application of coagulation-spun carbon nanotube fibers, ribbons, and yarns in actuators, supercapacitors, and in devices for electrical energy harvesting.

Abstract: To provide a method for producing a molded crystalline resin article which enables a higher crystallization degree and to mass-produce the molded crystalline resin articles. The method comprises molding a molded resin article from a thermoplastic resin containing a crystalline resin followed by performing a heating process to obtain a molded crystalline resin article having a surface layer whose crystallization index is 0.9 or higher when determined by IR spectrometry. It is preferable that the temperature of the heating process is within the range of 20° C. lower than the crystallization temperature of the molded resin article to 30° C. higher than the crystalline temperature, and that the crystalline resin is a polypropylene resin.

Abstract: Beads of melt-fabricable fluoropolymer dispersion particles are produced by a solvent-aided pelletization process using fluorinated solvent containing ether oxygen.

Abstract: A process of making polytrimethylene terephthalate staple fibers, comprising (a) providing polytrimethylene terephthalate, (b) melt spinning the melted polytrimethylene terephthalate at a temperature of 245-285° C. into filaments, (c) quenching the filaments, (d) drawing the quenched filaments, (e) crimping the drawn filaments using a mechanical crimper at a crimp level of 8-30 crimps per inch (3-12 crimps/cm), (f) relaxing the crimped filaments at a temperature of 50-120° C., and (g) cutting the relaxed filaments into staple fibers having a length of about 0.2-6 inches (about 0.5-about 15 cm), and polytrimethylene terephthalate staple fibers, yarns and fabrics. Further, a process of optimizing the crimp take-up of a polytrimethylene terephthalate staple fiber comprising determining the relationship between denier and crimp take-up and manufacturing staple fibers having a denier selected based upon that determination.

Abstract: The present invention provides a polymer composition comprising a fluorochemical oligomeric compound and a thermoplastic or thermoset polymer. The polymer composition is useful in preparing shaped articles such as fibers and films which have desirable oil- and water repellency properties.

Abstract: A radially expandable device having a body constructed of a generally inelastic, expanded fluoropolymer material is described. The body is deployable upon application of a radial expansion force from a reduced diameter, collapsed configuration to an expanded configuration having a pre-defined and fixed increased diameter. The body has a singular, unitary construction of generally homogenous material that is characterized by a seamless construction of expanded fluoropolymer material, such as expanded polytetrafluoroethylene (ePTFE), and is preferably constructed through an extrusion and expansion process. The body is further characterized by a microstructure of nodes interconnected by fibrils in which substantially all the nodes of the body are oriented generally perpendicularly to the longitudinal axis of the body.

Abstract: A plastic optical element producing method produces a plastic optical element by an ejection molding, and includes the step of cooling an optical surface of the plastic optical element with priority in a state where a temperature of the plastic optical element is within a predetermined temperature range which is less than or equal to a glass transition temperature of the resin material.

Abstract: A process for production of polyimide molded bodies which comprises a step in which a polyimide resin powder obtained by polymerization and imidation of p-phenylenediamine with 3,3,4,4′-biphenyltetracarboxylic acid, its ester or its dianhydride and 2,3,3′, 4′-biphenyltetracarboxylic acid, its ester or its dianhydride is molded at a pressure of approximately 800-5,000 kgf/cm2, a step in which the pressurized body is subjected to calcination at about 450-550° C. under low pressure, a step in which the calcined molded body is vacuum encapsulated into a metal capsule, and a step in which the encapsulated molded body is isotropically subjected to hot compression at approximately 460-550° C. in an inert gas atmosphere such as argon. The polyimide molded bodies obtained thereby have a density in the range of 1.44-1.38 g/cm3.

Abstract: A memorial product generated from the cremation remains of a deceased human or animal whereby a predetermined amount of bone ash is combined with a predetermined amount of a glass forming additive. In addition, a glass modifier may be added to enchance the durability of the final solid product. A flux may also be added to reduce the melting temperature of the mixture. These additives are combined with bone ash and milled to a desired particulate size to form a powder mixture. The mixture is heated to a melting temperature for a resident time to form a glass melt which is then poured into a mold. The cast or molded form is annealed for a resident time at a predetermined temperature to avoid stress fracture or crystalization from cooling too quickly or slowly.

Abstract: A method of producing three dimensional ordered arrays of particles. The method may be used for the preparation of nanocomposite materials with highly periodic structures. More particularly the invention provides a method of producing three dimensional arrays based on applying a controlled oscillatory motion to settling dispersions of colloid particles. The controlled oscillatory motion is characterized by G=A&ohgr;2/g, wherein g is the gravitational constant, A is the displacement and &ohgr; is angular frequency. G is maintained in the desired range by varying values of A within an effective range of displacements and &ugr; within an effective range of frequencies.

Abstract: Glass or glass ceramic plates with elevated thermal resistance and process for their production. After cooling, the glass or glass ceramic plates are subjected to zone annealing, whereby the plates are divided into two zones in which annealing is done at respectively different temperatures, and whereby the zones with the elevated temperature correspond, during annealing, to the sub-areas of the finished glass or glass ceramic plates in which compression stress builds up after uneven heating corresponding to the respective specific application of the glass or glass ceramic plates. The glass or glass ceramic plates that are obtained are thus characterized in that they are divided into two sub-areas, whereby one sub-area exhibits structural compression and the other sub-area exhibits compression stress. Glass or glass ceramic plates that are resistant to breakage that is caused by uneven heating result.

Abstract: A polyimide for optical communications, which is expressed by the formula (1) where R1 and R2 are independently selected from the group consisting of CF3, CCl3, unsubstituted aromatic ring group and halogenerated aromatic ring group; R3 and R4 are independently selected from the group consisting of Cl, F, I, Br, CF3, CCl3, unsubstituted aromatic ring group and halogenated aromatic ring group; and n is an integer from 1 to 39. The polyimides have a superior heat resistance, and can avoid the increase in optical absorption loss due to a refractive index increase and deterioration of adhesive and coating properties due to weak surface tension of a polyimide film. In addition, use of the polyimides as a material for a core layer of optical waveguides can expand the selection range of material for the cladding layer of the optical waveguide.

Abstract: Orthopaedic wires, cables, and methods of making them are based on the discovery that, in clinical orthopaedic applications, material toughness and fatigue strength are as important or more important than ultimate tensile strength. The wires and cables of the invention have a tensile strength lower than 280 ksi, but higher than 175 ksi. The presently preferred wires and cables have a tensile strength of 210-240 ksi. The fatigue strength of the wires and cables of the invention is between six and ten times that of other high strength cables used in orthopaedic applications. One method of making the wires and cables includes annealing high tensile strength wire or cable to reduce its tensile strength and thereby increase its fatigue strength. Another method is to cold work fully annealed wire or cable to the extent of decreasing its cross section by approximately 18%.

Abstract: Methods of thermal annealing of plastic pieces immediately after hot melt forming are disclosed to accelerate the time required to achieve dimensional stability. The present methods include the essential steps of: (A) forming molten plastic into molded plastic pieces and rapidly cooling to below the melting point of the plastic in a mold to form shaped cooled plastic pieces; (B) immediately thereafter, heating the plastic pieces to a temperature of about 150° to 170° F. (65.5° to 80° C.) to form heated plastic pieces; and, thereafter, (C) cooling the heated plastic pieces to room temperature to form thermally annealed plastic pieces. Tn its product aspect, the present invention resides in physically aged thermoplastic pieces having reduced rates of age shrinkage.

Abstract: A ceramic composition (sample) includes CaBi4Ti4O15 or another compound having a layered perovskite crystal structures and exhibiting ferroelectricity at ordinary temperature. The ceramic composition (sample) is then heated to a temperature higher than the melting point of the ceramic composition to make the ceramic composition molten or semi-molten. The ceramic composition is then annealed and solidified to yield a grain oriented ceramic (porcelain). This process can produce grain oriented ceramics from ceramic compositions mainly containing a compound having a layered perovskite crystal structure, and can improve electromechanical coefficients of piezoelectric ceramics containing a compound having a layered perovskite crystal structure.

Abstract: A method for making bioabsorbable block copolymer includes extruding a mixture of first polymeric component particles with second polymeric component particles under conditions sufficient to cause transesterification. The resulting block copolymer filaments can be used to form surgical sutures.

Abstract: A method for fabricating adherent, patterned carbon nanotube films is provided. According to the invention, a substrate is patterned with a carbide-forming material, a carbon-dissolving material, or a low melting point metal. Carbon nanotubes are then deposited onto the patterned substrate, but have relatively poor adhesion to either the substrate material or the patterned material. The substrate is then annealed, typically in vacuum, at a temperature dependent on the particular patterning material, e.g., a temperature at which carbide formation occurs, at which carbon dissolution occurs, or at which the low melting point metal melts. The annealing thereby provides an adherent nanotube film over the patterned areas, while the nanotubes deposited onto the non-patterned areas are easily removed, e.g., by blowing, rubbing, brushing and/or ultrasonication in a solvent such as methanol.

Abstract: A hydrostatic compression method for producing a fancy log with a decorative and complicated external appearance from a primary wood. In the method, a primary wood having a water content adjusted in the range of 10-80 wt % is brought into a softened state, then the softened wood is compressed with hydrostatic pressure by means of liquid as pressurizing medium. Next, the compressed wood is treated with a fixation means to fix the compressed state. The fixation means can be a shaping jig, a mold, heating in a particular temperature range conducted while constraining the volume relation of compressed wood, cooling down below the softening point of the wood while under pressure, compact-packing together with hard particles into a vessel followed by heating, or a primary wood is chemically treated to form a localized wood-plastics composite before applying hydrostatic compression.

Abstract: The invention provides an injection-molded product of polyglycolic acid obtainable by molding a thermoplastic resin material at an injection temperature ranging from the melting point, Tm of the polymer to 255° C., wherein the thermoplastic resin material comprises polyglycolic acid having a repeating unit represented by the following formula (1): and the following physical properties: (a) the melt viscosity, &eegr;* [as measured at a temperature of (the melting point, Tm of the polymer+20° C.) and a shear rate of 1,000/sec] being 30-10,000 Pa·s; (b) the melting point, Tm being at least 150° C.; (c) the melt enthalpy, &Dgr;Hm being at least 20 J/g; and (d) the density being at least 1.50 g/cm3 as measured in an unoriented, crystallized form, and a production process thereof.

Abstract: The present invention provides a novel fluorochemical oligomer, and polymer composition comprising the fluorochemical oligomeric compound and a thermoplastic or thermoset polymer. The polymer composition is useful in preparing shaped articles such as fibers and films which have desirable oil- and water repellency properties.

Abstract: A method of heat-setting garments by boarding the garment and subjecting it to preselected temperatures that are different for different parts of the garment and an apparatus for carrying out this method are provided.

Abstract: A method of manufacturing a balloon portion for a balloon catheter for radially expanding a vessel in the body of a mammal, which catheter comprises a tube portion with a passage therethrough and a hollow expandable balloon portion defined by a fluid impervious wall and secured to the tube portion, which balloon portion can be inflated and deflated by means of a fluid passed through the passage, such that:a. the wall of the balloon portion is formed from a flexible substantially fluid impervious material having re-inforcing fibers formed integrally with the wall material; andb. the balloon portion is preformed to the desired radial diameter at its inflated state having smaller diameter end portions and a wider diameter portion intermediate the said ends and has a substantially uniform wall thickness.

Abstract: A method for forming a socket on a pipe of biaxially oriented polyvinyl chloride including: placing a support in an end section of the pipe, heating the pipe in the region of the end section; deforming the pipe to produce a socket in the region of the heated end section, the heated end section being supported internally while the socket is being formed; cooling the pipe in the region of the end section, the end section being supported internally during the cooling operation; and removing the support from the pipe. For the purpose of heating the internally supported end section of the pipe, the end section is first heated until the end section has reached, substantially homogeneously, the glass transition temperature of polyvinyl chloride and is then further heated until the end section has reached, substantially homogeneously, a temperature near, preferably just above, the orientation temperature of polyvinyl chloride.

Abstract: A debonding layer is formed on fibers such as silicon carbide fibers by fing a thin film of a metal such as nickel or iron on the silicon carbide fibers and then annealing at a temperature of about 350-550.degree. C. to form a debond layer of a metal silicide and carbon. These fibers having the debond coating can be added to composite forming materials and the mixture treated to form a consolidated composite. A one heating-step method to form a consolidated composite involves inserting the silicon carbide fibers with just the initial metal film coating into the composite forming materials and then heating the mixture to form the debond coating in situ on the fibers and to form the consolidated composite. Preferred heating techniques include high temperature annealing, hot-pressing, or hot isostatic pressing (HIP).

Abstract: In a method of producing hollow fiber membranes, wherein a molten polymer charged with a gas under pressure is provided in an extrusion apparatus, the polymer melt including the gas under pressure is extruded from the extrusion apparatus through a hollow fiber-forming extrusion nozzle with a predetermined pressure drop which provides for a concurrent expansion of the gas contained in the polymer melt thereby forming a porous hollow fiber membrane.

Abstract: A process comprising the following steps: (a) maintaining the process in an essentially oxygen-free state; (b) introducing a first polymer directly from the polymerization reactor in which it was prepared, in molten form, into a mixer/compounder; (c) reducing any higher pressure accompanying the first polymer from the polymerization reactor to the mixer/compounder to a pressure in the range of about 0 to about 5 barg; (d) adding additives selected from the group consisting of antioxidants, second polymers, other polymer enhancing additives, and mixtures thereof to the mixer/compounder, and mixing same with the molten first polymer; (e) passing the molten mixture from step (d) through one or more screens, each having a maximum opening size of about 25 microns; (f) pelletizing the mixture from step (e); (g) introducing the pellets into a spraying chamber, the interior of said chamber being operated in a static condition; (h) spraying the pellets in the chamber with a crosslinking formulation including an organi

Abstract: Films, made of polyethylenes, and articles made therefrom exhibit, for a given density, improved oxygen transmission. The polyethylenes are produced in a metallocene-catalyzed production process. The films may be made by a cast film process, and may be made under conditions that raise the birefringence and the oxygen transmission rate of the film, such as increasing strain rate decreasing melt temperature, increasing quench rates, or may be post-extrusion treated, for instance annealed or cold drawn. Combinations of both extrusion techniques and post-extrusion techniques may also be used. Polyethylenes utilized for making such films typically have a Composition Distribution Breadth Index above 50%, a M.sub.w /M.sub.n below 3, and a M.sub.z /M.sub.w below 2. The permeability of the films so made will be 50% or more above the permeability of films based on similar resins based on previously used film formation techniques.

Abstract: In order to produce tubular moldings of high-temperature superconducting material based on oxides of bismuth, calcium, strontium, copper and optionally lead, a homogeneous melt of the oxide mixture in a predefined stoichiometry having temperatures from 900 to 1300.degree. C. is made to flow into a casting zone. The casting zone, as a function of its internal diameter, rotates at from 200 to 1500 rpm about its axis which is inclined by at least 15.degree. with respect to the horizontal. The solidified molding is taken from the casting zone and annealed for from 4 to 150 hours at from 700 to 900.degree. C. in an oxygen-containing atmosphere.

Abstract: A large, monolithic sapphire structure for use in mid-IR military applications, such as, for example, a window or screen for radar detection equipment. The structure is made by bonding together two or more smaller sapphire panes by a method including the steps of coating a surface of each of the panes with a magnesia vapor and contacting the magnesia-coated surfaces with each other in the presence of a hydrogen-containing gas at a temperature (e.g., about 1500.degree. C. and 2000.degree. C.) and for a time period (e.g., about 45 minutes to about ten hours) sufficient to form a continuous magnesia-alumina spinel interlayer bond between the panes.

Abstract: A method of winding a polymer film web around a cylindrical core, where the core is heated by blowing hot-air against the core prior to winding the polymer film web, and the polymer film web is wound around the heated core while blowing hot-air against the polymer film web. In another embodiment of the winding method, the polymer film is wound while knurled along both edge parts in the width direction of the film to form knurls so as to gradually decrease in the thickness thereof from one end of the film that contacts with the core toward the other end of the film. Furthermore, a heat treating method for annealing a film roll and a heat treating apparatus therefor are disclosed, which method comprises the steps of surrounding the film roll with heat insulating panels and blowing hot-air against the film roll in the direction along the core axis while rotating the core intermittently or continuously at a rotary speed of from 0.04 to 4 revolutions per hour.

Abstract: The invention relates to a process for preparing a microporous membrane from an unsulfonated poly(phenylene sulfide) polymer by forming a mixture of an unsulfonated poly(phenylene sulfide) polymer, an amorphous polymer, and optionally a plasticizer, heating the resulting mixture, extruding or optionally casting the mixture into a membrane, controlled cooling (quenching) or coagulating the membrane, and leaching the membrane, while optionally drawing the membrane before, during, and/or after leaching.

Abstract: Process for producing a steam-sterilizable porous polyolefin membrane with a porosity of at least 20% and a shrinkage of 4% at most in every direction in the plane of the membrane in steam sterilization by subjecting a porous stretched film to a shrink treatment at a temperature equalling at least the sterilization temperature, but below the melting point of the polyolefin, in which treatment the permitted shrinkage is at least 95% of the critical shrink factor of the film in every direction in the plane of the film and a membrane of polyethylene with an intrinsic viscosity of at least 5 dl/g, steam-sterilizable at 134.degree. C.

Abstract: A poly(ethyleneoxy) block copolymer including a hydrophobic block segment useful in making a porous polymer article with improved surface hydrophilicity. Also disclosed is a method of making such a polymer article.

Abstract: A process of making a biocampatible porous hollow fiber that is made of polyolefine material and is coated with a biocompatible carbon material is disclosed. The biocompatible hollow fiber produced can be used as exchange material, diaphragms and/or semipermeable membranes within devices which will contact blood or plasma outside of the living body. The coated fiber is produced by introducing a preformed porous hollow fiber into an atmosphere of gaseous monomer vinylidene chloride and subsequent induction, e.g. by gamma radiation, of a graft-polymerization reaction to form an uniform polyvinylidene chloride layer. The ultimate coating is formed after a dehydrochlorination reaction in which hydrogen chloride is removed from the layer. The dechlorination reaction is typically performed by treating the fiber with hot concentrated aqueous ammonia solution. The reaction can be continued to reduce the chlorine content of the coating to less than 6% of its original value.