Abstract: A process of producing carbon fibers, which comprises oxidizing polyacrylonitrile filaments having a tensile strength at 240.degree. C. of 0.3 g/d or higher and a tensile modulus at 240.degree. C. of 2.0 g/d or higher in an oxidizing atmosphere under a high tension of 0.2 g/d or higher, and carbonizing the oxidized filaments under a high tension.

Abstract: A process for producing almost perfect graphite films and fibers at lower graphization temperatures wherein a film or fiber of a polymer selected from a defined group is subjected to a preliminary heat treatment at a temperature of 400.degree. to 700.degree. C., under tension, in vacuo or in an inert gas, and then heat treating the film or fiber at a temperature of at least 1600.degree. C. in vacuo or in an inert gas, to graphitize the film or fiber. The process can be modified to produce graphite films having excellent electric conductivity and mechanical properties, by heat treating a polymer selected from a second defined group at a temperature of at least 1800.degree. C. in vacuo or in an inert gas, impregnating the film with a binder component, and then heat treating the impregnated film at a temperature of not more than 1400.degree. C.

Abstract: A process for producing hollow structures of carbon material having desired shape and properties of carbon by obtaining a carbon paste composition, molding portions of the hollow structure by a method selected from the group consisting of an injection molding method, an extrusion molding method, a casting method or a fluidizing method, bonding the molded portions together using a paste composition, solidifying the bonded portion by precarbonizing, the hollow structures thus provided, and then calcining in an inert gas atmosphere as required. Hollow structures of carbon materials having a rigid bond, excellent impermeability, and complicated shape can be readily accurately and inexpensively produced without working after calcining.

Abstract: Ceramic alloys or solid solutions are formed by dispersing a powdery metal alloy or intimate mixture of two alloying metals in a precarbonaceous polymer such as polyacrylonitrile, forming the mixture into a molded article such as fibers, and heating the molded articles at a temperature and in a pyrolyzation atmosphere sufficient to carbonize the polymer and cause reaction of the metals with carbon and/or the pyrolyzation gas.

Abstract: A novel isotropically reinforced microcomposite is described. An entirely fluid-phase method has been devised for producing the net-shape filamentary structures. The process depends for its success on the ability to generate in situ, within a shaped mold, a three-dimensional random weave of carbon filaments by catalytic decomposition of a hydrocarbon feed. Almost any desired filament filler matrix combination can be produced by utilizing chemical vapor deposition to modify the surface and bulk properties of the filamentary structure. Infiltration of filler matrix materials can be achieved by adaptation of existing materials technologies.

Abstract: A pre-formed (e.g. injection moulded) container body of flexible resilient plastics material is subjected to a subsequent cold-forming operation so that it is permanently deformed into a required configuration. For example, a desired container mouth configuration may be produced or handle-retaining recesses may be formed.

Abstract: A container is provided in the form of a cup-like container body with a round mouth closed by a lid which becomes removably replaceable upon tearing away of a circumferentially extending tear strip which initially surrounds the mouth rim of the container body as a radially outer, integral part of the lid flange. As the lid is differential pressure-thermoformed, its radially outer region is formed into a generally inverted U-shaped structure which near the juncture of the base and radially outer leg of the inverted U, is provided, within the channel, with an inverted V-shaped notch of substantially diminished wall thickness to provide a line of weakness which preferably extends nearly fully around the circumference of the lid, but for at an angularly short tear-starting site.

Abstract: In a process for producing hollow bodies of oriented thermoplastic material, a hollow blank having a bottom portion and a substantially cylindrical wall portion with an opening at its end remote from its bottom portion is subjected to pre-expansion in the region of the opening and then thermofixing in a subsequent treatment step. The thermofixing operation may be preceded by a mechanical expansion operation for orienting the plastic material forming the wall portion of the blank.

Abstract: A process for producing a carbon product having coarse and dense portions, the process including producing an integral porous carbon having high strength and uniform porosity distribution with dense structure carbon moldings. The carbon moldings are produced by calcining in an inert gas atmosphere a composite of (a) a green molding, a precarbonized material or a carbide and (b) chlorinated vinyl chloride resin particles, the chlorinated vinyl chloride resin producing, when carbonized in an inert gas atmosphere, a coarse structure. Dense carbon is formed by carbonizing the green molding, precarbonized material or carbide. Thus, the carbon product has coarse and dense portions.

Abstract: An improved process for producing hard carbonaceous sheets, which comprises uniformly dispersing as a viscous binder in fine carbon powder a mixture of relatively readily polymerizable thermosetting resins such as monomers, prepolymers or low polymers exhibiting high residual carbon yield after calcining; applying mechanical energy to the resultant mixture to induce mechanochemical phenomenon to produce molding paste composition in which said binder is uniformly rigidly bonded physicochemically to the surfaces of the primary particles of the fine powder, molding the composition by a fluid rolling method or a coating method in a film or sheet shape; infusibilizing the resultant molding; and calcining the resultant molding in an inert gas atmosphere. Thus, the hard carbonaceous sheets thus produced have small porosity, high mechanical strength, high elastic modulus, isotropy and uniform thickness of several microns to several mm using widely available and inexpensive manufacturing processes.

Abstract: Apparatus, a method for extruding and expanding tubular products of polytetrafluoroethylene (PTFE) and the products produced thereby are provided. In the apparatus, at least one helical groove is placed in the wall of the extruder tip or die. Preferably, at least one groove is machined in the tip having a pitch angle of 45 degrees and at least one groove is machined in the die having a pitch opposite that (135 degrees) of the tip groove. In the expanded products produced according to the invention, at least one radial position within the wall of a tube substantially all of the longitudinal axes of the nodes are oriented at an angle between about 85 degrees and about 15 degrees with respect to the longitudinal axis of the tube.

Abstract: In combination, a container and a linerless cap and a method of forming the cap. In the method the cap is molded from plastic and includes a top well, an outer depending skirt and an internal depending substantially annular wall having an upper end integral with and depending from the top wall and a lower free end. Thereafter the free end is engaged by a curling tool to progressively turn the free end away from the internal wall to curve the free end into a curvilinear compressible and resilient free end adapted to be engaged for sealing. The engageable free end of the seal can have a coil, O, U, J or quarter round cross sectional shape and can be a rim, plug or corner seal.

Abstract: A process for manufacturing an organic silazane polymer which comprises reacting ammonia with a mixture of at least one compound selected from the group consisting of organic silicon compounds of the following formulae (I) and (II) ##STR1## and at least one compound selected from the group consisting of organic silicon compounds of the following formula (III) ##STR2## in which R represents hydrogen, chlorine, bromine, methyl radical, ethyl radical, phenyl radical or vinyl radical, R.sub.1 represents hydrogen or methyl radical, R.sub.2 represents hydrogen, methyl radical, ethyl radical, phenyl radical or vinyl radical and X represents chlorine or bromine; to obtain an ammonolysis product. The ammonolysis product is polymerized in the presence of a basic catalyst capable of deprotonation to obtain an organic silazane polymer. The silazane polymer may be further melted, shaped and infusibilized. The thus infusibilized product is finally sintered to obtain a ceramic material.

Abstract: A flexible one-piece cable tie for harnessing a bundle of wires or the like, the cable tie including an elongated, flexible strap having a ladder structure comprising a plurality of spaced rung-like members with intermediate openings for receiving a locking pawl, the locking pawl being disposed within an enclosed head integral with the strap at one end thereof.

Abstract: A process and an apparatus for forming a flange on the wall portion of a hollow body of thermoplastic material with an opening at one end provides that the end part of the wall portion which defines the opening is heated and contracted by means of a force acting on the end portion from the outside thereof over the periphery thereof, whereupon the contracted end part is subjected to a pressing operation to form a flange extending around the contracted end part.

Abstract: A small metal member (50) is secured to a surface (32) of a plastic member (30) by lock tabs (54) bent into a recess (34) in the surface (32), and the plastic material of a central boss (38) in the recess (34) is bulk deformed over ends (68) of the lock tabs (54) forming a recessed joint (70).

Abstract: A process for producing a carbon heat generator is disclosed including the steps of uniformly dispersing one or more types of metal compounds capable of forming a vitreous film upon oxidation in a moldable composition, molding the resultant dispersed composition, precarbonizing the molded composition, and then carbonizing the composition in a nonoxidative atmosphere to form a carbon heat generator having an oxidation preventive glass film. The oxidation of the metal compound exposed on the surface of the molded composition by the use of an oxidative atmosphere forms a vitreous film which prevents oxygen from diffusing in the interior thereof. The film so produced can form a new glass film on a damaged portion by a self-recovery effect if a pinhole or a crack occurs in the glass film. Thus, the process does not cause external appearance and weight differences before and after heat generating.

Abstract: A method of fabricating a rubber double-toothed belt wherein the unvulcanized rubber thereof is firstly heat treated so as to define a first toothed portion of the belt without substantial vulcanization thereof. The preform is then entrained about pulleys and a pair of heated molds engaged with both the toothed portion and the nontoothed outer portion of the belt to place the preform under pressure at a vulcanization temperature for sufficient time to cause the outer rubber portion of the preform to flow outwardly and define the outer teeth of the final belt concurrently with the vulcanization of the double-toothed belt construction. The parameters for controlling the heat treatment to provide the configurational retention without substantial vulcanization of the preform rubber are disclosed.

Abstract: An apparatus for making parts having complex geometric shapes by injection molding apparatus. The apparatus avoids the formation of a parting line in the molded object. The apparatus includes an injector plate, an ejector plate and a floating plate. The injector plate has at least one mold cavity for making a part and a passageway to allow molten plastic to enter the mold cavity. The ejector plate has at least one mold cavity corresponding to the mold cavity in the injector plate. The floating plate has at least one projection. The plates are adapted to fit together when the mold is closed so that the floating plate is between the injector and ejector plates and the projection fits centrally between the cavities of the injector and ejector plates. A mechanism moves the injector plate, ejector plate and floating plate with respect to one another.

Abstract: Aluminum nitride fibers or films are made by carbothermal nitridation of precursor fibers or films which contain a source of alumina and a source of carbon. Improved articles are obtained by providing a stoichiometric excess of carbon, by stabilizing the precursor prior to carbonization and nitridation, by removing excess carbon after nitridation and introducing a sintering aid to promote densification of the final structure.

Abstract: A method and an apparatus for producing multilayer panels. In the method for producing multilayer panels from extrudable plastic, two plastic strips are fed from extruders to a roll-arrangement and are joined together, with an inclusion of material therebetween. The purpose of the invention is to produce predeterminable patterns and structures upon introducing the material. In order to achieve this result, the material in the form of threads, is introduced individually and independently of each other into a gap in an arrangement of rolls, and the threads are aligned, by means of guide-means, in relation to each other and to the gap.

Abstract: An electrode substrate for fuel cells with a three-layer separator and two porous single or double carbonaceous layers and processes for preparing the same. The separator includes a carbon plate and two flexible graphite sheets. The porous layer has a number of elongated holes for feeding reactant gases into a fuel cell. The elongated holes are provided near the center of the thickness in the porous single layer or in the interface between the porous double layer. The electrode substrate exhibits improved properties, such as mechanical strength, thermal and electric resistances and the like, as a fuel cell electrode substrate.

Abstract: A process for producing a diaphragm for a speaker of carbonaceous materials which includes the steps of mixing carbon powder in a binder mainly containing chlorine-containing vinyl resin to be carbonized after calcining, applying high shearing force to a mixture composition obtained by uniformly mixing and dispersing the resultant mixture to sufficiently knead the mixture, then preliminarily molding the resultant mixture in a sheet shape, molding the preliminarily molded sheet into a diaphragm, insolubilizing, infusibilizing the diaphragm and calcining the diaphragm in an inert atmosphere, wherein the mixture composition contains at least 0.1 to 5 percentage by weight of 1.8-diazobicyclo (5, 4, 0) undecene-7 or that in which its salt is chlorine-containing vinyl chloride.

Abstract: A method of preparing carbon filaments which comprises exposing a suitable thermostable substrate which is covered with reduced monocrystalline metal particles with a diameter of at least 5 nanometers to a carbon containing gas mixture at temperatures of about 250.degree. up to about 700.degree. C. to 800.degree. C., for a period of time sufficient to form filaments of the desired length, and thereafter removing the substrate and/or the metal particles. The filaments are characterized by a crystalline graphitic structure and a morphology defined by a fishbone-like arrangement of the graphite layers along the axis of the filaments. A high carbide content is a prerequisite for the nucleation of the filamentous carbon with a fishbone like structure.

Abstract: A method and tool for fabricating composite shafts with at least one flared end. The tool includes a specially adapted end fitting for each flared end which define the angle and direction of flaring. The end fitting includes structure for conforming/compacting the composite material at the flared ends either during and/or after the composite build-up is completed and during cure. The conforming/compacting insures that the external surfaces of the flared ends achieve dimensional control and a machined like quality without the necessity of machining.

Abstract: A method of making a hollow fiber reinforced plastic structure with integrally molded fastening devices for attaching external components. The fastening device is attached to a piece of fibrous material into which resin is injected. The finger holds the fastening device in place during the resin injection step. The resin is cured to form a molded structure with the fastening device lying on an outer surface thereof. After removal from the mold, the fastening device can be used to attach external components to the part.

Abstract: Carbonaceous powders are blended with a high coking value pitch, e.g. mesophase pitch, formed into shaped bodies and then simultaneously compressed and baked in an envelope of finely divided, non-reactive particles, followed by graphitizing, if required, to produce high strength, high density carbon or graphite articles.

Abstract: A process for producing boron-containing ceramics such as boron carbide and boron nitride comprises pyrolyzing a blend of a precarbonaceous polymer such as polyacrylonitrile and a boron-containing polymer such as that formed by the reaction of a borane with a Lewis base. Pyrolyzation in an inert atmosphere yields boron carbide while pyrolyzation in a reactive gas burns away the precarbonaceous polymer and yiels a ceramic comprising the reaction product of boron and the pyrolyzation gas. Boron nitride ceramics are formed by pyrolyzing the preceramic blend in ammonia.

Abstract: In the production of hollow bodies from oriented thermoplastic material, a cylindrical portion of a heated hollow preform is stretched, with a simultaneous reduction in the wall thickness thereof, at a starting temperature below the vitreous transition temperature of the material. A mandrel is positioned in the preform to support it during stretching, the outside diameter of the mandrel corresponding to the inside diameter of the preform. Directly before the mandrel is inserted into the preform the preform is subjected to re-alignment to adapt at least the cross-sectional shape of the mouth opening of the preform to the cross-section of the mandrel. The re-aligning operation is effected by inserting the preform into a sleeve adjoining a drawing ring for carrying out the stretching operation.

Abstract: A cap for a container having a depending wall with a free end adapted to constantly urge engaging means of the cap and the container together upon engagement therebetween. Preferably, the free end of the cap has low hoop stress when axially compressed to provide spring means which perform the required function. In forming the cap, preferably one end is attached at the top wall of the cap, its other end is free to move relative to the cap and a substantial horizontal intermediate element is provided therebetween. In use, the free end has a bearing surface at or beyond the horizontal element thereof.

Abstract: A method of manufacturing interior trimmings characterized in that an integral portion is extended from the circumferential rim of a skin material in die half, that the substantially whole of this extended portion is sandwiched and fixed between a holder member and that face of the die half which is combined with that of the other die half, that the paired die halves are thus combined with each other to mold a resin body, and that when the resin body thus molded is divided, the extended portion of the skin material is folded round the divided end of its corresponding resin body and fixed to the inner face of this resin body.

Abstract: Disclosed herein are a process for producing a carbonaceous thin plate comprisingdisposing a composite material comprising a carbonaceous raw material which is carbonized and solidifies after being softened by heating and paper-like substances which are carbonized without melting between the pressing-surfaces of a heating press, so as to sandwich said carbonaceous raw material between said paper-like substances and to contact said paper-like substances with each of the pressing-surfaces of said heating press,press-molding said composite material by raising a temperature of said heating presscontinuously heating the thus press-molded composite material under a pressure, thereby carbonizing the thus press-molded composite material, andcalcining the thus carbonized material under a reduced-pressure or in an inert gas.

Abstract: A method is described for producing hydrophobic carbon molecular sieves. The method does not employ a binder to form or shape previously carbonized materials. Instead, a cross-linked oxygen-free polymer is first produced. Fine particles of this polymer are then pelletized or shaped as by simple extrusion. The extruded pellets are then carbonized in an oxygen-free atmosphere to yield binderless homogeneous particles of similar shape comprised of carbon sieves.

Abstract: When preparing carbon fibers from mesophase pitches, we usually encounter to the formation of cracks along the fiber axis. The crack formation is the most serious and troublesome problem. A simple process which can effectively prevent the crack formation comprises preparing the carbon fibers from mesophase pitches by melt spinning sufficient only to give a rotatory motion to the molten mesophase pitches just before extrusion substantially around the axis of a spinning nozzle hole. The process employs a usual nozzle plate having a pitch introducing tube and a spinning nozzle hole further containing a plug member having an outer spiral groove such as a drill point or a worm gear which is inserted within the pitch introducing tube.

Abstract: A lid for a liquid pack is formed from a plastic material and includes a substantially flat end wall. A pouring spout is disposed within the outside contour of an outer first plane of the lid. An opening flap portion closes a pouring opening, and a handle is secured to the opening flap portion by a hinge. The opening flap portion is connected by way of an endless weakening line to the wall of the lid, and a collar is disposed at the periphery of the lid at an inwardly displaced position for mounteing to a side wall of the pack. The weakening line extends in a second inner plane and at a spacing below and parallel to the first outer plane, with the spacing between the two planes being greater than or equal to the height of a collar portion projecting outwardly from the weakening line at the opening flap portion.

Abstract: Ultralight carbon-bonded carbon fiber composites of densities in the range of about 0.04 to 0.10 grams per cubic centimeter are fabricated by forming an aqueous slurry of carbonaceous fibers which include carbonized fibers and 0-50 weight percent fugitive fibers and a particulate thermosetting resin precursor. The slurry is brought into contact with a perforated mandrel and the water is drained from the slurry through the perforations at a controlled flow rate of about 0.03 to 0.30 liters per minutes per square inch of mandrel surface. The deposited billet of fibers and resin precursor is heated to cure the resin precursor to bind the fibers together, removed from the mandrel, and then the resin and fugitive fibers, if any, are carbonized.

Abstract: A glassy carbon-coated article contains a graphite substrate and a glassy carbon coating applied on the graphite substrate. The coating has a thickness of 15 to 200 microns. The glassy carbon is obtained by heating a raw material containing a thermal decomposition product of an organic polymer and a heat resistant inorganic substance. The difference of thermal expansion coefficient between the glassy carbon and the graphite substrate is not higher than 1.5.times.10.sup.-6 /.degree.C.

Abstract: Boron ceramics including boron ceramic fibers are formed by pyrolyzing at temperatures greater than 800.degree. C. organoboron polymers which have been formed by condensing decaborane with amines or phosphines.

Abstract: A method and apparatus for moulding an assembly of a thermoplastics member with a fusion pad 2b such as a pipe tapping tee saddle or a pipe coupling. The fusion pad 2b has an element which is to be electrically heated to weld the assembly to a compatible thermoplastics material and this pad is mounted in the cavity 105, 106 of an injection moulding tool 100 by which the thermoplastics member is to be moulded over the fusion pad 2b. During this latter moulding a control system 111 electrically heats the element to assist in bonding the thermoplastics envelope of the fusion pad to the thermoplastics of the member which is being moulded. A wall part 103 of the moulding tool 100 on which the fusion pad 2b is mounted may be temperature controlled 122 to maintain the surface of the fusion pad in contact therewith substantially solid.

Abstract: A heat shrinkable plastic sleeve having an inner surface deformed in circumferentially spaced portions by unequal amounts from its normal heat stable or unstable configuration so as to provide different stresses in the circumferential direction whereby uniformity of heating of the sleeve throughout its thickness can be observed during heat shrinking by observing the shrinkage of the sleeve at its ends. Also, a method of making such sleeve in which a sleeve of heat shrinkable material is placed on a mandrel having expandable fingers, the sleeve is heated and the fingers are radially expanded and the sleeve is cooled to provide the desired sleeve.

Abstract: A method of producing a container of plastic material capable of being oriented and/or crystallized, in which a substantially tubular blank is, in at least two mutually consecutive and mutually separate shaping phases or shaping stages, reshaped into the container. The blank is reshaped into the container by mechanical forming elements (34,42) which stretch the material in the axial direction of the blank, and in the circumferential direction of the blank. By stretching the material in each separate shaping stage to a regulated degree, there will be accumulated in the material a total stretching corresponding to the requisite stretching in order to impart to the material the desired and predetermined orientation and thereby the requisite strength properties.

Abstract: In combination, a container and a linerless cap and a method of forming the cap. The cap includes plastic and has a sealing surface which is softer than contiguous plastic portions as a result of its method of forming which includes stretching. In the method the cap is molded from plastic and includes a top wall, an outer depending skirt and an internal depending substantially annular wall having an upper end integral with and depending from the top wall and a lower free end. Thereafter the free end is engaged by a forming tool to progressively turn the free end away from the internal wall to create a stretched intermediate portion for sealing which is softer than its contiguous portions.

Abstract: A process of forming an end closure of one end of a stick of shirred sausage casing. The casing 10 is twisted and then the twisted neck (16) is compressed and heated to seal it. The twisted portion is severed so as to form an end seal with about four to eight twists in it. This end seal resists rupture during stuffing.

Abstract: An arrangement for improved dispensed material bead profile control, in which a viscous material is dispensed in a stream upon a surface. The stream is transported along that surface and forms a bead of the viscous material. The bead is then confined with air streams which also reshape the profile of the bead. The material is dispensed by a nozzle which has at least two orifices in its proximity. One orifice is located at a distance from the nozzle which is greater than for the other orifice. The orifices form air streams under pressure and direct the air streams toward the material stream, as well as toward the bead formed on the surface when the material stream is transported along that surface.

Abstract: This invention relates to the production of a novel, porous, carbon structure. A stabilised porous polymer comprising cavities joined by interconnecting pores is heated in an inert atmosphere to yield a stable, porous, carbon structure having the inherent structure of the original stabilised polymer.

Abstract: The present invention concerns a glass-like carbon material which may be bonded to other materials, the carbon material having a high thermal expansion coefficient and being highly applicable for use as a slider part for a recording medium.

Abstract: In combination, a container and a one piece, linerless cap and a method of forming the cap. The cap includes plastic and has a sealing surface which is softer than contiguous plastic portions as a result of its method of forming which includes stretching. In the method the cap is molded from plastic and includes a top wall and an outer depending skirt. Thereafter the top wall is engaged by a forming tool to create a stretched portion for sealing.

Abstract: Disclosed herein are a process for producing a carbon fiber mat, having excellent production and energy efficiencies, comprising successively melt-spinning a fiber-forming pitch by a centrifugal spinning machine having a horizontal axis of rotation (parallel to the plane on which the spinning machine is placed), forming a mat by the thus spun pitch fibers, bringing the mat into an infusibilized state in an air atmosphere containing NO.sub.2 and calcining the thus infusibilized mat in an inert atmosphere, and an apparatus for carrying out the above-mentioned process.

Abstract: A sculptured structural fiberboard product is formed using a mold that includes porous forming areas which, in one embodiment, are porous forming mandrels movably mounted on the mold, and liquid impervious thimbles which removably cover the porous areas. A fiber network is formed as water is drained off through the porous areas and the thimbles are moved to gradually unveil the porous areas during the mat formation. When mandrels are used, the mandrels are withdrawn in cooperation with a pressing force applied to the mat to consolidate and dry the web. The porous areas can also act as heat and mass transfer means during consolidation and drying. An alternative embodiment permits formation of laminated products and another alternative embodiment permits close control over the product density during consolidation and drying.

Abstract: Nonwoven webs are disclosed which comprise monofilaments or fibers of a thermoplastic material. Basically, the improvement comprises the use of monofilaments or fibers which have a bilobal shaped cross-section. Nonwoven webs made according to this invention are particularly suited to be used for liners for disposable diapers as well as wraps for catamenial devices. Methods are also disclosed for producing such nonwoven webs.