Abstract: Methods, apparatus, systems and articles of manufacture are disclosed to estimate an audience population. An example apparatus includes at least one memory; instructions in the apparatus; and processor circuitry to execute the instructions to: determine whether respective ones of respondents are associated with a characteristic; detect unique instances of the respective ones of the respondents; in response to the respective ones of the respondents being associated with the characteristic, increase a sample capture count by one; in response to detecting the unique instances of the respective ones of the respondents exhibiting the characteristic, increase a unique capture count by one; determine a seed population estimate based on the unique capture count; and determine a population estimate having the characteristic based on the sample capture count, the unique capture count, the seed population estimate, and a number of available samples.

Abstract: A latex composition has a latex of a carboxyl group-containing conjugated diene rubber (A), and a plasticizer (B) having a SP value of 15 (cal/cm3)1/2 or less, wherein the content of a plasticizer (B) is 0.1 to 15 parts by weight based on 100 parts by weight of the carboxyl group-containing conjugated diene rubber (A) included in the latex.

Abstract: Methods, apparatus, systems and articles of manufacture are disclosed to estimate an audience population. An example apparatus includes at least one memory; instructions in the apparatus; and processor circuitry to execute the instructions to: determine whether respective ones of respondents are associated with a characteristic; detect unique instances of the respective ones of the respondents; in response to the respective ones of the respondents being associated with the characteristic, increase a sample capture count by one; in response to detecting the unique instances of the respective ones of the respondents exhibiting the characteristic, increase a unique capture count by one; determine a seed population estimate based on the unique capture count; and determine a population estimate having the characteristic based on the sample capture count, the unique capture count, the seed population estimate, and a number of available samples.

Abstract: Elastomeric articles, such as gloves, made from more than one layer, are provided. The gloves can include a first (grip side) layer in which a first colorant is compounded or integrated and a second (donning side) layer in which a second colorant is compounded or integrated. Alternatively, the gloves can include a translucent first layer and a second layer in which a colorant is compounded or integrated. Either arrangement can enable a breach of the first layer to be more easily detected, either due to the high level of contrast between the first layer and the second when a first colorant and a second colorant are utilized, or due to the translucence of the first layer as compared to the donning side layer, where the intensity of the second layer is increased upon a breach of the translucent first layer.

Abstract: The present invention provides ingestible dosage form articles such as opaque capsules with reduced light transmittance.

Abstract: A method of making garment material, the method having the steps: applying coagulant (34) to a substrate (32); applying a foam (38) of the polymeric material to the substrate (32); allowing the coagulant (34) to coagulate some of the foam (38); and removing uncoagulated foam (38) from the substrate (32) to leave a layer of coagulated polymeric material on the substrate (32).

Abstract: The present invention relates to new acid resistant hard pharmaceutical capsules, a process for their manufacture and use of such capsules particularly but not exclusively for oral administration of pharmaceuticals, veterinary products, food and dietary supplements to humans or animals. The capsules of the invention are obtained by aqueous compositions comprising a water soluble film forming polymer and gellan gum in a mutual weight ratio of 4 to 15 weight parts of gellan gum for 100 weight parts of film forming polymer.

Abstract: A medical article, such as a catheter, is formed from a blend of polyurethane and synthetic polyisoprene (SPIR). The blended medical article is preferably selected and prepared to be relatively rigid at room temperature and relatively flexible at body temperature. An intermittent catheter made from the blend provides a degree of stiffness for its insertion into the patient at room temperature. The catheter becomes softer, and therefore more comfortable, at warmer temperatures (e.g., body temperature) which reduce discomfort after insertion. Optionally, the catheter or a portion thereof can have a hydrophilic coating as to avoid the need for external lubricants. Advantageously, the blended catheter can meet the stiffness, tensile strength, and coefficient of friction requirements of intermittent catheterization applications while avoiding the risk of toxic or allergic reactions in sensitive users.

Abstract: A mandrel (5) for molding polymer valve leaflets for heart valve prostheses is disclosed, including a body portion (52) including an outer surface with ridges (60) and contoured surfaces (64) corresponding to the leaflets, the upper edge of the contoured surfaces corresponding to the free upper edge of the leaflets, and the mandrel including a mandrel extension (54) above the body portion, and a gap (68) extending around the mandrel between the upper edge of the contoured surface and the mandrel extension. A process for producing these polymer valve leaflets is also disclosed by dip coating with this mandrel and re-moving the polymer film created at the gap, preferably by applying suction or blowing thereto.

Abstract: The invention relates to methods of making articles of semiconducting material and semiconducting material articles formed thereby, such as articles of semiconducting material that may be useful in making photovoltaic cells.

Abstract: A method of making an article of a semiconducting material involves selecting a target thickness for the article and then submerging a mold into a molten semiconducting material for a submersion time effective to form a solid layer of semiconducting material over an external surface of the mold where the thickness of the solid layer is substantially equal to the target thickness. The submersion time is selected to be substantially equal to a transition time, which is determined from a plot of solid layer thickness versus submersion time for a mold having particular attributes, including mold composition, mold thickness and initial mold temperature. The transition time, and thus the submersion time, corresponds to a maximum in solid layer thickness in the solid layer thickness versus submersion time curve for the particular mold.

Abstract: The invention relates to methods of making articles of semiconducting material and semiconducting material articles formed thereby, such as articles of semiconducting material that may be useful in making photovoltaic cells.

Abstract: A biodegradable polymer stent with radiopacity and a method of making and using a stent with enhanced mechanical strength and/or controlled degradation for use in a bodily lumen is described.

Abstract: The present invention relates to new acid resistant hard pharmaceutical capsules, a process for their manufacture and use of such capsules particularly but not exclusively for oral administration of pharmaceuticals, veterinary products, food and dietary supplements to humans or animals. The capsules of the invention are obtained by aqueous compositions comprising a water soluble film forming polymer and gellan gum in a mutual weight ratio of 4 to 15 weight parts of gellan gum for 100 weight parts of film forming polymer.

Abstract: A composition for producing an elastomeric thin film comprising a carboxylated acrylonitrile polybutadiene latex which is vulcanized without the use of conventional sulphur and accelerators thereby reducing the possibility of contacting immediate Type I hypersensitivity and delay Type IV hypersensitivity caused by the presence of natural rubber latex proteins and accelerators respectively. The dipping process for making gloves by using a latex composition provided by: premixing carboxylated acrylonitrile polybutadiene latex with methacrylic acid, or alternatively using a self-crosslinked latex, adding zinc oxide, adjusted to 9 to 10 of the pH level, and diluted with water to obtain 18% to 30% by weight of total solid content; dipping the glove former into the composition to form a layer of thin film of the latex composition on the former; drying the thin latex film on the former and crosslinking the latex film on the former.

Abstract: An aqueous composition for an enteric hard capsule, a method of preparing an enteric hard capsule, and an enteric hard capsule prepared using the method. The aqueous composition for an enteric hard capsule includes an enteric base material, a capsule forming aid, and a neutralizing agent.

Abstract: A reusable, low investment tool for making parts is made by a process in which a mixture of sand and an activator is applied as a layer onto which a printed resin is deposited to form a base and a pattern. A plurality of sidewalls may also be provided on the base using the same process. The tool is coated with a curable resin to form a protective shell. The reusable tool may be used as a dump box or as a vacuum forming tool for forming parts. A stamping die may be formed by drawing a vacuum through the sand layer as the resin coating is applied to more fully permeate the stamping die.

Abstract: Multilayer elastomeric articles and methods of making the same are disclosed in which the outside or outer distal surface of the article is a different color or otherwise visually distinct in appearance from the inside or wearer contacting surface of the article so that the user of the article can readily identify the article as a multilayer elastomeric article. In one aspect, elastomer emulsions, solvent solutions, or plastisols used to form each layer may be modified with the addition of base color and/or colorant components in order to form a colored or patterned layer. In another aspect, one or both of the surfaces of the elastomeric articles (or layers of the articles) may be coated with such a colorant component to sufficiently visually distinguish the layers from each other.

Abstract: The invention relates to a method and a device for the production of plastic molded skins, which are formed by consecutively performing a plurality of partial melting processes of a plurality of plastic materials, wherein the first plastic material is applied to the mold as a plastic powder in a centrifugal molding method and the second plastic material by a spraying method.

Abstract: A medical article, such as a catheter, is formed from a blend of polyurethane and synthetic polyisoprene (SPIR). The blended medical article is preferably selected and prepared to be relatively rigid at room temperature and relatively flexible at body temperature. An intermittent catheter made from the blend provides a degree of stiffness for its insertion into the patient at room temperature. The catheter becomes softer, and therefore more comfortable, at warmer temperatures (e.g., body temperature) which reduce discomfort after insertion. Optionally, the catheter or a portion thereof can have a hydrophilic coating as to avoid the need for external lubricants. Advantageously, the blended catheter can meet the stiffness, tensile strength, and coefficient of friction requirements of intermittent catheterization applications while avoiding the risk of toxic or allergic reactions in sensitive users.

Abstract: An article comprising at least one cured, liquid-impervious polymeric shell substantially free from defects, at least one liner, and a non-tacky, thermoplastic adhesive layer between the shell and the liner, wherein the adhesive layer is melted and solidified to create a non-tacky bond between the shell and the liner, which can be moisture-absorbing or cut-resistant, whereby the liner supports and limits stretch ability of the shell, thereby preventing adhesive delamination between the adhesive layer and either of the shell and/or the liner; a method for the manufacture of an article comprising a supported, polymeric shell, such as a glove, a gauntlet, an apron, or a boot, comprising providing a cured, liquid-impervious, polymeric shell, providing a knitted/woven liner, incorporating a non-tacky, thermoplastic adhesive layer between the shell and the liner, such as by hot-melt spraying, dry-powder spraying or fiber-coating, creating intimate contact between the shell, the adhesive layer, and the liner, subjec

Abstract: Techniques for forming a carbon nanotube (CNT) structure are disclosed.

Abstract: A method and apparatus for forming hard shell capsule components, wherein the capsule components are formed from a material which undergoes gelation upon heating, such as HPMC. A heat station is provided to heat a plurality of molds prior to dipping into a solution of the thermogeling material. The drying conditions following dipping are carefully controlled to control the rate of drying.

Abstract: High performance microlens arrays are fabricated by (i) depositing liquid on the hydrophilic domains of substrates of patterned wettability by either (a) condensing liquid on the domains or (b) withdrawing the substrate from a liquid solution and (ii) optionally curing the liquid to form solid microlenses. The f-number (f#) of formed microlenses is controlled by adjusting liquid viscosity, surface tension, density, and index of refraction, as well as the surface free energies of the hydrophobic and hydrophilic areas. The f-number of formed microlenses is also adjustable by controlling substrate dipping angle and withdrawal speed, the array fill factor and the number of dip coats used. At an optimum withdrawal speed f# is minimized and array uniformity is maximized. At this optimum, arrays of f/3.48 microlenses were fabricated using one dip-coat with uniformity better than ?f/f˜±3.8% while multiple dip-coats permit production of f/1.38 microlens arrays and uniformity better than ?f/f˜±5.9%.

Abstract: A method of making zeolite microneedles includes providing a polymer microneedles template, depositing zeolite seeds on the polymer microneedles template, and growing the zeolite seeds into an array of zeolite microneedles.

Abstract: Extra coagulant is added to the cuff portion of the former by a spray nozzle located between the coagulant and latex dipping tanks. A former is placed into a coagulant. After removal from the coagulant, additional coagulant to the cuff portion of the former by any conventional means, such as a spray nozzle. The higher concentration of coagulant at the cuff portion results in a thicker latex thickness at the cuff portion and counteracts the reduced dwell time of the cuff in the latex dipping tank as compared to the fingertip portion of the former. The thickness of the cuff portion can be controlled by altering the concentration of the coagulant applied by the spray nozzle.

Abstract: Latex articles with geometrically defined surface structure providing enhanced grip characteristics in dry, wet or oily environment; and a method of making same comprising applying a polymeric coagulant coating to a smooth former surface, wherein the coating becomes tacky during drying, applying discrete coagulant particles of selected size, shape and distribution to the tacky coating to attach and protrude from the former surface with the polymeric coagulant coating, dipping the former into an aqueous latex emulsion, wherein the polymeric coagulant coating and the discrete coagulating particles destabilize the latex, thereby developing a latex layer, vulcanizing and stripping the latex article inside out, and dissolving the discrete coagulant particles in water or suitable solvents to reveal the geometrically designed texture with pre-selected size, shape and distribution of impressions providing improved dry, wet and oily surface grip by removal of a fluid boundary layer.

Abstract: Thin-walled rubber articles for use contact with living tissue or with materials to be delivered to living tissue are prepared from aqueous latex of either natural rubber or synthetic cis-1,4-polyisoprene by vulcanization to produce both carbon-carbon and carbon-(sulfur)n-carbon crosslinks, the vulcanization being performed in the absence of any compounding components that contain secondary amine groups or any components that have a tendency to produce nitrosamines. While sulfur activators may be included, it is preferable that no sulfur accelerators at all be included. Thin-walled rubber articles formed from the latex surprisingly exhibit a combination of high tensile strength, high ultimate percent elongation, and low 500% tensile modulus. The process is particularly effective in the manufacture of thin-walled articles from synthetic cis-1,4-polyisoprene.

Abstract: Presented is a method of manufacturing opened at both ends thin walled elastomeric sleeves of complex shapes. The proposed technique employs standard dip molding process but with modifications which enable producing of opened at both ends sleeves right from the drying stage and eliminates the necessity of cutting lower dipped ends subsequently to the dipping process. This technique allows sleeves to be manufactured with rolled beads at both ends. The main benefit of the present invention is a possibility of manufacturing sleeves on existing standard automated and semi-automated dip molding lines, traditionally used for manufacturing elastomeric gloves and condoms. The gist of the invention is a composition of a dipping former with a bottom coated by hydrophobic material such as PTFE. This composition impedes buildup of coagulant and coagulum on the bottom. The loose coagulum layer is removed by means of washing off with directed and appropriately timed sprinklers.

Abstract: A medical device, such as a catheter shaft, having an inner lumen defined by a layer of polymer coating, and a method for forming such a medical device. In some embodiments, the method generally includes the steps of applying a polymer coating to an elongated mandrel, and constructing the remainder of the catheter shaft body around the polymer coated mandrel. In some embodiments, the polymer coating layer is made from water dispersible polymer or water soluble polymer.

Abstract: A process for producing an article in a flexible foamed polymer material, including treating a former with a coagulant; dipping the treated former in a latex foam mixture to form a layer of the mixture on the former that includes air cells; curing the layer to gel the foam mixture to a cross-linked open cell structure; and stripping the layer from the former; where the latex foam mixture includes a natural latex polymer as a primary polymer component, and a synthetic latex polymer as a secondary polymer component, which synthetic latex polymer is selected to enhance the evenness and/or fineness of said open cell structure.

Abstract: A method for the layer-by-layer assembly of a free standing thin film includes the steps of preparing a support with a suitable substrate; forming a thin film having a plurality of layers onto the substrate utilizing a layer-by-layer assembly process; removing the substrate and thin film from the support; and separating the substrate from the thin film. Various compounds improving the strength, flexibility, tension and other mechanical properties may be included in the assembly to improve the structural quality of the film. Similar effect may also be achieved by cross-linking the applied layers.

Abstract: Pore-free rubber articles are prepared by dip-molding in a dipping medium that includes a vulcanizing agent, then by immersing the dip former in a heated liquid bath that is chemically inert. A particularly effective liquid bath is molten inorganic salt. In addition, the tensile properties of an article of vulcanized rubber can be improved to an unusually effective degree by immersing the already vulcanized article in a solution of a vulcanizing agent to cause the rubber of the article to absorb or imbibe the vulcanizing agent from the solution, and then immersing the rubber and the imbibed vulcanizing agent in a heated liquid bath to increase the degree of vulcanization.

Abstract: A hybrid stent is formed which exhibits both high flexibility and high radial strength. The expandable hybrid stent for implantation in a body lumen, such as a coronary artery, consists of radially expandable cylindrical rings generally aligned on a common longitudinal axis and interconnected by one or more links. In one embodiment, a dip-coated covered stent is formed by encapsulating cylindrical rings within a polymer material. In other embodiments, at least some of the rings and links are formed of a polymer material which provides longitudinal and flexural flexibility to the stent. These polymer rings and links are alternated with metallic rings and links in various configurations to attain sufficient column strength along with the requisite flexibility in holding open the target site within the body lumen. Alternatively, a laminated, linkless hybrid stent is formed by encapsulating cylindrical rings within a polymer tube.

Abstract: Pore-free rubber articles are prepared by dip-molding in a dipping medium that includes a vulcanizing agent, then by immersing the dip former in a heated liquid bath that is chemically inert. A particularly effective liquid bath is molten inorganic salt. In addition, the tensile properties of an article of vulcanized rubber can be improved to an unusually effective degree by immersing the already vulcanized article in a solution of a vulcanizing agent to cause the rubber of the article to absorb or imbibe the vulcanizing agent from the solution, and then immersing the rubber and the imbibed vulcanizing agent in a heated liquid bath to increase the degree of vulcanization.

Abstract: A slush-moulding method combined with cross-linking, including the filling of a tank with a suitable quantity of ground polymer blend and the coupling of said tank with a heated mold is provided. The closed system thus obtained is moved in order to transfer the powder onto the mold, so as to carry out on the latter a layer of completely or partially melted powder. Before and after a stage of stripping of the leather off the mold, said leather is cross-linked by means of radiations.

Abstract: The present invention is directed to the use of a polymer coating composition having a dispersant, microbeads and a high Tg polymer with a Tg of greater than −10° C. for the inner coating on natural and synthetic rubber articles, particularly for latex gloves. The coating for rubber articles, provides an inner surface coating that reduces friction between the latex and the hand to allow convenient donning. They are deliverable from aqueous solution.

Abstract: A multi element moving vacuum chamber (MEMVC) for rotational casting includes a mold having a predefined shape and an axis of rotation, and a box containing casting material. The MEMVC further includes a first vacuum element mounted to an outer mold surface and a second vacuum element mounted to an outer box surface. The mold and the box are detachably engageable with each other to define an engaged configuration in which air present in an enclosed area defined by the outer mold surface and an inner surface of the first vacuum element, by an inner mold surface and an inner box surface, and by the outer box surface and an inner surface of the second vacuum element, is removed to create a vacuum. Alternatively, the mold and/or the box may be constructed with vacuum loading capability, thereby eliminating the need for the first and/or the second vacuum elements.

Abstract: A bladder shell for inflatable balls having at least a pair of layers of compounded synthetic latex and compounded natural rubber latex or at least a layer of blended synthetic latex and natural rubber latex compounded with anti-oxidant, activators, accelerators, thickening and wetting agents, stabilizers etc. to form a low air permeability and high bounce bladder shell having thickness of between 0.25 mm to 3.0 mm.

Abstract: A method of making a colored, multi-layered polymer coated film-based article includes the steps of providing a former in the shape of an article; dipping the former in a first polymeric solution in order to coat the former with a polymeric film of the first polymeric solution; withdrawing the former from the first polymeric solution and allowing the coated former to dry; dipping the former in a second polymeric solution in order to again coat the previously coated former, wherein the second polymeric solution produces a coating of observable contrast to the first coating; withdrawing the former from the second polymeric solution and allowing the second coating to dry, thereby forming an article on the former; and stripping the article from the former. A colored polymer coated film-based article includes a first layer of a polymeric film material; a second layer of polymeric film material formed on top of the first layer, the second layer in visual contrast from said first layer.

Abstract: Pore-free rubber articles are prepared by dip-molding in a dipping medium that includes a vulcanizing agent, then by immersing the dip former in a heated liquid bath that is chemically inert. A particularly effective liquid bath is molten inorganic salt. In addition, the tensile properties of an article of vulcanized rubber can be improved to an unusually effective degree by immersing the already vulcanized article in a solution of a vulcanizing agent to cause the rubber of the article to absorb or imbibe the vulcanizing agent from the solution, and then immersing the rubber and the imbibed vulcanizing agent in a heated liquid bath to increase the degree of vulcanization.

Abstract: A rubber glove is produced by sequentially performing the step of immersing a glove mold in a coagulating synthetic rubber latex containing synthetic rubber in latex form, thermally expansible microcapsules, and a rubber coagulant to form a coagulant-containing synthetic rubber film on the surface of the glove mold; the step of immersing the glove mold in rubber-incorporating latex to form a gelled rubber layer; the step of heating a rubber laminate composed of the synthetic rubber film and the gelled rubber layer to vulcanize the rubber laminate; and the step of turning the vulcanized rubber laminate inside out, and removing it from the glove mold. This method produces a rubber glove, which is excellent in anti-blocking properties and grip under dry or wet conditions, by a simple procedure and for a low cost.

Abstract: A polymer useful in forming coatings for articles is provided. The polymer is an acrylic copolymer formed as the reaction product of a plurality of monomers which include an alkyl (meth)acrylate, a quaternary amine (meth)acrylate, a hydroxyalkyl (meth)acrylate, an N-vinyl lactam, an ethylenically unsaturated carboxylic acid, and a fluorinated (meth)acrylate. The polymer is formed in the presence of surfactants, preferably by sequential polymerization of two separate monomer mixtures. To form a coating, the polymer is blended with an elastomeric material such as nitrile rubber latex. The resulting coating is useful both as a print coating for substrates used with ink jet printers and as a coating for rubber articles.

Abstract: High performance microlens arrays are fabricated by (i) depositing liquid on the hydrophilic domains of substrates of patterned wettability by either (a) condensing liquid on the domains or (b) withdrawing the substrate from a liquid solution and (ii) optionally curing the liquid to form solid microlenses. The f-number (f#) of formed microlenses is controlled by adjusting liquid viscosity, surface tension, density, and index of refraction, as well as the surface free energies of the hydrophobic and hydrophilic areas. The f-number of formed microlenses is also adjustable by controlling substrate dipping angle and withdrawal speed, the array fill factor and the number of dip coats used. At an optimum withdrawal speed f# is minimized and array uniformity is maximized. At this optimum, arrays of f/3.48 microlenses were fabricated using one dip-coat with uniformity better than &Dgr;f/f˜±3.8% while multiple dip-coats permit production of f/1.

Abstract: A powder-free coagulant for use in latex dipping processes comprises a salt stable dispersion of a polychloroprene rubber and an inorganic metal salt. Optionally the coagulant will also contain a powder-free release agent, to aid release of the dipped article from the former, comprising a polypropylene wax emulsion and a cationic surfactant.

Abstract: A powder-free coagulant for use in latex dipping processes comprises a salt stable dispersion of a polychloroprene rubber and an inorganic metal salt. Optionally the coagulant will also contain a powder-free release agent, to aid release of the dipped article from the former, comprising a polypropylene wax emulsion and a cationic surfactant.

Abstract: A process which allows elastomeric materials of different colors, durometers and/or other material characteristics to chemically bond to one another so as to eliminate any possibility of delamination. Latex-based liquid elastomer solutions having different material characteristics are applied sequentially to a heated mold to form a series of layers making up the article, with rapid partial curing taking place between each application; the partial curing forms a skin coat over each layer which prevents intermixing of the different solutions, but which still permits a chemical bond to form during full curing of the materials. The process applies equally to dip (immersion) molded and flat molded goods. An example of the invention as it relates to flat-molded goods is an athletic shoe sole, and an example as it relates to dip-molded goods is a resilient, one piece watersports boot which can be fitted over a human foot without a zipper.

Abstract: A process for forming molded articles from particulate thermoplastic material, the process comprising:

Abstract: A molding apparatus and method for forming a thermoplastic shell or skin product. The molding apparatus includes a hollow mold housing provided with a mold tool thereon, which together define a fluid chamber within the mold housing. A quantity of heated liquid is supplied at a predetermined or operating temperature to the chamber of the mold housing from a liquid supply via an elongate feed pipe until a rear surface of the mold tool is covered. The mold housing is then oscillated to uniformly distribute the heated liquid within the chamber and to effect uniform heating of the mold tool. Heating devices are located within the chamber of the mold housing to add heat to the liquid within the housing chamber to maintain a desired liquid temperature.

Abstract: A modified elastomeric glove is disclosed having a lubricous coating made up of polyvinyl alcohol and a thickening agent. The thickening agent is initially added in order to increase the processability of the polyvinyl alcohol coating in order to prevent runbacks and drips during the manufacturing process. A hydroscopic thickener may be used. The polyvinyl alcohol coating becomes lubricous when wetted in a water bath and therefore becomes particularly useful in applying a water-activated resin casting material for forming orthopaedic casting bandages.