Carboxylic Acid Or Derivative Patents (Class 264/331.21)
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Patent number: 6544453Abstract: Shrinkage of cured resins is reduced by mixing the crosslinkable resin with a low profile additive (LPA). The LPA is in the form of particles which comprise an SCC polymer (or a similar crystalline polymer which melts over a narrow temperature range). The system is cured at a temperature above the melting point of the crystalline polymer (Tp), and the system and the LPA are such that at least part of the LPA remains as a separate phase in the curable resin at temperatures below Tp. It is believed that at least part of the crystalline polymer remains as a separate phase in the resin as it cures. Preferably at least part of the crystalline polymer forms a separate phase in the cured polymer after it has cooled.Type: GrantFiled: December 11, 2000Date of Patent: April 8, 2003Assignee: Landec CorporationInventors: David D. Taft, Steven P. Bitler
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Publication number: 20030011105Abstract: A cushioning molded product is provided which is produced by binding a vegetable fiber with a copolymer of a saccharide and an aliphatic dicarboxylic acid to conduct molding. Further a process is provided for producing a cushioning molded product from a copolymer of a saccharide and an aliphatic dicarboxylic acid, and a vegetable fiber, the process comprising (a) mixing or adhering the copolymer and the vegetable fiber, and (b) molding the resulting mixture into an intended shape by heating the mixture to bind the vegetable fiber with the copolymer.Type: ApplicationFiled: July 9, 2002Publication date: January 16, 2003Inventors: Yoshihiko Kikuchi, Chieko Mihara
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Publication number: 20030006520Abstract: A method of making patterned artificial material marble/granite/solid surface material that makes artificial marble/granite/solid surface material with variable patterns by use of polymers. The polymers are combined with filler materials, an accelerating reagent or colorful material to compose basic materials and pattern materials in different colors. Molds with at least one pattern are used for curing of the basic materials and the pattern material to form the patterned artificial material and to make the artificial marble/granite/solid surface material integral.Type: ApplicationFiled: July 5, 2001Publication date: January 9, 2003Inventor: Kuo-Yuan Lin
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Patent number: 6465583Abstract: Continuous anionic polymerization and melt-spinning of a polycaprolactam includes forming a reaction mixture by bringing at least two streams of liquid caprolactam respectively containing a polymerization initiator and co-initiator into contact with one another, and then subjecting the reaction mixture to anionic polymerization reaction conditions to obtain a molten polycaprolactam. The molten polycaprolactam is the directly (i.e., without intermediate solidification) transferred to, and extruded through, a fiber-forming orifice of a spinneret to form a fiber thereof. One exemplary system to achieve such continuous anionic polymerization and melt-spinning of polycaprolactam includes a mixer for receiving and mixing at least two streams of liquid caprolactam respectively containing a polymerization initiator and co-initiator, and a reactor and melt-spinning apparatus downstream of the mixer.Type: GrantFiled: June 13, 2001Date of Patent: October 15, 2002Assignee: BASF CorporationInventors: Dominick A. Burlone, Matthew B. Hoyt, Charles F. Helms, Jr., John A. Hodan, Richard Kotek, Carol W. Morgan, Randall A. Sferrazza, Fang A. Wang, Otto M. Ilg, Terry D. Roberts, Ronald G. Morrow
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Patent number: 6454983Abstract: A process is provided for single screw extrusion of a composition or masterbatch comprising a polymer and an antistatic agent wherein the feed zone temperature is maintained below 385° F. in order to allow processability of the composition.Type: GrantFiled: December 3, 1999Date of Patent: September 24, 2002Assignee: Eastman Chemical CompanyInventors: Douglas Stephens McWilliams, Harold Eugene Dobbs, Scott Arnold Hanson, Emily Tedrow Bell
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Patent number: 6455618Abstract: Described is a thermoplastic molding composition comprising: a) 0.05 to 1.5 wt. %, with respect to the entire molding composition, of a fatty acid amide ester wax; b) 0.5 to 10 wt. %, with respect to the entire molding composition, of a silica selected from natural silica, synthetic silica and mixtures thereof; c) 0 to 1 wt. %, with respect to the entire molding composition, of a montan wax; and d) at least one thermoplastic elastomer. Also described are a method of preparing the thermoplastic molding composition, and methods of preparing articles from the thermoplastic molding composition.Type: GrantFiled: June 7, 2001Date of Patent: September 24, 2002Assignee: Wolff Walsrode AGInventors: Ralf Schledjewski, Hans-Werner Funk, Dirk Schultze, Rainer Brandt
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Publication number: 20020130439Abstract: The present invention relates to the use of compositions comprising reaction products of low molecular mass dicarboxylic or tricarboxylic acids with ammonia to produce moldings comprising finely divided materials.Type: ApplicationFiled: January 15, 2002Publication date: September 19, 2002Applicant: BASF AktiengesellschaftInventors: Matthias Kroner, Matthias Gerst, Bernd Reck
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Patent number: 6447913Abstract: To provide a thermoplastic polyester resin composition which has a very good durability to alkaline solutions for a long period of time. That is, a thermoplastic polyester resin composition, wherein a thermoplastic polyester resin (A) is compounded with 1-25% by weight (in the total composition) of impact resistance rendering materials (B), 0.1-15% by weight (in the total composition) of a silicone compound and/or a fluorine compound (C), 1-50% by weight (in the total composition) of an inorganic filler (D), and 0.1-10% by weight of at least one polyfunctional compound (E) selected from the group consisting of an epoxy compound, an isocyanate compound and a carboxylic acid dianhydride. A molded article of the present invention has anti-stress properties even in a weld part thereof.Type: GrantFiled: January 25, 2001Date of Patent: September 10, 2002Assignees: Polyplastics Co., LTD, Denso CorporationInventors: Kazufumi Watanabe, Takayuki Ishikawa, Toru Katsumata, Tetsuya Hirose, Hiroyuki Wakabayashi
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Patent number: 6440566Abstract: This invention relates to a method for molding or curing a resin material using a multilayer release film as a barrier at the surface of the resin material. In one embodiment, the method comprises the surface of the resin material being in contact with the release film at a temperature of at least about 350° F. (about 180° C.). Here, the release film is non-oriented and comprises: (1) an enhancement layer which comprises a thermoplastic material; and (2) a first release layer which has a composition that is different from the enhancement layer, comprises a polymeric material, and is releasable from the resin material after the resin material is molded or cured. This invention also relates to a release film that may be used, for example, with the above method.Type: GrantFiled: October 1, 1999Date of Patent: August 27, 2002Assignee: Airtech International, Inc.Inventors: John Maligie, Thomas Malter
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Patent number: 6426024Abstract: A preform having a small content of acetaldehyde can be advantageously produced by forming a vent, from which air is exhausted during molding, at a specific position of a molding machine in order for an aromatic polyester to be advantageously exposed under reduced pressure in a molten state when a preform of the aromatic polyester is injection molded.Type: GrantFiled: September 23, 1999Date of Patent: July 30, 2002Assignee: Teijin LimitedInventor: Akio Komenoi
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Patent number: 6410156Abstract: Oxygen scavenging barrier polyamide compositions exhibiting high oxygen scavenging capability as well as good coinjection stretch blow moldability characteristics suitable for making multilayer PET bottles with good clarity and delamination resistance are claimed in this invention. The polyamide compositions of this invention comprise a slow crystallizing polyamide blend comprising (i) an amorphous, semiaromatic polyamide homopolymer, copolymer or mixture thereof and (ii) a semicrystalline, aliphatic polyamide homopolymer, copolymer or mixture thereof wherein in the weight ratio of (i):(ii) ranges from about 99:1 to about 30:70; at least one polyamide-compatible, oxidizable polydiene; and at least one oxidation promoting metal salt catalyst. The multilayer PET bottles, made with the polyamide compositions of this invention as the barrier layer, are suitable for extended shelf-life packaging of oxygen-sensitive food and beverage products such as beer and juices.Type: GrantFiled: March 6, 2001Date of Patent: June 25, 2002Assignee: Honeywell International Inc.Inventors: Murali K. Akkapeddi, Edward P. Socci, Timothy J. Kraft, Darnell C. Worley, II, Jeffrey D. Pratt, Clark V. Brown
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Patent number: 6342304Abstract: This invention relates to binary blends of cellulose esters and aliphatic-aromatic copolyesters, cellulose esters and aliphatic polyesters as well as ternary blends of cellulose esters and/or aliphatic polyesters and/or aliphatic-aromatic copolyesters and/or polymeric compounds as well as fibers, molded objects, and films prepared therefrom.Type: GrantFiled: July 23, 1998Date of Patent: January 29, 2002Assignee: Eastman Chemical CompanyInventors: Charles M. Buchanan, Robert M. Gardner, Matthew D. Wood, Alan W. White, Steven C. Gedon, Fred D. Barlow, Jr.
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Patent number: 6303069Abstract: A process for the production of moldings from a polymer alloy of multiphase morphology, in which the polymer alloy is prepared with the injection molding in one process step. For this, thermoplastically processable polymers which are incompatible or not very compatible with one another are introduced as granules, preferably having a particle size of greater than or equal to 3 mm, into the hopper of an injection molding machine and are subsequently plasticized, mixed thoroughly, and shaped in the injection molding machine; where at least one of the polymers employed is capable chemically, under the injection molding conditions, of association and/or copolymerization with at least one other of the participating polymers. The resulting polymer alloys are not inferior in their properties to corresponding conventionally produced alloys. The moldings are useful in orthopedics.Type: GrantFiled: November 6, 1997Date of Patent: October 16, 2001Assignee: Otto Bock Orthopaedische Industrie Besitz-Und Verwaltungs-KommanditgesellschaftInventors: Klaus-Peter Anhalt, Jürgen Deinert
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Publication number: 20010028132Abstract: Method for on-mold surface coating fiberglass-reinforced molded articles during their manufacture with environmentally friendly and physiologically safe thermosetting unsaturated polyester on-mold coating powders which serve as replacements for liquid gel coats. The thermosetting coating powders employed are adapted to cure at low temperatures to avoid causing thermal damage to the heat sensitive plastic molds which must be reused over and over again, and to cure in the presence of atmospheric oxygen to enable over coating with liquid fill resins and fiberglass, which constitute the bulk of the finished article, without having the fill resins bleed through the powder coating film and detrimentally affect the overall quality of the surface finish.Type: ApplicationFiled: March 16, 2001Publication date: October 11, 2001Inventors: Edward G. Nicholl, Navin B. Shah
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Patent number: 6235228Abstract: Method for on-mold surface coating fiberglass-reinforced molded articles during their manufacture with environmentally friendly and physiologically safe thermosetting unsaturated polyester on-mold coating powders which serve as replacements for liquid gel coats. The thermosetting coating powders employed are adapted to cure at low temperatures to avoid causing thermal damage to the heat sensitive plastic molds which must be reused over and over again, and to cure in the presence of atmospheric oxygen to enable over coating with liquid fill resins and fiberglass, which constitute the bulk of the finished article, without having the fill resins bleed through the powder coating film and detrimentally affect the overall quality of the surface finish.Type: GrantFiled: April 8, 1999Date of Patent: May 22, 2001Assignee: Morton International, Inc.Inventors: Edward G. Nicholl, Navin B. Shah
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Patent number: 6222007Abstract: High quality films, preimpregnated tape (prepegs) and composites have been fabricated from polyimide precursor “salt-like” solutions. These “salt-like” solutions have a low viscosity (5,000 to 10,000 cp) and a high solids content (50-65% by weight) and can be coated onto reinforcing fiber to produce prepegs with excellent tack and drape at 12-15% residual solvent (˜4-6% water from thermal imidization reaction). The processing of these types of prepegs significantly overcomes solvent removal problems and allows excellent fiber wet out. In addition, the physical characteristics of the polyimide precursor “salt-like” solutions permits processing into high-performance materials through the use of standard prepregging and composite fabrication equipment. The resultant composites are of high quality.Type: GrantFiled: May 29, 1998Date of Patent: April 24, 2001Assignee: The United States of America as represented by the National Aeronautics and Space AdministrationInventors: Roberto J. Cano, Erik S. Weiser, Terry L. St. Clair, Yoshiaki Echigo, Hisayasu Kaneshiro
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Patent number: 6200507Abstract: Cremated ash remains of a deceased individual may be combined in a suitable resin material to fill a statuary urn or to fill a shell as a memorial to the decedent. The sculptural urn or shell may be molded of a resin in any desired shape. By use of a suitable resin with additives, the urn or shell may be molded with surface finishes such as marble, bronze, metal, ceramic, stone, and wood. The same resin may be mixed with the cremated ashes to fill the shell and to top off any remaining space. After the material cures the resulting sculpture may be place in a garden, shrine, or elsewhere as a permanent memorial.Type: GrantFiled: February 16, 1999Date of Patent: March 13, 2001Inventor: Nancy B. Dennis
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Patent number: 6180053Abstract: Process for manufacturing a blown film essentially consisting of an aliphatic polyester, according to which: (1) the polyester is synthesized from at least one cycloaliphatic ester, with the intervention of an initiator comprising at least one metal trialkoxide and/or metal tetraalkoxide, in an extrusion device; (2) the polyester is extrusion blow-moulded, immediately after it has been synthesized in the said extrusion device, fitted for this purpose with an extrusion blow-moulding die, with a swelling ratio of at least 2.5. The invention also relates to a film essentially consisting of an aliphatic polyester, which can be obtained according to the process of one of the preceding claims, in which the modulus of longitudinal elasticity (LE) and the modulus of transverse elasticity (TE) and the longitudinal shrinkage (LS) and transverse shrinkage (TS), these shrinkages being measured at a temperature about 5° C.Type: GrantFiled: May 15, 1998Date of Patent: January 30, 2001Assignee: Solvay S.A. (Societe Anonyme)Inventors: Ivan Claeys, Claude Dehennau