Abstract: A method of producing gypsum building board, comprises allowing a layer of an aqueous gypsum slurry to set so as to form a board, in which the improvement comprises mixing the gypsum slurry with an aqueous foam produced by foaming water containing at least one non-ionic alkylpolysaccharide foaming agent of the general formula (I) R—O-(G)x??(I) where: R represents a linear or branched alkyl group having from 6 to 20 carbon atoms; G represents a reducing saccharide moiety connected to R via an ethereal O-glycosidical bond; and x is 1 to 10.

Abstract: A method and mould for forming upwardly extending protrusions on a wall masonry block during moulding of the block. The method including pouring a flowable concrete mixture into a lower mould to form a body of said wall masonry block, applying a head shoe to form an upper section of said wall masonry block, the head shoe including a first mould portion for forming an upper bedding face of said block and a second mould portion for forming at least one protrusion extending upwardly from the upper bedding face, the head shoe being shaped to improve the flow of said concrete mixture into the second mould portion during compression of the block, and removing the masonry block from the mould.

Abstract: In one aspect, the invention is directed to an efficient and economical process for dispersing fiber in water and clay. In another aspect, the process for dispersing fiber in water and clay is used in methods of making fiber reinforced composite products. In another aspect, the dispersed fiber/clay material is formulated to make products which include, but which are not limited to, fiber reinforced thermoplastic composites, paperboard products, kitty litter, and/or lightweight building materials comprising fiber.

Abstract: The present invention relates to an apparatus and method for forming molded tapered products, such as masonry blocks, whereby high quality finished products are removed from their mold without the need for complex machinery for demolding. The mold may include one or more mold cavities having one or more movable cavity walls. The movable cavity walls may include an end liner having a planar product forming surface capable of moving from a vertical position to an angled position. Tapered products may be formed by moving the mold towards a pallet so that the pallet engages with the end liner and causes the end liner to move from the vertical position to the angled position. Moldable material may then be introduced into the mold cavity and may be allowed to remain in the mold cavity until it is self-sustaining. The mold may then be moved away from the pallet such that a molded product remains on the pallet, thereby allowing the end liner to move from the angled position to the vertical position.

Abstract: A method for forming a clay slab includes providing a frame, a first panel supported on the frame in a vertical orientation and a second panel supported on the frame in a vertical orientation, with the first panel and the second panel defining a gap therebetween. The method further includes positioning a block of clay adjacent the gap defined by the first panel and the second panel, moving at least one of the first panel and the second panel from an initial position to an intermediate position to draw the block of clay between the first panel and the second panel and thereby form the clay slab, and moving at least one of the first panel and the second panel from the intermediate position back to the initial position to withdraw the clay slab from between the first panel and the second panel.

Abstract: The present invention provides a technique for prolonging the working time and setting time of a calcium sulfate hemihydrate paste by mixing calcium sulfate hemihydrate powder with an aqueous solution containing phosphate ions, so that the paste is suitable for operation and the resultant hardened calcium sulfate dihydrate block from the paste has an improved mechanical strength.

Abstract: The present invention provides a bone cement formula having a powder component and a setting liquid component, wherein the powder component includes a calcium sulfate source and a calcium phosphate source with a weight ratio of the calcium sulfate source less than 65%, based on the total weight of the calcium sulfate source and the calcium phosphate source, and the setting liquid component comprises ammonium ion (NH4+) in a concentration of about 0.5 M to 4 M, wherein the calcium phosphate source includes tetracalcium phosphate (TTCP) and dicalcium phosphate in a molar ratio of TTCP to dicalcium phosphate of about 0.5 to about 2.5, and the calcium sulfate source is calcium sulfate hemihydrate (CSH), calcium sulfate dehydrate (CSD), or anhydrous calcium sulfate.

Abstract: A wall forming system utilizing flowable construction materials, such as concrete, to construct walls. The wall forming system comprises a wall forming assembly and a method of using the wall forming assembly to form a wall having an exterior surface. The wall forming assembly comprises an exterior first panel having a plurality of openings therethrough and a second panel. The first and second panels are spaced apart so that a cavity is formed therebetween for receiving the flowable construction material. The flowable construction material will flow through the openings in the exterior panel and extend beyond an external surface of the exterior panel. The flowable construction material that extends beyond the external surface can be shaped to form various surface designs. The exterior panel and the flowable construction material become a substantially monolithic structure when the flowable construction material is set.

Abstract: A method of applying a cement mixture to an exposed matrix of intersecting walls of a honeycomb body is disclosed. The method may include the steps of providing an applicator, feeding the cement mixture into applicator, forcing the cement mixture to exit the applicator with a substantially uniform velocity, while depositing the cement mixture on the exposed matrix of the honeycomb body.

Abstract: A gypsum slurry is described that includes water, a hydraulic component comprising at least 50% calcined gypsum by weight based on the dry weight of the hydraulic component, foam, a defoamer and a polycarboxylate dispersant. In some embodiments of the invention, the defoamer is combined with the dispersant prior to being added to the gypsum slurry. The defoamer and dispersant can be added as a physical mixture, wherein the defoamer is attached onto the dispersant polymer, or a combination thereof. A gypsum building panel is made from the gypsum slurry.

Abstract: Provided herein are compositions and methods including hydraulic cement, supplementary cementitious material, and/or self-cementing material. Methods for making the compositions and using the compositions are provided.

Abstract: Molds and processes that permit high-speed, mass production of retaining wall blocks having patterned or other processed front faces, as well as retaining wall blocks formed by such processes. The invention permits the front face of the block to be impressed with a pattern or otherwise directly processed, to allow the formation of pre-determined block front faces, while at the same time facilitating high-speed, high-volume production of blocks. A mirror image of the desired pattern can be created on a stripper shoe by selecting a desired three-dimensional surface from a naturally occurring or man made object and digitally scanning the selected three-dimensional pattern to create scanned data. The scanned data can then be used to machine a face of the stripper shoe that is the mirror image of the selected pattern.

Abstract: An apparatus for molding dry cast products having a textured side surface is disclosed. The apparatus comprises an open compartment for receiving a dry concrete mixture and a plurality of walls laterally enclosing the compartment. At least one of the walls has a multilevel surface with a plurality of sections in an overhanging relationship with each other and transitional curvilinear steps bridging adjacent one of the sections to impart a textured side surface resembling a natural rockface and allowing stripping of the dry cast products from an open bottom side of the compartment.

Abstract: Compositions for fabricating architectural works wherein the compositions utilize one or more cement materials, additives, fibers and recycled glass. Exemplary cement materials include Portland cement, calcium aluminate, fly ash and/or E glass. Exemplary additives include boric acid, citric acid, lithium, plasticizer and/or methylcellulose ethers. Exemplary fibers include polyvinyl alcohol (PVA) and/or micro-fibers. Crushed recycled glass is used as an aggregate or non-reactive material. Other ingredients may be used including: sodium hydroxide, potassium hydroxide and hydrated lime to alter the PH; ferrous sulfate, mono-potassium phosphate, or manganese carbonate and magnesium sulfate as color enhancements; and/or pozzolans (Vcas) to neutralize the ASR efflorescence.

Abstract: The present invention describes an improved building material composition, useful for example as a fire door core. The building material of the present invention is prepared by compressing an aqueous mixture of expanded perlite and a fast setting, cementitious composition consisting essentially of a hydraulic cement, preferably Portland cement, and a pozzolan additive selected from the group consisting of metakaolin, VCAS and mixtures thereof, and preferably also includes an organic binder and a fibrous reinforcement.

Abstract: A process for manufacturing concrete bodies at elevated temperatures including the steps of providing pre-selected amounts of cement, aggregate and water where the temperature of at least the aggregate and more likely the cement and water are heated to a temperature between about 32° C. and 45° C. The heated amounts of cement, aggregate and water are mixed at an elevated temperature within the aforementioned range and a set retarding, water reducing admixture added. The mixing is continued and the hot mixture including the set retarding, water reducing admixture is cast at an elevated temperature within the same range to provide a concrete body form or structure with improved short and long-term compressive strengths.

Abstract: A method and an apparatus for the manufacture of concrete pipes (2) made of an outer layer and having an inner layer of greater density in surface structure is described. The inner layer is applied by an applicator in a mould (1) having both outer (3) and inner (4) mould parts. The applicator is formed by an inner mould part or core (4) or by an applicator unit in immediate connection with the core (4). The applicator applies the inner layer simultaneously or immediately following vibration of the concrete forming the pipe. The inner layer is applied during movement of the inner mould part or core (4) in its longitudinal direction, the core having one or more supply openings (14) provided along the circumference of the core (4) at the upper end of the core (4) for supplying a further material of greater density to form the inner layer.

Abstract: A subject of the invention is a mixture comprising in proportions by mass: from 0.4 to 4%, preferably from 0.8 to 1.7%, of materials in the ultrafine particle size range, constituted by particles with a D90 smaller than 1 ?m and/or with a specific BET surface area greater than 6 m2/g; from 1 to 6%, preferably from 2 to 5%, of Portland cement; from 8 to 25%, preferably from 12 to 21%, of materials in the fine particle size range, constituted by particles the D10 and the D90 of which are comprised between 1 ?m and 100 ?m and with a specific BET surface area of less than 5 m2/g, different from the cement; from 25 to 50%, preferably from 30 to 42%, of materials in the medium particle size range, constituted by particles the D10 and the D90 of which are comprised between 100 ?m and 5 mm; and from 25 to 55%, preferably from 35 to 47%, of materials in the larger particle size range, constituted by particles the D10 of which is greater than 5 mm.

Abstract: A vibrating flexible smoothing sheet or shroud disposed transversely of a direction of travel of a formed fiber panel including gypsum-cementitious slurry and embedded chopped fibers. The sheet is used to smooth the surface of the panel as it exits a fiber embedment station of a structural cementitious panel production line to remove grooves and other non-uniform surface imperfections to reduce the need for costly finishing after the panels are cured and cut to size. The flexible sheet is designed to float over the surface of the formed panel without tearing or otherwise damaging the surface of the heavily fiber reinforced surface layers of the panel. The vibrating sheet is pivotally mounted on the side dams of the web production line so it can float over the panel surface during use, but be raised off the line when not in use.

Abstract: Concrete structures and components with improved strength and toughness. A uniform mix of first constituents comprises: cement of Blaine fineness of 280-360 m2/kg; sand at a mass ratio of 0.75-1.25 of the cement; silica fume at a mass ratio of 0.15-0.4 of the cement; silica flour at a mass ratio of 0.15-0.3 of the cement; and microinclusions at a mass ratio up to 0.35 of the cement. This is then mixed with a blend of second constituents comprising a specified amount of an HRWRA and an amount of water at a mass ratio of 0.2-0.35 of the cement. This is mixed sufficiently to form a uniform cement-based paste to which an amount of macrofibers at a mass ratio of up to 0.35 of the cement is added to yield a uniform product. Nanoinclusions may be added to improve crack resistance and increase density.

Abstract: A premixed material is obtained by tempering a castable refractory powder composition comprising refractory aggregate, fine refractory powder, alumina cement, a dispersing agent and an alumina cement hydration stopper with water. The hydration stopper is acidic in a state of an aqueous solution. The amount of the hydration stopper is controlled such that the premixed material has a pH of 2 to 7. Immediately after adding and mixing an alumina cement hydration starter to the premixed material, the resultant mixture is cast into a mold. The addition of the hydration starter can be carried out 5 days or more after the production of the premixed material.

Abstract: In a method for manufacturing slabs which are thin (10-30 mm) and broad, a cement mix comprising water, cement and a fluidizer is mixed with inert stone aggregate having a controlled particle size. The resultant mix is deposited in a predetermined thickness onto a temporary support and subjected to vacuum vibrocompression. The slab thus formed is subjected to the steps of setting and hardening by means of curing, enclosing it between two thin sheets of plastic impermeable to water vapor which are hermetically sealed along their edges. The method envisages specific measures as regards the method of mixing performed during the steps of preparation of the cement mix and mixing of the cement paste with the stone aggregrate. Other improvements concern the components of the cement paste as well as the order of introduction of the aggregate during mixing with the latter.

Abstract: A method of making durable, non-vitrified masonry units comprising fly ash, the method comprising mixing fly ash comprising a minimum of 15% CaO by weight and no more than about 10% loss on ignition, water, and an air entrainment agent to form a fly ash mixture; compacting the fly ash mixture in a shaping device by applying pressure of at least 1000 psi to the fly ash mixture; and curing the compacted fly ash mixture to cause the mixture to harden and gain strength.

Abstract: A permeable paver that has water permeability of on average about 1 inch per hour and compressive strength of an average of about 8000 psi, the paver manufactured by forming a mixture comprising blast-furnace slag, sand, gravel and portland cement into predetermined sizes, shapes and colors as desired utilizing a hydraulic-type or equivalent compacting block forming machine.

Abstract: Provided is a high manufacturing method of the production efficiency for a wood cement board that has a pattern of recesses and projections. The method for making a wood cement board having a pattern of recesses and projections on its surface, comprising: dispersing a raw material mixture onto a template provided with recesses corresponding to the portions of the wood cement board on which projections are formed, while conveying the template, thereby forming a mat; pressurizing only a section of the mat raw material mixture that is layered on the recesses of the template from above; leveling the surface of the partly pressurized mat; and pressing the resulting mat and the template together, followed by hardening and curing.

Abstract: Synthetic fibers, such as polypropylene fibers, are mixed in a shrinkage compensating concrete to provide restraint in lieu of conventional steel reinforcement used in a shrinkage compensating concrete. While the synthetic fibers have a low elastic modulus and low strength, they act to restrain expansion of the concrete in the same way that conventional steel rebar does. In addition, only a small amount of the synthetic fibers are needed to restrain the expansion. As a result, shrinkage compensating concrete can be used in more varied applications, and can be provided more quickly, easily and inexpensively. Construction time requirements and expenses of concrete structures are correspondingly reduced.

Abstract: Method of producing binders for building and building products consisting of a material of man-made and/or natural origin from solid products produced by burning of solid fuels, metallurgical slag, ground fire products, products from burnt out mining deep stock piles, glass production waste, ceramic production waste, brick and concrete construction waste, heat-activated clays, low-crystalline pyroclastic rocks, sedimentary laterite, bauxite, opalolite, allophanolite, diatomite rocks, limestones and claystones and clays. The material is subjected to physical treatment consisting in action of a power pulse, during which mechanical energy Etk is passed on to the particles of the material treated by acting of a force of the size from 50 to 3.105 N, related to 1 g of the treated material during a very short time in the range from 1.10?6 to 1.10?2 s or more.

Abstract: A plant and method for the manufacture of cementitious products, viz. cast concrete roof tiles (T), the plant comprising a mixing station (2) where the constituents of a cementitious composition, less an air entraining agent, are admixed under atmospheric pressure and further mixed under a partial vacuum of 200 to 340 mBar after the addition of an air entraining agent, the plant also comprising a molding station (4) where the tiles (T) are cast in a gang-mold (6) before being cured in a conventional autoclave for up to 10 hours at 45 degrees C. The cured concrete roof tiles (T) are de-molded after curing and conveyed to a surface preparation zone (12) where a primer coat of a water based epoxy and a surface coating of a water based emulsion paint are applied to at least an upper surface in use of the cast concrete roof tiles (T). The admixed cementitious composition has a Ford Cup flow of between 40 and 60 seconds and a slump test of between 180 and 220 mm.

Abstract: A protective element for a breakwater or wave-retarding construction comprises a body that has at least two opposing projections. The projections are on either side of a flat base and extend transversely thereto. The periphery of the base is non-circular, so that rolling of the protective element under the influence of the beating of the waves is resisted.

Abstract: The problems to be solved by the invention are to provide a fiber reinforced cement composition for obtaining a fiber reinforced cement product which is inexpensive and economical, and to provide pushing forward disposal of defective products. Namely, the fiber reinforced cement composition comprises a hydraulic inorganic material, a siliceous material, a woody reinforcement, a finely dividing fiber reinforced cement product and/or a finely dividing intermediate of fiber reinforced cement product which is produced by said raw materials.

Abstract: A mold and a process for non-manually cleaning the undercut along the bottom edge of the division plate which with a pallet under the mold defines a lip-forming subcavity results in a dry cast concrete block with an inside lip radius that is controlled to be within certain tolerances. Non-manually cleaning the undercut during the molding process can include spraying a jet of fluid, such as compressed air, at the undercut.

Abstract: A construction apparatus including a body having a front, a rear, a top, a bottom, and first and second opposite sides. The front has a front surface having a plurality of block images configured to generally depict a plurality of courses of blocks, each of the courses having a respective course width. The first and second sides have generally complementary step shapes including at least two rises and at least one run between the rises, each rise being about equal to one of the course widths or a sum of a plurality of the course widths.

Abstract: Building wall panels having lightweight hollow core interiors include embodiments suitable for interior and exterior walls, for industrial, commercial or residential buildings, and for multi-story structures. Various methods for making these wall panels are disclosed, including the formation of cast gypsum firewall layers.

Abstract: A building element may be formed from a first cementitious mixture and a second cementitious mixture containing a photocatalytic cementitious mixture. The first cementitious mixture and the photocatalytic cementitious mixture may be co-formed into a shaped uncured two layer monolith having a base layer of the first cementitious mixture and a top layer of the photocatalytic cementitious mixture. The shaped uncured two layer monolith is then cured. The resulting building element may be algae-resistant.

Abstract: A fiber reinforced cement composition having the following raw material composition is provided to manufacture a fiber reinforced cement product which is excellent in bending strength, dimension stability, handling property, flexibility performance, and processability such as nail performance, as well as to provide a process for manufacturing the product. Namely, the fiber reinforced cement composition comprises a hydraulic inorganic material, a siliceous material and a woody reinforcement in a mass ratio of CaO to SiO2 contained in the hydraulic inorganic material and the siliceous material in the raw materials in a range of from 23:77 to 60:40.

Abstract: A concrete product is produced by providing red dune sand having a particle size of 45 microns or less and mixing the red dune sand with hydraulic cement in a ratio of about 30% of the cement being replaced by the red dune sand. The cement and red dune sand are then mixed with fine and course aggregate, water and a superplasticizer and cast after pouring into a mold cavity. Then within 24 hours of casting, the cast article is steam cured for 12 hours under atmospheric pressure, demolded and placed in an auto clave at 100% humidity. The temperature in the auto clave is raised to 180° C. within one to two hours and maintained at that temperature for 4 to 5 hours. The temperature also increases the pressure to about 10 bars. The pressure is released to reach atmospheric pressure within 20-30 minutes and the temperature reduced gradually, so that the article can be removed.

Abstract: A method of producing a paperless gypsum/fiber board from a mixture including reinforcing material particles, calcined gypsum and water. A headbox feeds the mixture into a panel forming area (forming pond) over the upper surface of a continuous forming fabric to form a panel mat. Also, a reinforcing mesh is fed over a transverse member, located over a portion of the forming fabric, and into the forming pond to embed the mesh in the mixture. At least a portion of a downstream end of the transverse member is under a downstream portion of the headbox or downstream of the headbox. Then the panel mat is pressed, the calcined gypsum of the pressed panel mat is rehydrated, and the resulting board is dried.

Abstract: Self-reducing, cold-bonded pellets and a method for their production for smelting a great variety of steels, including blast furnace iron-making, non-blast furnace iron-making, and all sorts of steelmaking in steel smelting furnaces, etc. The self-reducing, cold-bonded pellets comprise iron ore concentrate, carbonaceous reducing agent, and finely divided Portland cement clinker with special requirements as binder. The components are combined together to form a mixture. Pellets are produced when the mixture is placed into a balling disc or rotating drum and water is added. Pellets with predetermined size normally ranging from about 8-16 mm are obtained by using roller screens. The pellets are then continuously placed into a curing device. Inside the curing device, the pellets will then be hydrated and carbonated by using hot gases containing carbon dioxide with a temperature range of about 100-300° C. Thereafter, after drying, the dried pellets are discharged from the curing device and will be ready for use.

Abstract: A moisture resistant gypsum-based product, e.g., a gypsum board, is made by adding a small amount of a siloxane to the aqueous slurry used to make the gypsum-based product along with a small amount of a dead burned magnesium oxide catalyst to enhance the curing of the siloxane. In the preferred embodiment, the siloxane is formed into an aqueous emulsion in situ with no chemical emulsifier.

Abstract: Concrete bricks are produced that have a similar appearance to natural or clay brick. Each brick includes internal colors throughout the brick that mimic the flashings in natural or clay brick.

Abstract: A composition for synthetic structural building materials, such as lumber, and the method used to fabricate such building materials. The synthetic building materials are molded from a composition that contains cement, sand, curing agents, water, synthetic fibers, a low density particulate and a curable polymer. These ingredients and a few others are mixed in unique ratios to produce a synthetic material that mimics the strength, flexibility, and weight of natural wood. The composition cures with time. Prior to curing, the composition is molded into the form of structural building materials, such as framing lumber and planks. Depending upon the intended purpose of the building materials, the composition can be molded around reinforcement elements that internally strengthen the composition when it is cured. The final piece of structural building material has a weight, strength and flexibility comparable to wood, yet is resistant to rot and insects.

Abstract: A casted concrete stone having opposed parallel surfaces formed in a mold and wherein the opposed parallel surfaces have a molded textured surface. The concrete stone is fabricated by a dry-cast concrete mold wherein a profiling plate is provided with mold bottom wall formations each having a textured outer surface. A bond release film or spray or permanent coating is provided on the textured outer surface of the mold bottom wall formations. Mold forming side walls are disposed about the mold bottom wall formations. After the mold is filled with a dry-cast concrete mixture a top plate, having mold top wall formations, is disposed over the mold forming side walls with the mold top wall formations disposed inside respective ones of the molds to close the molds. Pressure and vibration is applied to compact the dry-cast concrete whereby to form a dry-cast concrete stone with opposed molded textured surfaces.

Abstract: The invention relates to a method of controlling the quality of blocks that are produced front face-up in a mold, and verifying the accuracy of the production of such blocks, to ensure that the blocks are manufactured with consistent quality and minimal block-to-block variability. Measurement locations are formed on the front faces of predetermined blocks. By measuring the distances between the measurement locations and the rear faces and comparing with a target distance, any variation provides an indication that the blocks are not being properly formed. The process variables, such as the alignment of the compression head and/or the pressure plates to the mold, can then be adjusted accordingly.

Abstract: A method for preparing a high-temperature heat-resistant composite material by combining a mixture of submicron alumina powder and submicron silica powder, wherein the ratio of alumina to silica is from about 4:1 to about 5:1, submicron Group II metal oxide powder, and a Group I metal silicate solution to form a slurry, wherein the weight of the Group II metal oxide powder is an amount corresponding to about 5% to about 10% of the weight of the silicate solution; contacting reinforcing high-temperature resistant fibers with the slurry to form a composite precursor composition; and curing the composition at a temperature sufficient to produce the high-temperature heat-resistant composite material capable of resisting temperatures up to about 1400° C. Composite materials prepared according to the method and articles incorporating the material are also presented.

Abstract: Producing a structure, in which: building elements are juxtaposed so as to define a space between said building elements; a joint compound composition is mixed with water so as to obtain a joint compound; said space is filled with said joint compound composition, without using a tape; and said joint compound is left to harden, wherein said joint compound composition includes: a) 50 to 60% of calcium sulphate hemihydrate; b) 5 to 15% of an organic binder in powder form; and c) 0.05 to 0.2% of a water repellent selected from the group consisting of oleic acid, stearic acid and their alkali metal or alkaline-earth metal salts.

Abstract: This invention is a fiber reinforced cement composition comprising the following raw materials: a hydraulic inorganic material, a siliceous material, and a woody reinforcement wherein the siliceous material is a mixture of an average particle size of not less than 15 um and not more than 50 um which is burned ash of coal and/or rhyolite and an average particle size of not less than 1 um and not more than 15 um which is burned ash of coal and/or rhyolite.

Abstract: An industrial waste byproduct from a titanium metal or a titanium dioxide production process can be utilized as a partial cement replacement. In some embodiments, the byproduct can comprise a byproduct from the production of titanium dioxide pigment from a sulphate process or from a chloride process. The cement can be used to make concrete and other cementitious material products for structural and non-structural uses, for example, grout, mortar, gunite, stucco, masonry, decorative stonework, bricks, blocks, roof tiles, floor tiles, cobblestones, pavers, combinations thereof, and the like.

Abstract: A system for forming thin-wall pre-cast concrete forms and structures, using vertical casting and slip-form techniques to partition wet concrete into separate thin-wall sections, the system being particularly useful for fabricating pre-cast concrete column forms having a composition and vertical consistency substantially the same as the integral poured concrete core of the finished concrete column.

Abstract: The present invention provides for a refractory aggregate composition comprising an improved calcium aluminate clinker having the formula CnAx wherein C is calcium oxide and A is aluminum oxide, wherein n is an integer from about 1 to about 12, wherein x is an integer from about 1 to about 24, and wherein said clinker has from zero to less than about fifty weight percent C12A7. Analogs, derivatives and hydrates of the improved calcium aluminate clinker are provided. A refractory composition and a sprayable refractory composition are disclosed comprising the improved calcium aluminate clinker. A method for improving the insulating character and/or penetration resistance of a liner in contact with molten aluminum in an aluminum manufacturing process or during aluminum transport is provided.

Abstract: Bonded aggregate compositions such as concrete, concrete repair products, high temperature refractories, high temperature insulation and fire resistant insulation are made from an aqueous solution of phosphoric acid and a separate, storable dry mixture of suitable aggregate, monocalcium phosphate, and calcium in the form of calcium aluminate cement or calcium oxide. The proportion of wet to dry constituents is variable so as to select the working time and strength of the aggregate composition, typically on the order of ten to fifteen minutes. The mixture of the preferred dry constituents, and the binder to be mixed with the aggregate to yield the preferred dry mixture, are also disclosed.