Burning Out Components To Form Pores Patents (Class 264/44)
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Patent number: 5063007Abstract: The process for manufacturing an open pore foam body with three dimensional ceramic network, in particular as a filter for the treatment of hot gases or as a catalyst substrate, has as its starting material a block of open pore plastic foam. This is impregnated at least once with a ceramic suspension, freed of excess ceramic suspension and heated to a temperature below the melting point of the plastic, then finally burnt off at a temperature at which the ceramic sinters together. At least one plastic foam layer is impregnated, assembled into a plastic foam block with flow channels between two layers and sintered to form a Z-flow filter.Type: GrantFiled: July 18, 1990Date of Patent: November 5, 1991Assignee: Alusuisse-Lonza Services Ltd.Inventors: Jean-Pierre Gabathuler, Karl-Ludwig Eckert, Peter Kaser, Albert Maurer, Anton Fischer
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Patent number: 5059366Abstract: The fiter membrane comprises a porous structure made of a material selected from sintered ceramics, sintered metals, microporous carbon, and microporous glass, and is characterized by the fact that its entire external surface, including the inside surface of the pores in the structure, is covered with a thin and continuous film of carbon or of an oxide. In a sintered aluminum membrane, the surfaces of pores are coated with a dense and continuous thin layer of zirconia which prevents the surfaces from being degraded in service. In the figure, curve 3 shows how the throughput of a membrane without a zirconia layer falls off over time, while curve 4 shows little change in the same membrane having such a layer.Type: GrantFiled: May 7, 1990Date of Patent: October 22, 1991Assignee: Societe des Ceramiques TechniquesInventors: Stanislas Galaj, Marie-Paule Besland, Alain Wicker, Jacques Gillot, Raymond Soria
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Patent number: 5053217Abstract: Pro-liposome compositions comprise membrane lipids such as lecithin or distearyl dimethylammonium chloride, water-miscible solvents such as ethanol, optionally a minor proportion of water, and optionally fatty acid esters and drugs. In addition to excess water they spontaneously form dispersions of liposomes having high void volumes and high drug entrapment ratios. Aerosol compositions are presented in a volatile liquid propellant. On being sprayed they form an aerosol of droplets which, on contact with aqueous media, spontaneously form liposome dispersions.Type: GrantFiled: June 8, 1990Date of Patent: October 1, 1991Assignee: Phares Pharmaceutical Research NVInventor: Steven Lehigh
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Patent number: 5049324Abstract: A method of making an insulating furnace lining by forming a reticulated ceramic having interconnected webs defining a plurality of interconnected pores and a plurality of fibers distributed within substantially all of the pores in a selected volume of the reticulated ceramic. The reticulated ceramic is arranged to form at least a portion of a furnace lining. The reticulated ceramic and the fibers may be oxides, ceramics, carbides, nitrides, silicides, borides, carbon and mixtures thereof. The fibers form a batt which fills at least a portion of the pores.Type: GrantFiled: July 28, 1989Date of Patent: September 17, 1991Assignee: Hi-Tech Ceramics, Inc.Inventors: Jeffrey R. Morris, William E. Meinking
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Patent number: 5045511Abstract: Ceramic bodies suitable for use in the filtration of molten metal are formed by immersing a porous organic substrate material in an aqueous thixotropic slurry containing yttria, zirconia and alumina; expelling excess slurry; drying the impregnated material; and heating to an elevated temperature to burn off the organic material and sinter the ceramic materials. The resulting zirconia-alumina ceramic bodies have from about 5-80% of the zirconia in a monoclinic phase and the remainder of the zirconia essentially in a stabilized cubic phase due to the yttria. The ceramic bodies thus produced have excellent strength, density, and thermal shock resistance properties.Type: GrantFiled: February 26, 1990Date of Patent: September 3, 1991Assignee: Alusuisse-Lonza Services, Ltd.Inventors: Paul A. Bosomworth, Cinta M. Kelzenberg, Kenneth R. Butcher
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Patent number: 5041248Abstract: A thermoplastic ceramic molding composition comprised of about 40 to 70 volume percent of a binder, consisting essentially of an organic acid containing from 12 to 26 carbon atoms per molecule and a polyisobutylene polymer having a molecular weight between about 8,700 and 135,000, and about 30 to 60 volume percent of a ceramic powder is disclosed. The molding composition can be thermoplastically extruded into elongate ceramic bodies that can be uniformly elongated many times the original length of the ceramic body to form, for example, very fine diameter fibers or filaments suitable for sintering into a polycrystalline ceramic fiber or filament having a very fine diameter.Type: GrantFiled: January 28, 1991Date of Patent: August 20, 1991Assignee: General Electric CompanyInventors: Gary M. Renlund, Curtis A. Johnson
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Patent number: 5033939Abstract: Shaped parts are formed from a powder having the desired chemistry of the finished part by mixing the powder with a thermosetting condensation resin that acts as a binder. The resin may be partially catalyzed, or additives or surfactants added to improve rheology, mixing properties, or processing time. Upon heating, the inherently low viscosity mixture will solidify without pressure being applied to it. A rigid form is produced which is capable of being ejected from a mold. Pre-sintered shapes or parts are made by injection molding, by using semi-permanent tooling, or by prototyping. Binder removal is accomplished by thermal means and without a separate debinding step, despite the known heat resistance of thermosetting resins. Removal is due to the film forming characteristic of the binder leaving open the part's pores, by providing oxidizing conditions within the part's pores as the part is heated, and by insuring that the evolving resin vapor diffuses through the pores by heating the part in a vacuum.Type: GrantFiled: October 29, 1990Date of Patent: July 23, 1991Assignee: Megamet IndustriesInventor: Gregory M. Brasel
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Patent number: 5030396Abstract: A process for the production of a ceramic shaped implant having a porous layer with interconnected spherical pores on the surface thereof includes the steps of disposing a porous element having a three dimensionally connected structure made of a heat decomposable material, in which structure, adjacent units share connecting portions and voids, in contact with or adjacent to a ceramic substrate, and filling a space between the ceramic substrate and the porous element and the voids of the porous element with a slurry comprising ceramic powder made from the same material as the ceramic substrate, and then heating to sinter the porous material and the ceramic substrate together.Type: GrantFiled: August 21, 1989Date of Patent: July 9, 1991Assignee: Sumitomo Chemical Company, LimitedInventors: Kenji Saita, Susumu Miyazaki
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Patent number: 5008220Abstract: There is disclosed a porous inorganic material suitable for use as a support for immobilizing biological macromolecules and which comprises a 3-dimensional network of defect aluminium-silicon spinel, said network defining an interconnecting array of pores predominantly in the size range of from 100 to 1000 .ANG..A process for preparing the porous inorganic material is also disclosed.Type: GrantFiled: February 15, 1989Date of Patent: April 16, 1991Assignee: ECC International LimitedInventors: Alan J. Brown, Roger James, Nigel P. Glasson
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Patent number: 5001088Abstract: A porous form body is produced of sinterable SiC-powder by forming a suitable suspension of said SiC-powder and then treating the suspension to convert it into droplets and the droplets into a granular material in which the granules are substantially larger than the particles of SiC-powder. The granular material is then formed into a green body, e.g. by spraying the granules onto a negative mold of the form body or slip-casting or the like. The green body is then sintered whereby the resulting porosity in the final form body provides the form body with low drag.Type: GrantFiled: October 25, 1988Date of Patent: March 19, 1991Assignee: MTU Motoren- und Turbinen-UnionInventors: Holger Hauptmann, Gerhard Andrees
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Patent number: 4990398Abstract: A method for producing a foam glass tile having a surface skin comprises the steps of molding a material consisting essentially of a vitrifiable mineral and a foaming agent into a tile-like block; coating the block with a thin layer comprising a vitrifying agent for the mineral material; heating the coated block to a temperature sufficient to fuse the coated layer whereby the molten vitrifying agent permeates into the coated surface of the block; and further heating the coated block to a temperature sufficient to soften the vitrifiable mineral. The method may further include the step of forming a thin layer comprising a vitrifiable mineral and a lesser amount of a foaming agent between the tile-like block and the vitrifying agent layer, followed by firing. The foam glass tile formed by the above method comprises a foam glass tile body and a rigid reinforcing vitrified surface skin, the surface skin being integrally melt-bonded onto at least a top surface of the foam glass body.Type: GrantFiled: August 23, 1988Date of Patent: February 5, 1991Assignee: Inax CorporationInventors: Katsuhisa Fukumoto, Kiyotaka Kawanishi, Ryo Nakada, Junpei Yamano
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Patent number: 4983573Abstract: There is disclosed an improved process for preparing a superconducting composition having the formula MBa.sub.2 Cu.sub.3 O.sub.x wherein M is selected from the group consisting of Y, Nd, Sm, Eu, Gd, Dy, Ho, Er, Tn, Yb and Lu; x is from about 6.5 to about 7.0; said composition having a superconducting transition temperature of about 90.degree. K.; said process consisting essentially of preparing a precursor solution, drying the solution to obtain a solid material, and heating and cooling the solid material under specified conditions to obtain the desired product. In another embodiment, a shaped superconducting MBa.sub.2 Cu.sub.3 O.sub.x article is prepared by impregnating an article of cellulose material with the precursor solution, drying the impregnated article, and heating and cooling the impregnated article under prescribed conditions to obtain the desired product.Type: GrantFiled: March 13, 1989Date of Patent: January 8, 1991Assignee: E. I. Du Pont de Nemours and CompanyInventors: John D. Bolt, Munirpallam A. Subramanian
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Patent number: 4981820Abstract: Cellular glass structures are made by foaming select silicone resins. A foaming agent is reacted together with the silicone resin to form a foam that carries the resin as a continuous separate phase distributed throughout the foam. The foaming agent is removed by decomposition, and the remaining silicone resin is crosslinked to retain the foamed structure. The silicone resin is then heated in a non-oxidizing atmosphere at a temperature that will pyrolize the resin. During pyrolysis, the resin densifies to foam a unique glass composition comprised of silicon, oxygen and carbon, where carbon is chemically bonded to silicon, but there are essentially no chemical bonds between carbon and oxygen.Type: GrantFiled: July 28, 1989Date of Patent: January 1, 1991Assignee: General Electric CompanyInventors: Gary M. Renlund, William P. Minnear, Angelo A. Bracco
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Patent number: 4973435Abstract: Porous membranes made of sintered refractory metal oxides, e.g., silica aluimina, titania, zirconia, tungsten oxide, etc., and to a process for their formation. The membranes are formed by dispersing a powder of the metal oxide in an organic polymer. The relative amount of metal oxide to polymer is such that, after the polymer has been carbonized in a subsquent step, there is a stoichiometrical excess of the oxide to carbon. The solution is then shaped to form a desired thin membrane, and the polymer is then carbonized by heating it in a non-oxidizing atmosphere. The resulting oxide/carbon product is heated to a temperature at which (a) the carbon reacts with the oxide to form a volatile sub-oxide and carbon monoxide and (b) the remaining (unreacted) oxide particles sinter together. The heating is carried out in a non-oxidizing atmosphere containing either no nitrogen whatsoever, or an amount of nitrogen less than that which results in the formation of a non-porous product.Type: GrantFiled: November 1, 1988Date of Patent: November 27, 1990Assignee: Alcan International LimitedInventors: Mukesh K. Jain, Sadashiv K. Nadkarni
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Patent number: 4970035Abstract: The invention concerns a process for the production of open pore ceramic bodies, wherewith is applied onto the contacting areas of the pores of an open pore matrix body a hardenable ceramic mass, this latter next being hardened and the matrix body being removed, there remaining behind a ceramic body of hardened, open pore ceramic mass. Before curing the ceramic mass, the matrix body is furnished with filaments extending, at least in one spatial direction, into this matrix body, which are removed during or after curing of the ceramic mass while forming appropriate channels.Type: GrantFiled: February 3, 1989Date of Patent: November 13, 1990Assignee: E. Dittrich KG "Schlussel"-ErzeugnisseInventor: Kurt Baarsch
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Patent number: 4923830Abstract: The present invention relates to ceramic bodies suitable for use in high temperature applications such as molten metal filters and kiln furniture. The ceramic bodies are formed from partially stabilized zirconia and are characterized by the presence of from about 12% to about 80% by weight zirconia in a monoclinic phase and the balance essentially in a cubic phase at room temperature. The ceramic bodies possess an excellent combination of physical properties including high temperature strength and thermal shock resistance. The invention also relates to the process for forming the ceramic bodies and the thixotropic ceramic slurry used therein.Type: GrantFiled: September 18, 1989Date of Patent: May 8, 1990Assignee: Swiss Aluminum Ltd.Inventors: Richard Everhart, Paul Bosomworth, Kenneth Butcher, Matthias Hoffmann
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Patent number: 4921633Abstract: A method of heterogeneous reaction is described, comprising reacting a water-soluble component and an oil-soluble component dispersed in the water-soluble component or an aqueous medium containing the same. This dispersion is attained by passing the oil-soluble component through the micropores of a hydrophilic material as it is introduced into the aqueous medium. This hydrophilic material can be shaped into a desired form such as a membrane and a fabric. The flow rate, reaction rate and conversion are easy to control in the present method since the particle size of the oil-soluble component can be appropriately controlled. Furthermore, the present method does not need any stirring power nor an emulsification operation, and thus is advantageous from an economic standpoint.Type: GrantFiled: August 28, 1986Date of Patent: May 1, 1990Assignee: Nippon Oil and Fats Co., Ltd.Inventors: Tadashi Funada, Jiro Hirano, Shiro Ishida, Kensuke Morioka, Sachiko Murakami
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Patent number: 4917951Abstract: Disclosed is a method of making lipid vesicles of a steroid and surfactants which do not form vesicles in the absence of the steroid. The surfactants are polyoxyethylene derivatives of 16-20 carbon ethers and amines.Type: GrantFiled: November 24, 1987Date of Patent: April 17, 1990Assignee: Micro-Pak, Inc.Inventor: Donald F. H. Wallach
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Patent number: 4891174Abstract: A process for the preparation of a micro-cellular porous ceramic body is disclosed, in which an .alpha.-olefin oligomer is added as a molding assistant to an ultrafine ceramic powder in an amount of 65 to 330% by weight based on the ultrafine ceramic powder, the mixture is kneaded, the kneaded mixture is compression-molded to give a molded body, and the molded body is fired.Type: GrantFiled: October 28, 1988Date of Patent: January 2, 1990Assignee: Agency of Industrial Science and TechnologyInventors: Yachiho Seki, Saburo Kose, Teruo Kodama
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Patent number: 4888140Abstract: The invention is a process for preparing round, fluid filled microcapsules by the simultaneous extrusion, of core and shell material from coaxially aligned and concentric extrusion nozzles into a surrounding carrier fluid moving in the direction of the extrusion wherein a surfactant having affinity with the carrier fluid is added to the carrier fluid.When the carrier fluid is an oil based carrier, a lipophilic emulsifier such as a sorbitan monoester of a fatty acid can be used.Type: GrantFiled: February 11, 1987Date of Patent: December 19, 1989Assignee: Chesebrough-Pond's Inc.Inventors: Herman W. Schlameus, Chel W. Lew, Donald M. Atkinson
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Patent number: 4888095Abstract: The invention is directed to a method for extracting water from a paper web in a paper making machine using a ceramic foam component. The component includes a supporting structure and a water permeable member is mounted on the supporting structure and is adapted to support a paper web. The water permeable member comprises a rigid mass of ceramic foam having a plurality of interconnected cells. The ceramic foam has an air permeability in the range of 10 to 1,000 cubic feet per square foot of surface area per minute and has a density of 5 to 100 lbs/cubic foot. When a pressure differential is applied to the permeable member to the paper web, moisture will be extracted from the web and passes through the permeable member.Type: GrantFiled: May 25, 1989Date of Patent: December 19, 1989Assignee: Appleton MillsInventors: Thomas G. Gulya, Gary V. Schultz, Ronald A. Arnold
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Patent number: 4885263Abstract: An improved ceramic foam filter for use in filtering molten metal prepared from a ceramic slurry containing silicon carbide and a colloidal silica binder. The filter has a solids content of at least 50% silicon carbide and at least 3% of silica.Type: GrantFiled: March 23, 1987Date of Patent: December 5, 1989Assignee: Swiss Aluminium Ltd.Inventors: Jerry W. Brockmeyer, Leonard S. Aubrey, James E. Dore
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Patent number: 4874611Abstract: A method of manufacture and the product made thereby are set forth; in the preferred and illustrated embodiment, a core including an insect poison is encapsulated by shell material melting and hardening for encapsulation. The core is primarily soybean extract mixed with DURSBAN.RTM. insecticide, an example of a toxicant. The surrounding shell or encapsulation is formed by melt extrusion of shell material. The surrounding shell encloses the core material to form an impervious shell. The surrounding shell includes soy protein as an insect attractant mixed in gelatin or poly(vinyl alcohol). A gelling agent such as carrageenan and the attractant were added to the shell. The beads formed by the melt extrusion encapsulation has sufficient shell strength to enable mechanical handling for dispensing, are resistant to water, do not bleed from the inside to the outside, and yet can be penetrated by the insect.Type: GrantFiled: December 7, 1987Date of Patent: October 17, 1989Assignee: The Dow Chemical CompanyInventors: Wilfred W. Wilson, Sotiros C. Polemenakos, J. Larry Potter, Donald J. Mangold, William W. Harlowe, Herman W. Schlameus
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Patent number: 4873207Abstract: A ceramic aggregate for concrete is made from a mixture of clay and dried organic garbage in a ratio of about three parts by volume of organic garbage to about one part by volume clay. The mixture is shaped into pancake-shaped pellets and fired at a temperature in excess of the vitrification point of the clay to cause the surface of the pellets to melt and harden the pellets.Type: GrantFiled: May 3, 1988Date of Patent: October 10, 1989Inventor: Fred Keller, Jr.
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Patent number: 4871495Abstract: A process for producing a porous ceramic filter for use in the filtering of particulates from diesel exhaust gases, and the filter so produced, in which a foamable ceramic composition based upon an aluminosilicate hydrogel binder is expanded into a self-supporting, open-celled porous body of desired shape by virtue of in situ reaction between components of the composition, and thereafter treated to substantially reduce its alkali metal content and fired to produce ceramic bonds, the process further preferably providing on the intended outlet surface of the filter a thin porous ceramic membrane layer whose pores have an average diameter less than that of the pores within and at other surfaces of the ceramic filter.Type: GrantFiled: December 2, 1987Date of Patent: October 3, 1989Assignee: The Duriron Company, Inc.Inventors: Richard L. Helferich, Robert C. Schenck
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Patent number: 4867932Abstract: A process is disclosed for making a casting nozzle wherein gas can be blown out through the outlet of the nozzle to prevent the sticking of nonmetallic impurities to the nozzle during use. Reticulate organic filaments in the form, e.g., of a net are applied around a preformed inner cylindrical refractory body having a pouring hole therein. An outer cylinder body is then formed around the inner cylinder body including the organic filaments. The entire body is then fired, whereby the organic filaments carbonize and evaporate, leaving a network of gas-permeable reticulate holes in the body. An outlet is drilled or cut in the fired body through the gas-permeable holes to the pouring holes. Accordingly, when the nozzle is in use, a blowing gas can be provided through the reticulate holes to the nozzle outlet to prevent the sticking of nonmetallic impurities.Type: GrantFiled: August 25, 1987Date of Patent: September 19, 1989Assignee: Kurosaki Refractories Co., Ltd.Inventors: Haruyoshi Kimura, Yoshitaka Hiraiwa, Hiroyuki Shiokawa, Hiroshi Nagata, Yukio Inoue
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Patent number: 4866011Abstract: The present invention relates to a ceramic foam material, preferably a ceramic foam filter, prepared by providing an open cell flexible foam having a plurality of interconnected voids surrounded by a web of the flexible foam, applying an adhesion promoting material to at least one surface of the flexible foam, impregnating the flexible foam after applying the adhesion promoting material with a ceramic slurry, drying and heating the impregnated material to remove the organic component therefrom, and firing at an elevated temperature to form the filter. In a preferred embodiment, a flocked coating is formed on at least one surface of the flexible foam prior to impregnation. The flocked coating may be formed either by first applying a solution containing an adhesive to the surface(s) and thereafter applying fibers to the surface or by applying a solution containing the adhesive and the fibers.Type: GrantFiled: May 2, 1988Date of Patent: September 12, 1989Assignee: Swiss Aluminium, Ltd.Inventors: Phillip M. Hargus, Joseph A. Mula, Myron K. Redden
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Patent number: 4855092Abstract: An electrode substrate for fuel cells with a three-layer separator and two porous single or double carbonaceous layers and processes for preparing the same. The separator includes a carbon plate and two flexible graphite sheets. The porous layer has a number of elongated holes for feeding reactant gases into a fuel cell. The elongated holes are provided near the center of the thickness in the porous single layer or in the interface between the porous double layer. The electrode substrate exhibits improved properties, such as mechanical strength, thermal and electric resistances and the like, as a fuel cell electrode substrate.Type: GrantFiled: November 18, 1985Date of Patent: August 8, 1989Assignee: Kurcha Kagaku Kogyo Kabushiki KaishaInventors: Hiroyuki Fukuda, Masatomo Shigeta, Hisatsugu Kaji, Kuniyuki Saitoh
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Patent number: 4849140Abstract: Monosized ceramic particles produced through synergistic combination of monosized latex particles and organometallic reagents in a solvent system. By swelling a poly(vinyltoluene) or other monosized latex with an appropriate organometallic reagent, decomposing the organometallic to ceramic within the latex vehicle, and then removing the latex polymer through thermolysis, monosized ceramic particles are produced. The swelling of the monosized latex particles with the organometallic reagent requires the judicious selection of a solvent system specific to the latex polymer and organic being employed.Type: GrantFiled: August 5, 1987Date of Patent: July 18, 1989Assignee: Southwest Research InstituteInventors: Stephen T. Wellinghoff, Stuart T. Schwab, Carlos D. Herrera
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Patent number: 4824615Abstract: A process for making foam-like material to form useful structures having a plurality of beads held together by a medium molded into a desired shape with interstices formed between the beads.Type: GrantFiled: September 17, 1987Date of Patent: April 25, 1989Inventor: Gregory R. Brotz
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Patent number: 4824593Abstract: An antifoam ingredient suitable for incorporation into a detergent powder comprises an antifoam material, for example, a hydrocarbon and/or a polysiloxane together with hydrophobic silica, enclosed within a matrix formed of a mixture of fatty acid and fatty acid soap.Type: GrantFiled: August 10, 1987Date of Patent: April 25, 1989Assignee: Lever Brothers CompanyInventors: Peter W. Appel, Fabrizio Bortolotti, Francois Delwel, Fredrik Hornung, Alan D. Tomlinson, Simon Willemse
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Patent number: 4814125Abstract: A fixing carrier for fixing an activated sludge employed in a sewage or waste-water treatment in whicha clay, containing kaolinite minerals, of from 10 to 40 parts by weight and a foaming agent of from 5 to 20 parts by weight are blended with a granulated blast furnace slag of from 60 to 90 parts by weight in the presence of water to prepare a wet mixture which is kneaded and shaped into a shaped mixture; andsaid shaped mixture is baked at a baking temperature of less than 950.degree. C. at maximum, with the proviso that each of a heat-up time required of said shaped mixture to reach said baking temperature for producing a baked product and a heat-down time required of said baked product to reach a temperature of up to 100.degree. C. is about one hour.Type: GrantFiled: September 18, 1987Date of Patent: March 21, 1989Assignees: Nippon Steel Corporation, Iwao Jiki Kogyo Co., Ltd.Inventors: Masahiro Fujii, Osamu Miki, Takehisa Muronaga, Takaharu Fujii
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Patent number: 4798693Abstract: A method of manufacturing an electrochemical device having an electrochemical cell including a planar solid electrolyte body and at least two electrodes disposed in contact with the solid electrolyte body. The method comprising: forming a first unfired ceramic layer on one side of an unfired structure of the electrochemical cell, the first unfired ceramic layer being given a porous structure by firing thereof; forming a second unfired ceramic layer on the other side of the unfired structure of the electrochemical cell, the second unfired ceramic layer having substantially the same property of firing shrinkage as the first unfired ceramic layer; and co-firing the unfired structure of the electrochemical cell, the first and second unfired ceramic layers. The two unfired ceramic layers may be formed on opposite sides of an unfired structure of an electrochemical cell assembly which includes plural cells, for example, an oxygen pumping cell and an oxygen sensing cell.Type: GrantFiled: August 3, 1987Date of Patent: January 17, 1989Assignee: NGK Insulators, Ltd.Inventors: Syunzo Mase, Shigeo Soejima
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Patent number: 4781873Abstract: A reversed phase analogue of at least part of a first membrane having substantially interconnected pores is formed by first filling at least some of the pores of the first membrane with a fluid that will form the analogue membrane and then forming the analogue membrane in the pores of the first membrane. The first membrane is then removed from the analogue membrane. The structure of the analogue membrane is of different morphology from that of the first membrane and the reversed phase nature arises because it is the pores of the first membrane which lead to the formation of the walls of the reversed phase membrane and it is the walls of the pores of the first membrane which lead to the formation of the pores of the reverse phase membrane.Type: GrantFiled: November 17, 1986Date of Patent: November 1, 1988Assignee: Memtec LimitedInventor: Douglas L. Ford
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Patent number: 4780433Abstract: A ceramic composition to make cement with insulating properties is a mixture of cement, ceramic grog and ceramic aggregate beads, the ceramic grog and aggregate being a mixture of clay and dried organic mulch. After firing, the resulting ceramic product is porous. When added to the cement, the porous ceramic grog and aggregate greatly enhance the insulation qualities of the resultant cement structure. The dried organic mulch is formed from pellets produced from commercially reclaimed garbage.Type: GrantFiled: January 13, 1988Date of Patent: October 25, 1988Inventor: Fred Keller, Jr.
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Patent number: 4777153Abstract: A process for producing porous ceramics with controlled microstructure. Colloidal suspensions of polymeric microspheres of a selected size and shape, and aluminum oxide particles are consolidated to form a compact. The compact is heated to decompose the microspheres to leave pores, and to sinter the compact, to form a porous ceramic body with a plurality of pores preferably substantially the same size and shape, where the pores are substantially spherical and are evenly distributed and noncontiguous throughout the ceramic matrix and with strength comparable to its dense state.Type: GrantFiled: May 6, 1986Date of Patent: October 11, 1988Assignee: Washington Research FoundationInventors: Birol Sonuparlak, Ilhan A. Aksay
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Patent number: 4755397Abstract: A wide range of materials may be encapsulated in a starch matrix by combining the material with a high temperature-stabilized pressurized dispersion of starch in the presence of salt. The temperature-stabilized starch dispersion acts as a protective colloid; upon subsequent rapid reduction of the pressure, the mixture cools and the starch polymer chains collapse upon themselves, encapsulating the core material in particulate form.Type: GrantFiled: December 24, 1986Date of Patent: July 5, 1988Assignee: National Starch and Chemical CorporationInventors: James Eden, Ralph Trksak, Robert Williams
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Patent number: 4753908Abstract: A microporous separating material is produced by a method which comprises preparing a mixture of (1) macromolecular quaternary ammonium salt having a quaternary amine linked to a water-soluble macromolecular compound and possessing basicity, (2) a polymer of a polyoxyethylene alkylvinyl monomer and a vinyl monomer possessing basicity, or (3) a polymer of a halogenide of a quaternary amine, i.e. a basic macromolecular compound, and at least one water-soluble macromolecular substance selected from the group consisting of cellulose, polyvinyl alcohol, polyethylene oxide, and polyacrylamide with a smectite type mineral, mixing the aforementioned mixture with an inorganic substance in a water-soluble state, drying the resulting mixture, and firing the dried mixture.Type: GrantFiled: December 10, 1986Date of Patent: June 28, 1988Assignees: Agency of Industrial Science, Ministry of International Trade & IndustryInventors: Kaoru Kawase, Hiroshi Sakami, Kenzi Suzuki, Shozo Iida
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Patent number: 4751013Abstract: A piezoelectric ceramic powder is, together with a binder, processed to a granulate. This granulate is mixed with a pearl polymer to a mixture. The mixture is pressed to a suitable shape, and then in a first firing step the binder and the pearl polymer are fired out. Preferably the first firing process is followed by a second firing step for sintering. Thereafter mechanical fabrication may take place, to give the end product its shape. The firing out of the pearl polymer results in a porous piezoelectric ceramic, with which, when used in an ultrasonic transducer, a high transducer effectiveness, sharp ultrasonic pulses with little edge radiation as well as a good electric and acoustic adaptation can be achieved.Type: GrantFiled: July 26, 1985Date of Patent: June 14, 1988Assignee: Siemens AktiengesellschaftInventors: Hans Kaarmann, Karl Lubitz, Jutta Mohaupt, Martina Vogt, Wolfram Wersing
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Patent number: 4746287Abstract: A fiber matrix burner and method of manufacture in which a shaped burner element is formed by accreting a slurry onto a foraminous support. The slurry is comprised of ceramic fibers, a binding agent, a vaporizable filler, and a powdered, normally non-flammable aluminum alloy having a melting point between 660.degree. C. and 1,000.degree. C. After the drying and firing, a porous matrix of the fibers is formed which flamelessly combusts a fuel-air mixture. During combustion, the aluminum alloy inhibits growth of alumina crystals on the fiber surface to prolong burner life and, in addition, protects the burner both from extreme temperature and flashback.Type: GrantFiled: January 17, 1986Date of Patent: May 24, 1988Assignee: Gas Research InstituteInventor: John J. Lannutti
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Patent number: 4744831Abstract: Novel hollow inorganic spheres are prepared by(1) tumbling together a mixture comprising(a) solidifiable liquid globules that comprise a fugitive organic binder material and a source of volatile void-forming agent and(b) a mass of free-flowing inorganic sinterable parting agent particles that are at least partially absorbed into the globules during the tumbling action;(2) providing conditions under which hollow spheres form in which the sphere walls contain the sinterable particles; and(3) firing the spheres to remove the binder material and sinter the parting agent particles to form shape-retaining spheres having sintered inorganic walls.Type: GrantFiled: July 30, 1984Date of Patent: May 17, 1988Assignee: Minnesota Mining and Manufacturing CompanyInventor: Warren R. Beck
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Patent number: 4707311Abstract: In a method of manufacturing silica-free, interconnected porous ceramics, use is made of ceramic material powder which exhibits an expansion phenomenon due to reaction when fired; the ceramic material powder is mixed with binder; the mixture is molded; thereafter the molded mixture is fired and, during the firing process, held for a predetermined period of time at a predetermined temperature which is not lower than a temperature at which maximum expansion occurs in the expansion phenomenon but lower than a temperature at which the firing of the molded mixture is completed; and the firing process is stopped after a lapse of the predetermined period of time.Type: GrantFiled: August 10, 1984Date of Patent: November 17, 1987Assignee: Mitsubishi Mining & Cement Co., Ltd.Inventor: Kiyoshi Okazaki
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Patent number: 4705767Abstract: Surface active agent added to an acid-peptized alumina catalyst paste preserves macropores in the calcined particle.Type: GrantFiled: December 15, 1986Date of Patent: November 10, 1987Assignee: W. R. Grace & Co.Inventors: Wu-Cheng Cheng, Richard G. Donnelly
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Patent number: 4698264Abstract: A solid, water-dispersible, delayed-release particulate composition comprising: a matrix composition, a relatively small amount of an active ingredient insoluble in and uniformly distributed through the matrix composition, the matrix composition comprising: a normally solid, slowly water soluble or slightly water soluble salt selected from the group consisting of alkali metal and calcium phosphates, citrates, tartrates and carbonates, and hydrates thereof, and readily cold water soluble bulking agent.Type: GrantFiled: May 3, 1985Date of Patent: October 6, 1987Assignee: Durkee Industrial Foods, Corp.Inventor: James A. Steinke
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Patent number: 4697632Abstract: Ceramic porous bodies, including ceramic foam filters and smooth-faced ceramic objects, e.g., ceramic foam bricks, ceramic foam melting crucibles, and ceramic foam cores, made in accordance with the present invention are suitable for use with molten metal in general and molten superalloys in particular. The invention also provides a tundish for use with ceramic foam filters to filter metal en route from a metal furnace to a casting mold, and a melting device for use in casting metal which employs a ceramic foam filter as a bottom pour valve for a melting crucible such that the ceramic foam filter valve regulates the flow of molten metal therethrough in order to permit an entire ingot of metal to melt in the melting crucible before any metal begins to pour from the melting device into a casting mold.Type: GrantFiled: June 11, 1982Date of Patent: October 6, 1987Assignee: Howmet Turbine Components CorporationInventor: Nick G. Lirones
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Patent number: 4687607Abstract: Disclosed herein is a process for producing a porous carbonaceous electrode substrate provided with elongated holes opening from one side to the opposite side of the electrode substrate through nearly the central region of the thickness of the substrate, for use in fuel cells, characterized by using high polymeric substance as a material for forming the elongated holes.Type: GrantFiled: March 15, 1985Date of Patent: August 18, 1987Assignee: Kureha Kagaku Kogyo Kabushiki KaishaInventors: Masatomo Shigeta, Kuniyuki Saitoh, Hiroyuki Fukuda
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Patent number: 4682718Abstract: Silica powder is added to a primary mixture consisting of alumina powder and graphite powder, and is mixed therewith. A binder is added to the resultant secondary mixture and is well mixed therewith. The mixture thus obtained is granulated. The granulated product is placed in a rubber mold, and pressure is applied uniformly thereto to mold it. The molded product is fired but not sintered at a temperature between 850.degree. and 950.degree. C., preferably 900.degree. C., which allows unreacted alumina and silica to remain in the final fired-product. Thus, a nozzle consisting of a fired body having a cavity volume index (the sum of the volume of open and closed pores/the volume of the fired body) of 0.15-0.25 including 6-60% of closed pores therein is manufactured.Type: GrantFiled: November 12, 1985Date of Patent: July 28, 1987Assignee: Toshiba Ceramics Co., Ltd.Inventors: Kuniaki Watanabe, Hideo Suzuki
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Patent number: 4680153Abstract: In order to produce mineralic bodies of high porosity, usable inter alia as adsorbers, purifiers and catalyst carriers, a predominantly mineralic mass with organic admixtures--both preferably obtained from industrial waste products--are subjected to a three-phase treatment. In a first phase, the mass is heated in an inert or reducing atmosphere to a sintering temperature between about 1000.degree. C. and 1350.degree. C. whereby the organic constituents are carbonized and partly penetrate the consolidating mineralic structure. In a second phase, still under the same nonoxidizing atmosphere and at the sintering temperature referred to, the mineralic structure is sintered into a coherent matrix. In a third phase, with reduction of the temperature to a lower level between about 600.degree. and 1000.degree. C. and exposure to the atmosphere, the carbonaceous substances occluded in the mineralic skeleton are burned off to increase its porosity.Type: GrantFiled: May 29, 1984Date of Patent: July 14, 1987Assignee: Institut for Energetik - Zentralstelle fur Rationelle EnergieanwendungInventors: Reiner Kinder, Johannes Teubel, Herbert Schuster, Christine Fanslau
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Patent number: 4675140Abstract: Solid particles or viscous liquid droplets of core material are encapsulated in a coating material largely as single particles with a single coherent coating, by feeding a suspension of the two materials onto a rotating surface. The suspension is centrifugally dispersed by the rotating surface into relatively large coated particles and relatively small droplets of coating material. Only the size of the droplets of unused coating corresponds to the droplets formed from atomization of the liquid coating material. The size of the coated particles depends on the size of the uncoated particles and is much less dependent upon the atomization characteristics of the rotating surface. Upon being thrown from the rotating surface, or falling from that surface, the droplets and coated particles are solidified by exposure to air and are separated by sieving, or the like. The solidified droplets of pure coating material may be recycled into the suspension.Type: GrantFiled: May 6, 1985Date of Patent: June 23, 1987Assignee: Washington University Technology AssociatesInventors: Robert E. Sparks, Norbert S. Mason
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Patent number: RE32603Abstract: A ceramic foam material and process for making same having superior strength and durability properties wherein the impregnated foam impregnated with an alumina hydrate binder is fired at an elevated temperature so as to produce a ceramic body characterized by a solid state, sintered ceramic bond.Type: GrantFiled: March 23, 1987Date of Patent: February 16, 1988Assignee: Swiss Aluminium Ltd.Inventor: Jerry W. Brockmeyer